WO2020082343A1 - Apparatus for coating layer of graphene on outer portion of wire - Google Patents
Apparatus for coating layer of graphene on outer portion of wire Download PDFInfo
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- WO2020082343A1 WO2020082343A1 PCT/CN2018/112127 CN2018112127W WO2020082343A1 WO 2020082343 A1 WO2020082343 A1 WO 2020082343A1 CN 2018112127 W CN2018112127 W CN 2018112127W WO 2020082343 A1 WO2020082343 A1 WO 2020082343A1
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
- C01B32/19—Preparation by exfoliation
Definitions
- the invention belongs to the technical field of graphene coating equipment, and in particular relates to a graphene coating device for a wire outer ring.
- Graphene is a two-dimensional carbon nanomaterial with excellent optical, electrical, and mechanical properties, and has important application prospects in materials science, micro-nano processing, energy, biomedicine, and drug delivery.
- graphene already exists in nature, but it is difficult to peel off the single-layer structure.
- Graphene is graphite layered together. Due to the ultra-thin nature of graphene, it is difficult for graphene to coat a sufficiently thin single layer or several layers of graphene coating on the workpiece to be coated, which cannot meet the needs of graphene coating.
- the traditional mechanical peeling method uses special adhesive tape to continuously bond and separate the graphite layer. It takes a long time to obtain the required graphene coating material. The production efficiency is low and mass production cannot be achieved.
- the traditional graphene coating The production method also cannot generate a graphene coating on the surface of a thin workpiece. For example, the traditional graphene coating method cannot generate a graphene coating on the surface of a thin rod or a thin wire.
- the present invention provides a continuous industrial peeling structure, which can form a graphene-coated graphene coating device on the surface of an elongated wire or rod.
- the graphene coating device of the outer ring of the wire includes a glue module, a paint module, and an adhesive module placed in a line on a horizontal working surface, and the interior design of the glue module There is a glue cavity, the glue cavity is filled with glue, the glue line is machined with a glue line hole communicating with the glue cavity, and the paint module is designed with a graphite cavity inside the graphite cavity There is graphite, and the coating module is processed with a material line hole that communicates with the graphite material cavity left and right, and the material to be coated passes through the glue line hole and the material line hole in sequence; the adhesive material module includes an assembly on the rotating shaft
- the adhesive wheel on the upper side is equipped with a glue spray block and a trimming knife on both sides of the glue wheel.
- the glue spray block is designed with a glue spray structure that can spray a thin layer of glue on the surface of the glue wheel.
- An annular wire groove is machined on the annular surface of the adhesive wheel, the wire groove has an arc cross section, the wire material has a circular cross section, the wire groove cross section has an arc and the wire material cross section radius.
- the shape of the front edge of the edge cutter is the same as that of the adhesive wheel
- the cross-sectional shape of the thread groove is the same, the front edge of the edge cutter is attached to the surface of the adhesive wheel, and the glue spraying block sprays the glue on the surface of the adhesive wheel to form an adhesive layer.
- the edge of the edge cutter can cut the rubber layer, and the side of the edge cutter is equipped with a waste rubber wheel that rolls up the cut rubber layer;
- the adhesive modules are paired
- the rotation axes of the two adhesive wheels of each pair of adhesive modules are parallel to each other, the arc center of the cross section of the two adhesive wheels near the position of the wire groove is at the same point, and the graphene coating device of the outer ring of the line includes two pairs The above-mentioned sticky material module; the wire material passing through the material wire hole is sequentially passed through each pair of two wire grooves where the adhesive wheel is close to the position, the wire material is assembled on the movement module, and the wire material is directed
- the speed of the front movement is the same as the linear speed of the surface of the sticky wheel.
- a ring block is assembled between the paint module and the first pair of adhesive modules close to the paint module, the ring block is ring-shaped, and the wire material passes through the middle of the ring block.
- a brush used in pairs in an up-and-down manner is also installed between the ring material block and the first pair of adhesive modules close to the ring material block, and the thread material passes between the upper and lower brushes.
- the side of the glue spraying block is equipped with an airflow block, and the air outlet of the airflow block is directly facing the surface of the adhesive wheel.
- the two adhesive wheels of a pair of adhesive modules have a gap near the position, the two adhesive wheels of the pair of adhesive modules are on the same plane, and the two pairs of two adjacent adhesive modules are in the same plane
- the two planes on which the adhesive wheel is located are perpendicular.
- the beneficial effect of the present invention is that the graphene coating device for the outer ring of the wire is mainly used for graphene coating processing of thin round rods or other wire materials that can be folded.
- the wire material first passes through the glue chamber of the glue module, so that the surface of the wire material is coated with glue, and then the glued wire passes through the graphite material chamber of the paint module, so that the graphite material chamber
- the graphite is attached to the glue surface of the wire material, so that when the wire attached to the graphite passes through the wire groove of the two adhesive wheels of the pair of adhesive modules, the annular surface of the adhesive wheel includes the wire groove through the glue spray block Has a glue layer.
- the upper and lower glue layers just adhere the graphene on the surface of the wire, so that the number of graphene layers on the surface of the wire is reduced, and then the wire Continue to pass between the next pair of adhesive wheels, and peel the graphene layer on the strand again, so that multiple pairs of adhesive wheels can adhere to the graphene on the surface of the strand multiple times, making Graphene continues to thin, eventually becoming a single layer of graphene coating.
- the device realizes profiling through the wire groove of the adhesive wheel, then the glue is added to the wire groove through the glue spraying process, and finally the adhesion of the graphene layer on the surface of the wire material is achieved by the rotation of the adhesive wheel and the wire groove, and finally the graphite is adhered
- the layer of ene is taken up by the waste rubber wheel.
- a continuous adhesion process is realized, so that the device can be continuously produced, thereby realizing an industrial production process of wire graphene coating.
- FIG. 1 is a schematic structural diagram of a graphene coating device for an outer ring.
- Fig. 2 is a schematic structural view of an edge cutter.
- the graphene coating device of the outer ring of the present line includes a glue module 1, a paint module 2, and an adhesive module 3 placed linearly on a horizontal working surface in sequence, and the interior design of the glue module 1
- a glue cavity 11 the glue cavity 11 is filled with glue
- the glue coating module 1 is processed with a glue line hole communicating with the glue cavity 11
- the paint module 2 is designed with a graphite material cavity 21
- the graphite material cavity 21 is filled with graphite
- the coating module 2 is processed with a material line hole communicating with the graphite material cavity 21, and the wire material 4 to be coated passes through the glue line hole and the material line hole in sequence
- the sticky material module 3 includes a sticky wheel 31 mounted on the rotating shaft, and a glue spraying block 32 and a trimming knife 33 are mounted on both sides of the sticky wheel 31 respectively.
- the glue spraying block 32 is designed with a glue spraying structure capable of spraying a thin layer of glue on the surface of the glue wheel 31.
- An annular wire groove 34 is formed on the annular surface of the glue wheel 31, and the wire groove 34
- the cross-section is arc-shaped, the cross-section of the wire material 4 is circular, and the cross-sectional arc shape of the wire groove 34 is the same as the radius of the cross-section of the wire material 4.
- the front edge of the edge cutter 33 is the same as the cross-sectional shape of the line groove 34 of the adhesive wheel 31. As shown in FIG. 2, the front edge of the edge cutter 33 is attached to the adhesive wheel 31 On the surface, the glue spraying block 3 sprays the glue on the surface of the adhesive wheel 31 to form a glue layer.
- the blade of the edge cutter 33 can cut the glue layer
- the annular surface of the adhesive wheel 31 is processed with a non-stick layer. This makes it easy to cut out the forming compound.
- the side of the edge cutter 33 is equipped with a waste rubber wheel 35 which rolls up the cut rubber layer; the adhesive modules 3 are used in pairs, and the rotating shafts of the two adhesive wheels 31 of each pair of adhesive modules 3 are mutually Parallel, the arc center of the cross section of the two adhesive wheels 31 near the line groove 34 is at the same point, and the graphene coating device of the outer ring of the line includes more than two pairs of adhesive modules 3; passing through the material hole
- the wire 4 passes through each pair of two wire grooves 34 close to the position of the adhesive wheel 31, the wire 4 is assembled on the motion module, and the speed of the wire 4 moving forward is The linear velocity of the surface of the feed wheel 31 is the same.
- the graphene coating device of the outer ring of the wire is mainly used for processing graphene coating of thin round rods or other wire materials 4 that can be folded.
- the wire material 4 first passes through the glue chamber 11 of the glue module 1 so that the surface of the wire material 4 is coated with glue, and then the glued wire 4 passes from the graphite material chamber 21 of the paint module 2 Pass, so that the graphite in the graphite material cavity 21 is attached to the glue surface of the wire material 4, so that when the wire material 4 attached with graphite passes through the wire groove 34 of the two adhesive wheels 31 of the paired adhesive module 3,
- the annular surface of the sticky wheel 31 includes the wire groove 34 sprayed through the glue spray block, which already has a layer of glue.
- the device realizes profiling through the wire groove of the adhesive wheel 31, and then the glue is added to the wire groove 34 through the glue spraying process, and finally the adhesion of the graphene layer on the surface of the wire material 5 is achieved by the rotation of the adhesive wheel 31 together with the wire groove 34 Finally, the glue layer adhering to graphene is rolled away by the waste rubber wheel 35.
- a continuous adhesion process is realized, so that the device can be continuously produced, thereby realizing an industrial production process of wire graphene coating.
- a ring material block 5 is assembled between the paint module 2 and the first pair of adhesive modules close to the paint module 2, the ring material block 5 is ring-shaped, and the wire material 4 Passing through the loop block 5.
- the diameter of the inner ring of the ring material block 5 is slightly larger than the diameter of the wire material 4, so that the ring material block 5 can not only guide the wire material 4, but also squeeze out the excess graphite on the surface of the wire material 4 One part reduces the workload when the lower part adheres.
- Between the ring material block 5 and the first pair of adhesive modules 3 close to the ring material block 5 are also equipped with a pair of upper and lower brushes 6 used in pairs, and the thread material 4 passes between the upper and lower two brushes 6.
- the brush 6 can further remove excess graphite on the surface of the strand material 4 to make the graphite layer on the strand material surface thinner, further reducing the workload when the lower part is adhered.
- the side of the glue-spraying block 32 is equipped with an airflow block 36, and the air outlet of the airflow block 36 faces the surface of the adhesive wheel 31.
- the air flow block 36 is located between the sticky wheel 31 and the wire 4, the sticky wheel 31 rotates from the position directly opposite the glue spraying block to the wire 4 position, and the airflow block 36 is inserted With high-pressure airflow, the airflow block 36 can spray airflow onto the surface of the adhesive wheel 31 to quickly dry the glue, so that the adhesive layer on the surface of the adhesive wheel 31 can quickly become stable.
Abstract
An apparatus for coating a layer of graphene on the outer portion of a wire. The apparatus comprises disposing on a horizontal work surface, and sequentially in a straight line, a gluing module (1), a coating module (2), and adhesion modules (3). The gluing module (1) is internally designed to include a glue cavity (11), the glue cavity (11) having a glue provided therein. The coating module (2) is internally designed to include a graphite cavity (21). The adhesion modules (3) each comprise an adhesion wheel (31) arranged on a rotary shaft, and an adhesive-spraying block (32) and an edging blade (33) respectively provided on either side of the adhesion wheel (31). The adhesive sprayed on the surface of the adhesion wheels (31) by means of the adhesive-spraying blocks (32) forms an adhesive layer. As the adhesive layer rotates to each edging blade (33) position, the tip of each edging blade (33) cuts off the adhesive layer. A waste-adhesive wheel (35) provided to the side of each edging blade (33) collects the adhesive layer that has been cut off. The adhesion modules (3) are used in pairs, and wire material passing through the gluing module (1) and the coating module (2) also passes between each pair of adhesion wheels (31). In the apparatus, a continuous stripping structure is used to form a layer of graphene coated on the surface of a thin wire or rod.
Description
本发明属于石墨烯涂层设备技术领域，具体涉及一种线外圈石墨烯涂层装置。The invention belongs to the technical field of graphene coating equipment, and in particular relates to a graphene coating device for a wire outer ring.
石墨烯是一种二维碳纳米材料，它具有优异的光学、电学、力学特性，在材料学、微纳加工、能源、生物医学和药物传递等方面具有重要的应用前景。实际上石墨烯本来就存在于自然界，只是难以剥离出单层结构。石墨烯一层层叠起来就是石墨。由于石墨烯的超薄特性，使得石墨烯很难在需要涂层的工件上涂层出足够单薄的单层或者几层的石墨烯涂层，无法达到石墨烯涂层的使用需求。传统的机械剥离法，使用特除胶布对石墨层不停的进行粘结分离，需要很久才可以得到需要的石墨烯涂层材料，生产效率低下，无法实现量产，而且传统的石墨烯涂层生产方法也无法在较细工件的表面生成石墨烯涂层，例如传统的石墨烯涂层方法，无法在细杆或者细线的表面生成石墨烯涂层。Graphene is a two-dimensional carbon nanomaterial with excellent optical, electrical, and mechanical properties, and has important application prospects in materials science, micro-nano processing, energy, biomedicine, and drug delivery. In fact, graphene already exists in nature, but it is difficult to peel off the single-layer structure. Graphene is graphite layered together. Due to the ultra-thin nature of graphene, it is difficult for graphene to coat a sufficiently thin single layer or several layers of graphene coating on the workpiece to be coated, which cannot meet the needs of graphene coating. The traditional mechanical peeling method uses special adhesive tape to continuously bond and separate the graphite layer. It takes a long time to obtain the required graphene coating material. The production efficiency is low and mass production cannot be achieved. Moreover, the traditional graphene coating The production method also cannot generate a graphene coating on the surface of a thin workpiece. For example, the traditional graphene coating method cannot generate a graphene coating on the surface of a thin rod or a thin wire.
发明内容Summary of the invention
针对以上问题，本发明提供一种连续的工业剥离结构，可以在细长的线体或者杆件表面形成石墨烯涂层的线外圈石墨烯涂层装置。In view of the above problems, the present invention provides a continuous industrial peeling structure, which can form a graphene-coated graphene coating device on the surface of an elongated wire or rod.
本发明解决其技术问题所采用的技术方案是：该线外圈石墨烯涂层装置包 括在水平工作面上依次直线放置的涂胶模块、涂料模块、粘料模块，所述涂胶模块内部设计有胶料腔，所述胶料腔内装有胶水，所述涂胶模块上加工有和胶料腔左右连通的胶线孔，所述涂料模块内部设计有石墨料腔，所述石墨料腔内装有石墨，所述涂料模块上加工有和石墨料腔左右连通的料线孔，待涂层的线料依次从所述胶线孔、料线孔穿过；所述粘料模块包括装配在转轴上的粘料轮，所述粘料轮的两侧分别装配有喷胶块、切边刀，所述喷胶块内设计有可以在粘料轮表面喷射出薄层胶料的喷胶结构，所述粘料轮的环形面上加工有环形的线槽，所述线槽截面成弧形，所述线料截面为圆形，所述线槽的截面弧形与所述线料截面的半径相同，所述切边刀前部的刀锋外形与所述粘料轮线槽位置截面外形相同，所述切边刀前部刀锋贴附在所述粘料轮表面，喷胶块喷射在所述粘料轮表面的胶料形成胶层，当胶层旋转到所述切边刀位置时，所述切边刀的刀锋可以将胶料层切下，所述切边刀侧边装配有将切下胶料层卷起的废胶轮；所述粘料模块成对使用，每对粘料模块的两个粘料轮的转轴相互平行，两个粘料轮的靠近位置线槽截面的弧形圆心在同一点，该线外圈石墨烯涂层装置包括有两对以上的粘料模块；穿过所述料线孔的线料依次从每对两个所述粘料轮靠近位置的线槽穿过，所述线料装配在运动模块上，所述线料向前运动的速度与所述粘料轮表面的线速度相同。The technical solution adopted by the present invention to solve its technical problems is that the graphene coating device of the outer ring of the wire includes a glue module, a paint module, and an adhesive module placed in a line on a horizontal working surface, and the interior design of the glue module There is a glue cavity, the glue cavity is filled with glue, the glue line is machined with a glue line hole communicating with the glue cavity, and the paint module is designed with a graphite cavity inside the graphite cavity There is graphite, and the coating module is processed with a material line hole that communicates with the graphite material cavity left and right, and the material to be coated passes through the glue line hole and the material line hole in sequence; the adhesive material module includes an assembly on the rotating shaft The adhesive wheel on the upper side is equipped with a glue spray block and a trimming knife on both sides of the glue wheel. The glue spray block is designed with a glue spray structure that can spray a thin layer of glue on the surface of the glue wheel. An annular wire groove is machined on the annular surface of the adhesive wheel, the wire groove has an arc cross section, the wire material has a circular cross section, the wire groove cross section has an arc and the wire material cross section radius The same, the shape of the front edge of the edge cutter is the same as that of the adhesive wheel The cross-sectional shape of the thread groove is the same, the front edge of the edge cutter is attached to the surface of the adhesive wheel, and the glue spraying block sprays the glue on the surface of the adhesive wheel to form an adhesive layer. When the adhesive layer rotates to the When the edge cutter is in position, the edge of the edge cutter can cut the rubber layer, and the side of the edge cutter is equipped with a waste rubber wheel that rolls up the cut rubber layer; the adhesive modules are paired In use, the rotation axes of the two adhesive wheels of each pair of adhesive modules are parallel to each other, the arc center of the cross section of the two adhesive wheels near the position of the wire groove is at the same point, and the graphene coating device of the outer ring of the line includes two pairs The above-mentioned sticky material module; the wire material passing through the material wire hole is sequentially passed through each pair of two wire grooves where the adhesive wheel is close to the position, the wire material is assembled on the movement module, and the wire material is directed The speed of the front movement is the same as the linear speed of the surface of the sticky wheel.
作为优选，所述涂料模块与靠近涂料模块的第一对粘料模块之间装配有环料块，所述环料块为环形，所述线料从所述环料块中间通过。Preferably, a ring block is assembled between the paint module and the first pair of adhesive modules close to the paint module, the ring block is ring-shaped, and the wire material passes through the middle of the ring block.
作为优选，所述环料块与靠近环料块的第一对粘料模块之间还装配有上下成对使用的毛刷，所述线料从上下两个毛刷之间通过。Preferably, a brush used in pairs in an up-and-down manner is also installed between the ring material block and the first pair of adhesive modules close to the ring material block, and the thread material passes between the upper and lower brushes.
作为优选，所述喷胶块的侧边装配有气流块，所述气流块的出气口正对所述粘料轮的表面。Preferably, the side of the glue spraying block is equipped with an airflow block, and the air outlet of the airflow block is directly facing the surface of the adhesive wheel.
作为优选，成对粘料模块的两个所述粘料轮靠近位置留有间隙，成对的粘料模块的两个所述粘料轮在同一平面，靠近的两对粘料模块的两对所述粘料轮所在的两个平面垂直。Preferably, the two adhesive wheels of a pair of adhesive modules have a gap near the position, the two adhesive wheels of the pair of adhesive modules are on the same plane, and the two pairs of two adjacent adhesive modules are in the same plane The two planes on which the adhesive wheel is located are perpendicular.
本发明的有益效果在于：该线外圈石墨烯涂层装置主要用来对较细的圆杆，或者其它可以折卷的线类的线料进行石墨烯涂层加工。该装置在使用时，线料先从涂胶模块的涂胶腔穿过，使得线料表面涂上胶料，然后涂胶后的线料从涂料模块的石墨料腔通过，使得石墨料腔中的石墨贴附在线料的胶水表面，这样当贴附石墨的线料通过所述成对粘料模块的两个粘料轮的线槽时，粘料轮的环形面包括线槽通过喷胶块的喷涂，已经具有胶水层，当线料从上下两个线槽通过时，上下的胶水层恰好将线料表面的石墨烯粘附走，使得线料表面的石墨烯层数降低，然后线料继续通过从下个成对粘料轮之间通过，再一次的将线料上的石墨烯层剥离，这样多对的粘料轮就可以多次对线料表面的石墨烯进行粘附，使得石墨烯继续变薄，最终变成单层的石墨烯涂层。该装置通过粘料轮的线槽实现仿形，然后通过喷胶过程使得线槽附带胶水，最后通过粘料轮连同线槽的旋转实现对线料表面石墨烯层的粘附，最终粘附石墨烯的胶层被废胶轮卷走。从而实现了源源不断粘附过程，使得该装置可以持续的进行生产，从而实现了对线料石墨烯涂层的工业生产过程。The beneficial effect of the present invention is that the graphene coating device for the outer ring of the wire is mainly used for graphene coating processing of thin round rods or other wire materials that can be folded. When the device is used, the wire material first passes through the glue chamber of the glue module, so that the surface of the wire material is coated with glue, and then the glued wire passes through the graphite material chamber of the paint module, so that the graphite material chamber The graphite is attached to the glue surface of the wire material, so that when the wire attached to the graphite passes through the wire groove of the two adhesive wheels of the pair of adhesive modules, the annular surface of the adhesive wheel includes the wire groove through the glue spray block Has a glue layer. When the wire passes through the upper and lower grooves, the upper and lower glue layers just adhere the graphene on the surface of the wire, so that the number of graphene layers on the surface of the wire is reduced, and then the wire Continue to pass between the next pair of adhesive wheels, and peel the graphene layer on the strand again, so that multiple pairs of adhesive wheels can adhere to the graphene on the surface of the strand multiple times, making Graphene continues to thin, eventually becoming a single layer of graphene coating. The device realizes profiling through the wire groove of the adhesive wheel, then the glue is added to the wire groove through the glue spraying process, and finally the adhesion of the graphene layer on the surface of the wire material is achieved by the rotation of the adhesive wheel and the wire groove, and finally the graphite is adhered The layer of ene is taken up by the waste rubber wheel. Thus, a continuous adhesion process is realized, so that the device can be continuously produced, thereby realizing an industrial production process of wire graphene coating.
图1是线外圈石墨烯涂层装置的结构示意图。FIG. 1 is a schematic structural diagram of a graphene coating device for an outer ring.
图2是切边刀的结构示意图。Fig. 2 is a schematic structural view of an edge cutter.
下面结合实施例对本发明进一步说明：The present invention is further described below in conjunction with examples:
如图1中实施例所示，本线外圈石墨烯涂层装置包括在水平工作面上依次直线放置的涂胶模块1、涂料模块2、粘料模块3，所述涂胶模块1内部设计有胶料腔11，所述胶料腔11内装有胶水，所述涂胶模块1上加工有和胶料腔11左右连通的胶线孔，所述涂料模块2内部设计有石墨料腔21，所述石墨料腔21内装有石墨，所述涂料模块2上加工有和石墨料腔21左右连通的料线孔，待涂层的线料4依次从所述胶线孔、料线孔穿过；所述粘料模块3包括装配在转轴上的粘料轮31，所述粘料轮31的两侧分别装配有喷胶块32、切边刀33。所述喷胶块32内设计有可以在粘料轮31表面喷射出薄层胶料的喷胶结构，所述粘料轮31的环形面上加工有环形的线槽34，所述线槽34截面成弧形，所述线料4截面为圆形，所述线槽34的截面弧形与所述线料4截面的半径相同。所述切边刀33前部的刀锋外形与所述粘料轮31线槽34位置截面外形相同，如图2所示，所述切边刀33前部刀锋贴附在所述粘料轮31表面，喷胶块3喷射在所述粘料轮31表面的胶料形成胶层，当胶层旋转到所述切边刀33位置时，所述切边刀33的刀锋可以将胶料层切下，在具体设计时，所述粘料轮31的环形表面加工有不粘层。这样便于形成胶料切出。所述切边刀33侧边装配有将切下胶料层卷起的废胶轮35；所述粘料模块3成对使用，每对粘料模块3的两个粘料轮31的转轴相互平行，两个粘料轮31的靠近位置线槽34截面的弧形圆心在同一点，该线外圈石墨烯涂层装置包括有两对以上的粘料模块3；穿过所述料线孔的线料4依次从每对两个所述粘料轮31靠近位置的线槽34穿过，所述线料4装配在运动模块上，所述线料4向前运动的速度与所述粘料轮31表面的线速度相同。As shown in the embodiment in FIG. 1, the graphene coating device of the outer ring of the present line includes a glue module 1, a paint module 2, and an adhesive module 3 placed linearly on a horizontal working surface in sequence, and the interior design of the glue module 1 There is a glue cavity 11, the glue cavity 11 is filled with glue, the glue coating module 1 is processed with a glue line hole communicating with the glue cavity 11, and the paint module 2 is designed with a graphite material cavity 21, The graphite material cavity 21 is filled with graphite, and the coating module 2 is processed with a material line hole communicating with the graphite material cavity 21, and the wire material 4 to be coated passes through the glue line hole and the material line hole in sequence The sticky material module 3 includes a sticky wheel 31 mounted on the rotating shaft, and a glue spraying block 32 and a trimming knife 33 are mounted on both sides of the sticky wheel 31 respectively. The glue spraying block 32 is designed with a glue spraying structure capable of spraying a thin layer of glue on the surface of the glue wheel 31. An annular wire groove 34 is formed on the annular surface of the glue wheel 31, and the wire groove 34 The cross-section is arc-shaped, the cross-section of the wire material 4 is circular, and the cross-sectional arc shape of the wire groove 34 is the same as the radius of the cross-section of the wire material 4. The front edge of the edge cutter 33 is the same as the cross-sectional shape of the line groove 34 of the adhesive wheel 31. As shown in FIG. 2, the front edge of the edge cutter 33 is attached to the adhesive wheel 31 On the surface, the glue spraying block 3 sprays the glue on the surface of the adhesive wheel 31 to form a glue layer. When the glue layer rotates to the position of the edge cutter 33, the blade of the edge cutter 33 can cut the glue layer Next, in a specific design, the annular surface of the adhesive wheel 31 is processed with a non-stick layer. This makes it easy to cut out the forming compound. The side of the edge cutter 33 is equipped with a waste rubber wheel 35 which rolls up the cut rubber layer; the adhesive modules 3 are used in pairs, and the rotating shafts of the two adhesive wheels 31 of each pair of adhesive modules 3 are mutually Parallel, the arc center of the cross section of the two adhesive wheels 31 near the line groove 34 is at the same point, and the graphene coating device of the outer ring of the line includes more than two pairs of adhesive modules 3; passing through the material hole The wire 4 passes through each pair of two wire grooves 34 close to the position of the adhesive wheel 31, the wire 4 is assembled on the motion module, and the speed of the wire 4 moving forward is The linear velocity of the surface of the feed wheel 31 is the same.
该线外圈石墨烯涂层装置主要用来对较细的圆杆，或者其它可以折卷的线类的线料4进行石墨烯涂层加工。该装置在使用时，线料4先从涂胶模块1的涂胶腔11穿过，使得线料4表面涂上胶料，然后涂胶后的线料4从涂料模块2的石墨料腔21通过，使得石墨料腔21中的石墨贴附在线料4的胶水表面，这样当贴附石墨的线料4通过所述成对粘料模块3的两个粘料轮31的线槽34时，粘料轮31的环形面包括线槽34通过喷胶块的喷涂，已经具有胶水层，当线料4从上下两个线槽34通过时，上下的胶水层恰好将线料4表面的石墨烯粘附走，使得线料4表面的石墨烯层数降低，然后线料4继续通过从下个成对粘料轮31之间通过，再一次的将线料4上的石墨烯层剥离，这样多对的粘料轮31就可以多次对线料4表面的石墨烯进行粘附，使得石墨烯继续变薄，最终变成单层的石墨烯涂层。该装置通过粘料轮31的线槽实现仿形，然后通过喷胶过程使得线槽34附带胶水，最后通过粘料轮31连同线槽34的旋转实现对线料5表面石墨烯层的粘附，最终粘附石墨烯的胶层被废胶轮35卷走。从而实现了源源不断粘附过程，使得该装置可以持续的进行生产，从而实现了对线料石墨烯涂层的工业生产过程。The graphene coating device of the outer ring of the wire is mainly used for processing graphene coating of thin round rods or other wire materials 4 that can be folded. When the device is in use, the wire material 4 first passes through the glue chamber 11 of the glue module 1 so that the surface of the wire material 4 is coated with glue, and then the glued wire 4 passes from the graphite material chamber 21 of the paint module 2 Pass, so that the graphite in the graphite material cavity 21 is attached to the glue surface of the wire material 4, so that when the wire material 4 attached with graphite passes through the wire groove 34 of the two adhesive wheels 31 of the paired adhesive module 3, The annular surface of the sticky wheel 31 includes the wire groove 34 sprayed through the glue spray block, which already has a layer of glue. When the wire material 4 passes through the upper and lower two wire grooves 34, the upper and lower glue layers just turn the graphene on the surface of the wire material 4 Adhering away, the number of graphene layers on the surface of the wire 4 is reduced, and then the wire 4 continues to pass between the next pair of adhesive wheels 31, and the graphene layer on the wire 4 is peeled off again, so Multiple pairs of sticky wheels 31 can adhere to the graphene on the surface of the strand 4 multiple times, so that the graphene continues to thin, and eventually becomes a single layer of graphene coating. The device realizes profiling through the wire groove of the adhesive wheel 31, and then the glue is added to the wire groove 34 through the glue spraying process, and finally the adhesion of the graphene layer on the surface of the wire material 5 is achieved by the rotation of the adhesive wheel 31 together with the wire groove 34 Finally, the glue layer adhering to graphene is rolled away by the waste rubber wheel 35. Thus, a continuous adhesion process is realized, so that the device can be continuously produced, thereby realizing an industrial production process of wire graphene coating.
在具体设计时，如图1所示，所述涂料模块2与靠近涂料模块2的第一对粘料模块之间装配有环料块5，所述环料块5为环形，所述线料4从所述环料块5中间通过。所述环料块5内环的直径略大于所述线料4的直径，这样所述环料块5不仅可以对线料4进行导向，同时，可以将线料4表面多余的石墨给挤掉一部分，减小下部粘附时的工作量。所述环料块5与靠近环料块5的第一对粘料模块3之间还装配有上下成对使用的毛刷6，所述线料4从上下两个毛刷6之间通过。所述毛刷6可以进一步将线料4表面多余石墨进行扫除，使得线料表面石墨层更薄，进一步减小下部粘附时的工作量。In a specific design, as shown in FIG. 1, a ring material block 5 is assembled between the paint module 2 and the first pair of adhesive modules close to the paint module 2, the ring material block 5 is ring-shaped, and the wire material 4 Passing through the loop block 5. The diameter of the inner ring of the ring material block 5 is slightly larger than the diameter of the wire material 4, so that the ring material block 5 can not only guide the wire material 4, but also squeeze out the excess graphite on the surface of the wire material 4 One part reduces the workload when the lower part adheres. Between the ring material block 5 and the first pair of adhesive modules 3 close to the ring material block 5 are also equipped with a pair of upper and lower brushes 6 used in pairs, and the thread material 4 passes between the upper and lower two brushes 6. The brush 6 can further remove excess graphite on the surface of the strand material 4 to make the graphite layer on the strand material surface thinner, further reducing the workload when the lower part is adhered.
在具体设计时，如图1所示，所述喷胶块32的侧边装配有气流块36，所述气流块36的出气口正对所述粘料轮31的表面。具体来说，所述气流块36位于所述粘料轮31与线料4之间，所述粘料轮31从喷胶块正对位置向线料4位置旋转，所述气流块36接入高压气流，所述气流块36可以向所述粘料轮31表面喷射气流，从而快速将胶水吹干，使得粘料轮31表面的胶层可以迅速变得稳定。In a specific design, as shown in FIG. 1, the side of the glue-spraying block 32 is equipped with an airflow block 36, and the air outlet of the airflow block 36 faces the surface of the adhesive wheel 31. Specifically, the air flow block 36 is located between the sticky wheel 31 and the wire 4, the sticky wheel 31 rotates from the position directly opposite the glue spraying block to the wire 4 position, and the airflow block 36 is inserted With high-pressure airflow, the airflow block 36 can spray airflow onto the surface of the adhesive wheel 31 to quickly dry the glue, so that the adhesive layer on the surface of the adhesive wheel 31 can quickly become stable.
在具体设计时，如图1所示，成对粘料模块3的两个所述粘料轮31靠近位置留有间隙，这样可以防止成对的粘料轮31靠近位置被黏住，从而无法完成对线料4表面石墨烯层的粘附剥离过程。成对的粘料模块3的两个所述粘料轮31在同一平面，靠近的两对粘料模块3的两对所述粘料轮31所在的两个平面垂直。这样可以保证在粘料轮31表面胶层再对线料4表面石墨粘附时没有死角，对石墨中石墨烯层的剥离效果更好。In the specific design, as shown in FIG. 1, there is a gap between the two adhesive wheels 31 of the pair of adhesive modules 3 close to the position, so that the pair of adhesive wheels 31 can be prevented from being stuck near the position, which makes it impossible The adhesion and peeling process of the graphene layer on the surface of the strand 4 is completed. The two adhesive wheels 31 of the pair of adhesive modules 3 are in the same plane, and the two planes where the two pairs of adhesive wheels 31 of the two adjacent pairs of adhesive modules 3 are located are perpendicular. This can ensure that there is no dead angle when the adhesive layer on the surface of the adhesive wheel 31 is adhered to the graphite on the surface of the wire material 4, and the peeling effect of the graphene layer in the graphite is better.
以上所述仅为本发明的较佳实施例，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。The above are only preferred embodiments of the present invention and are not intended to limit the present invention. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection of the present invention Within range.
Claims (5)
- 一种线外圈石墨烯涂层装置，它包括在水平工作面上依次直线放置的涂胶模块(1)、涂料模块(2)、粘料模块(3)，所述涂胶模块(1)内部设计有胶料腔(11)，所述胶料腔(11)内装有胶水，所述涂胶模块(1)上加工有和胶料腔(11)左右连通的胶线孔，所述涂料模块(2)内部设计有石墨料腔(21)，所述石墨料腔(21)内装有石墨，所述涂料模块(2)上加工有和石墨料腔(21)左右连通的料线孔，其特征在于：待涂层的线料(4)依次从所述胶线孔、料线孔穿过；所述粘料模块(3)包括装配在转轴上的粘料轮(31)，所述粘料轮(31)的两侧分别装配有喷胶块(32)、切边刀(33)，所述喷胶块(32)内设计有可以在粘料轮(31)表面喷射出薄层胶料的喷胶结构，所述粘料轮(31)的环形面上加工有环形的线槽(34)，所述线槽(34)截面成弧形，所述线料(4)截面为圆形，所述线槽(34)的截面弧形与所述线料(4)截面的半径相同，所述切边刀(33)前部的刀锋外形与所述粘料轮(31)线槽(34)位置截面外形相同，所述切边刀(33)前部刀锋贴附在所述粘料轮(31)表面，喷胶块(32)喷射在所述粘料轮(31)表面的胶料形成胶层，当胶层旋转到所述切边刀(33)位置时，所述切边刀(33)的刀锋可以将胶料层切下，所述切边刀(33)侧边装配有将切下胶料层卷起的废胶轮(35)；所述粘料模块(3)成对使用，每对粘料模块(3)的两个粘料轮(31)的转轴相互平行，两个粘料轮(31)的靠近位置线槽(34)截面的弧形圆心在同一点，该线外圈石墨烯涂层装置包括有两对以上的粘料模块(3)；穿过所述料线孔的线料(4)依次从每对两个所述粘料轮(31)靠近位置的线槽(34)穿过，所述线料(4)装配在运动模块上，所述线料(4)向前运动的速度与所述粘料轮(31)表面的线速度相同。A graphene coating device for a line outer ring, which comprises a glue coating module (1), a paint module (2), an adhesive material module (3) placed in a line on a horizontal working surface in sequence, and the glue coating module (1) The interior is designed with a glue cavity (11), the glue cavity (11) is filled with glue, the glue application module (1) is processed with a glue line hole communicating with the glue cavity (11), and the paint A graphite material cavity (21) is designed inside the module (2), the graphite material cavity (21) is filled with graphite, and the coating module (2) is processed with a material line hole that communicates with the graphite material cavity (21), The utility model is characterized in that the thread material (4) to be coated passes through the glue thread hole and the thread hole in sequence; the adhesive material module (3) includes an adhesive material wheel (31) assembled on the rotating shaft, Both sides of the adhesive wheel (31) are respectively equipped with a glue spraying block (32) and a trimming knife (33). The glue spraying block (32) is designed to spray a thin layer on the surface of the adhesive wheel (31) In the glue spraying structure of the rubber material, an annular wire groove (34) is processed on the annular surface of the adhesive wheel (31), the wire groove (34) has an arc-shaped cross section, and the wire material (4) has a cross section Round, the arc of the cross section of the wire groove (34) and the radius of the cross section of the wire material (4) In the same way, the front edge of the edge cutter (33) is the same as the cross-sectional profile of the groove (34) of the adhesive wheel (31), and the front edge of the edge cutter (33) is attached to the On the surface of the adhesive wheel (31), a glue spraying block (32) sprays the glue on the surface of the adhesive wheel (31) to form an adhesive layer. When the adhesive layer rotates to the position of the edge cutter (33), the The edge of the edge cutter (33) can cut off the rubber layer. The side edge of the edge cutter (33) is equipped with a waste rubber wheel (35) that rolls up the cut rubber layer; the adhesive module ( 3) Used in pairs, the rotation axes of the two adhesive wheels (31) of each pair of adhesive modules (3) are parallel to each other, and the arc center of the cross section of the two adhesive wheels (31) near the position of the wire groove (34) is at At the same point, the wire outer ring graphene coating device includes more than two pairs of adhesive modules (3); the wire material (4) passing through the material wire hole is sequentially taken from each pair of the two adhesive wheels (3) 31) The thread groove (34) close to the position passes through, the thread material (4) is assembled on the movement module, the speed of the thread material (4) moving forward and the thread on the surface of the adhesive wheel (31) The speed is the same.
- 根据权利要求1所述的线外圈石墨烯涂层装置，其特征在于：所述涂 料模块(2)与靠近涂料模块(2)的第一对粘料模块之间装配有环料块(5)，所述环料块(5)为环形，所述线料(4)从所述环料块(5)中间通过。The graphene coating device for an outer ring according to claim 1, characterized in that: a ring block (5) is assembled between the coating module (2) and the first pair of adhesive modules close to the coating module (2) ), The loop material block (5) is ring-shaped, and the strand material (4) passes through the middle of the loop material block (5).
- 根据权利要求2所述的线外圈石墨烯涂层装置，其特征在于：所述环料块(5)与靠近环料块(5)的第一对粘料模块(3)之间还装配有上下成对使用的毛刷(6)，所述线料(4)从上下两个毛刷(6)之间通过。The graphene coating device for an outer ring according to claim 2, characterized in that the ring material block (5) is further assembled between the first pair of adhesive modules (3) close to the ring material block (5) There are upper and lower brushes (6) used in pairs, and the strand (4) passes between the upper and lower brushes (6).
- 根据权利要求1所述的线外圈石墨烯涂层装置，其特征在于：所述喷胶块(32)的侧边装配有气流块(36)，所述气流块(36)的出气口正对所述粘料轮(31)的表面。The graphene coating device for an outer ring according to claim 1, characterized in that: the side of the glue spraying block (32) is equipped with an airflow block (36), and the air outlet of the airflow block (36) is positive To the surface of the adhesive wheel (31).
- 根据权利要求1所述的线外圈石墨烯涂层装置，其特征在于：成对粘料模块(3)的两个所述粘料轮(31)靠近位置留有间隙，成对的粘料模块(3)的两个所述粘料轮(31)在同一平面，靠近的两对粘料模块(3)的两对所述粘料轮(31)所在的两个平面垂直。The graphene coating device for an outer ring according to claim 1, wherein the two adhesive wheels (31) of the pair of adhesive modules (3) leave a gap near the position, and the pair of adhesive The two adhesive wheels (31) of the module (3) are in the same plane, and the two planes where the two pairs of adhesive wheels (31) of the two adjacent pairs of adhesive modules (3) are located are perpendicular.
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| JP2015034102A (en) * | 2013-08-08 | 2015-02-19 | 学校法人中部大学 | Method for producing graphene film |
| CN103435035A (en) * | 2013-08-20 | 2013-12-11 | 常州二维碳素科技有限公司 | Device and method for continuous preparing and transferring graphene |
| CN204417133U (en) * | 2015-02-12 | 2015-06-24 | 成都格莱飞科技股份有限公司 | Prepare the device of transparent graphene conductive film |
| CN104925799A (en) * | 2015-06-30 | 2015-09-23 | 张峰 | Industrial graphene production device |
| CN206705685U (en) * | 2016-12-30 | 2017-12-05 | 深圳市大族元亨光电股份有限公司 | The device of extensive continuous transfer high quality monolayer graphene film |
| CN107457141A (en) * | 2017-09-18 | 2017-12-12 | 陕西浩合机械有限责任公司 | A kind of device in metal foil surface coating graphene |
| CN207325175U (en) * | 2017-09-18 | 2018-05-08 | 陕西浩合机械有限责任公司 | A kind of device in metal foil surface coating graphene |
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