WO2021082423A1 - 一种直流耦合制氢***及其控制方法 - Google Patents
一种直流耦合制氢***及其控制方法 Download PDFInfo
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- WO2021082423A1 WO2021082423A1 PCT/CN2020/093091 CN2020093091W WO2021082423A1 WO 2021082423 A1 WO2021082423 A1 WO 2021082423A1 CN 2020093091 W CN2020093091 W CN 2020093091W WO 2021082423 A1 WO2021082423 A1 WO 2021082423A1
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- hydrogen production
- preset threshold
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- new energy
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 184
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 184
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 183
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 175
- 238000000034 method Methods 0.000 title claims abstract description 34
- 230000008878 coupling Effects 0.000 title abstract description 6
- 238000010168 coupling process Methods 0.000 title abstract description 6
- 238000005859 coupling reaction Methods 0.000 title abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 30
- 238000004891 communication Methods 0.000 claims description 25
- 238000005868 electrolysis reaction Methods 0.000 claims description 16
- 238000010248 power generation Methods 0.000 claims description 16
- 230000002457 bidirectional effect Effects 0.000 claims description 12
- SJWPTBFNZAZFSH-UHFFFAOYSA-N pmpp Chemical compound C1CCSC2=NC=NC3=C2N=CN3CCCN2C(=O)N(C)C(=O)C1=C2 SJWPTBFNZAZFSH-UHFFFAOYSA-N 0.000 claims description 12
- 239000012670 alkaline solution Substances 0.000 claims description 9
- 239000003792 electrolyte Substances 0.000 claims description 9
- 230000005611 electricity Effects 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 3
- 238000004146 energy storage Methods 0.000 abstract description 12
- 239000000243 solution Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000011217 control strategy Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000006698 induction Effects 0.000 description 2
- 230000001360 synchronised effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J3/00—Circuit arrangements for ac mains or ac distribution networks
- H02J3/38—Arrangements for parallely feeding a single network by two or more generators, converters or transformers
- H02J3/381—Dispersed generators
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/50—Processes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/50—Processes
- C25B1/55—Photoelectrolysis
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/02—Process control or regulation
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06Q—INFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES; SYSTEMS OR METHODS SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES, NOT OTHERWISE PROVIDED FOR
- G06Q50/00—Information and communication technology [ICT] specially adapted for implementation of business processes of specific business sectors, e.g. utilities or tourism
- G06Q50/06—Energy or water supply
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J15/00—Systems for storing electric energy
- H02J15/008—Systems for storing electric energy using hydrogen as energy vector
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J3/00—Circuit arrangements for ac mains or ac distribution networks
- H02J3/28—Arrangements for balancing of the load in a network by storage of energy
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J2300/00—Systems for supplying or distributing electric power characterised by decentralized, dispersed, or local generation
- H02J2300/20—The dispersed energy generation being of renewable origin
- H02J2300/22—The renewable source being solar energy
- H02J2300/24—The renewable source being solar energy of photovoltaic origin
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J2300/00—Systems for supplying or distributing electric power characterised by decentralized, dispersed, or local generation
- H02J2300/20—The dispersed energy generation being of renewable origin
- H02J2300/22—The renewable source being solar energy
- H02J2300/24—The renewable source being solar energy of photovoltaic origin
- H02J2300/26—The renewable source being solar energy of photovoltaic origin involving maximum power point tracking control for photovoltaic sources
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J2300/00—Systems for supplying or distributing electric power characterised by decentralized, dispersed, or local generation
- H02J2300/20—The dispersed energy generation being of renewable origin
- H02J2300/28—The renewable source being wind energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/56—Power conversion systems, e.g. maximum power point trackers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E70/00—Other energy conversion or management systems reducing GHG emissions
- Y02E70/30—Systems combining energy storage with energy generation of non-fossil origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
Definitions
- the invention relates to the technical field of automatic control, in particular to a direct current coupling hydrogen production system and a control method thereof.
- Figure 1 shows a typical DC-coupled off-grid hydrogen production system; the DC power generated by the PV system is output to multiple hydrogen production tank systems through the DC/DC converter (or the AC power generated by the fan system through the AC/DC converter).
- the electrolytic cell in each hydrogen production tank system replaces the hydrogen in the water, and then the obtained hydrogen and oxygen are transported to the hydrogen storage/oxygen system.
- the hydrogen production tank system mostly uses lye electrolyzers to electrolyze hydrogen, but lye electrolyzers have minimum current/voltage restrictions, and the power of new energy sources is fluctuating. If the restrictions cannot be met, the As a result, the purity of the gas produced by the lye electrolyzer is low, the shutdown is active, and even safety hazards are caused.
- battery energy storage is introduced in order to maximize the use of new energy power while overcoming the minimum current/voltage limit requirements of the lye electrolyzer, the cost will not be negligible, resulting in poor system economy.
- the present invention provides a DC-coupled hydrogen production system and a control method thereof to solve the problem of poor system economy caused by the introduction of battery energy storage in the prior art.
- the first aspect of the present invention provides a DC-coupled hydrogen production system, including: a new energy system, a first converter, a hydrogen production tank system, a second converter, a conversion device, and a communication unit; wherein:
- the new energy system is connected to the hydrogen production tank system through the first converter, and the new energy system is connected to the grid through the second converter and the conversion device in turn;
- the communication unit is respectively communicatively connected with the first converter, the second converter and the hydrogen production tank system;
- the first converter is used to provide hydrogen production electrical energy to the hydrogen production tank system when the output electrical energy of the new energy system is greater than a preset threshold;
- the second converter is used for grid-connected output through the converter when the output electric energy of the new energy system is less than or equal to the preset threshold.
- the hydrogen production tank of the hydrogen production tank system is any one of an alkaline solution electrolysis tank, a PEM electrolysis tank and a solid oxide electrolysis tank;
- the preset threshold value is the minimum power requirement value of the alkaline solution electrolysis tank.
- the second converter is a bidirectional converter
- the conversion device is a bidirectional converter
- the electric energy output branch of the new energy system is further provided with a controllable switch
- the controllable switch is used to open when the output electric energy of the new energy system is less than or equal to the start-up threshold and the current moment is in the grid price stage, and to close at other times;
- the second converter is further configured to receive the grid power through the conversion device for reverse conversion when the output power of the new energy system is less than or equal to the start-up threshold and the current time is in the grid price stage;
- the first converter is also used to receive the electric energy from the second converter when the output electric energy of the new energy system is less than or equal to the start-up threshold and the current time is in the grid price stage, and to produce hydrogen to the The tank system provides electricity for hydrogen production.
- the first converter and the second converter adopt master-slave control; or,
- the DC-coupled hydrogen production system further includes: a system controller connected to the communication unit for realizing centralized control of the DC-coupled hydrogen production system.
- the communication unit is installed independently, or integrated in any one of the first converter and the second converter.
- the first converter is a DC/DC converter
- the second converter is a DC/AC converter or a DC/DC converter connected in series and a DC /AC converter
- the first converter is an AC/DC converter or an AC/DC converter and a DC/DC converter connected in series
- the second converter is an AC/AC converter Device.
- Control methods include:
- the second converter is controlled to be in a standby state, and the first converter provides a system to the hydrogen production tank system in the DC-coupled hydrogen production system. Hydrogen power
- the first converter is maintained in a standby state, and the second converter is connected to the grid through a conversion device.
- performing MPPT calculation and judging whether the output electric energy of the new energy system in the DC-coupled hydrogen production system is greater than a preset threshold according to the calculation information obtained by the calculation includes:
- the preset threshold value includes: a first preset threshold value and a second preset threshold value, and the first preset threshold value is greater than or equal to the second preset threshold value;
- Determining whether the power value of the maximum power point is greater than the preset threshold value includes:
- the power value of the maximum power point rises to be greater than the first preset threshold value, and does not fall below the second preset threshold value, then it is determined that the power value of the maximum power point is greater than the preset threshold value .
- the preset threshold value is the minimum power requirement value of the lye electrolyzer, which is equal to the minimum current of the lye electrolyzer
- the product of the required value and the minimum voltage required value, and in the control method of the DC-coupled hydrogen production system, determining whether the power value of the maximum power point is greater than the preset threshold includes:
- the formula used to calculate the theoretical value of the hydrogen production current of the lye electrolyzer according to the power value of the maximum power point includes:
- Uin is the theoretical value of the hydrogen production voltage of the lye electrolyzer
- Iin is the theoretical value of the hydrogen production current of the lye electrolyzer
- U_limit is the minimum voltage required value of the lye electrolyzer
- Pmpp is the The power value at the maximum power point
- Req is the equivalent resistance of the alkaline electrolyte electrolyzer.
- the control method of the DC coupling hydrogen production system controls the first converter in the DC coupling hydrogen production system to be in standby Before the second converter performs grid-connected output through the conversion device, it also includes:
- control method of the DC-coupled hydrogen production system further includes:
- the controllable switch is controlled to be turned off, and the second converter receives grid power through the conversion device.
- the first converter receives electric energy from the second converter and provides hydrogen production electric energy to the hydrogen production tank system.
- the first converter provides hydrogen production power to the hydrogen production tank system only when the output power of the new energy system is greater than the preset threshold; while the output power of the new energy system is less than or equal to
- the second converter is used for grid-connected output through the conversion device; therefore, even if the hydrogen production tank of the hydrogen production tank system is an alkaline electrolyte electrolyzer, the above principles can also take into account the maximum utilization of new energy power. , And the minimum current/voltage limit requirements of the lye electrolyzer, and there is no need to introduce battery energy storage, which avoids the problem of poor economy caused by the installation of battery energy storage.
- Figure 1 is a schematic structural diagram of a DC-coupled off-grid hydrogen production system provided by the prior art
- Figure 2 is a schematic structural diagram of a DC-coupled hydrogen production system provided by an embodiment of the present invention
- Figure 3a is a schematic structural diagram of a DC-coupled photovoltaic hydrogen production system provided by an embodiment of the present invention
- Figure 3b is a schematic structural diagram of a DC-coupled wind power hydrogen production system provided by an embodiment of the present invention.
- FIG. 4 is a flowchart of a method for controlling a DC-coupled hydrogen production system according to an embodiment of the present invention
- Fig. 5 is a partial flowchart of a control method of a DC-coupled hydrogen production system provided by an embodiment of the present application.
- the invention provides a direct current coupling hydrogen production system to solve the problem of poor system economy caused by the introduction of battery energy storage in the prior art.
- the DC-coupled hydrogen production system includes: a new energy system 101, a first converter 102, a hydrogen production tank system 104, a second converter 103, a conversion device 105, and a communication unit 106; among them:
- the new energy system 101 is connected to the hydrogen production tank system 104 through the first converter 102, and the new energy system 101 is connected to the grid through the second converter 103 and the conversion device 105 in turn.
- the new energy system 101 can be a photovoltaic power generation system (as shown in Figure 3a) or a wind power generation system (as shown in Figure 3b).
- the photovoltaic power generation system includes at least one photovoltaic string; each photovoltaic string is connected in parallel, and the two ends of the parallel connected are used as the output terminals of the new energy system 101.
- the photovoltaic string can be composed of photovoltaic modules of various power levels currently on the market, and can form a photovoltaic 1000V system, or a 1500V system, or even a photovoltaic system with a higher voltage level; there is no specific limitation here, depending on the application environment However, they are all within the scope of protection of this application.
- the new energy system 101 is a photovoltaic power generation system, as shown in FIG.
- the first converter 102 is a DC/DC converter
- the second converter 103 is a DC/AC converter or a series-connected DC/DC converter and DC/AC converter;
- the DC/DC converter can be an isolated topology, or a non-isolated topology, a boost topology, a buck topology, or a boost/buck topology, It can be a resonant topology or a non-resonant topology. It can be a full-bridge structure or a half-bridge structure. It can be a two-level topology or a three-level topology; there are no specific restrictions here, depending on its application environment. Are all within the scope of protection of this application.
- the DC/AC converter in the second converter 103 can be a two-level topology, a three-level topology, an isolated topology, or a non-isolated topology; there is no specific limitation here, depending on its application environment , Are all within the protection scope of this application.
- Wind power generation system including: wind turbine, and, DFIG (Doubly fed Induction Generator, double-fed induction motor) or PMSG (permanent magnet synchronous generator, permanent magnet synchronous generator); wind turbine through DFIG or PMSG for electrical output, DFIG or PMSG
- the output terminal serves as the output terminal of the new energy system 101.
- the first converter 102 is an AC/DC converter or an AC/DC converter and a DC/DC converter connected in series
- the second converter 103 is AC/AC converter.
- the AC/DC converter is an isolated topology, a boost topology, a buck topology, a boost/buck topology, a two-level topology, a three-level topology, or a full bridge
- the topology may also be a half-bridge topology; there is no specific limitation here, depending on its application environment, and all are within the protection scope of this application.
- the conversion device 105 may be a solid-state power electronic transformer or a box-type transformer; the power grid to which the conversion device 105 is connected is a high-voltage power grid, and the high-voltage power grid may be a power grid with a voltage level of 16KV or a power grid with a voltage level of 35KV; There is no specific limitation here, and it depends on the application environment, and all are within the protection scope of this application.
- the communication unit 106 is respectively connected to the first converter 102, the second converter 103 and the hydrogen production tank system 104; the communication connection can be wired or wireless according to the actual application environment. All restrictions are within the scope of protection of this application.
- the communication unit 106 can be set independently, or it can be integrated in any one of the first converter 102 and the second converter 103, depending on its application environment, and both are within the protection scope of the present application.
- the DC-coupled hydrogen production system can be neutralized by the first converter 102 and the second converter 103, and master-slave control can be achieved through the communication unit 106; or, the DC-coupled hydrogen production system can also be connected to the communication unit 106 by setting
- the system controller of the system controller comes through the communication unit 106 to achieve centralized control; it depends on its application environment, and they are all within the protection scope of this application.
- the hydrogen production tank system 104 includes a hydrogen production tank and a control cabinet; the control cabinet is responsible for monitoring the tank pressure, tank temperature, hydrogen/oxygen level, etc. of the hydrogen production tank, generating corresponding voltage/current commands, and communicating
- the unit 106 directly or indirectly transmits to the second converter 103, so that the second converter 103 can output electric energy according to the voltage/current command.
- the hydrogen production tank can be any one of an alkaline solution electrolysis tank, a PEM electrolysis tank and a solid oxide electrolysis tank; there is no specific limitation here, and it depends on its specific application environment, and they are all within the scope of protection of this application. Inside.
- the DC-coupled hydrogen production system combines the energy volatility of the new energy system 101 and the minimum current/voltage limit requirements of the lye electrolyzer gas production. Two working modes can be realized through corresponding control: one is when the new energy system 101 The output electric energy is less than or equal to the preset threshold.
- the DC-coupled hydrogen production system switches out of the hydrogen production mode and switches to the grid-connected mode, that is, the second converter 103 is combined by the converter 105 Grid output, the energy of the new energy system 101 is delivered to the grid;
- the DC-coupled hydrogen production system is cut out and connected to the grid Mode, switch to the hydrogen production mode, that is, the first converter 102 provides hydrogen production electric energy to the hydrogen production tank system 104.
- the preset threshold refers to the minimum power requirement value of the lye electrolyzer.
- the specific control strategy for the DC-coupled hydrogen production system to achieve the above principles is: after startup, the second converter 103 starts to work first and enters the grid connection.
- the second converter 103 switches out of grid-connected mode and enters standby mode.
- the first converter 102 starts to work, enters the hydrogen production mode, and outputs the energy of the new energy system 101 to the lye electrolyzer for hydrogen production;
- Iin ⁇ I_limit the first converter 102 remains in the standby state, and the second The converter 103 still works in the grid-connected mode.
- the minimum current required value I_limit for the gas produced by the lye electrolyzer is determined according to the actual lye electrolyzer system. It can be 30% of the rated current or 50% of the rated current; there is no specific limit here, depending on its application Depending on the environment, all are within the protection scope of this application.
- the switching principle of the above-mentioned grid-connected/off-grid mode can be based on the same comparison threshold, such as the minimum current requirement I_limit for gas production in the lye electrolyzer; in practical applications, the hysteresis control strategy can also be adopted.
- a higher comparison threshold is used, and when the current/power decreases, a lower comparison threshold is used.
- the switching principle is the same as the above. No more detailed description here.
- the first converter 102 provides hydrogen production power to the hydrogen production tank system 104 only when the output power of the new energy system 101 is greater than the preset threshold; while in the new energy system
- the second converter 103 is connected to the grid through the converter 105; therefore, even if the hydrogen production tank of the hydrogen production tank system 104 is an alkaline electrolysis tank, it can pass through the above
- the principle of on-grid/off-grid mode switching takes into account the maximum utilization of new energy power, as well as the minimum current/voltage limit requirements of the lye electrolyzer, and there is no need to introduce battery energy storage, which avoids the setting of battery energy storage. The problem of poor economy.
- the DC-coupled hydrogen production system has simple structure, simple control, reliable operation, and easy implementation of the scheme.
- the new energy system 101 when it is a photovoltaic power generation system, the photovoltaic modules have no energy output at night, and when it is a wind power generation system, the wind farm will also have a period of no wind. In both cases, considering the actual demand for hydrogen production, the grid electricity can be used to produce hydrogen.
- the DC-coupled hydrogen production system is based on the previous embodiment, and its second converter 103 is a bidirectional converter.
- the conversion device 105 selects the bidirectional conversion device 105, and the electric energy output branch of the new energy system 101 is also provided with a controllable switch (as shown by K in Fig. 2 to Fig. 3b); the controllable switch may be a circuit breaker, It may also be a switch device such as a contactor; there is no specific limitation here, and it depends on its application environment, and they are all within the protection scope of this application.
- the communication host or system controller issues the valley electricity hydrogen production command through the communication unit 106 to cut off the controllable switch on the new energy system 101 side to prevent the grid side Energy is poured back into the new energy system 101, damaging photovoltaic modules and other devices; and the communication host or system controller also issues the received voltage/current command of the alkaline electrolyte electrolyzer to the first converter 102 through the communication unit 106, and the second conversion
- the converter 103 works to rectify and output the grid-side energy; the first converter 102 performs corresponding output according to the received voltage/current command to realize hydrogen production from valley electricity.
- the second converter 103 is also used to receive the grid electric energy through the conversion device 105 for reverse conversion; the first converter 102 It is also used to receive the electrical energy of the second converter 103 and provide hydrogen production electrical energy to the hydrogen production tank system 104.
- the controllable switch can be turned off when the output power of the new energy system 101 is less than or equal to the start-up threshold and the current time is in the grid price stage; and in order to achieve the normal operation of the system, the controllable switch can be turned off at other times It should be in a closed state, which requires that after the system is started, the communication host or system controller first issues a new energy discharge command through the communication unit 106, and closes the controllable switch on the side of the new energy system 101 so that the energy on the new energy side can be used. Output to the first inverter 102 or the second inverter 103.
- This embodiment can not only take into account the maximum utilization of new energy power and the minimum current/voltage limit requirements of the lye electrolyzer, but also the photovoltaic power generation system can also achieve hydrogen production from valley electricity at night, which is also useful for wind power generation systems. It can realize the hydrogen production from valley electricity during the windless period, thereby realizing the economic efficiency of hydrogen production.
- Another embodiment of the present invention also provides a control method of a DC-coupled hydrogen production system, which is applied to the communication host or system controller in the DC-coupled hydrogen production system described in any of the above embodiments; as shown in FIG. 4 ,
- the control method of the DC-coupled hydrogen production system includes:
- step S102 includes:
- S201 Perform an MPPT operation to determine the power value of the maximum power point.
- S202 Determine whether the power value of the maximum power point is greater than a preset threshold.
- Step S202 includes:
- U_limit is the minimum voltage required value of the lye electrolyzer
- Pmpp is the power value at the maximum power point
- Req is the equivalent resistance of the lye electrolyzer.
- the minimum current required value of the lye electrolyzer can be determined according to the actual lye electrolyzer. It can be 30% of its rated current, 50% of its rated current, or other ratios of rated current. Here It is not limited, and they are all within the protection scope of this application.
- the power value of the maximum power point is greater than the preset threshold value. If the theoretical value of the hydrogen production current is less than or equal to the minimum current requirement value of the lye electrolyzer, it is determined that the power value of the maximum power point is less than or equal to the preset threshold.
- step S202 includes: determining whether the power value of the maximum power point rises to greater than the first preset threshold, and does not fall below the second preset threshold; if the power value of the maximum power point rises When it is greater than the first preset threshold and does not fall below the second preset threshold, it is determined that the power value of the maximum power point is greater than the preset threshold.
- the minimum current requirement may mean that the theoretical value of the hydrogen production current rises to greater than the first current threshold, and , Before falling to less than or equal to the second current threshold; the first current threshold is greater than or equal to the second current threshold, and the second current threshold is greater than or equal to the minimum current requirement value.
- step S103 If the power value of the maximum power point is greater than the preset threshold, it is determined that the output power of the new energy system is greater than the preset threshold, and step S103 is executed; if the power value of the maximum power point is less than or equal to the preset threshold, the output power of the new energy system is determined If it is less than or equal to the preset threshold, step S104 is executed.
- the above process can realize the switch of grid-connected/off-grid mode, to take into account the maximum utilization of new energy power, and the minimum current/voltage limit requirements of the lye electrolyzer, and there is no need to introduce battery energy storage, avoiding the need to install batteries. Poor economy caused by energy storage.
- the DC-coupled hydrogen production system has simple structure, simple control, reliable operation, and easy implementation of the scheme.
- control method of the DC-coupled hydrogen production system as shown in FIG. 4, before step S101, further includes:
- the control method of the DC-coupled hydrogen production system further includes as shown in Fig. 5:
- S401 Determine whether the output electric energy of the new energy system is less than or equal to the start-up threshold and whether it is in the grid price stage at the current moment;
- step S402 is executed.
- the controllable switch is controlled to be turned off, the second converter receives the grid electric energy through the conversion device for reverse conversion, and the first converter receives the electric energy of the second converter and provides hydrogen production electric energy to the hydrogen production tank system.
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Abstract
Description
Claims (13)
- 一种直流耦合制氢***,其特征在于,包括:新能源***、第一变换器、制氢槽***、第二变换器、变换装置以及通信单元;其中:所述新能源***通过所述第一变换器连接所述制氢槽***,且所述新能源***依次通过所述第二变换器和所述变换装置连接电网;所述通信单元分别与所述第一变换器、所述第二变换器和所述制氢槽***通信连接;所述第一变换器用于在所述新能源***的输出电能大于预设阈值时,向所述制氢槽***提供制氢电能;所述第二变换器用于在所述新能源***的输出电能小于等于所述预设阈值时,通过所述变换装置进行并网输出。
- 根据权利要求1所述的直流耦合制氢***,其特征在于,所述制氢槽***的制氢槽为:碱液电解槽、PEM电解槽及固体氧化物电解槽中的任意一种;并且,所述制氢槽***中的制氢槽为碱液电解槽时,所述预设阈值为所述碱液电解槽的最小功率要求值。
- 根据权利要求1所述的直流耦合制氢***,其特征在于,所述第二变换器为双向变换器,所述变换装置为双向变换装置,所述新能源***的电能输出支路上还设置有可控开关;所述可控开关用于在所述新能源***的输出电能小于等于启机阈值且当前时刻处于电网谷价阶段时断开、在其他时间闭合;所述第二变换器还用于在所述新能源***的输出电能小于等于所述启机阈值且当前时刻处于电网谷价阶段时,通过所述变换装置接收电网电能进行反向变换;所述第一变换器还用于在所述新能源***的输出电能小于等于所述启机阈值且当前时刻处于电网谷价阶段时,接收所述第二变换器的电能,向所述制氢槽***提供制氢电能。
- 根据权利要求1-3任一所述的直流耦合制氢***,其特征在于,所述第一变换器中和所述第二变换器,采用主从控制;或者,所述直流耦合制氢***还包括:与所述通信单元相连的***控制器,用于实现所述直流耦合制氢***的集中控制。
- 根据权利要求1-3任一所述的直流耦合制氢***,其特征在于,所述通信单元独立设置,或者,集成于所述第一变换器和所述第二变换器中任意一个的内部。
- 根据权利要求1-3任一所述的直流耦合制氢***,其特征在于,所述新能源***为光伏发电***时,所述第一变换器为DC/DC变换器,所述第二变换器为DC/AC变换器或者串联连接的DC/DC变换器及DC/AC变换器;所述新能源***为风力发电***时,所述第一变换器为AC/DC变换器或者串联连接的AC/DC变换器和DC/DC变换器,所述第二变换器为AC/AC变换器。
- 一种直流耦合制氢***的控制方法,其特征在于,应用于如权利要求1-6任一所述的直流耦合制氢***中的通信主机或者***控制器,所述直流耦合制氢***的控制方法包括:启机后,控制所述直流耦合制氢***中的第一变换器处于待机状态、第二变换器通过变换装置进行并网输出;进行最大功率点跟踪MPPT运算,并根据运算得到的运算信息判断所述直流耦合制氢***中新能源***的输出电能是否大于预设阈值;若所述新能源***的输出电能大于所述预设阈值,则控制所述第二变换器处于待机状态、所述第一变换器向所述直流耦合制氢***中的制氢槽***提供制氢电能;若所述新能源***的输出电能小于等于所述预设阈值,则维持所述第一变换器处于待机状态、所述第二变换器通过变换装置进行并网输出。
- 根据权利要求7所述的直流耦合制氢***的控制方法,其特征在于,进行最大功率点跟踪MPPT运算,并根据运算得到的运算信息判断所述直流耦合制氢***中新能源***的输出电能是否大于预设阈值,包括:进行所述MPPT运算,确定最大功率点的功率值;判断所述最大功率点的功率值是否大于所述预设阈值;若所述最大功率点的功率值大于所述预设阈值,则判定所述新能源***的输出电能大于所述预设阈值。
- 根据权利要求8所述的直流耦合制氢***的控制方法,其特征在于,所述预设阈值包括:第一预设阈值和第二预设阈值,所述第一预设阈值大于等于所述第二预设阈值;判断所述最大功率点的功率值是否大于所述预设阈值,包括:判断所述最大功率点的功率值是否上升到大于所述第一预设阈值,并且,未下降到小于所述第二预设阈值;若所述最大功率点的功率值上升到大于所述第一预设阈值,并且,未下降到小于所述第二预设阈值,则判定所述最大功率点的功率值大于所述预设阈值。
- 根据权利要求8所述的直流耦合制氢***的控制方法,其特征在于,若所述制氢槽***中的制氢槽为碱液电解槽,则所述预设阈值为所述碱液电解槽的最小功率要求值、等于所述碱液电解槽的最小电流要求值与最小电压要求值的乘积,并且所述直流耦合制氢***的控制方法中,判断所述最大功率点的功率值是否大于所述预设阈值,包括:根据所述最大功率点的功率值计算得到所述碱液电解槽的制氢电流理论值;判断所述制氢电流理论值是否满足所述碱液电解槽的最小电流要求;若所述制氢电流理论值满足所述碱液电解槽的最小电流要求,则判定所述最大功率点的功率值大于所述预设阈值。
- 根据权利要求10所述的直流耦合制氢***的控制方法,其特征在于,根据所述最大功率点的功率值计算得到所述碱液电解槽的制氢电流理论值所采用的公式包括:Uin=U_limit+(Pmpp*Req) 1/2和Iin=Pmpp/Uin;其中,Uin为所述碱液电解槽的制氢电压理论值,Iin为所述碱液电解槽的制氢电流理论值,U_limit为所述碱液电解槽的最小电压要求值,Pmpp为所述最大功率点的功率值,Req为所述碱液电解槽的等效电阻。
- 根据权利要求7-11任一所述的直流耦合制氢***的控制方法,其特征在于,当所述新能源***的电能输出支路上还设置有可控开关时,所述直流耦合制氢***的控制方法,在控制所述直流耦合制氢***中的第一变换器处于 待机状态、第二变换器通过变换装置进行并网输出之前,还包括:控制所述可控开关闭合。
- 根据权利要求12所述的直流耦合制氢***的控制方法,其特征在于,当所述第二变换器为双向变换器、所述变换装置为双向变换装置时,所述直流耦合制氢***的控制方法,还包括:判断所述新能源***的输出电能是否小于等于启机阈值以及当前时刻是否处于电网谷价阶段;若所述新能源***的输出电能小于等于所述启机阈值且当前时刻处于电网谷价阶段,则控制所述可控开关断开、所述第二变换器通过所述变换装置接收电网电能进行反向变换、所述第一变换器接收所述第二变换器的电能并向所述制氢槽***提供制氢电能。
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