ATE440891T1 - Elektronenstrahlvernetzte brom-, chlor- oder iodfunktionelle polymerelektrolyte - Google Patents

Elektronenstrahlvernetzte brom-, chlor- oder iodfunktionelle polymerelektrolyte

Info

Publication number
ATE440891T1
ATE440891T1 AT04795931T AT04795931T ATE440891T1 AT E440891 T1 ATE440891 T1 AT E440891T1 AT 04795931 T AT04795931 T AT 04795931T AT 04795931 T AT04795931 T AT 04795931T AT E440891 T1 ATE440891 T1 AT E440891T1
Authority
AT
Austria
Prior art keywords
sup
electron beam
typically
chlorine
functional polymer
Prior art date
Application number
AT04795931T
Other languages
English (en)
Inventor
Michael A Yandrasits
Steven J Hamrock
Klaus Hintzer
Arne Thaler
Tatsuo Fukushi
Naiyong Jing
Kai H Lochhaas
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Application granted granted Critical
Publication of ATE440891T1 publication Critical patent/ATE440891T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C08J5/225—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/009—After-treatment of organic or inorganic membranes with wave-energy, particle-radiation or plasma
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F114/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F114/18—Monomers containing fluorine
    • C08F114/26—Tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/26—Tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/28—Treatment by wave energy or particle radiation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. insitu polymerisation or insitu crosslinking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • H01M8/1088—Chemical modification, e.g. sulfonation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Plasma & Fusion (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Conductive Materials (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
AT04795931T 2003-11-13 2004-10-20 Elektronenstrahlvernetzte brom-, chlor- oder iodfunktionelle polymerelektrolyte ATE440891T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/712,590 US7265162B2 (en) 2003-11-13 2003-11-13 Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
PCT/US2004/034835 WO2005052041A1 (en) 2003-11-13 2004-10-20 Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam

Publications (1)

Publication Number Publication Date
ATE440891T1 true ATE440891T1 (de) 2009-09-15

Family

ID=34573577

Family Applications (1)

Application Number Title Priority Date Filing Date
AT04795931T ATE440891T1 (de) 2003-11-13 2004-10-20 Elektronenstrahlvernetzte brom-, chlor- oder iodfunktionelle polymerelektrolyte

Country Status (10)

Country Link
US (1) US7265162B2 (de)
EP (1) EP1687363B1 (de)
JP (1) JP4943855B2 (de)
KR (1) KR20060107777A (de)
CN (1) CN100417677C (de)
AT (1) ATE440891T1 (de)
CA (1) CA2545176A1 (de)
DE (1) DE602004022852D1 (de)
TW (1) TW200538495A (de)
WO (1) WO2005052041A1 (de)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7259208B2 (en) * 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7074841B2 (en) * 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7179847B2 (en) * 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7060756B2 (en) * 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
WO2005054363A1 (ja) * 2003-12-01 2005-06-16 Daikin Industries, Ltd. 含フッ素ポリマー液状組成物及びフッ素系架橋体製造方法
US7112614B2 (en) * 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) * 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
US7304101B2 (en) * 2004-07-19 2007-12-04 3M Innovative Properties Company Method of purifying a dispersion of ionic fluoropolymer
US7214740B2 (en) * 2005-05-03 2007-05-08 3M Innovative Properties Company Fluorinated ionomers with reduced amounts of carbonyl end groups
ATE442399T1 (de) * 2007-02-12 2009-09-15 Atomic Energy Council Verfahren zur herstellung einer protonenaustauschmembran
US20110230575A1 (en) * 2007-12-20 2011-09-22 E.I. Du Pont De Nemours And Company Crosslinkable trifluorostyrene polymers and membranes
EP2554579B1 (de) 2008-04-24 2016-03-30 3M Innovative Properties Company Protonenleitende materialen
US7820321B2 (en) 2008-07-07 2010-10-26 Enervault Corporation Redox flow battery system for distributed energy storage
US8785023B2 (en) 2008-07-07 2014-07-22 Enervault Corparation Cascade redox flow battery systems
CA2783850C (en) 2009-12-11 2016-07-12 Shandong Huaxia Shenzhou New Material Co., Ltd Perfluorinated ion exchange resin, preparation method and use thereof
WO2011072418A1 (zh) * 2009-12-15 2011-06-23 山东东岳神舟新材料有限公司 高交换容量全氟离子交换树脂及其制备方法和用途
CN103004001B (zh) 2010-05-25 2016-02-17 3M创新有限公司 强化的电解质膜
US8980484B2 (en) 2011-03-29 2015-03-17 Enervault Corporation Monitoring electrolyte concentrations in redox flow battery systems
US8916281B2 (en) 2011-03-29 2014-12-23 Enervault Corporation Rebalancing electrolytes in redox flow battery systems
CN103732680B (zh) * 2011-08-04 2016-10-26 3M创新有限公司 低当量重量聚合物
US10164284B2 (en) 2012-07-27 2018-12-25 Lockheed Martin Energy, Llc Aqueous redox flow batteries featuring improved cell design characteristics
US9559374B2 (en) 2012-07-27 2017-01-31 Lockheed Martin Advanced Energy Storage, Llc Electrochemical energy storage systems and methods featuring large negative half-cell potentials
US9899694B2 (en) 2012-07-27 2018-02-20 Lockheed Martin Advanced Energy Storage, Llc Electrochemical energy storage systems and methods featuring high open circuit potential
US9865893B2 (en) 2012-07-27 2018-01-09 Lockheed Martin Advanced Energy Storage, Llc Electrochemical energy storage systems and methods featuring optimal membrane systems
US9768463B2 (en) 2012-07-27 2017-09-19 Lockheed Martin Advanced Energy Storage, Llc Aqueous redox flow batteries comprising metal ligand coordination compounds
US9382274B2 (en) 2012-07-27 2016-07-05 Lockheed Martin Advanced Energy Storage, Llc Aqueous redox flow batteries featuring improved cell design characteristics
US8753761B2 (en) 2012-07-27 2014-06-17 Sun Catalytix Corporation Aqueous redox flow batteries comprising metal ligand coordination compounds
US9692077B2 (en) 2012-07-27 2017-06-27 Lockheed Martin Advanced Energy Storage, Llc Aqueous redox flow batteries comprising matched ionomer membranes
US8691413B2 (en) 2012-07-27 2014-04-08 Sun Catalytix Corporation Aqueous redox flow batteries featuring improved cell design characteristics
PL3224266T3 (pl) 2014-11-26 2021-09-27 Lockheed Martin Energy, Llc Kompleksy metali podstawionych katecholanów i zawierające je akumulatory przepływowe redoks
US10253051B2 (en) 2015-03-16 2019-04-09 Lockheed Martin Energy, Llc Preparation of titanium catecholate complexes in aqueous solution using titanium tetrachloride or titanium oxychloride
CN108137750A (zh) 2015-09-23 2018-06-08 3M创新有限公司 制备具有磺酰基侧基的四氟乙烯共聚物的方法
US10644342B2 (en) 2016-03-03 2020-05-05 Lockheed Martin Energy, Llc Coordination complexes containing monosulfonated catecholate ligands and methods for producing the same
US10316047B2 (en) 2016-03-03 2019-06-11 Lockheed Martin Energy, Llc Processes for forming coordination complexes containing monosulfonated catecholate ligands
US9938308B2 (en) 2016-04-07 2018-04-10 Lockheed Martin Energy, Llc Coordination compounds having redox non-innocent ligands and flow batteries containing the same
US10377687B2 (en) 2016-07-26 2019-08-13 Lockheed Martin Energy, Llc Processes for forming titanium catechol complexes
US10343964B2 (en) 2016-07-26 2019-07-09 Lockheed Martin Energy, Llc Processes for forming titanium catechol complexes
US10065977B2 (en) 2016-10-19 2018-09-04 Lockheed Martin Advanced Energy Storage, Llc Concerted processes for forming 1,2,4-trihydroxybenzene from hydroquinone
US10930937B2 (en) 2016-11-23 2021-02-23 Lockheed Martin Energy, Llc Flow batteries incorporating active materials containing doubly bridged aromatic groups
US10497958B2 (en) 2016-12-14 2019-12-03 Lockheed Martin Energy, Llc Coordinatively unsaturated titanium catecholate complexes and processes associated therewith
US10741864B2 (en) 2016-12-30 2020-08-11 Lockheed Martin Energy, Llc Aqueous methods for forming titanium catecholate complexes and associated compositions
US10320023B2 (en) 2017-02-16 2019-06-11 Lockheed Martin Energy, Llc Neat methods for forming titanium catecholate complexes and associated compositions
WO2019055793A1 (en) 2017-09-14 2019-03-21 3M Innovative Properties Company FLUOROPOLYMER DISPERSION, METHOD FOR PRODUCING FLUOROPOLYMER DISPERSION, CATALYTIC INK, AND POLYMER ELECTROLYTE MEMBRANE

Family Cites Families (101)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3635926A (en) * 1969-10-27 1972-01-18 Du Pont Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers
US3784399A (en) * 1971-09-08 1974-01-08 Du Pont Films of fluorinated polymer containing sulfonyl groups with one surface in the sulfonamide or sulfonamide salt form and a process for preparing such
US4000356A (en) * 1972-06-19 1976-12-28 Dynamit Nobel Aktiengesellschaft Process for the preparation of thermoplastically workable fluoro-olefin polymers
US3853828A (en) * 1973-11-21 1974-12-10 Us Army Process for crosslinking fluorocarbon polymers
US4169023A (en) * 1974-02-04 1979-09-25 Tokuyama Soda Kabushiki Kaisha Electrolytic diaphragms, and method of electrolysis using the same
US4035565A (en) * 1975-03-27 1977-07-12 E. I. Du Pont De Nemours And Company Fluoropolymer containing a small amount of bromine-containing olefin units
US4073752A (en) 1975-06-02 1978-02-14 The B. F. Goodrich Company High normality ion exchange membranes containing entrapped electrostatically bulky multicharged ions and method of production
GB1518387A (en) 1975-08-29 1978-07-19 Asahi Glass Co Ltd Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide
US4508603A (en) * 1976-08-22 1985-04-02 Asahi Glass Company Ltd. Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide
JPS5329291A (en) 1976-09-01 1978-03-18 Toyo Soda Mfg Co Ltd Cation exchange membrane and production of the same
JPS5397988A (en) 1977-02-08 1978-08-26 Toyo Soda Mfg Co Ltd Production of cation exchange membrane
FR2387260A1 (fr) 1977-04-12 1978-11-10 Rhone Poulenc Ind Membranes echangeuses d'ions
JPS53134088A (en) 1977-04-28 1978-11-22 Asahi Glass Co Ltd Production of fluorocopolymer having ion exchange groups and its crosslinked article
US4230549A (en) * 1977-05-31 1980-10-28 Rai Research Corporation Separator membranes for electrochemical cells
JPS53149881A (en) * 1977-06-03 1978-12-27 Asahi Glass Co Ltd Strengthened cation exchange resin membrane and production thereof
JPS6026145B2 (ja) 1977-10-04 1985-06-21 旭硝子株式会社 改良された含フツ素陽イオン交換膜
DE2964541D1 (en) * 1978-09-05 1983-02-24 Ici Plc Sulphonated polyaryletherketones and process for the manufacture thereof
US4281092A (en) * 1978-11-30 1981-07-28 E. I. Du Pont De Nemours And Company Vulcanizable fluorinated copolymers
US4242498A (en) * 1979-04-09 1980-12-30 Frosch Robert A Process for the preparation of fluorine containing crosslinked elastomeric polytriazine and product so produced
JPS5672002A (en) 1979-11-16 1981-06-16 Asahi Glass Co Ltd Production of fluorine-containing polymer containing iodine
US4330654A (en) * 1980-06-11 1982-05-18 The Dow Chemical Company Novel polymers having acid functionality
US4470889A (en) * 1980-06-11 1984-09-11 The Dow Chemical Company Electrolytic cell having an improved ion exchange membrane and process for operating
DE3023455A1 (de) * 1980-06-24 1982-01-14 Hoechst Ag, 6000 Frankfurt Verfahren zur fluorierung von polymeren und perfluorierte ionenaustauscher
US4334082A (en) 1980-09-26 1982-06-08 E. I. Du Pont De Nemours And Company Dialkyl perfluoro-ω-fluoroformyl diesters and monomers and polymers therefrom
US4414159A (en) * 1980-09-26 1983-11-08 E. I. Du Pont De Nemours & Co. Vinyl ether monomers and polymers therefrom
ZA818207B (en) * 1980-11-27 1982-10-27 Ici Australia Ltd Permselective membranes
US4391844A (en) * 1981-06-26 1983-07-05 Diamond Shamrock Corporation Method for making linings and coatings from soluble cross-linkable perfluorocarbon copolymers
US4440917A (en) * 1981-12-14 1984-04-03 E. I. Du Pont De Nemours & Company Vinyl ethers monomers and polymers therefrom
US4454247A (en) * 1981-12-14 1984-06-12 E. I. Du Pont De Nemours & Company Ion exchange membranes
JPS60250009A (ja) 1984-05-25 1985-12-10 Asahi Glass Co Ltd スルホン酸型官能基を有するパ−フルオロカ−ボン重合体の製造方法
JPH0657723B2 (ja) * 1984-07-13 1994-08-03 エルフ アトケム ソシエテ アノニム 新規なイオン性フッ素化ポリマーと、その製造方法
JPH0641494B2 (ja) * 1984-08-31 1994-06-01 旭化成工業株式会社 架橋可能な含フツ素共重合体
US4686024A (en) * 1985-02-01 1987-08-11 The Green Cross Corporation Novel perfluoro chemicals and polyfluorinated compounds and process for production of the same
US4743419A (en) * 1985-03-04 1988-05-10 The Dow Chemical Company On-line film fluorination method
US4755567A (en) * 1985-11-08 1988-07-05 Exfluor Research Corporation Perfluorination of ethers in the presence of hydrogen fluoride scavengers
US5693748A (en) * 1989-02-01 1997-12-02 Asahi Kasei Kogyo Kabushiki Kaisha High molecular weight polyimidoylamidine and a polytriazine derived therefrom
JP2750594B2 (ja) 1989-02-01 1998-05-13 旭化成工業株式会社 高分子量ポリイミドイルアミジンとその製造法および用途
US5986012A (en) * 1989-04-24 1999-11-16 E. I. Du Pont De Nemours And Company Fluorination of radiation crosslinked perfluoroelastomers
US5260351A (en) * 1989-04-24 1993-11-09 E. I. Du Pont De Nemours And Company Radiation curing of perfluoroelastomers
IT1235545B (it) 1989-07-10 1992-09-09 Ausimont Srl Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione
FR2670791A1 (fr) * 1990-12-21 1992-06-26 Atochem Composition a base de copolymere fluore reticulable pour peintures et vernis.
US5852148A (en) * 1991-07-10 1998-12-22 Minnesota Mining & Manufacturing Company Perfluoroalkyl halides and derivatives
US6048952A (en) * 1991-07-10 2000-04-11 3M Innovative Properties Company Perfluoroalkyl halides and derivatives
US5264508A (en) * 1992-06-25 1993-11-23 The Dow Chemical Company Polymers of haloperfluoro and perfluoro ethers
US5330626A (en) * 1993-02-16 1994-07-19 E. I. Du Pont De Nemours And Company Irradiation of polymeric ion exchange membranes to increase water absorption
WO1995010541A1 (fr) * 1993-10-12 1995-04-20 Asahi Kasei Kogyo Kabushiki Kaisha Copolymere de perfluorocarbone ayant des groupes fonctionnels et procede pour sa production
US5466930A (en) * 1994-02-23 1995-11-14 Florida State University Solid scintillators for detecting radioactive ions in solution
US5447993A (en) * 1994-04-19 1995-09-05 E. I. Du Pont De Nemours And Company Perfluoroelastomer curing
JP3298321B2 (ja) * 1994-08-31 2002-07-02 ダイキン工業株式会社 ビニリデンフルオライド系共重合体水性分散液、ビニリデンフルオライド系シード重合体水性分散液およびそれらの製法
US6254978B1 (en) * 1994-11-14 2001-07-03 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
USRE37701E1 (en) * 1994-11-14 2002-05-14 W. L. Gore & Associates, Inc. Integral composite membrane
USRE37307E1 (en) * 1994-11-14 2001-08-07 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
US5547551A (en) * 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
US5795496A (en) * 1995-11-22 1998-08-18 California Institute Of Technology Polymer material for electrolytic membranes in fuel cells
DE19622337C1 (de) * 1996-06-04 1998-03-12 Dlr Deutsche Forschungsanstalt Vernetzung von modifizierten Engineering Thermoplasten
US5798417A (en) * 1996-10-15 1998-08-25 E. I. Du Pont De Nemours And Company (Fluorovinyl ether)-grafted high-surface-area polyolefins and preparation thereof
US5747546A (en) * 1996-12-31 1998-05-05 The Dow Chemical Company Ion-exchange polymers having an expanded microstructure
EP1026152B1 (de) * 1997-03-31 2006-07-26 Daikin Industries, Limited Verfahren zur herstellung von perfluorvinylethersulfonsäure-derivaten
JP4657390B2 (ja) * 1997-07-25 2011-03-23 アセップ・インク ペルフルオロビニルイオン化合物および重合体型のイオン電導体の成分、選択膜の成分または触媒の成分としてのそれらの使用
US6248469B1 (en) * 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
JPH11111310A (ja) * 1997-09-30 1999-04-23 Aisin Seiki Co Ltd 燃料電池用の固体高分子電解質膜およびその製造方法
DE19854728B4 (de) * 1997-11-27 2006-04-27 Aisin Seiki K.K., Kariya Polymerelektrolyt-Brennstoffzelle
US6462228B1 (en) * 1997-12-22 2002-10-08 3M Innovative Properties Company Process for preparation of fluorinated sulfinates
JPH11204121A (ja) * 1998-01-19 1999-07-30 Aisin Seiki Co Ltd 固体高分子電解質型燃料電池
EP1400539B1 (de) * 1998-01-30 2008-12-03 Hydro Quebec Verfahren zur Herstellung von vernetzten sulfonierten Polymeren
WO1999045048A1 (en) * 1998-03-03 1999-09-10 E.I. Du Pont De Nemours And Company Substantially fluorinated ionomers
JP4150867B2 (ja) 1998-05-13 2008-09-17 ダイキン工業株式会社 燃料電池に使用するのに適した固体高分子電解質用材料
US6090895A (en) * 1998-05-22 2000-07-18 3M Innovative Properties Co., Crosslinked ion conductive membranes
CN1142976C (zh) * 1998-05-29 2004-03-24 纳幕尔杜邦公司 纤维及其制法
KR20010073167A (ko) * 1998-09-15 2001-07-31 캐써린 메리 스프링에트 ; 앤드류 존 론스 ; 앤드류 존 스완슨 수기제 그라프팅
US6255370B1 (en) * 1999-04-29 2001-07-03 Railroad-Solutions, Llc Rail spike retention and tie preservation mixture and method
US6277512B1 (en) * 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
JP4539896B2 (ja) 1999-09-17 2010-09-08 独立行政法人産業技術総合研究所 プロトン伝導性膜、その製造方法及びそれを用いた燃料電池
US6423784B1 (en) * 1999-12-15 2002-07-23 3M Innovative Properties Company Acid functional fluoropolymer membranes and method of manufacture
JP4352546B2 (ja) * 1999-12-22 2009-10-28 ユニマテック株式会社 フルオロエラストマー、その製造方法、架橋性組成物およびその硬化物
JP4406984B2 (ja) * 1999-12-22 2010-02-03 旭硝子株式会社 固体高分子電解質型燃料電池用電極用塗工液及び固体高分子電解質型燃料電池用電極の製造方法
US6780935B2 (en) * 2000-02-15 2004-08-24 Atofina Chemicals, Inc. Fluoropolymer resins containing ionic or ionizable groups and products containing the same
DE10021104A1 (de) 2000-05-02 2001-11-08 Univ Stuttgart Organisch-anorganische Membranen
DE10024576A1 (de) * 2000-05-19 2001-11-22 Univ Stuttgart Kovalent und ionisch vernetzte Polymere und Polymermembranen
US6982303B2 (en) * 2000-05-19 2006-01-03 Jochen Kerres Covalently cross-linked polymers and polymer membranes via sulfinate alkylation
CA2312194A1 (fr) * 2000-06-13 2001-12-13 Mario Boucher Elastomeres reticulables fluores bromosulfones a faible tg a base de fluorure de vinylidene et ne contenant ni du tetrafluoroethylene ni de groupement siloxane
IT1318593B1 (it) * 2000-06-23 2003-08-27 Ausimont Spa Ionomeri fluorurati.
IT1318669B1 (it) 2000-08-08 2003-08-27 Ausimont Spa Ionomeri fluorurati solfonici.
WO2002062749A1 (fr) 2001-02-01 2002-08-15 Asahi Kasei Kabushiki Kaisha Monomere d'ether perfluorovinylique ayant un groupe sulfonamide
ITMI20010383A1 (it) * 2001-02-26 2002-08-26 Ausimont Spa Membrane idrofiliche porose
DE10114243B4 (de) * 2001-03-22 2004-07-29 Heraeus Kulzer Gmbh & Co. Kg Verfahren zur Herstellung einer Prothese sowie Prothesenwerkstoff und dessen Verwendung
US6503378B1 (en) * 2001-04-23 2003-01-07 Motorola, Inc. Polymer electrolyte membrane and method of fabrication
US7045571B2 (en) * 2001-05-21 2006-05-16 3M Innovative Properties Company Emulsion polymerization of fluorinated monomers
DE60228303D1 (de) * 2001-10-15 2008-09-25 Du Pont Festpolymermembran für eine brennstoffzelle mit darin eingebettetem polyvinylamin für verringerte methanoldurchlässigkeit
US6727386B2 (en) * 2001-10-25 2004-04-27 3M Innovative Properties Company Aromatic imide and aromatic methylidynetrissulfonyl compounds and method of making
JP2004010744A (ja) * 2002-06-06 2004-01-15 Japan Atom Energy Res Inst 大きなイオン交換容量と優れた耐酸化性を有するフッ素系高分子共重合体及びその製造方法
US6624328B1 (en) * 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7179847B2 (en) * 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7074841B2 (en) * 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7259208B2 (en) * 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7060756B2 (en) * 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7112614B2 (en) 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) * 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) * 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination

Also Published As

Publication number Publication date
JP4943855B2 (ja) 2012-05-30
TW200538495A (en) 2005-12-01
WO2005052041A1 (en) 2005-06-09
EP1687363A1 (de) 2006-08-09
EP1687363B1 (de) 2009-08-26
JP2007515508A (ja) 2007-06-14
CN100417677C (zh) 2008-09-10
KR20060107777A (ko) 2006-10-16
US20050107490A1 (en) 2005-05-19
CA2545176A1 (en) 2005-06-09
DE602004022852D1 (de) 2009-10-08
CN1882643A (zh) 2006-12-20
US7265162B2 (en) 2007-09-04

Similar Documents

Publication Publication Date Title
ATE440891T1 (de) Elektronenstrahlvernetzte brom-, chlor- oder iodfunktionelle polymerelektrolyte
JP4997968B2 (ja) 固体高分子形燃料電池用電解質材料、電解質膜及び膜電極接合体
JP6856073B2 (ja) 電解質材料、それを含む液状組成物およびその使用
RU2001130757A (ru) Фторполимеры, содержащие ионные или ионизируемые группы, и продукты, содержащие указанные фторполимеры
DE602004018380D1 (de) Polymerelektrolyt mit aromatischer sulfonvernetzung
US20170098846A1 (en) Electrolyte material, liquid composition, membrane electrode assembly for polymer electrolyte fuel cell and fluorinated branched polymer
JP2004134294A (ja) 固体高分子電解質
WO2017221840A1 (ja) 電解質材料、その製造方法およびその使用
KR20070008544A (ko) 직접 플루오르화에 의해 가교결합된 폴리머 전해질 막
CN101037506A (zh) 多嵌段共聚物、其制备方法、由其制备的聚合物电解质膜、膜的制备方法和用膜的燃料电池
CN107849364B (zh) 液体组合物、其制造方法以及膜电极接合体的制造方法
US20050131096A1 (en) Crosslinked polymer
WO2008023801A1 (fr) Membrane électrolytique polymère composée d'une base de membrane polymère aromatique et son procédé de production
JP2011140605A (ja) 高酸素透過電解質及びその製造方法、並びに、スルホンイミドモノマ
KR101298796B1 (ko) 전해질막
WO2012096653A1 (en) Proton exchange material and method therefor
JP2002348389A (ja) 広いイオン交換容量を有するフッ素系高分子イオン交換膜及びその製造方法
JP6635112B2 (ja) 液状組成物、固体高分子電解質膜、触媒層および膜電極接合体の製造方法
JP4979236B2 (ja) 架橋電解質膜及びその製造方法
JP2012226970A (ja) 電解質
AU2004302304B2 (en) Photovoltaic cell
JP2005294171A (ja) 固体高分子電解質、その製造方法、及び固体高分子電解質膜
US9212246B1 (en) Methods of producing cross-linked polymer electrolyte membranes having free-radical scavengers
JP2007507560A5 (de)
JP5477583B2 (ja) 放射線架橋フッ素系固体高分子電解質とその製造方法

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties