AR017441A1 - Metodo de polimerizacion por adicion, iniciada por radicales libres, de monomeros etilenicamente insaturados - Google Patents
Metodo de polimerizacion por adicion, iniciada por radicales libres, de monomeros etilenicamente insaturadosInfo
- Publication number
- AR017441A1 AR017441A1 ARP980106574A ARP980106574A AR017441A1 AR 017441 A1 AR017441 A1 AR 017441A1 AR P980106574 A ARP980106574 A AR P980106574A AR P980106574 A ARP980106574 A AR P980106574A AR 017441 A1 AR017441 A1 AR 017441A1
- Authority
- AR
- Argentina
- Prior art keywords
- initiated
- free radicals
- unsaturated monomers
- polymerization method
- addition polymerization
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/911—Emulsifying agents
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Paints Or Removers (AREA)
- Paper (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Se describe la polimerizacion por adicion, iniciada por radicales libres, de monomeros etilénicamente insaturados, en particular acrílicos, en donde lafase dispersa se estabiliza mediante un surfactante que incluye al menos un compuesto surfactantea nionico de la formula: R1-(OA)n-X en donde: R1 es un grupohidrocarbilo C16 a C22 que incluye al menos dos enlaces dobles; OA es un grupo oxialquileno; n de 2 a 60; y X incluye al menos un átomo de H ácido y enparticular es un grupo éster fosfato,o u na sal del mismo. El uso de los surfactantes de formula (I) permite realizar una emulsificacion eficaz y por tanto unapolimerizacion a temperaturas por encima de aquellas a las cuales resultan eficaces los surfactantes insaturados no ionicos.Los pro ductos de látex poliméricosobtenidos proporcionan películas poliméricas que exhiben buenas propiedades de resistencia al agua.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9726890.8A GB9726890D0 (en) | 1997-12-20 | 1997-12-20 | Polymerisation method |
Publications (1)
Publication Number | Publication Date |
---|---|
AR017441A1 true AR017441A1 (es) | 2001-09-05 |
Family
ID=10823917
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP980106574A AR017441A1 (es) | 1997-12-20 | 1998-12-21 | Metodo de polimerizacion por adicion, iniciada por radicales libres, de monomeros etilenicamente insaturados |
Country Status (24)
Country | Link |
---|---|
US (2) | US6878763B2 (es) |
EP (1) | EP1042370B1 (es) |
JP (1) | JP4271849B2 (es) |
KR (1) | KR100512224B1 (es) |
CN (3) | CN1667002A (es) |
AR (1) | AR017441A1 (es) |
AT (1) | ATE386058T1 (es) |
AU (1) | AU1769499A (es) |
BR (1) | BR9813734A (es) |
CA (1) | CA2313102C (es) |
CO (1) | CO5050311A1 (es) |
DE (1) | DE69839129T2 (es) |
DK (1) | DK1042370T3 (es) |
ES (1) | ES2299222T3 (es) |
GB (1) | GB9726890D0 (es) |
HK (1) | HK1045848A1 (es) |
HU (1) | HUP0100291A3 (es) |
MX (1) | MXPA00006031A (es) |
MY (1) | MY148147A (es) |
NO (1) | NO20003168L (es) |
NZ (1) | NZ504985A (es) |
PL (1) | PL194315B1 (es) |
TW (1) | TW400336B (es) |
WO (1) | WO1999032522A1 (es) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0101771D0 (en) * | 2001-01-24 | 2001-03-07 | Ici Plc | Anionic surfactants |
US20070219294A1 (en) * | 2004-03-08 | 2007-09-20 | Kaneka Corporation | Method for manufacturing coagulated particles from latex prepared by emulsion polymerization |
US20060199877A1 (en) * | 2005-03-01 | 2006-09-07 | Sivapackia Ganapathiappan | Shear stable latex particles |
US7468412B2 (en) * | 2005-10-05 | 2008-12-23 | Geo Specialty Chemicals, Inc. | Method and composition for the suppression of bloom in peroxide crosslinked polymeric articles |
US8252425B2 (en) * | 2007-12-12 | 2012-08-28 | Ashland Licensing And Intellectual Property Llc | Acrylic emulsion pressure sensitive adhesive composition |
GB2462105A (en) | 2008-07-24 | 2010-01-27 | Nuplex Resins Bv | Thixotropic aqueous coating composition |
CN102268115B (zh) * | 2010-06-02 | 2015-04-22 | 武汉强力荷新材料有限公司 | 免加热法生产聚合物乳液 |
KR101698054B1 (ko) | 2014-12-30 | 2017-01-19 | 한국기술교육대학교 산학협력단 | 반응성 라텍스 입자를 포함하는 고분자 필름 |
ES2964746T3 (es) * | 2015-12-30 | 2024-04-09 | Celgene Corp | Métodos de producción de linfocitos T y linfocitos T producidos mediante el mismo |
WO2018027907A1 (en) * | 2016-08-12 | 2018-02-15 | Dow Global Technologies Llc | Surfactant composition |
CN112410063B (zh) * | 2019-08-22 | 2022-05-24 | 中国石油化工股份有限公司 | 一种原油破乳剂及其制备方法和应用 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2606178A (en) * | 1949-06-18 | 1952-08-05 | Monsanto Chemicals | Alkali sulfate salts of ethylene oxide condensation products as emulsifies for styrene polymerization |
BE630043A (es) * | 1962-08-28 | |||
CA1157598A (en) * | 1979-10-03 | 1983-11-22 | Paritosh M. Chakrabarti | Polyethyleneoxy sulfonate surfactants |
US4283321A (en) * | 1979-10-03 | 1981-08-11 | Gaf Corporation | Alkyl aryl ethyleneoxy sulfonate surfactants for vinyl acetate polymerization |
JP3592408B2 (ja) * | 1995-07-25 | 2004-11-24 | 旭電化工業株式会社 | 界面活性剤、乳化重合用乳化剤、懸濁重合用分散剤及び樹脂改質剤 |
AUPO846297A0 (en) | 1997-08-08 | 1997-09-04 | Ici Australia Operations Proprietary Limited | Anionic alkoxylate surfactant |
-
1997
- 1997-12-20 GB GBGB9726890.8A patent/GB9726890D0/en not_active Ceased
-
1998
- 1998-12-18 EP EP98962559A patent/EP1042370B1/en not_active Expired - Lifetime
- 1998-12-18 PL PL98341282A patent/PL194315B1/pl not_active IP Right Cessation
- 1998-12-18 AU AU17694/99A patent/AU1769499A/en not_active Abandoned
- 1998-12-18 HU HU0100291A patent/HUP0100291A3/hu unknown
- 1998-12-18 CN CNA2005100651840A patent/CN1667002A/zh active Pending
- 1998-12-18 CO CO98075437A patent/CO5050311A1/es unknown
- 1998-12-18 AT AT98962559T patent/ATE386058T1/de not_active IP Right Cessation
- 1998-12-18 NZ NZ504985A patent/NZ504985A/xx not_active IP Right Cessation
- 1998-12-18 DK DK98962559T patent/DK1042370T3/da active
- 1998-12-18 KR KR10-2000-7006776A patent/KR100512224B1/ko not_active IP Right Cessation
- 1998-12-18 ES ES98962559T patent/ES2299222T3/es not_active Expired - Lifetime
- 1998-12-18 CN CN98813040A patent/CN1285849A/zh active Pending
- 1998-12-18 MX MXPA00006031A patent/MXPA00006031A/es not_active IP Right Cessation
- 1998-12-18 BR BR9813734-4A patent/BR9813734A/pt not_active IP Right Cessation
- 1998-12-18 CA CA002313102A patent/CA2313102C/en not_active Expired - Fee Related
- 1998-12-18 JP JP2000525457A patent/JP4271849B2/ja not_active Expired - Lifetime
- 1998-12-18 MY MYPI98005729A patent/MY148147A/en unknown
- 1998-12-18 WO PCT/GB1998/003829 patent/WO1999032522A1/en active IP Right Grant
- 1998-12-18 DE DE69839129T patent/DE69839129T2/de not_active Expired - Lifetime
- 1998-12-21 AR ARP980106574A patent/AR017441A1/es active IP Right Grant
-
1999
- 1999-01-06 TW TW088100132A patent/TW400336B/zh not_active IP Right Cessation
-
2000
- 2000-06-19 NO NO20003168A patent/NO20003168L/no not_active Application Discontinuation
-
2001
- 2001-09-10 CN CN01132937A patent/CN1346834A/zh active Pending
-
2002
- 2002-04-17 US US10/123,527 patent/US6878763B2/en not_active Expired - Lifetime
- 2002-09-26 HK HK02107073.3A patent/HK1045848A1/zh unknown
-
2004
- 2004-04-15 US US10/824,644 patent/US20040225042A1/en not_active Abandoned
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Legal Events
Date | Code | Title | Description |
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FG | Grant, registration |