WO2023202267A1 - Multi-metal compounding method for polymeric fiber material, and multi-metal composite fiber - Google Patents

Multi-metal compounding method for polymeric fiber material, and multi-metal composite fiber Download PDF

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Publication number
WO2023202267A1
WO2023202267A1 PCT/CN2023/081377 CN2023081377W WO2023202267A1 WO 2023202267 A1 WO2023202267 A1 WO 2023202267A1 CN 2023081377 W CN2023081377 W CN 2023081377W WO 2023202267 A1 WO2023202267 A1 WO 2023202267A1
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fiber
nickel
metal composite
concentration
solution
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PCT/CN2023/081377
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French (fr)
Chinese (zh)
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刘丹丹
李清文
侯立干
陈城
张永毅
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中国科学院苏州纳米技术与纳米仿生研究所
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Publication of WO2023202267A1 publication Critical patent/WO2023202267A1/en

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31—Coating with metals
    • C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/38—Electroplating: Baths therefor from solutions of copper
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/54—Electroplating of non-metallic surfaces
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D06M2101/36—Aromatic polyamides

Definitions

  • the present application relates to the technical field of composite fibers, and in particular to a multi-metal composite method of polymer fiber materials and multi-metal composite fibers.
  • polymer fibers especially aramid fibers
  • aramid fibers give them a series of excellent characteristics such as high strength, high modulus, corrosion resistance, and heat resistance. They are widely used in aerospace, military and national defense, special protection, building reinforcement, etc. direction.
  • metal composite aramid fiber combines metal conductivity, weldability, and electromagnetic shielding properties with non-metallic fiber lightweight, softness, and braidability. This material has been used in aerospace, military and national defense, and artificial intelligence. Wearable and other fields are emerging.
  • the preparation methods of metal composite aramid fibers mainly include electroless plating, electroless plating + electroplating, CVD, PVD, and other methods.
  • the process flow of each method can be summarized as pre-treatment, metal composite, and post-treatment.
  • the main problems existing in the preparation methods in the prior art are as follows:
  • the single type of composite metal results in single product performance. For example, if only silver is plated on the surface of aramid fiber, it is limited by the environmental resistance of silver. When the silver coating corrodes and falls off, the fiber loses its conductivity, making the product difficult to withstand harsh service environments. The scene is single;
  • the purpose of this application is to provide a multi-metal composite method of polymer fiber materials and multi-metal composite fibers.
  • this application provides a multi-metal composite method of polymer fiber materials, including:
  • the polymer fibers are etched in an etching solution including an oxidizing acid and a hydrophilic agent to obtain micro-etched fibers;
  • a multi-metal composite layer is deposited on the surface of the activated fiber, wherein the multi-metal composite layer at least includes an electroless nickel plating bottom layer and at least one electroplated copper layer covering the surface of the activated fiber.
  • the present application also provides a multi-metal composite fiber of a polymer fiber prepared by the above-mentioned multi-metal composite method.
  • the beneficial effects of this application at least include:
  • the multi-metal composite method of polymer fiber materials uses a combination of oxidizing acid and hydrophilic agent to etch micro-etched fibers, which avoids cracking, ineffective etching and fiber agglomeration of polymer fibers.
  • the surface of the polymer fiber constructs a surface microstructure with suitable morphology and roughness, which greatly improves the binding force between the multi-metal composite layer and the polymer fiber in the multi-metal composite fiber and the uniformity of the multi-metal composite layer.
  • this etching treatment can effectively avoid the load loss of polymer fibers, improve the mechanical properties of the prepared multi-metal composites, and provide an effective and feasible solution for preparing high-quality multi-metal composite fibers.
  • Figure 1 is a surface morphology diagram of micro-etched aramid fiber provided in a typical implementation case of this application;
  • Figure 2 is a macroscopic optical photo of an electroless nickel-plated aramid fiber provided in a typical implementation case of this application;
  • Figure 3 is a low-magnification electron microscope image of an electroless nickel-plated aramid fiber provided in a typical implementation case of this application;
  • Figure 4 is a macroscopic optical photograph of aramid fiber electroplated with copper provided in a typical implementation case of this application;
  • Figure 5 is a macroscopic optical photograph of the first electroplated nickel aramid fiber provided in a typical implementation case of this application;
  • Figure 6 is a macroscopic optical photograph of aramid fiber electroplated with silver provided in a typical implementation case of this application;
  • Figure 7 is a cross-sectional morphology diagram of a multi-metal composite aramid fiber provided in a typical implementation case of this application;
  • Figure 8 is a radial element distribution diagram of a multi-metal composite aramid fiber provided in a typical implementation case of this application;
  • Figure 9 is a load retention rate test chart of multi-metal composite aramid fiber provided in a typical implementation case of this application.
  • Figure 10 is a photo of a shielding sleeve made of multi-metal (nickel + copper) composite aramid fiber provided in a typical implementation case of this application;
  • Figure 11 is a partial structural schematic diagram of equipment for preparing multi-metal composite fibers provided in a typical implementation example of this application;
  • Figure 12 is a partial structural schematic diagram of equipment for preparing multi-metal composite fibers provided in a typical implementation example of this application;
  • Figure 13 is a picture of the surface morphology of aramid fiber after etching provided by a typical comparative case of this application;
  • Figure 14 is another typical comparative example of the etched aramid fiber surface morphology provided by this application.
  • Figure 15 is another typical comparison case of the etched aramid fiber surface morphology provided by this application.
  • Figure 16 is another typical comparative example of the peeling morphology of the knotted coating provided by this application.
  • the embodiment of the present application provides a multi-metal composite method of polymer fiber materials, including the following steps:
  • the polymer fiber is etched in an etching solution including an oxidizing acid and a hydrophilic agent to obtain a micro-etched fiber.
  • micro-etched fiber is subjected to surface activation treatment to obtain activated fiber.
  • a multi-metal composite layer is deposited on the surface of the activated fiber, wherein the multi-metal composite layer at least includes an electroless nickel plating bottom layer and at least one electroplated copper layer covering the surface of the activated fiber.
  • the multi-metal composite method provided by this application can be implemented by using the following processes: wire-laying, hydrophilicity, catalysis, degumming, nickel-boron chemical nickel, electroplating copper, and optional electroplating nickel, electroplating silver, electroplating Nickel, etc., as well as protection, drying, and take-up.
  • the multi-metal composite layer can be: nickel+copper layer, nickel+copper+nickel layer, nickel+copper+nickel+silver layer, nickel+copper+nickel+silver+nickel layer.
  • the micro-etched fiber surface is etched to produce a plurality of etched grooves.
  • the depth of the etched grooves is 30-50 nm and the width is 300-500 nm.
  • the roughness of the micro-etched fiber surface is is 0.1-0.5 ⁇ m.
  • the oxidizing acid includes sulfuric acid and/or chromic acid.
  • the hydrophilic agent includes any one or a combination of two or more of sodium dodecyl benzene sulfonate, sodium dodecyl sulfonate, polyethylene glycol and polyvinyl alkanone, or It can be purchased directly, such as UDIQUE Etch Wetting Agent.
  • the content of sulfuric acid is 50-80 mL/L, and the content of the hydrophilic agent is 2-5 ml/L.
  • the temperature of the etching solution is 28-30°C, and the etching treatment time is 4-7 minutes.
  • the etching effect of the etching treatment is mild, the hydrophilicity of the aramid fiber is improved, and a micro-etched aramid surface is formed, which maintains the mechanical properties of the fiber while providing effective hooks and riveting points for the multi-metal composite layer.
  • the surface morphology of the aramid fiber after etching is shown in Figure 1, along with other etching treatments shown in Figures 13-15. The surface morphology of the method is used as a comparison.
  • the polymer fibers include polyester (polyadipate terephthalate, PET), nylon (polyamide fiber, Nylon), polypropylene (polypropylene fiber), aramid (aromatic polyester fiber) Any one or both of amide fiber), ultra-high molecular polyethylene (UHMWPE), poly-paraphenylene benzobisoxazole fiber (PBO), polybenzimidazole (PBI), polyimide fiber (PI) combinations of more than one species.
  • the combination may refer to a combination such as mixed weaving of multiple fibers or mixed spinning of multiple polymer raw materials.
  • the surface activation treatment includes a catalytic step and a degumming step.
  • the catalytic step includes: placing the micro-etched fiber in a catalytic liquid with a temperature of 25-33°C for 3-6 minutes, and the catalytic liquid includes palladium with a concentration of 2-5ml/L.
  • the palladium-containing catalyst includes palladium chloride at a concentration of 5-12 g/L, hydrochloric acid at a concentration of 120-260 mL/L, sodium chloride at a concentration of 30-80 g/L, and sodium chloride at a concentration of 5-12 g/L.
  • 13g/L stannous chloride may be purchased directly, such as UDIQUE 8710 ACTIVATOR.
  • colloidal palladium active sites with an electric double layer structure are uniformly covered on the surface of the aramid fiber.
  • the degumming step includes: placing the catalyzed micro-etched fiber in a degumming solution with a temperature of 27-54°C for 30s-3 minutes, and the degumming solution includes a degumming solution with a concentration of 15-54°C. 25g/L accelerator and concentrated sulfuric acid with a volume fraction of 1.6-2.6%.
  • the accelerator includes stannous sulfate and/or tin sulfate solution with a concentration of 150-300g/L, or can be purchased directly, such as UDIQUE 887 DT.
  • the above embodiment dissolves the divalent tin ions around the colloidal palladium, exposing the catalytically active metallic palladium.
  • the polymer fiber is selected from multi-filament aramid
  • the deposition method of the electroless nickel plating bottom layer specifically includes: placing the activated fiber in an electroless nickel solution with a temperature of 55-65°C. Electroless nickel plating takes 4-8 minutes.
  • the chemical nickel solution includes nickel sulfate hexahydrate with a concentration of 15-25g/L, dimethylamine borane with a concentration of 2-5g/L, and citric acid with a concentration of 5-15g/L. , hydrochloric acid with a concentration of 30-50mL/L and dimercaptobenzothiazole with a concentration of 0.01-0.05g/L, and using ammonia water to adjust the pH of the chemical nickel solution to 6.5-7.2.
  • the nickel-boron alloy formed by this nickel-boron system has better bonding strength than other types of nickel plating, and the plating is softer. In some examples, as shown in Figures 2-3.
  • the electroless nickel plating bottom layer increases the bonding force and provides a conductive foundation for subsequent electroplating.
  • the multi-metal composite layer further includes an electroplated copper layer covering the outer surface of the electroless nickel plating bottom layer.
  • the deposition method of the electroplated copper layer specifically includes: coating the electroplated copper layer with the chemical nickel plating layer.
  • the activated fibers of the nickel bottom layer are placed in a copper electroplating solution with a temperature of 50-60°C for copper electroplating for 4-8 minutes, wherein the copper electroplating solution is alkaline.
  • Aramid fibers are easier to disperse in alkaline copper plating reagents than in acidic copper plating reagents.
  • the prepared copper-plated aramid fiber tows are dispersed and the plating layer is uniform.
  • the copper plating layer mainly increases the conductivity of the aramid fiber, especially when used as a cable shielding layer, it can reduce the transfer impedance.
  • the multi-metal composite layer of aramid fibers formed by this step is as shown in Figure 4.
  • the copper electroplating solution includes: potassium pyrophosphate with a concentration of 250-290 g/L, copper pyrophosphate with a concentration of 59-88 g/L, and ammonia water with a concentration of 2-4 mL/L, and is adjusted to The pH value of the copper electroplating solution is 8.6-9.2.
  • the current density used during copper electroplating is 1-6 amperes/square decimeter.
  • the multi-metal composite layer sequentially includes an electroless nickel plating bottom layer, an electroplated copper layer, a first electroplated nickel layer, an electroplated silver layer, and a second electroplated nickel layer.
  • the first electroplating nickel layer deposition method includes: placing the activated fiber after copper electroplating in a first electroplating nickel solution with a temperature of 50-60°C to electroplat nickel for 4-8 minutes, the The first nickel plating solution includes: 380-650mL/L nickel sulfamate, 5.7-14g/L nickel chloride and 30-40g/L boric acid.
  • the current density during electroplating is 2-4 amps/square decimeter. .
  • the deposition method of the electroplated silver layer includes: placing the activated fiber covered with the first electroplated nickel layer in an electroplating silver solution with a temperature of 15-25°C for 4-8 minutes to electroplat silver.
  • the silver solution includes: silver nitrate with a concentration of 15-40g/L, 5,5-dimethylhydantoin with a concentration of 50-90g/L, and potassium hydroxide with a concentration of 35-60g/L; the electroplating
  • the pH value of the silver solution is 8-10 and the temperature is 40-60°C, or the solution solution provided by the supplier can be used: 10-23.3g/L Ecosilver Ag, 60-100g/L Ecosilver Cosalt and 200g/L Ecosilver 210 Additive; the current density of the electroplated silver is 2.5-5 amps/square decimeter.
  • the silver layer can further improve the conductivity of the aramid fiber and make the multi-metal composite fiber have good weldability, which facilitates the connection of electronic components.
  • the second electroplating nickel layer deposition method includes: placing the silver electroplated activated fiber in a second electroplating nickel solution at a temperature of 50-60°C for 1-2 minutes to electroplat nickel,
  • the second electroplating nickel solution includes: 380-650mL/L nickel sulfamate, 5.7-14g/L nickel chloride and 30-40g/L boric acid.
  • the current density during electroplating is 1-2 ampere/square decimeter. .
  • the first electroplated nickel layer can be used as a protective layer to make the multi-metal composite fiber meet environmental adaptability and other requirements; when the metal composite layer is nickel+copper+nickel+ When adding a silver layer, the first electroplated nickel layer can be used as a transition layer to ensure good adhesion of the electroplated silver layer and improve product stability. Also referring to Figure 6, the second electroplated nickel layer serves as a protective layer for the electroplated silver layer, further improving the environmental tolerance of the product. Nickel metal has good electromagnetic shielding properties. In some practical applications, the compound proportion of nickel metal can be adjusted so that the product can meet the service requirements in different electromagnetic environments.
  • the resistance of the polymer fiber and its coating is calculated in real time.
  • the resistance of the polymer fiber during electroplating can be calculated based on the output voltage of the power supply and the plating current; when the resistance When the resistance is greater than the first preset threshold, the power supply is controlled to increase the plating current; when the resistance is less than the second preset threshold, the power supply is controlled to reduce the plating current.
  • a plurality of the polymer fibers separately prepare a power supply and independently control the current of a plurality of the power supplies. Due to the differences in the raw materials of polymer fibers, especially aramid fiber, and the differences in each channel in the pre-treatment process, the resistance of aramid fiber in each channel after chemical nickel treatment is different.
  • this application adopts a multi-channel independent preparation of electrodes and power sources for electroplating in each electroplating channel.
  • 1, 2, 3, and 4 are four sets of independently conductive copper conductive cathodes, fixed with an insulated transmission shaft 5 in the middle; conductive posts 6 are installed on the sides of each set of electrodes, and the conductive posts are equipped with conductive poles connected to the copper conductive cathodes.
  • Brush 7, wiring port 8, supplemented by guide The wire is connected to the negative pole of the externally controllable DC power supply; each group of copper conductive cathodes shares an insulating pressure roller 9 to ensure good conductive contact between the fiber and the electrode; the electrode is also equipped with a transmission gear 10 and a ceramic bearing 11.
  • the resistance values of products of various specifications in different processes are preset.
  • the controllable DC power supply adopts constant voltage output mode, and the current of each channel in continuous production is remotely controlled through PLC, thereby achieving controllable production. When the resistance value increases, the PLC increases the output current according to the formula; when the resistance value decreases, the PLC decreases the output current according to the formula.
  • the step of forming a protective layer on the surface of the multi-metal composite layer is also included.
  • the above-mentioned protective layer can be formed by the following method: Equipment preparation: the upper and lower sub-troughs and water supply pipes are equipped with filtering devices and constant temperature devices. Process conditions: The sub-tank reagent is circulated 5 times every 10 minutes, the temperature is 45-55°C, and the processing time is 5s-1min.
  • the protective agent was purchased from Shanghai Zeshi Chemical Technology Co., Ltd.
  • the multi-metal composite fiber prepared in the above embodiment can also be dried at a temperature of 90-120°C and a time of 3-5 minutes. Drying is helpful for the preservation of the above-mentioned multi-metal composite fiber.
  • the above-mentioned multi-metal composite fiber The drying conditions can be appropriately adjusted to other conditions according to different needs and environments.
  • the multi-metal composite method of polymer fiber materials provided in the embodiments of the present application also includes a pay-off and take-up process.
  • the pay-off and take-up equipment is equipped with an angle sensor, and the pay-off and take-up speeds can be automatically matched according to the production speed.
  • the equipment used in each of the above processes can be an upper and lower sub-tank, a filter device in the upper water pipe, and a thermostatic device to control the temperature in the sub-tank, and the solution or dispersion in the sub-tank is continuously circulated.
  • the amount can be controlled to cycle 2-8 times every 10 minutes according to the actual situation.
  • embodiments of the present application also provide multi-metal composite fibers of polymer fibers prepared by the above-mentioned multi-metal composite method.
  • This embodiment provides a multi-metal composite method for aramid fibers, which specifically includes the following steps:
  • Etching Place multiple rolls of aramid fiber on the pay-off device and let it enter the etching process.
  • the etching process use the mother-and-son groove Device, control the temperature of the etching solution to 30°C, the sub-tank circulation volume is 5 cycles every 10 minutes, and the traveling speed of the aramid fiber makes the etching treatment time of the aramid fiber in the etching solution to be 4 minutes.
  • the etching solution The ingredients and content are: concentrated sulfuric acid is 80ml/L, hydrophilic agent UDIQUE Etch Wetting Agent (the main ingredients are sodium dodecyl benzene sulfonate, sodium dodecyl sulfonate, polyethylene glycol or polyethylene glycol The concentration of ketone) is 5%; the surface morphology of the micro-etched fiber obtained by etching in this step is shown in Figure 1. The blistering and peeling phenomena caused by excessive etching on the surface do not cause fiber rupture, and the surface micro-etching The structure is good and suitable for subsequent multi-metal layer composite processes;
  • the aramid fiber continues to enter the sub-trough carrying the catalytic liquid and degumming liquid.
  • the catalytic liquid sub-tank circulates twice every 10 minutes, and the degumming liquid sub-trough
  • the tank circulates 5 times every 10 minutes.
  • the catalytic liquid temperature is controlled at 25°C, the catalytic time is 6 minutes, the degumming liquid temperature is controlled at 54°C, and the degumming time is 30s; in this step, the catalytic liquid is: palladium chloride is 10g/ L, hydrochloric acid (37%) is 200mL/L, sodium chloride is 50g/L, stannous chloride is 4g/L, the composition and content of the degumming solution are: UDIQUE 887 DT accelerator is 15g/L, concentrated H 2 SO 4 is 2.6%;
  • Electroless nickel plating Electroless nickel plating using nickel boron system. This step uses upper and lower sub-tank devices, a filter device in the water supply pipe, and a thermostatic device to control the temperature of the chemical nickel liquid; the process conditions are: sub-tank reagents every 10 minutes Cycle 8 times, the temperature is 60°C, and the treatment time is 6 minutes; the composition and content of chemical nickel are: nickel sulfate hexahydrate 25g/L, dimethylamine borane 5g/L, citric acid 15g/L, hydrochloric acid 40mL/L, dimethyl sulfate Mercaptobenzothiene 0.01g/L, and use ammonia to adjust pH to 7.2;
  • Electroplating copper This step uses an upper and lower sub-tank device, a filter device in the water supply pipe, and a constant temperature device to control the temperature of the electroplating copper solution; the process conditions are: the sub-tank reagents are circulated 5 times every 10 minutes, the temperature is 55°C, and the electroplating The time is 8 minutes; the composition and content of the copper electroplating solution are: potassium pyrophosphate 250g/L, copper pyrophosphate 59g/L, use ammonia to adjust the pH to 8.6, and the current density of copper electroplating is 1 ampere/square decimeter;
  • This step uses an upper and lower sub-tank device, a filter device in the water supply pipe, and a thermostatic device to control the temperature of the nickel plating solution; process conditions: the sub-tank reagents are circulated 5 times every 10 minutes, and the temperature is 60°C. Plating time is 6 minutes.
  • Reagent composition nickel sulfamate 500mL/L, nickel chloride 10g/L, boric acid 30g/L, current density 2 ampere/square decimeter;
  • This step uses an upper and lower sub-tank device, a filter device in the water supply pipe, and a constant temperature device to control the temperature of the electroplating silver solution; the process conditions are: the sub-tank reagents are circulated 5 times every 10 minutes, the temperature is 20°C, and the electroplating Time 6min.
  • the reagents were purchased from Shanghai Zeshi Chemical Technology Co., Ltd.
  • the reagent composition is: Ecosilver Ag 20g/L, Ecosilver Cosalt 80g/L, Ecosilver 210 Additive 200g/L, and the current density is 4 amps/square decimeter;
  • Second nickel electroplating The structure of the equipment, reagent composition and process conditions used in this step are the same as those of the first nickel electroplating. The only difference is that the electroplating time is 1.5 minutes and the current density is 1.5 amps/square decimeter;
  • the load changes of the aramid fiber prepared by the multi-metal composite method provided in this embodiment before and after composite are shown in Figure 9.
  • the composite method provided by the embodiment of this application causes damage to the aramid fiber.
  • Extremely small, aramid load Low loss is conducive to providing high-quality multi-metal composite fibers. Affected by the difference in diameter of aramid fibrils, the reliability of the fiber coating thickness characterization after metal composite treatment is low and the error is large. Therefore, multiple groups of multi-metal composites are analyzed and counted. The uniformity of fiber linear density and the percentage of multi-metal composite fiber mass (metal mass + aramid fibril mass) occupied by metal per unit length were obtained. Five sets of data were randomly tested, and the CV value of the coating mass fraction was 5.44%.
  • This embodiment provides a multi-metal composite method for aramid fibers, which is basically the same as Embodiment 1, with the only difference being:
  • the first nickel electroplating, silver electroplating and second nickel electroplating steps are omitted, and the composition of the multi-metal composite layer is only an electroless nickel bottom layer + an electroplated copper layer.
  • the multi-metal composite fiber provided in this embodiment can be used to make a cable shielding sleeve, and a picture of the finished product is shown in Figure 10.
  • This embodiment provides a multi-metal composite method for aramid fibers, which is basically the same as Embodiment 1, with the only difference being:
  • the temperature of the etching liquid is 28°C.
  • the traveling speed of the aramid fiber makes the etching treatment time of the aramid fiber in the etching liquid 7 minutes.
  • the composition and content of the etching liquid are: concentrated sulfuric acid is 50ml/L. , the outsourced hydrophilic agent UDIQUE Etch Wetting Agent is 2%;
  • the temperature of the catalytic liquid is controlled at 33°C, the catalytic time is 3 minutes, the temperature of the degumming liquid is controlled at 27°C, and the degumming time is 3 minutes; in this step, the catalytic liquid is: the same company's product UDIQUE 8710 ACTIVATOR is 5mL/L, Hydrochloric acid (37%) is 300mL/L, sodium chloride is 40g/L, stannous chloride is 2g/L, the composition and content of the degumming solution are: UDIQUE 887 DT accelerator is 25g/L, concentrated H 2 SO 4 is 1.6%;
  • Electroless nickel plating temperature is 55°C, processing time is 4 minutes; the composition and content of chemical nickel are: nickel sulfate hexahydrate 15g/L, dimethylamine borane 2g/L, citric acid 5g/L, hydrochloric acid 50mL/L, dimethyl sulfate Mercaptobenzothiene 0.01g/L, and use ammonia to adjust pH to 6.5;
  • Electroplating copper The temperature is 60°C, the electroplating time is 4 minutes, the composition and content of the electroplating copper solution are: potassium pyrophosphate 270g/L, copper pyrophosphate 88g/L, use ammonia to adjust the pH to between 8.6-9.2, the current density of electroplated copper 6 amps/dm2;
  • Second nickel plating temperature is 50°C, plating time is 4 minutes.
  • Reagent composition nickel sulfamate 650mL/L, nickel chloride 5.7g/L, boric acid 40g/L, current density 4 amps/square decimeter;
  • the reagents were purchased from Shanghai Zeshi Chemical Technology Co., Ltd.
  • the reagent composition is: Ecosilver Ag 10g/L, Ecosilver Cosalt 60g/L, Ecosilver 210 Additive 200g/L, and the current density is 2.5 amps/square decimeter;
  • Second nickel electroplating The structure of the equipment, reagent composition and process conditions used in this step are the same as those of the first nickel electroplating in this embodiment. The only difference is that the time is 1 minute and the current density is 2 amperes/square decimeter.
  • the prepared multi-metal composite aramid fiber has similar conductive properties and load retention rate to those in Example 1.
  • This embodiment provides a multi-metal composite method for aramid fibers, which is basically the same as Embodiment 1, with the only difference being:
  • the temperature of the etching liquid is 30°C
  • the circulation volume of the sub-tank is 5 times every 10 minutes
  • the traveling speed of the aramid fiber is such that the etching treatment time of the aramid fiber in the etching liquid is 5 minutes.
  • the etching liquid The ingredients and content are: concentrated sulfuric acid is 70ml/L, and the purchased hydrophilic agent UDIQUE Etch Wetting Agent is 4ml/L;
  • the temperature of the catalytic liquid is controlled at 29°C, the catalytic time is 4 minutes, the temperature of the degumming liquid is controlled at 35°C, and the degumming time is 2 minutes; in this step, the catalytic liquid is: the same company's product UDIQUE 8710 ACTIVATOR is 3mL/L, Hydrochloric acid (37%) is 250mL/L, sodium chloride is 60g/L, stannous chloride is 3g/L, the composition and content of the degumming solution are: UDIQUE 887 DT accelerator is 21g/L, concentrated H 2 5O 4 is 2.0%;
  • Electroless nickel plating temperature is 65°C, processing time is 8 minutes; the composition and content of chemical nickel are: nickel sulfate hexahydrate 17g/L, dimethylamine borane 4g/L, citric acid 10g/L, hydrochloric acid 30mL/L, dimethyl sulfate Mercaptobenzothiene 0.01g/L, and use ammonia to adjust pH to 7.0;
  • Electroplating copper The temperature is 50°C, the electroplating time is 6 minutes, the composition and content of the electroplating copper solution are: potassium pyrophosphate 290g/L, copper pyrophosphate 66g/L, use 4ml/L ammonia to adjust the pH to 9.2, the current for electroplating copper Density 3 amperes/square decimeter;
  • the first nickel plating temperature is 55°C, plating time is 8 minutes.
  • Reagent composition nickel sulfamate 380mL/L, nickel chloride 14g/L, boric acid 33g/L, current density 3 ampere/square decimeter;
  • the reagents were purchased from Shanghai Zeshi Chemical Technology Co., Ltd.
  • the reagent composition is: Ecosilver Ag 23g/L, Ecosilver Cosalt 100g/L, Ecosilver 210 Additive 200g/L, and the current density is 5 amps/square decimeter;
  • Second nickel electroplating The structure of the equipment, reagent composition, and process conditions used in this step are the same as those of the first nickel electroplating in this embodiment. The only difference is that the time is 2 minutes and the current density is 1 ampere/square decimeter.
  • the prepared multi-metal composite aramid fiber has similar conductive properties and load retention rate to those in Example 1.
  • multi-strand nylon fiber as the basic fiber for multi-metal composites, multi-metal composite polymer fibers with similar conductor properties and load retention rates can also be obtained.
  • multi-strand PBO fiber as the basic fiber for multi-metal composite, multi-metal composite polymer fiber with similar conductor properties and load retention rate can also be obtained.
  • multi-strand PI fiber as the basic fiber for multi-metal composite, multi-metal composite polymer fiber with similar conductor properties and load retention rate can also be obtained.
  • This comparative example is basically the same as Example 1. The only difference is that the composition of the etching solution is: 40g/L of chromium trioxide and 20mL/L of concentrated sulfuric acid.
  • the surface morphology of the aramid fiber after etching is as shown in Figure 13 It shows that there is a lot of peeling and cavitation on the surface, which is not conducive to the subsequent multi-metal composite. Moreover, after multi-metal composite, the load retention rate is 76%, which is significantly lower than that of Example 1.
  • This comparative example is basically the same as Example 1. The only difference is that the composition of the etching solution is: 600 mL/L concentrated sulfuric acid.
  • the surface morphology of the aramid fiber after etching is shown in Figure 14. A large number of aramid fiber appears on the surface. The fiber bundles cracked, and the composite of multi-metal layers could not be continued. Moreover, the load retention rate of the fibers was 45%, which was significantly lower than that of Example 1.
  • This comparative example is basically the same as Example 1. The only difference is that the composition of the etching solution is: 80mL/L concentrated sulfuric acid.
  • the surface morphology of the aramid fiber after etching is shown in Figure 15. There is no effective etching on the surface. , is not conducive to subsequent multi-metal composites, and although after multi-metal composites, the load retention rate is similar to that of Example 1, or even slightly higher than that of Example 1, however, after knotting as shown in Figure 3 , the multi-metal composite layer is extremely easy to fall off, and the peeling off state of the plating after knotting is shown in Figure 16, indicating that the binding force between the multi-metal composite layer and the aramid fiber provided by this comparative example is significantly lower than that of Example 1. Although the multi-metal composite aramid fiber in the proportion does not suffer a large loss in load, the multi-metal layer is too easy to fall off and cannot meet the needs of applications such as braided shielding sleeves.
  • This comparative example is basically the same as Example 1. The only difference is that a nickel-phosphorus system is used for electroless nickel plating.
  • the specific conditions are: nickel sulfate hexahydrate 15g/L, sodium hypophosphite 20g/L, lactic acid 25mL/L, thiourea 0.3g/L, temperature 90°C, pH 4.5, there are few bubbles on the surface of the aramid fiber, and the multi-metal composite aramid prepared in this comparative example is easily prone to plating leakage.
  • This comparative example is basically the same as Example 1. The only difference is that an acidic copper plating system is used for copper electroplating. The specific conditions are: 210g/L copper sulfate pentahydrate, 50g/L sulfuric acid, 110uL/L hydrochloric acid, and a temperature of 27°C.
  • the tows of aramid fiber are not easy to disperse.
  • the multi-metal composite aramid fiber prepared in this comparative example has a hardening phenomenon and is extremely loose, making it difficult to apply.
  • the multi-metal composite method provided by the present application can better maintain the load of the polymer fiber, thereby improving the mechanical properties of the multi-metal composite fiber finished product.
  • the method provided by the present application is useful for optimizing The uniformity of the composite fibers and the bonding strength of the coating also significantly help.

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Abstract

The present application discloses a multi-metal compounding method for a polymeric fiber material and a multi-metal composite fiber. The method comprises: etching a polymeric fiber in an etching solution containing an oxidizing acid and a hydrophilic agent to obtain a micro-etched fiber; performing surface activation treatment on the micro-etched fiber to obtain an activated fiber; and depositing a multi-metal composite layer on the surface of the activated fiber, the multi-metal composite layer at least comprising an electroless nickel plated bottom layer applied on the surface of the activated fiber and at least one electroplated copper layer. According to the multi-metal compounding method for a polymeric fiber material provided by the present application, the oxidizing acid and the hydrophilic agent are used in combination, so that the phenomena of cracking, ineffective etching, and fiber agglomeration of the polymeric fiber are avoided, and the bonding force, uniformity, and mechanical property of the multi-metal composite layer and the polymeric fiber are improved.

Description

高分子纤维材料的多金属复合方法及多金属复合纤维Multi-metal composite method of polymer fiber materials and multi-metal composite fiber
本申请基于并要求于2022年4月19日递交的申请号为202210413055.X、发明名称为“高分子纤维材料的多金属复合方法及多金属复合纤维”的中国专利申请的优先权。This application is based on and claims priority to the Chinese patent application with application number 202210413055.
技术领域Technical field
本申请涉及复合纤维技术领域，尤其涉及一种高分子纤维材料的多金属复合方法及多金属复合纤维。The present application relates to the technical field of composite fibers, and in particular to a multi-metal composite method of polymer fiber materials and multi-metal composite fibers.
背景技术Background technique
高分子纤维，尤其是芳纶纤维独特的结构特征赋予了它高强、高模、耐腐蚀、耐热等一系列优异特点，被广泛的应用于航空航天、军工国防、特种防护、建筑补强等方向。金属复合芳纶纤维作为新型高性能轻量化导电材料，兼具金属导电、可焊接、电磁屏蔽性和非金属纤维轻质、柔软、可编织性，该材料已在航空航天、军工国防、人工智能穿戴等领域崭露头角。The unique structural characteristics of polymer fibers, especially aramid fibers, give them a series of excellent characteristics such as high strength, high modulus, corrosion resistance, and heat resistance. They are widely used in aerospace, military and national defense, special protection, building reinforcement, etc. direction. As a new high-performance lightweight conductive material, metal composite aramid fiber combines metal conductivity, weldability, and electromagnetic shielding properties with non-metallic fiber lightweight, softness, and braidability. This material has been used in aerospace, military and national defense, and artificial intelligence. Wearable and other fields are emerging.
现有技术中，金属复合芳纶纤维的制备方法主要有化学镀、化学镀+电镀、CVD、PVD、等方法，各方法工艺流程可归纳为前处理、金属复合、后处理。目前，现有技术中的制备方法所存在的主要问题如下：In the existing technology, the preparation methods of metal composite aramid fibers mainly include electroless plating, electroless plating + electroplating, CVD, PVD, and other methods. The process flow of each method can be summarized as pre-treatment, metal composite, and post-treatment. At present, the main problems existing in the preparation methods in the prior art are as follows:
前处理步骤存在的问题：Problems with pre-processing steps:
1)使用易燃、易爆、易挥发的试剂，增加安全事故风险，危害人体健康；1) The use of flammable, explosive, and volatile reagents increases the risk of safety accidents and harms human health;
2)对纤维表面进行刻蚀时，难以控制刻蚀效果。例如：①选用较高浓度的硫酸，导致纤维沿径向龟裂，严重影响纤维的力学性能。选用低浓度的硫酸，对纤维表面无有效刻蚀处理；②选用二甲基亚砜为溶剂配制的试剂，导致纤维团聚，难以分散，影响后续金属复合的均匀性；2) When etching the fiber surface, it is difficult to control the etching effect. For example: ① Using a higher concentration of sulfuric acid will cause cracks in the fiber along the radial direction, seriously affecting the mechanical properties of the fiber. Choosing a low concentration of sulfuric acid will not effectively etch the fiber surface; ② Choosing a reagent prepared with dimethyl sulfoxide as the solvent will cause the fibers to agglomerate and be difficult to disperse, affecting the uniformity of subsequent metal composites;
3)工艺时间过长。例如，一些相关专利中采用多巴胺水溶液下反应20小时进行芳纶改性，或在氢氧化钠溶液中超声波清洗30min，抑或在高锰酸钾溶液中浸泡20-40分钟，工艺时间过长制约了产业化制备的应用前景。3) The process time is too long. For example, some related patents use a dopamine aqueous solution for 20 hours to modify aramid, or ultrasonic cleaning in a sodium hydroxide solution for 30 minutes, or soaking in a potassium permanganate solution for 20-40 minutes. The process time is too long and restricts Application prospects of industrial preparation.
金属复合步骤存在的问题：Problems with the metal composite step:
1)复合金属种类单一，导致产品性能单一。如在芳纶纤维表面仅进行镀银，受限于银的耐环境性能，当银镀层腐蚀脱落，纤维丧失导电性，使得产品难以胜任恶劣服役环境，应用 场景单一；1) The single type of composite metal results in single product performance. For example, if only silver is plated on the surface of aramid fiber, it is limited by the environmental resistance of silver. When the silver coating corrodes and falls off, the fiber loses its conductivity, making the product difficult to withstand harsh service environments. The scene is single;
2)磁控溅射、热蒸镀、电子束蒸发等PVD生产方式成本过高。高昂的设备投入，拉升生产成本，制约了产品的市场推广应用。并且，受限于PVD设备的工作原理方式，难以在直径约12微米芳纶纤维表面形成连续镀层。2) The cost of PVD production methods such as magnetron sputtering, thermal evaporation, and electron beam evaporation is too high. High equipment investment increases production costs and restricts the market promotion and application of products. Moreover, limited by the working principle of PVD equipment, it is difficult to form a continuous coating on the surface of aramid fiber with a diameter of about 12 microns.
3)物理浸涂，印染技术结合力差。如在疏水，光滑的芳纶纤维表面，仅进行物理浸涂导电物质，无法实现导电金属的有效复合。3) Physical dip coating and poor printing and dyeing technology combination. For example, on the surface of hydrophobic, smooth aramid fiber, only physical dip-coating of conductive substances cannot achieve effective compounding of conductive metals.
发明内容Contents of the invention
针对现有技术的不足，本申请的目的在于提供一种高分子纤维材料的多金属复合方法及多金属复合纤维。In view of the shortcomings of the existing technology, the purpose of this application is to provide a multi-metal composite method of polymer fiber materials and multi-metal composite fibers.
为实现前述发明目的，本申请采用的技术方案包括：In order to achieve the foregoing invention objectives, the technical solutions adopted in this application include:
第一方面，本申请提供一种高分子纤维材料的多金属复合方法，包括：In the first aspect, this application provides a multi-metal composite method of polymer fiber materials, including:
使高分子纤维在包括氧化性酸、亲水剂的刻蚀液中进行刻蚀处理，得到微蚀纤维；The polymer fibers are etched in an etching solution including an oxidizing acid and a hydrophilic agent to obtain micro-etched fibers;
对所述微蚀纤维进行表面活化处理，得到活化纤维；Perform surface activation treatment on the micro-etched fibers to obtain activated fibers;
在所述活化纤维表面沉积多金属复合层，其中，所述多金属复合层至少包括包覆于所述活化纤维表面的化学镀镍底层以及至少一电镀铜层。A multi-metal composite layer is deposited on the surface of the activated fiber, wherein the multi-metal composite layer at least includes an electroless nickel plating bottom layer and at least one electroplated copper layer covering the surface of the activated fiber.
第二方面，本申请还提供一种上述多金属复合方法制备得到的高分子纤维的多金属复合纤维。In a second aspect, the present application also provides a multi-metal composite fiber of a polymer fiber prepared by the above-mentioned multi-metal composite method.
基于上述技术方案，与现有技术相比，本申请的有益效果至少包括：Based on the above technical solution, compared with the existing technology, the beneficial effects of this application at least include:
本申请提供的高分子纤维材料的多金属复合方法利用氧化性酸和亲水剂的组合，刻蚀得到微蚀纤维，避免了高分子纤维的龟裂、无效刻蚀以及纤维团聚的现象，在高分子纤维表面构筑了形貌及粗糙度均适宜的表面微结构，极大地提高了多金属复合纤维中多金属复合层与高分子纤维的结合力以及多金属复合层的均匀性，同时，基于同样的原因，该刻蚀处理能够有效地避免高分子纤维的载荷损失，提高所制备的多金属复合的力学性能，为制备高品质的多金属复合纤维提供了一种切实有效的可行方案。The multi-metal composite method of polymer fiber materials provided by this application uses a combination of oxidizing acid and hydrophilic agent to etch micro-etched fibers, which avoids cracking, ineffective etching and fiber agglomeration of polymer fibers. The surface of the polymer fiber constructs a surface microstructure with suitable morphology and roughness, which greatly improves the binding force between the multi-metal composite layer and the polymer fiber in the multi-metal composite fiber and the uniformity of the multi-metal composite layer. At the same time, based on For the same reason, this etching treatment can effectively avoid the load loss of polymer fibers, improve the mechanical properties of the prepared multi-metal composites, and provide an effective and feasible solution for preparing high-quality multi-metal composite fibers.
上述说明仅是本申请技术方案的概述，为了能够使本领域技术人员能够更清楚地了解本申请的技术手段，并可依照说明书的内容予以实施，以下以本申请的较佳实施例并配合详细附图说明如后。The above description is only an overview of the technical solution of the present application. In order to enable those skilled in the art to understand the technical means of the present application more clearly and implement them in accordance with the contents of the specification, the following describes the preferred embodiments of the present application in conjunction with the detailed description. The description of the drawings is as follows.
附图说明Description of the drawings
图1是本申请一典型的实施案例提供的微蚀芳纶纤维的表面形貌图； Figure 1 is a surface morphology diagram of micro-etched aramid fiber provided in a typical implementation case of this application;
图2是本申请一典型的实施案例提供的经过化学镀镍芳纶纤维的宏观光学照片；Figure 2 is a macroscopic optical photo of an electroless nickel-plated aramid fiber provided in a typical implementation case of this application;
图3是本申请一典型的实施案例提供的经过化学镀镍芳纶纤维的低倍率电镜图；Figure 3 is a low-magnification electron microscope image of an electroless nickel-plated aramid fiber provided in a typical implementation case of this application;
图4是本申请一典型的实施案例提供的经过电镀铜的芳纶纤维的宏观光学照片；Figure 4 is a macroscopic optical photograph of aramid fiber electroplated with copper provided in a typical implementation case of this application;
图5是本申请一典型的实施案例提供的经过第一电镀的镍芳纶纤维的宏观光学照片；Figure 5 is a macroscopic optical photograph of the first electroplated nickel aramid fiber provided in a typical implementation case of this application;
图6是本申请一典型的实施案例提供的经过电镀银的芳纶纤维的宏观光学照片；Figure 6 is a macroscopic optical photograph of aramid fiber electroplated with silver provided in a typical implementation case of this application;
图7是本申请一典型的实施案例提供的多金属复合芳纶纤维的截面形貌图；Figure 7 is a cross-sectional morphology diagram of a multi-metal composite aramid fiber provided in a typical implementation case of this application;
图8是本申请一典型的实施案例提供的多金属复合芳纶纤维的径向元素分布图；Figure 8 is a radial element distribution diagram of a multi-metal composite aramid fiber provided in a typical implementation case of this application;
图9是本申请一典型的实施案例提供的多金属复合芳纶纤维的载荷保持率测试图；Figure 9 is a load retention rate test chart of multi-metal composite aramid fiber provided in a typical implementation case of this application;
图10是本申请一典型的实施案例提供的多金属(镍+铜)复合芳纶纤维制作的屏蔽套照片；Figure 10 is a photo of a shielding sleeve made of multi-metal (nickel + copper) composite aramid fiber provided in a typical implementation case of this application;
图11是本申请一典型的实施案例提供的用于制备多金属复合纤维的设备的部分结构示意图；Figure 11 is a partial structural schematic diagram of equipment for preparing multi-metal composite fibers provided in a typical implementation example of this application;
图12是本申请一典型的实施案例提供的用于制备多金属复合纤维的设备的部分结构示意图；Figure 12 is a partial structural schematic diagram of equipment for preparing multi-metal composite fibers provided in a typical implementation example of this application;
图13是本申请一典型的对比案例提供的刻蚀后的芳纶纤维表面形貌图；Figure 13 is a picture of the surface morphology of aramid fiber after etching provided by a typical comparative case of this application;
图14是本申请另一典型的对比案例提供的刻蚀后的芳纶纤维表面形貌图；Figure 14 is another typical comparative example of the etched aramid fiber surface morphology provided by this application;
图15是本申请又一典型的对比案例提供的刻蚀后的芳纶纤维表面形貌图；Figure 15 is another typical comparison case of the etched aramid fiber surface morphology provided by this application;
图16是本申请又一典型的对比案例提供的打结镀层脱落形貌图。Figure 16 is another typical comparative example of the peeling morphology of the knotted coating provided by this application.
具体实施方式Detailed ways
鉴于现有技术中的不足，本案发明人经长期研究和大量实践，得以提出本申请的技术方案。如下将对该技术方案、其实施过程及原理等作进一步的解释说明。In view of the deficiencies in the prior art, the inventor of this case was able to propose the technical solution of this application after long-term research and extensive practice. The technical solution, its implementation process and principles will be further explained below.
在下面的描述中阐述了很多具体细节以便于充分理解本申请，但是，本申请还可以采用其他不同于在此描述的方式来实施，因此，本申请的保护范围并不受下面公开的具体实施例的限制。Many specific details are set forth in the following description to fully understand the present application. However, the present application can also be implemented in other ways different from those described here. Therefore, the protection scope of the present application is not limited to the specific implementation disclosed below. Example limitations.
而且，诸如“第一”和“第二”等之类的关系术语仅仅用来将一个与另一个具有相同名称的部件或方法步骤区分开来，而不一定要求或者暗示这些部件或方法步骤之间存在任何这种实际的关系或者顺序。Furthermore, relative terms such as "first" and "second" are merely used to distinguish one component or method step from another with the same name and do not necessarily require or imply that such components or method steps are mutually exclusive. any such actual relationship or sequence exists between them.
参见图1-图6，本申请实施例提供的一种高分子纤维材料的多金属复合方法，包括如下的步骤：Referring to Figures 1-6, the embodiment of the present application provides a multi-metal composite method of polymer fiber materials, including the following steps:
使高分子纤维在包括氧化性酸、亲水剂的刻蚀液中进行刻蚀处理，得到微蚀纤维。 The polymer fiber is etched in an etching solution including an oxidizing acid and a hydrophilic agent to obtain a micro-etched fiber.
对所述微蚀纤维进行表面活化处理，得到活化纤维。The micro-etched fiber is subjected to surface activation treatment to obtain activated fiber.
在所述活化纤维表面沉积多金属复合层，其中，所述多金属复合层至少包括包覆于所述活化纤维表面的化学镀镍底层以及至少一电镀铜层。A multi-metal composite layer is deposited on the surface of the activated fiber, wherein the multi-metal composite layer at least includes an electroless nickel plating bottom layer and at least one electroplated copper layer covering the surface of the activated fiber.
基于上述技术方案，本申请所提供的多金属复合方法可以采用如下工序进行实施：放线、亲水、催化、解胶、镍硼化学镍、电镀铜，可选择的电镀镍、电镀银、电镀镍等，以及保护、烘干、收线。多金属复合层可以为：镍+铜层、镍+铜+镍层、镍+铜+镍+银层、镍+铜+镍+银+镍层。Based on the above technical solution, the multi-metal composite method provided by this application can be implemented by using the following processes: wire-laying, hydrophilicity, catalysis, degumming, nickel-boron chemical nickel, electroplating copper, and optional electroplating nickel, electroplating silver, electroplating Nickel, etc., as well as protection, drying, and take-up. The multi-metal composite layer can be: nickel+copper layer, nickel+copper+nickel layer, nickel+copper+nickel+silver layer, nickel+copper+nickel+silver+nickel layer.
在一些实施方式中，所述微蚀纤维表面刻蚀产生多个刻蚀沟槽，所述刻蚀沟槽的深度为30-50nm，宽度为300-500nm，所述微蚀纤维表面的粗糙度为0.1-0.5μm。In some embodiments, the micro-etched fiber surface is etched to produce a plurality of etched grooves. The depth of the etched grooves is 30-50 nm and the width is 300-500 nm. The roughness of the micro-etched fiber surface is is 0.1-0.5μm.
在一些实施方式中，所述氧化性酸包括硫酸和/或铬酸。In some embodiments, the oxidizing acid includes sulfuric acid and/or chromic acid.
在一些实施方式中，所述亲水剂包括十二烷基苯磺酸钠、十二烷基磺酸钠、聚乙二醇以及聚乙烯烷酮中的任意一种或两种以上的组合或直接可以外购，例如UDIQUE Etch Wetting Agent。In some embodiments, the hydrophilic agent includes any one or a combination of two or more of sodium dodecyl benzene sulfonate, sodium dodecyl sulfonate, polyethylene glycol and polyvinyl alkanone, or It can be purchased directly, such as UDIQUE Etch Wetting Agent.
在一些实施方式中，所述刻蚀液中，硫酸的含量为50-80mL/L，亲水剂的含量为2-5ml/L。In some embodiments, in the etching solution, the content of sulfuric acid is 50-80 mL/L, and the content of the hydrophilic agent is 2-5 ml/L.
在一些实施方式中，所述刻蚀液的温度为28-30℃，所述刻蚀处理的时间为4-7min。In some embodiments, the temperature of the etching solution is 28-30°C, and the etching treatment time is 4-7 minutes.
基于上述工艺条件，使得刻蚀处理的刻蚀作用温和，提升芳纶纤维亲水性，形成微蚀的芳纶表面，在保持纤维力学性能的同时为多金属复合层提供有效钩链与铆合点。作为一个典型的应用示例，某些实施案例中，刻蚀处理后的所述一种芳纶纤维的表面形貌如图1所示，并附如图13-图15所示的其他刻蚀处理方法的表面形貌作为对比。Based on the above process conditions, the etching effect of the etching treatment is mild, the hydrophilicity of the aramid fiber is improved, and a micro-etched aramid surface is formed, which maintains the mechanical properties of the fiber while providing effective hooks and riveting points for the multi-metal composite layer. . As a typical application example, in some implementation cases, the surface morphology of the aramid fiber after etching is shown in Figure 1, along with other etching treatments shown in Figures 13-15. The surface morphology of the method is used as a comparison.
在一些实施方式中，所述高分子纤维包括涤纶(聚对苯二甲酸己二酸酯醇，PET)、尼龙(聚酰胺纤维，Nylon)、丙纶(聚丙烯纤维)、芳纶(芳香族聚酰胺纤维)、超高分子聚乙烯(UHMWPE)、聚对苯撑苯并双恶唑纤维(PBO)、聚苯并咪唑(PBI)、聚酰亚胺纤维(PI)中的任意一种或两种以上的组合。其中，所述的组合可以是指多种纤维的混合编织或多种高分子原料的混合纺丝等组合方式。In some embodiments, the polymer fibers include polyester (polyadipate terephthalate, PET), nylon (polyamide fiber, Nylon), polypropylene (polypropylene fiber), aramid (aromatic polyester fiber) Any one or both of amide fiber), ultra-high molecular polyethylene (UHMWPE), poly-paraphenylene benzobisoxazole fiber (PBO), polybenzimidazole (PBI), polyimide fiber (PI) combinations of more than one species. The combination may refer to a combination such as mixed weaving of multiple fibers or mixed spinning of multiple polymer raw materials.
在一些实施方式中，所述表面活化处理包括催化步骤和解胶步骤。In some embodiments, the surface activation treatment includes a catalytic step and a degumming step.
在一些实施方式中，所述催化步骤包括：将所述微蚀纤维置于温度为25-33℃的催化液中处理3-6min，所述催化液包括浓度为2-5ml/L的含钯催化剂、浓度为200-300ml/L的37％的盐酸、浓度为40-60g/L的氯化钠以及浓度为2-4g/L的氯化亚锡。In some embodiments, the catalytic step includes: placing the micro-etched fiber in a catalytic liquid with a temperature of 25-33°C for 3-6 minutes, and the catalytic liquid includes palladium with a concentration of 2-5ml/L. Catalyst, 37% hydrochloric acid with a concentration of 200-300ml/L, sodium chloride with a concentration of 40-60g/L and stannous chloride with a concentration of 2-4g/L.
在一些实施方式中，所述含钯催化剂包括浓度为5-12g/L的氯化钯、浓度为120-260mL/L的盐酸、浓度为30-80g/L的氯化钠以及浓度为5-13g/L的氯化亚锡，或可以直接外购，例如UDIQUE 8710 ACTIVATOR。 In some embodiments, the palladium-containing catalyst includes palladium chloride at a concentration of 5-12 g/L, hydrochloric acid at a concentration of 120-260 mL/L, sodium chloride at a concentration of 30-80 g/L, and sodium chloride at a concentration of 5-12 g/L. 13g/L stannous chloride may be purchased directly, such as UDIQUE 8710 ACTIVATOR.
上述实施方案在芳纶纤维表面形成均匀覆盖具有双电层结构的胶体钯活性位点。In the above embodiment, colloidal palladium active sites with an electric double layer structure are uniformly covered on the surface of the aramid fiber.
在一些实施方式中，所述解胶步骤包括：将催化后的所述微蚀纤维置于温度为27-54℃的解胶液中处理30s-3min，所述解胶液包括浓度为15-25g/L的加速剂以及体积分数为1.6-2.6％的浓硫酸。In some embodiments, the degumming step includes: placing the catalyzed micro-etched fiber in a degumming solution with a temperature of 27-54°C for 30s-3 minutes, and the degumming solution includes a degumming solution with a concentration of 15-54°C. 25g/L accelerator and concentrated sulfuric acid with a volume fraction of 1.6-2.6%.
在一些实施方式中，所述加速剂包括浓度为150-300g/L的硫酸亚锡和/或硫酸锡溶液，或可直接外购，例如UDIQUE 887 DT。In some embodiments, the accelerator includes stannous sulfate and/or tin sulfate solution with a concentration of 150-300g/L, or can be purchased directly, such as UDIQUE 887 DT.
上述实施方案使胶体钯周围的二价锡离子溶解，使具有催化活性的金属钯裸露。The above embodiment dissolves the divalent tin ions around the colloidal palladium, exposing the catalytically active metallic palladium.
在一些实施方式中，所述高分子纤维选自多丝束芳纶，所述化学镀镍底层的沉积方法具体包括：将所述活化纤维置于温度为55-65℃的化学镍溶液中进行化学镀镍4-8min，所述化学镍溶液包括浓度为15-25g/L的六水合硫酸镍、浓度为2-5g/L的二甲胺硼烷、浓度为5-15g/L的柠檬酸、浓度为30-50mL/L的盐酸以及浓度为0.01-0.05g/L的二巯基苯并噻唑，并使用氨水调节所述化学镍溶液的pH为6.5-7.2。In some embodiments, the polymer fiber is selected from multi-filament aramid, and the deposition method of the electroless nickel plating bottom layer specifically includes: placing the activated fiber in an electroless nickel solution with a temperature of 55-65°C. Electroless nickel plating takes 4-8 minutes. The chemical nickel solution includes nickel sulfate hexahydrate with a concentration of 15-25g/L, dimethylamine borane with a concentration of 2-5g/L, and citric acid with a concentration of 5-15g/L. , hydrochloric acid with a concentration of 30-50mL/L and dimercaptobenzothiazole with a concentration of 0.01-0.05g/L, and using ammonia water to adjust the pH of the chemical nickel solution to 6.5-7.2.
多丝束的芳纶纤维在上述的镍硼体系的化学镍试剂中反应时，纤维丝束表面产生的气泡较多，有助于纤维丝束的分散，从而提升表面镀层均匀性。并且，该镍硼体系所形成的镍硼合金的结合力相比于其他种类的镍镀层更好，且镀层更加柔软。在一些示例中，如图2-图3所示。该化学镀镍底层在增加结合力的同时为后续电镀提供导电基础。When multi-strand aramid fibers react in the above-mentioned chemical nickel reagent of the nickel-boron system, more bubbles are generated on the surface of the fiber bundles, which helps to disperse the fiber bundles and thereby improves the uniformity of the surface coating. Moreover, the nickel-boron alloy formed by this nickel-boron system has better bonding strength than other types of nickel plating, and the plating is softer. In some examples, as shown in Figures 2-3. The electroless nickel plating bottom layer increases the bonding force and provides a conductive foundation for subsequent electroplating.
在一些实施方式中，所述多金属复合层还包括覆设于所述化学镀镍底层外表面的电镀铜层，所述电镀铜层的沉积方法具体包括：将所述包覆有所述化学镍底层的活化纤维置于温度为50-60℃的电镀铜溶液中电镀铜4-8min，其中，所述电镀铜溶液为碱性。In some embodiments, the multi-metal composite layer further includes an electroplated copper layer covering the outer surface of the electroless nickel plating bottom layer. The deposition method of the electroplated copper layer specifically includes: coating the electroplated copper layer with the chemical nickel plating layer. The activated fibers of the nickel bottom layer are placed in a copper electroplating solution with a temperature of 50-60°C for copper electroplating for 4-8 minutes, wherein the copper electroplating solution is alkaline.
芳纶纤维在碱性镀铜试剂中较酸性镀铜试剂中更容易分散，制备的镀铜芳纶丝束分散，镀层均匀。该镀铜层主要增加芳纶纤维的导电性，特别在用作电缆屏蔽层时，可降低转移阻抗。在一些示例中，该步骤所形成的多金属复合层的芳纶纤维如图4所示。Aramid fibers are easier to disperse in alkaline copper plating reagents than in acidic copper plating reagents. The prepared copper-plated aramid fiber tows are dispersed and the plating layer is uniform. The copper plating layer mainly increases the conductivity of the aramid fiber, especially when used as a cable shielding layer, it can reduce the transfer impedance. In some examples, the multi-metal composite layer of aramid fibers formed by this step is as shown in Figure 4.
在一些实施方式中，所述电镀铜溶液包括：浓度为250-290g/L的焦磷酸钾、浓度为59-88g/L的焦磷酸铜以及浓度为2-4mL/L的氨水，并调节所述电镀铜溶液的pH值为8.6-9.2。In some embodiments, the copper electroplating solution includes: potassium pyrophosphate with a concentration of 250-290 g/L, copper pyrophosphate with a concentration of 59-88 g/L, and ammonia water with a concentration of 2-4 mL/L, and is adjusted to The pH value of the copper electroplating solution is 8.6-9.2.
在一些实施方式中，所述电镀铜时采用的电流密度为1-6安培/平方分米。In some embodiments, the current density used during copper electroplating is 1-6 amperes/square decimeter.
在一些实施方式中，所述多金属复合层依次包括化学镀镍底层、电镀铜层、第一电镀镍层、电镀银层以及第二电镀镍层。In some embodiments, the multi-metal composite layer sequentially includes an electroless nickel plating bottom layer, an electroplated copper layer, a first electroplated nickel layer, an electroplated silver layer, and a second electroplated nickel layer.
在一些实施方式中，所述第一电镀镍层沉积方法包括：将电镀铜后的所述活化纤维置于温度为50-60℃的第一电镀镍溶液中电镀镍4-8min，所述第一电镀镍溶液包括：380-650mL/L的氨基磺酸镍、5.7-14g/L的氯化镍以及30-40g/L的硼酸，电镀时的电流密度为2-4安培/平方分米。 In some embodiments, the first electroplating nickel layer deposition method includes: placing the activated fiber after copper electroplating in a first electroplating nickel solution with a temperature of 50-60°C to electroplat nickel for 4-8 minutes, the The first nickel plating solution includes: 380-650mL/L nickel sulfamate, 5.7-14g/L nickel chloride and 30-40g/L boric acid. The current density during electroplating is 2-4 amps/square decimeter. .
在一些实施方式中，所述电镀银层的沉积方法包括：将覆设有第一电镀镍层的活化纤维置于温度为15-25℃的电镀银溶液中电镀银4-8min，所述电镀银溶液包括：浓度为15-40g/L的硝酸银、浓度为50-90g/L的5，5-二甲基乙内酰脲以及浓度为35-60g/L的氢氧化钾；所述电镀银溶液的pH值为8-10，温度为40-60℃，或者可以采用供应商提供的溶液方案：10-23.3g/L的Ecosilver Ag、60-100g/L的Ecosilver Cosalt以及200g/L的Ecosilver 210 Additive；所述电镀银的电流密度为2.5-5安培/平方分米。参见图5，银层可以进一步提升芳纶纤维的导电性，并且使多金属复合纤维具有良好的可焊性，便于电子元器件的连接。In some embodiments, the deposition method of the electroplated silver layer includes: placing the activated fiber covered with the first electroplated nickel layer in an electroplating silver solution with a temperature of 15-25°C for 4-8 minutes to electroplat silver. The silver solution includes: silver nitrate with a concentration of 15-40g/L, 5,5-dimethylhydantoin with a concentration of 50-90g/L, and potassium hydroxide with a concentration of 35-60g/L; the electroplating The pH value of the silver solution is 8-10 and the temperature is 40-60°C, or the solution solution provided by the supplier can be used: 10-23.3g/L Ecosilver Ag, 60-100g/L Ecosilver Cosalt and 200g/L Ecosilver 210 Additive; the current density of the electroplated silver is 2.5-5 amps/square decimeter. Referring to Figure 5, the silver layer can further improve the conductivity of the aramid fiber and make the multi-metal composite fiber have good weldability, which facilitates the connection of electronic components.
在一些实施方式中，所述第二电镀镍层沉积方法包括：将电镀银后的所述活化纤维置于温度为50-60℃的第二电镀镍溶液中电镀镍1-2min，所述第二电镀镍溶液包括：380-650mL/L的氨基磺酸镍、5.7-14g/L的氯化镍以及30-40g/L的硼酸，电镀时的电流密度为1-2安培/平方分米。In some embodiments, the second electroplating nickel layer deposition method includes: placing the silver electroplated activated fiber in a second electroplating nickel solution at a temperature of 50-60°C for 1-2 minutes to electroplat nickel, The second electroplating nickel solution includes: 380-650mL/L nickel sulfamate, 5.7-14g/L nickel chloride and 30-40g/L boric acid. The current density during electroplating is 1-2 ampere/square decimeter. .
当多金属复合层为镍+铜+镍层时，所述的第一电镀镍层可以作为保护层，使多金属复合纤维满足环境适应性等要求；当金属复合层为镍+铜+镍+银层时，所述的第一电镀镍层可以作为过渡层，保证电镀银层的良好附着，提升产品稳定性。同时参见图6，第二电镀镍层作为电镀银层的保护层，进一步提升产品环境耐受性。镍金属具有良好的电磁屏蔽性能，在一些实际应用中，可调节镍金属复合比例，使产品满足不同电磁环境下的服役需求。When the multi-metal composite layer is a nickel+copper+nickel layer, the first electroplated nickel layer can be used as a protective layer to make the multi-metal composite fiber meet environmental adaptability and other requirements; when the metal composite layer is nickel+copper+nickel+ When adding a silver layer, the first electroplated nickel layer can be used as a transition layer to ensure good adhesion of the electroplated silver layer and improve product stability. Also referring to Figure 6, the second electroplated nickel layer serves as a protective layer for the electroplated silver layer, further improving the environmental tolerance of the product. Nickel metal has good electromagnetic shielding properties. In some practical applications, the compound proportion of nickel metal can be adjusted so that the product can meet the service requirements in different electromagnetic environments.
在一些实施方式中，电镀时，实时计算所述高分子纤维及其镀层的电阻，具体的，可以根据电源的输出电压以及电镀电流计算电镀中的所述高分子纤维的电阻；当所述电阻大于第一预设阈值时，控制电源提高所述电镀电流，当所述电阻小于第二预设阈值时，控制电源降低所述电镀电流。In some embodiments, during electroplating, the resistance of the polymer fiber and its coating is calculated in real time. Specifically, the resistance of the polymer fiber during electroplating can be calculated based on the output voltage of the power supply and the plating current; when the resistance When the resistance is greater than the first preset threshold, the power supply is controlled to increase the plating current; when the resistance is less than the second preset threshold, the power supply is controlled to reduce the plating current.
在一些实施方式中，电镀中，多个所述高分子纤维单独配制电源并独立控制多个所述电源的电流。由于高分子纤维，尤其是芳纶的原材料差异性以及前处理工序各通道的差异性，导致各通道芳纶经化学镍处理后电阻存在差异。为解决上述问题，本申请在各电镀通道采用多通道独立配制电极以及电源的方式进行电镀。In some embodiments, during electroplating, a plurality of the polymer fibers separately prepare a power supply and independently control the current of a plurality of the power supplies. Due to the differences in the raw materials of polymer fibers, especially aramid fiber, and the differences in each channel in the pre-treatment process, the resistance of aramid fiber in each channel after chemical nickel treatment is different. In order to solve the above problems, this application adopts a multi-channel independent preparation of electrodes and power sources for electroplating in each electroplating channel.
以芳纶的多金属复合为例，实际生产中，采用多通道共用子母槽的方法进行生产，而由于芳纶纤维的原材料、前处理各通道存在差异性，导致各通道的芳纶经化学镀镍后的电阻存在差异。为提升产品稳定性，本申请采用多通道制备导电芳纶纤维，可根据生产需求，独立地控制各通道电流大小，实现多通道均匀制备或多通道多规格制备。电镀工位多通道电极及子槽结构如图11、图12所示。Take the multi-metal composite of aramid fibers as an example. In actual production, multiple channels share a mother-sub-trough method for production. However, due to the differences in the raw materials and pre-treatment of aramid fibers in each channel, the aramid fibers in each channel are chemically processed. There is a difference in resistance after nickel plating. In order to improve product stability, this application uses multi-channel preparation of conductive aramid fibers. The current size of each channel can be independently controlled according to production needs to achieve uniform preparation of multi-channels or preparation of multi-channels and multiple specifications. The multi-channel electrode and sub-tank structures of the electroplating station are shown in Figures 11 and 12.
图中，1、2、3、4为四组独立导电的铜导电阴极，中间用绝缘传动轴5固定；各组电极侧面分别安装导电柱6，导电柱上配有与铜导电阴极相连的导电电刷7、接线端口8，辅以导 线与可外控直流电源负极相连；各组铜导电阴极共用绝缘压辊9，以确保纤维与电极导电接触良好；电极另配有传动齿轮10、陶瓷轴承11。12、13、14、15为铺设在子槽底部相互独立阳极钛篮，对应的16、17、18、19为接线端口，辅以导线与可外控直流电源正极相连。在工作时，分别与铜导电阴极1、2、3、4形成一组导电回路。每组导电回路上施加的电流值根据各纤维的电阻或镀层厚度设置。上述可外控直流电源信号源均接入PLC，实现PLC可编程远控。In the figure, 1, 2, 3, and 4 are four sets of independently conductive copper conductive cathodes, fixed with an insulated transmission shaft 5 in the middle; conductive posts 6 are installed on the sides of each set of electrodes, and the conductive posts are equipped with conductive poles connected to the copper conductive cathodes. Brush 7, wiring port 8, supplemented by guide The wire is connected to the negative pole of the externally controllable DC power supply; each group of copper conductive cathodes shares an insulating pressure roller 9 to ensure good conductive contact between the fiber and the electrode; the electrode is also equipped with a transmission gear 10 and a ceramic bearing 11. 12, 13, 14, and 15 are Independent anode titanium baskets are laid at the bottom of the sub-trough, and the corresponding 16, 17, 18, and 19 are wiring ports, supplemented by wires to connect to the positive pole of the externally controllable DC power supply. During operation, they form a set of conductive circuits with the copper conductive cathodes 1, 2, 3, and 4 respectively. The value of the current applied on each set of conductive loops is set based on the resistance or plating thickness of each fiber. The above-mentioned externally controllable DC power signal sources are all connected to the PLC to realize PLC programmable remote control.
上述实例性的电镀设备各通道阴极相互独立，相互之间无干扰；并且可以通过直流电源显示的电压V，电流A，应用公式R＝V/A计算产品在电镀各工序中的电阻情况。预设各规格产品在不同工序中的电阻值，可控直流电源选用恒压输出模式，通过PLC远程智能控制连续生产中各通道电流大小，从而实现可控生产。当电阻值增大时，PLC根据公式增加输出电流；当电阻值减小时，PLC根据公式降低输出电流。The cathodes of each channel of the above-mentioned example electroplating equipment are independent of each other and have no interference with each other; and the voltage V and current A displayed by the DC power supply can be used to calculate the resistance of the product in each electroplating process using the formula R=V/A. The resistance values of products of various specifications in different processes are preset. The controllable DC power supply adopts constant voltage output mode, and the current of each channel in continuous production is remotely controlled through PLC, thereby achieving controllable production. When the resistance value increases, the PLC increases the output current according to the formula; when the resistance value decreases, the PLC decreases the output current according to the formula.
在一些实施方式中，还包括在多金属复合层表面形成保护层的步骤。并且，作为一个具体的应用示例，上述保护层可以采用如下的方法形成：设备配制：上下子母槽、上水管道具有过滤装置、恒温装置。工艺条件：子槽试剂每10分钟循环5次，温度45-55℃，处理时间5s-1min。保护剂采购于上海择势化学科技有限公司，保护剂名称：Silverguard 290 100-200mL/L。该保护剂不含重金属和有机溶剂，可改善可焊性，防腐性能较好。In some embodiments, the step of forming a protective layer on the surface of the multi-metal composite layer is also included. Moreover, as a specific application example, the above-mentioned protective layer can be formed by the following method: Equipment preparation: the upper and lower sub-troughs and water supply pipes are equipped with filtering devices and constant temperature devices. Process conditions: The sub-tank reagent is circulated 5 times every 10 minutes, the temperature is 45-55°C, and the processing time is 5s-1min. The protective agent was purchased from Shanghai Zeshi Chemical Technology Co., Ltd. The protective agent name: Silverguard 290 100-200mL/L. This protective agent does not contain heavy metals and organic solvents, can improve weldability, and has good anti-corrosion properties.
上述实施方案所制备的多金属复合纤维还可以在温度为90-120℃，时间为3-5min条件下烘干，烘干有助于上述多金属复合纤维的保存，当然，上述多金属复合纤维的烘干条件可以根据需求及环境的不同，适当地调整为其他条件。此外，本申请实施例提供的高分子纤维材料的多金属复合方法还包括放线和收线工序，放线和收线设备配有角度传感器，放线和收线速度可以根据生产速度自动匹配。The multi-metal composite fiber prepared in the above embodiment can also be dried at a temperature of 90-120°C and a time of 3-5 minutes. Drying is helpful for the preservation of the above-mentioned multi-metal composite fiber. Of course, the above-mentioned multi-metal composite fiber The drying conditions can be appropriately adjusted to other conditions according to different needs and environments. In addition, the multi-metal composite method of polymer fiber materials provided in the embodiments of the present application also includes a pay-off and take-up process. The pay-off and take-up equipment is equipped with an angle sensor, and the pay-off and take-up speeds can be automatically matched according to the production speed.
上述各工序所采用的设备均可以是上下子母槽、上水管道内设置过滤装置、并设置恒温装置控制子母槽中的温度，并且，子槽中的溶液或分散液均不断循环，其循环量可以根据实际情况控制为每10分钟循环2-8次。The equipment used in each of the above processes can be an upper and lower sub-tank, a filter device in the upper water pipe, and a thermostatic device to control the temperature in the sub-tank, and the solution or dispersion in the sub-tank is continuously circulated. The amount can be controlled to cycle 2-8 times every 10 minutes according to the actual situation.
参见图7-图8，本申请实施例还提供上述多金属复合方法制备得到的高分子纤维的多金属复合纤维。Referring to Figures 7-8, embodiments of the present application also provide multi-metal composite fibers of polymer fibers prepared by the above-mentioned multi-metal composite method.
以下通过若干实施例并结合附图进一步详细说明本申请的技术方案。然而，所选的实施例仅用于说明本申请，而不限制本申请的范围。The technical solution of the present application will be further described in detail below through several embodiments and in conjunction with the accompanying drawings. However, the selected embodiments are merely illustrative of the present application and do not limit the scope of the present application.
实施例1Example 1
本实施例提供一种芳纶纤维的多金属复合方法，具体包括如下的步骤：This embodiment provides a multi-metal composite method for aramid fibers, which specifically includes the following steps:
刻蚀：将多卷芳纶纤维放置于放线器上，使其进入刻蚀工序，在刻蚀工序，利用子母槽 装置，控制刻蚀液温度为30℃，子槽循环量为每10分钟循环5次，芳纶纤维行进速度使得该芳纶纤维在刻蚀液中的刻蚀处理时间为4min，该刻蚀液的成分及含量为：浓硫酸为80ml/L，亲水剂UDIQUE Etch Wetting Agent(主要成分为十二烷基苯磺酸钠、十二烷基磺酸钠、聚乙二醇或者是聚乙烯烷酮的浓缩液)为5％；该步骤刻蚀处理得到的微蚀纤维的表面形貌如图1所示，其表面过度刻蚀导致的起泡、脱皮现象，更无纤维破裂现象，表面微结构良好，适宜于后续的多金属层复合等工序；Etching: Place multiple rolls of aramid fiber on the pay-off device and let it enter the etching process. In the etching process, use the mother-and-son groove Device, control the temperature of the etching solution to 30°C, the sub-tank circulation volume is 5 cycles every 10 minutes, and the traveling speed of the aramid fiber makes the etching treatment time of the aramid fiber in the etching solution to be 4 minutes. The etching solution The ingredients and content are: concentrated sulfuric acid is 80ml/L, hydrophilic agent UDIQUE Etch Wetting Agent (the main ingredients are sodium dodecyl benzene sulfonate, sodium dodecyl sulfonate, polyethylene glycol or polyethylene glycol The concentration of ketone) is 5%; the surface morphology of the micro-etched fiber obtained by etching in this step is shown in Figure 1. The blistering and peeling phenomena caused by excessive etching on the surface do not cause fiber rupture, and the surface micro-etching The structure is good and suitable for subsequent multi-metal layer composite processes;
表面活化：包括催化步骤和解胶步骤，上述刻蚀结束后的芳纶纤维继续依次进入承载有催化液和解胶液的子母槽中，催化液子槽每10分钟循环2次，解胶液子槽每10分钟循环5次，催化液温度控制为25℃，催化时间为6min，解胶液温度控制为54℃，解胶时间为30s；该步骤中，催化液为：氯化钯为10g/L，盐酸(37％)为200mL/L，氯化钠为50g/L，氯化亚锡为4g/L，解胶液组成及含量为：UDIQUE 887 DT加速剂为15g/L，浓H2SO4为2.6％；Surface activation: including the catalytic step and the degumming step. After the above etching, the aramid fiber continues to enter the sub-trough carrying the catalytic liquid and degumming liquid. The catalytic liquid sub-tank circulates twice every 10 minutes, and the degumming liquid sub-trough The tank circulates 5 times every 10 minutes. The catalytic liquid temperature is controlled at 25°C, the catalytic time is 6 minutes, the degumming liquid temperature is controlled at 54°C, and the degumming time is 30s; in this step, the catalytic liquid is: palladium chloride is 10g/ L, hydrochloric acid (37%) is 200mL/L, sodium chloride is 50g/L, stannous chloride is 4g/L, the composition and content of the degumming solution are: UDIQUE 887 DT accelerator is 15g/L, concentrated H 2 SO 4 is 2.6%;
化学镀镍：采用镍硼体系的化学镀镍，该步骤采用上下子母槽装置、上水管道内设置过滤装置、并设置恒温装置控制化学镍液的温度；工艺条件为：子槽试剂每10分钟循环8次、温度为60℃，处理时间6min；化学镍的组成及含量为：六水合硫酸镍25g/L，二甲胺硼烷5g/L，柠檬酸15g/L，盐酸40mL/L，二巯基苯并噻0.01g/L，并使用氨水调节pH至7.2；Electroless nickel plating: Electroless nickel plating using nickel boron system. This step uses upper and lower sub-tank devices, a filter device in the water supply pipe, and a thermostatic device to control the temperature of the chemical nickel liquid; the process conditions are: sub-tank reagents every 10 minutes Cycle 8 times, the temperature is 60°C, and the treatment time is 6 minutes; the composition and content of chemical nickel are: nickel sulfate hexahydrate 25g/L, dimethylamine borane 5g/L, citric acid 15g/L, hydrochloric acid 40mL/L, dimethyl sulfate Mercaptobenzothiene 0.01g/L, and use ammonia to adjust pH to 7.2;
电镀铜：该步骤采用上下子母槽装置、上水管道内设置过滤装置、并设置恒温装置控制电镀铜溶液的温度；工艺条件为：子槽试剂每10分钟循环5次、温度为55℃，电镀时间8min；电镀铜溶液的组成及含量为：焦磷酸钾250g/L，焦磷酸铜59g/L，使用氨水调节pH为8.6，电镀铜的电流密度1安培/平方分米；Electroplating copper: This step uses an upper and lower sub-tank device, a filter device in the water supply pipe, and a constant temperature device to control the temperature of the electroplating copper solution; the process conditions are: the sub-tank reagents are circulated 5 times every 10 minutes, the temperature is 55°C, and the electroplating The time is 8 minutes; the composition and content of the copper electroplating solution are: potassium pyrophosphate 250g/L, copper pyrophosphate 59g/L, use ammonia to adjust the pH to 8.6, and the current density of copper electroplating is 1 ampere/square decimeter;
第一电镀镍：该步骤采用上下子母槽装置、上水管道内设置过滤装置、并设置恒温装置控制电镀镍溶液的温度；工艺条件：子槽试剂每10分钟循环5次、温度为60℃，电镀时间6min。试剂组成：氨基磺酸镍500mL/L，氯化镍10g/L，硼酸30g/L，电流密度2安培/平方分米；First nickel plating: This step uses an upper and lower sub-tank device, a filter device in the water supply pipe, and a thermostatic device to control the temperature of the nickel plating solution; process conditions: the sub-tank reagents are circulated 5 times every 10 minutes, and the temperature is 60°C. Plating time is 6 minutes. Reagent composition: nickel sulfamate 500mL/L, nickel chloride 10g/L, boric acid 30g/L, current density 2 ampere/square decimeter;
电镀银：该步骤采用上下子母槽装置、上水管道内设置过滤装置、并设置恒温装置控制电镀银溶液的温度；工艺条件为：子槽试剂每10分钟循环5次、温度为20℃，电镀时间6min。试剂采购于上海择势化学科技有限公司，试剂组成：Ecosilver Ag 20g/L，Ecosilver Cosalt 80g/L，Ecosilver 210 Additive 200g/L，电流密度为4安培/平方分米；Silver electroplating: This step uses an upper and lower sub-tank device, a filter device in the water supply pipe, and a constant temperature device to control the temperature of the electroplating silver solution; the process conditions are: the sub-tank reagents are circulated 5 times every 10 minutes, the temperature is 20°C, and the electroplating Time 6min. The reagents were purchased from Shanghai Zeshi Chemical Technology Co., Ltd. The reagent composition is: Ecosilver Ag 20g/L, Ecosilver Cosalt 80g/L, Ecosilver 210 Additive 200g/L, and the current density is 4 amps/square decimeter;
第二电镀镍：该步骤所用设备的结构以及试剂组成及工艺条件与第一电镀镍相同，区别仅在于，电镀的时间为1.5min，电流密度为1.5安培/平方分米；Second nickel electroplating: The structure of the equipment, reagent composition and process conditions used in this step are the same as those of the first nickel electroplating. The only difference is that the electroplating time is 1.5 minutes and the current density is 1.5 amps/square decimeter;
本实施例所提供的多金属复合方法所制备的芳纶纤维的复合前后的载荷变化如图9所示，相比于其他复合方法，本申请实施例所提供的复合方法对芳纶纤维的损伤极小，芳纶的载荷 损失低，有利于提供高品质的多金属复合纤维，受芳纶原纤维直径差异的影响，金属复合处理后的纤维镀层厚度表征可靠度低，误差较大，因此通过分析统计多组多金属复合纤维线密度得出均匀性，及单位长度金属所占多金属复合纤维质量(金属质量+芳纶原纤维质量)的百分数，随机测试五组数据，其镀层质量分数的CV值为5.44％。The load changes of the aramid fiber prepared by the multi-metal composite method provided in this embodiment before and after composite are shown in Figure 9. Compared with other composite methods, the composite method provided by the embodiment of this application causes damage to the aramid fiber. Extremely small, aramid load Low loss is conducive to providing high-quality multi-metal composite fibers. Affected by the difference in diameter of aramid fibrils, the reliability of the fiber coating thickness characterization after metal composite treatment is low and the error is large. Therefore, multiple groups of multi-metal composites are analyzed and counted. The uniformity of fiber linear density and the percentage of multi-metal composite fiber mass (metal mass + aramid fibril mass) occupied by metal per unit length were obtained. Five sets of data were randomly tested, and the CV value of the coating mass fraction was 5.44%.
实施例2Example 2
本实施例提供一种芳纶纤维的多金属复合方法，与实施例1基本相同，区别仅在于：This embodiment provides a multi-metal composite method for aramid fibers, which is basically the same as Embodiment 1, with the only difference being:
省略第一电镀镍、电镀银以及第二电镀镍步骤，多金属复合层的组成仅仅为化学镍底层+电镀铜层。The first nickel electroplating, silver electroplating and second nickel electroplating steps are omitted, and the composition of the multi-metal composite layer is only an electroless nickel bottom layer + an electroplated copper layer.
本实施例所提供的多金属复合纤维可以用于制作电缆屏蔽套，其成品图片如图10所示。The multi-metal composite fiber provided in this embodiment can be used to make a cable shielding sleeve, and a picture of the finished product is shown in Figure 10.
实施例3Example 3
本实施例提供一种芳纶纤维的多金属复合方法，与实施例1基本相同，区别仅在于：This embodiment provides a multi-metal composite method for aramid fibers, which is basically the same as Embodiment 1, with the only difference being:
刻蚀：刻蚀液温度为28℃，芳纶纤维行进速度使得该芳纶纤维在刻蚀液中的刻蚀处理时间为7min，该刻蚀液的成分及含量为：浓硫酸为50ml/L，外购亲水剂UDIQUE Etch Wetting Agent为2％；Etching: The temperature of the etching liquid is 28°C. The traveling speed of the aramid fiber makes the etching treatment time of the aramid fiber in the etching liquid 7 minutes. The composition and content of the etching liquid are: concentrated sulfuric acid is 50ml/L. , the outsourced hydrophilic agent UDIQUE Etch Wetting Agent is 2%;
表面活化：催化液温度控制为33℃，催化时间为3min，解胶液温度控制为27℃，解胶时间为3min；该步骤中，催化液为：同公司产品UDIQUE 8710 ACTIVATOR为5mL/L，盐酸(37％)为300mL/L，氯化钠为40g/L，氯化亚锡为2g/L，解胶液组成及含量为：UDIQUE 887 DT加速剂为25g/L，浓H2SO4为1.6％；Surface activation: the temperature of the catalytic liquid is controlled at 33°C, the catalytic time is 3 minutes, the temperature of the degumming liquid is controlled at 27°C, and the degumming time is 3 minutes; in this step, the catalytic liquid is: the same company's product UDIQUE 8710 ACTIVATOR is 5mL/L, Hydrochloric acid (37%) is 300mL/L, sodium chloride is 40g/L, stannous chloride is 2g/L, the composition and content of the degumming solution are: UDIQUE 887 DT accelerator is 25g/L, concentrated H 2 SO 4 is 1.6%;
化学镀镍：温度为55℃，处理时间4min；化学镍的组成及含量为：六水合硫酸镍15g/L，二甲胺硼烷2g/L，柠檬酸5g/L，盐酸50mL/L，二巯基苯并噻0.01g/L，并使用氨水调节pH至6.5；Electroless nickel plating: temperature is 55°C, processing time is 4 minutes; the composition and content of chemical nickel are: nickel sulfate hexahydrate 15g/L, dimethylamine borane 2g/L, citric acid 5g/L, hydrochloric acid 50mL/L, dimethyl sulfate Mercaptobenzothiene 0.01g/L, and use ammonia to adjust pH to 6.5;
电镀铜：温度为60℃，电镀时间4min电镀铜溶液的组成及含量为：焦磷酸钾270g/L，焦磷酸铜88g/L，使用氨水调节pH为8.6-9.2之间，电镀铜的电流密度6安培/平方分米；Electroplating copper: The temperature is 60°C, the electroplating time is 4 minutes, the composition and content of the electroplating copper solution are: potassium pyrophosphate 270g/L, copper pyrophosphate 88g/L, use ammonia to adjust the pH to between 8.6-9.2, the current density of electroplated copper 6 amps/dm2;
第一电镀镍：温度为50℃，电镀时间4min。试剂组成：氨基磺酸镍650mL/L，氯化镍5.7g/L，硼酸40g/L，电流密度4安培/平方分米；First nickel plating: temperature is 50°C, plating time is 4 minutes. Reagent composition: nickel sulfamate 650mL/L, nickel chloride 5.7g/L, boric acid 40g/L, current density 4 amps/square decimeter;
电镀银：温度为15℃，电镀时间8min。试剂采购于上海择势化学科技有限公司，试剂组成：Ecosilver Ag 10g/L，Ecosilver Cosalt 60g/L，Ecosilver 210 Additive 200g/L，电流密度为2.5安培/平方分米；Silver plating: temperature is 15℃, plating time is 8 minutes. The reagents were purchased from Shanghai Zeshi Chemical Technology Co., Ltd. The reagent composition is: Ecosilver Ag 10g/L, Ecosilver Cosalt 60g/L, Ecosilver 210 Additive 200g/L, and the current density is 2.5 amps/square decimeter;
第二电镀镍：该步骤所用设备的结构以及试剂组成及工艺条件与本实施例中的第一电镀镍相同，区别仅在于，时间为1min，电流密度为2安培/平方分米。Second nickel electroplating: The structure of the equipment, reagent composition and process conditions used in this step are the same as those of the first nickel electroplating in this embodiment. The only difference is that the time is 1 minute and the current density is 2 amperes/square decimeter.
所制备的多金属复合芳纶与实施例1中具有相似的导电性质及载荷保持率。 The prepared multi-metal composite aramid fiber has similar conductive properties and load retention rate to those in Example 1.
实施例4Example 4
本实施例提供一种芳纶纤维的多金属复合方法，与实施例1基本相同，区别仅在于：This embodiment provides a multi-metal composite method for aramid fibers, which is basically the same as Embodiment 1, with the only difference being:
刻蚀：刻蚀液温度为30℃，子槽循环量为每10分钟循环5次，芳纶纤维行进速度使得该芳纶纤维在刻蚀液中的刻蚀处理时间为5min，该刻蚀液的成分及含量为：浓硫酸为70ml/L，购亲水剂UDIQUE Etch Wetting Agent为4ml/L；Etching: The temperature of the etching liquid is 30°C, the circulation volume of the sub-tank is 5 times every 10 minutes, and the traveling speed of the aramid fiber is such that the etching treatment time of the aramid fiber in the etching liquid is 5 minutes. The etching liquid The ingredients and content are: concentrated sulfuric acid is 70ml/L, and the purchased hydrophilic agent UDIQUE Etch Wetting Agent is 4ml/L;
表面活化：催化液温度控制为29℃，催化时间为4min，解胶液温度控制为35℃，解胶时间为2min；该步骤中，催化液为：同公司产品UDIQUE 8710 ACTIVATOR为3mL/L，盐酸(37％)为250mL/L，氯化钠为60g/L，氯化亚锡为3g/L，解胶液组成及含量为：UDIQUE 887 DT加速剂为21g/L，浓H25O4为2.0％；Surface activation: the temperature of the catalytic liquid is controlled at 29°C, the catalytic time is 4 minutes, the temperature of the degumming liquid is controlled at 35°C, and the degumming time is 2 minutes; in this step, the catalytic liquid is: the same company's product UDIQUE 8710 ACTIVATOR is 3mL/L, Hydrochloric acid (37%) is 250mL/L, sodium chloride is 60g/L, stannous chloride is 3g/L, the composition and content of the degumming solution are: UDIQUE 887 DT accelerator is 21g/L, concentrated H 2 5O 4 is 2.0%;
化学镀镍：温度为65℃，处理时间8min；化学镍的组成及含量为：六水合硫酸镍17g/L，二甲胺硼烷4g/L，柠檬酸10g/L，盐酸30mL/L，二巯基苯并噻0.01g/L，并使用氨水调节pH至7.0；Electroless nickel plating: temperature is 65°C, processing time is 8 minutes; the composition and content of chemical nickel are: nickel sulfate hexahydrate 17g/L, dimethylamine borane 4g/L, citric acid 10g/L, hydrochloric acid 30mL/L, dimethyl sulfate Mercaptobenzothiene 0.01g/L, and use ammonia to adjust pH to 7.0;
电镀铜：温度为50℃，电镀时间6min电镀铜溶液的组成及含量为：焦磷酸钾290g/L，焦磷酸铜66g/L，使用4ml/L氨水调节pH为9.2之间，电镀铜的电流密度3安培/平方分米；Electroplating copper: The temperature is 50°C, the electroplating time is 6 minutes, the composition and content of the electroplating copper solution are: potassium pyrophosphate 290g/L, copper pyrophosphate 66g/L, use 4ml/L ammonia to adjust the pH to 9.2, the current for electroplating copper Density 3 amperes/square decimeter;
第一电镀镍：温度为55℃，电镀时间8min。试剂组成：氨基磺酸镍380mL/L，氯化镍14g/L，硼酸33g/L，电流密度3安培/平方分米；The first nickel plating: temperature is 55℃, plating time is 8 minutes. Reagent composition: nickel sulfamate 380mL/L, nickel chloride 14g/L, boric acid 33g/L, current density 3 ampere/square decimeter;
电镀银：温度为25℃，电镀时间4min。试剂采购于上海择势化学科技有限公司，试剂组成：Ecosilver Ag 23g/L，Ecosilver Cosalt 100g/L，Ecosilver 210 Additive 200g/L，电流密度为5安培/平方分米；Silver plating: temperature is 25℃, plating time is 4 minutes. The reagents were purchased from Shanghai Zeshi Chemical Technology Co., Ltd. The reagent composition is: Ecosilver Ag 23g/L, Ecosilver Cosalt 100g/L, Ecosilver 210 Additive 200g/L, and the current density is 5 amps/square decimeter;
第二电镀镍：该步骤所用设备的结构以及试剂组成及工艺条件与本实施例中的第一电镀镍相同，区别仅在于，时间为2min，电流密度为1安培/平方分米。Second nickel electroplating: The structure of the equipment, reagent composition, and process conditions used in this step are the same as those of the first nickel electroplating in this embodiment. The only difference is that the time is 2 minutes and the current density is 1 ampere/square decimeter.
所制备的多金属复合芳纶与实施例1中具有相似的导电性质及载荷保持率。The prepared multi-metal composite aramid fiber has similar conductive properties and load retention rate to those in Example 1.
实施例5Example 5
本实施例与实施例1基本相同，区别仅在于：This embodiment is basically the same as Embodiment 1, the only difference is:
使用多丝束的尼龙纤维作为基础纤维进行多金属复合，同样可以获得导线性质与载荷保持率相似的多金属复合高分子纤维。Using multi-strand nylon fiber as the basic fiber for multi-metal composites, multi-metal composite polymer fibers with similar conductor properties and load retention rates can also be obtained.
实施例6Example 6
本实施例与实施例1基本相同，区别仅在于：This embodiment is basically the same as Embodiment 1, the only difference is:
使用多丝束的PBO纤维作为基础纤维进行多金属复合，同样可以获得导线性质与载荷保持率相似的多金属复合高分子纤维。Using multi-strand PBO fiber as the basic fiber for multi-metal composite, multi-metal composite polymer fiber with similar conductor properties and load retention rate can also be obtained.
实施例7 Example 7
本实施例与实施例1基本相同，区别仅在于：This embodiment is basically the same as Embodiment 1, the only difference is:
使用多丝束的PI纤维作为基础纤维进行多金属复合，同样可以获得导线性质与载荷保持率相似的多金属复合高分子纤维。Using multi-strand PI fiber as the basic fiber for multi-metal composite, multi-metal composite polymer fiber with similar conductor properties and load retention rate can also be obtained.
对比例1Comparative example 1
本对比例与实施例1基本相同，区别仅在于，刻蚀液的组成为：三氧化铬为40g/L、浓硫酸为20mL/L，其刻蚀后的芳纶表面形貌如图13所示，表面出现大量的起皮、空泡现象，不利于后续的多金属复合，并且，经过多金属复合后，其载荷保持率为76％，显著低于实施例1。This comparative example is basically the same as Example 1. The only difference is that the composition of the etching solution is: 40g/L of chromium trioxide and 20mL/L of concentrated sulfuric acid. The surface morphology of the aramid fiber after etching is as shown in Figure 13 It shows that there is a lot of peeling and cavitation on the surface, which is not conducive to the subsequent multi-metal composite. Moreover, after multi-metal composite, the load retention rate is 76%, which is significantly lower than that of Example 1.
对比例2Comparative example 2
本对比例与实施例1基本相同，区别仅在于，刻蚀液的组成为：600mL/L的浓硫酸，其刻蚀后的芳纶表面形貌如图14所示，表面出现大量的芳纶纤维丝束开裂，无法继续进行多金属层的复合，并且，其纤维的载荷保持率为45％，显著低于实施例1。This comparative example is basically the same as Example 1. The only difference is that the composition of the etching solution is: 600 mL/L concentrated sulfuric acid. The surface morphology of the aramid fiber after etching is shown in Figure 14. A large number of aramid fiber appears on the surface. The fiber bundles cracked, and the composite of multi-metal layers could not be continued. Moreover, the load retention rate of the fibers was 45%, which was significantly lower than that of Example 1.
对比例3Comparative example 3
本对比例与实施例1基本相同，区别仅在于，刻蚀液的组成为：80mL/L浓硫酸，其刻蚀后的芳纶表面形貌如图15所示，其表面无有效的刻蚀，不利于后续的多金属复合，并且，虽然经过多金属复合后，其载荷保持率与实施例1相似，甚至略微高于实施例1，但是，在进行如图3所示的在打结后，其多金属复合层极其容易脱落，其打结后的镀层脱落状态如图16所示，说明该对比例提供的多金属复合层与芳纶纤维的结合力显著低于实施例1，该对比例中的多金属复合芳纶虽然载荷未发生较大损失，但多金属层过于容易脱落，无法满足编织屏蔽套等应用需求。This comparative example is basically the same as Example 1. The only difference is that the composition of the etching solution is: 80mL/L concentrated sulfuric acid. The surface morphology of the aramid fiber after etching is shown in Figure 15. There is no effective etching on the surface. , is not conducive to subsequent multi-metal composites, and although after multi-metal composites, the load retention rate is similar to that of Example 1, or even slightly higher than that of Example 1, however, after knotting as shown in Figure 3 , the multi-metal composite layer is extremely easy to fall off, and the peeling off state of the plating after knotting is shown in Figure 16, indicating that the binding force between the multi-metal composite layer and the aramid fiber provided by this comparative example is significantly lower than that of Example 1. Although the multi-metal composite aramid fiber in the proportion does not suffer a large loss in load, the multi-metal layer is too easy to fall off and cannot meet the needs of applications such as braided shielding sleeves.
对比例4Comparative example 4
本对比例与实施例1基本相同，区别仅在于，使用镍磷体系进行化学镀镍，具体条件为：六水合硫酸镍15g/L，次亚磷酸钠20g/L，乳酸25mL/L，硫脲0.3g/L，温度90℃，pH值4.5，芳纶纤维表面气泡较少，该对比例所制备的多金属复合芳纶极易出现镀层漏镀的现象。This comparative example is basically the same as Example 1. The only difference is that a nickel-phosphorus system is used for electroless nickel plating. The specific conditions are: nickel sulfate hexahydrate 15g/L, sodium hypophosphite 20g/L, lactic acid 25mL/L, thiourea 0.3g/L, temperature 90°C, pH 4.5, there are few bubbles on the surface of the aramid fiber, and the multi-metal composite aramid prepared in this comparative example is easily prone to plating leakage.
对比例5Comparative example 5
本对比例与实施例1基本相同，区别仅在于，使用酸性镀铜体系进行电镀铜，具体条件为：五水合硫酸铜210g/L，硫酸50g/L，盐酸110uL/L，温度27℃。芳纶的丝束不易分散，该对比例所制备的多金属复合芳纶出现板结现象，松散性极差，难以应用。This comparative example is basically the same as Example 1. The only difference is that an acidic copper plating system is used for copper electroplating. The specific conditions are: 210g/L copper sulfate pentahydrate, 50g/L sulfuric acid, 110uL/L hydrochloric acid, and a temperature of 27°C. The tows of aramid fiber are not easy to disperse. The multi-metal composite aramid fiber prepared in this comparative example has a hardening phenomenon and is extremely loose, making it difficult to apply.
基于上述实施例以及对比例，可以明确，本申请提供的多金属复合方法能够较好地保持高分子纤维的载荷，进而提高多金属复合纤维成品的力学性能，同时，本申请提供的方法对于优化复合纤维的均匀性以及镀层结合力亦有明显助益。 Based on the above examples and comparative examples, it is clear that the multi-metal composite method provided by the present application can better maintain the load of the polymer fiber, thereby improving the mechanical properties of the multi-metal composite fiber finished product. At the same time, the method provided by the present application is useful for optimizing The uniformity of the composite fibers and the bonding strength of the coating also significantly help.
应当理解，上述实施例仅为说明本申请的技术构思及特点，其目的在于让熟悉此项技术的人士能够了解本申请的内容并据以实施，并不能以此限制本申请的保护范围。凡根据本申请精神实质所作的等效变化或修饰，都应涵盖在本申请的保护范围之内。 It should be understood that the above embodiments are only to illustrate the technical concepts and features of the present application. Their purpose is to enable those familiar with this technology to understand the contents of the present application and implement them accordingly. This does not limit the scope of protection of the present application. Any equivalent changes or modifications made based on the spirit and essence of this application shall be included in the protection scope of this application.

Claims (10)

  1. 一种高分子纤维材料的多金属复合方法，其特征在于，包括：A multi-metal composite method of polymer fiber materials, which is characterized by including:
    使高分子纤维在包括氧化性酸、亲水剂的刻蚀液中进行刻蚀处理，得到微蚀纤维；The polymer fibers are etched in an etching solution including an oxidizing acid and a hydrophilic agent to obtain micro-etched fibers;
    对所述微蚀纤维进行表面活化处理，得到活化纤维；Perform surface activation treatment on the micro-etched fibers to obtain activated fibers;
    在所述活化纤维表面沉积多金属复合层，其中，所述多金属复合层至少包括包覆于所述活化纤维表面的化学镀镍底层以及至少一电镀铜层。A multi-metal composite layer is deposited on the surface of the activated fiber, wherein the multi-metal composite layer at least includes an electroless nickel plating bottom layer and at least one electroplated copper layer covering the surface of the activated fiber.
  2. 根据权利要求1所述的多金属复合方法，其特征在于，所述微蚀纤维表面刻蚀产生多个刻蚀沟槽，所述刻蚀沟槽的深度为30-50nm，宽度为300-500nm，所述微蚀纤维表面的粗糙度为0.1-0.5μm；The multi-metal composite method according to claim 1, wherein the surface etching of the micro-etched fiber produces a plurality of etching grooves, the depth of the etching grooves is 30-50nm, and the width is 300-500nm. , the roughness of the micro-etched fiber surface is 0.1-0.5 μm;
    所述氧化性酸包括硫酸和/或铬酸；The oxidizing acid includes sulfuric acid and/or chromic acid;
    所述亲水剂包括十二烷基苯磺酸钠、十二烷基磺酸钠、聚乙二醇以及聚乙烯烷酮中的任意一种或两种以上的组合；The hydrophilic agent includes any one or a combination of two or more of sodium dodecyl benzene sulfonate, sodium dodecyl sulfonate, polyethylene glycol and polyvinyl alkanone;
    优选的，所述刻蚀液中，硫酸的含量为50-80mL/L，亲水剂的体积分数为1-10％；Preferably, in the etching solution, the content of sulfuric acid is 50-80 mL/L, and the volume fraction of the hydrophilic agent is 1-10%;
    优选的，所述刻蚀液的温度为28-30℃，所述刻蚀处理的时间为4-7min。Preferably, the temperature of the etching solution is 28-30°C, and the etching treatment time is 4-7 minutes.
  3. 根据权利要求1所述的多金属复合方法，其特征在于，所述高分子纤维包括芳纶、涤纶、尼龙、丙纶、超高分子聚乙烯纤维、聚对苯撑苯并双恶唑纤维、聚苯并咪唑纤维、聚酰亚胺纤维中的任意一种或两种以上的组合。The multi-metal composite method according to claim 1, wherein the polymer fiber includes aramid, polyester, nylon, polypropylene, ultra-high molecular polyethylene fiber, poly-p-phenylene benzobisoxazole fiber, poly(p-phenylene benzobisoxazole fiber), Any one or a combination of two or more of benzimidazole fiber and polyimide fiber.
  4. 根据权利要求1所述的多金属复合方法，其特征在于，所述表面活化处理包括催化步骤和解胶步骤；The multi-metal composite method according to claim 1, wherein the surface activation treatment includes a catalytic step and a degumming step;
    所述催化步骤包括：将所述微蚀纤维置于温度为25-33℃的催化液中处理3-6min，所述催化液包括浓度为2-5ml/L的含钯催化剂、浓度为200-300ml/L的37％的盐酸、浓度为40-60g/L的氯化钠以及浓度为2-4g/L的氯化亚锡；The catalytic step includes: placing the micro-etched fiber in a catalytic liquid with a temperature of 25-33°C for 3-6 minutes. The catalytic liquid includes a palladium-containing catalyst with a concentration of 2-5ml/L and a concentration of 200-200 ml/L. 300ml/L of 37% hydrochloric acid, sodium chloride with a concentration of 40-60g/L and stannous chloride with a concentration of 2-4g/L;
    优选的，所述含钯催化剂包括浓度为5-12g/L的氯化钯、浓度为120-260mL/L的盐酸、浓度为30-80g/L的氯化钠以及浓度为5-13g/L的氯化亚锡；Preferably, the palladium-containing catalyst includes palladium chloride with a concentration of 5-12g/L, hydrochloric acid with a concentration of 120-260mL/L, sodium chloride with a concentration of 30-80g/L, and sodium chloride with a concentration of 5-13g/L. of stannous chloride;
    和/或，所述解胶步骤包括：将催化后的所述微蚀纤维置于温度为27-54℃的解胶液中处理30s-3min，所述解胶液包括浓度为15-25g/L的加速剂以及体积分数为1.6-2.6％的浓硫酸；And/or, the degumming step includes: placing the catalyzed micro-etched fiber in a degumming solution with a temperature of 27-54°C for 30s-3min, and the degumming solution contains a degumming solution with a concentration of 15-25g/ L of accelerator and concentrated sulfuric acid with a volume fraction of 1.6-2.6%;
    优选的，所述加速剂包括浓度为150-300g/L的硫酸亚锡和/或硫酸锡溶液。Preferably, the accelerator includes stannous sulfate and/or tin sulfate solution with a concentration of 150-300g/L.
  5. 根据权利要求1所述的多金属复合方法，其特征在于，所述高分子纤维选自多丝束芳纶，所述化学镀镍底层的沉积方法具体包括：The multi-metal composite method according to claim 1, wherein the polymer fiber is selected from multi-strand aramid, and the deposition method of the electroless nickel plating bottom layer specifically includes:
    将所述活化纤维置于温度为55-65℃的化学镍溶液中进行化学镀镍4-8min，所述化学镍溶液包括浓度为15-25g/L的六水合硫酸镍、浓度为2-5g/L的二甲胺硼烷、浓度为5-15g/L的 柠檬酸、浓度为30-50mL/L的盐酸以及浓度为0.01-0.05g/L的二巯基苯并噻唑，并使用氨水调节所述化学镍溶液的pH为6.5-7.2。The activated fiber is placed in an electroless nickel solution with a temperature of 55-65°C for electroless nickel plating for 4-8 minutes. The electroless nickel solution includes nickel sulfate hexahydrate with a concentration of 15-25g/L and a concentration of 2-5g. /L of dimethylamine borane, with a concentration of 5-15g/L Citric acid, hydrochloric acid with a concentration of 30-50 mL/L and dimercaptobenzothiazole with a concentration of 0.01-0.05 g/L, and ammonia water is used to adjust the pH of the chemical nickel solution to 6.5-7.2.
  6. 根据权利要求5所述的多金属复合方法，其特征在于，所述电镀铜层的沉积方法具体包括：将所述包覆有所述化学镍底层的活化纤维置于温度为50-60℃的电镀铜溶液中电镀铜4-8min，其中，所述电镀铜溶液为碱性；The multi-metal composite method according to claim 5, wherein the deposition method of the electroplated copper layer specifically includes: placing the activated fiber coated with the chemical nickel bottom layer at a temperature of 50-60°C. Electroplating copper in a copper electroplating solution for 4-8 minutes, wherein the copper electroplating solution is alkaline;
    优选的，所述电镀铜溶液包括浓度为250-290g/L的焦磷酸钾、浓度为59-88g/L的焦磷酸铜以及浓度为2-4mL/L的氨水，并调节所述电镀铜溶液的pH值为8.6-9.2；Preferably, the copper electroplating solution includes potassium pyrophosphate with a concentration of 250-290g/L, copper pyrophosphate with a concentration of 59-88g/L, and ammonia water with a concentration of 2-4mL/L, and the copper electroplating solution is adjusted. The pH value is 8.6-9.2;
    优选的，所述电镀铜时采用的电流密度为1-6安培/平方分米。Preferably, the current density used during copper electroplating is 1-6 amperes/square decimeter.
  7. 根据权利要求6所述的多金属复合方法，其特征在于，所述多金属复合层依次包括化学镀镍底层、电镀铜层、第一电镀镍层、电镀银层以及第二电镀镍层；The multi-metal composite method according to claim 6, wherein the multi-metal composite layer sequentially includes an electroless nickel plating bottom layer, an electroplated copper layer, a first electroplated nickel layer, an electroplated silver layer and a second electroplated nickel layer;
    和/或，所述第一电镀镍层沉积方法包括：将电镀铜后的所述活化纤维置于温度为50-60℃的第一电镀镍溶液中电镀镍4-8min，所述第一电镀镍溶液包括：380-650mL/L的氨基磺酸镍、5.7-14g/L的氯化镍以及30-40g/L的硼酸，电镀时的电流密度为2-4安培/平方分米；And/or, the first electroplated nickel layer deposition method includes: placing the activated fiber after copper electroplating in a first electroplating nickel solution with a temperature of 50-60°C for 4-8 minutes to electroplat nickel, and the first electroplated nickel layer deposition method includes: The nickel electroplating solution includes: 380-650mL/L nickel sulfamate, 5.7-14g/L nickel chloride and 30-40g/L boric acid. The current density during electroplating is 2-4 amps/square decimeter;
    和/或，所述电镀银层的沉积方法包括：将覆设有第一电镀镍层的活化纤维置于温度为15-25℃的电镀银溶液中电镀银4-8min，所述电镀银溶液包括：浓度为15-40g/L的硝酸银、浓度为50-90g/L的5，5-二甲基乙内酰脲以及浓度为35-60g/L的氢氧化钾；所述电镀银溶液的pH值为8-10，温度为40-60℃；所述电镀银的电流密度为2.5-5安培/平方分米；And/or, the deposition method of the electroplated silver layer includes: placing the activated fiber covered with the first electroplated nickel layer in an electroplating silver solution with a temperature of 15-25°C for 4-8 minutes to electroplat silver, and the electroplated silver solution It includes: silver nitrate with a concentration of 15-40g/L, 5,5-dimethylhydantoin with a concentration of 50-90g/L, and potassium hydroxide with a concentration of 35-60g/L; the silver electroplating solution The pH value is 8-10, the temperature is 40-60°C; the current density of the electroplated silver is 2.5-5 ampere/square decimeter;
    和/或，所述第二电镀镍层沉积方法包括：将电镀银后的所述活化纤维置于温度为50-60℃的第二电镀镍溶液中电镀镍1-2min，所述第二电镀镍溶液包括：380-650mL/L的氨基磺酸镍、5.7-14g/L的氯化镍以及30-40g/L的硼酸，电镀时的电流密度为1-2安培/平方分米。And/or, the second electroplating nickel layer deposition method includes: placing the silver electroplated activated fiber in a second electroplating nickel solution with a temperature of 50-60°C for 1-2 minutes to electroplat nickel, and the second electroplated nickel layer deposition method includes: The nickel electroplating solution includes: 380-650mL/L nickel sulfamate, 5.7-14g/L nickel chloride and 30-40g/L boric acid. The current density during electroplating is 1-2 ampere/square decimeter.
  8. 根据权利要求1-7中任意一项所述的多金属复合方法，其特征在于，实时计算所述高分子纤维及其镀层的电阻；The multi-metal composite method according to any one of claims 1 to 7, characterized in that the resistance of the polymer fiber and its coating is calculated in real time;
    当所述电阻大于第一预设阈值时，控制电源提高电镀电流，当所述电阻小于第二预设阈值时，控制电源降低电镀电流；When the resistance is greater than the first preset threshold, the power supply is controlled to increase the plating current; when the resistance is less than the second preset threshold, the power supply is controlled to reduce the plating current;
    优选的，电镀中，多个所述高分子纤维单独配制电源并独立控制多个所述电源的电流。Preferably, during electroplating, a plurality of the polymer fibers separately prepare a power supply and independently control the current of a plurality of the power supplies.
  9. 根据权利要求1-7中任意一项所述的多金属复合方法，其特征在于，还包括在多金属复合层表面形成保护层的步骤。The multi-metal composite method according to any one of claims 1 to 7, further comprising the step of forming a protective layer on the surface of the multi-metal composite layer.
  10. 由权利要求1-9中任意一项所述的多金属复合方法制备得到的高分子纤维的多金属复合纤维。 Multi-metal composite fibers of polymer fibers prepared by the multi-metal composite method according to any one of claims 1 to 9.
PCT/CN2023/081377 2022-04-19 2023-03-14 Multi-metal compounding method for polymeric fiber material, and multi-metal composite fiber WO2023202267A1 (en)

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