AR012259A1 - Masas de moldeo termoplasticas, metodo de preparacion de las mismas, su uso y cuerpos de moldeo fabricados a partir de ellas. - Google Patents
Masas de moldeo termoplasticas, metodo de preparacion de las mismas, su uso y cuerpos de moldeo fabricados a partir de ellas.Info
- Publication number
- AR012259A1 AR012259A1 ARP980103236A ARP980103236A AR012259A1 AR 012259 A1 AR012259 A1 AR 012259A1 AR P980103236 A ARP980103236 A AR P980103236A AR P980103236 A ARP980103236 A AR P980103236A AR 012259 A1 AR012259 A1 AR 012259A1
- Authority
- AR
- Argentina
- Prior art keywords
- weight
- monomer
- grafted
- thermoplastic
- polymer
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/14—Copolymers of styrene with unsaturated esters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Masas de moldeo termoplásticas que contienen como componentes : A) a F): A) 5 a 80% en peso de un polímero injertado A) con una distribucion detamano de partículas bimodal, formado por, referido a A), a1) 40 a 90% en peso de una base injertada en forma de partículas elásticas de caucho a1),formada por, referido a a1); a11) 70 a 100% en peso por lo menos de un dieno conjugado; a12) 0 a 30% en peso por lo menos de otro monomeromonoetilénicamente insaturado, y a13) 0 a 10, preferentemente 0,01 a 5 y más preferentemente 0,02 a 2% en peso por lo menos de un monomero reticulantepolifuncional, a2) 10 a 60% en peso de una capa injertada a2) por, referido a a2); a21)65 a 95% en peso por lo menos de un monomero vinilaromático, a22) 5a 35% en peso de acrilonitrilo; a23) 0 a 30% en peso por lo menos de otro monomero monoetilénicamente insaturado; y a24) 0 a 10, preferentemente 0,01 ay más preferentemente 0,02 a 2% en peso por lo menos de un monomero reticulante polifuncional; B) 20 a 95% en peso de un polímero termoplástico B) con uníndice de viscosidad VZ de 50 a 120 ml/g, formado por referido a B), b1) 69 a 81% en peso de por lo menos de un monomero vinilaromático; b2) 19 a 31% enpeso de acrilonitrilo; b3) 0 a 30% en peso por lo menos de otro monomero monoetilénicamente insaturado; así como también, opcionalmente, otros polímerostermoplásticos C), D) y/o E) en base a por lo menos un monomero vinilaromático y opcionalmente sustancias auxiliares F). Dichas masas de moldeo termoplásticasse pueden obtener mediante el siguiente método 1) preparacion de los polímeros injertados A) segun el procedimiento de polimerizacion por emulsion; 2) mezcladel polímero injertado A) con el polímero B) y en tanto se encuentren presentes los otros componentes C), D), E) y/o F), en un dispositivo de mezcla formándose
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19728629A DE19728629A1 (de) | 1997-07-04 | 1997-07-04 | Thermoplastische Formmassen mit geringer Eigenfarbe |
Publications (1)
Publication Number | Publication Date |
---|---|
AR012259A1 true AR012259A1 (es) | 2000-09-27 |
Family
ID=7834666
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP980103236A AR012259A1 (es) | 1997-07-04 | 1998-07-03 | Masas de moldeo termoplasticas, metodo de preparacion de las mismas, su uso y cuerpos de moldeo fabricados a partir de ellas. |
Country Status (14)
Country | Link |
---|---|
US (1) | US6323279B1 (es) |
EP (1) | EP0993476B1 (es) |
JP (1) | JP2002510349A (es) |
KR (1) | KR100361001B1 (es) |
CN (1) | CN1140551C (es) |
AR (1) | AR012259A1 (es) |
AU (1) | AU8728598A (es) |
BR (1) | BR9810666A (es) |
CA (1) | CA2294918A1 (es) |
DE (2) | DE19728629A1 (es) |
ES (1) | ES2172908T3 (es) |
TW (1) | TW470755B (es) |
WO (1) | WO1999001489A1 (es) |
ZA (1) | ZA985868B (es) |
Families Citing this family (61)
Publication number | Priority date | Publication date | Assignee | Title |
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DE19860526A1 (de) | 1998-12-30 | 2000-07-06 | Basf Ag | Wärmeüberträger mit verringerter Neigung, Ablagerungen zu bilden und Verfahren zu deren Herstellung |
DE19960855A1 (de) * | 1999-12-16 | 2001-06-28 | Basf Ag | Verfahren zur Herstellung von thermoplastischen Formmassen |
DE10021565A1 (de) * | 2000-05-03 | 2001-11-22 | Basf Ag | Thermoplastische Formmassen mit verbesserter Schlagzähigkeit |
DE10060411A1 (de) * | 2000-12-05 | 2002-06-06 | Bayer Ag | Thermoplastische Formmassen |
US7017352B2 (en) * | 2001-01-19 | 2006-03-28 | Crane Plastics Company Llc | Cooling of extruded and compression molded materials |
US6637213B2 (en) * | 2001-01-19 | 2003-10-28 | Crane Plastics Company Llc | Cooling of extruded and compression molded materials |
US6578368B1 (en) * | 2001-01-19 | 2003-06-17 | Crane Plastics Company Llc | Cryogenic cooling of extruded and compression molded materials |
GB0206880D0 (en) | 2002-03-23 | 2002-05-01 | Rolls Royce Plc | A vane for a rotor arrangement for a gas turbine engine |
ATE341579T1 (de) * | 2002-06-21 | 2006-10-15 | Basf Ag | Verfahren zur herstellung einer wässrigen polymerdispersion |
CN1322054C (zh) * | 2002-11-21 | 2007-06-20 | 大科能树脂有限公司 | 车辆外装饰用成型品用热塑性树脂组合物及车辆外装饰用成型品及其制造方法 |
DE10349144A1 (de) * | 2003-10-17 | 2005-05-12 | Roehm Gmbh | Polymermischung für mattierte Spritzgußteile |
MX2007008855A (es) * | 2003-10-18 | 2008-03-13 | Roehm Gmbh | Masas de pieza moldeada de poli (met) acrilato resistentes a impactos con alta estabilidad termica. |
DE102005022635B4 (de) * | 2005-05-11 | 2018-05-30 | Ineos Styrolution Europe Gmbh | Thermoplastische Formmassen mit verbesserter Anfärbbarkeit |
EP1752478A1 (en) * | 2005-08-08 | 2007-02-14 | Basf Aktiengesellschaft | A process for the production of a graft copolymer having a bimodal particle distribution. |
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FR2895085B1 (fr) | 2005-12-21 | 2008-07-04 | Breuil Sa Engineering Const Et | Dispositf de mirage d'oeufs. |
WO2008020012A2 (de) * | 2006-08-18 | 2008-02-21 | Basf Se | Thermoplastische formmassen auf basis von acrylnitril, styrol und butadien |
DE102006062269A1 (de) | 2006-12-22 | 2008-06-26 | Eckart Gmbh & Co. Kg | Verwendung von sphärischen Metallpartikeln als Lasermarkierungs- oder Laserschweißbarkeitsmittel sowie lasermarkierbarer und/oder laserschweißbarer Kunststoff |
DE102006062270A1 (de) * | 2006-12-22 | 2008-06-26 | Eckart Gmbh & Co. Kg | Aluminiumgrieß für dünne, plättchenförmige Effektpigmente, Verfahren zu dessen Herstellung und Verwendung desselben |
DE102008015124A1 (de) | 2007-05-16 | 2008-11-20 | Bayer Materialscience Ag | Schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
DE102007038578A1 (de) | 2007-08-16 | 2009-02-19 | Evonik Degussa Gmbh | Verfahren zur Dekorierung von Oberflächen |
ATE447476T1 (de) | 2007-11-30 | 2009-11-15 | Eckart Gmbh | Verwendung einer mischung mit sphärischen metallpartikeln und metallflakes als lasermarkierungs- oder laserschweissbarkeitsmittel sowie lasermarkierbarer und/oder laserschweissbarer kunststoff |
CN101970720B (zh) * | 2008-03-13 | 2014-10-15 | 巴斯夫欧洲公司 | 施加金属层至基质的方法和分散体及可金属化热塑性模塑组合物 |
CA2718835C (en) | 2008-03-22 | 2016-05-24 | Bayer Materialscience Ag | Impact-resistant modified polycarbonate compositions with a good combination of raw talc, hydrolysis- and melt stability |
ES2621607T3 (es) | 2010-07-12 | 2017-07-04 | Ineos Styrolution Europe Gmbh | Masas moldeables de copolímero de estireno estabilizadas a la intemperie |
EP2603558B1 (en) * | 2010-08-09 | 2015-04-15 | Styrolution Europe GmbH | Thermoplastic moulding compositions with improved adhesion of electroplated metal layer |
EP2652035B1 (en) * | 2010-12-16 | 2024-03-27 | INEOS Styrolution Europe GmbH | Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact |
DE102011103882A1 (de) | 2011-03-25 | 2012-09-27 | Eckart Gmbh | Kupferhaltige Metallpigmente mit Metalloxidschicht und Kunststoffschicht, Verfahren zu deren Herstellung, Beschichtungsmittel und beschichteter Gegenstand |
US20140230692A1 (en) | 2011-07-25 | 2014-08-21 | Eckart Gmbh | Methods for Substrate Coating and Use of Additive-Containing Powdered Coating Materials in Such Methods |
DE102011052120A1 (de) | 2011-07-25 | 2013-01-31 | Eckart Gmbh | Verwendung speziell belegter, pulverförmiger Beschichtungsmaterialien und Beschichtungsverfahren unter Einsatz derartiger Beschichtungsmaterialien |
DE102011052119A1 (de) | 2011-07-25 | 2013-01-31 | Eckart Gmbh | Verfahren zur Substratbeschichtung und Verwendung additivversehener, pulverförmiger Beschichtungsmaterialien in derartigen Verfahren |
KR20140097156A (ko) | 2011-10-13 | 2014-08-06 | 스티롤루션 게엠베하 | 안정화 폴리아미드/abs 성형물 |
EP2802619B1 (de) | 2012-01-13 | 2016-03-09 | Styrolution Europe GmbH | Terpolymer-formmassen mit geringem gelbwert, verfahren zu deren herstellung sowie deren verwendung |
MX2015007081A (es) * | 2012-12-07 | 2015-09-28 | Bayer Materialscience Ag | Compuestos ii de moldeo de policarbonato ignifugos. |
EP3080201B1 (en) * | 2013-12-11 | 2018-11-28 | INEOS Styrolution Group GmbH | Abs product with improved fire retardancy |
ES2726660T3 (es) * | 2013-12-18 | 2019-10-08 | Ineos Styrolution Group Gmbh | Uso de masas moldeables basadas en copolímeros de bloque de compuesto aromático de vinilo-dieno para la impresión en 3D |
US10815367B2 (en) | 2013-12-18 | 2020-10-27 | Ineos Styrolution Group Gmbh | Moulding compositions based on vinylaromatic copolymers for 3D printing |
CN106459541B (zh) * | 2014-04-02 | 2020-06-23 | 英力士苯领集团股份公司 | 用于制备具有改良机械性能的热塑性成型组合物的方法 |
CN107667143B (zh) | 2015-03-25 | 2021-03-19 | 英力士苯领集团股份公司 | 制备具有优化交联度的热塑性聚合物组合物的方法 |
TWI572659B (zh) * | 2015-09-07 | 2017-03-01 | 奇美實業股份有限公司 | 橡膠改質苯乙烯系樹脂組成物及其所形成的成型品 |
ES2769261T3 (es) | 2015-10-09 | 2020-06-25 | Ineos Styrolution Group Gmbh | Composición de resina termoconductora basada en compuestos estirénicos con baja densidad |
EP3359592B1 (en) | 2015-10-09 | 2019-07-24 | INEOS Styrolution Group GmbH | Electrically conducting thermally conductive polymer resin composition based on styrenics with balanced properties |
EP3359593B1 (en) | 2015-10-09 | 2019-12-11 | INEOS Styrolution Group GmbH | Electrically insulating thermally conductive polymer resin composition based on styrenics with balanced properties |
WO2017104508A1 (ja) * | 2015-12-15 | 2017-06-22 | 日本エイアンドエル株式会社 | 熱可塑性樹脂組成物 |
WO2017102762A1 (en) | 2015-12-17 | 2017-06-22 | Ineos Styrolution Group Gmbh | Process for producing foam molded parts with aesthetic surfaces by foam injection molding |
KR101955514B1 (ko) * | 2016-02-19 | 2019-03-07 | 주식회사 엘지화학 | 고무질 중합체와 이의 제조방법, 그라프트 공중합체 및 열가소성 수지 조성물 |
US10619061B2 (en) | 2016-03-17 | 2020-04-14 | Ineos Styrolution Group Gmbh | Use of moulding compounds based on blends of san-copolymers and polyamide for 3D printing |
KR102237246B1 (ko) | 2016-04-21 | 2021-04-07 | 이네오스 스티롤루션 그룹 게엠베하 | 개선된 균열 및 화학적 내성을 갖는 abs 몰딩 조성물 및 그의 사용 |
KR102273553B1 (ko) | 2016-04-21 | 2021-07-06 | 이네오스 스티롤루션 그룹 게엠베하 | 개선된 균열 및 화학적 내성을 갖는 abs 몰딩 조성물 및 그의 사용 |
ES2829292T3 (es) * | 2016-05-10 | 2021-05-31 | Ineos Styrolution Group Gmbh | Procedimiento para la fabricación de una masa termoplástica de moldeo |
KR102357615B1 (ko) | 2016-08-17 | 2022-02-03 | 이네오스 스티롤루션 그룹 게엠베하 | 아크릴레이트 경질 상을 기반으로 하는 투명 그래프트 공중합체 |
EP3500607B1 (en) | 2016-08-17 | 2023-07-19 | INEOS Styrolution Group GmbH | Transparent graft copolymers based on acrylate soft phases |
KR102464098B1 (ko) | 2017-02-10 | 2022-11-07 | 이네오스 스티롤루션 그룹 게엠베하 | 높은 표면 에너지를 가진 아크릴로니트릴―부타디엔―스티렌 공중합체 조성물 |
US11591462B2 (en) | 2017-03-22 | 2023-02-28 | Ineos Styrolution Group Gmbh | Styrenic copolymer blend with low shrinkage |
KR20210069031A (ko) | 2018-07-24 | 2021-06-10 | 이네오스 스티롤루션 그룹 게엠베하 | 폴리아크릴레이트 그라프트 고무 코폴리머 및 충격 개질된 열가소성 성형 조성물 |
WO2020020834A1 (en) | 2018-07-24 | 2020-01-30 | Ineos Styrolution Group Gmbh | Polyacrylate graft rubber copolymer and thermoplastic molding composition |
KR102288853B1 (ko) * | 2018-09-05 | 2021-08-12 | 주식회사 엘지화학 | 열가소성 수지 조성물 |
EP4045593B1 (en) * | 2019-10-15 | 2023-05-31 | INEOS Styrolution Group GmbH | Styrene copolymer molding compositions with reduced mold deposit formation for high gloss applications |
WO2021230492A1 (ko) * | 2020-05-14 | 2021-11-18 | 주식회사 엘지화학 | 그라프트 공중합체, 이의 제조방법 및 이를 포함하는 수지 조성물 |
KR20240012450A (ko) | 2021-05-25 | 2024-01-29 | 이네오스 스티롤루션 그룹 게엠베하 | 우수한 저온 충격 강도를 갖는 열가소성 물질을 위한 아크릴 고무 |
WO2023036760A1 (en) | 2021-09-07 | 2023-03-16 | Ineos Styrolution Group Gmbh | Multilayer article comprising a recycled abs copolymer core layer |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE80268C (es) | ||||
DD71615A (es) * | ||||
US4206300A (en) | 1978-06-12 | 1980-06-03 | Standand Oil Company | Method for improving color and impact strength of nitrile polymers |
US4419492A (en) | 1981-08-06 | 1983-12-06 | Monsanto Company | Process for preparing ABS polymeric polyblends |
DE3505749A1 (de) | 1985-02-20 | 1986-08-21 | Bayer Ag, 5090 Leverkusen | Formmassen mit einheitlicher korngroesse und verbesserter thermostabilitaet ii |
DE4402394B4 (de) | 1994-01-27 | 2005-02-10 | Basf Ag | Verfahren zur Entwässerung von wasserfeuchtem Pfropfkautschuk |
US5817266A (en) | 1994-01-27 | 1998-10-06 | Basf Aktiengesellschaft | Dewatering of water-moist graft rubber |
KR970701215A (ko) | 1994-02-22 | 1997-03-17 | 그레이스 스티븐 에스. | 다형태 ABS 중합체의 제조방법(Process for the preparation of multimodal ABS polymers) |
DE4414124A1 (de) | 1994-04-22 | 1995-10-26 | Bayer Ag | ABS-Formmassen mit verbesserter Zähigkeit |
ES2130541T3 (es) | 1994-11-21 | 1999-07-01 | Gen Electric | Composiciones termoplasticas vinil aromaticas alfa-alquil sustituidas-vinil cianuro modificadas al impacto. |
DE19520286A1 (de) | 1995-06-02 | 1996-12-05 | Bayer Ag | ABS-Formmassen mit verbesserten Eigenschaften |
-
1997
- 1997-07-04 DE DE19728629A patent/DE19728629A1/de not_active Withdrawn
-
1998
- 1998-06-23 CA CA002294918A patent/CA2294918A1/en not_active Abandoned
- 1998-06-23 EP EP98938632A patent/EP0993476B1/de not_active Expired - Lifetime
- 1998-06-23 JP JP50626499A patent/JP2002510349A/ja active Pending
- 1998-06-23 WO PCT/EP1998/003836 patent/WO1999001489A1/de active IP Right Grant
- 1998-06-23 BR BR9810666-0A patent/BR9810666A/pt not_active Application Discontinuation
- 1998-06-23 DE DE59803025T patent/DE59803025D1/de not_active Expired - Lifetime
- 1998-06-23 AU AU87285/98A patent/AU8728598A/en not_active Abandoned
- 1998-06-23 CN CNB988088614A patent/CN1140551C/zh not_active Expired - Lifetime
- 1998-06-23 US US09/446,982 patent/US6323279B1/en not_active Expired - Lifetime
- 1998-06-23 KR KR1020007000027A patent/KR100361001B1/ko not_active IP Right Cessation
- 1998-06-23 ES ES98938632T patent/ES2172908T3/es not_active Expired - Lifetime
- 1998-07-02 TW TW087110695A patent/TW470755B/zh not_active IP Right Cessation
- 1998-07-03 ZA ZA9805868A patent/ZA985868B/xx unknown
- 1998-07-03 AR ARP980103236A patent/AR012259A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
DE19728629A1 (de) | 1999-01-07 |
TW470755B (en) | 2002-01-01 |
ZA985868B (en) | 2000-01-10 |
AU8728598A (en) | 1999-01-25 |
EP0993476A1 (de) | 2000-04-19 |
WO1999001489A1 (de) | 1999-01-14 |
KR100361001B1 (ko) | 2002-11-22 |
CA2294918A1 (en) | 1999-01-14 |
JP2002510349A (ja) | 2002-04-02 |
CN1269808A (zh) | 2000-10-11 |
CN1140551C (zh) | 2004-03-03 |
DE59803025D1 (de) | 2002-03-21 |
KR20010021502A (ko) | 2001-03-15 |
US6323279B1 (en) | 2001-11-27 |
EP0993476B1 (de) | 2002-02-06 |
ES2172908T3 (es) | 2002-10-01 |
BR9810666A (pt) | 2000-09-26 |
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