AR042254A1 - Derivados de sulfonilaminopirazol pesticidas - Google Patents

Derivados de sulfonilaminopirazol pesticidas

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Publication number
AR042254A1
AR042254A1 ARP030104420A ARP030104420A AR042254A1 AR 042254 A1 AR042254 A1 AR 042254A1 AR P030104420 A ARP030104420 A AR P030104420A AR P030104420 A ARP030104420 A AR P030104420A AR 042254 A1 AR042254 A1 AR 042254A1
Authority
AR
Argentina
Prior art keywords
alkyl
group
halo
halogen
substituted
Prior art date
Application number
ARP030104420A
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English (en)
Original Assignee
Bayer Cropscience Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Cropscience Sa filed Critical Bayer Cropscience Sa
Publication of AR042254A1 publication Critical patent/AR042254A1/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Veterinary Medicine (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Derivados sulfonilaminopirazol 5-sustituidos, procesos para su preparación, composiciones de dichos compuestos y su uso para el control de plagas tales como artrópodos (insectos y arácnidos) y helmintos (nematodos). Reivindicación 1: Un compuesto de fórmula (1) en donde R1 es alquilo (C1-6), haloalquilo (C1-6), -CN, -C(S)NH2, o halógeno; W es N, -C-CH3 o -C-halógeno; R2 es H, -CH3 o halógeno; R3 es halo, alquilo (C1-6), haloalquilo (C1-6), haloalcoxi (C1-6), S(O)p-haloalquilo(C1-6) o SF5; R4 es H, alquenilo (C2-6), haloalquenilo (C2-6), alquinilo (C2-6), haloalquinilo (C2-6), cicloalquilo (C3-7), -CO2-alquilo (C1-6), -CO2-cicloalquilo (C3-7), -CO2-alquilo (C1-4)-cicloalquilo (C3-7), -CO2-alquenilo (C3-6), -CO2-alquinilo (C3-6), -CO2-(CH2)qR7, -CONR8R9, -CO2-(CH2)qR10, -(CH2)qR7, -(CH2)qR10, -COR9, -COCH2NR8R9, -CO-(CH2)qR7 o -CO-(CH2)qR10; o alquilo (C1-6) no sustituido o sustituido con uno o más radicales seleccionados entre el grupo que consiste en halógeno, alcoxi (C1-6), haloalcoxi (C1-6), cicloalquilo (C3-7), -S(O)pR11, -CO2-alquilo(C1-6), -O(C=O)-alquilo (C1-6), NR8R9, CONR8R9, -SO2NR8R9, -OH, -CN, -NO2, -OR7, -OR10, NR8COR12 y NR8SO2R11; R5 es cicloalquilo (C3-7), alquenilo (C2-6), haloalquenilo (C2-6), R13, R10, R17 o -CH=CH-R15, o es alquilo (C1-15) no sustituido o sustituido con uno o más radicales seleccionados entre el grupo que consiste en halógeno, alcoxi (C1-6), haloalcoxi (C1-6), alqueniloxi (C3-6), haloalqueniloxi (C3-6), alquiniloxi (C3-6), haloalquiniloxi (C3-6), cicloalquilo (C3-7), -S(O)pR7, -S(O)pR10, -S(O)pR11, -CN, -NO2, -OH, -COR8, NR8COR12, NR8SO2R11, -CONR8R9, NR8R9, -OR7, -OR10, R13, R10 y -CO2R8, o un grupo metileno en el alquilo (C1-6) no sustituido o sustituido es reemplazado por un grupo seleccionado entre -CO, -O-, -S(O)p-, -NR8-, -COO-, -OCO-, -CONR8-, -NR8CO-, -C(=NOR8)-, -C(=N-NR8R9)- y -C(=NR8)-, siempre que el grupo reemplazante no esté directamente ligado al grupo SO2 en fórmula (1); R6 y R11 son, cada uno en forma independiente, alquilo (C1-6), haloalquilo (C1-6), alquenilo (C2-6), haloalquenilo (C2-6), alquinilo (C2-6), haloalquinilo (C2-6) o cicloalquilo (C3-7); R7 es fenilo no sustituido o sustituido con uno o más radicales seleccionados entre el grupo que consiste en halógeno, alquilo (C1-6), haloalquilo (C1-6), alcoxi (C1-6), haloalcoxi (C1-6), -CN, -NO2, -S(O)pR11 y NR9R12; R8 es H, alquilo (C1-6), haloalquilo (C1-6), cicloalquilo (C3-7), alquilo(C1-4)-cicloalquilo-(C3-7), -(CH2)qR7 o -(CH2)qR10; R9 y R12 son, cada uno en forma independiente, H, alquilo (C1-6), haloalquilo (C1-6), cicloalquilo (C3-7) o alquilo (C1-4)-cicloalquilo(C3-7); o R8 y R9 junto con el átomo de N adjunto forman un anillo saturado de cinco o seis miembros que en forma opcional contiene un heteroátomo adicional en el anillo, seleccionado entre O, S y N; el anillo está no sustituido o sustituido con uno o más radicales seleccionados entre el grupo que consiste en halógeno, alquilo (C1-6) y haloalquilo (C1-6); R10 y R20 son, cada uno en forma independiente, heterociclilo no sustituido o sustituido con uno o más radicales seleccionados entre el grupo que consiste en halógeno, alquilo (C1-4), haloalquilo (C1-4), alcoxi (C1-4), S(O)pR14, -OH, -OR7 y oxo; R13 es arilo no sustituido o sustituido con uno o más radicales seleccionados entre el grupo que consiste en halógeno, alquilo (C1-6), haloalquilo (C1-6), alcoxi (C1-6), haloalcoxi (C1-6), -CN, -NO2, -S(O)pR11, -SF5, NR8R9, -COR11, -COR7, -CONR8R9, -SO2NR8R9, -OH, -OR7, R15, R16, -OR16, -SO3H, alquilidenimino (C1-6), -CH=NOR14, -S(O)pR18, -CO2R19 y R20; R14 es alquilo (C1-6) o haloalquilo (C1-6); R15 es fenilo o naftilo, ambos no sustituidos o sustituidos con uno o más radicales seleccionados entre el grupo que consiste en halógeno, alquilo (C1-6), haloalquilo (C1-6) y alcoxi (C1-6); R16 es un radical heteroaromático seleccionado entre el grupo que consiste en piridilo, pirimidinilo, piridazinilo, pirazinilo, triazinilo, tienilo, tiazolilo, tiadiazolilo, oxazolilo, isoxazolilo, furilo, pirrolilo, pirazolilo, imidazolilo y triazolilo, en donde dichos grupos están no sustituidos o sustituidos con uno o más radicales seleccionados entre el grupo que consiste en halógeno, alquilo (C1-6),haloalquilo (C1-6) y alcoxi (C1-6); R17 es un radical heteroaromático seleccionado entre el grupo que consiste en piridilo, pirimidinilo, piridazinilo, pirazinilo, triazinilo, tienilo, tiazolilo, tiadiazolilo, oxazolilo, isoxazolilo, furilo, pirrolilo, pirazolilo, imidazolilo y triazolilo, en donde dichos grupos están no sustituidos o sustituidos con uno o más radicales seleccionados entre el grupo que consiste en halógeno, alquilo (C1-6), haloalquilo (C1-6) y alcoxi (C1-6); y en donde dicho radical heteroaromático está sustituido con R15, R16 u -OR16; R18 es fenilo no sustituido o sustituido con uno o más radicales seleccionados entre el grupo que consiste en halógeno, alquilo (C1-6), haloalquilo (C1-6) y alcoxi (C1-6); R19 es alquilo (C1-6), haloalquilo (C1-6), R18 o alquilo (C1-6)-alcoxi (C1-3); n, p y q son, cada uno en forma independiente, cero, uno o dos; y cada heterociclilo en los radicales antes mencionados es independientemente un radical heterocíclico que tiene 3 a 6 átomos de anillo, y 1, 2, o 3 heteroátomos en el anillo seleccionado entre el grupo que consiste en N, O y S; o una sal de dicho compuesto, aceptable para uso pesticida.
ARP030104420A 2002-12-03 2003-12-01 Derivados de sulfonilaminopirazol pesticidas AR042254A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP02027034 2002-12-03

Publications (1)

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AR042254A1 true AR042254A1 (es) 2005-06-15

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ID=32405690

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Country Status (18)

Country Link
US (1) US7504362B2 (es)
EP (1) EP1569910B1 (es)
JP (1) JP4839462B2 (es)
KR (1) KR101033717B1 (es)
CN (1) CN1720233A (es)
AR (1) AR042254A1 (es)
AT (1) ATE501123T1 (es)
AU (1) AU2003296246B2 (es)
BR (2) BR0317000A (es)
CA (1) CA2508474C (es)
CO (1) CO5690507A2 (es)
DE (1) DE60336338D1 (es)
EA (1) EA009293B1 (es)
ES (1) ES2358899T3 (es)
MX (1) MXPA05005898A (es)
NZ (1) NZ540461A (es)
WO (1) WO2004049797A2 (es)
ZA (1) ZA200503742B (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7872038B2 (en) 2004-03-15 2011-01-18 Merial Limited 1-phenyl and 1-pyridylpyrazole derivatives and their use as pesticides
AU2005223483B2 (en) 2004-03-18 2009-04-23 Zoetis Llc N-(1-arylpyrazol-4l)sulfonamides and their use as parasiticides
MX2007000167A (es) * 2004-06-26 2007-10-10 Bayer Cropscience Sa Derivados de n-fenilpirazol como pesticidas.
US9919979B2 (en) * 2005-01-21 2018-03-20 Bayer Cropscience Lp Fertilizer-compatible composition
WO2016094307A1 (en) 2014-12-08 2016-06-16 The Research Foundation For The State University Of New York Anti-fungals targeting the synthesis of fungal shingolipids
EP3638649A4 (en) 2017-06-16 2021-03-17 The Research Foundation for The State University of New York FUNGUSKID AGENTS AGAINST THE SYNTHESIS OF FUNGAL SHINGOLIPIDS
CN107629005A (zh) * 2017-08-22 2018-01-26 王泊理 多取代苯基吡唑衍生物及其制备方法和用途
CN109705101B (zh) * 2018-12-29 2020-09-15 中南民族大学 一种吡唑***磺酰胺类化合物及其溶剂热合成方法与应用

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US4631211A (en) * 1985-03-25 1986-12-23 Scripps Clinic & Research Foundation Means for sequential solid phase organic synthesis and methods using the same
DE3602728A1 (de) * 1985-05-17 1986-11-20 Bayer Ag, 51373 Leverkusen Schaedlingsbekaempfungsmittel auf basis von pyrazolderivaten
GB8531485D0 (en) * 1985-12-20 1986-02-05 May & Baker Ltd Compositions of matter
GB8713768D0 (en) 1987-06-12 1987-07-15 May & Baker Ltd Compositions of matter
US5232940A (en) 1985-12-20 1993-08-03 Hatton Leslie R Derivatives of N-phenylpyrazoles
GB9120641D0 (en) 1991-09-27 1991-11-06 Ici Plc Heterocyclic compounds
GB9306184D0 (en) 1993-03-25 1993-05-19 Zeneca Ltd Heteroaromatic compounds
DE4343832A1 (de) 1993-12-22 1995-06-29 Bayer Ag Substituierte 1-Arylpyrazole
DE19511269A1 (de) * 1994-03-30 1995-10-05 Ciba Geigy Ag Pyrazole
DE4414333A1 (de) 1994-04-25 1995-10-26 Bayer Ag Substituierte Pyridylpyrazole
JP3476997B2 (ja) * 1995-12-18 2003-12-10 新日本製鐵株式会社 樹脂クロメート処理金属板
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GB9625045D0 (en) 1996-11-30 1997-01-22 Pfizer Ltd Parasiticidal compounds
DE19650197A1 (de) 1996-12-04 1998-06-10 Bayer Ag 3-Thiocarbamoylpyrazol-Derivate
AR021608A1 (es) 1998-12-11 2002-07-31 Merial Ltd Represion de artropodos en animales

Also Published As

Publication number Publication date
BR0310113B1 (pt) 2013-10-29
WO2004049797A2 (en) 2004-06-17
NZ540461A (en) 2008-03-28
CA2508474A1 (en) 2004-06-17
EP1569910B1 (en) 2011-03-09
US7504362B2 (en) 2009-03-17
KR101033717B1 (ko) 2011-05-09
ES2358899T3 (es) 2011-05-16
CA2508474C (en) 2011-04-26
KR20050085284A (ko) 2005-08-29
MXPA05005898A (es) 2005-08-29
DE60336338D1 (de) 2011-04-21
US20060247242A1 (en) 2006-11-02
ATE501123T1 (de) 2011-03-15
WO2004049797A3 (en) 2004-09-02
EA009293B1 (ru) 2007-12-28
EP1569910A2 (en) 2005-09-07
CN1720233A (zh) 2006-01-11
AU2003296246A1 (en) 2004-06-23
AU2003296246B2 (en) 2009-06-04
CO5690507A2 (es) 2006-10-31
BR0317000A (pt) 2005-10-25
JP4839462B2 (ja) 2011-12-21
JP2006509003A (ja) 2006-03-16
ZA200503742B (en) 2008-01-30
EA200500932A1 (ru) 2006-10-27

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