AR046790A1 - Pirimidinas herbicidas. mezclas que las contienen. - Google Patents

Pirimidinas herbicidas. mezclas que las contienen.

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Publication number
AR046790A1
AR046790A1 ARP040104675A AR046790A1 AR 046790 A1 AR046790 A1 AR 046790A1 AR P040104675 A ARP040104675 A AR P040104675A AR 046790 A1 AR046790 A1 AR 046790A1
Authority
AR
Argentina
Prior art keywords
alkyl
haloalkyl
phenyl
optionally substituted
alkoxy
Prior art date
Application number
Other languages
English (en)
Inventor
David Clark
Bruce Finkelstein
Gregory Armel
Vernon Wittenbach
Original Assignee
Du Pont
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Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of AR046790A1 publication Critical patent/AR046790A1/es

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/26—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/30—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32—One oxygen, sulfur or nitrogen atom
    • C07D239/42—One nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/47—One nitrogen atom and one oxygen or sulfur atom, e.g. cytosine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/48—Two nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/04—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente se refiere a pirimidinas herbicidas, también se describen composiciones que comprenden los compuestos herbicidas que comprenden estos compuestos Reivindicación 1: Un compuesto seleccionado de la fórmula (19, un N-óxido o una sal agrícolamente aceptable del mismo, en donde R1 es ciclopropilo sustituido opcionalmente con 1-5 R5, isopropilo sustituido opcionalmente con 1-5 R6 o fenilo sustituido con 1-3 R7; R2 es ((O)jC(R15)(R16))kR; R es CO2H o un derivado herbicidamente efectivo de CO2H; R3 es halógeno, ciano, nitro, OR20, SR21 o N(R22)R23; R4 es -N(R24)R25 o -NO2; cada R5 y R6 es independientemente halógeno, alquilo C1-6, haloalquilo C1-6-alquenilo C2-6, haloalquenilo C2-6, alcoxi C1-3, haloalcoxi C1-2, alquiltio C1-3 o haloalquiltio C1-2; cada R7 es independientemente halógeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, cicloalquilo C3-6, halocicloalquilo C3-6, hidroxialquilo C1-4, alcoxialquilo C2-4, haloalcoxialquilo C2-4, alquenilo C2-4, haloalquenilo C2-4, alquinilo C3-4, haloalquinilo C3-4, hidroxi, alcoxi C1-4, haloalcoxi C1-4, alqueniloxi C2-4, haloalqueniloxi C2-4, alquiniloxi C3-4, haloalquiniloxi C3-4, alquiltio C1-4, haloalquiltio C1-4, alquilsulfinilo C1-4, haloalquilsulfinilo C1-4, alquilsulfonilo C1-4, haloalquilsulfonilo C2-4, alqueniltio 2-4, haloalqueniltio C2-4, alquenilsulfinilo C2-4, haloalquenilsulfinilo C2-4, alquenilsulfonilo C2-4, haloalquenilsulfonilo C2-4, alquiniltio C3-4, haloalquiniltio C3-4, alquilsulfinilo C3- 4, haloalquinilsulfinilo C3-4, alquinilsulfonilo C3-4, haloalquinilsulfonilo C3-4, alquilamino C1-4, dialquilamino C2-8, cicloalquilamino C3-6, (alquil)cicloalquilamino C4-6, alquilcarbonilo C2-6,alcoxicarbonilo C2-6, alquilaminocarbonilo C2-6, dialquilaminocarbonilo C3-8, trialquilsililo C3-6, fenilo, fenoxi y anillos heteroaromáticos de 5 o 6 miembros, cada fenilo, fenoxi y anillo heteroaromático de 5 o 6 miembros es sustituido opcionalmente con uno a tres sustituyentes seleccionados independientemente de R45 o dos R7 adyacentes se toman juntos como -OCH2O-, CH2CH2O-, OCH(CH3)O-, -OC(CH3)2O-, OCF2O-, -CF2CF2O-, -OCF2CF2O- o -CH=CH-CH=CH-; R15 es H, halógeno, alquilo C1-4, haloalquilo C1-4, hidroxi, alcoxi C1-4 o alquilcarboniloxi C2-4; R16 es H, halógeno, alquilo C1-4 o haloalquilo C1-4; o R15 y R16 se toman juntos como un átomo de O para formar, con el átomo de C al cual están unidos, una porción carbonilo; R20 es H, alquilo C1-4 o haloalquilo C1-3; R21 es H, alquilo C1-4 o haloalquilo C1-3; R22 y R23 son independientemente H o alquilo C1-4; R24 es h, alquilo C1-4 sustituido opcionalmente con 1-2 R30, alquenilo C2-4 opcionalmente sustituido con 1-2 R31 o alquinilo C2-4 sustituido opcionalmente con 1-2 R32; o R24 es C(=O)R33, nitro, OR34, S(O)2R35, N(R36)R37 o N=C(R62)R63; R25 es H, alquilo C1-4 sustituido opcionalmente con 1-2 R30 o C(=O)R33; o R24 y R25 se toman juntos como un radical seleccionado de -(CH2)4-,-(CH2)5-, -CH2CH=CHCH2- y - (CH2)2O(CH2)2-, cada radical sustituido opcionalmente con 1-2 R38; o R24 y R25 se toman juntos como =C(R39)N(R40)R41 o =C(R42)OR43; cada R30, R31 y R32 es independientemente halógeno, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, haloalquiltio C1-3, amino, alquilamino C1-3, dialquilamino C2-4 o alcoxicarbonilo C2-4; cada R33 es independientemente H, alquilo C1-14, haloalquilo C1-3, alcoxi C1-4, fenilo, fenoxi o benciloxi; R34 es H, alquilo C1-4, haloalquilo C1-3 o CHR66C(O)OR67; R35 es alquilo C1-4 o haloalquilo C1-3; R36 es H, alquilo C1-4 o C(=O)R64; R37 es H o alquilo C1-4; cada R38 es independientemente halógeno, alquilo C1-3, alcoxi C1-3, haloalcoxi C1-3, alquiltio C1-3, haloalquiltio C1-3, amino, alquilamino C1-3, dialquilamino C2-4 o alcoxicarbonilo C2-4; R39 es H o alquilo C1-4; R40 y R41 son independientemente H o alquilo C1-4; o R40 y R41 se toman juntos como -(CH2)4-, -(CH2)5-, -CH2CH=CHCH2- o -(CH2)2O(CH2)2-; R42 es H o alquilo C1-4; R43 es alquilo C1-4 cada R45 es independientemente halógeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, cicloalquilo C3-6, halocicloalquilo C3-6, alquenilo C2-4, haloalquenilo C2-4, alquinilo C3-4, haloalquinilo C3-4, alcoxi C1-4, haloalcoxi C1-4, alquiltio C1-4, haloalquiltio C1-4, alquilsulfinilo C1-4, alquilsulfonilo C1-4, alquilamino C1-4, dialquilamino C2-8, cicloalquilamino C3-6, alquilcicloalquilamino C4-6, alquilcarbonilo C2-4, alcoxicarbonilo C2-6, alquilaminocarbonilo C2-6, dialquilaminocarbonilo C3-8 o trialquilsililo C3-6; R62es H, alquilo C1-4 o fenilo sustituido opcionalmente con 1-3 R65; R63 es H o alquilo C1-4; o R62 y R63 se toman juntos como -(CH2)4- o -(CH2)5-; R64 es H, alquilo C1-14, haloalquilo C1-3, alcoxi C1-4, fenilo, fenoxi o benciloxi; cada R65 es independientemente CH3, Cl u OCH3; R66 es H, alquilo C1-4 o alcoxi C1-4; R67 es H, alquilo C1-4 o bencilo; j es 0 o 1; y k es 0 o 1; siempre y cuando que: a) cuando k sea 0, entonces j sea 0; b) cuando R2 sea CH2ORa en donde Ra es H, alquilo o bencilo sustituido opcionalmente, entonces R3 no sea ciano; c) cuando R1 sea fenilo sustituido por Cl en cada una de las posiciones meta, el fenilo también sea sustituido por R7 en la posición para; d) cuando R1 sea fenilo sustituido por R7 en la posición para, el R7 no sea ter-butilo, ciano o fenilo sustituido opcionalmente; e) cuando R1 sea ciclopropilo o isopropilo sustituido opcionalmente con 1-5 R6, entonces R no sea C(=W)N(Rb)S(O)2-Rc-; Rd en donde W es O, S, NRe o NORe, Rb sea H, alquilo C1-4, alquenilo C2-6 o alquinilo C2-6; Rc sea un enlace directo o CHRf, O, NRe o NORe; Rd sea un radical aromático heterocíclico o carbocíclico sustituido opcionalmente que tenga 5 a 6 átomos de anillo, el radical siendo condensado opcionalmente con un anillo de 5 o 6 miembros aromático o no aromático; cada R3 sea independiente de H, alquilo C1-3, haloalquilo C1-3 o fenilo; y Rf sea H, alquilo C1-3 o fenilo; y f) el compuesto de la fórmula (1) no sea 6-amino- 5-nitro-2-fenil-4-pirimidinmalonato de dietilo.
ARP040104675 2003-12-19 2004-12-15 Pirimidinas herbicidas. mezclas que las contienen. AR046790A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53130003P 2003-12-19 2003-12-19
US59839704P 2004-08-03 2004-08-03

Publications (1)

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AR046790A1 true AR046790A1 (es) 2005-12-21

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ARP040104675 AR046790A1 (es) 2003-12-19 2004-12-15 Pirimidinas herbicidas. mezclas que las contienen.

Country Status (24)

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US (3) US7863220B2 (es)
EP (1) EP1694651B1 (es)
JP (1) JP4991311B2 (es)
KR (1) KR101180557B1 (es)
CN (1) CN102675218B (es)
AR (1) AR046790A1 (es)
AT (1) ATE529412T1 (es)
AU (1) AU2004309325B2 (es)
BR (1) BRPI0417279B8 (es)
CA (1) CA2548058C (es)
EC (1) ECSP066645A (es)
EG (1) EG24843A (es)
ES (1) ES2375479T3 (es)
GE (1) GEP20125626B (es)
IL (1) IL175866A (es)
MA (1) MA28274A1 (es)
MX (1) MXPA06007033A (es)
MY (1) MY148489A (es)
NZ (1) NZ547251A (es)
PE (1) PE20050747A1 (es)
PL (1) PL1694651T3 (es)
TW (1) TWI355894B (es)
UY (1) UY28678A1 (es)
WO (1) WO2005063721A1 (es)

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