WO2022021921A1 - 一种机器人谐波减速器润滑脂 - Google Patents
一种机器人谐波减速器润滑脂 Download PDFInfo
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- WO2022021921A1 WO2022021921A1 PCT/CN2021/084566 CN2021084566W WO2022021921A1 WO 2022021921 A1 WO2022021921 A1 WO 2022021921A1 CN 2021084566 W CN2021084566 W CN 2021084566W WO 2022021921 A1 WO2022021921 A1 WO 2022021921A1
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- WIPO (PCT)
- Prior art keywords
- parts
- harmonic reducer
- ester
- oil
- robot harmonic
- Prior art date
Links
- 239000003638 chemical reducing agent Substances 0.000 title claims abstract description 35
- 239000004519 grease Substances 0.000 title claims abstract description 32
- 230000001050 lubricating effect Effects 0.000 title claims abstract description 12
- -1 dipentaerythritol ester Chemical class 0.000 claims abstract description 36
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 17
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 15
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 15
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 15
- 239000011733 molybdenum Substances 0.000 claims abstract description 15
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 15
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000008117 stearic acid Substances 0.000 claims abstract description 15
- 101100407037 Oryza sativa subsp. japonica PAO6 gene Proteins 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910021485 fumed silica Inorganic materials 0.000 claims abstract description 14
- PQVSTLUFSYVLTO-UHFFFAOYSA-N ethyl n-ethoxycarbonylcarbamate Chemical compound CCOC(=O)NC(=O)OCC PQVSTLUFSYVLTO-UHFFFAOYSA-N 0.000 claims abstract description 13
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium hydroxide monohydrate Substances [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 claims abstract description 13
- 229940040692 lithium hydroxide monohydrate Drugs 0.000 claims abstract description 13
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- IKXFIBBKEARMLL-UHFFFAOYSA-N triphenoxy(sulfanylidene)-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=S)OC1=CC=CC=C1 IKXFIBBKEARMLL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 7
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 12
- SGHWILJCQCTGGE-UHFFFAOYSA-N 2-dodecyl-2-hydroxyoctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)(C(O)=O)CCCCCCCCCCCC SGHWILJCQCTGGE-UHFFFAOYSA-N 0.000 claims description 6
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 6
- 239000003921 oil Substances 0.000 abstract description 13
- 239000000654 additive Substances 0.000 abstract description 8
- 239000002199 base oil Substances 0.000 abstract description 6
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 230000000996 additive effect Effects 0.000 abstract description 2
- RMKNTZWZQFIOOB-UHFFFAOYSA-N n-butyl-2-octyl-n-phenylaniline Chemical compound CCCCCCCCC1=CC=CC=C1N(CCCC)C1=CC=CC=C1 RMKNTZWZQFIOOB-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004327 boric acid Substances 0.000 abstract 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 abstract 1
- 239000012990 dithiocarbamate Substances 0.000 abstract 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 4
- SXNBVULTHKFMNO-UHFFFAOYSA-N 2,2-dihydroxyoctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)(O)C(O)=O SXNBVULTHKFMNO-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000003064 anti-oxidating effect Effects 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 101150092791 PAO4 gene Proteins 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 231100000241 scar Toxicity 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- JJJPTTANZGDADF-UHFFFAOYSA-N thiadiazole-4-thiol Chemical compound SC1=CSN=N1 JJJPTTANZGDADF-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/105—Silica
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
- C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Definitions
- the invention relates to the field of new materials, in particular to a lubricating grease for a robot harmonic reducer.
- the robot harmonic reducer grease is a high-end grease specially used for the harmonic reducer on the robot arm to lubricate, prevent rust, cool down and reduce wear.
- the present invention provides a long-life robot harmonic reducer grease to solve the above-mentioned defects.
- a kind of robot harmonic reducer lubricating grease the raw material of the robot harmonic reducer lubricating grease is composed of the following components by weight:
- the 150N (three types of oil) is 20 parts
- PAO6 is 20 parts
- dipentaerythritol ester is 10 parts
- lithium hydroxide monohydrate is 1.2 parts
- stearic acid is 1.6 parts
- twelve 6.4 parts of hydroxystearic acid 1 part of fumed silica
- 1 part of molybdenum dialkyldithiocarbamate 0.8 part of triphenyl thiophosphate, 0.5 part of borate, and 0.5 part of octylbutyldiphenylamine 0.5 part and 0.5 part of phenolic ester antioxidant.
- the 150N (three types of oil) is 30 parts
- the PAO6 is 30 parts
- the dipentaerythritol ester is 12.5 parts
- the lithium hydroxide monohydrate is 1.2 parts
- the stearic acid is 1.6 parts
- the ten 6.4 parts of dihydroxystearic acid 1.5 parts of fumed silica
- 2 parts of molybdenum dialkyldithiocarbamate 1.25 parts of triphenyl thiophosphate
- the phenolic ester antioxidant is 0.75 part.
- the 150N (three types of oil) is 40 parts
- PAO6 is 40 parts
- dipentaerythritol ester is 12.5 parts
- lithium hydroxide monohydrate is 1.2 parts
- stearic acid is 1.6 parts
- ten 6.4 parts of dihydroxystearic acid 1.8 parts
- fumed silica 3.5 parts
- molybdenum dialkyldithiocarbamate 1.1 parts
- triphenyl thiophosphate 0.75 parts of borate
- octylbutyldiphenylamine It is 0.75 part
- the phenolic ester antioxidant is 0.75 part.
- the 150N (three types of oil) is 35 parts, PAO6 is 32 parts, dipentaerythritol ester is 11 parts, lithium hydroxide monohydrate is 1.2 parts, stearic acid is 1.6 parts, ten 6.4 parts of dihydroxystearic acid, 1.5 parts of fumed silica, 2 parts of molybdenum dialkyldithiocarbamate, 1.25 parts of triphenyl thiophosphate, 0.75 parts of borate, octylbutyldiphenylamine It is 0.85 part, and the phenolic ester antioxidant is 0.95 part.
- 150N (three types of oil) is mineral oil, which has good compatibility with additives and is conducive to better functioning of additives;
- PAO6 is a synthetic base oil, which has better low-temperature properties and oxidation resistance than mineral oil. , but it has poor compatibility with additives, and can be used together with mineral oil to make up for its shortcomings;
- dipentaerythritol ester has very good lubricating properties and additive compatibility, which can effectively reduce the temperature generated by the operation of harmonic reducers; monohydrate hydrogen Lithium oxide, stearic acid and dodecahydroxystearic acid are all thickeners for preparing lithium-based grease.
- Lithium-based grease has the characteristics of shear resistance, good high temperature resistance and stable preparation process; fumed silica It can improve the high temperature performance of lubricating grease and reduce the separation of lubricating oil from lubricating grease; molybdenum dialkyldithiocarbamate, triphenyl thiophosphate and borate are all wear reducing agents, and the synergistic effect of the three makes Grease has very good anti-wear properties; octyl butyl diphenylamine and phenolic ester antioxidants are both antioxidants, and the synergistic effect of the two is also of great help to the service life of the grease; through mineral oil, synthetic base oil , Ester oils complement each other's advantages and disadvantages.
- Embodiment 1 is a diagrammatic representation of Embodiment 1:
- a robot harmonic reducer grease the raw material of the robot harmonic reducer grease is composed of the following components by weight: 20 parts of 150N (three types of oil), 20 parts of PAO6, and 10 parts of dipentaerythritol ester. parts, 1.2 parts of lithium hydroxide monohydrate, 1.6 parts of stearic acid, 6.4 parts of dodecylhydroxystearic acid, 1 part of fumed silica, 1 part of molybdenum dialkyldithiocarbamate, sulfur 0.8 part of triphenyl phosphate, 0.5 part of borate, 0.5 part of octylbutyldiphenylamine, and 0.5 part of phenolic ester antioxidant.
- Embodiment 2 is a diagrammatic representation of Embodiment 1:
- a robot harmonic reducer grease the raw material of the robot harmonic reducer grease is composed of the following components by weight: 30 parts of 150N (three types of oil), 30 parts of PAO6, and 12.5 parts of dipentaerythritol ester 1.2 parts of lithium hydroxide monohydrate, 1.6 parts of stearic acid, 6.4 parts of dodecahydroxystearic acid, 1.5 parts of fumed silica, 2 parts of molybdenum dialkyldithiocarbamate, sulfur
- the triphenyl phosphate was 1.25 parts
- the borate ester was 1.15 parts
- the octylbutyl diphenylamine was 0.75 parts
- the phenolic ester antioxidant was 0.75 parts.
- a robot harmonic reducer grease the raw material of the robot harmonic reducer grease is composed of the following components by weight: 40 parts of 150N (three types of oil), 40 parts of PAO6, and 12.5 parts of dipentaerythritol ester 1.2 parts of lithium hydroxide monohydrate, 1.6 parts of stearic acid, 6.4 parts of dodecylhydroxystearic acid, 1.8 parts of fumed silica, 3.5 parts of molybdenum dialkyldithiocarbamate, sulfur 1.1 part of triphenyl phosphate, 0.75 part of borate, 0.75 part of octylbutyl diphenylamine, and 0.75 part of phenolic ester antioxidant.
- a robot harmonic reducer grease the raw material of the robot harmonic reducer grease is composed of the following components by weight: 35 parts of 150N (three types of oil), 32 parts of PAO6, and 11 parts of dipentaerythritol ester 1.2 parts of lithium hydroxide monohydrate, 1.6 parts of stearic acid, 6.4 parts of dodecahydroxystearic acid, 1.5 parts of fumed silica, 2 parts of molybdenum dialkyldithiocarbamate, sulfur 1.25 parts of triphenyl phosphates, 0.75 parts of borate esters, 0.85 parts of octylbutyldiphenylamine, and 0.95 parts of phenolic ester antioxidants.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
一种机器人谐波减速器润滑脂,该机器人谐波减速器润滑脂的原料按重量份由以下组份组成:20-40份150N(三类油),20-40份PAO6,10-15份双季戊四醇酯,1-3份单水氢氧化锂,1-5份硬脂酸,6-12份十二羟基硬脂酸,1-3份气相二氧化硅,1-4份二烷基二硫代氨基甲酸钼,0.8-1.5份硫代磷酸三苯酯,0.5-1份硼酸酯,0.5-1份辛丁基二苯胺,酚酯类抗氧剂。基础油和添加剂相互作用使润滑脂具有非常好的减磨和抗氧化性能,提高了机器人谐波减速器的寿命。
Description
本发明涉及一种新材料领域,具体涉及一种机器人谐波减速器润滑脂。
机器人谐波减速器润滑脂是专门用于机器人手臂关闭上的谐波减速器,起到润滑、防锈、降温及减磨作用的一款高端润滑脂。
机器人代替人工是未来的发展方向,在“机器人换人”大潮下,中国已经连续两年坐上世界机器人做大消费国的宝座。
目前市场上谐波减速器用的绝大部多数润滑脂都被国外垄断,国产润滑脂在寿命上还是远不如进口润滑脂。关键原因是国产润滑脂在减磨性能上跟进口润滑脂存在差距,减磨性能的不足致使谐波减速器磨损大,温升高,降低谐波减速器的使用寿命。而坚决这一关键问题的方法就是基础油和添加剂的完美配伍,配伍不合理会造成谐波减速器磨损大、抗氧化性能差、长期使用出现油泥等情况,严重影响谐波减速器的使用寿命,这正是制备机器人谐波减速器的最大难点。
发明内容
本发明提供一种长寿命机器人谐波减速器润滑脂以解决上述缺陷。
本发明采用的技术方案如下:
一种机器人谐波减速器润滑脂,所述机器人谐波减速器润滑脂的原料按重量份由以下组份组成:
在一个具体的实施方式中,所述150N(三类油)为20份、PAO6为20份、双季戊四醇酯为10份、单水氢氧化锂为1.2份、硬脂酸为1.6份、十二羟基硬脂酸为6.4份、气相二氧化硅为1份、二烷基二硫代氨基甲酸钼为1份、硫代磷酸三苯酯为0.8份、硼酸酯为0.5份、辛丁基二苯胺为0.5份、酚酯类抗氧剂为0.5份。
在另一个具体的实施方式中,所述150N(三类油)为30份、PAO6为30份、双季戊四醇酯为12.5份、单水氢氧化锂为1.2份、硬脂酸为1.6份、十二羟基硬脂酸为6.4份、气相二氧化硅为1.5份、二烷基二硫代氨基甲酸钼为2份、硫代磷酸三苯酯为1.25份、硼酸酯为1.15份、辛丁基二苯胺为0.75份、酚酯类抗氧剂为0.75份。
在另一个具体的实施方式中,所述150N(三类油)为40份、PAO6为40份、双季戊四醇酯为12.5份、单水氢氧化锂为1.2份、硬脂酸为1.6份、十二羟基硬脂酸为6.4份、气相二氧化硅为1.8份、二烷基二硫代氨基甲酸钼为3.5份、 硫代磷酸三苯酯为1.1份、硼酸酯为0.75份、辛丁基二苯胺为0.75份、酚酯类抗氧剂为0.75份。
在另一个具体的实施方式中,所述150N(三类油)为35份、PAO6为32份、双季戊四醇酯为11份、单水氢氧化锂为1.2份、硬脂酸为1.6份、十二羟基硬脂酸为6.4份、气相二氧化硅为1.5份、二烷基二硫代氨基甲酸钼为2份、硫代磷酸三苯酯为1.25份、硼酸酯为0.75份、辛丁基二苯胺为0.85份、酚酯类抗氧剂为0.95份。
本发明中,150N(三类油)为矿物油,跟添加剂有较好的相容性,有利于添加剂更好的发挥作用;PAO6为合成基础油,低温性、抗氧化性比矿物油更好,但是跟添加剂相容性较差,与矿物油一起使用可弥补其缺点;双季戊四醇酯有非常好的润滑性能和添加剂相容性,可有效降低谐波减速器运转产生的温度;单水氢氧化锂、硬脂酸和十二羟基硬脂酸均为制备锂基润滑脂的稠化剂,锂基润滑脂具有抗剪切性能、耐高温性能好、制备工艺稳定的特点;气相二氧化硅可提高润滑脂的高温性能,并减少润滑油从润滑脂中分离;二烷基二硫代氨基甲酸钼、硫代磷酸三苯酯、硼酸酯均为减磨剂,三者的协同作用使润滑脂具有非常好的减磨性能;辛丁基二苯胺和酚酯类抗氧剂都是抗氧剂,两者的协同作用对润滑脂的使用寿命亦有很大帮助;通过矿物油、合成基础油、酯类油三者优缺点互补,同时通过三款减磨剂(二烷基二硫代氨基甲酸钼、硫代磷酸三苯酯、硼酸酯)及两款抗氧剂(辛丁基二苯胺、酚酯类抗氧剂)的协同作用,从减磨、抗氧两方面提高机器人谐波减速器寿命。
实施方式一:
一种机器人谐波减速器润滑脂,所述机器人谐波减速器润滑脂的原料按重 量份由以下组份组成:150N(三类油)为20份、PAO6为20份、双季戊四醇酯为10份、单水氢氧化锂为1.2份、硬脂酸为1.6份、十二羟基硬脂酸为6.4份、气相二氧化硅为1份、二烷基二硫代氨基甲酸钼为1份、硫代磷酸三苯酯为0.8份、硼酸酯为0.5份、辛丁基二苯胺为0.5份、酚酯类抗氧剂为0.5份。
实施方式二:
一种机器人谐波减速器润滑脂,所述机器人谐波减速器润滑脂的原料按重量份由以下组份组成:150N(三类油)为30份、PAO6为30份、双季戊四醇酯为12.5份、单水氢氧化锂为1.2份、硬脂酸为1.6份、十二羟基硬脂酸为6.4份、气相二氧化硅为1.5份、二烷基二硫代氨基甲酸钼为2份、硫代磷酸三苯酯为1.25份、硼酸酯为1.15份、辛丁基二苯胺为0.75份、酚酯类抗氧剂为0.75份。
实施方式三:
一种机器人谐波减速器润滑脂,所述机器人谐波减速器润滑脂的原料按重量份由以下组份组成:150N(三类油)为40份、PAO6为40份、双季戊四醇酯为12.5份、单水氢氧化锂为1.2份、硬脂酸为1.6份、十二羟基硬脂酸为6.4份、气相二氧化硅为1.8份、二烷基二硫代氨基甲酸钼为3.5份、硫代磷酸三苯酯为1.1份、硼酸酯为0.75份、辛丁基二苯胺为0.75份、酚酯类抗氧剂为0.75份。
实施方式四:
一种机器人谐波减速器润滑脂,所述机器人谐波减速器润滑脂的原料按重量份由以下组份组成:150N(三类油)为35份、PAO6为32份、双季戊四醇酯为11份、单水氢氧化锂为1.2份、硬脂酸为1.6份、十二羟基硬脂酸为6.4份、气相二氧化硅为1.5份、二烷基二硫代氨基甲酸钼为2份、硫代磷酸三苯酯为1.25份、硼酸酯为0.75份、辛丁基二苯胺为0.85份、酚酯类抗氧剂为0.95份。
对照例一:
将实施方式二中的20份150N(三类油)用20份PAO4替代,其余组分不变。
对照例二:
将实施方式二中的12.5份双季戊四醇酯用12.5份PAO4替代,其余组分不变。
对照例三:
在实施方式二基础上,加入1%的磷酸三甲酚酯。
对照例四:
在实施方式二基础上,加入1%巯基噻二唑。
对照例四:
在实施方式二基础上,加入1%伯烷基二硫代磷酸锌。
对上述实施方式以及对照例进行测试(具体测试方法如下表所示),测试结果如下:
表1
从表1可以看出,实验方式二滴点(高温性能)、PB(油膜强度)、PD(极压性能)、磨斑直径(减磨性能)及氧化安定性(抗氧化性能)都处于一个较均衡的水平。替换其中的基础油或者增加其他添加剂都会破坏最重要的两个性能:磨斑直径(减磨性能)和PB(油膜强度)。实验方式二中基础油和添加剂的协同作用可避免谐波减速器在长期高温高速的运转情况下较早出现磨损造成寿命降低。
对于本领域技术人员而言,显然本发明不限于上述示范性实施例的细节,而且在不背离本发明的精神或基本特征的情况下,能够以其他的具体形式实现 本发明。因此,无论从哪一点来看,均应将实施例看作是示范性的,而且是非限制性的,本发明的范围由所附权利要求而不是上述说明限定,因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。不应将权利要求中的任何附图标记视为限制所涉及的权利要求。
此外,应当理解,虽然本说明书按照实施方式加以描述,但并非每个实施方式仅包含一个独立的技术方案,说明书的这种叙述方式仅仅是为清楚起见,本领域技术人员应当将说明书作为一个整体,各实施例中的技术方案也可以经适当组合,形成本领域技术人员可以理解的其他实施方式。
Claims (5)
- 如权利要求1所述的机器人谐波减速器润滑脂,其特征在于:所述150N(三类油)为20份、PAO6为20份、双季戊四醇酯为10份、单水氢氧化锂为1份、硬脂酸为1份、十二羟基硬脂酸为6份、气相二氧化硅为1份、二烷基二硫代氨基甲酸钼为1份、硫代磷酸三苯酯为0.8份、硼酸酯为0.5份、辛丁基二苯胺为0.5份、酚酯类抗氧剂为0.5份。
- 如权利要求1所述的机器人谐波减速器润滑脂,其特征在于:所述150N(三类油)为30份、PAO6为30份、双季戊四醇酯为12.5份、单水氢氧化锂为2份、硬脂酸为2.5份、十二羟基硬脂酸为9份、气相二氧化硅为1.5份、二烷基二硫代氨基甲酸钼为2份、硫代磷酸三苯酯为1.25份、硼酸酯为1.15份、辛丁 基二苯胺为0.75份、酚酯类抗氧剂为0.75份。
- 如权利要求1所述的机器人谐波减速器润滑脂,其特征在于:所述150N(三类油)为40份、PAO6为40份、双季戊四醇酯为12.5份、单水氢氧化锂为2.5份、硬脂酸为4份、十二羟基硬脂酸为12份、气相二氧化硅为1.8份、二烷基二硫代氨基甲酸钼为3.5份、硫代磷酸三苯酯为1.1份、硼酸酯为0.75份、辛丁基二苯胺为0.75份、酚酯类抗氧剂为0.75份。
- 如权利要求1所述的机器人谐波减速器润滑脂,其特征在于:所述150N(三类油)为35份、PAO6为32份、双季戊四醇酯为11份、单水氢氧化锂为2份、硬脂酸为2.5份、十二羟基硬脂酸为9份、气相二氧化硅为1.5份、二烷基二硫代氨基甲酸钼为2份、硫代磷酸三苯酯为1.25份、硼酸酯为0.75份、辛丁基二苯胺为0.85份、酚酯类抗氧剂为0.95份。
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