WO2020109014A1 - Elektrochemische energiespeicherzelle - Google Patents
Elektrochemische energiespeicherzelle Download PDFInfo
- Publication number
- WO2020109014A1 WO2020109014A1 PCT/EP2019/081295 EP2019081295W WO2020109014A1 WO 2020109014 A1 WO2020109014 A1 WO 2020109014A1 EP 2019081295 W EP2019081295 W EP 2019081295W WO 2020109014 A1 WO2020109014 A1 WO 2020109014A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- insulation element
- energy storage
- cell
- housing
- electrochemical energy
- Prior art date
Links
- 210000000352 storage cell Anatomy 0.000 title claims abstract description 56
- 238000012983 electrochemical energy storage Methods 0.000 title claims abstract description 24
- 210000004027 cell Anatomy 0.000 claims abstract description 105
- 238000009413 insulation Methods 0.000 claims abstract description 103
- 239000004020 conductor Substances 0.000 claims abstract description 10
- 238000004146 energy storage Methods 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 25
- 239000002245 particle Substances 0.000 claims description 16
- 229920001971 elastomer Polymers 0.000 claims description 11
- 239000000806 elastomer Substances 0.000 claims description 9
- 239000013536 elastomeric material Substances 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 239000012782 phase change material Substances 0.000 claims description 5
- 229920000098 polyolefin Polymers 0.000 claims description 5
- 238000002955 isolation Methods 0.000 claims description 4
- 238000005496 tempering Methods 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 description 10
- 238000004804 winding Methods 0.000 description 7
- 229920002379 silicone rubber Polymers 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 230000017525 heat dissipation Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000004945 silicone rubber Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000013013 elastic material Substances 0.000 description 2
- 238000005338 heat storage Methods 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 229910002706 AlOOH Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910021518 metal oxyhydroxide Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/654—Means for temperature control structurally associated with the cells located inside the innermost case of the cells, e.g. mandrels, electrodes or electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/64—Heating or cooling; Temperature control characterised by the shape of the cells
- H01M10/647—Prismatic or flat cells, e.g. pouch cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/653—Means for temperature control structurally associated with the cells characterised by electrically insulating or thermally conductive materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/659—Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/103—Primary casings; Jackets or wrappings characterised by their shape or physical structure prismatic or rectangular
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/446—Composite material consisting of a mixture of organic and inorganic materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/471—Spacing elements inside cells other than separators, membranes or diaphragms; Manufacturing processes thereof
- H01M50/474—Spacing elements inside cells other than separators, membranes or diaphragms; Manufacturing processes thereof characterised by their position inside the cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/471—Spacing elements inside cells other than separators, membranes or diaphragms; Manufacturing processes thereof
- H01M50/48—Spacing elements inside cells other than separators, membranes or diaphragms; Manufacturing processes thereof characterised by the material
- H01M50/486—Organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/584—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
- H01M50/586—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries inside the batteries, e.g. incorrect connections of electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/584—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
- H01M50/59—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries characterised by the protection means
- H01M50/593—Spacers; Insulating plates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the invention relates to an electrochemical energy storage cell, comprising at least one cell coil, which is accommodated in a housing, the housing being closed with a cover on at least one end face.
- Such an energy storage cell is from, for example
- Electrochemical reactions inside the cell coil release heat when the energy storage cell is charged or discharged. Depending on the operating conditions, it may be necessary to remove the heat generated inside the cell coil. So far, this has been done by a cooling device, which is usually assigned outside in the area of the bottom or the side wall of the housing. Due to the design, however, the heat flow inside the
- the invention has for its object the electrochemical
- the electrochemical energy storage cell comprises at least one cell coil which is accommodated in a housing, the housing being closed on at least one end face with a cover which forms part of the housing, an insulation element being arranged between the cell coil and the housing, wherein the insulation element is made of electrically insulating and at the same time thermally conductive material.
- the insulation component of the term insulation element in the present invention relates exclusively to electrical insulation.
- the electrically insulating properties of the insulation element prevent an electrical short circuit between the components of the cell coil and the housing.
- the housing component cover is usually assigned a pole section, which is connected to an arrester of the cell coil.
- the insulation element has the effect that an electrically conductive connection between the cover, or the pole section of the cover, and the cell winding only via the arrester given is.
- the insulation element prevents an electrical short circuit between the individual layers of the winding.
- heat generated in the cell coil can be transported in the direction of the insulation element and can be passed on through the insulation element in the direction of the cover, the side wall of the housing or the floor assigned to the insulation element.
- the heat transported through the insulation element can be dissipated via a cooling device arranged on the outside in the corresponding areas of the energy storage cell.
- the insulation element can absorb and transmit a large amount of heat. This enables effective cooling of the cell wrap.
- the arrangement of the cell coil in round cells is mostly upright due to the shape of the round cells.
- the electrical pole sections can be designed such that the two pole sections and their connections point in one direction, for example in the direction of the cover. It is also conceivable that the two pole sections point in opposite directions, one pole section pointing towards the cover and one pole section pointing towards the bottom.
- the cell coil can also be arranged upright in the housing. In this case, especially in the case of larger prismatic cells, the two pole sections mostly point towards the cover.
- Several parallel cell coils can also be arranged in one housing. Alternatively, it is also possible to arrange the cell coils transversely in the housing. In this case, the arresters protrude in the direction of the side wall of the housing and are diverted within the housing in the direction of the pole sections arranged in the cover.
- the insulation element is preferably designed such that the space between the cell winding and the housing, in particular between the cell winding and the cover, is filled.
- the insulation element contacts both the Front of the cell wrap as well as the inside of the lid and the side wall of the housing. Through direct contact with them
- the insulation element preferably has a thermal conductivity of at least 0.5 W / (m K).
- the thermal conductivity is particularly preferably at least 1 W / (m K).
- Heating can be particularly in the case of types of
- the insulation element according to the invention also contributes to a homogenization of the temperature in the cell itself.
- the insulation element according to the invention also contributes to a homogenization of the temperature in the cell itself.
- the insulation element is preferably formed from swellable material.
- sealing elements the choice of material has hitherto usually been carried out in such a way that a sealing element does not swell as far as possible with regard to the media to be sealed.
- the insulation element experiences a certain swelling after being placed in the housing and in particular after contact with the electrolyte which surrounds the cell coil.
- the swelling process means that the insulation element fills the space between the cell wrap, cover and side wall of the housing. This is a direct and immediate contact of the insulation element with the
- the insulation element can be formed from an elastomeric material.
- An insulation element made of elastomeric material can adapt to the shape of the adjacent components and thus enable optimal filling of the available space.
- the insulation element can be formed from a silicone-based elastomer.
- Advantageous silicone-based elastomers are, for example, silicone rubber (VMQ) or fluorinated silicone rubber (F-VMQ).
- silicone-based elastomers are elastic materials and make that possible
- electrochemical energy storage cells for example with the electrolyte of a lithium-ion battery.
- electrochemical energy storage cells for example with the electrolyte of a lithium-ion battery.
- the insulation element can be formed from a polyolefin-based elastomer.
- a particularly preferred polyolefin-based elastomer is butysobutylene rubber (IIR). IIR is chemically stable, especially with regard to the electrolytes. Furthermore, IIR can be designed such that upon contact with electrolytes and the like, the release of
- Another polyolefin-based elastomer is ethylene propylene diene monomer (EPDM).
- EPDM is also chemically stable with respect to electrolytes.
- the insulation element is formed from a polymeric material.
- Other materials that may be used are materials based on fluororubber (FKM), polyacrylate rubber (ACM). In principle, the use is also
- thermoplastic elastomers for example based on polyolefins, polyamides or polyesters.
- the insulation element lies after completion of the
- the thermal conductivity of the insulation element can be improved if the insulation element is equipped with thermally conductive particles.
- electrically non-conductive mineral particles are preferably considered as heat-conductive particles.
- heat-conductive particles are, for example, particles of aluminum oxide (Al2O3), aluminum oxide flydroxide (AlOOH), aluminum hydroxide (Al (OH) 3), magnesium hydroxide
- Mg (OH) 2 magnesium oxide
- Al nitride (AIN) aluminum nitride (AIN) or boron nitride (BN).
- Oxides, hydroxides or nitrides of other base metals are also conceivable.
- heat-conductive particles in the form of metal hydroxides or oxyhydroxides generally lead to a lower thermal conductivity in comparison to oxides, the use of such compounds can, however, be advantageous because these can be exceeded when a
- the housing can have a base, a further insulation element being arranged between the base and the cell coil.
- the temperature control of the energy storage cell can be further improved.
- the cell coil is sandwiched between two thermally conductive insulation elements. The heat dissipation of the heat transported through the insulation elements takes place between the cell coil, the insulation element and the housing wall.
- the insulation element can surround the cell coil.
- the insulation element is between
- the insulation element can be provided with heat-storing particles. Large amounts of heat can be generated in a particularly short time, particularly in the case of rapid charging processes.
- the heat-storing particles can in this case a part of the over the cell coil in the
- phase transfer materials are conceivable, which are selected so that they are in the upper one
- phase transfer material can absorb thermal energy without causing an increase in
- the insulation element acts as a heat buffer and partially absorbs heat emitted during the rapid charging process and then gradually releases it to the housing of the energy storage cell. The occurrence of temperature peaks can thereby be reduced.
- the heat storage particles are designed as phase change material.
- Advantageous heat-storing particles in the form of exchangeable material are, for example, waxes present in capsule form or organic or inorganic salts.
- the heat-storing particles designed as phase change material preferably have a phase transition temperature in the range from 30 ° C. to 50 ° C., preferably 40 ° C.
- the insulation element is an independent component.
- Insulation elements consisting of a compressible structure are also conceivable. These can be, for example, nonwovens with ceramic particles in their matrix.
- FIG. 1 an energy storage cell with an insulation element in section
- Fig. 2 shows an energy storage cell with two insulation elements in
- FIG. 3 shows a first embodiment of an energy storage cell in the form of a prismatic cell
- FIG. 4 shows a second embodiment of an energy storage cell in the form of a prismatic cell
- FIG. 5 shows a third embodiment of an energy storage cell in the form of a prismatic cell
- Fig. 6 in detail the contact area between the cell coil and
- Fig. 7 in detail the contact area between the cell coil and
- Isolation element according to a second embodiment
- Fig. 10 is an insulation element with a rod-shaped central part made of solid
- 11 shows a battery system with several energy storage cells.
- FIGS. 1 and 2 show an electrochemical energy storage cell 1 in the form of a round cell.
- FIGS. 3 to 5 show an electrochemical energy storage cell 1 in the form of a prismatic cell.
- Energy storage cell 1 a cell coil 2, which is accommodated in a housing 3. Is the energy storage cell 1 as a lithium-ion
- the cell coil 2 comprises two current conductors, namely an anode 15 and a cathode 17, and two separators 16, 18, the current conductors 15, 17 being separated from one another by the separators 16, 18.
- An active material is applied to the current conductors 15, 17 and the two current conductors 15, 17 separated by the separators 16, 18 are wound into a round structure - the cell coil 2.
- the housing 3 is made of metallic material and is in the
- the housing 3 has a material uniform and in one piece with the
- the lid 5 has a fastening section 6 for fastening the
- the second arrester 8 ′ of the cell coil 2 is assigned to the bottom 13 of the housing 3.
- the lid 5 has a fastening section 6 for fastening the
- the fastening section 6 and the pole section 7 are connected to one another via a compensating element 9.
- the compensating element 9 is designed to be elastic and electrically insulating.
- the compensating element 9 consists of an elastomeric material.
- an insulation element 11 is arranged between cell coil 2 and cover 5.
- the insulation element 11 consists of insulating and thermally conductive material.
- the base material of the insulation element 11 is a silicone rubber, which is formed with thermally conductive particles from a metal flydroxide - in the present case aluminum flydroxide. With this configuration, the insulation element 11 has a thermal conductivity of 1.5 W / (m K). Based on the currently available materials, one is Thermal conductivity of the insulation element of 10 W / (m K) achievable, a thermal conductivity of up to 75 W / (m K) is conceivable.
- the base material of the insulation element 11 is made of IIR.
- the insulation member 11 is also particulate
- phase change material In the present case, this is made up of a
- the insulation element 11 is provided with encapsulated phase change material based on an organic wax.
- the insulation element 11 lies over the entire area of the cell coil 2, on the inside of the cover 5 and on the side wall of the housing 3. This ensures that the
- Insulation element 11 contacts the cell coil 2, the cover 5 and the housing 3. This results in a heat flow between cell wrap 2, the
- the cell coil 2 is arranged directly on the bottom 13 of the housing 3.
- FIG. 2 shows an embodiment of an energy storage cell 1 according to FIG. 1, a further insulation element 1 T being arranged between the cell coil 2 and the base 13.
- the further insulation element 1 T is designed in the same way as the insulation element 11 arranged between the cell coil 2 and the cover 5.
- a conductor 8, 8 ′ projects through both insulation elements 11, 1 T.
- the cover 5 When viewed in plan view, the cover 5 is circular.
- the pole section 7 is arranged centrally and centrally in the cover 5 and from Compensation element 9 surrounded.
- the compensating element 9 is positively and materially connected to the pole section 7.
- Fastening section 6 has a disk-shaped section, in the opening of which the compensating element 9 and the pole section 7 are arranged.
- the compensating element 9 is firmly attached in the region of the edge of the opening of the fastening section 6.
- the fastening section 6 also has a cylindrical section which rests on the front edge of the housing 3. In the area of the two touching edges, cover 5 and housing 3 are integrally connected by means of
- FIG. 3 shows a first alternative embodiment of an electrochemical energy storage cell 1 in the form of a prismatic cell.
- the two pole sections 7, 7 'in the cover 5 are configured
- a first insulation element 11 ' is arranged between cell coil 2 and base 13.
- Compensation elements 9, 9 ' connected to the fastening section 6 of the cover 5.
- the compensating elements 9, 9 ' are designed to be elastic and electrically insulating, so that the two pole sections 7, 7' are electrically insulated from one another.
- FIG. 4 shows a first alternative embodiment of an electrochemical energy storage cell 1 in the form of a prismatic cell.
- the two pole sections 7, 7 'in the cover 5 are configured
- a first insulation element 11 is arranged between cell wrap 2 and cover 5 and a further insulation element 11 'is arranged between cell wrap 2 and bottom 13.
- FIG. 5 shows a first alternative embodiment of an electrochemical energy storage cell 1 in the form of a prismatic cell.
- the two pole sections 7, 7 'in the cover 5 are configured
- a first insulation element 11 is between cell wrap 2 and cover 5, a second insulation element 11 'is between cell wrap 2 and bottom 13 and a third insulation element 11 "is arranged between cell wrap 2 and the side wall 14 of the housing.
- the two pole sections 7, 7 ' are connected to the fastening section 6 of the cover 5 via compensating elements 9, 9'.
- the compensating elements 9, 9 ' are designed to be elastic and electrically insulating, so that the two pole sections 7, 7' are electrically insulated from one another.
- Figure 6 shows in detail the contact area between cell coils 2 and
- the cell coil 2 comprises a spirally wound arrangement of a flat anode 15, a flat first separator 16, a flat cathode 17 and a flat second separator 18. These flat components are spiral to a cell coil 2
- Separators 16, 18 have a relatively poor thermal conductivity. In this respect, the thermal conductivity across the separators 16, 18 is far worse. In the embodiment shown above immediately after assembly, the insulation element 11 is only on the front side
- FIG. 7 shows an alternative embodiment of the cell coil 2 according to FIG. 4.
- the anode 15 is located on the front over the first separator 16 over.
- the insulation element 11 surrounds the anode 15 on the end face and thereby prevents a short circuit between the anode 15 and the cathode 17, for example due to dendrite formation .
- the material of the insulation element 11 swells, so that this - as shown in the figure below - finally contacts the anode 15, the two separators 16, 18 and the cathode 17 on the end face.
- the heat emitted by the anode 15 and the cathode 17 can be absorbed and dissipated by the insulation element 11.
- the insulation element 11 can be absorbed and dissipated by the insulation element 11.
- Insulation element 11 embeds the anode 15 on the end face.
- FIG. 8 shows an alternative embodiment of an insulation element 11.
- the arrester 8 is integrated in the insulation element 11.
- the arrester 8 is designed as a metallic insert, to which the elastomeric material of the insulation element 11 is injection molded.
- FIG. 9 shows an insulation element 11 which has a base 19 and a rod-shaped extension 12.
- the extension 12 forms the core of the cell coil 2 and simplifies the production of the cell coil 2. Furthermore, the extension 12 improves the heat transfer from the core of the
- the extension 12 is preferably rotationally symmetrical, in the case of energy storage cells 1 in the form of prismatic cells the extension 12 is preferred
- FIG. 10 shows a development of the insulation element 11 according to FIG. 7, the material of the extension 12 differing from the base 19 of the insulation element 11 in the upper embodiment.
- the extension 12 has a core made of a different material, preferably a firmer material, which is surrounded by the elastomeric material of the base 19.
- FIG. 11 shows a battery system 20 with a plurality of energy storage cells 1 in accordance with the previously described configurations.
- the energy storage cells 1 are arranged on a device 21 for tempering the energy storage cells 1.
- the energy storage cells 1 can be arranged lying or standing on the device 21.
- the device 21 is a channel through which a bath liquid flows.
- the channel consists of a solid material made of plastic or metal. There is a between the channel and the energy storage cell 1
- Heat transfer element 22 made of elastic material. This ensures good heat transfer between the cell coil 2, the insulation element 11, the housing 3, the heat transfer element 22 and the device 21 with the channel and bath fluid.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Battery Mounting, Suspending (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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KR1020217013567A KR20210068123A (ko) | 2018-11-28 | 2019-11-14 | 전기화학적 에너지 저장 셀 |
US17/297,496 US20220037712A1 (en) | 2018-11-28 | 2019-11-14 | Electrochemical energy storage cell |
JP2021530150A JP7137014B2 (ja) | 2018-11-28 | 2019-11-14 | 電気化学エネルギ蓄積セル |
CN201980076453.3A CN113169420A (zh) | 2018-11-28 | 2019-11-14 | 电化学的蓄能单元 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102018130173.1A DE102018130173A1 (de) | 2018-11-28 | 2018-11-28 | Elektrochemische Energiespeicherzelle |
DE102018130173.1 | 2018-11-28 |
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WO2020109014A1 true WO2020109014A1 (de) | 2020-06-04 |
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PCT/EP2019/081295 WO2020109014A1 (de) | 2018-11-28 | 2019-11-14 | Elektrochemische energiespeicherzelle |
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US (1) | US20220037712A1 (de) |
JP (1) | JP7137014B2 (de) |
KR (1) | KR20210068123A (de) |
CN (1) | CN113169420A (de) |
DE (1) | DE102018130173A1 (de) |
WO (1) | WO2020109014A1 (de) |
Families Citing this family (4)
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DE102020115226A1 (de) | 2020-06-09 | 2021-12-09 | Bayerische Motoren Werke Aktiengesellschaft | Energiespeicherzelle |
US20230246302A1 (en) * | 2021-01-19 | 2023-08-03 | Lg Energy Solution, Ltd. | Battery, and battery pack and vehicle comprising the same |
WO2023031113A1 (en) * | 2021-08-30 | 2023-03-09 | Northvolt Ab | Secondary cell |
WO2023143879A1 (de) * | 2022-01-31 | 2023-08-03 | Carl Freudenberg Kg | Energiespeicherzelle |
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JP4496582B2 (ja) | 1999-12-28 | 2010-07-07 | 株式会社ジーエス・ユアサコーポレーション | リチウム二次電池 |
US20050026014A1 (en) | 2003-07-31 | 2005-02-03 | Michael Fogaing | Polymer batteries having thermal exchange apparatus |
JP2011108507A (ja) | 2009-11-18 | 2011-06-02 | Honda Motor Co Ltd | 二次電池 |
JP5422596B2 (ja) | 2011-04-22 | 2014-02-19 | 株式会社日立製作所 | 二次電池モジュール及び二次電池パック |
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DE102014222173A1 (de) * | 2014-10-30 | 2016-05-04 | Robert Bosch Gmbh | Batteriezelle und Verwendung derselben |
JP6315480B2 (ja) * | 2015-05-13 | 2018-04-25 | アイシン化工株式会社 | 蓄熱ポリマ成形体 |
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CN207587875U (zh) * | 2017-11-30 | 2018-07-06 | 广东安电能源科技有限公司 | 一种具有散热结构的锂离子电池 |
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2018
- 2018-11-28 DE DE102018130173.1A patent/DE102018130173A1/de active Pending
-
2019
- 2019-11-14 US US17/297,496 patent/US20220037712A1/en active Pending
- 2019-11-14 JP JP2021530150A patent/JP7137014B2/ja active Active
- 2019-11-14 CN CN201980076453.3A patent/CN113169420A/zh active Pending
- 2019-11-14 WO PCT/EP2019/081295 patent/WO2020109014A1/de active Application Filing
- 2019-11-14 KR KR1020217013567A patent/KR20210068123A/ko not_active Application Discontinuation
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DE102008025884A1 (de) | 2008-05-29 | 2009-12-03 | Temic Automotive Electric Motors Gmbh | Energiespeicherzelle mit gewickelten Elektroden und Abstandshalter zum Zelldeckel |
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Also Published As
Publication number | Publication date |
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CN113169420A (zh) | 2021-07-23 |
US20220037712A1 (en) | 2022-02-03 |
JP2022509227A (ja) | 2022-01-20 |
JP7137014B2 (ja) | 2022-09-13 |
DE102018130173A1 (de) | 2020-05-28 |
KR20210068123A (ko) | 2021-06-08 |
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