AR029773A1 - Un metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y una composicion de un monomero etilenicamente insaturado preparada con el mismo - Google Patents
Un metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y una composicion de un monomero etilenicamente insaturado preparada con el mismoInfo
- Publication number
- AR029773A1 AR029773A1 ARP000106235A ARP000106235A AR029773A1 AR 029773 A1 AR029773 A1 AR 029773A1 AR P000106235 A ARP000106235 A AR P000106235A AR P000106235 A ARP000106235 A AR P000106235A AR 029773 A1 AR029773 A1 AR 029773A1
- Authority
- AR
- Argentina
- Prior art keywords
- insatured
- ethenically
- alkyl
- monomers
- group
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B63/00—Purification; Separation; Stabilisation; Use of additives
- C07B63/04—Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
- C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
- C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
- C07C15/46—Styrene; Ring-alkylated styrenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Materials Engineering (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogenated Pyridines (AREA)
Abstract
Un método para inhibir la polimerizacion prematura de monomeros etilénicamente insaturados, que comprende agregar a dichos monomeros una cantidad efectiva de una mezcla que comprende: A) por lo menos un compuesto de nitroxilo impedido estable que tiene la formula estructural (1), en la cual R1 y R2 son independientemente seleccionados entre el grupo que consiste en hidrogeno, alquilo y alquilo heteroátomo-sustituido y R2 y R3 son independientemente seleccionados entre el grupo que consiste en alquilo y alquilo sustituido en heteroátomo; y X1 y X2 (I) se seleccionan independientemente entre el grupo que consiste en halogeno, ciano, COOR7, -S-COR7, -OCOR7, en donde R7 es alquilo o arilo, amido, -S-C6H5, carbonilo, alquenilo, o alquilo de 1a 15 átomos de carbono, o (II) tomados juntos, forman una estructura de anillo con el nitrogeno, y B) por lo menos un inhibidor seleccionado entre el grupo que consiste en orto-quinona, orto-hidroquinona, para-quinona, para-hidroquinona, y derivados de los que anteceden; y una composicion de un monomero etilénicamente insaturado que comprende una cantidad inhibitoria efectiva, para evitar la polimerizacion prematura del monomero etilénicamente insaturado, de la mezcla del método.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US45297299A | 1999-12-02 | 1999-12-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR029773A1 true AR029773A1 (es) | 2003-07-16 |
Family
ID=23798714
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP000106235A AR029773A1 (es) | 1999-12-02 | 2000-11-27 | Un metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y una composicion de un monomero etilenicamente insaturado preparada con el mismo |
ARP100101858A AR076896A2 (es) | 1999-12-02 | 2010-05-28 | Un metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP100101858A AR076896A2 (es) | 1999-12-02 | 2010-05-28 | Un metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados |
Country Status (13)
Country | Link |
---|---|
US (1) | US6653414B2 (es) |
EP (1) | EP1233937B1 (es) |
JP (1) | JP3854149B2 (es) |
KR (1) | KR100715592B1 (es) |
CN (1) | CN1238312C (es) |
AR (2) | AR029773A1 (es) |
AT (1) | ATE307789T1 (es) |
BR (1) | BR0016112A (es) |
CA (1) | CA2392055C (es) |
DE (1) | DE60023542T2 (es) |
MX (1) | MXPA02005423A (es) |
TW (1) | TW593214B (es) |
WO (1) | WO2001040149A2 (es) |
Families Citing this family (34)
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CA2392526C (en) * | 1999-12-03 | 2010-07-27 | Uniroyal Chemical Company, Inc. | Composition and method for inhibiting polymerization and polymer growth |
US7696290B2 (en) * | 2004-12-03 | 2010-04-13 | Crompton Corporation | Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or C-nitrosanilines as polymerization inhibitors |
MX2007009236A (es) | 2005-02-04 | 2007-09-19 | Chemtura Corp | Medios para controlar la reaccion exotermica de monomeros estirenicos con acidos sulfonicos. |
US7731794B2 (en) | 2005-06-09 | 2010-06-08 | United States Gypsum Company | High starch light weight gypsum wallboard |
USRE44070E1 (en) | 2005-06-09 | 2013-03-12 | United States Gypsum Company | Composite light weight gypsum wallboard |
US7883639B2 (en) * | 2005-09-12 | 2011-02-08 | Fujifilm Electronic Materials, U.S.A., Inc. | Additives to prevent degradation of cyclic alkene derivatives |
JP2009507837A (ja) * | 2005-09-12 | 2009-02-26 | フジフィルム・エレクトロニック・マテリアルズ・ユーエスエイ・インコーポレイテッド | 環状アルケン誘導体の分解を防止する添加剤 |
US7985826B2 (en) | 2006-12-22 | 2011-07-26 | Reichhold, Inc. | Molding resins using renewable resource component |
CN101274875B (zh) * | 2007-03-30 | 2011-04-20 | 中国石油天然气股份有限公司 | 一种丁二烯提纯及精制过程中的复合型阻聚剂的应用 |
CA2707158A1 (en) * | 2007-11-28 | 2009-06-04 | Revision Therapeutics, Inc. | Modulators of ocular oxidative stress |
US8440099B2 (en) | 2007-12-19 | 2013-05-14 | Air Products And Chemicals, Inc. | Stabilizers for the stabilization of unsaturated hydrocarbon-based precursor |
EP2072485B1 (en) * | 2007-12-19 | 2012-06-20 | Air Products and Chemicals, Inc. | Stabilizers for the stabilization of unsaturated hydrocarbon-based precursor |
US7968001B2 (en) * | 2007-12-19 | 2011-06-28 | Air Products And Chemicals, Inc. | Stabilizers for the stabilization of unsaturated hydrocarbon-based precursor |
CN101240169B (zh) * | 2008-03-10 | 2011-12-21 | 上海华谊丙烯酸有限公司 | 一种酚焦油废渣的再利用方法 |
US8173213B2 (en) * | 2008-05-28 | 2012-05-08 | Air Products And Chemicals, Inc. | Process stability of NBDE using substituted phenol stabilizers |
EP2318477B1 (en) | 2008-07-08 | 2019-06-05 | FujiFilm Electronic Materials USA, Inc. | Additives to prevent degradation of cyclic alkene derivatives |
GB0903005D0 (en) | 2009-02-23 | 2009-04-08 | Nufarm Ltd | Composition for controlling polymerisation |
DE102009027115A1 (de) | 2009-06-23 | 2010-12-30 | Wacker Chemie Ag | Verfahren zur Herstellung von Vinylacetat |
EP2319821A1 (en) * | 2009-11-06 | 2011-05-11 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Stabilization of bicycloheptadiene |
US20110207950A1 (en) | 2010-02-24 | 2011-08-25 | Hildeberto Nava | Vinyl-containing compounds and processes for making the same |
GB201011594D0 (en) | 2010-07-09 | 2010-08-25 | Nufarm Uk Ltd | Retarder composition |
US8323785B2 (en) | 2011-02-25 | 2012-12-04 | United States Gypsum Company | Lightweight, reduced density fire rated gypsum panels |
US9611336B2 (en) * | 2012-10-25 | 2017-04-04 | Baker Hughes Incorporated | Quinone compounds for inhibiting monomer polymerization |
US10544299B2 (en) | 2012-12-18 | 2020-01-28 | Reichhold Llc 2 | Vinyl-containing compounds with high heat distortion |
US9068045B2 (en) | 2013-04-05 | 2015-06-30 | Reichhold, Inc. | Curing of liquid thermosetting resins |
DE102013225114A1 (de) | 2013-12-06 | 2015-06-11 | Wacker Chemie Ag | Verfahren zur Herstellung von Vinylacetat mit inhibierter Nebenproduktbildung |
US10000602B2 (en) | 2014-10-02 | 2018-06-19 | Reichhold Llc 2 | Curable compositions |
TWI624480B (zh) * | 2015-04-20 | 2018-05-21 | 藝康美國公司 | 供不飽和單體用作防污劑之受阻對苯二酚 |
CN112533902A (zh) | 2018-07-13 | 2021-03-19 | 埃科莱布美国股份有限公司 | 抑制单体聚合的包含氮氧化物抑制剂、醌甲基化物阻滞剂和胺稳定剂的组合物 |
EP3820836A1 (en) | 2018-07-13 | 2021-05-19 | Ecolab USA, Inc. | Compositions of oxygenated amines and quinone methides as antifoulants for vinylic monomers |
US11312793B2 (en) | 2018-09-28 | 2022-04-26 | Ecolab Usa Inc. | Amino-quinone antipolymerants and methods of using |
CN113166020A (zh) * | 2018-12-20 | 2021-07-23 | 埃科莱布美国股份有限公司 | 羟基化醌抗聚合剂及其使用方法 |
US11518834B2 (en) | 2019-01-02 | 2022-12-06 | Polynt Composites USA, Inc. | Radically polymerizable compositions |
WO2023143939A1 (de) | 2022-01-26 | 2023-08-03 | Basf Se | Lagerung und/oder transport ethylenisch ungesättigter verbindungen |
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-
2000
- 2000-11-06 CA CA2392055A patent/CA2392055C/en not_active Expired - Fee Related
- 2000-11-06 BR BR0016112-8A patent/BR0016112A/pt not_active Application Discontinuation
- 2000-11-06 DE DE60023542T patent/DE60023542T2/de not_active Expired - Lifetime
- 2000-11-06 JP JP2001541841A patent/JP3854149B2/ja not_active Expired - Fee Related
- 2000-11-06 CN CNB008165440A patent/CN1238312C/zh not_active Expired - Fee Related
- 2000-11-06 AT AT00976993T patent/ATE307789T1/de not_active IP Right Cessation
- 2000-11-06 WO PCT/US2000/030552 patent/WO2001040149A2/en active IP Right Grant
- 2000-11-06 KR KR1020027007006A patent/KR100715592B1/ko not_active IP Right Cessation
- 2000-11-06 MX MXPA02005423A patent/MXPA02005423A/es active IP Right Grant
- 2000-11-06 EP EP00976993A patent/EP1233937B1/en not_active Expired - Lifetime
- 2000-11-27 AR ARP000106235A patent/AR029773A1/es active IP Right Grant
- 2000-12-02 TW TW089125679A patent/TW593214B/zh not_active IP Right Cessation
-
2001
- 2001-07-30 US US09/916,580 patent/US6653414B2/en not_active Expired - Fee Related
-
2010
- 2010-05-28 AR ARP100101858A patent/AR076896A2/es unknown
Also Published As
Publication number | Publication date |
---|---|
DE60023542T2 (de) | 2006-07-20 |
DE60023542D1 (de) | 2005-12-01 |
EP1233937A2 (en) | 2002-08-28 |
CA2392055C (en) | 2010-06-22 |
WO2001040149A3 (en) | 2002-01-24 |
MXPA02005423A (es) | 2002-11-29 |
ATE307789T1 (de) | 2005-11-15 |
CN1402697A (zh) | 2003-03-12 |
KR20020070302A (ko) | 2002-09-05 |
JP3854149B2 (ja) | 2006-12-06 |
JP2003515575A (ja) | 2003-05-07 |
EP1233937B1 (en) | 2005-10-26 |
BR0016112A (pt) | 2002-11-26 |
TW593214B (en) | 2004-06-21 |
US6653414B2 (en) | 2003-11-25 |
CA2392055A1 (en) | 2001-06-07 |
WO2001040149A2 (en) | 2001-06-07 |
CN1238312C (zh) | 2006-01-25 |
US20020037958A1 (en) | 2002-03-28 |
AR076896A2 (es) | 2011-07-13 |
KR100715592B1 (ko) | 2007-05-10 |
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