WO2021184162A1 - 电极极片、电芯及电化学装置 - Google Patents
电极极片、电芯及电化学装置 Download PDFInfo
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- WO2021184162A1 WO2021184162A1 PCT/CN2020/079497 CN2020079497W WO2021184162A1 WO 2021184162 A1 WO2021184162 A1 WO 2021184162A1 CN 2020079497 W CN2020079497 W CN 2020079497W WO 2021184162 A1 WO2021184162 A1 WO 2021184162A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0431—Cells with wound or folded electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/665—Composites
- H01M4/667—Composites in the form of layers, e.g. coatings
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/668—Composites of electroconductive material and synthetic resins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/538—Connection of several leads or tabs of wound or folded electrode stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/54—Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- This application relates to the field of energy storage technology, and in particular to an electrode pole piece, a cell and an electrochemical device including the electrode pole piece.
- Lithium-ion batteries have many advantages such as large volume and mass energy density, long cycle life, high nominal voltage, low self-discharge rate, small size, and light weight, and have a wide range of applications in the field of consumer electronics. With the rapid development of electric vehicles and portable electronic devices in recent years, people have higher and higher requirements for the energy density, safety, and cycle performance of lithium-ion batteries.
- the current collector has the function of collecting the current generated by the active material of the lithium-ion battery to form a larger current for external output.
- the use of composite current collectors can further increase energy density, increase toughness and ductility, so as to achieve process optimization in production, as well as increase energy density per unit mass and improve safety.
- the metal layers on both sides of the composite current collector are isolated by the polymer layer in the middle and cannot be conducted, which affects the performance of the lithium ion battery.
- the present application provides an electrode pole piece that can conveniently conduct the metal layers on both sides of the composite current collector, and a cell and an electrochemical device including the electrode pole piece.
- the embodiment of the application provides an electrode pole piece, which includes a composite current collector, a first tab, a second tab, and an active material layer.
- the composite current collector includes a first metal layer, a second metal layer, and a polymer layer sandwiched between the first metal layer and the second metal layer.
- the first tab is arranged on the edge of the first metal layer and extends out of the polymer layer.
- the second tab corresponding to the first tab is arranged on the edge of the second metal layer and extends out of the polymer layer.
- the second tab and the first tab extend in the same direction.
- the active material layer is arranged on the first metal layer and the second metal layer, and covers the first tab located on the first metal layer and the second tab located on the second metal layer.
- the electrode pole piece provided by the embodiment of the present application can conduct the first tab and the second tab through welding, etc., and can realize the conduction between the first metal layer and the second metal on both sides of the composite current collector .
- both the first tab and the second tab are arranged at intervals along the length direction of the electrode pole piece.
- the projection of the first tab overlaps the projection of the second tab.
- the projection of the first tab along the thickness direction of the electrode pole piece and the projection of the second tab along the thickness direction of the electrode pole piece are alternately arranged in sequence.
- the overall thickness of the electrode tab can be reduced.
- the spacing between two adjacent first tabs is equal, and the spacing between two adjacent second tabs is equal.
- the distance between two adjacent first tabs increases or decreases along the length direction of the electrode pole piece, and the distance between two adjacent second tabs increases or decreases along the length direction of the electrode pole piece correspondingly. Decreasing.
- the electrode pole piece in the length direction of the electrode pole piece, includes a head portion, a middle portion, and a tail portion that are sequentially connected, and the first tab is disposed at at least one of the head portion, the middle portion, and the tail portion of the first metal layer.
- the second tab corresponding to the first tab is disposed at at least one of the head, middle, and tail of the second metal layer.
- the electrode pole piece further includes a first end surface disposed adjacent to the head and a second end surface disposed adjacent to the tail.
- first tab and the second tab are both disposed on the head or tail of the second metal layer In the length direction of the electrode pole piece, the distance between the first tab and the second tab and the first end surface or the second end surface is less than 1/5 of the length of the electrode pole piece.
- the polymer layer extends outside the first metal layer and the second metal layer in the width direction of the electrode pole piece, and the side of the first tab and the second tab away from the polymer layer is provided with an insulating sheet.
- the first tab and the second tab can be insulated to avoid short circuits.
- the first tab is attached to the surface of the first metal layer
- the second tab is attached to the surface of the second metal layer
- the embodiment of the present application also provides a battery cell, including a first pole piece, a second pole piece, and an isolation film arranged between the first pole piece and the second pole piece.
- the first pole piece and the second pole piece are stacked or Winding to form a battery core.
- the first pole piece is any one of the above-mentioned electrode pole pieces.
- the first tab is electrically connected to the second tab. By electrically connecting the first tab and the second tab, the first metal layer and the second metal layer of the composite current collector can be conducted.
- the projection of the first tab overlaps with the projection of the second tab.
- the embodiment of the present application also provides an electrochemical device, including an adapter sheet and any of the above-mentioned batteries.
- the first tab and the second tab are stacked to form a multi tab structure, and the multi tab structure is connected with the adapter sheet.
- FIG. 1 is a schematic diagram of the structure of an electrochemical device provided by the first embodiment of the application.
- FIG. 2 is a plan view of the first pole piece of the cell of the electrochemical device shown in FIG. 1 with the active material layer removed.
- Figure 3 is a side view of the first pole piece shown in Figure 2
- Fig. 4 is a bottom view of the first pole piece shown in Fig. 2.
- Fig. 5 is a side view of the first pole piece provided by the second embodiment of the application.
- Fig. 6 is a side view of the first pole piece provided by the third embodiment of the application.
- FIG. 7 is a side view of the first pole piece provided by the fourth embodiment of the application.
- FIG. 8 is a side view of the first pole piece provided by the fifth embodiment of this application.
- FIG. 9 is a side view of the first pole piece provided by the sixth embodiment of this application.
- FIG. 10 is a side view of the first pole piece provided by the seventh embodiment of this application.
- FIG. 11 is a side view of the first pole piece provided by the eighth embodiment of this application.
- FIG. 12 is a side view of the first pole piece provided by the ninth embodiment of this application.
- the second pole piece 150 is The second pole piece 150
- the electrochemical device 100 provided by the first embodiment of the present application includes a battery cell 10 and an adapter plate 30.
- the battery cell 10 includes a first pole piece 130, a second pole piece 150, and an isolation film 160 disposed between the first pole piece 130 and the second pole piece 150.
- the first pole piece 130 and the second pole piece 150 are wound or stacked to form the battery core 10.
- the first pole piece 130 includes a composite current collector 131, a first pole 133 and a second pole 134.
- the first tab 133 and the second tab 134 are arranged on two opposite surfaces of the composite current collector 131 and located on the same side of the first pole piece 130.
- the first tab 133 and the The extension direction of the second tab 134 is the same.
- the first tab 133 and the second tab 134 are electrically connected by the adapter plate 30 to conduct two opposite surfaces of the composite current collector 131.
- the composite current collector 131 includes a first metal layer 132, a second metal layer 135, and a polymer layer 136 sandwiched between the first metal layer 132 and the second metal layer 135.
- the first tab 133 is disposed on the edge of the first metal layer 132 and extends out of the polymer layer 136.
- the second tab 134 is disposed on the edge of the second metal layer 135 and extends out of the polymer layer 136. Please also refer to FIG. 2.
- the first tab 133 is disposed on the edge of the first metal layer 132 along the length direction L of the first pole piece 130 and extends from the first pole piece.
- the width direction W of 130 extends out of the polymer layer 136; the second tab 134 is disposed on the edge of the second metal layer 135 along the length direction L of the first pole piece 130 and extends from the width direction W
- the polymer layer 136 is extended.
- the length direction L of the first pole piece 130 refers to the extension direction of the first pole piece 130, that is, the direction in which the battery core 10 is wound; the width direction W of the first pole piece 10 It refers to the extension direction of the tab, and is substantially perpendicular to the length direction L.
- the first tab 133 and the second tab 134 are stacked to form a multi-pole structure 17, and the multi-pole structure 17 is connected to the adapter plate 30 to conduct the first metal layer. 132 and the second metal layer 135.
- the cell 10 in FIG. 1 shows two layers of first pole pieces 130 for illustration, and the second tab 134 on the first pole piece 130 of one layer faces the first pole piece 130 on the other layer. After the first tab 133 is bent and extended, it is stacked with the first tab 133 to form the multi- tab structure 17.
- the material of the polymer layer 136 is selected from polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polyether ether ketone, polyimide, and polyamide. , Polyethylene glycol, polyamideimide, polycarbonate, cyclic polyolefin, polyphenylene sulfide, polyvinyl acetate, polytetrafluoroethylene, polymethylene naphthalene, polyvinylidene fluoride, polynaphthalene Ethylene diformate, polypropylene carbonate, polyvinylidene fluoride-hexafluoropropylene, poly(vinylidene fluoride-co-chlorotrifluoroethylene), silicone, vinylon, polypropylene, polyethylene, poly At least one of vinyl chloride, polystyrene, polyether nitrile, polyurethane, polyphenylene ether, polyester, and polysulfone and derivatives thereof.
- Both the first metal layer 132 and the second metal layer 135 can be formed by sputtering, vacuum deposition, ion plating, laser pulse deposition and other methods. Since the polymer layer 136 only needs to be cut during preparation, metal burrs generated during cutting of traditional current collectors can be avoided, the voltage drop (K value) of the battery per unit time can be improved, and the safety performance of the battery can be improved.
- the material of the first metal layer 132 and the second metal layer 135 can be selected from Ni, Ti, Cu, Ag, Au, Pt, Fe, Co, Cr, W, Mo, Al, Mg, K, Na , Ca, Sr, Ba, Si, Ge, Sb, Pb, In, Zn, and at least one of combinations (alloys) thereof.
- the materials of the first metal layer 132 and the second metal layer 135 may be the same or different.
- the first tab 133 and the second tab 134 are both metal sheets, and the material can be selected from Ni, Ti, Cu, Ag, Au, Pt, Fe, Co, Cr, W, Mo, Al, Mg At least one of, K, Na, Ca, Sr, Ba, Si, Ge, Sb, Pb, In, Zn, and combinations (alloys) thereof.
- the projection of the first tab 133 overlaps with the projection of the second tab 134.
- the first tab 133 and the second tab 134 overlap together, so that the first tab 133 and the second tab
- the connection of 134 is more convenient.
- the thickness direction H of the battery core 10 refers to the stacking direction of each laminated structure formed after the pole pieces in the battery core 10 are wound or the stacking direction of the pole pieces in the battery core 10.
- the polymer layer 136 extends from the first metal layer 132 and the second metal layer 135 in the width direction W of the first pole piece 10.
- the polymer layer 136 includes a coated area 1361 and a non-coated area 1363 connected to the coated area 1361.
- the coating area 1361 is used for disposing the first metal layer 132 and the second metal layer 135.
- the first tab 133 and the second tab 134 are attached to the surface of the first metal layer 132 and the second metal layer 135 away from the polymer layer 136 and extend to cover the non-coating layer.
- the polymer layer 136 extends after the covering area 1363. Please refer to FIG. 1 again.
- the first pole piece 130 further includes a first active material layer 137.
- the first active material layer 137 is disposed on the first metal layer 132 and the second metal layer 135 and covers the first tab 133 and the second tab 134 on the coating area 1361.
- the coating area 1361, the first metal layer 132, the second metal layer 135, and the first active material layer 137 are flush with each other.
- the thickness of the edge of the first pole piece 130 on which the tab is provided is the polymer layer 136, the first tab 133, and the second The thickness of the tab 134, which does not include the thickness of the first metal layer 132 and the thickness of the second metal layer 135, reduces the thickness of the edge of the first pole piece 130, which can reduce the battery core 10 occupies a space in the thickness direction H, thereby increasing the energy density of the electrochemical device 100.
- the first tab 133 and the second tab 134 are partially embedded in the first active material layer 137, which can reduce the The space occupied in the width direction W further increases the energy density of the electrochemical device 100.
- the first pole piece 130 is a cathode pole piece
- the second pole piece 150 is an anode pole piece.
- the second pole piece 150 includes a current collector 151 and a second active material layer 153 coated on two opposite surfaces of the current collector 151.
- the current collector 151 is a metal foil. In the width direction W of the first pole piece 10, the current collector 151 is flush with the second active material layer 153, and the second active material layer 153 extends beyond the first active material layer 137 .
- the battery core 10 further includes an insulating sheet 170.
- the insulating sheet 170 is disposed on the side of the first tab 133 and the second tab 134 away from the polymer layer 136, and covers the first tab 133 and the second tab 133 in the non-coating area 1363.
- the second tab 134 is used to insulate the first tab 133 and the second tab 134.
- the first tabs 133 are disposed on the edge of the first metal layer 132, and are arranged at intervals along the length direction L of the first pole piece 130.
- the second tabs 134 are arranged on the edge of the second metal layer 135 and are arranged at intervals along the length direction L of the first pole piece 130.
- the projection of the first pole piece 133 along the thickness direction H of the first pole piece 130 and the second pole piece 134 along the first pole piece The projections of the thickness direction H of 130 are arranged alternately in sequence.
- the thickness direction H of the first pole piece 130 refers to the stacking direction of the laminated structure in the first pole piece 130.
- the thickness direction H of the first pole piece 130 is The thickness direction H of the battery core 10 is consistent.
- the distance between two adjacent first tabs 133 increases along the length direction L, and the distance between two adjacent second tabs 134 correspondingly increases along the length direction L.
- the projection of the first tab 133 in the thickness direction H overlaps with the projection of the second tab 134 in the thickness direction H.
- the length direction L extends from left to right. It can be understood that when the length direction L is marked as extending from right to left, the distance between two adjacent first tabs 133 decreases along the length direction L.
- the distance between two adjacent second tabs 134 decreases correspondingly along the length direction L.
- the electrochemical device provided in the second embodiment of the present application is substantially the same as the electrochemical device provided in the first embodiment, except that the first tab 233 and the second tab 234 are on the first pole piece 230 Way of setting.
- the first tabs 233 are arranged on the edge of the first metal layer 232 and are arranged at intervals along the length direction L
- the second tabs 234 are disposed on the second tabs 233 corresponding to the first tabs 233.
- the edges of the metal layer 235 are arranged at intervals along the length direction L; in the length direction L, the projection of the first tab 233 along the thickness direction H and the thickness of the second tab 234 along the first pole piece 130 The projections of the direction H overlap.
- the distance between two adjacent first tabs 233 increases along the length direction L, and the distance between two adjacent second tabs 234 increases correspondingly along the length direction L.
- the first tab 233 and the second tab 234 are added, so that the positions of the first tab 233 and the second tab 234 are in the thickness direction of the first pole piece 230.
- the impedance of the electrochemical device can be reduced.
- the electrochemical device provided by the third embodiment of the present application is substantially the same as the electrochemical device provided by the second embodiment, except that the first tab 333 and the second tab 334 are on the first pole piece 330
- the arrangement way Specifically, the first tabs 333 are disposed on the edge of the first metal layer 332 and are arranged at intervals along the length direction L, and the second tabs 334 are disposed on the second tabs 333 corresponding to the first tabs 333.
- the edges of the metal layer 335 are arranged at intervals along the length direction L; in the length direction L, the projection of the first tab 333 along the thickness direction H and the thickness of the second tab 334 along the first pole piece 130 The projections of the direction H overlap.
- the distance between two adjacent first tabs 333 is equal, and the distance between two adjacent second tabs 334 is equal.
- the first pole piece 330 in this embodiment is stacked to form the battery core.
- the electrochemical device provided by the fourth embodiment of the present application is substantially the same as the electrochemical device provided by the first embodiment, except that the first tab 433 and the second tab 434 are on the first pole piece 430 The setting location.
- the first pole piece 430 includes a head 481, a middle portion 482, and a tail 483 connected in sequence, and the first pole piece 433 is disposed on the head 481 of the first metal layer 432.
- the second tab 434 corresponds to the head 481 of the first tab 433 on the second metal layer 435.
- the first pole piece 430 also includes a first end surface 491 and a second end surface 493 that are arranged oppositely.
- the first end surface 491 is the initial end of the first pole piece 430 in the length direction L
- the second end surface 493 is The end of the first pole piece 430 in the length direction L.
- the head of the first pole piece 430 is disposed adjacent to the first end surface 491
- the tail of the first pole piece 430 is disposed adjacent to the second end surface 493
- the middle of the first pole piece 430 It is arranged adjacent to the center of the first pole piece 430.
- the first pole piece 430 is equally divided into a first section, a second section, and a third section from the first end surface 491 to the second end surface 493, the first section adjacent to the first end surface 491 is the head, and the first section adjacent to the first end surface 491 The third section of the two end face 493 is the tail, and the second section is the middle.
- the distance between the first tab 433 and the second tab 434 and the first end surface 491 is less than 1/5 of the length of the first pole piece 430 .
- the first pole piece 430 of this embodiment can be stacked or wound to form the battery core.
- the electrochemical device provided in the fifth embodiment of the present application is substantially the same as the electrochemical device provided in the fourth embodiment, except that the first tab 533 and the second tab 534 are on the first pole piece 530 The setting location.
- the first tab 533 is disposed on the tail 583 of the first metal layer 532
- the second tab 534 is disposed on the tail 583 of the second metal layer 535 corresponding to the first tab 533.
- the distance between the first tab 533 and the second tab 534 and the first end surface 493 is less than 1/5 of the length of the first pole piece 530 .
- the electrochemical device provided in the sixth embodiment of the present application is substantially the same as the electrochemical device provided in the fourth embodiment, except that the first tab 633 and the second tab 634 are on the first pole piece 630 The setting location. Specifically, the first tab 633 is disposed in the middle 682 of the first metal layer 632, and the second tab 634 is disposed in the middle 682 of the second metal layer 635 corresponding to the first tab 633.
- the electrochemical device provided in the seventh embodiment of the present application is substantially the same as the electrochemical device provided in the fourth embodiment, except that the first tab 733 and the second tab 734 are on the first pole piece 730 The setting location.
- the first tab 733 is disposed on the head 781 and the tail 783 of the first metal layer 732
- the second tab 734 corresponds to the head of the first tab 733 disposed on the second metal layer 735. Section 781 and tail 783.
- the electrochemical device provided in the eighth embodiment of the present application is substantially the same as the electrochemical device provided in the fourth embodiment, except that the first tab 833 and the second tab 834 are on the first pole piece 830 The setting location.
- the first tab 833 is disposed on the head 881 and the middle part 882 of the first metal layer 832
- the second tab 834 corresponds to the first tab 833 disposed on the head of the second metal layer 835 881 and central 882.
- the electrochemical device provided in the ninth embodiment of the present application is substantially the same as the electrochemical device provided in the fourth embodiment, except that the first tab 933 and the second tab 934 are on the first pole piece 930 The setting location.
- the first tab 933 is disposed on the tail 983 and the middle part 981 of the first metal layer 932
- the second tab 934 is corresponding to the first tab 933 disposed on the tail 983 and the middle part of the second metal layer 935.
- Central 982 is Central 982.
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- Secondary Cells (AREA)
Abstract
一种电极极片(130、230、330、430、530、630、730、830、930)、包括所述电极极片(130、230、330、430、530、630、730、830、930)的电芯(10)及电化学装置(100)。所述电极极片(130、230、330、430、530、630、730、830、930)包括复合集流体(131)、第一极耳( 133、233、333、433、533、633、733、833、933)、第二极耳(134、234、334、434、534、 634、734、834、934)及活性物质层(137)。复合集流体(131)包括第一金属层( 132、232、332、432、532、 632、732、832、932)、第二金属层(135、235、335、435、535、 635、735、835、935)及夹设于第一金属层( 132、232、332、432、532、 632、732、832、932)与第二金属层(135、235、335、435、535、 635、735、835、935)之间的聚合物层(136)。第一极耳( 133、233、333、433、533、633、733、833、933)设置于第一金属层( 132、232、332、432、532、 632、732、832、932)的边沿并延伸出聚合物层(136)。第二极耳(134、234、334、434、534、 634、734、834、934)对应第一极耳( 133、233、333、433、533、633、733、833、933)设置于第二金属层(135、235、335、435、535、 635、735、835、935)的边沿并延伸出聚合物层(136)。第二极耳(134、234、334、434、534、 634、734、834、934)与第一极耳( 133、233、333、433、533、633、733、833、933)的延伸方向相同。活性物质层(137)设置于第一金属层( 132、232、332、432、532、 632、732、832、932)及第二金属层(135、235、335、435、535、 635、735、835、935)上,并覆盖位于第一金属层( 132、232、332、432、532、 632、732、832、932)的第一极耳( 133、233、333、433、533、633、733、833、933)及位于第二金属层(135、235、335、435、535、 635、735、835、935)的第二极耳(134、234、334、434、534、 634、734、834、934)。
Description
本申请涉及储能技术领域,尤其涉及一种电极极片及包括所述电极极片的电芯及电化学装置。
锂离子电池具有体积和质量能量密度大、循环寿命长、标称电压高、自放电率低、体积小、重量轻等许多优点,在消费电子领域具有广泛的应用。随着近年来电动汽车和可移动电子设备的高速发展,人们对锂离子电池的能量密度、安全性、循环性能等相关需求越来越高。
集流体作为锂离子电池中的一个重要部件,具有将锂离子电池活性物质产生的电流汇集起来以形成较大的电流对外输出的功能。复合集流体的使用可进一步提高能量密度、提高韧性和延展率从而实现生产中的工艺优化、以及提高单位质量能量密度并提高安全性。然而,复合集流体两侧的金属层被中间的聚合物层隔绝,无法导通,影响锂离子电池的性能。
发明内容
基于以上现有技术的不足,本申请提供一种能够方便导通复合集流体两侧的金属层的电极极片及包括所述电极极片的电芯及电化学装置。
本申请实施例提供一种电极极片,包括复合集流体、第一极耳、第二极耳及活性物质层。复合集流体包括第一金属层、第二金属层及夹设于第一金属层与第二金属层之间的聚合物 层。第一极耳设置于第一金属层的边沿并延伸出聚合物层。第二极耳对应第一极耳设置于第二金属层的边沿并延伸出聚合物层,第二极耳与第一极耳的延伸方向相同。活性物质层设置于第一金属层及第二金属层上,并覆盖位于第一金属层的第一极耳及位于第二金属层的第二极耳。
本申请实施方式提供的电极极片,能够通过焊接等方式导通第一极耳及第二极耳,就能实现位于复合集流体两侧的第一金属层及第二金属之间的导通。
一些实施例中,第一极耳及第二极耳均沿电极极片的长度方向间隔设置。通过设置沿电极极片的长度方向排列的多个第一极耳及第二极耳,可降低电极极片的阻抗。
一些实施例中,沿电极极片的厚度方向,第一极耳的投影与第二极耳的投影相重叠。通过使第一极耳及第二极耳在电极极片的厚度方向重叠设置,可简化加工工序。
一些实施例中,在电极极片的长度方向上,第一极耳沿电极极片的厚度方向的投影和第二极耳沿电极极片的厚度方向的投影依次交替设置。通过使第一极耳及第二极耳交替设置,可减小电极极片的整体厚度。
一些实施例中,相邻两个第一极耳之间的间距相等,相邻两个第二极耳之间的间距相等。
一些实施例中,相邻两个第一极耳之间的间距沿电极极片的长度方向递增或递减,相邻两个第二极耳之间的间距沿电极极片的长度方向对应递增或递减。
一些实施例中,在电极极片的长度方向上,电极极片包括依次连接的头部、中部及尾部,第一极耳设置于第一金属层的头部、中部及尾部中的至少一处,第二极耳对应第一极耳设置于第二金属层的头部、中部及尾部中的至少一处。
一些实施例中,电极极片还包括邻近头部设置的第一端面及邻近尾部设置的第二端面,当第一极耳及第二极耳均设置于第二金属层的头部或尾部时,在电极极片的长度方向上,第一极耳及第二极耳与第一端面或第二端面之间的距离小于电极极片的长度的1/5。
一些实施例中,聚合物层在电极极片的宽度方向上伸出第一金属层与第二金属层外,第一极耳及第二极耳背离聚合物层的一侧设置有绝缘片。通过设置绝缘片,可绝缘第一极耳及第二极耳,避免发生短路。
一些实施例中,第一极耳贴合于第一金属层的表面,第二极耳贴合于第二金属层的表面。
本申请实施方式还提供一种电芯,包括第一极片、第二极片和设置于第一极片与第二极片之间的隔离膜,第一极片和第二极片堆叠或卷绕形成电芯。第一极片为上述任一种电极极片。第一极耳与第二极耳电连接。通过将第一极耳及第二极耳电连接,可导通复合集流体的第一金属层及第二金属层。
在电芯的厚度方向上,第一极耳的投影与第二极耳的投影相重叠。
本申请实施方式还提供一种电化学装置,包括转接片及上述任一种电芯。第一极耳和第二极耳层叠设置形成多极耳结构,多极耳结构与转接片相连接。
为了更清楚地说明本申请实施方式或现有技术中的技术方案,下面将对实施方式或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本申请的一些实施方式,对于本领域普通技术人员来讲,在不付出创 造性劳动的前提下,还可以根据这些附图获得其他的附图。
图1为本申请第一实施方式提供的电化学装置的结构示意图。
图2为图1所示电化学装置的电芯的第一极片去掉活性物质层的俯视图。
图3为图2所示第一极片的侧视图
图4为图2所示第一极片的仰视图。
图5为本申请第二实施方式提供的第一极片的侧视图。
图6为本申请第三实施方式提供的第一极片的侧视图。
图7为本申请第四实施方式提供的第一极片的侧视图。
图8为本申请第五实施方式提供的第一极片的侧视图。
图9为本申请第六实施方式提供的第一极片的侧视图。
图10为本申请第七实施方式提供的第一极片的侧视图。
图11为本申请第八实施方式提供的第一极片的侧视图。
图12为本申请第九实施方式提供的第一极片的侧视图。
主要元件符号说明
电化学装置 100
电芯 10
转接片 30
第一极片 130、230、330、430、530、
630、730、830、930
第二极片 150
隔离膜 160
复合集流体 131
第一极耳 133、233、333、433、533、
633、733、833、933
第二极耳 134、234、334、434、534、
634、734、834、934
第一金属层 132、232、332、432、532、
632、732、832、932
第二金属层 135、235、335、435、535、
635、735、835、935
聚合物层 136
多极耳结构 17
涂覆区 1361
非涂覆区 1363
第一活性物质层 137
集流体 151
第二活性物质层 153
绝缘片 170
头部 481、781、881
中部 482、682、882、982
尾部 483、583、783、983
第一端面 491
第二端面 493
如下具体实施方式将结合上述附图进一步说明本申请。
下面将结合本申请实施方式中的附图,对本申请实施方式中的技术方案进行清楚、完整地描述,显然,所描述的实施方式仅是本申请的一部分实施方式,而不是全部的实施方式。基于本申请中的实施方式,本领域普通技术人员在没有付出创造性劳动前提下所获得的所有其他实施方式,都属于本申请保护的范围。
需要说明的是,当组件被称为“连接于”另一个组件,它可以直接在另一个组件上或者也可以存在居中的组件。当一个组 件被认为是“设置于”另一个组件,它可以是直接设置在另一个组件或者可能同时存在居中组件。除非另有定义,本文所使用的所有的技术和科学术语与属于本申请的技术领域的技术人员通常理解的含义相同。在本申请实施方式中使用的术语是仅仅出于描述特定实施方式的目的,而非旨在限制本申请。本文所使用的术语“及/或”包括一个或多个相关的所列项目的任意的和所有的组合。
请参阅图1,本申请第一实施方式提供的电化学装置100包括电芯10及转接片30。所述电芯10包括第一极片130、第二极片150和设置于所述第一极片130及所述第二极片150之间的隔离膜160。所述第一极片130和所述第二极片150卷绕或堆叠形成所述电芯10。所述第一极片130包括复合集流体131、第一极耳133及第二极耳134。所述第一极耳133及所述第二极耳134设置于所述复合集流体131相对的两表面并位于所述第一极片130的同一侧,所述第一极耳133与所述第二极耳134的延伸方向相同。所述第一极耳133和所述第二极耳134通过所述转接片30电连接,以导通所述复合集流体131相对的两表面。
所述复合集流体131包括第一金属层132、第二金属层135及夹设于所述第一金属层132与所述第二金属层135之间的聚合物层136。所述第一极耳133设置于所述第一金属层132的边沿并延伸出所述聚合物层136。所述第二极耳134设置于所述第二金属层135的边沿并延伸出所述聚合物层136。请一并参阅图2,在一实施方式中,所述第一极耳133设置于所述第一金属层132的沿所述第一极片130的长度方向L的边沿并自第一极片130的宽度方向W延伸出所述聚合物层136;所述第二极耳134设置于所述第二金属层135的沿所述第一极片130 的长度方向L的边沿并自宽度方向W延伸出所述聚合物层136。本申请中,所述第一极片130的长度方向L指的是所述第一极片130的延伸方向,即为电芯10卷绕的方向;所述第一极片10的宽度方向W指的是极耳的延伸方向,且大致垂直所述长度方向L。
所述第一极耳133和所述第二极耳134层叠设置形成多极耳结构17,所述多极耳结构17与所述转接片30相连接,以导通所述第一金属层132及所述第二金属层135。具体的,图1中的电芯10示出两层第一极片130进行示意,位于其中一层第一极片130上的第二极耳134朝向位于另一层第一极片130上的第一极耳133弯折延伸后,与所述第一极耳133层叠设置形成所述多极耳结构17。
所述聚合物层136的材质选自聚对苯二甲酸亚乙酯、聚对苯二甲酸丁二醇酯、聚萘二甲酸乙二醇酯、聚醚醚酮、聚酰亚胺、聚酰胺、聚乙二醇、聚酰胺酰亚胺、聚碳酸酯、环状聚烯烃、聚苯硫醚、聚乙酸乙烯酯、聚四氟乙烯,聚亚甲基萘、聚偏二氟乙烯,聚萘二甲酸亚乙酯、聚碳酸亚丙酯、聚偏二氟乙烯-六氟丙烯、聚(偏二氟乙烯-共-三氟氯乙烯)、有机硅、维尼纶、聚丙烯、聚乙烯、聚氯乙烯、聚苯乙烯、聚醚腈、聚氨酯、聚苯醚、聚酯以及聚砜及其衍生物中的至少一种。
所述第一金属层132及所述第二金属层135均可通过溅射法、真空沉积法、离子电镀法、激光脉冲沉积法等方法形成。由于制备时仅需对所述聚合物层136进行裁剪,能够避免传统集流体在裁切时产生的金属毛刺,改善单位时间内电池的电压降(K值),提高电池安全性能。所述第一金属层132及所述第二金属层135的材质均可选自Ni、Ti、Cu、Ag、Au、Pt、Fe、Co、Cr、W、Mo、Al、Mg、K、Na、Ca、Sr、Ba、Si、Ge、 Sb、Pb、In、Zn及其组合物(合金)中的至少一种。可选的,所述第一金属层132以及所述第二金属层135的材质可以相同,也可以不同。
所述第一极耳133及所述第二极耳134均为金属片,其材质可选自Ni、Ti、Cu、Ag、Au、Pt、Fe、Co、Cr、W、Mo、Al、Mg、K、Na、Ca、Sr、Ba、Si、Ge、Sb、Pb、In、Zn及其组合物(合金)中的至少一种。
沿所述电芯10的厚度方向H,所述第一极耳133的投影与所述第二极耳134的投影相重叠。换句话说,在所述电芯10的厚度方向H上,所述第一极耳133和所述第二极耳134重叠在一起,使得所述第一极耳133和所述第二极耳134的连接更为方便。本申请中,所述电芯10的厚度方向H指的是所述电芯10中极片绕卷后形成的各层叠结构堆叠的方向或所述电芯10中极片堆叠的方向。
可选的,所述聚合物层136在所述第一极片10的宽度方向W上延伸出所述第一金属层132及所述第二金属层135。所述聚合物层136包括涂覆区1361及与所述涂覆区1361相连接的非涂覆区1363。所述涂覆区1361用于设置所述第一金属层132及所述第二金属层135。所述第一极耳133及所述第二极耳134分别贴合于所述第一金属层132及所述第二金属层135背离所述聚合物层136的表面并延伸覆盖所述非涂覆区1363后延伸出所述聚合物层136。请再次参阅图1,所述第一极片130还包括第一活性物质层137。所述第一活性物质层137设置于所述第一金属层132及所述第二金属层135上,并覆盖位于所述涂覆区1361上的第一极耳133及第二极耳134。在所述第一极片10的宽度方向W上,所述涂覆区1361、所述第一金属层132、所述第二金属层135及所述第一活性物质层137相互平 齐。
在所述电芯10的厚度方向H上,所述第一极片130设置有极耳的一侧的边沿的厚度为所述聚合物层136、所述第一极耳133及所述第二极耳134的厚度和,其未包括所述第一金属层132及所述第二金属层135的厚度,减小了所述第一极片130边沿的厚度,即可减小所述电芯10在所述厚度方向H上所占空间,进而提高所述电化学装置100的能量密度。在所述第一极片10的宽度方向W上,所述第一极耳133及所述第二极耳134部分嵌入所述第一活性物质层137中,可减小所述电芯10在所述宽度方向W上所占空间,进一步提高所述电化学装置100的能量密度。
本实施方式中,所述第一极片130为阴极极片,所述第二极片150为阳极极片。所述第二极片150包括集流体151及涂覆于所述集流体151相对两表面的第二活性物质层153。所述集流体151为金属箔片。在所述第一极片10的宽度方向W上,所述集流体151与所述第二活性物质层153相平齐,且所述第二活性物质层153超出所述第一活性物质层137。所述电芯10还包括绝缘片170。所述绝缘片170设置于所述第一极耳133以及所述第二极耳134背离所述聚合物层136的一侧,并覆盖位于所述非涂覆区1363的第一极耳133与第二极耳134,用于绝缘所述第一极耳133及所述第二极耳134。
请参阅图2-4,所述第一极耳133设置于所述第一金属层132的边沿,并沿所述第一极片130的长度方向L间隔排列。所述第二极耳134设置于所述第二金属层135的边沿,并沿所述第一极片130的长度方向L间隔排列。在所述第一极片130的长度方向L上,所述第一极耳133沿所述第一极片130的厚度方向H的投影和所述第二极耳134沿所述第一极片130的厚 度方向H的投影依次交替设置。本申请中,所述第一极片130的厚度方向H指的是所述第一极片130中的层叠结构的堆积方向,可以理解的是,所述第一极片130的厚度方向H与所述电芯10的厚度方向H相一致。相邻两个第一极耳133之间的间距沿长度方向L递增,相邻两个第二极耳134之间的间距沿长度方向L对应递增。将所述第一极片130卷绕形成所述电芯10后,所述第一极耳133在厚度方向H上的投影与所述第二极耳134在厚度方向H上的投影相重叠。图示中,长度方向L自左向右延伸,可以理解的是,当长度方向L标为自右向左延伸时,相邻两个第一极耳133之间的间距沿长度方向L递减,相邻两个第二极耳134之间的间距沿长度方向L对应递减。
请参阅图5,本申请第二实施方式提供的电化学装置与第一实施方式提供的电化学装置大致相同,其不同在于第一极耳233及第二极耳234在第一极片230上的设置方式。具体的,所述第一极耳233设置于所述第一金属层232的边沿并沿长度方向L间隔排列,所述第二极耳234对应所述第一极耳233设置于所述第二金属层235的边沿并沿长度方向L间隔排列;在长度方向L上,所述第一极耳233沿厚度方向H的投影和所述第二极耳234沿所述第一极片130的厚度方向H的投影相重叠。相邻两个第一极耳233之间的间距沿长度方向L递增,相邻两个第二极耳234之间的间距沿长度方向L对应递增。相较实施方式一,本实施方式通过增设第一极耳233及第二极耳234,使所述第一极耳233和所述第二极耳234的位置在第一极片230的厚度方向H上相对应,可降低所述电化学装置的阻抗。
请参阅图6,本申请第三实施方式提供的电化学装置与第二实施方式提供的电化学装置大致相同,其不同在于第一极耳 333及第二极耳334在第一极片330上的排列方式。具体的,所述第一极耳333设置于所述第一金属层332的边沿并沿长度方向L间隔排列,所述第二极耳334对应所述第一极耳333设置于所述第二金属层335的边沿并沿长度方向L间隔排列;在长度方向L上,所述第一极耳333沿厚度方向H的投影和所述第二极耳334沿所述第一极片130的厚度方向H的投影相重叠。相邻两个第一极耳333之间的间距相等,相邻两个第二极耳334之间的间距相等。相较实施方式二,本实施方式中的第一极片330堆叠形成所述电芯。
请参阅图7,本申请第四实施方式提供的电化学装置与第一实施方式提供的电化学装置大致相同,其不同在于第一极耳433及第二极耳434在第一极片430上的设置位置。具体的,在长度方向L上,所述第一极片430包括依次连接的头部481、中部482及尾部483,所述第一极耳433设置于第一金属层432的头部481,所述第二极耳434对应所述第一极耳433于第二金属层435的头部481。所述第一极片430还包括相对设置的第一端面491及第二端面493,所述第一端面491为第一极片430在长度方向L上的起始端,所述第二端面493为所述第一极片430在长度方向L上的收尾端。本申请中,所述第一极片430的头部邻近所述第一端面491设置,所述第一极片430的尾部邻近所述第二端面493设置,所述第一极片430的中部邻近所述第一极片430的中心设置。例如,将所述第一极片430从第一端面491至第二端面493平均分为第一段、第二段及第三段,邻近第一端面491的第一段为头部,邻近第二端面493的第三段为尾部,第二段为中部。可选的,在长度方向L上,所述第一极耳433及所述第二极耳434与所述第一端面491之间的距离小于所述第一极片430的长度的1/5。本实施方式的 第一极片430可堆叠或卷绕形成所述电芯。
请参阅图8,本申请第五实施方式提供的电化学装置与第四实施方式提供的电化学装置大致相同,其不同在于第一极耳533及第二极耳534在第一极片530上的设置位置。具体的,所述第一极耳533设置于第一金属层532的尾部583,所述第二极耳534对应所述第一极耳533设置于第二金属层535的尾部583。可选的,在长度方向L上,所述第一极耳533及所述第二极耳534与所述第一端面493之间的距离小于所述第一极片530的长度的1/5。
请参阅图9,本申请第六实施方式提供的电化学装置与第四实施方式提供的电化学装置大致相同,其不同在于第一极耳633及第二极耳634在第一极片630上的设置位置。具体的,所述第一极耳633设置于第一金属层632的中部682,所述第二极耳634对应所述第一极耳633设置于第二金属层635的中部682。
请参阅图10,本申请第七实施方式提供的电化学装置与第四实施方式提供的电化学装置大致相同,其不同在于第一极耳733及第二极耳734在第一极片730上的设置位置。具体的,所述第一极耳733设置于第一金属层732的头部781及尾部783,所述第二极耳734对应所述第一极耳733设置于第二金属层735的的头部781及尾部783。
请参阅图11,本申请第八实施方式提供的电化学装置与第四实施方式提供的电化学装置大致相同,其不同在于第一极耳833及第二极耳834在第一极片830上的设置位置。具体的,所述第一极耳833设置于第一金属层832的头部881和中部882,所述第二极耳834对应所述第一极耳833设置于第二金属层835的头部881和中部882。
请参阅图11,本申请第九实施方式提供的电化学装置与第四实施方式提供的电化学装置大致相同,其不同在于第一极耳933及第二极耳934在第一极片930上的设置位置。具体的,所述第一极耳933设置于第一金属层932的尾部983和中部981,所述第二极耳934对应所述第一极耳933设置于第二金属层935的尾部983和中部982。
以上所揭露的仅为本申请较佳实施方式而已,当然不能以此来限定本申请,因此依本申请所作的等同变化,仍属本申请所涵盖的范围。
Claims (13)
- 一种电极极片,其特征在于,包括:复合集流体,包括第一金属层、第二金属层及夹设于所述第一金属层与所述第二金属层之间的聚合物层;第一极耳,设置于所述第一金属层的边沿并延伸出所述聚合物层;第二极耳,对应所述第一极耳设置于所述第二金属层的边沿并延伸出所述聚合物层,所述第二极耳与所述第一极耳的延伸方向相同;以及活性物质层,设置于所述第一金属层及所述第二金属层上,并覆盖位于所述第一金属层的第一极耳及位于所述第二金属层的第二极耳。
- 如权利要求1所述的电极极片,其特征在于,所述第一极耳及所述第二极耳均沿所述电极极片的长度方向间隔设置。
- 如权利要求2所述的电极极片,其特征在于,沿所述电极极片的厚度方向,所述第一极耳的投影与所述第二极耳的投影相重叠。
- 如权利要求2所述的电极极片,其特征在于,在所述电极极片的长度方向上,所述第一极耳沿所述电极极片的厚度方向的投影和所述第二极耳沿所述电极极片的厚度方向的投影依次交替设置。
- 如权利要求3或4所述的电极极片,其特征在于,相邻两个第一极耳之间的间距相等,相邻两个第二极耳之间的间距相等。
- 如权利要求3或4所述的电极极片,其特征在于,相邻两个第一极耳之间的间距沿所述电极极片的长度方向递增或递减,相邻两个第二极耳之间的间距沿所述电极极片的长度方 向对应递增或递减。
- 如权利要求1所述的电极极片,其特征在于,在所述电极极片的长度方向上,所述电极极片包括依次连接的头部、中部及尾部,所述第一极耳设置于所述第一金属层的头部、中部及尾部中的至少一处,所述第二极耳对应所述第一极耳设置于所述第二金属层的头部、中部及尾部中的至少一处。
- 如权利要求7所述的电极极片,其特征在于,所述电极极片还包括邻近所述头部设置的第一端面及邻近所述尾部设置的第二端面,当所述第一极耳及所述第二极耳均设置于所述第二金属层的头部或尾部时,在所述电极极片的长度方向上,所述第一极耳及所述第二极耳与所述第一端面或所述第二端面之间的距离小于所述电极极片的长度的1/5。
- 如权利要求1所述的电极极片,其特征在于,所述聚合物层在所述电极极片的宽度方向上伸出所述第一金属层与所述第二金属层外,所述第一极耳及所述第二极耳背离所述聚合物层的一侧设置有绝缘片。
- 如权利要求1所述的电极极片,其特征在于,所述第一极耳贴合于所述第一金属层的表面,所述第二极耳贴合于所述第二金属层的表面。
- 一种电芯,包括第一极片、第二极片和设置于所述第一极片与所述第二极片之间的隔离膜,所述第一极片和所述第二极片堆叠或卷绕形成所述电芯,其特征在于:所述第一极片为权利要求1-10中任一项所述的电极极片,所述第一极耳与所述第二极耳电连接。
- 如权利要求11所述的电芯,其特征在于,在所述电芯的厚度方向上,所述第一极耳的投影与所述第二极耳的投影相重叠。
- 一种电化学装置,其特征在于,所述电化学装置包括转接片及权力要求11-12中任一项所述的电芯,所述第一极耳和所述第二极耳层叠设置形成多极耳结构,所述多极耳结构与所述转接片相连接。
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