WO2022141831A1 - 高强度防火板、以高强度防火板为基材的耐磨防火饰面板及制造方法 - Google Patents
高强度防火板、以高强度防火板为基材的耐磨防火饰面板及制造方法 Download PDFInfo
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- WO2022141831A1 WO2022141831A1 PCT/CN2021/082697 CN2021082697W WO2022141831A1 WO 2022141831 A1 WO2022141831 A1 WO 2022141831A1 CN 2021082697 W CN2021082697 W CN 2021082697W WO 2022141831 A1 WO2022141831 A1 WO 2022141831A1
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Definitions
- the invention belongs to the technical field of sheet materials, and mainly relates to a high-strength fireproof board, a wear-resistant fireproof decorative board and a manufacturing method thereof.
- the foaming technology of melamine foam plastic is to first prepare modified melamine foam through substitution reaction, and then synthesize melamine foam formaldehyde resin with formaldehyde, vigorously develop new deep-processing products with melamine foam as raw material, and extend its industrial chain, which is undoubtedly a good solution. way.
- it can stimulate the market consumption of melamine foam and ensure the healthy, stable and sustainable development of the melamine foam industry; on the other hand, the rapidly increasing production capacity of melamine foam also provides a stable raw material guarantee for the industrialization of these new products.
- the lower market price of melamine foam also makes it a good market opportunity for the development of new downstream products, making its downstream products more cost-effective and improving its market competitiveness.
- add an environmentally friendly emulsifier mix the foaming agent and the catalyst evenly, heat foaming at a high temperature and set a new type of foam with a three-dimensional grid structure with an opening rate of more than 99%.
- melamine foam As a new type of chemical material with low density, flame retardant and sound absorption, melamine foam has very important application value in civil, industrial, construction, transportation, aviation, military, daily chemical, electronic information and other industrial fields, especially in the field of resistance It can be used under harsh environmental conditions that require high temperature and low frequency noise absorption, and it has become an irreplaceable material in the field of new chemical materials and a new chemical environmental protection material with great development prospects in the 21st century. Melamine foam is widely used in automobiles, ships, trains, airplanes and other vehicles to replace expanded polystyrene. It can also effectively reduce its own weight, reduce energy consumption, and has excellent flame retardant properties.
- the purpose of the present invention is to overcome the deficiencies in the existing decorative plate technology, and provides a high-strength fireproof board, a wear-resistant decorative board with a high-strength fireproof board as a base material, and a manufacturing method thereof.
- the polished panel is made of thermosetting resin, which has the characteristics of flame retardant, wear resistance, high and low temperature resistance, sound absorption, antistatic and so on.
- a high-strength fireproof board is characterized in that the high-strength fireproof board has two structures, the first structure is an ABA three-layer hot-pressed composite structure, which are respectively a fiber layer, a foamed fiber layer, and a fiber layer from top to bottom. , and its second structure is composited by hot pressing of fiber layers.
- the present invention is a wear-resistant fire-resistant decorative panel, which is characterized in that the wear-resistant fire-resistant decorative panel can be formed by one-time hot pressing, secondary hot pressing, or composite molding by gluing.
- the wear-resistant and fire-resistant decorative panel has four structures by one-time hot pressing.
- the first structure is from top to bottom, which are respectively the wear-resistant performance layer, fiber layer, foam fiber layer, fiber layer, and balance layer.
- the second structure It is a wear-resistant performance layer, a fiber layer, and a balance layer from top to bottom, and the third structure is from top to bottom.
- the fourth structure is the wear-resistant layer, the pattern layer, the fiber layer, and the balance layer from top to bottom.
- the secondary hot-pressing molding of the wear-resistant fire-resistant decorative panel has two structures.
- the first structure is the wear-resistant performance layer, the high-strength fireproof board, and the balance layer from top to bottom.
- the second structure is from top to bottom. Wear-resistant layer, pattern layer, high-strength fireproof board and balance layer respectively.
- the wear-resistant fire-resistant decorative panel is glued and compounded, and its structure is from top to bottom: wear-resistant performance layer, glue, high-strength fireproof board, glue, and balance layer.
- the wear-resistant performance layer is made of commercial melamine sprayed paper or colored paper with printed patterns, dipped in a mixed solution of thermosetting resin and dried, and then the surface is rolled with melamine wear-resistant glue, and then dried and cut.
- the wear-resistant layer is made of commercially available transparent melamine wear-resistant paper or a mixed solution of a thermosetting resin impregnated with transparent paper and dried, and then the surface is rolled with melamine wear-resistant glue and then dried and cut.
- the fiber layer is composed of a single or multiple fiber mats that are dipped in a thermosetting resin mixed solution and then dried and cut.
- the foamed fiber layer is composed of a single or multiple fiber mats that are dipped in a thermosetting resin foaming mixed solution and then dried and cut.
- the pattern layer is formed by printing pattern patterns on white film or paper prepared from one of PE, PP, PET, PETG, PVC and other materials.
- the balancing layer is obtained from commercial melamine balancing paper or paper that is dipped in a thermosetting resin mixed solution and then dried and cut.
- the fiber felt can be one or more of chemical fibers, natural fibers, and inorganic fibers that are woven or needled.
- Commonly used chemical fibers include: polyester, polypropylene, acrylic, spandex, nylon, vinylon, etc.
- Natural fibers include: hemp fiber, cotton fiber, bamboo fiber, wood fiber, straw fiber, etc.
- inorganic fibers include carbon fiber, glass fiber, aluminum silicate fiber, ceramic fiber, basalt fiber, etc.
- thermosetting resin mixed solution uses thermosetting resin, curing agent, graphene oxide, water, and the specific components and parts by weight are:
- the melamine wear-resistant adhesive uses melamine formaldehyde resin (MF), curing agent, polyurethane resin, nano-aluminum oxide, and water, and the specific components and parts by weight are:
- thermosetting resin foaming mixed solution uses a thermosetting resin, a curing agent, a foaming agent and water, and the specific components and parts by weight are:
- thermosetting resin is one or more of melamine formaldehyde resin, phenolic resin, epoxy resin and unsaturated polyester.
- the curing agent is one or more of polyamines, acid anhydrides, polyethers, and methyl ethyl ketone peroxide.
- the manufacturing method of the high-strength fireproof board is as follows: selecting a corresponding press tray according to the thickness of the high-strength fireproof board, laying the release film from bottom to top, and laying each layer of the high-strength fireproof board and the release film from bottom to top according to the structure. Lay it on a tray, put it into a hot press at a temperature of 130°C-160°C and a pressure of 1-20MPa for 2-60 minutes, and then place it in a cold press (press through cooling water, and the temperature of the cooling water is Water at room temperature varies with climate change) Cooling for 10-30 minutes under the pressure of 1-20MPa, the high-strength fireproof board formed after removing the release film.
- the one-step hot-press forming manufacturing method is as follows: according to the thickness of the wear-resistant fire-resistant decorative panel, a corresponding press tray is selected, and the shading plate, release film, According to the structure of the wear-resistant fire-resistant decorative panel formed by one-time hot pressing, the layers, release film and embossed board are laid in the tray from bottom to top, and put into a hot press at a temperature of 130°C-160°C and a pressure of 1-20MPa. After pressing and foaming for 2-60 minutes, cool down for 10-30 minutes under the pressure of 1-20MPa in a cold press, remove the embossed plate, release film and shading plate to form a hot-pressed wear-resistant fireproof decorative panel.
- the manufacturing method of the secondary hot pressing is as follows: first, the high-strength fire-proof board is manufactured according to the manufacturing method of the high-strength fire-proof board of the present invention, the corresponding press tray is selected according to the thickness of the two-step wear-resistant fire-resistant decorative panel, and the two-step wear-resistant fire-resistant decorative panel is selected. The layers of the fireproof decorative panel structure from bottom to top are laid in the tray, put into a hot press at a temperature of 130°C-190°C, and hot-pressed for 0.5-10 minutes at a pressure of 1-50MPa, finally forming a secondary hot-pressing molding wear-resistant Fire retardant veneer.
- the glue-coating composite molding manufacturing method is as follows: firstly, a high-strength fire-proof board is manufactured according to the high-strength fire-proof board manufacturing method of the present invention, and glue is applied on both sides of the high-strength fire-proof board;
- the high-strength fireproof board can be used for partitions, protective boards, and veneer forming panels for decorative boards, sound insulation boards, and other fields.
- the wear-resistant fire-resistant decorative panel can be used in the fields of floors, wall panels, decorative panels and the like.
- the beneficial effects of the present invention are: a large amount of nitrogen is contained in the melamine molecule, during the combustion process, when decomposing, the nitrogen escapes, so that the product has self-extinguishing property, and the following standards can be achieved without adding any flame retardant or other additives
- Nano-aluminum oxide is added to the surface to enhance the wear resistance and scratch resistance, exceeding the requirements of EN16094 standard gloss retention A1 and micro scratch B1.
- the opening rate is as high as 99.9%
- the sound wave can easily and effectively enter the deep layer of the bubble body, and is converted into the vibration of the grid to be consumed and absorbed, and at the same time, it can effectively Eliminates reflected waves, and has excellent sound absorption performance in a wide sound frequency range, especially in the absorption of low-frequency noise. Coupled with the unique thermal stability, it can be used in high temperature places such as floor heating and direct sunlight. Adding graphene oxide increases the strength of the sheet, while also having good toughness and antistatic properties. Using water-soluble thermosetting resin solution, no solvent is more environmentally friendly.
- FIG. 1 is a schematic diagram of the high-strength fireproof board of the present invention being the first structure ABA three-layer hot-pressed composite structure, and the reference numerals in FIG. 1 are: 11-fiber layer, 12-foam fiber layer, 13-fiber layer;
- Figure 2 is a schematic diagram of the first structure of the one-time hot-pressing molding of the wear-resistant fire-resistant decorative panel of the present invention, and the reference numerals in Figure 2 are: 21-wear-resistant performance layer, 22-fiber layer, 23-foam layer, 24- Fiber layer, 25-balance layer;
- Figure 3 is a schematic diagram of the second structure of the one-time hot-pressing molding of the wear-resistant fire-resistant decorative panel of the present invention, and the reference numerals in Figure 3 are: 31-wear-resistant performance layer, 32-fiber layer, 33-balance layer;
- Fig. 4 is a schematic diagram of the third structure of the one-time hot pressing molding of the wear-resistant and fire-resistant decorative panel of the present invention, and the reference numerals in Fig. 4 are: 41-wear-resistant layer, 42-pattern layer, 43-fiber layer, 44-foaming layer, 45-fiber layer, 46-balance layer;
- Fig. 5 is a schematic diagram of the fourth structure of the one-time hot pressing molding of the wear-resistant and fire-resistant decorative panel of the present invention, and the reference numerals in Fig. 5 are: 51 - wear-resistant layer, 52 - pattern layer, 53 - fiber layer, 54 - balance layer ;
- FIG. 6 is a schematic diagram of the first structure of the second hot pressing molding of the wear-resistant fire-resistant decorative panel of the present invention, and the reference numerals in FIG. 6 are: 61-wear-resistant performance layer, 62-high-strength fireproof board, 63-balance layer;
- FIG. 7 is a schematic diagram of the second structure of the second hot-pressing molding of the wear-resistant and fire-resistant decorative panel of the present invention, and the reference numerals in FIG. 7 are: 71 - wear-resistant layer, 72 - pattern layer, 73 - high-strength fireproof board, 74 - Balance layer;
- FIG. 8 is a schematic diagram of the composite molding structure of the wear-resistant fire-resistant decorative panel coated with glue, and the reference numerals in FIG. 8 are: 81-wear-resistant performance layer, 82-glue, 83-high-strength fireproof board, 84-glue, 85 - Balance layer;
- FIG. 9 is a judgment standard diagram for a surface micro-scratch performance test.
- a high-strength fireproof board is characterized in that the high-strength fireproof board has two structures, the first structure is an ABA three-layer hot-pressed composite structure, as shown in Figure 1, from top to bottom are fiber layers 11, The second structure of the foamed fiber layer 12 and the fiber layer 13 is that the fiber layers are composited by hot pressing.
- the fiber layer is composed of a single or multiple fiber mats that have been dipped in a thermosetting resin mixed solution and then dried and cut. It can be made of one or more of chemical fibers, natural fibers and inorganic fibers by knitting or needle punching. Commonly used chemical fibers include: polyester, polypropylene, acrylic, spandex, nylon, vinylon, etc. Natural fibers include: hemp fiber , cotton fiber, bamboo fiber, wood fiber, straw fiber, etc. Inorganic fibers include carbon fiber, glass fiber, aluminum silicate fiber, ceramic fiber, basalt fiber, etc.
- thermosetting resin mixed solution uses thermosetting resin, curing agent, graphene oxide and water, and the specific components and parts by weight are:
- thermosetting resin foaming mixed solution uses thermosetting resin, curing agent, foaming agent and water, and the specific components and parts by weight are:
- thermosetting resin is one or more of melamine formaldehyde resin, phenolic resin, epoxy resin and unsaturated polyester.
- the curing agent is one or more of polyamines, acid anhydrides, polyethers, and methyl ethyl ketone peroxide.
- the tested product is a three-layer hot-pressed composite structure
- the fiber layer is composed of a single fiber mat impregnated with a thermosetting resin mixed solution and then dried and cut
- the foamed fiber layer is two fiber mats impregnated with a thermosetting resin. After foaming the mixed solution, it is composed of drying and cutting.
- the fiber mat is woven from hemp fibers.
- the specific components and weight parts of the thermosetting resin mixed solution are: 100 parts of thermosetting resin, 1 part of curing agent, 1 part of graphene oxide, and 20 parts of water.
- the specific components and weight parts of the thermosetting resin foaming mixed solution are: 100 parts of thermosetting resin, 1 part of curing agent, 5 parts of foaming agent, 2.5 parts of polysorbate-80, and 20 parts of water;
- the agent is polyamine.
- the above-mentioned high-strength fireproof board manufacturing method is as follows: according to the thickness of the high-strength fireproof board, the corresponding press tray is selected, the release film is respectively laid from bottom to top, and the layers of the high-strength fireproof board are laid from bottom to top according to the structure. In the tray, put it into a hot press at a temperature of 130°C-160°C and a pressure of 1-20MPa for 2-60 minutes, then cool it for 10-30 minutes under a cold press at a pressure of 1-20MPa, remove the separator. High-strength fireproof board formed after molding film.
- a wear-resistant fire-resistant decorative panel is characterized in that the wear-resistant fire-resistant decorative panel is formed by one-time hot pressing and has four structures, as shown in Figure 2, the first structure is from top to bottom. layer 21, fiber layer 22, foam fiber layer 23, fiber layer 24, balance layer 25; as shown in Figure 3, the second structure is from top to bottom respectively wear-resistant performance layer 31, fiber layer 32, balance layer 33; As shown in Figure 4, its third structure is from top to bottom respectively the wear-resistant layer 41, the pattern layer 42, the fiber layer 43, the foamed fiber layer 44, the fiber layer 45, and the balance layer 46; as shown in Figure 5 As shown, the fourth structure is a wear-resistant layer 51, a pattern layer 52, a fiber layer 53, and a balance layer 54 from top to bottom.
- the wear-resistant performance layer is a commercial melamine sprayed paper or a colored paper with a printed pattern, which is dipped in a mixed solution of thermosetting resin and dried.
- the surface is rolled with a melamine wear-resistant adhesive and then dried and cut.
- the wear-resistant layer is a commercial transparent melamine.
- the fiber layer is composed of single or multiple fiber mats impregnated with thermosetting resin mixed solution and then dried and cut.
- the foamed fiber layer is composed of a single or multiple fiber mats that are dipped in a thermosetting resin foaming mixed solution and then dried and cut.
- the pattern layer is a white film or The paper is made of printed patterns.
- the balance layer is commercial melamine balance paper or the paper is dried and cut after dipping in a thermosetting resin mixed solution.
- the fiber mat can be one or more of chemical fibers, natural fibers, and inorganic fibers. Woven or needle punched, commonly used chemical fibers include: polyester, polypropylene, acrylic, spandex, nylon, vinylon, etc., natural fibers include: hemp fiber, cotton fiber, bamboo fiber, wood fiber, straw fiber, etc., inorganic fibers include Carbon fiber, glass fiber, aluminum silicate fiber, ceramic fiber, basalt fiber, etc.
- thermosetting resin mixed solution uses thermosetting resin, curing agent, graphene oxide and water, and the specific components and parts by weight are:
- the melamine wear-resistant adhesive uses melamine formaldehyde resin (MF), curing agent, polyurethane resin, nano-aluminum oxide, and water.
- MF melamine formaldehyde resin
- curing agent curing agent
- polyurethane resin polyurethane resin
- nano-aluminum oxide and water.
- the specific components and parts by weight are:
- thermosetting resin foaming mixed solution uses thermosetting resin, curing agent, foaming agent and water, and the specific components and parts by weight are:
- thermosetting resin is one or more of melamine formaldehyde resin, phenolic resin, epoxy resin and unsaturated polyester.
- the curing agent is one or more of polyamines, acid anhydrides, polyethers, and methyl ethyl ketone peroxide.
- the test product is the fourth structure.
- the wear-resistant layer is a commercial transparent melamine wear-resistant paper impregnated with a thermosetting resin mixed solution and dried. The surface is rolled with melamine wear-resistant glue and then dried and cut. It is composed of a single fiber mat impregnated with a thermosetting resin mixed solution and then dried and cut.
- the balance layer is a commercial melamine paper impregnated with a thermosetting resin mixed solution and then dried and cut.
- the fiber mat is made of polyester and acrylic.
- thermosetting The components and parts by weight of the resin mixed solution are: 100 parts of thermosetting resin, 1.5 parts of curing agent, 1 part of graphene oxide, and 20 parts of water; the components and parts by weight of melamine wear-resistant adhesive are: melamine formaldehyde resin (MF) 100 parts parts, 2 parts of curing agent, 40 parts of polyurethane, 20 parts of nano aluminum oxide, and 5 parts of water; the thermosetting resin is melamine formaldehyde resin, and the curing agent is acid anhydride and polyether.
- MF melamine formaldehyde resin
- the manufacturing method of the above-mentioned wear-resistant fire-resistant decorative panel is as follows: according to the thickness of the wear-resistant fire-resistant decorative panel, a corresponding press tray is selected, and from bottom to top, the shading plate, the release film, and the structure of the wear-resistant fire-resistant decorative panel are formed by one-time hot pressing. The layers from bottom to top, the release film, and the embossed board are laid on the tray, put into a hot press at a temperature of 130°C-160°C and a pressure of 1-20MPa for 2-60 minutes. The press is cooled for 10-30 minutes under the pressure of 1-20MPa, and the embossed plate, release film and shading plate are removed to form a hot-pressed wear-resistant fire-resistant decorative panel.
- a wear-resistant fire-resistant decorative panel is characterized in that the wear-resistant fire-resistant decorative panel is formed by secondary hot pressing, and has two structures, as shown in Figure 6, the first structure is from top to bottom. layer 61 , high-strength fireproof board 62 , balance layer 63 ; as shown in FIG. 7 , the second structure is wear-resistant layer 71 , pattern layer 72 , high-strength fireproof board 73 , balance layer 74 respectively from top to bottom.
- the wear-resistant performance layer is a commercial melamine sprayed paper or a colored paper with a printed pattern, which is dipped in a mixed solution of thermosetting resin and dried. The surface is rolled with a melamine wear-resistant adhesive and then dried and cut.
- the wear-resistant layer is a commercial transparent melamine.
- Abrasion-resistant paper or a mixed solution of thermosetting resin impregnated with transparent paper is dried, and then the surface is rolled with melamine wear-resistant glue, and then dried and cut.
- the high-strength fireproof board is prepared according to the embodiment.
- the pattern layer is made of PE, PP, PET, PETG , PVC and other materials, the white film or paper is printed with patterns, the balance layer is commercial melamine balance paper or the base paper is dipped in a thermosetting resin mixed solution and then dried and cut.
- the fiber felt can be chemical One or more of fiber, natural fiber and inorganic fiber are woven or needled.
- Commonly used chemical fibers include: polyester, polypropylene, acrylic, spandex, nylon, vinylon, etc.
- Natural fibers include: hemp fiber, cotton fiber , bamboo fiber, wood fiber, straw fiber, etc.
- Inorganic fibers include carbon fiber, glass fiber, aluminum silicate fiber, ceramic fiber, basalt fiber, etc.
- thermosetting resin mixed solution uses thermosetting resin, curing agent, graphene oxide and water, and the specific components and parts by weight are:
- the melamine wear-resistant adhesive uses melamine formaldehyde resin (MF), curing agent, polyurethane resin, nano-aluminum oxide, and water.
- MF melamine formaldehyde resin
- curing agent curing agent
- polyurethane resin polyurethane resin
- nano-aluminum oxide and water.
- the specific components and parts by weight are:
- thermosetting resin is one or more of melamine formaldehyde resin, phenolic resin, epoxy resin and unsaturated polyester.
- the curing agent is one or more of polyamines, acid anhydrides, polyethers, and methyl ethyl ketone peroxide.
- the test product involved in this example is the first structure, and the wear-resistant performance layer is a commercial colored paper with a printed pattern pattern, which is dipped in a mixed solution of thermosetting resin and dried, and then the surface is rolled with melamine wear-resistant glue, and then dried and cut.
- the high-strength fireproof board is the product tested in Example 1, and the balance layer is a commercial melamine balance paper that is dipped in a thermosetting resin mixed solution and then dried and cut;
- the components and weight parts of the thermosetting resin mixed solution are: 100 parts of thermosetting resin, 1 part of curing agent, 1 part of graphene oxide, 20 parts of water;
- the components and parts by weight of melamine wear-resistant adhesive are: 100 parts of melamine formaldehyde resin (MF), 2 parts of curing agent, 40 parts of polyurethane, 20 parts of nano aluminum oxide and 6 parts of water;
- the thermosetting resin is epoxy resin, and the curing agent is methyl ethyl ketone peroxide.
- the manufacturing method of the above-mentioned wear-resistant and fire-resistant decorative panel is as follows: first, a high-strength fire-resistant panel is manufactured according to the manufacturing method of the high-strength fire-resistant panel of the present invention, and a corresponding press tray is selected according to the thickness of the secondary hot-pressed wear-resistant fire-resistant decorative panel, and the second step The structure of the wear-resistant fire-resistant decorative panel is laid in the tray from bottom to top, and put into a hot press for 0.5-10 minutes at a temperature of 130°C-190°C and a pressure of 1-50MPa for 0.5-10 minutes, and finally a two-step method is formed. Ground fire veneer.
- a wear-resistant fire-resistant decorative panel is characterized in that the wear-resistant fire-resistant decorative panel is a composite molding with glue, as shown in FIG. Plate 83, glue 84, balance layer 85.
- the wear-resistant performance layer is a commercial melamine sprayed paper or a patterned paper with a printed pattern, which is dipped in a mixed solution of thermosetting resin and dried. The surface is rolled with a melamine wear-resistant adhesive and then dried and cut.
- the balance layer is made of commercial melamine balance paper or paper impregnated with thermosetting resin mixed solution and then dried and cut.
- the fiber mat can be one or more of chemical fibers, natural fibers and inorganic fibers.
- Commonly used chemical fibers include: polyester, polypropylene, acrylic, spandex, nylon, vinylon, etc.
- natural fibers include: hemp fiber, cotton fiber, bamboo fiber, wood fiber, straw fiber, etc.
- Inorganic fibers include carbon fiber, glass fiber , aluminum silicate fiber, ceramic fiber, basalt fiber, etc.
- thermosetting resin mixed solution uses thermosetting resin, curing agent, graphene oxide and water, and the specific components and parts by weight are:
- the melamine wear-resistant adhesive uses melamine formaldehyde resin (MF), curing agent, polyurethane resin, nano-aluminum oxide, and water.
- MF melamine formaldehyde resin
- curing agent curing agent
- polyurethane resin polyurethane resin
- nano-aluminum oxide and water.
- the specific components and parts by weight are:
- thermosetting resin is one or more of melamine formaldehyde resin, phenolic resin, epoxy resin and unsaturated polyester.
- the curing agent is one or more of polyamines, acid anhydrides, polyethers, and methyl ethyl ketone peroxide.
- the wear-resistant performance layer is a commercial colored paper with printed patterns, which is dipped in a mixed solution of thermosetting resin and dried.
- the board is the product tested in Example 1
- the balance layer is a commercial melamine balance paper that is dried and cut after dipping into the thermosetting resin mixed solution; the components and parts by weight of the thermosetting resin mixed solution are the same as those in Example 2 product; the components and parts by weight of the melamine wear-resistant adhesive are the same as the product tested in Example 2; the thermosetting resin and the curing agent are the same as the product tested in Example 2.
- the manufacturing method of the above-mentioned wear-resistant fire-resistant decorative panel is as follows: first, a high-strength fire-resistant board is manufactured according to the manufacturing method of the high-strength fire-resistant board of the present invention, and glue is applied on both sides of the high-strength fire-resistant board, and the wear-resistant performance layer is attached on the top, and the balance is attached on the bottom. Floor.
- the present invention is the product of Examples 1-4 of the present invention.
- the present invention is the product of Examples 1-4 of the present invention.
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Abstract
一种高强度防火板，其具有两种结构；第一种结构为三层热压复合结构，由上至下分别为纤维层、发泡纤维层、纤维层；其第二种结构为纤维层热压复合而成。一种耐磨防火饰面板，其由包含的高强度防火板经一次热压成型，或者可以二次热压成型，或者涂胶复合成型制得。还公开了高强度防火板、以高强度防火板为基材的耐磨饰面板的制造方法。该高强度防火板、耐磨饰面板采用热固性树脂制备而成，具有阻燃、耐磨、耐高低温、吸音、抗静电的特点。
Description
本发明属于板材技术领域，主要涉及的是一种高强度防火板、耐磨防火饰面板及其制造方法。
从阻燃、环保和节能方面推进三聚氰胺泡沫新型后续加工产品，尤其是三聚氰胺泡沫、三聚氰胺泡沫新型纤维、三聚氰胺泡沫阻燃剂等三聚氰胺泡沫新型后续加工产品尽快地进入航天航空、高速交通、电子信息、环境保护等高技术领域的应用市场，显得越发重要。
三聚氰胺泡沫塑料发泡技术是先通过取代反应制取改性三聚氰胺泡沫，然后与甲醛合成三聚氰胺泡沫甲醛树脂，大力发展以三聚氰胺泡沫为原料的深加工新型产品，延伸其产业链，无疑是很好的解决途径。一方面，可以拉动三聚氰胺泡沫的市场消费，保证三聚氰胺泡沫产业健康稳定持续发展；另外，迅速增加的三聚氰胺泡沫生产能力也为这些新型产品产业化发展提供了稳定的原料保障。同时三聚氰胺泡沫较低的市场价格也使其下游新型产品的开发获得一个良好的市场机遇，使其下游产品具有较高的性价比，提高其市场竞争力。再加入环保的乳化剂，发泡剂和催化剂混合均匀，高温加热发泡和高温定型制造的一种开孔率高达99％以上的三维网格结构的新型泡沫塑料。
作为一种低密度、阻燃、吸音的新型化工材料，三聚氰胺泡沫在民用、工业、建筑、交通、航空、军事、日化、电子信息等工业领域具有十分重要的应用价值，特别是在有阻燃、高温、低频噪音吸收要求的恶劣环境条件下使用，成为化工新型材料界不可替代的材料和2l世纪中具有巨大发展前景的新型化工环保材料。三聚氰胺泡沫在汽车、轮船、火车、飞机等交通工具座位衬垫替代发泡聚苯乙烯的大量的应用，也能有效地降低其自身重量，减少能源的消耗，并具有优良的阻燃性能。
发明内容
本发明的目的在于克服现有装饰板材技术中的不足之处，提供了一种高强度防火板、以高强度防火板为基材的耐磨饰面板及其制造方法，高强度防火板、耐磨饰面板采用热固性树脂制备而成，具有阻燃、耐磨、耐高低温、吸音、抗静电等特点。
一种高强度防火板，其特征在于该高强度防火板具有两种结构，其第一种结构为ABA三层热压复合结构，由上至下分别为纤维层、发泡纤维层、纤维层，其第二种结构为纤维层热压复合而成。
本发明一种耐磨防火饰面板，其特征在于该耐磨防火饰面板可以一次热压成型也可以二次热压成型,或者涂胶复合成型。
耐磨防火饰面板一次热压成型具有四种结构，其第一种结构为由上至下分别是耐磨表现层、纤维层、发泡纤维层、纤维层、平衡层，其第二种结构为由上至下分别耐磨表现层、纤维层、平衡层，其第三种结构为由上至下分别耐磨层、花纹层、纤维层、发泡纤维层、纤维层、平衡层，其第四种结构为由上至下分别耐磨层、花纹层、纤维层、平衡层。
耐磨防火饰面板二次热压成型具有两种结构，其第一种结构为由上至下分别是耐磨表现层、高强度防火板、平衡层，其第二种结构为由上至下分别耐磨层、花纹层、高强度防火板、平衡层。
耐磨防火饰面板涂胶复合成型，其结构为由上至下分别是耐磨表现层、胶、高强度防火板、胶、平衡层。
所述的耐磨表现层是已商用的三聚氰胺喷涂纸或者用印刷花纹图案的花色纸经过浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥裁切而成。
所述的耐磨层是已商用的透明三聚氰胺耐磨纸或者用透明纸浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥裁切而成。
所述的纤维层是单张或者多张纤维毡经过浸渍热固性树脂混合溶液后干燥裁切组成。
所述的发泡纤维层是单张或者多张纤维毡经过浸渍热固性树脂发泡混合溶液后干燥裁切组成。
所述的花纹层是由PE、PP、PET、PETG、PVC等材料中的一种制备的白膜或者纸印刷花纹图案而成的。
本发明中平衡层是已商用的三聚氰胺平衡纸或者纸经过浸渍热固性树脂混合溶液后干燥裁切而成。
所述的纤维毡可以为化学纤维、天然纤维、无机纤维中的一种或几种编织或针刺而成的毡，常用的化学纤维包括：涤纶、丙纶、腈纶、氨纶、锦纶、维纶等，天然纤维包括：麻纤维、棉纤维、竹纤维、木纤维、秸秆纤维等，无机纤维包括碳纤维、玻璃纤维、硅酸铝纤维、陶瓷纤维、玄武岩纤维等。
所述的热固性树脂混合溶液使用了热固性树脂、固化剂、氧化石墨烯、水，具体组分及重量份为：
所述的三聚氰胺耐磨胶使用了三聚氰胺甲醛树脂(MF)、固化剂、聚氨酯树脂、纳米三氧化二铝、水，具体组分及重量份为：
所述的热固性树脂发泡混合溶液使用了热固性树脂、固化剂、发泡剂、水，具体组分及重量份为：
所述的热固性树脂为三聚氰胺甲醛树脂、酚醛树脂、环氧树脂、不饱和聚酯中的一种或几种。
所述的固化剂为多元胺、酸酐、聚醚、过氧化甲乙酮中的一种或几种。
所述的高强度防火板制造方法为：根据高强度防火板的厚度选择相应的压机托盘，由下至上分别将离型膜、根据结构由下至上铺设高强度防火板各层、离型膜铺设在托盘中，放入热压机在温度130℃-160℃，压力1-20MPa条件下热压发泡2-60分钟后，在冷压机(压机通冷却水，冷却水的温度为常温水随气候变化而不同)1-20MPa压力条件下冷却10-30分钟，拆除离型膜后形成的高强度防火板。
所述的耐磨防火饰面板有三种制造方法，其一次热压成型制造方法为：根据耐磨防火饰面板的厚度选择相应的压机托盘，由下至上分别将底纹版、离型膜、根据一次热压成型耐磨防火饰面板结构由下至上的各层、离型膜、压纹板铺设在托盘中，放入热压机在温度130℃-160℃，压力1-20MPa条件下热压发泡2-60分钟后，在冷压机1-20MPa压力条件下冷却10-30分钟，拆除压纹版、离型膜、底纹版后形成一次热压成型耐磨防火饰面板。其二次热压成型制造方法为：先根据本发明高强度防火板制造方法制造高强度防火板，根据二步法耐磨防火饰面板的厚度选择相应的压机托盘，将二步法耐磨防火饰面板结构由下至上的各层铺设在托盘中，放入热压机在温度130℃- 190℃，压力1-50MPa条件下热压0.5-10分钟，最终形成二次热压成型耐磨防火饰面板。其涂胶复合成型制造方法为：先根据本发明高强度防火板制造方法制造高强度防火板，在高强度防火板上双面涂胶，上方贴合耐磨表现层，下方贴合平衡层。
所述的高强度防火板可用于隔断、防护板、贴面形成饰面板用于装饰板、隔音板等领域。
所述的耐磨防火饰面板可用于地板、墙板、装饰板等领域。
本发明的有益效果是：在三聚氰胺分子中含有大量的氮，在燃烧过程中，分解时，氮气逸出，使制品具有自熄灭性，不添加任何阻燃剂或其它添加剂，即可达到如下标准要求：德国DIN4102规定的B1级低可燃性材料标准；美国保险协会UL94-V0级高阻燃材料标准；欧盟BS 6853、NF F16-101、DIN5510防火认证；中国国家标准GB/T8624-2006中B级(难燃级)阻燃标准。表面添加纳米三氧化二铝，增强耐磨耐刮性能，超过EN16094标准保光性A1和微刮伤B1的要求。由三维网状开孔结构构成和高开孔率(开孔率高达99.9％)，声波能方便而有效地进入泡体的深层，转变为网格的震动而被消耗和吸收，同时能有效地消除反射波，在较宽的声频范围内具有优越的吸声性能，特别是在低频噪音的吸收上具有突出的效果。加之独具特色的热稳定性，可适用于高温场所如地暖和阳光直射地区。添加氧化石墨烯增加板材的强度，同时还具有很好的韧性和抗静电性。使用水溶性热固性树脂溶液，无溶剂更环保。
为了使本发明的内容更容易被清楚的理解，下面根据本发明的具体实施例并结合附图，对本发明作进一步详细的说明，其中：
图1为本发明的高强度防火板为第一种结构ABA三层热压复合结构示意图，图1中附图标记表示为：11-纤维层，12-发泡纤维层，13-纤维层；
图2为本发明的耐磨防火饰面板一次热压成型第一种结构示意图，图2中附图标记表示为：21-耐磨表现层，22-纤维层，23-发泡层，24-纤维层，25-平衡层；
图3为本发明的耐磨防火饰面板一次热压成型第二种结构示意图，图3中附图标记表示为：31-耐磨表现层，32-纤维层，33-平衡层；
图4为本发明的耐磨防火饰面板一次热压成型第三种结构示意图，图4中附图标记表示为：41-耐磨层，42-花纹层，43-纤维层，44-发泡层，45-纤维层，46-平衡层；
图5为本发明的耐磨防火饰面板一次热压成型第四种结构示意图，图5中附图标记表示为：51-耐磨层，52-花纹层，53-纤维层，54-平衡层；
图6为本发明的耐磨防火饰面板二次热压成型第一种结构示意图，图6中附图标记表示为：61-耐磨表现层，62-高强度防火板，63-平衡层；
图7为本发明的耐磨防火饰面板二次热压成型第二种结构示意图，图7中附图标记表示为：71-耐磨层，72-花纹层，73-高强度防火板，74-平衡层；
图8为本发明的耐磨防火饰面板涂胶复合成型结构示意图，图8中附图标记表示为：81-耐磨表现层，82-胶，83-高强度防火板，84-胶，85-平衡层；
图9为表面微刮伤性能测试的判断标准图。
实施例1：
一种高强度防火板，其特征在于该高强度防火板具有两种结构，其第一种结构为ABA三层热压复合结构，如图1所示，由上至下分别为纤维层11、发泡纤维层12、纤维层13，其第二种结构为纤维层热压复合而成。纤维层是单张或者多张纤维毡经过浸渍热固性树脂混合溶液后干燥裁切组成，发泡纤维层是单张或者多张纤维毡经过浸渍热固性树脂发泡混合溶液后干燥裁切组成，纤维毡可以为化学纤维、天然纤维、无机纤维中的一种或几种编织或者针刺而成的，常用的化学纤维包括：涤纶、丙纶、腈纶、氨纶、锦纶、维纶等，天然纤维包括：麻纤维、棉纤维、竹纤维、木纤维、秸秆纤维等，无机纤维包括碳纤维、玻璃纤维、硅酸铝纤维、陶瓷纤维、玄武岩纤维等。
热固性树脂混合溶液使用了热固性树脂、固化剂、氧化石墨烯、水，具体组分及重量份为：
热固性树脂发泡混合溶液使用了热固性树脂、固化剂、发泡剂、水，具体组分及重量份为：
热固性树脂为三聚氰胺甲醛树脂、酚醛树脂、环氧树脂、不饱和聚酯中的一种或几种。
固化剂为多元胺、酸酐、聚醚、过氧化甲乙酮中的一种或几种。
本实施例中参与测试产品为三层热压复合结构，所述的纤维层是单张纤维毡经过浸渍热固性树脂混合溶液后干燥裁切组成，发泡纤维层是两张纤维毡经过浸渍热固性树脂发泡混合溶液后干燥裁切组成，纤维毡为麻纤维编织而成，热固性树脂混合溶液具体组分及重量份为：热固性树脂100份、固化剂1份、氧化石墨烯1份、水20份；热固性树脂发泡混合溶液具体组分及重量份为：热固性树脂100份、固化剂1份、发泡剂5份、聚山梨酯-80 2.5份、水20份；热固性树脂为酚醛树脂，固化剂为多元胺。
上述高强度防火板制造方法为：根据高强度防火板的厚度选择相应的压机托盘，由下至上分别将离型膜、根据结构由下至上铺设高强度防火板各层、离型膜铺设在托盘中，放入热压机在温度130℃-160℃，压力1-20MPa条件下热压发泡2-60分钟后，在冷压机1-20MPa压力条件下冷却10-30分钟，拆除离型膜后形成的高强度防火板。
实施例2：
一种耐磨防火饰面板，其特征在于该耐磨防火饰面板为一次热压成型成型，具有四种结构，如图2所示，其第一种结构为由上至下分别是耐磨表现层21、纤维层22、发泡纤维层23、纤维层24、平衡层25；如图3所示，其第二种结构为由上至下分别耐磨表现层31、纤维层32、平衡层33；如图4所示，其第三种结构为由上至下分别耐磨层41、花纹层42、纤维层43、发泡纤维层44、纤维层45、平衡层46；如图5所示，其第四种结构为由上至下分别耐磨层51、花纹层52、纤维层53、平衡层54。耐磨表现层是已商用的三聚氰胺喷涂纸或者用印刷花纹图案的花色纸经过浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥裁切而成，耐磨层是已商用的透明三聚氰胺耐磨纸或者用透明纸浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥裁切而成，纤维层是单张或者多张纤维毡经过浸渍热固性树脂混合溶液后干燥裁切组成，发泡纤维层是单张或者多张纤维毡经过浸渍热固性树脂发泡混合溶液后干燥裁切组成，花纹层是由PE、PP、PET、PETG、PVC等材料中的一种制备的白膜或者纸印刷花纹图案而成，平衡层是已商用的三聚氰胺平衡纸或者纸经过浸渍热固性树脂混合溶液后干燥裁切而成，纤维毡可以为化学纤维、天然纤维、无机纤维中的一种或几种编织或者针刺而成的，常用的化学纤维包括：涤纶、丙纶、腈纶、氨纶、锦纶、维纶等，天然纤维包括：麻纤维、棉纤维、竹纤维、木纤维、秸秆纤维等，无机纤维包括碳纤维、玻璃纤维、硅酸铝纤维、陶瓷纤维、玄武岩纤维等。
热固性树脂混合溶液使用了热固性树脂、固化剂、氧化石墨烯、水，具体组分及重量份为：
三聚氰胺耐磨胶使用了三聚氰胺甲醛树脂(MF)、固化剂、聚氨酯树脂、纳米三氧化二铝、水，具体组分及重量份为：
热固性树脂发泡混合溶液使用了热固性树脂、固化剂、发泡剂、水，具体组分及重量份为：
热固性树脂为三聚氰胺甲醛树脂、酚醛树脂、环氧树脂、不饱和聚酯中的一种或几种。
固化剂为多元胺、酸酐、聚醚、过氧化甲乙酮中的一种或几种。
本实施例中参与测试产品为第四种结构，所述耐磨层是已商用的透明三聚氰胺耐磨纸浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥裁切而成，纤维层是单张纤维毡经过浸渍热固性树脂混合溶液后干燥裁切组成，平衡层是已商用的三聚氰胺纸经过浸渍热固性树脂混合溶液后干燥裁切而成，纤维毡为涤纶、腈纶针刺而成；热固性树脂混合溶液的组分及重量份为：热固性树脂100份、固化剂1.5份、氧化石墨烯1份、水20份；三聚氰胺耐磨胶的组分及重量份为：三聚氰胺甲醛树脂(MF)100份、固化剂2份、聚氨酯40份、纳米三氧化二铝20份、水5份；热固性树脂为三聚氰胺甲醛树脂，固化剂为酸酐和聚醚。
上述耐磨防火饰面板的制造方法为：根据耐磨防火饰面板的厚度选择相应的压机托盘，由下至上分别将底纹版、离型膜、根据一次热压成型耐磨防火饰面板结构由下至上的各层、离型膜、压纹板铺设在托盘中，放入热压机在温度130℃-160℃，压力1-20MPa条件下热压发泡2-60分钟后，在冷压机1-20MPa压力条件下冷却10-30分钟，拆除压纹版、离型膜、底纹版后形成一次热压成型耐磨防火饰面板。
实施例3：
一种耐磨防火饰面板，其特征在于该耐磨防火饰面板为二次热压成型，具有两种结构，如图6所示，其第一种结构为由上至下分别是耐磨表现层61、高强度防火板62、平衡层63；如图7所示，其第二种结构为由上至下分别耐磨层71、花纹层72、高强度防火板73、平衡层74。耐磨表现层是已商用的三聚氰胺喷涂纸或者用印刷花纹图案的花色纸经过浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥裁切而成，耐磨层是已商用的透明三聚氰胺耐磨纸或者用透明纸浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥裁切而成，高强度防火板根据实施例制备而成，花纹层是由PE、PP、PET、PETG、PVC等材料中的一种制备的白膜或者纸印刷花纹图案而成，平衡层是已商用的三聚氰胺平衡纸或者用原纸经过浸渍热固性树脂混合溶液后干燥裁切而成，纤维毡可以为化学纤维、天然纤维、无机纤维中的一种或几种编织或者针刺而成的，常用的化学纤维包括：涤纶、丙纶、腈纶、氨纶、锦纶、维纶等，天然纤维包括：麻纤维、棉纤维、竹纤维、木纤维、秸秆纤维等，无机纤维包括碳纤维、玻璃纤维、硅酸铝纤维、陶瓷纤维、玄武岩纤维等。
热固性树脂混合溶液使用了热固性树脂、固化剂、氧化石墨烯、水，具体组分及重量份为：
三聚氰胺耐磨胶使用了三聚氰胺甲醛树脂(MF)、固化剂、聚氨酯树脂、纳米三氧化二铝、水，具体组分及重量份为：
热固性树脂为三聚氰胺甲醛树脂、酚醛树脂、环氧树脂、不饱和聚酯中的一种或几种。
固化剂为多元胺、酸酐、聚醚、过氧化甲乙酮中的一种或几种。
本实施例中参与的测试产品为第一种结构，所述耐磨表现层是已商用的用印刷花纹图案的花色纸经过浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥 裁切而成，高强度防火板为实施例1参与测试的产品，平衡层是已商用的三聚氰胺平衡纸经过浸渍热固性树脂混合溶液后干燥裁切而成；热固性树脂混合溶液的组分及重量份为：热固性树脂100份、固化剂1份、氧化石墨烯1份、水20份；三聚氰胺耐磨胶的组分及重量份为：三聚氰胺甲醛树脂(MF)100份、固化剂2份、聚氨酯40份、纳米三氧化二铝20份、水6份；热固性树脂为环氧树脂，固化剂为过氧化甲乙酮。
上述耐磨防火饰面板的制造方法为：先根据本发明高强度防火板制造方法制造高强度防火板，根据二次热压成型耐磨防火饰面板的厚度选择相应的压机托盘，将二步法耐磨防火饰面板结构由下至上的各层铺设在托盘中，放入热压机在温度130℃-190℃，压力1-50MPa条件下热压0.5-10分钟，最终形成二步法耐磨防火饰面板。
实施例4：
一种耐磨防火饰面板，其特征在于该耐磨防火饰面板为涂胶复合成型，如图8所示，其结构为由上至下分别是耐磨表现层81、胶82、高强度防火板83、胶84、平衡层85。耐磨表现层是已商用的三聚氰胺喷涂纸或者用印刷花纹图案的花色纸经过浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥裁切而成，高强度防火板根据实施例制备而成，平衡层是已商用的三聚氰胺平衡纸或者用纸经过浸渍热固性树脂混合溶液后干燥裁切而成，纤维毡可以为化学纤维、天然纤维、无机纤维中的一种或几种编织或者针刺而成的，常用的化学纤维包括：涤纶、丙纶、腈纶、氨纶、锦纶、维纶等，天然纤维包括：麻纤维、棉纤维、竹纤维、木纤维、秸秆纤维等，无机纤维包括碳纤维、玻璃纤维、硅酸铝纤维、陶瓷纤维、玄武岩纤维等。
热固性树脂混合溶液使用了热固性树脂、固化剂、氧化石墨烯、水，具体组分及重量份为：
三聚氰胺耐磨胶使用了三聚氰胺甲醛树脂(MF)、固化剂、聚氨酯树脂、纳米三氧化二铝、水，具体组分及重量份为：
热固性树脂为三聚氰胺甲醛树脂、酚醛树脂、环氧树脂、不饱和聚酯中的一种或几种。
固化剂为多元胺、酸酐、聚醚、过氧化甲乙酮中的一种或几种。
本实施例中参与测试的产品中，耐磨表现层是已商用的用印刷花纹图案的花色纸经过浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥裁切而成，高强度防火板为实施例1参与测试的产品，平衡层是已商用的三聚氰胺平衡纸经过浸渍热固性树脂混合溶液后干燥裁切而成；热固性树脂混合溶液的组分及重量份同实施例2中参与测试的产品；三聚氰胺耐磨胶的组分及重量份同实施例2中参与测试的产品；热固性树脂及固化剂同实施例2中参与测试的产品。
上述耐磨防火饰面板的制造方法为：先根据本发明高强度防火板制造方法制造高强度防火板，在高强度防火板上双面涂胶，上方贴合耐磨表现层，下方贴合平衡层。
性能测试：
防火燃烧性测试：样品尺寸长*宽*厚＝127*12.7*5mm，用酒精灯垂直燃烧15min，样品长度垂直向下移动与距离酒精灯火焰顶端下方10mm处火焰部分接触燃烧。结构如下表所示：
*注：本发明为本发明实施例1-4的产品。
耐磨性能测试：根据NALFA Standards LF 01-2011LAMINATE FLOORINGSPECIFICATIONS AND TEST METHODS，第3.7Wear Resistance方法测试，结果如下表所示：
表面微刮伤性能测试：根据标准EN 16094:2012 Laminate floor coverings—Test method for thedetermination ofmicro-scratch resistance测试，结果如下表所示：
*注：本发明为本发明实施例1-4的产品。
强度(刚性)测试：根据标准ASTM D1037–12Standard Test Methods forEvaluating Properties of Wood-Base Fiber and ParticlePanel Materials测试，样品厚度全部为5mm，结构如下表所示：
Claims (14)
- 一种高强度防火板，其特征在于：所述高强度防火板具有两种结构，其第一种结构为三层热压复合结构，由上至下分别为纤维层、发泡纤维层、纤维层，其第二种结构为纤维层热压复合而成。
- 一种耐磨防火饰面板，其特征在于：所述耐磨防火饰面板由包含权利要求1所述的高强度防火板经一次热压成型，或者可以二次热压成型，或者涂胶复合成型制得。
- 根据权利要求2所述的耐磨防火饰面板，其特征在于：所述的一次热压成型具有四种结构，其第一种结构为由上至下分别是耐磨表现层、纤维层、发泡纤维层、纤维层、平衡层，其第二种结构为由上至下分别耐磨表现层、纤维层、平衡层，其第三种结构为由上至下分别耐磨层、花纹层、纤维层、发泡纤维层、纤维层、平衡层，其第四种结构为由上至下分别耐磨层、花纹层、纤维层、平衡层；所述的二次热压成型具有两种结构，其第一种结构为由上至下分别是耐磨表现层、高强度防火板、平衡层，其第二种结构为由上至下分别耐磨层、花纹层、高强度防火板、平衡层；所述的涂胶复合成型，其结构为由上至下分别是耐磨表现层、胶、高强度防火板、胶、平衡层。
- 根据权利要求3所述的耐磨防火饰面板，其特征在于：所述的耐磨表现层是已商用的三聚氰胺喷涂纸或者用印刷花纹图案的花色纸经过浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥裁切而成；所述的耐磨层是已商用的透明三聚氰胺耐磨纸或者用透明纸浸渍热固性树脂混合溶液干燥后表面滚涂三聚氰胺耐磨胶后干燥裁切而成；所述的纤维层是单张或者多张纤维毡经过浸渍热固性树脂混合溶液后干燥裁切组成；所述的发泡纤维层是单张或者多张纤维毡经过浸渍热固性树脂发泡混合溶液后干燥裁切组成；所述的花纹层是由PE、PP、PET、PETG、PVC材料中的一种制备的白膜或者纸印刷花纹图案而成的；所述的平衡层是已商用的三聚氰胺平衡纸或者纸经过浸渍热固性树脂混合溶液后干燥裁切而成。
- 根据权利要求4所述的耐磨防火饰面板，其特征在于：所述的纤维毡为化学纤维、天然纤维、无机纤维中的一种或几种编织或针刺而成的毡，所述的化学纤维为涤纶、丙纶、腈纶、氨纶、锦纶、维纶中的一种或几种，天然纤维为麻纤维、棉纤维、竹纤维、木纤维、秸秆纤维中的一种或几种，无机纤维为碳纤维、玻璃纤维、硅酸铝纤维、陶瓷纤维、玄武岩纤维中的一种或几种。
- 根据权利要求4所述的耐磨防火饰面板，其特征在于：所述的热固性树脂混合溶液由热固性树脂、固化剂、氧化石墨烯、水组成，具体组分及重量份为：
- 根据权利要求4所述的耐磨防火饰面板，其特征在于：所述的三聚氰胺耐磨胶由三聚氰胺甲醛树脂(MF)、固化剂、聚氨酯树脂、纳米三氧化二铝、水组成，具体组分及重量份为：
- 根据权利要求4所述的耐磨防火饰面板，其特征在于：所述的热固性树脂发泡混合溶液由热固性树脂、固化剂、发泡剂、水组成，具体组分及重量份为：
- 根据权利要求6或8所述的耐磨防火饰面板，其特征在于：所述的热固性树脂为三聚氰胺甲醛树脂、酚醛树脂、环氧树脂、不饱和聚酯中的一种或几种。
- 根据权利要求6-8任一项所述的耐磨防火饰面板，其特征在于：所述的固化剂为多元胺、酸酐、聚醚、过氧化甲乙酮中的一种或几种。
- 权利要求1-10任一项所述的高强度防火板制造方法，其特征在于，包括以下步骤：根据高强度防火板的厚度选择相应的压机托盘，由下至上分别将离型膜、根据结构由下至上铺设高强度防火板各层、离型膜铺设在托盘中，放入热压机在温度130℃-160℃，压力1-20MPa条件下热压发泡2-60min后，在冷压机1-20MPa压力条件下冷却10-30min，拆除离型膜后形成的高强度防火板。
- 权利要求2-10任一项所述的耐磨防火饰面板的制造方法，其特征在于，包括3种制造方法，其一次热压成型制造方法为：根据耐磨防火饰面板的厚度选择相应的压机托 盘，由下至上分别将底纹版、离型膜、根据一次热压成型耐磨防火饰面板结构由下至上的各层、离型膜、压纹板铺设在托盘中，放入热压机在温度130℃-160℃，压力1-20MPa条件下热压发泡2-60分钟后，在冷压机1-20MPa压力条件下冷却10-30分钟，拆除压纹版、离型膜、底纹版后形成一次热压成型耐磨防火饰面板；其二次热压成型制造方法为：先根据本发明高强度防火板制造方法制造高强度防火板，根据二步法耐磨防火饰面板的厚度选择相应的压机托盘，将二步法耐磨防火饰面板结构由下至上的各层铺设在托盘中，放入热压机在温度130℃-190℃，压力1-50MPa条件下热压0.5-10分钟，最终形成二次热压成型耐磨防火饰面板；其涂胶复合成型制造方法为：先根据本发明高强度防火板制造方法制造高强度防火板，在高强度防火板上双面涂胶，上方贴合耐磨表现层，下方贴合平衡层。
- 高强度防火板在隔断、防护板、贴面形成饰面板用于装饰板、隔音板中的应用。
- 耐磨防火饰面板在地板、墙板、装饰板中的应用。
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