WO2022091780A1 - 熱可塑性樹脂及びそれを含む光学部材 - Google Patents
熱可塑性樹脂及びそれを含む光学部材 Download PDFInfo
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- WO2022091780A1 WO2022091780A1 PCT/JP2021/037853 JP2021037853W WO2022091780A1 WO 2022091780 A1 WO2022091780 A1 WO 2022091780A1 JP 2021037853 W JP2021037853 W JP 2021037853W WO 2022091780 A1 WO2022091780 A1 WO 2022091780A1
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- LZGAFUNRMOUFFI-UHFFFAOYSA-N [3-(2-cyano-3,3-diphenylprop-2-enoyl)oxyphenyl] 2-cyano-3,3-diphenylprop-2-enoate Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)=C(C#N)C(=O)OC(C=1)=CC=CC=1OC(=O)C(C#N)=C(C=1C=CC=CC=1)C1=CC=CC=C1 LZGAFUNRMOUFFI-UHFFFAOYSA-N 0.000 description 1
- VSVVZZQIUJXYQA-UHFFFAOYSA-N [3-(3-dodecylsulfanylpropanoyloxy)-2,2-bis(3-dodecylsulfanylpropanoyloxymethyl)propyl] 3-dodecylsulfanylpropanoate Chemical group CCCCCCCCCCCCSCCC(=O)OCC(COC(=O)CCSCCCCCCCCCCCC)(COC(=O)CCSCCCCCCCCCCCC)COC(=O)CCSCCCCCCCCCCCC VSVVZZQIUJXYQA-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 description 1
- BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 description 1
- ZUHUBHPNTSKVDZ-UHFFFAOYSA-N [4-[9-[4-(hydroxymethoxy)phenyl]fluoren-9-yl]phenoxy]methanol Chemical compound C1=CC(OCO)=CC=C1C1(C=2C=CC(OCO)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 ZUHUBHPNTSKVDZ-UHFFFAOYSA-N 0.000 description 1
- NCPIYHBOLXSJJR-UHFFFAOYSA-H [Al+3].[Al+3].[O-]P([O-])=O.[O-]P([O-])=O.[O-]P([O-])=O Chemical compound [Al+3].[Al+3].[O-]P([O-])=O.[O-]P([O-])=O.[O-]P([O-])=O NCPIYHBOLXSJJR-UHFFFAOYSA-H 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
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- 229910052783 alkali metal Inorganic materials 0.000 description 1
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- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
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- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
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- KMJRBSYFFVNPPK-UHFFFAOYSA-K aluminum;dodecanoate Chemical compound [Al+3].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O KMJRBSYFFVNPPK-UHFFFAOYSA-K 0.000 description 1
- YNCDEEFMDXHURQ-UHFFFAOYSA-N aluminum;ethyl 3-oxobutanoate Chemical compound [Al].CCOC(=O)CC(C)=O YNCDEEFMDXHURQ-UHFFFAOYSA-N 0.000 description 1
- LIQDVINWFSWENU-UHFFFAOYSA-K aluminum;prop-2-enoate Chemical compound [Al+3].[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C LIQDVINWFSWENU-UHFFFAOYSA-K 0.000 description 1
- DMGNPLVEZUUCBT-UHFFFAOYSA-K aluminum;propanoate Chemical compound [Al+3].CCC([O-])=O.CCC([O-])=O.CCC([O-])=O DMGNPLVEZUUCBT-UHFFFAOYSA-K 0.000 description 1
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- 125000004429 atom Chemical group 0.000 description 1
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- UCVMQZHZWWEPRC-UHFFFAOYSA-L barium(2+);hydrogen carbonate Chemical compound [Ba+2].OC([O-])=O.OC([O-])=O UCVMQZHZWWEPRC-UHFFFAOYSA-L 0.000 description 1
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
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- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- MUCRFDZUHPMASM-UHFFFAOYSA-N bis(2-chlorophenyl) carbonate Chemical compound ClC1=CC=CC=C1OC(=O)OC1=CC=CC=C1Cl MUCRFDZUHPMASM-UHFFFAOYSA-N 0.000 description 1
- ZCLVNIZJEKLGFA-UHFFFAOYSA-H bis(4,5-dioxo-1,3,2-dioxalumolan-2-yl) oxalate Chemical compound [Al+3].[Al+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O ZCLVNIZJEKLGFA-UHFFFAOYSA-H 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
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- 125000005619 boric acid group Chemical class 0.000 description 1
- MOOAHMCRPCTRLV-UHFFFAOYSA-N boron sodium Chemical compound [B].[Na] MOOAHMCRPCTRLV-UHFFFAOYSA-N 0.000 description 1
- FLLNLJJKHKZKMB-UHFFFAOYSA-N boron;tetramethylazanium Chemical compound [B].C[N+](C)(C)C FLLNLJJKHKZKMB-UHFFFAOYSA-N 0.000 description 1
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 description 1
- NIKBCKTWWPVAIC-UHFFFAOYSA-N butyl benzenesulfonate Chemical compound CCCCOS(=O)(=O)C1=CC=CC=C1 NIKBCKTWWPVAIC-UHFFFAOYSA-N 0.000 description 1
- ZOAIGCHJWKDIPJ-UHFFFAOYSA-M caesium acetate Chemical compound [Cs+].CC([O-])=O ZOAIGCHJWKDIPJ-UHFFFAOYSA-M 0.000 description 1
- FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 description 1
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- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
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- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
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- 235000013539 calcium stearate Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- BLUMOBPWAAOPOY-UHFFFAOYSA-M cesium;benzoate Chemical compound [Cs+].[O-]C(=O)C1=CC=CC=C1 BLUMOBPWAAOPOY-UHFFFAOYSA-M 0.000 description 1
- WLZGEDNSZCPRCJ-UHFFFAOYSA-M cesium;octadecanoate Chemical compound [Cs+].CCCCCCCCCCCCCCCCCC([O-])=O WLZGEDNSZCPRCJ-UHFFFAOYSA-M 0.000 description 1
- 230000008859 change Effects 0.000 description 1
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- 239000007795 chemical reaction product Substances 0.000 description 1
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- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
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- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 description 1
- VZEGPPPCKHRYGO-UHFFFAOYSA-N diethoxyphosphorylbenzene Chemical compound CCOP(=O)(OCC)C1=CC=CC=C1 VZEGPPPCKHRYGO-UHFFFAOYSA-N 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- XMQYIPNJVLNWOE-UHFFFAOYSA-N dioctyl hydrogen phosphite Chemical compound CCCCCCCCOP(O)OCCCCCCCC XMQYIPNJVLNWOE-UHFFFAOYSA-N 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- 235000019797 dipotassium phosphate Nutrition 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- TYJOJLOWRIQYQM-UHFFFAOYSA-L disodium;phenyl phosphate Chemical compound [Na+].[Na+].[O-]P([O-])(=O)OC1=CC=CC=C1 TYJOJLOWRIQYQM-UHFFFAOYSA-L 0.000 description 1
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- 238000005886 esterification reaction Methods 0.000 description 1
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- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- XDRMBCMMABGNMM-UHFFFAOYSA-N ethyl benzenesulfonate Chemical compound CCOS(=O)(=O)C1=CC=CC=C1 XDRMBCMMABGNMM-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
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- 150000002291 germanium compounds Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- IVQOVYWBHRSGJI-UHFFFAOYSA-N hexyl 4-methylbenzenesulfonate Chemical compound CCCCCCOS(=O)(=O)C1=CC=C(C)C=C1 IVQOVYWBHRSGJI-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910000032 lithium hydrogen carbonate Inorganic materials 0.000 description 1
- HQRPHMAXFVUBJX-UHFFFAOYSA-M lithium;hydrogen carbonate Chemical compound [Li+].OC([O-])=O HQRPHMAXFVUBJX-UHFFFAOYSA-M 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- QWDJLDTYWNBUKE-UHFFFAOYSA-L magnesium bicarbonate Chemical compound [Mg+2].OC([O-])=O.OC([O-])=O QWDJLDTYWNBUKE-UHFFFAOYSA-L 0.000 description 1
- 229910000022 magnesium bicarbonate Inorganic materials 0.000 description 1
- 239000002370 magnesium bicarbonate Substances 0.000 description 1
- 235000014824 magnesium bicarbonate Nutrition 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 230000005499 meniscus Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- VUQUOGPMUUJORT-UHFFFAOYSA-N methyl 4-methylbenzenesulfonate Chemical compound COS(=O)(=O)C1=CC=C(C)C=C1 VUQUOGPMUUJORT-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- KDQQMEAEIKFPLQ-UHFFFAOYSA-N n-(1-cyanocyclohexyl)-2-fluorobenzamide Chemical compound FC1=CC=CC=C1C(=O)NC1(C#N)CCCCC1 KDQQMEAEIKFPLQ-UHFFFAOYSA-N 0.000 description 1
- NGBBFNQEPSYETA-UHFFFAOYSA-N octadecanoic acid;hydrochloride Chemical compound Cl.CCCCCCCCCCCCCCCCCC(O)=O NGBBFNQEPSYETA-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- KCRLWVVFAVLSAP-UHFFFAOYSA-N octyl dihydrogen phosphite Chemical compound CCCCCCCCOP(O)O KCRLWVVFAVLSAP-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- LYTNHSCLZRMKON-UHFFFAOYSA-L oxygen(2-);zirconium(4+);diacetate Chemical compound [O-2].[Zr+4].CC([O-])=O.CC([O-])=O LYTNHSCLZRMKON-UHFFFAOYSA-L 0.000 description 1
- RKHQZMOCQHXUBC-UHFFFAOYSA-N phenol;potassium Chemical compound [K].OC1=CC=CC=C1 RKHQZMOCQHXUBC-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- KZQFPRKQBWRRHQ-UHFFFAOYSA-N phenyl 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)OC1=CC=CC=C1 KZQFPRKQBWRRHQ-UHFFFAOYSA-N 0.000 description 1
- VCAFTIGPOYBOIC-UHFFFAOYSA-N phenyl dihydrogen phosphite Chemical compound OP(O)OC1=CC=CC=C1 VCAFTIGPOYBOIC-UHFFFAOYSA-N 0.000 description 1
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical compound OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 description 1
- HXITXNWTGFUOAU-UHFFFAOYSA-N phenylboronic acid Chemical compound OB(O)C1=CC=CC=C1 HXITXNWTGFUOAU-UHFFFAOYSA-N 0.000 description 1
- IBIRZFNPWYRWOG-UHFFFAOYSA-N phosphane;phosphoric acid Chemical class P.OP(O)(O)=O IBIRZFNPWYRWOG-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003008 phosphonic acid esters Chemical class 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- WJMMDJOFTZAHHS-UHFFFAOYSA-L strontium;carbonic acid;carbonate Chemical compound [Sr+2].OC([O-])=O.OC([O-])=O WJMMDJOFTZAHHS-UHFFFAOYSA-L 0.000 description 1
- FRKHZXHEZFADLA-UHFFFAOYSA-L strontium;octadecanoate Chemical compound [Sr+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O FRKHZXHEZFADLA-UHFFFAOYSA-L 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- VXYADVIJALMOEQ-UHFFFAOYSA-K tris(lactato)aluminium Chemical compound CC(O)C(=O)O[Al](OC(=O)C(C)O)OC(=O)C(C)O VXYADVIJALMOEQ-UHFFFAOYSA-K 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- IFNXAMCERSVZCV-UHFFFAOYSA-L zinc;2-ethylhexanoate Chemical compound [Zn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O IFNXAMCERSVZCV-UHFFFAOYSA-L 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L69/005—Polyester-carbonates
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Definitions
- the present invention relates to a novel thermoplastic resin and an optical member formed thereof, particularly an optical lens.
- Imaging modules are used in devices such as smartphones.
- the optical system used in this image pickup module is required to be miniaturized. As the optical system becomes smaller, the chromatic aberration of the optical system becomes a big problem. Therefore, chromatic aberration can be corrected by combining an optical lens with a high refractive index and a small Abbe number for high dispersion and an optical lens with a low refractive index and a large Abbe number for low dispersion. It is done.
- a polycarbonate resin composition containing a polycarbonate resin having a structural unit represented by the formula (M) and a polycarbonate resin having a structural unit represented by the formula (N) may be kneaded at each ratio. It is described that a polycarbonate resin having a low refractive index and a high Abbe number can be obtained without deteriorating the hue and haze.
- Patent Document 2 describes a polycarbonate resin composition obtained by kneading a polycarbonate resin having a structural unit represented by the formula (P) and a polycarbonate resin having a structural unit represented by the formula (Q). It has been described that the composition has a high refractive index, has a fluidity suitable for molding, has low birefringence, and is less likely to cause optical strain.
- an object of the present invention is to provide a material having a wide high refractive index, which has a high refractive index, a small haze, low birefringence, an excellent balance between heat resistance and moldability, high Charpy impact strength, and low water absorption. It is to efficiently manufacture and provide.
- thermoplastic resin composition comprising a thermoplastic resin (A) containing a unit represented by the formula (1) and a thermoplastic resin (B) containing a unit represented by the formula (2).
- L 1 and L 2 independently represent divalent linking groups, k and l independently represent integers of 0 or more, and R 1 , R 2 , R 3 and R, respectively.
- Reference numeral 4 indicates a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms, respectively, and W indicates a divalent linking group.
- L 3 and L 4 independently represent divalent linking groups, m and n independently represent integers greater than or equal to 0, and R 5 , R 6 , R 7 and R 8 respectively. Independently indicate a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms.
- W in the formula (1) comprises the formula (3) or the formula (4).
- L 5 and L 6 independently represent divalent linking groups, and o and p independently represent integers of 0 or more, R 9 , R 10 , R 11 and R 12 independently represents a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms.
- ring Z represents the same or different aromatic hydrocarbon ring
- L 7 and L 8 each independently represent a divalent linking group
- q and r independently represent 0 or more.
- R 13 , R 14 , R 15 and R 16 each independently represent a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms.
- ⁇ ⁇ Aspect 3 The thermoplastic resin composition according to aspect 2, wherein Z in the formula (4) is a naphthalene ring.
- ⁇ Aspect 4 >> The thermoplastic resin composition according to any one of aspects 1 to 3, wherein the haze when measured to a thickness of 3 mm is 0.5% or less.
- thermoplastic resin composition according to any one of aspects 1 to 4 wherein the thermoplastic resin (A) and the thermoplastic resin (B) have a mass ratio (A: B) of 1: 99 to 99: 1.
- ⁇ Aspect 6 The thermoplastic resin composition according to any one of aspects 1 to 5, which has a refractive index of 1.645 to 1.690.
- ⁇ Aspect 7 The thermoplastic resin composition according to any one of aspects 1 to 6, wherein the orientation birefringence is 4.5 ⁇ 10 -3 or less.
- notchless Charpy impact strength is 25 J / m 2 or more.
- thermoplastic resin composition according to any one of aspects 1 to 8 wherein the thermoplastic resin (A) is a polyester carbonate resin.
- thermoplastic resin (B) is a polyester carbonate resin or a polycarbonate resin.
- thermoplastic resin composition according to any one of aspects 1 to 10 is a polyester carbonate resin or a polycarbonate resin.
- thermoplastic resin composition according to any one of aspects 1 to 10 is a polyester carbonate resin or a polycarbonate resin.
- thermoplastic resin composition according to any one of aspects 1 to 10 is a polyester carbonate resin or a polycarbonate resin.
- An optical member comprising the thermoplastic resin composition according to any one of aspects 1 to 10.
- thermoplastic resin composition of the present invention has an excellent balance of high refractive index, low birefringence, heat resistance and moldability, has a small haze, has high sharpy impact strength, and exhibits low water absorption, and has a wide high refractive index range.
- the material can be manufactured efficiently.
- thermoplastic resin (A) contains a structural unit represented by the above formula (1).
- R 1 , R 2 , R 3 and R 4 independently represent a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms, and the hydrocarbon groups include an alkyl group and a cyclo. Examples thereof include an alkyl group and an aryl group.
- alkyl group examples include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a t-butyl group and the like, and a methyl group is preferable.
- cycloalkyl group examples include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a bicyclo [1.1.1] pentanyl group.
- aryl group examples include a phenyl group, a tolyl group, a naphthyl group, a xylyl group and the like, and a phenyl group is preferable.
- R 1 to R 4 are preferably a hydrogen atom, a methyl group, or a phenyl group, more preferably a hydrogen atom or a phenyl group, and even more preferably a hydrogen atom.
- L 1 and L 2 each independently represent a divalent linking group, and examples thereof include an alkylene group having 1 to 4 carbon atoms, preferably a methylene group, an ethylene group, or a propylene group. , Methylene groups are more preferred.
- k and l each independently represent an integer of 0 or more, preferably 0 to 2, and more preferably 1.
- W represents a divalent linking group, preferably the above formula (3) or the above formula (4).
- the 1,1'-binaphthyl skeleton has a conformation that improves the refractive index and is orthogonal to the bond axis connecting the two naphthalene rings, thus reducing birefringence. effective.
- R 9 , R 10 , R 11 and R 12 independently represent a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms, and the hydrocarbon groups include an alkyl group and a cyclo. Alkyl groups and aryl groups can be mentioned.
- alkyl group examples include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a t-butyl group and the like, and a methyl group is preferable.
- cycloalkyl group examples include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a bicyclo [1.1.1] pentanyl group.
- aryl group examples include a phenyl group, a tolyl group, a naphthyl group, a xylyl group and the like, and a phenyl group is preferable.
- R 9 to R 12 are preferably a hydrogen atom, a methyl group, and a phenyl group, more preferably a hydrogen atom or a phenyl group, and even more preferably a hydrogen atom.
- L 5 and L 6 each independently represent a divalent linking group, and examples thereof include an alkylene group having 1 to 4 carbon atoms, preferably an ethylene group or a propylene group. More preferably, it shows an ethylene group.
- O and p each independently indicate an integer of 0 or more, preferably 0 to 2, and more preferably 1.
- the 1,1'-binaphthyl skeleton has a conformation that improves the refractive index and is orthogonal to the bond axis connecting the two naphthalene rings, thus reducing birefringence. effective.
- Z represents the same or different aromatic hydrocarbon ring, and examples thereof include a naphthalene ring and a benzene ring, and a naphthalene ring is preferable.
- R 13 , R 14 , R 15 and R 16 independently represent a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms, and the hydrocarbon groups include an alkyl group, a cycloalkyl group and an aryl group. Can be mentioned.
- alkyl group examples include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a t-butyl group and the like, and a methyl group is preferable.
- cycloalkyl group examples include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a bicyclo [1.1.1] pentanyl group.
- aryl group examples include a phenyl group, a tolyl group, a naphthyl group, a xylyl group and the like, and a phenyl group is preferable.
- each of R 13 to R 16 is preferably a hydrogen atom, a methyl group, or a phenyl group, more preferably a hydrogen atom or a phenyl group, and even more preferably a hydrogen atom.
- L 7 and L 8 each independently represent a divalent linking group, and examples thereof include an alkylene group having 1 to 4 carbon atoms, preferably an ethylene group or a propylene group, and more preferably an ethylene group. ..
- Q and r each independently indicate an integer of 0 or more, preferably 0 to 2, and more preferably 1.
- the thermoplastic resin (A) may contain the unit represented by the above formula (1) alone, or may contain two or more kinds in combination.
- the unit in which W is the above formula (3) and the unit in which W is the above formula (4) may be included.
- thermoplastic resin (A) a polyester resin or a polyester carbonate resin is preferable, and a polyester carbonate resin is more preferable.
- Dicarboxylic acid component used for the unit represented by the above formula (1) >> The dicarboxylic acid component used in the unit represented by the above formula (1) of the thermoplastic resin of the present invention is mainly a compound represented by the formula (a) or an ester-forming derivative thereof.
- L 1, L 2 , k, l, R 1 to R 4 are the same as each formula of the above formula (1).
- ester-forming derivative acid chloride and esters such as methyl ester, ethyl ester and phenyl ester may be used.
- ⁇ Glycol component used for the unit represented by the above formula (1) >> The diol component used in the unit represented by W in the above formula (1) of the thermoplastic resin of the present invention includes ethylene glycol, propanediol, butanediol, pentanediol, hexanediol, heptanediol, octanediol, and nonane.
- Glycol tricyclo [5.2.1.0 2,6 ] decanedimethanol, cyclohexane-1,4-dimethanol, decalin-2,6-dimethanol, norbornan dimethanol, pentacyclopentadecanedimethanol, cyclopentane- 1,3-Dimethanol, Spiroglycol, Isosorbide, Isomannide, Isoidide, Hydroquinone, Resolsinol, Dihydroxynaphthalene, 2,2-Bis (4-hydroxyphenyl) Propane, 2,2-Bis (3-Methyl-4-hydroxyphenyl) ) Propane, 1,1-bis (4-hydroxyphenyl) -1-phenylethane, 1,3-bis (2- (4-hydroxyphenyl) -2-propyl) benzene, 1,1-bis (4-hydroxy) Phenyl) -3,3,5-trimethylcyclohexane, 1,1-bis (4-hydroxyphenyl) cyclohexan
- L 5 L 6 , o, p, R 9 to R 12 are the same as each formula of the above formula (3).
- the above formula (b) is 2,2'-bis (2-hydroxyethoxy) -1,1'-binaphthyl, 2,2'-bis (2-hydroxyethoxy) -3,3'-diphenyl. -1,1'-binaphthyl, 2,2'-bis (2-hydroxyethoxy) -6,6'-diphenyl-1,1'-binaphthyl, 2,2'-bis (2-hydroxyethoxy) -7, 7'-diphenyl-1,1'-binaphthyl, 2,2'-bis (2-hydroxyethoxy) -3,3'-dimethyl-1,1'-binaphthyl, 2,2'-bis (2-hydroxyethoxy) ) -6,6'-dimethyl-1,1'-binaphthyl, 2,2'-bis (2-hydroxyethoxy) -7,7'-dimethyl-1,1'-binaphthyl, 1,1'-bi- 2-
- the above formula (c) is 9,9-bis (6- (2-hydroxyethoxy) -2-naphthyl) -2,7-dimethylfluorene, 9,9-bis (6- (2-hydroxy). Ethoxy) -2-naphthyl) -2,7-diphenylfluorene, 9,9-bis (6- (2-hydroxyethoxy) -2-naphthyl) fluorene, 9,9-bis (6- (3-hydroxypropoxy) -2-naphthyl) -2,7-diphenylfluorene, 9,9-bis (6- (3-hydroxypropoxy) -2-naphthyl) -2,7-dimethylfluorene, 9,9-bis (6- (3) -Hydroxypropoxy) -2-naphthyl) fluorene, 9,9-bis (6-hydroxy-2-naphthyl) -2,7-diphenylfluorene, 9,9-bis (6
- 9,9-bis (6- (3-hydroxypropoxy) -2-naphthyl) fluorene, 9,9-bis (6- (2-hydroxyethoxy) -2-naphthyl) fluorene, 9,9-bis ( 6-Hydroxy-2-naphthyl) fluorene is preferred, and 9,9-bis (6- (2-hydroxyethoxy) -2-naphthyl) fluorene is more preferred.
- thermoplastic resin (A) of the present invention may contain a repeating unit other than the repeating unit represented by the above formula (1) as long as the above-mentioned advantageous effects of the present invention can be obtained.
- the ratio of the structural unit represented by the above formula (1) to the thermoplastic resin (A) in the present invention is preferably 50 mol% or more, more preferably 70 mol% or more.
- Polycarbonate, polyester and polyester carbonate are examples of the repeating unit other than the repeating unit represented by the above formula (1), and their dicarboxylic acid components and diol components are shown below.
- dicarboxylic acid component examples include aliphatic dicarboxylic acid components such as malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, methylmalonic acid, and ethylmalonic acid, phthalic acid, isophthalic acid, and terephthalic acid.
- aliphatic dicarboxylic acid components such as malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, methylmalonic acid, and ethylmalonic acid, phthalic acid, isophthalic acid, and terephthalic acid.
- Monocyclic aromatic dicarboxylic acid components such as 2,6-naphthalenedicarboxylic acid, 2,7-naphthalenedicarboxylic acid, 2,3-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid, 1,8-naphthalenedicarboxylic acid , Anthracendicarboxylic acid, phenanthrangecarboxylic acid, 9,9-bis (carboxymethyl) fluorene, 9,9-bis (2-carboxyethyl) fluorene, 9,9-bis (1-carboxyethyl) fluorene, 9,9- Bis (1-carboxypropyl) fluorene, 9,9-bis (2-carboxypropyl) fluorene, 9,9-bis (2-carboxy-1-methylethyl) fluorene, 9,9-bis (2-carboxy-1) -Methylpropyl) fluorene, 9,9-bis (2-carboxybuty
- the diol components include ethylene glycol, propanediol, butanediol, pentanediol, hexanediol, heptanediol, octanediol, nonanediol, tricyclo [5.2.1.0 2,6 ] decandimethanol, cyclohexane-1, 4-Dimethanol, Decalin-2,6-Dimethanol, Norbornan Dimethanol, Pentacyclopentadecane Dimethanol, Cyclopentane-1,3-Dimethanol, Spiroglycol, Isosorbide, Isomannide, Isoidide, Hydroquinone, Resolsinol, Dihydroxynaphthalene, 2,2-bis (4-hydroxyphenyl) propane, 2,2-bis (3-methyl-4-hydroxyphenyl) propane, 1,1-bis (4-hydroxyphenyl) -1-phenylethane, 1,3 -Bis (2- (4-hydroxyphenyl
- R 5 , R 6 , R 7 and R 8 independently represent a hydrogen atom and a hydrocarbon group having 1 to 20 carbon atoms, and the hydrocarbon groups include an alkyl group and a cyclo. Alkyl groups and aryl groups can be mentioned.
- alkyl group examples include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a t-butyl group and the like, and a methyl group is preferable.
- cycloalkyl group examples include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a bicyclo [1.1.1] pentanyl group.
- aryl group examples include a phenyl group, a tolyl group, a naphthyl group, a xylyl group and the like, and a phenyl group is preferable.
- R 5 to R 8 are each independently preferably a hydrogen atom, a methyl group and a phenyl group, R 5 and R 6 are independently hydrogen atoms or phenyl groups, and R 7 and R 8 are hydrogen. It is more preferably an atom.
- L 3 and L 4 each independently represent a divalent linking group, and examples thereof include an alkylene group having 1 to 4 carbon atoms, preferably an ethylene group or a propylene group. More preferably, it shows an ethylene group.
- n and n each independently represent an integer of 0 or more, preferably 0 to 2, and more preferably 1.
- thermoplastic resin (A) a polycarbonate resin or a polyester carbonate resin is preferable.
- ⁇ Glycol component used for the unit represented by the above formula (2) >>
- diol component used in the unit represented by the above formula (2) of the thermoplastic resin of the present invention a raw material represented by the formula (d) is preferably used.
- L 3 L 4 , m, n, R 5 to R 8 are the same as each formula of the above formula (2).
- thermoplastic resin (B) in the present invention has a structural unit represented by the above formula (2), but may contain other structural units as long as the effect according to the present invention is not impaired.
- the ratio of the structural unit represented by the above formula (2) to the thermoplastic resin (B) in the present invention is preferably 70 mol% or more, more preferably 80 mol% or more.
- Polycarbonate, polyester and polyester carbonate are preferable as other repeating units, and the dicarboxylic acid component and the diol component constituting them are shown below.
- dicarboxylic acid component examples include aliphatic dicarboxylic acid components such as malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, methylmalonic acid, and ethylmalonic acid, phthalic acid, isophthalic acid, and terephthalic acid.
- Monocyclic aromatic dicarboxylic acid components such as 2,6-naphthalenedicarboxylic acid, 2,7-naphthalenedicarboxylic acid, 2,3-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid, 1,8-naphthalenedicarboxylic acid , Anthracendicarboxylic acid, phenanthrangecarboxylic acid, 9,9-bis (carboxymethyl) fluorene, 9,9-bis (2-carboxyethyl) fluorene, 9,9-bis (1-carboxyethyl) fluorene, 9,9- Bis (1-carboxypropyl) fluorene, 9,9-bis (2-carboxypropyl) fluorene, 9,9-bis (2-carboxy-1-methylethyl) fluorene, 9,9-bis (2-carboxy-1) -Methylpropyl) fluorene, 9,9-bis (2-carboxybuty
- Acid 2,6-naphthalenedicarboxylic acid, 9,9-bis (2-carboxyethyl) fluorene are preferable, and terephthalic acid is more preferable. These may be used alone or in combination of two or more. Further, as the ester-forming derivative, acid chloride and esters such as methyl ester, ethyl ester and phenyl ester may be used.
- the diol components include ethylene glycol, propanediol, butanediol, pentanediol, hexanediol, heptanediol, octanediol, nonanediol, tricyclo [5.2.1.0 2,6 ] decandimethanol, cyclohexane-1, 4-Dimethanol, Decalin-2,6-Dimethanol, Norbornan Dimethanol, Pentacyclopentadecane Dimethanol, Cyclopentane-1,3-Dimethanol, Spiroglycol, Isosorbide, Isomannide, Isoidide, Hydroquinone, Resolsinol, Dihydroxynaphthalene, 2,2-bis (4-hydroxyphenyl) propane, 2,2-bis (3-methyl-4-hydroxyphenyl) propane, 1,1-bis (4-hydroxyphenyl) -1-phenylethane, 1,3 -Bis (2- (4-hydroxyphenyl
- thermoplastic resin (A) and thermoplastic resin (B) are produced, for example, by a method of reacting a diol component with a carbonate precursor such as phosgene or a carbonic acid diester, or a method of reacting a diol component with a dicarboxylic acid or an ester-forming derivative thereof.
- a carbonate precursor such as phosgene or a carbonic acid diester
- a method of reacting a diol component with a dicarboxylic acid or an ester-forming derivative thereof are shown below.
- a diol component and a dicarboxylic acid component or an ester-forming derivative thereof are generally subjected to an esterification reaction or a transesterification reaction, and the obtained reaction product is subjected to a polycondensation reaction to obtain a high molecular weight substance having a desired molecular weight.
- an appropriate method can be selected from known methods such as a direct polymerization method, a melt polymerization method such as a transesterification method, a solution polymerization method, and an interfacial polymerization method.
- a solution (organic phase) in which dicarboxylic acid chloride is dissolved in an organic solvent that is incompatible with water is mixed with an alkaline aqueous solution (aqueous phase) containing an aromatic diol and a polymerization catalyst, and the temperature is 50 ° C. or lower.
- a method of carrying out the polymerization reaction while stirring at a temperature of 25 ° C. or lower for 0.5 to 8 hours is preferable.
- a solvent that is incompatible with water and dissolves the polyester resin of the present invention is preferable.
- a solvent include chlorine-based solvents such as methylene chloride, 1,2-dichloroethane, chloroform and chlorobenzene, and aromatic hydrocarbon-based solvents such as toluene, benzene and xylene, which are preferably used in production.
- Methylene chloride is more preferable because it is easy.
- alkaline aqueous solution used for the aqueous phase for example, an aqueous solution of sodium hydroxide, potassium hydroxide, sodium carbonate or the like is preferably mentioned.
- a diol component and a dicarboxylic acid component or a diester thereof are usually mixed and reacted at preferably 120 to 350 ° C., more preferably 150 to 300 ° C., still more preferably 180 to 270 ° C.
- the degree of decompression can be changed stepwise, and finally, the hydroxy compounds such as water and alcohol produced at 0.13 kPa or less can be distilled off from the system.
- the reaction time is usually preferably about 1 to 10 hours.
- a transesterification catalyst and a polymerization catalyst can be used to increase the polymerization rate.
- the ester exchange catalyst a catalyst known per se can be adopted, and for example, a compound containing manganese, magnesium, titanium, zinc, aluminum, calcium, cobalt, sodium, lithium and lead elements can be preferably used. Specifically, oxides, acetates, carboxylates, hydrides, alcoholates, halides, carbonates, sulfates and the like containing these elements can be more preferably mentioned.
- compounds such as manganese, magnesium, zinc, titanium, cobalt oxides, acetates, and alcoholates are more preferable from the viewpoint of melt stability of the polyester resin, hue, and a small amount of resin insoluble foreign matter.
- These compounds can be used in combination of two or more.
- a catalyst known per se can be adopted, and for example, an antimony compound, a titanium compound, a germanium compound, a tin compound or an aluminum compound is preferable.
- Preferred examples of such compounds include antimony, titanium, germanium, tin, aluminum oxides, acetates, carboxylates, hydrides, alcoholates, halides, carbonates, sulfates and the like.
- these compounds can be used in combination of two or more.
- the amount of the polymerization catalyst used is preferably in the range of 1 ⁇ 10 -8 to 1 ⁇ 10 -3 mol with respect to the total of 1 mol of all the monomer units.
- the polyester resin used in the present invention may use an end sealant for adjusting the molecular weight and improving the thermal stability.
- Preferred examples of the terminal encapsulant include monofunctional hydroxy compounds, epoxy compounds, oxazoline compounds, isocyanate compounds, carbodiimide compounds, ketenimine compounds and the like.
- the polyester resin used in the present invention may contain a diol component and a copolymerization component other than a dicarboxylic acid component or an ester-forming derivative thereof.
- ⁇ Manufacturing method of polycarbonate resin The polycarbonate resin is generally produced by a method of reacting a dihydroxy compound with a carbonic acid precursor such as a carbonic acid diester.
- the transesterification reaction using a carbonic acid diester as a carbonic acid precursor is carried out by a method of distilling the produced alcohol or phenol by stirring a predetermined ratio of the dihydroxy component with the carbonic acid diester while heating it in an inert gas atmosphere.
- the reaction temperature varies depending on the boiling point of the alcohol or phenol produced, but is usually in the range of 120 to 300 ° C.
- the reaction is completed by distilling off the produced alcohols or phenols under reduced pressure from the initial stage. Further, if necessary, a terminal terminator, an antioxidant or the like may be added.
- Examples of the carbonic acid diester used in the transesterification reaction include esters such as aryl groups and aralkyl groups having 6 to 12 carbon atoms which may be substituted. Specific examples thereof include diphenyl carbonate, ditriel carbonate, bis (chlorophenyl) carbonate and m-cresyl carbonate. Of these, diphenyl carbonate is particularly preferable.
- the amount of the diphenyl carbonate used is preferably 0.95 to 1.10 mol, more preferably 0.98 to 1.04 mol, based on 1 mol of the total dihydroxy compound.
- a polymerization catalyst can be used in order to accelerate the polymerization rate, and examples of the polymerization catalyst include alkali metal compounds, alkaline earth metal compounds, nitrogen-containing compounds and the like.
- an organic acid salt, an inorganic salt, an oxide, a hydroxide, a hydride, an alkoxide, a quaternary ammonium hydroxide and the like of an alkali metal or an alkaline earth metal are preferably used, and these compounds are used. It can be used alone or in combination.
- alkali metal compounds include sodium hydroxide, potassium hydroxide, cesium hydroxide, lithium hydroxide, sodium hydrogencarbonate, sodium carbonate, potassium carbonate, cesium carbonate, lithium carbonate, sodium acetate, potassium acetate, cesium acetate, lithium acetate, etc.
- Examples thereof include 2 lithium hydrogen acid, 2 sodium phenyl phosphate, 2 sodium salt of bisphenol A, 2 potassium salt, 2 cesium salt, 2 lithium salt, sodium salt of phenol, potassium salt, cesium salt, lithium salt and the like.
- alkaline earth metal compounds include magnesium hydroxide, calcium hydroxide, strontium hydroxide, strontium hydroxide, magnesium carbonate, calcium carbonate, strontium carbonate, barium carbonate, magnesium diacetate, calcium diacetate, strontium diacetate, and diacetic acid. Barium and the like are exemplified.
- nitrogen-containing compound examples include quaternary ammonium hydroxides having alkyl and aryl groups such as tetramethylammonium hydroxide, tetraethylammonium hydroxide, tetrapropylammonium hydroxide, tetrabutylammonium hydroxide and trimethylbenzylammonium hydroxide.
- examples thereof include bases or basic salts such as tetramethylammonium borohydride, tetrabutylammonium borohydride, tetrabutylammonium tetraphenylborate, and tetraphenylammonium tetraphenylborate.
- ester exchange catalysts include salts of zinc, tin, zirconium, lead, titanium, germanium, antimony and osmium, such as zinc acetate, zinc benzoate, zinc 2-ethylhexanoate, tin chloride (II), Tin chloride (IV), tin acetate (II), tin acetate (IV), dibutyltin dilaurate, dibutyltin oxide, dibutyltin dimethoxyd, zirconium acetylacetonate, zirconium oxyacetate, zirconium tetrabutoxide, lead acetate (II), lead acetate ( IV) Titanium tetrabutoxide (IV) or the like is used.
- the catalyst used in International Publication No. 2011/010741 and JP-A-2017-179323 may be used.
- a catalyst composed of aluminum or a compound thereof and a phosphorus compound may be used.
- it may be 8 ⁇ 10 -5 mol or more, 9 ⁇ 10 -5 mol or more, 1 ⁇ 10 -4 mol or more, and 1 ⁇ 10 -3 mol or more with respect to the total of 1 mol of all the monomer units used.
- it can be used in an amount of 8 ⁇ 10 -4 mol or less and 6 ⁇ 10 -4 mol or less.
- Examples of the aluminum salt include organic acid salts and inorganic acid salts of aluminum.
- Examples of the organic acid salt of aluminum include a carboxylate of aluminum, specifically, aluminum formate, aluminum acetate, aluminum propionate, aluminum oxalate, aluminum acrylate, aluminum laurate, aluminum stearate, and the like. Examples thereof include aluminum benzoate, aluminum trichloroacetate, aluminum lactate, aluminum citrate, and aluminum salicylate.
- Examples of the inorganic acid salt of aluminum include aluminum chloride, aluminum hydroxide, aluminum hydroxide chloride, aluminum carbonate, aluminum phosphate, and aluminum phosphonate.
- Examples of the aluminum chelate compound include aluminum acetyl acetonate, aluminum acetyl acetate, aluminum ethyl acetoacetate, and aluminum ethyl acetoacetate diiso-propoxide.
- Examples of the phosphorus compound include a phosphonic acid-based compound, a phosphinic acid-based compound, a phosphine oxide-based compound, a phosphonic acid-based compound, a subphosphinic acid-based compound, and a phosphinic acid-based compound.
- phosphonic acid-based compounds, phosphinic acid-based compounds, and phosphine oxide-based compounds can be mentioned in particular, and phosphonic acid-based compounds can be particularly mentioned.
- the amount of these polymerization catalysts used is preferably 0.1 ⁇ mol to 500 ⁇ mol, more preferably 0.5 ⁇ mol to 300 ⁇ mol, and even more preferably 1 ⁇ mol to 100 ⁇ mol with respect to 1 mol of the dihydroxy component.
- catalyst deactivating agent it is also possible to add a catalyst deactivating agent in the latter stage of the reaction.
- the catalyst deactivating agent to be used known catalytic deactivating agents are effectively used, and among these, ammonium salts and phosphonium salts of sulfonic acids are preferable. Further, salts of dodecylbenzenesulfonic acid such as dodecylbenzenesulfonic acid tetrabutylphosphonium salt and salts of paratoluenesulfonic acid such as paratoluenesulfonic acid tetrabutylammonium salt are preferable.
- esters of sulfonic acid methyl benzenesulfonic acid, ethyl benzenesulfonate, butyl benzenesulfonate, octyl benzenesulfonic acid, phenylbenzenesulfonic acid, methyl paratoluenesulfonate, ethyl paratoluenesulfonate, butyl paratoluenesulfonate, Octyl paratoluenesulfonate, phenyl paratoluenesulfonate and the like are preferably used.
- the dodecylbenzene sulfonic acid tetrabutylphosphonium salt is most preferably used.
- the amount of these catalyst deactivating agents used is preferably 0.5 to 50 mol per 1 mol of the catalyst when at least one polymerization catalyst selected from the alkali metal compound and / or the alkaline earth metal compound is used. , More preferably 0.5 to 10 mol, and even more preferably 0.8 to 5 mol.
- the polyester carbonate resin is generally produced by a method of polycondensing a dihydroxy compound with a carbonate precursor such as a carbonic acid diester and a dicarboxylic acid or an ester-forming derivative thereof.
- the reaction is carried out in a non-aqueous system in the presence of an acid binder and a solvent.
- an acid binder for example, pyridine, dimethylaminopyridine, tertiary amine and the like are used.
- the solvent for example, halogenated hydrocarbons such as methylene chloride and chlorobenzene are used. It is desirable to use a terminal terminator such as phenol or p-tert-butylphenol as the molecular weight modifier.
- the reaction temperature is usually 0 to 40 ° C., and the reaction time is preferably several minutes to 5 hours.
- a dihydroxy compound and a dicarboxylic acid or a diester thereof and a bisaryl carbonate are mixed under an inert gas atmosphere, and the reaction is carried out under reduced pressure at usually 120 to 350 ° C, preferably 150 to 300 ° C. The degree of decompression is changed stepwise, and finally the alcohols produced at 133 Pa or less are distilled off from the system.
- the reaction time is usually about 1 to 4 hours.
- a polymerization catalyst can be used to promote the reaction.
- alkali metal compounds include sodium hydroxide, potassium hydroxide, lithium hydroxide, sodium hydrogencarbonate, potassium hydrogencarbonate, lithium hydrogencarbonate, sodium carbonate, potassium carbonate, lithium carbonate, sodium acetate, potassium acetate, lithium acetate, and sodium stearate.
- nitrogen-containing basic compound examples include tetramethylammonium hydroxide, tetraethylammonium hydroxide, tetrabutylammonium hydroxide, trimethylbenzylammonium hydroxide, trimethylamine, triethylamine, dimethylbenzylamine, triphenylamine, and dimethylaminopyridine.
- the catalyst listed as the transesterification catalyst can be similarly used in the above-mentioned method for producing polycarbonate.
- the catalyst may be removed or inactivated in order to maintain thermal stability and hydrolysis stability.
- a method of inactivating the catalyst by adding a known acidic substance is preferably carried out.
- these substances include esters such as butyl benzoate, aromatic sulfonic acids such as p-toluenesulfonic acid, and aromatic sulfonic acids such as butyl p-toluenesulfonate and hexyl p-toluenesulfonate.
- esters such as phosphite, phosphate, phosphonic acid, triphenyl phosphite, monophenyl phosphite, diphenyl phosphite, diethyl phosphite, din-propyl phosphite, phosphite Subphosphate esters such as din-butyl, din-hexyl phosphite, dioctyl phosphite, monooctyl phosphite, triphenyl phosphate, diphenyl phosphate, monophenyl phosphate, dibutyl phosphate, phosphorus Phosphate esters such as dioctyl acid and monooctyl phosphate, phosphonic acids such as diphenylphosphonic acid, dioctylphosphonic acid and dibutylphosphonic acid, phosphonic acid esters such as diethylphenylphosphonate, triphenyl phos
- Phosphins such as ethane, boric acids such as boric acid and phenylboric acid, aromatic sulfonates such as dodecylbenzene sulfonic acid tetrabutylphosphonium salt, organic halogens such as stearate chloride, benzoyl chloride and p-toluenesulfonic acid chloride.
- organic halogens such as stearate chloride, benzoyl chloride and p-toluenesulfonic acid chloride.
- a compound, an alkyl sulfate such as dimethyl sulfate, an organic halide such as benzyl chloride, and the like are preferably used.
- These deactivating agents are used in an amount of 0.01 to 50 times mol, preferably 0.3 to 20 times mol, based on the amount of the catalyst.
- the deactivation effect becomes insufficient, which is not preferable. Further, if the amount is more than 50 times mol with respect to the amount of the catalyst, the heat resistance is lowered and the molded product is easily colored, which is not preferable.
- thermoplastic resin composition of the present invention contains a thermoplastic resin (A) and a thermoplastic resin (B).
- the thermoplastic resin composition of the present invention may contain other resins as long as the effects of the present invention are not impaired.
- the total ratio of the thermoplastic resin (A) and the thermoplastic resin (B) to the thermoplastic resin composition of the present invention is preferably 70% by mass or more, more preferably 90% by mass.
- the mass ratio (A: B) of the thermoplastic resin (A) and the thermoplastic resin (B) is preferably 1:99 to 99: 1, preferably 20:80. It is more preferably ⁇ 99: 1, more preferably 30:70 to 99: 1, and particularly preferably 60:40 to 90:10.
- thermoplastic resin having high impact strength can be obtained while having a high refractive index and a low Abbe number.
- the thermoplastic resin composition of the present invention may contain, as required, a mold release agent, a heat stabilizer, an ultraviolet absorber, a brewing agent, an antistatic agent, a flame retardant, a plasticizer, a filler, an antioxidant and the like. It can be used as a resin composition by appropriately adding an additive.
- a mold release agent e.g., a heat stabilizer, an ultraviolet absorber, a brewing agent, an antistatic agent, a flame retardant, a plasticizer, a filler, an antioxidant and the like.
- stearic acid monoglyceride, stearic acid triglyceride, pentaerythritol tetrastearate, and a mixture of stearic acid triglyceride and stearyl stearate are preferably used.
- the amount of the ester in the release agent is preferably 90% by mass or more, more preferably 95% by mass or more, when the release agent is 100% by mass.
- the mold release agent to be blended in the thermoplastic resin composition is preferably in the range of 0.005 to 2.0 parts by mass, preferably 0.01 to 0.6 parts by mass with respect to 100 parts by mass of the thermoplastic resin composition.
- the range of 0.02 to 0.5 weight mass is more preferable, and the range of 0.02 to 0.5 weight mass is further preferable.
- heat stabilizer examples include phosphorus-based heat stabilizers, sulfur-based heat stabilizers, and hindered phenol-based heat stabilizers.
- Particularly preferable phosphorus-based heat stabilizers include tris (2,4-di-tert-butylphenyl) phosphite and bis (2,6-di-tert-butyl-4-methylphenyl) pentaerythritol diphos. Fight, tetrakis (2,4-di-tert-butylphenyl) -4,4'-biphenylenediphosphonite is used.
- the amount of the phosphorus-based heat stabilizer to be blended in the thermoplastic resin composition is preferably 0.001 to 0.2 parts by mass with respect to 100 parts by mass of the thermoplastic resin composition.
- a particularly preferable sulfur-based heat stabilizer is pentaerythritol-tetrakis (3-laurylthiopropionate).
- the content of the sulfur-based heat stabilizer in the thermoplastic resin composition is preferably 0.001 to 0.2 parts by mass with respect to 100 parts by mass of the thermoplastic resin composition.
- Preferred hindered phenolic heat stabilizers include octadecyl-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate and pentaerythritol-tetrakis [3- (3,5-di-tert). -Butyl-4-hydroxyphenyl) propionate].
- the blending amount of the hindered phenol-based heat stabilizer in the thermoplastic resin composition is preferably 0.001 to 0.3 parts by mass with respect to 100 parts by mass of the thermoplastic resin composition.
- Phosphorus-based heat stabilizer and hindered phenol-based heat stabilizer can be used together.
- the UV absorber is at least one UV absorber selected from the group consisting of benzotriazole-based UV absorbers, benzophenone-based UV absorbers, triazine-based UV absorbers, cyclic iminoester-based UV absorbers, and cyanoacrylate-based UV absorbers. Is preferable.
- benzotriazole-based UV absorber more preferably, 2- (2-hydroxy-5-tert-octylphenyl) benzotriazol, 2,2'-methylenebis [4- (1,1,3,3-tetramethyl) Butyl) -6- (2H-benzotriazole-2-yl) phenol].
- benzophenone-based ultraviolet absorber examples include 2-hydroxy-4-n-dodecyloxybenzophenone and 2-hydroxy-4-methoxy-2'-carboxybenzophenone.
- triazine-based UV absorbers examples include 2- (4,6-diphenyl-1,3,5-triazine-2-yl) -5-[(hexyl) oxy] -phenol and 2- (4,6-bis (4,6-bis).
- 2.4-Dimethylphenyl) -1,3,5-triazine-2-yl) -5-[(octyl) oxy] -phenol and the like can be mentioned.
- 2,2'-p-phenylenebis (3,1-benzoxazine-4-one) is particularly suitable.
- Examples of the cyanoacrylate-based UV absorber include 1,3-bis-[(2'-cyano-3', 3'-diphenylacryloyl) oxy] -2,2-bis [(2-cyano-3,3-diphenyl). Examples thereof include acryloyl) oxy] methyl) propane and 1,3-bis-[(2-cyano-3,3-diphenylacryloyl) oxy] benzene.
- the blending amount of the ultraviolet absorber is preferably 0.01 to 3.0 parts by mass with respect to 100 parts by mass of the thermoplastic resin composition, and as long as it is within the range of such blending amount, the thermoplastic resin composition is depending on the application. It is possible to impart sufficient weather resistance to a molded product of an object.
- Antioxidants include triethylene glycol-bis [3- (3-tert-butyl-5-methyl-4-hydroxyphenyl) propionate] and 1,6-hexanediol-bis [3- (3,5-di).
- -Tert-Butyl-4-hydroxyphenyl) propionate pentaerythritol-tetrakis [3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate]
- octadecyl-3- (3,5-di-) tert-Butyl-4-hydroxyphenyl) propionate 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene, N, N-hexamethylene Bis (3,5-di-tert-butyl-4-hydroxy-hydrocinnamide), 3,5-di-tert-butyl-4-hydroxy-benzylphosphonate-die
- the blending amount of the antioxidant is preferably 0.50 parts by mass or less, more preferably 0.05 to 0.40 parts by mass, and 0. It is more preferably 05 to 0.20 parts by mass or 0.10 to 0.40 parts by mass, and particularly preferably 0.20 to 0.40 parts by mass.
- the method for producing the thermoplastic resin composition of the present invention is not particularly limited, and for example, a method of mixing each solid of the thermoplastic resin (A) and the thermoplastic resin (B) and kneading them with a kneader, melting.
- the kneading may be continuous or batch. If the kneader is a continuous type, an extruder is suitable, and if it is a batch type, it is regarded as Lab Plus, and a kneader is preferably used.
- the refractive index of the thermoplastic resin composition of the present invention is 1.645 or more, 1.650 or more, 1.655 or more, 1.660 or more, 1 when measured at a temperature of 20 ° C. and a wavelength of 589 nm. It may be .665 or more, 1.667 or 1.670 or more, 1.690 or less, 1.685 or less, or 1.680 or less.
- the refractive index of the thermoplastic resin of the present invention is 1.645 to 1.690, preferably 1.650 to 1.690, more preferably 1.655 to 1.690, and 1.660 to 1. 690 is more preferable, 1.665 to 1.690 is particularly preferable, and 1.667 to 1.685 is most preferable.
- the refractive index is at least the lower limit, the spherical aberration of the optical lens can be reduced, and the focal length of the optical lens can be shortened.
- the Abbe number of the thermoplastic resin composition of the present invention may be 10.0 or more, 11.0 or more, 12.0 or more, 13.0 or more, or 14.0 or more, and 30.0 or less, 29. It may be 0.0 or less, 28.0 or less, 27.0 or less, 26.0 or less, or 25.0 or less. For example, even if the Abbe number of the thermoplastic resin composition of the present invention is 15.0 to 25.0, 16.0 to 24.0, 17.0 to 23.0, 18.0 to 22.0. good.
- the absolute value of the orientation birefringence ( ⁇ n) of the thermoplastic resin composition of the present invention is preferably 4.6 ⁇ 10 -3 or less, more preferably 4.4 ⁇ 10 -3 or less, 4 It is more preferably 2 ⁇ 10 -3 or less. If the orientation birefringence is within the above range, it does not significantly affect chromatic aberration, so that the performance as designed by the optical can be maintained. Orientation birefringence ( ⁇ n) is measured at a wavelength of 589 nm after a 100 ⁇ m-thick cast film obtained from the thermoplastic resin is stretched twice at Tg + 10 ° C.
- thermoplastic resin composition of the present invention has a haze having a thickness of 3 mm, preferably 2% or less, more preferably 1% or less, still more preferably 0.5% or less.
- haze having a thickness of 3 mm, preferably 2% or less, more preferably 1% or less, still more preferably 0.5% or less.
- the viscosity average molecular weight of the thermoplastic resin composition in the present invention may be 5,000 or more, 6,000 or more, or 7,000 or more, and 25,000 or more, when measured by the method described in Examples. Hereinafter, it may be 20,000 or less, or 15,000 or less.
- the viscosity average molecular weight of the thermoplastic resin composition of the present invention may be 6,000 to 20,000 or 7,000 to 15,000.
- the thermoplastic resin composition of the present invention has a water absorption rate of 0.01% by mass or more, 0.04% by mass or more, 0.07% by mass or more, and 0.10% by mass or more after being immersed for 24 hours at 23 ° C. It may be 0.30% by mass or less, 0.25% by mass or less, and 0.20% by mass or less.
- the water absorption rate of the thermoplastic resin composition of the present invention is preferably 0.01% by mass to 0.30% by mass, more preferably 0.04% by mass to 0.25% by mass, and 0. It is more preferably 0.7% by mass to 0.25% by mass, and particularly preferably 0.07% by mass to 0.20% by mass.
- the water absorption rate is within the above range, the change in optical characteristics due to water absorption is small, which is preferable.
- the glass transition temperature of the thermoplastic resin composition of the present invention may be 130 ° C. or higher, 135 ° C. or higher, 140 ° C. or higher, or 145 ° C. or higher, 170 ° C. or lower, 165 ° C. or lower, 160 ° C. or lower. May be good.
- the glass transition temperature of the thermoplastic resin composition of the present invention is preferably 130 ° C to 170 ° C, more preferably 135 ° C to 165 ° C, further preferably 140 ° C to 160 ° C, and particularly preferably 145 ° C to 160 ° C. When the glass transition temperature is within the above range, the balance between heat resistance and moldability is excellent, which is preferable.
- the value of the notched Charpy impact strength measured according to ISO179 is preferably 25 J / m 2 or more, more preferably 27 J / m 2 or more, and 29 J. It is particularly preferable that it is / m 2 or more. If the Charpy impact strength without notch is within the above range, the occurrence of sprue and runner breakage can be suppressed in continuous molding.
- the optical member of the present invention contains the above-mentioned thermoplastic resin composition.
- the optical member is not particularly limited as long as it is an optical application in which the above-mentioned thermoplastic resin composition is useful, but an optical fiber, a transparent conductive substrate, an optical card, a sheet, a film, an optical fiber, a lens, a prism, and the like. Examples thereof include an optical film, a substrate, an optical filter, and a hard coat film.
- the optical member of the present invention may be composed of a resin composition containing the above-mentioned thermoplastic resin composition, and the resin composition may contain a heat stabilizer, a plasticizer, and a light stabilizer, if necessary.
- Additives such as agents, polymerized metal inactivating agents, flame retardants, lubricants, antistatic agents, surfactants, antibacterial agents, ultraviolet absorbers, and mold release agents can be blended.
- ⁇ Optical lens As the optical member of the present invention, an optical lens can be particularly mentioned.
- optical lens examples include an image pickup lens for a mobile phone, a smartphone, a tablet terminal, a personal computer, a digital camera, a video camera, an in-vehicle camera, a surveillance camera, and a sensing camera such as a TOF camera.
- the optical lens of the present invention is manufactured by injection molding, it is preferable to mold it under the conditions of a cylinder temperature of 230 to 350 ° C. and a mold temperature of 70 to 180 ° C. More preferably, molding is performed under the conditions of a cylinder temperature of 250 to 300 ° C. and a mold temperature of 80 to 170 ° C.
- the cylinder temperature is higher than 350 ° C.
- the thermoplastic resin composition is decomposed and colored
- the melt viscosity is high and molding tends to be difficult.
- the mold temperature is higher than 180 ° C., it tends to be difficult to remove the molded piece made of the thermoplastic resin composition from the mold.
- the mold temperature is less than 70 ° C, the resin hardens too quickly in the mold at the time of molding, making it difficult to control the shape of the molded piece, or sufficiently transferring the mold attached to the mold. Tends to be difficult.
- the optical lens of the present invention preferably uses the shape of an aspherical lens as needed. Since it is possible to eliminate spherical aberration with a single lens for aspherical lenses, it is not necessary to remove spherical aberration by combining multiple spherical lenses, resulting in weight reduction and reduction of molding costs. It will be possible. Therefore, the aspherical lens is particularly useful as a camera lens among optical lenses.
- the thermoplastic resin composition of the present invention has high molding fluidity, it is particularly useful as a material for an optical lens having a thin wall, a small size, and a complicated shape.
- the thickness of the central portion is 0.05 to 3.0 mm, more preferably 0.05 to 2.0 mm, and further preferably 0.1 to 2.0 mm.
- the diameter is 1.0 mm to 20.0 mm, more preferably 1.0 to 10.0 mm, and even more preferably 3.0 to 10.0 mm.
- the shape is a meniscus lens having one side convex and one side concave.
- the lens made of the thermoplastic resin of the present invention is molded by any method such as mold molding, cutting, polishing, laser processing, electric discharge machining, and etching. Among these, mold molding is more preferable from the viewpoint of manufacturing cost.
- ⁇ d (nd-1) / (nF-nC) nd: Refractive index at wavelength 587.56 nm, nF: Refractive index at wavelength 486.13 nm, nC: means the refractive index at a wavelength of 656.27 nm.
- ⁇ Charpy impact strength without notch> Using a 4 mm thick prismatic molded piece obtained by injection molding, the notchless Charpy impact strength was measured according to ISO179.
- ⁇ Water absorption rate> Using a plate-shaped molded piece having a thickness of 2 mm obtained by injection molding, the water absorption rate after immersion at 23 ° C. for 24 hours was measured according to ISO62.
- thermoplastic resin composition was dissolved in methylene chloride, cast on a glass petri dish, and sufficiently dried to prepare a cast film having a thickness of 100 ⁇ m.
- the film was stretched twice at Tg + 10 ° C., the phase difference (Re) at 589 nm was measured using an ellipsometer M-220 manufactured by JASCO Corporation, and the absolute value of orientation birefringence (
- thermoplastic resin (A1) had an Mv of 8,400 and a Tg of 155 ° C.
- thermoplastic resin (B1) had an Mv of 10,100 and a Tg of 149 ° C.
- thermoplastic resin (B2) had an Mv of 9,400 and a Tg of 142 ° C.
- thermoplastic resin (A1) manufactured in Synthesis Example 1 and 77.0 parts by mass of the thermoplastic resin (B1) manufactured in Synthesis Example 2 are well mixed, and an extruder (TEX30 ⁇ manufactured by Nippon Steel Works Co., Ltd.) is mixed well.
- a melted thermoplastic resin (A1) and a thermoplastic resin (B1) were kneaded at 270 ° C. and a vent pressure of 30 mmHg using a 30 mm ⁇ twin-screw extruder) and pelletized to obtain blend pellets.
- the Tg of the pellet was 151 ° C., which was a single peak in DSC measurement.
- the Mv of the pellet was 9,700.
- the pellet was injection-molded to obtain a plate-shaped molded piece having a thickness of 2 mm, a disk having a thickness of 3 mm, and a prismatic molded piece having a thickness of 4 mm.
- the molded body was transparent.
- the evaluation results are shown in Table 1.
- a melted thermoplastic resin (A1) and a thermoplastic resin (B1) were kneaded at 270 ° C.
- the Tg of the pellet was 152 ° C., which was a single peak in DSC measurement.
- the Mv of the pellet was 9,400.
- the pellet was injection-molded to obtain a plate-shaped molded piece having a thickness of 2 mm, a disk having a thickness of 3 mm, and a prismatic molded piece having a thickness of 4 mm.
- the molded body was transparent. The evaluation results are shown in Table 1.
- thermoplastic resin (A1) manufactured in Synthesis Example 1 and 36.0 parts by mass of the thermoplastic resin (B1) manufactured in Synthesis Example 2 are well mixed, and an extruder (TEX30 ⁇ manufactured by Nippon Steel Works Co., Ltd.) is mixed well.
- a melted thermoplastic resin (A1) and a thermoplastic resin (B1) were kneaded at 270 ° C. and a vent pressure of 30 mmHg using a 30 mm ⁇ twin-screw extruder) and pelletized to obtain blend pellets.
- the Tg of the pellet was 153 ° C., which was a single peak in DSC measurement.
- the Mv of the pellet was 9,000.
- the pellet was injection-molded to obtain a plate-shaped molded piece having a thickness of 2 mm, a disk having a thickness of 3 mm, and a prismatic molded piece having a thickness of 4 mm.
- the molded body was transparent.
- the evaluation results are shown in Table 1.
- a melted thermoplastic resin (A1) and a thermoplastic resin (B1) were kneaded at 270 ° C.
- the Tg of the pellet was 154 ° C, which was a single peak as measured by DSC.
- the Mv of the pellet was 8,600.
- the pellet was injection-molded to obtain a plate-shaped molded piece having a thickness of 2 mm, a disk having a thickness of 3 mm, and a prismatic molded piece having a thickness of 4 mm.
- the molded body was transparent. The evaluation results are shown in Table 1.
- thermoplastic resin (A1) manufactured in Synthesis Example 1 and 5.0 parts by mass of the thermoplastic resin (B1) manufactured in Synthesis Example 2 are well mixed, and an extruder (TEX30 ⁇ manufactured by Nippon Steel Works Co., Ltd.) is mixed well.
- a melted thermoplastic resin (A1) and a thermoplastic resin (B1) were kneaded at 270 ° C. and a vent pressure of 30 mmHg using a 30 mm ⁇ twin-screw extruder) and pelletized to obtain blend pellets.
- the Tg of the pellet was 155 ° C., which was a single peak in DSC measurement.
- the Mv of the pellet was 8,500.
- the pellet was injection-molded to obtain a plate-shaped molded piece having a thickness of 2 mm, a disk having a thickness of 3 mm, and a prismatic molded piece having a thickness of 4 mm.
- the molded body was transparent.
- the evaluation results are shown in Table 1.
- a melted thermoplastic resin (A1) and a thermoplastic resin (B2) were kneaded at 270 ° C.
- the Tg of the pellet was 148 ° C., which was a single peak in DSC measurement.
- the Mv of the pellet was 8,800.
- the pellet was injection-molded to obtain a plate-shaped molded piece having a thickness of 2 mm, a disk having a thickness of 3 mm, and a prismatic molded piece having a thickness of 4 mm.
- the molded body was transparent. The evaluation results are shown in Table 1.
- Example 7 74.0 parts by mass of the thermoplastic resin (A1) manufactured in Synthesis Example 1 and 26.0 parts by mass of the thermoplastic resin (B2) manufactured in Synthesis Example 3 are well mixed, and an extruder (TEX30 ⁇ manufactured by Nippon Steel Works Co., Ltd.) is mixed well.
- a melted thermoplastic resin (A1) and a thermoplastic resin (B2) were kneaded at 270 ° C. and a vent pressure of 30 mmHg using a 30 mm ⁇ twin-screw extruder) and pelletized to obtain blend pellets.
- the Tg of the pellet was 152 ° C., which was a single peak in DSC measurement.
- the Mv of the pellet was 8,600.
- the pellet was injection-molded to obtain a plate-shaped molded piece having a thickness of 2 mm, a disk having a thickness of 3 mm, and a prismatic molded piece having a thickness of 4 mm.
- the molded body was transparent.
- the evaluation results are shown in Table 1.
- ⁇ Comparative Example 1> The pellet produced in Synthesis Example 1 was injection-molded to obtain a plate-shaped molded piece having a thickness of 2 mm, a disk having a thickness of 3 mm, and a prismatic molded piece having a thickness of 4 mm. The molded body was transparent. The evaluation results are shown in Table 1.
- ⁇ Comparative Example 2> The pellet produced in Synthesis Example 2 was injection-molded to obtain a plate-shaped molded piece having a thickness of 2 mm, a disk having a thickness of 3 mm, and a prismatic molded piece having a thickness of 4 mm. The molded body was transparent. The evaluation results are shown in Table 1.
- ⁇ Comparative Example 3> The pellet produced in Synthesis Example 3 was injection-molded to obtain a plate-shaped molded piece having a thickness of 2 mm, a disk having a thickness of 3 mm, and a prismatic molded piece having a thickness of 4 mm. The molded body was transparent. The evaluation results are shown in Table 1.
- ⁇ Comparative Example 4 Pellets of polycarbonate resin "AD-5503" (manufactured by Teijin Limited) made of bisphenol A type polycarbonate resin were injection molded to obtain 2 mm thick plate-shaped molded pieces, 3 mm thick disks and 4 mm thick prismatic molded pieces. .. The molded body was transparent. The evaluation results are shown in Table 1.
- ⁇ Comparative Example 5> Mix 50.0 parts by mass of the thermoplastic resin (A1) pellets manufactured in Synthesis Example 1 and 50.0 parts by mass of the pellets of AD-5503 well, and use an extruder (TEX30 ⁇ 30 mm ⁇ twin-screw extruder manufactured by Japan Steel Works, Ltd.).
- thermoplastic resin (A1) in a molten state and AD-5503 were kneaded and pelletized at 270 ° C. and a vent pressure of 30 mmHg to obtain blend pellets. The pellet became cloudy.
- the evaluation results are shown in Table 1.
- thermoplastic resin of the present invention is used as an optical material and is used for optical members such as optical lenses, prisms, optical disks, transparent conductive substrates, optical cards, sheets, films, optical fibers, optical films, optical filters, and hard coat films. It can be very useful especially for optical lenses.
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Abstract
Description
《態様1》
式(1)で表される単位を含む熱可塑性樹脂(A)、および式(2)で表される単位を含む熱可塑性樹脂(B)を含む熱可塑性樹脂組成物。
《態様2》
前記式(1)のWが式(3)もしくは式(4)を含む態様1に記載の熱可塑性樹脂組成物。
《態様3》
前記式(4)のZがナフタレン環である態様2に記載の熱可塑性樹脂組成物。
《態様4》
3mm厚みで測定した際のヘーズが、0.5%以下である、態様1~3のいずれか一項に記載の熱可塑性樹脂組成物。
《態様5》
熱可塑性樹脂(A)および熱可塑性樹脂(B)の質量比率(A:B)が1:99~99:1である態様1~4のいずれか一項に記載の熱可塑性樹脂組成物。
《態様6》
屈折率が1.645~1.690である態様1~5のいずれか一項に記載の熱可塑性樹脂組成物。
《態様7》
配向複屈折が4.5×10-3以下である、態様1~6のいずれか一項に記載の熱可塑性樹脂組成物。
《態様8》
ノッチなしシャルピー衝撃強度が25J/m2以上である態様1~7のいずれか一項に記載の熱可塑性樹脂組成物。
《態様9》
熱可塑性樹脂(A)がポリエステルカーボネート樹脂である態様1~8のいずれか一項に記載の熱可塑性樹脂組成物。
《態様10》
熱可塑性樹脂(B)がポリエステルカーボネート樹脂、または、ポリカーボネート樹脂である態様1~9のいずれか一項に記載の熱可塑性樹脂組成物。
《態様11》
態様1~10のいずれか一項に記載の熱可塑性樹脂組成物を含む、光学部材。
《熱可塑性樹脂(A)》
本発明における熱可塑性樹脂(A)は、上記式(1)で表される構成単位を含む。
《上記式(1)で表される単位に使用するジカルボン酸成分》
本発明の熱可塑性樹脂の上記式(1)で表される単位に使用するジカルボン酸成分は、主に式(a)で表される化合物、またはそのエステル形成性誘導体である。
《上記式(1)で表される単位に使用するジオール成分》
本発明の熱可塑性樹脂の上記式(1)のWで表される単位に使用されるジオール成分としては、エチレングリコール、プロパンジオール、ブタンジオール、ペンタンジオール、ヘキサンジオール、ヘプタンジオール、オクタンジオール、ノナンジオール、トリシクロ[5.2.1.02,6 ]デカンジメタノール、シクロヘキサン-1,4-ジメタノール、デカリン-2,6-ジメタノール、ノルボルナンジメタノール、ペンタシクロペンタデカンジメタノール、シクロペンタン-1,3-ジメタノール、スピログリコール、イソソルビド、イソマンニド、イソイジド、ヒドロキノン、レゾルシノール、ジヒドロキシナフタレン、2,2-ビス(4-ヒドロキシフェニル)プロパン、2,2-ビス(3-メチル-4-ヒドロキシフェニル)プロパン、1,1-ビス(4-ヒドロキシフェニル)-1-フェニルエタン、1,3-ビス(2-(4-ヒドロキシフェニル)-2-プロピル)ベンゼン、1,1-ビス(4-ヒドロキシフェニル)-3,3,5-トリメチルシクロヘキサン、1,1-ビス(4-ヒドロキシフェニル)シクロヘキサン、ビス(4-ヒドロキシフェニル)ジフェニルメタン、1,1-ビス(4-ヒドロキシフェニル)デカン、ビス(4-ヒドロキシフェニル)スルフィド、ビス(4-ヒドロキシ-3-メチルフェニル)スルフィド、ビフェノール、9,9-ビス(4-ヒドロキシフェニル)フルオレン、9,9-ビス(4-ヒドロキシ-3-メチルフェニル)フルオレン、9,9-ビス(4-ヒドロキシ-3-シクロヘキシルフェニル)フルオレン、9,9-ビス(4-ヒドロキシ-3-フェニルフェニル)フルオレン、9,9-ビス(4-(2-ヒドロキシエトキシ)フェニル)フルオレン、9,9-ビス(4-(2-ヒドロキシエトキシ)-3-メチルフェニル)フルオレン、9,9-ビス(4-(2-ヒドロキシエトキシ)-3-シクロヘキシルフェニル)フルオレン、9,9-ビス(4-(2-ヒドロキシエトキシ)-3-フェニルフェニル)フルオレン、ビス(4-ヒドロキシフェニル)スルホン、ビス(4-(2-ヒドロキシエトキシ)フェニル)スルホン、10,10-ビス(4-ヒドロキシフェニル)アントロン、下記式(b)、下記式(c)が挙げられ、なかでも9,9-ビス(4-(2-ヒドロキシエトキシ)フェニル)フルオレン、9,9-ビス(4-(2-ヒドロキシエトキシ)-3-メチルフェニル)フルオレン、式(b)及び式(c)が好ましく、式(b)及び式(c)がより好ましい。
《上記式(1)以外の共重合成分》
本発明の熱可塑性樹脂(A)は、上記の本発明の有利な効果が得られる範囲で、上記式(1)で表される繰返し単位以外の繰返し単位を含んでいてもよい。本発明における熱可塑性樹脂(A)に占める上記式(1)で表される構成単位の割合は、50mol%以上であることが好ましく、70mol%以上であることがより好ましい。上記式(1)で表される繰返し単位以外の繰返し単位として、ポリカーボネート、ポリエステル及びポリエステルカーボネートがあり、それらのジカルボン酸成分及びジオール成分を下記に示す。
《熱可塑性樹脂(B)》
本発明における熱可塑性樹脂(B)は、上記式(2)で表される構成単位を含む。
《上記式(2)で表される単位に使用するジオール成分》
本発明の熱可塑性樹脂の上記式(2)で表される単位に使用されるジオール成分としては、主に式(d)で表される原料が好ましく用いられる。
本発明における熱可塑性樹脂(B)は、上記式(2)で表される構成単位を有するが、本発明による効果を損なわない範囲で他の構成単位を含んでも良い。本発明における熱可塑性樹脂(B)に占める上記式(2)で表される構成単位の割合は、70mol%以上であることが好ましく、80mol%以上であることがより好ましい。その他の繰返し単位として、ポリカーボネート、ポリエステル及びポリエステルカーボネートが好ましく、それらを構成するジカルボン酸成分及びジオール成分を下記に示す。
《熱可塑性樹脂(A)及び熱可塑性樹脂(B)の製造方法》
本発明の熱可塑性樹脂は、例えばジオール成分にホスゲンや炭酸ジエステルなどのカーボネート前駆物質を反応させる方法やジオール成分にジカルボン酸またはそのエステル形成性誘導体を反応させる方法等により製造される。以下にその具体例を示す。
《ポリエステル樹脂の製造方法》
ポリエステル樹脂は、一般にジオール成分とジカルボン酸成分またはそのエステル形成性誘導体とをエステル化反応もしくはエステル交換反応させ、得られた反応生成物を重縮合反応させ、所望の分子量の高分子量体とすることで製造される。
《ポリカーボネート樹脂の製造方法》
ポリカーボネート樹脂は、一般にジヒドロキシ化合物に炭酸ジエステルなどのカーボネート前駆物質を反応させる方法により製造される。
《ポリエステルカーボネート樹脂の製造方法》
ポリエステルカーボネート樹脂は一般に、ジヒドロキシ化合物に炭酸ジエステルなどのカーボネート前駆物質とジカルボン酸又はそのエステル形成性誘導体を重縮合反応させる方法により製造される。
《熱可塑性樹脂組成物》
本発明の熱可塑性樹脂組成物は、熱可塑性樹脂(A)及び熱可塑性樹脂(B)を含む。本発明の熱可塑性樹脂組成物は本発明による効果を損なわない範囲で他の樹脂を含んでもよい。本発明の熱可塑性樹脂組成物に占める上記熱可塑性樹脂(A)及び熱可塑性樹脂(B)の合計の割合は、70質量%以上であることが好ましく、90質量%であることがより好ましい。
《熱可塑性樹脂組成物の製造方法》
本発明の熱可塑性樹脂組成物の製造方法は、特に制限は無く、例えば、熱可塑性樹脂(A)と熱可塑性樹脂(B)のそれぞれの固体を混合し、混練機により混錬する方法、溶融状態の熱可塑性樹脂(A)に固体の熱可塑性樹脂(B)を添加して混錬する方法、固体の熱可塑性樹脂(B)に固体の熱可塑性樹脂(A)を添加して混錬する方法、溶融状態の熱可塑性樹脂(A)と溶融状態の熱可塑性樹脂(B)とを混合して混錬する方法、のいずれの方法によっても製造することができる。
《熱可塑性樹脂組成物の物性》
本発明の熱可塑性樹脂組成物の屈折率は、温度:20℃、波長:589nmで測定した場合に、1.645以上であり、1.650以上、1.655以上、1.660以上、1.665以上、1.667又は1.670以上であってもよく、1.690以下であり、1.685以下、又は1.680以下であってもよい。例えば、本発明の熱可塑性樹脂の屈折率は、1.645~1.690であり、1.650~1.690が好ましく、1.655~1.690がより好ましく、1.660~1.690がさらに好ましく、1.665~1.690が特に好ましく、1.667~1.685が最も好ましい。屈折率が下限以上の場合、光学レンズの球面収差を低減でき、さらに光学レンズの焦点距離を短くすることができる。
νd=(nd-1)/(nF-nC)
nd:波長587.56nmでの屈折率、
nF:波長486.13nmでの屈折率、
nC:波長656.27nmでの屈折率を意味する。
《光学部材》
本発明の光学部材は、上記の熱可塑性樹脂組成物を含む。そのような光学部材としては、上記の熱可塑性樹脂組成物が有用となる光学用途であれば、特に限定されないが、光ディスク、透明導電性基板、光カード、シート、フィルム、光ファイバー、レンズ、プリズム、光学膜、基盤、光学フィルター、ハードコート膜等を挙げることができる。
《光学レンズ》
本発明の光学部材として、特に光学レンズを挙げることができる。このような光学レンズとしては、携帯電話、スマートフォン、タブレット端末、パソコン、デジタルカメラ、ビデオカメラ、車載カメラ、監視カメラ等のための撮像レンズや、TOFカメラ等のセンシングカメラを挙げることができる。
《評価方法》
〈屈折率〉
各熱可塑性樹脂組成物の3mm厚円板を作製し、切削、研磨した後、島津製作所製のカルニュー精密屈折計KPR-2000を使用して、屈折率nd(587.56nm)を測定した。
〈アッベ数〉
アッベ数の測定波長は、486.13nm、587.56nm、656.27nmの屈折率から下記の式を用いて算出した。
nd:波長587.56nmでの屈折率、
nF:波長486.13nmでの屈折率、
nC:波長656.27nmでの屈折率を意味する。
〈ノッチなしシャルピー衝撃強度〉
射出成型により得られた4mm厚の角柱状成型片を用いて、ISO179に準拠してノッチなしシャルピー衝撃強度を測定した。
〈吸水率〉
射出成型により得られた2mm厚の板状成型片を用いて、ISO62に準拠して23℃、24時間浸漬後の吸水率を測定した。
〈ヘーズ(Hz)〉
射出成型により得られた3mm厚の円板を用いて、本電飾工業(株)製 Haze Meter NDH 2000により、ヘーズを測定した。
〈ガラス転移温度(Tg)〉
得られた熱可塑性樹脂組成物をティー・エイ・インスツルメント・ジャパン(株)製DSC Discovery DSC25Auto型により、昇温速度20℃/minでガラス転移温度を測定した。試料は5~10mgで測定した。
〈粘度平均分子量(Mv)〉
熱可塑性樹脂組成物の粘度平均分子量を、以下の方法で測定した。熱可塑性樹脂組成物0.7gを塩化メチレン100mlに溶解した溶液から、その溶液の20℃における比粘度(ηsp)を測定した。そして、下記式により算出されるMvを粘度平均分子量とした。
ηsp/c=[η]+0.45×[η]2c
[η]=1.23×10-4×Mv0.83
ηsp:比粘度
η:極限粘度
c:定数(=0.7)
Mv:粘度平均分子量
〈配向複屈折の絶対値〉
熱可塑性樹脂組成物を塩化メチレンに溶解した後、ガラスシャーレ上にキャストし、十分乾燥することで厚さ100μmのキャストフィルムを作製した。該フィルムをTg+10℃で2倍延伸し、日本分光(株)製エリプソメーターM-220を用いて589nmにおける位相差(Re)を測定し、下記式より配向複屈折の絶対値(|Δn|)を求めた。
Δn:配向複屈折
Re:位相差(nm)
d:厚さ(nm)
[合成例]
〈合成例1〉(熱可塑性樹脂(A1)の製造)
2,2’-ビス(カルボキシメトキシ)-1,1’-ビナフチル18.1質量部、9,9-ビス[6-(2-ヒドロキシエトキシ)-2-ナフチル]フルオレン18.9質量部、2,2’-ビス(2-ヒドロキシエトキシ)-1,1’-ビナフチル7.5質量部、ジフェニルカーボネート(以下、DPCと省略することがある)2.4質量部、アルミニウムアセチルアセトネート19.5×10-3質量部及び3,5-ジ-tert-ブチル-4-ヒドロキシベンジルホスホン酸ジエチル42.7×10-3質量部を攪拌機および留出装置付きの反応釜に入れ、窒素置換を3度行った後、ジャケットを200℃に加熱し、原料を溶融させた。
〈合成例2〉(熱可塑性樹脂(B1)の製造)
9,9-ビス(4-(2-ヒドロキシエトキシ)フェニル)フルオレン36.0質量部、テレフタル酸ジメチル3.5質量部、DPC13.7質量部及びチタンテトラブトキシド4.3×10-3質量部を攪拌機および留出装置付きの反応釜に入れ、窒素置換を3度行った後、ジャケットを200℃に加熱し、原料を溶融させた。
〈合成例3〉(熱可塑性樹脂(B2)の製造)
9,9-ビス(4-(2-ヒドロキシエトキシ)フェニル)フルオレンを43.9質量部、DPCを22.3質量部及び炭酸水素ナトリウムを6.7×10-5質量部を攪拌機および留出装置付きの反応釜に入れ、窒素置換を3度行った後、ジャケットを200℃に加熱し、原料を溶融させた。
〈実施例1〉
合成例1で製造した熱可塑性樹脂(A1)23.0質量部と、合成例2で製造した熱可塑性樹脂(B1)77.0質量部をよく混合し、押出機(日本製鋼所社製 TEX30α 30mmφ二軸押出機)により270℃、ベント圧力30mmHgで溶融状態の熱可塑性樹脂(A1)及び熱可塑性樹脂(B1)を混練してペレタイズしブレンドペレットを得た。該ペレットのTgは151℃であり、DSC測定では単一のピークであった。また、該ペレットのMvは9,700であった。該ペレットを射出成型して2mm厚の板状成型片、3mm厚の円板及び4mm厚の角柱状成型片を得た。成型体は透明であった。評価結果を表1に示す。
〈実施例2〉
合成例1で製造した熱可塑性樹脂(A1)44.0質量部と、合成例2で製造した熱可塑性樹脂(B1)56.0質量部をよく混合し、押出機(日本製鋼所社製 TEX30α 30mmφ二軸押出機)により270℃、ベント圧力30mmHgで溶融状態の熱可塑性樹脂(A1)及び熱可塑性樹脂(B1)を混練してペレタイズしブレンドペレットを得た。該ペレットのTgは152℃であり、DSC測定では単一のピークであった。また、該ペレットのMvは9,400であった。該ペレットを射出成型して2mm厚の板状成型片、3mm厚の円板及び4mm厚の角柱状成型片を得た。成型体は透明であった。評価結果を表1に示す。
〈実施例3〉
合成例1で製造した熱可塑性樹脂(A1)64.0質量部と、合成例2で製造した熱可塑性樹脂(B1)36.0質量部をよく混合し、押出機(日本製鋼所社製 TEX30α 30mmφ二軸押出機)により270℃、ベント圧力30mmHgで溶融状態の熱可塑性樹脂(A1)及び熱可塑性樹脂(B1)を混練してペレタイズしブレンドペレットを得た。該ペレットのTgは153℃であり、DSC測定では単一のピークであった。また、該ペレットのMvは9,000であった。該ペレットを射出成型して2mm厚の板状成型片、3mm厚の円板及び4mm厚の角柱状成型片を得た。成型体は透明であった。評価結果を表1に示す。
〈実施例4〉
合成例1で製造した熱可塑性樹脂(A1)86.0質量部と、合成例2で製造した熱可塑性樹脂(B1)14.0質量部をよく混合し、押出機(日本製鋼所社製 TEX30α 30mmφ二軸押出機)により270℃、ベント圧力30mmHgで溶融状態の熱可塑性樹脂(A1)及び熱可塑性樹脂(B1)を混練してペレタイズしブレンドペレットを得た。該ペレットのTgは154℃であり、DSC測定では単一のピークであった。また、該ペレットのMvは8,600であった。該ペレットを射出成型して2mm厚の板状成型片、3mm厚の円板及び4mm厚の角柱状成型片を得た。成型体は透明であった。評価結果を表1に示す。
〈実施例5〉
合成例1で製造した熱可塑性樹脂(A1)95.0質量部と、合成例2で製造した熱可塑性樹脂(B1)5.0質量部をよく混合し、押出機(日本製鋼所社製 TEX30α 30mmφ二軸押出機)により270℃、ベント圧力30mmHgで溶融状態の熱可塑性樹脂(A1)及び熱可塑性樹脂(B1)を混練してペレタイズしブレンドペレットを得た。該ペレットのTgは155℃であり、DSC測定では単一のピークであった。また、該ペレットのMvは8,500であった。該ペレットを射出成型して2mm厚の板状成型片、3mm厚の円板及び4mm厚の角柱状成型片を得た。成型体は透明であった。評価結果を表1に示す。
〈実施例6〉
合成例1で製造した熱可塑性樹脂(A1)44.0質量部と、合成例3で製造した熱可塑性樹脂(B2)56.0質量部をよく混合し、押出機(日本製鋼所社製 TEX30α 30mmφ二軸押出機)により270℃、ベント圧力30mmHgで溶融状態の熱可塑性樹脂(A1)及び熱可塑性樹脂(B2)を混練してペレタイズしブレンドペレットを得た。該ペレットのTgは148℃であり、DSC測定では単一のピークであった。また、該ペレットのMvは8,800であった。該ペレットを射出成型して2mm厚の板状成型片、3mm厚の円板及び4mm厚の角柱状成型片を得た。成型体は透明であった。評価結果を表1に示す。
〈実施例7〉
合成例1で製造した熱可塑性樹脂(A1)74.0質量部と、合成例3で製造した熱可塑性樹脂(B2)26.0質量部をよく混合し、押出機(日本製鋼所社製 TEX30α 30mmφ二軸押出機)により270℃、ベント圧力30mmHgで溶融状態の熱可塑性樹脂(A1)及び熱可塑性樹脂(B2)を混練してペレタイズしブレンドペレットを得た。該ペレットのTgは152℃であり、DSC測定では単一のピークであった。また、該ペレットのMvは8,600であった。該ペレットを射出成型して2mm厚の板状成型片、3mm厚の円板及び4mm厚の角柱状成型片を得た。成型体は透明であった。評価結果を表1に示す。
〈比較例1〉
合成例1で作製したペレットを射出成型して2mm厚の板状成型片、3mm厚の円板及び4mm厚の角柱状成型片を得た。成型体は透明であった。評価結果を表1に示す。
〈比較例2〉
合成例2で作製したペレットを射出成型して2mm厚の板状成型片、3mm厚の円板及び4mm厚の角柱状成型片を得た。成型体は透明であった。評価結果を表1に示す。
〈比較例3〉
合成例3で作製したペレットを射出成型して2mm厚の板状成型片、3mm厚の円板及び4mm厚の角柱状成型片を得た。成型体は透明であった。評価結果を表1に示す。
〈比較例4〉
ビスフェノールA型ポリカーボネート樹脂からなるポリカーボネート樹脂“AD-5503”(帝人社製)のペレットを射出成型して2mm厚の板状成型片、3mm厚の円板及び4mm厚の角柱状成型片を得た。成型体は透明であった。評価結果を表1に示す。
〈比較例5〉
合成例1で製造した熱可塑性樹脂(A1)ペレット50.0質量部と、AD-5503のペレット50.0質量部をよく混合し、押出機(日本製鋼所社製 TEX30α 30mmφ二軸押出機)により270℃、ベント圧力30mmHgで溶融状態の熱可塑性樹脂(A1)及びAD-5503を混練してペレタイズしブレンドペレットを得た。該ペレットは白濁した。評価結果を表1に示す。
Claims (11)
- 前記式(4)のZがナフタレン環である請求項2に記載の熱可塑性樹脂組成物。
- 3mm厚みで測定した際のヘーズが、0.5%以下である、請求項1~3のいずれか一項に記載の熱可塑性樹脂組成物。
- 熱可塑性樹脂(A)および熱可塑性樹脂(B)の質量比率(A:B)が1:99~99:1である請求項1~4のいずれか一項に記載の熱可塑性樹脂組成物。
- 屈折率が1.645~1.690である請求項1~5のいずれか一項に記載の熱可塑性樹脂組成物。
- 配向複屈折が4.5×10-3以下である、請求項1~6のいずれか一項に記載の熱可塑性樹脂組成物。
- ノッチなしシャルピー衝撃強度が25J/m2以上である請求項1~7のいずれか一項に記載の熱可塑性樹脂組成物。
- 熱可塑性樹脂(A)がポリエステルカーボネート樹脂である請求項1~8のいずれか一項に記載の熱可塑性樹脂組成物。
- 熱可塑性樹脂(B)がポリエステルカーボネート樹脂、または、ポリカーボネート樹脂である請求項1~9のいずれか一項に記載の熱可塑性樹脂組成物。
- 請求項1~10のいずれか一項に記載の熱可塑性樹脂組成物を含む、光学部材。
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