ATE314144T1 - Verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung von chiralen salenkatalysatoren - Google Patents
Verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung von chiralen salenkatalysatorenInfo
- Publication number
- ATE314144T1 ATE314144T1 AT01932385T AT01932385T ATE314144T1 AT E314144 T1 ATE314144 T1 AT E314144T1 AT 01932385 T AT01932385 T AT 01932385T AT 01932385 T AT01932385 T AT 01932385T AT E314144 T1 ATE314144 T1 AT E314144T1
- Authority
- AT
- Austria
- Prior art keywords
- chiral
- catalysts
- epoxides
- compounds
- producing
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 6
- 150000002118 epoxides Chemical class 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- VEUMANXWQDHAJV-UHFFFAOYSA-N 2-[2-[(2-hydroxyphenyl)methylideneamino]ethyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCN=CC1=CC=CC=C1O VEUMANXWQDHAJV-UHFFFAOYSA-N 0.000 abstract 5
- 150000000180 1,2-diols Chemical class 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000000269 nucleophilic effect Effects 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 230000000707 stereoselective effect Effects 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/48—Ring-opening reactions
- B01J2231/482—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates
- B01J2231/485—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates kinetic resolution of epoxide racemates
- B01J2231/487—Ring-opening reactions asymmetric reactions, e.g. kinetic resolution of racemates kinetic resolution of epoxide racemates by hydrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20000028099 | 2000-05-24 | ||
PCT/KR2001/000854 WO2001089690A1 (en) | 2000-05-24 | 2001-05-23 | Novel chiral salen catalysts, and a process for preparing chiral compounds from racemic epoxides for using them |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE314144T1 true ATE314144T1 (de) | 2006-01-15 |
Family
ID=19670066
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT01932385T ATE314144T1 (de) | 2000-05-24 | 2001-05-23 | Verfahren zur herstellung chiraler verbindungen aus racemischen epoxiden unter verwendung von chiralen salenkatalysatoren |
Country Status (9)
Country | Link |
---|---|
US (1) | US6720434B2 (de) |
EP (1) | EP1289655B1 (de) |
JP (1) | JP3962587B2 (de) |
CN (1) | CN1174804C (de) |
AT (1) | ATE314144T1 (de) |
AU (1) | AU5891201A (de) |
DE (1) | DE60116295D1 (de) |
IN (1) | IN2002DE01011A (de) |
WO (1) | WO2001089690A1 (de) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2002345388A1 (en) * | 2001-06-27 | 2003-03-03 | Rs Tech Corp. | New chiral salen catalyst and methods for the preparation of chiral compounds from racemic epoxides by using new catalyst |
EP1419128A4 (de) | 2001-08-22 | 2006-02-15 | Rhodia Pharma Solution Inc For | Verbesserte hydrolytische kinetische racemattrennung von epoxiden |
US6639087B2 (en) * | 2001-08-22 | 2003-10-28 | Rhodia Pharma Solutions Inc. | Kinetic resolution method |
DE10164348A1 (de) | 2001-12-28 | 2003-07-17 | Basf Ag | Verfahren zur Herstellung von 1-Methoypropanol-2 |
DE10208252A1 (de) * | 2002-02-26 | 2003-09-04 | Celanese Ventures Gmbh | Konvalent fixierte Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen |
WO2004076391A1 (ja) * | 2003-02-28 | 2004-09-10 | Japan Science And Technology Agency | 光学活性化合物の製造方法 |
US20070092541A1 (en) * | 2004-03-01 | 2007-04-26 | Walling David W | Direct contact quench crystallization process and cosmetic products produced thereby |
US7304172B2 (en) * | 2004-10-08 | 2007-12-04 | Cornell Research Foundation, Inc. | Polycarbonates made using highly selective catalysts |
US7399822B2 (en) * | 2005-06-21 | 2008-07-15 | Cornell Research Foundation, Inc. | Isotactic specific catalyst for direct production of highly isotactic poly (propylene oxide) or highly isotactic poly (butylene oxide) |
KR100894680B1 (ko) * | 2007-06-13 | 2009-04-24 | 주식회사 카이로켐 | 신규 키랄 살렌 촉매와 이를 이용한 라세믹 에폭시화합물로부터 키랄 화합물의 제조방법 |
US20090286968A1 (en) * | 2008-04-25 | 2009-11-19 | Auburn University | 2-Quinoxalinol Salen Compounds and Uses Thereof |
CN101967165B (zh) * | 2010-09-21 | 2012-09-05 | 中国科学院上海有机化学研究所 | 桥链双希夫碱-钴络合物及其合成方法和用途 |
TR201202779A2 (tr) | 2012-03-12 | 2013-10-21 | Petkim Petrokimya Holding Anonim Sirketi | Polietilen karbonat üretim yöntemi. |
EP2664641B1 (de) | 2012-05-18 | 2018-04-25 | Petkim Petrokimya Holding Anonim Sirekti | Verfahren zur herstellung von polyethylencarbonat mit metallsalzen |
CA3107987A1 (en) * | 2018-07-31 | 2020-02-06 | China Petroleum & Chemical Corporation | Nanocage-confined catalyst, preparation process and use thereof |
CN111097529B (zh) * | 2018-10-25 | 2023-05-02 | 中国石油化工股份有限公司 | 高性能纳米笼限域催化剂、制备方法及应用 |
CN113943206A (zh) * | 2021-10-25 | 2022-01-18 | 华今(山东)新材料科技有限公司 | 一种高品质(r)-3-氯-1,2-丙二醇的制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5637739A (en) * | 1990-03-21 | 1997-06-10 | Research Corporation Technologies, Inc. | Chiral catalysts and catalytic epoxidation catalyzed thereby |
AU648301B2 (en) * | 1990-03-21 | 1994-04-21 | Research Corporation Technologies, Inc. | Chiral catalysts and epoxidation reactions catalyzed thereby |
US5665890A (en) * | 1995-03-14 | 1997-09-09 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
US6262278B1 (en) * | 1995-03-14 | 2001-07-17 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
-
2001
- 2001-05-23 CN CNB018094376A patent/CN1174804C/zh not_active Expired - Fee Related
- 2001-05-23 EP EP01932385A patent/EP1289655B1/de not_active Expired - Lifetime
- 2001-05-23 AT AT01932385T patent/ATE314144T1/de not_active IP Right Cessation
- 2001-05-23 JP JP2001585922A patent/JP3962587B2/ja not_active Expired - Fee Related
- 2001-05-23 WO PCT/KR2001/000854 patent/WO2001089690A1/en active IP Right Grant
- 2001-05-23 AU AU58912/01A patent/AU5891201A/en not_active Abandoned
- 2001-05-23 US US10/181,193 patent/US6720434B2/en not_active Expired - Lifetime
- 2001-05-23 DE DE60116295T patent/DE60116295D1/de not_active Expired - Lifetime
-
2002
- 2002-10-09 IN IN1011DE2002 patent/IN2002DE01011A/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO2001089690A1 (en) | 2001-11-29 |
US20030032821A1 (en) | 2003-02-13 |
US6720434B2 (en) | 2004-04-13 |
AU5891201A (en) | 2001-12-03 |
JP3962587B2 (ja) | 2007-08-22 |
EP1289655A1 (de) | 2003-03-12 |
JP2003534117A (ja) | 2003-11-18 |
IN2002DE01011A (de) | 2005-01-28 |
CN1436098A (zh) | 2003-08-13 |
EP1289655B1 (de) | 2005-12-28 |
DE60116295D1 (de) | 2006-02-02 |
CN1174804C (zh) | 2004-11-10 |
EP1289655A4 (de) | 2004-03-31 |
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Legal Events
Date | Code | Title | Description |
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RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |