AR013188A1 - Compuestos que tienen un elemento del grupo 11, 12 o 14 y un ligante bis(amido)amina, un procedimiento para su preparacion y su utilizacion enparticular como catalizadores de polimerizacion - Google Patents
Compuestos que tienen un elemento del grupo 11, 12 o 14 y un ligante bis(amido)amina, un procedimiento para su preparacion y su utilizacion enparticular como catalizadores de polimerizacionInfo
- Publication number
- AR013188A1 AR013188A1 ARP980103294A ARP980103294A AR013188A1 AR 013188 A1 AR013188 A1 AR 013188A1 AR P980103294 A ARP980103294 A AR P980103294A AR P980103294 A ARP980103294 A AR P980103294A AR 013188 A1 AR013188 A1 AR 013188A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- group
- compounds
- radical
- aryl
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 239000002685 polymerization catalyst Substances 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 7
- 150000003254 radicals Chemical class 0.000 abstract 5
- 125000005843 halogen group Chemical group 0.000 abstract 4
- 125000003118 aryl group Chemical group 0.000 abstract 3
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 3
- 125000001424 substituent group Chemical group 0.000 abstract 3
- JEVCWSUVFOYBFI-UHFFFAOYSA-N cyanyl Chemical compound N#[C] JEVCWSUVFOYBFI-UHFFFAOYSA-N 0.000 abstract 2
- 125000001188 haloalkyl group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 125000003368 amide group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000005840 aryl radicals Chemical class 0.000 abstract 1
- 125000005110 aryl thio group Chemical group 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 229920001400 block copolymer Polymers 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 125000000000 cycloalkoxy group Chemical group 0.000 abstract 1
- 125000005366 cycloalkylthio group Chemical group 0.000 abstract 1
- -1 halogen radicals Chemical class 0.000 abstract 1
- 150000002431 hydrogen Chemical group 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229920005604 random copolymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2284—Compounds with one or more Sn-N linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyethers (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Se refiere a nuevos compuestos que tienen un elemento del grupo 11, 12 o 14 y que tienen un ligante bis (amido)amina. Dichos compuestos tienen laformula general (1): en la cual M representa un elemento de los grupos 11, 12 o 14; A y Brepresentan, independientemente, una cadena carbonada C2-4,opcionalmente substituída por uno de los siguientes radicales substituidos o no substituidos; alquilo, cicloalquilo o arilo, en los cuales dichotsubstituyente es un átomo de halogeno, unradical alquilo , nitro, o ciano, L1, L2 y L3 representan, independientemente, un grupo de formula -E15(R15)- en lacual E15 es un elemento del grupo 15 y R15 representa hidrogeno, uno de los siguientes radicales substituidos; cicloalquilo oarilo, en los cuales dichosubstituyente es un átomo de halogeno, el radical alquilo, nitro o ciano, un radical de formula RR R E14-, en donde E14 es un elemento del grupo 14 y R,R y Rrepresentan, independientemente, hidrogeno o uno de lossiguientes radicales su bstituidos o no substituídos; alquilo, cicloalquilo, arilo, alcoxi,cicloalcoxi, ariloxi, alquiltio, cicloalquiltio o ariltio, en los cuales dicho substituyente es un átomo de halogeno, el radical alquilo, nitro o ciano;o unradical de formula SO2R1 5, en el cual R15 representa halogeno, un radical alquilo, haloalquilo o arilo substituído optativamente por uno o mássubstituyentes elegidos de los radicales alquilo, haloalquilo, y halogeno. La invenciontambién se refiere a un procedimiento para preparar dichos compuestos, utilizacion como catalizador de polimerizacion o copolimerizacion, un procedimiento para preparar copolímeros o polímeros en bloque o aleatorios ypolímeros o copolímerosobtenidos con dicho procedimiento.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97401621A EP0890575A1 (fr) | 1997-07-08 | 1997-07-08 | Nouveaux composés possédant un élément du groupe 11,12 ou 14 et un ligand tridentate, leur procédé de préparation et leur application notamment comme catalyseurs de polymérisation |
Publications (1)
Publication Number | Publication Date |
---|---|
AR013188A1 true AR013188A1 (es) | 2000-12-13 |
Family
ID=8229802
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP980103294A AR013188A1 (es) | 1997-07-08 | 1998-07-07 | Compuestos que tienen un elemento del grupo 11, 12 o 14 y un ligante bis(amido)amina, un procedimiento para su preparacion y su utilizacion enparticular como catalizadores de polimerizacion |
Country Status (14)
Country | Link |
---|---|
US (1) | US6303807B1 (es) |
EP (2) | EP0890575A1 (es) |
AR (1) | AR013188A1 (es) |
AT (1) | ATE225795T1 (es) |
AU (1) | AU8544298A (es) |
CA (1) | CA2295874C (es) |
DE (1) | DE69808634T2 (es) |
DK (1) | DK0998478T3 (es) |
ES (1) | ES2185193T3 (es) |
NO (1) | NO20000049L (es) |
RU (1) | RU2197494C2 (es) |
TW (1) | TW505667B (es) |
WO (1) | WO1999002536A1 (es) |
ZA (1) | ZA985932B (es) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6271325B1 (en) | 1999-05-17 | 2001-08-07 | Univation Technologies, Llc | Method of polymerization |
EP1063239A1 (fr) * | 1999-06-25 | 2000-12-27 | Societe De Conseils De Recherches Et D'applications Scientifiques (S.C.R.A.S.) | Nouveaux composés possédant un lanthanide et un ligand tridentate, leur procédé de préparation et leur application notamment comme catalyseurs de polymérisation |
US6380328B1 (en) | 1999-12-10 | 2002-04-30 | Univation Technologies, Llc | Catalyst systems and their use in a polymerization process |
US6274684B1 (en) | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
US6265505B1 (en) | 1999-11-18 | 2001-07-24 | Univation Technologies, Llc | Catalyst system and its use in a polymerization process |
US6624107B2 (en) | 1999-10-22 | 2003-09-23 | Univation Technologies, Llc | Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof |
US6417304B1 (en) | 1999-11-18 | 2002-07-09 | Univation Technologies, Llc | Method of polymerization and polymer produced therefrom |
US6271323B1 (en) | 1999-10-28 | 2001-08-07 | Univation Technologies, Llc | Mixed catalyst compounds, catalyst systems and their use in a polymerization process |
US6300438B1 (en) | 1999-10-22 | 2001-10-09 | Univation Technolgies, Llc | Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process |
US6300439B1 (en) | 1999-11-08 | 2001-10-09 | Univation Technologies, Llc | Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process |
US6281306B1 (en) * | 1999-12-16 | 2001-08-28 | Univation Technologies, Llc | Method of polymerization |
HU229198B1 (hu) * | 2000-05-15 | 2013-09-30 | Centre Nat Rech Scient | Sztannilén és germilén vegyületek alkalmazása polimerizációs katalizátorként heterociklusos vegyületek polimerizálásánál |
AU2002307982B8 (en) * | 2001-04-10 | 2007-03-29 | Centre National De La Recherche Scientifique (C.N.R.S.) | Use of zinc derivatives as cyclic ester polymerisation catalysts |
US20050009687A1 (en) * | 2003-05-02 | 2005-01-13 | Verkade John G. | Titanium alkoxide catalysts for polymerization of cyclic esters and methods of polymerization |
EP2196486A1 (en) * | 2008-12-12 | 2010-06-16 | Total Petrochemicals Research Feluy | Process to prepare di- and multiblock copolymers |
RU2525235C1 (ru) * | 2013-05-20 | 2014-08-10 | Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" | Способ получения катализатора полимеризации лактонов или поликонденсации альфа-оксикислот |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5344948A (en) * | 1992-02-25 | 1994-09-06 | Iowa State University Research Foundation, Inc. | Single-source molecular organic chemical vapor deposition agents and use |
-
1997
- 1997-07-08 EP EP97401621A patent/EP0890575A1/fr not_active Withdrawn
-
1998
- 1998-07-06 EP EP98936450A patent/EP0998478B1/fr not_active Expired - Lifetime
- 1998-07-06 ES ES98936450T patent/ES2185193T3/es not_active Expired - Lifetime
- 1998-07-06 DK DK98936450T patent/DK0998478T3/da active
- 1998-07-06 ZA ZA9805932A patent/ZA985932B/xx unknown
- 1998-07-06 AT AT98936450T patent/ATE225795T1/de active
- 1998-07-06 WO PCT/FR1998/001433 patent/WO1999002536A1/fr active IP Right Grant
- 1998-07-06 RU RU2000102898/04A patent/RU2197494C2/ru not_active IP Right Cessation
- 1998-07-06 DE DE69808634T patent/DE69808634T2/de not_active Expired - Lifetime
- 1998-07-06 CA CA002295874A patent/CA2295874C/fr not_active Expired - Fee Related
- 1998-07-06 AU AU85442/98A patent/AU8544298A/en not_active Abandoned
- 1998-07-06 US US09/446,793 patent/US6303807B1/en not_active Expired - Lifetime
- 1998-07-07 AR ARP980103294A patent/AR013188A1/es active IP Right Grant
- 1998-09-02 TW TW087114536A patent/TW505667B/zh not_active IP Right Cessation
-
2000
- 2000-01-06 NO NO20000049A patent/NO20000049L/no unknown
Also Published As
Publication number | Publication date |
---|---|
DK0998478T3 (da) | 2003-02-10 |
CA2295874C (fr) | 2009-01-20 |
EP0890575A1 (fr) | 1999-01-13 |
ATE225795T1 (de) | 2002-10-15 |
EP0998478A1 (fr) | 2000-05-10 |
TW505667B (en) | 2002-10-11 |
NO20000049D0 (no) | 2000-01-06 |
ZA985932B (en) | 1999-12-06 |
ES2185193T3 (es) | 2003-04-16 |
NO20000049L (no) | 2000-01-06 |
DE69808634T2 (de) | 2003-08-07 |
WO1999002536A1 (fr) | 1999-01-21 |
EP0998478B1 (fr) | 2002-10-09 |
DE69808634D1 (de) | 2002-11-14 |
CA2295874A1 (fr) | 1999-01-21 |
RU2197494C2 (ru) | 2003-01-27 |
AU8544298A (en) | 1999-02-08 |
US6303807B1 (en) | 2001-10-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant, registration |