WO2019117414A1 - Procédé de fabrication d'élément en aluminium ou en alliage d'aluminium anodisé ayant d'excellentes caractéristiques de résistance à la corrosion et d'isolation, et dispositif semi-conducteur traité en surface - Google Patents
Procédé de fabrication d'élément en aluminium ou en alliage d'aluminium anodisé ayant d'excellentes caractéristiques de résistance à la corrosion et d'isolation, et dispositif semi-conducteur traité en surface Download PDFInfo
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- WO2019117414A1 WO2019117414A1 PCT/KR2018/008077 KR2018008077W WO2019117414A1 WO 2019117414 A1 WO2019117414 A1 WO 2019117414A1 KR 2018008077 W KR2018008077 W KR 2018008077W WO 2019117414 A1 WO2019117414 A1 WO 2019117414A1
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- aluminum
- corrosion resistance
- semiconductor
- coating
- manufacturing apparatus
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 42
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 230000007797 corrosion Effects 0.000 title claims abstract description 39
- 238000005260 corrosion Methods 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 38
- 239000004065 semiconductor Substances 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 24
- 238000009413 insulation Methods 0.000 title abstract description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 58
- 238000000576 coating method Methods 0.000 claims description 39
- 239000011248 coating agent Substances 0.000 claims description 35
- 239000010407 anodic oxide Substances 0.000 claims description 27
- 230000003647 oxidation Effects 0.000 claims description 22
- 238000007254 oxidation reaction Methods 0.000 claims description 22
- 239000008151 electrolyte solution Substances 0.000 claims description 20
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 13
- 235000002906 tartaric acid Nutrition 0.000 claims description 13
- 239000011975 tartaric acid Substances 0.000 claims description 13
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 12
- 239000003792 electrolyte Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 235000006408 oxalic acid Nutrition 0.000 claims description 4
- 239000011247 coating layer Substances 0.000 abstract description 9
- 230000007547 defect Effects 0.000 abstract description 8
- 230000000052 comparative effect Effects 0.000 description 18
- 239000010410 layer Substances 0.000 description 12
- 239000007789 gas Substances 0.000 description 6
- 230000004888 barrier function Effects 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000007743 anodising Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- ZNEMGFATAVGQSF-UHFFFAOYSA-N 1-(2-amino-6,7-dihydro-4H-[1,3]thiazolo[4,5-c]pyridin-5-yl)-2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]ethanone Chemical compound NC=1SC2=C(CN(CC2)C(CC=2OC(=NN=2)C=2C=NC(=NC=2)NC2CC3=CC=CC=C3C2)=O)N=1 ZNEMGFATAVGQSF-UHFFFAOYSA-N 0.000 description 1
- AWFYPPSBLUWMFQ-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(1,4,6,7-tetrahydropyrazolo[4,3-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=C2 AWFYPPSBLUWMFQ-UHFFFAOYSA-N 0.000 description 1
- 229910016569 AlF 3 Inorganic materials 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- -1 aluminum-fluorine Chemical compound 0.000 description 1
- 238000002048 anodisation reaction Methods 0.000 description 1
- QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/06—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
- C25D11/08—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing inorganic acids
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28158—Making the insulator
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/06—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
- C25D11/10—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing organic acids
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02172—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing at least one metal element, e.g. metal oxides, metal nitrides, metal oxynitrides or metal carbides
- H01L21/02175—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing at least one metal element, e.g. metal oxides, metal nitrides, metal oxynitrides or metal carbides characterised by the metal
- H01L21/02178—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing at least one metal element, e.g. metal oxides, metal nitrides, metal oxynitrides or metal carbides characterised by the metal the material containing aluminium, e.g. Al2O3
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02551—Group 12/16 materials
- H01L21/02554—Oxides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
- H01L21/28506—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
- H01L21/28512—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table
- H01L21/28556—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table by chemical means, e.g. CVD, LPCVD, PECVD, laser CVD
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/288—Deposition of conductive or insulating materials for electrodes conducting electric current from a liquid, e.g. electrolytic deposition
Definitions
- the present invention relates to a method of forming an anodized film having excellent corrosion resistance and insulation characteristics on the surface of an aluminum or aluminum alloy member and an aluminum or aluminum alloy member formed with the anodized film produced by the method, And an inner member for a semiconductor or display manufacturing apparatus coated with an anodic oxide coating produced by the method.
- Vacuum plasma equipment is widely used in the field of semiconductor devices or other ultrafine shape implementations.
- Examples of using vacuum plasma equipment include plasma enhanced chemical vapor deposition (PECVD) equipment for forming a vapor deposition layer by chemical vapor deposition using plasma on a substrate, sputtering equipment for forming a vapor deposition layer by a physical method, And dry etching equipment for etching with a desired pattern.
- PECVD plasma enhanced chemical vapor deposition
- sputtering equipment for forming a vapor deposition layer by a physical method
- dry etching equipment for etching with a desired pattern.
- etching or ultrafine shape of a semiconductor device is realized by using a high-temperature plasma.
- a high temperature plasma is generated inside the vacuum plasma apparatus, so that the chamber and the internal parts thereof are damaged, and specific elements and contaminating particles are generated from the surface of the chamber and its parts, and the inside of the chamber is likely to be contaminated.
- a reaction gas used in a semiconductor manufacturing apparatus a corrosive gas including halogen elements such as Cl, F, Br, and O, N, H, S, C and the like is introduced, Corrosion resistance against the gases is required, and halogen plasma is also generated during the process of the semiconductor or liquid crystal manufacturing apparatus, so that plasma resistance is also required.
- halogen elements such as Cl, F, Br, and O, N, H, S, C and the like
- aluminum is mainly used as a material used for semiconductor equipment because of its conductivity, ease of manufacture, and availability at a reasonable price.
- aluminum readily reacts with halogens such as chlorine, fluorine and bromine to produce AlCl 3 , Al 2 Cl 6 , AlF 3 or AlBr 3 .
- the aluminum-fluorine compound may be peeled from the surface of the processing device component, causing corrosion of the component itself, and may serve as a source of fine particles of the processing chamber (and parts manufactured in the chamber).
- a preferred means of protecting the aluminum surface in a semiconductor device is an anodic alumina coating process, which is an electrolytic oxidation process to form an integral coating of aluminum oxide, which is relatively porous on the aluminum surface.
- anodic oxide film As a method for forming the anodic oxide film, a method of controlling the electrolyte at the time of forming the anodic oxide film at a low temperature or a method of electrolytically electrolyzing at a high current density is adopted.
- a method of controlling the electrolyte at the time of forming the anodic oxide film at a low temperature or a method of electrolytically electrolyzing at a high current density is adopted.
- Japanese Patent Publication No. 4660760 (Jan. 14, 2011) proposes a method of forming an anodic oxide film of high hardness by using an alcohol-added sulfuric acid-based electrolytic solution have.
- the prior art has a problem in that the control of the concentration change of the alcohol in the electrolytic solution by the anodizing treatment becomes troublesome.
- Korean Patent Registration No. 10-0664900 (April 04, 2007) proposes a method in which an anodic oxidation surface treatment is carried out using an electrolyte solution in which sulfuric acid is slightly added with sulfuric acid.
- the prior art is anodizing treatment conditions for obtaining an oxide film thickness of 50 ⁇ to 60 ⁇ in a semiconductor manufacturing apparatus, in order to form a film having a desired thickness, a large amount of defects And corrosion resistance is deteriorated.
- the main object of the present invention is to provide a method of manufacturing an anodized aluminum or aluminum alloy member and a surface-treated semiconductor device which are excellent in corrosion resistance and insulation properties against gases used in a semiconductor manufacturing process.
- the present invention provides a method for forming an oxide film of an aluminum-containing member of a semiconductor or display manufacturing apparatus, the method comprising the steps of: a) mixing sulfuric acid, Lt; / RTI > And b) forming an anodic oxide coating on the surface of the aluminum or aluminum alloy member using the electrolyte solution prepared in the step a), wherein the anodic oxide coating is formed on the surface of the aluminum or aluminum alloy member .
- the content of sulfuric acid, oxalic acid, and tartaric acid may be 9 to 11: 2.5 to 3.5: 0.3 to 0.7 in terms of weight ratio.
- the concentration of the electrolytic solution may be 1 wt% to 10 wt%.
- the applied current is 0.8 A / dm 2 To 1.7 A / dm < 2 >
- the temperature of the electrolytic solution may be from 8 [deg.] C to 22 [deg.] C.
- the anodized film thickness may be 50 [mu] m to 60 [mu] m.
- the present invention provides an aluminum or aluminum alloy member of a semiconductor or display manufacturing apparatus manufactured by the method of forming an oxide film of a member including aluminum in the semiconductor or display manufacturing apparatus.
- the present invention provides a member comprising aluminum of a semiconductor or display manufacturing apparatus coated with an anodic oxidation coating having a hardness of 370 Hv to 425 Hv and a withstand voltage of 1500 V to 2000 V, which may have corrosion resistance of 120 minutes or more.
- the present invention can provide a member including aluminum of a semiconductor or display manufacturing apparatus coated with an anodic oxide coating having a hardness of 370 Hv to 425 Hv and a corrosion resistance of 120 minutes or more, as well as a member having an withstand voltage of 1500 V to 2000 V , And an aluminum-containing member of a semiconductor or display manufacturing apparatus coated with an anodic oxide coating having a corrosion resistance of 120 minutes or more.
- the method of forming an anodic oxide coating having excellent corrosion resistance and insulation properties on the surface of aluminum or aluminum alloy member according to the present invention has an effect of forming a coating thickness of 50 ⁇ or more without defect in the anodic oxidation coating layer.
- FIG. 1 is a sectional view showing a schematic structure in which an anodic oxidation coating is formed on the surface of an aluminum or aluminum alloy member.
- Example 2 is an SEM image of Example 3 and Comparative Example 7, wherein (a) is an image obtained by measuring the cross-section of the oxide film of Comparative Example 7, and (b) is an image obtained by measuring the cross section of the oxide film of Example 3 .
- the present invention relates to a method for producing an aluminum or aluminum alloy member of a semiconductor or display manufacturing apparatus, in which an anodic oxide coating is formed on the surface thereof, comprising the steps of: a) preparing an electrolytic solution by mixing sulfuric acid, And b) forming an anodic oxide coating on the surface of the aluminum or aluminum alloy member using the electrolyte prepared in the step a).
- an electrolyte solution containing sulfuric acid, oxalic acid, and tartaric acid is used. This is compared with a conventional sulfuric acid bath using a mixed bath containing sulfuric acid, An anodic oxide film of 50 ⁇ ⁇ or more can be formed even if a low applied current is used. By using an applied current lower than that of the sulfuric acid bath, internal defects of the anodic oxide film are not generated and corrosion resistance can be increased.
- a water bath using a mixed bath containing aqua regia, tartaric acid, organic matters, and the like has a high corrosion resistance by forming a film which does not cause defects in the anodic oxidation film by applying a low applied current. Resulting in low hardness and insulation properties.
- a coating layer having a thickness of 50 ⁇ or more can be formed, which is superior in corrosion resistance, hardness, and insulation characteristics to the conventional anodic oxidation film formation method.
- the aluminum or aluminum alloy member formed with the anodized coating according to the present invention forms an anodic oxide coating by mixing sulfuric acid, anhydrous acid, and tartaric acid at a predetermined ratio, so that a coating layer having a thickness of 50 ⁇ or more is formed using a low applied current
- the corrosion resistance of the coating layer is improved to prolong the service life of the product, and since the insulation property is excellent, the occurrence rate of the arcing phenomenon of the semiconductor device or the display manufacturing apparatus connected to the high voltage power supply unit can be reduced.
- the content of sulfuric acid, sulfuric acid, and tartaric acid may be 9 to 11: 2.5 to 3.5: 0.3 to 0.7 in the step a), and the concentration of the electrolyte may be 1 to 10 wt% .
- the applied current is 0.8 A / dm 2
- the electrolytic solution may be 8 °C to 22 °C.
- the applied current is 0.8 A / dm 2
- the hardness, withstand voltage and corrosion resistance of the coating layer are lowered, and when it exceeds 1.7 A / dm 2 , the withstand voltage and corrosion resistance of the coating layer may be lowered.
- the withstand voltage and corrosion resistance of the coating layer may be deteriorated.
- the thickness of the anodized film may be 50 ⁇ or more, more preferably 50 ⁇ to 60 ⁇ .
- FIG. 1 is a sectional view showing a schematic structure in which an anodic oxidation coating is formed on the surface of an aluminum or aluminum alloy member.
- the barrier layer 6 having no pores 3 is formed first.
- the porous layer 5 having the pores 3 grows.
- the uppermost porous layer interface 2 which is in contact with the electrolyte solution 1, And the growth structure of the pores 3 and the cells 7 of the porous layer 5 due to the growth and erosion in accordance with the composition of the electrolyte, the temperature, and the applied current in the barrier layer 6 and the barrier layer 6.
- the present invention provides an aluminum or aluminum alloy member of a semiconductor or display manufacturing apparatus manufactured by a method of manufacturing an aluminum or aluminum alloy member of a semiconductor or display manufacturing apparatus in which the anodized film is formed on the surface thereof.
- a member including aluminum of a semiconductor or display manufacturing apparatus coated with an anodized coating having a hardness of 370 Hv to 425 Hv and a withstand voltage of 1500 V to 2000 V The corrosion resistance of the member may be 120 minutes or more.
- the anodic oxidation coating having a hardness of 370 Hv to 425 Hv and a corrosion resistance of 120 minutes or more can be coated on a member of a semiconductor or display manufacturing apparatus and can be coated with anodic oxidation having an withstand voltage of 1500 V to 2000 V and a corrosion resistance of 120 minutes or more
- the coating may be coated on a member of a semiconductor or display manufacturing apparatus.
- an anodized film is formed on the surface of the aluminum alloy according to the present invention.
- the electrolyte solution (solvent: DI Water) having a concentration of 5 wt% in which the weight ratio of sulfuric acid (95% sulfuric acid), water (100%
- Anodic oxidation treatment was carried out at 20 ° C and an applied current of 1 A / dm 2 to obtain an anodic oxide film.
- aluminum was used as a positive electrode and lead was used as a negative electrode (-).
- Example 2 The anodic oxidation coatings of Examples 2 to 8 were obtained in the same manner as in Example 1 except that the weight ratio of the electrolytic solution and the anodization treatment time were the same, Lt; / RTI >
- the anodic oxidation coatings of Comparative Examples 1 to 8 were obtained in the same manner as in Example 1 except that the weight ratio of the electrolytic solution and the anodic oxidation treatment time were the same, Lt; / RTI >
- the physical property analyzer was an external current type thickness gauge (Positector 6000, Defelsko), a Vickers hardness meter (HM 810-124K, Mitutoyo), and an electric strength meter (HIPOT TESTER 19052, Chroma).
- a PVC pipe having a diameter of 2 mm was attached to a specimen using a sealant, diluted to 5 wt% with hydrochloric acid, and put into a 2 ml flask. The time of occurrence was measured.
- Comparing Comparative Examples 1 to 8 it was found that when the sulfuric acid content was increased, the hardness was good, but the withstand voltage and corrosion resistance characteristics were deteriorated. When the sulfuric acid content was smaller than the weight ratio of the present invention, But it was confirmed that the withstand voltage and corrosion resistance characteristics were slightly lowered.
- the weight ratio of sulfuric acid, water, and tartaric acid in the electrolytic solution for forming the anodic oxide coating is preferably 9 to 11: 2.5 to 3.5: 0.3 to 0.7, and the thickness of the coating layer of 50 ⁇ or more and the appropriate hardness, withstand voltage and corrosion resistance It is confirmed that an anodic oxide film having a high dielectric constant can be obtained.
- Example 2 is an SEM image of Example 3 and Comparative Example 7, wherein (a) is an image obtained by measuring the cross-section of the oxide film of Comparative Example 7, and (b) is a cross section of the oxide film of Example 3 Image.
- (a) shows the formation of an anodic oxide film under the same conditions as those of the conventional sulfuric acid method, and it was confirmed that a large number of defects were present. In (b), it was confirmed that there was almost no defect.
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Abstract
La présente invention porte sur un procédé de formation, sur la surface d'un élément en aluminium ou en alliage d'aluminium, d'un film anodisé ayant d'excellentes caractéristiques de résistance à la corrosion et d'isolation, et un élément en aluminium ou en alliage d'aluminium comportant un film anodisé fabriqué par le procédé et, plus spécifiquement, sur un procédé de formation d'un film anodisé de dureté élevée sans défauts internes dans une couche de revêtement anodisée et de formation d'un film anodisé ayant d'excellentes caractéristiques de résistance à la corrosion et d'isolation; et sur un semi-conducteur revêtu d'un film anodisé fabriqué par le même procédé, ou un élément interne pour un dispositif de fabrication d'affichage.
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CN201880072917.9A CN111344836B (zh) | 2017-12-11 | 2018-07-17 | 耐腐蚀性及绝缘特性优秀的阳极氧化包含铝的构件及其的氧化膜形成方法 |
US16/765,093 US20200354850A1 (en) | 2017-12-11 | 2018-07-17 | Method for manufacturing anodized aluminum or aluminum alloy member having excellent corrosion resistance and insulation characteristics, and surface-treated semiconductor device |
SG11202003710SA SG11202003710SA (en) | 2017-12-11 | 2018-07-17 | Method for manufacturing anodized aluminum or aluminum alloy member having excellent corrosion resistance and insulation characteristics, and surface-treated semiconductor device |
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KR10-2017-0169126 | 2017-12-11 | ||
KR1020170169126A KR102443973B1 (ko) | 2017-12-11 | 2017-12-11 | 내부식성 및 절연특성이 우수한 양극산화된 알루미늄 또는 알루미늄 합금 부재의 제조방법 및 표면처리된 반도체 장치 |
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PCT/KR2018/008077 WO2019117414A1 (fr) | 2017-12-11 | 2018-07-17 | Procédé de fabrication d'élément en aluminium ou en alliage d'aluminium anodisé ayant d'excellentes caractéristiques de résistance à la corrosion et d'isolation, et dispositif semi-conducteur traité en surface |
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US (1) | US20200354850A1 (fr) |
KR (1) | KR102443973B1 (fr) |
SG (1) | SG11202003710SA (fr) |
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WO (1) | WO2019117414A1 (fr) |
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KR100820744B1 (ko) * | 2007-09-05 | 2008-04-11 | (주)제이스 | 금속 모재의 텅스텐 코팅방법 |
JP4796464B2 (ja) * | 2005-11-17 | 2011-10-19 | 株式会社神戸製鋼所 | 耐食性に優れたアルミニウム合金部材 |
JP2013084954A (ja) * | 2011-09-30 | 2013-05-09 | Fujifilm Corp | 発光装置 |
KR101592147B1 (ko) * | 2015-08-19 | 2016-02-04 | 이대석 | 알루미늄 기판의 산화막 형성방법 |
JP5992208B2 (ja) * | 2012-05-30 | 2016-09-14 | 富士フイルム株式会社 | 熱電変換素子の製造方法 |
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JPS6081817A (ja) * | 1983-10-13 | 1985-05-09 | 松下電器産業株式会社 | アルミニウム電解コンデンサ用陽極箔の製造方法 |
JP4194143B2 (ja) * | 1998-10-09 | 2008-12-10 | 株式会社神戸製鋼所 | ガス耐食性とプラズマ耐食性に優れたアルミニウム合金材 |
KR100664900B1 (ko) | 2004-07-15 | 2007-01-04 | 주식회사 코미코 | 내열균열성이 우수한 양극산화된 알루미늄 혹은 알루미늄 합금 부재의 제조방법과 알루미늄 혹은 알루미늄 합금 부재 |
JP4660760B2 (ja) | 2005-06-02 | 2011-03-30 | 国立大学法人広島大学 | アルミニウム又は/及びアルミニウム合金の陽極酸化皮膜の形成方法およびその方法により形成される陽極酸化皮膜 |
JP4824430B2 (ja) * | 2006-02-28 | 2011-11-30 | 富士フイルム株式会社 | ナノ構造体の製造方法 |
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KR20150092948A (ko) * | 2014-02-06 | 2015-08-17 | 인 경 황 | 알루미늄 다이캐스팅 소재의 표면처리방법 |
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JP4796464B2 (ja) * | 2005-11-17 | 2011-10-19 | 株式会社神戸製鋼所 | 耐食性に優れたアルミニウム合金部材 |
KR100820744B1 (ko) * | 2007-09-05 | 2008-04-11 | (주)제이스 | 금속 모재의 텅스텐 코팅방법 |
JP2013084954A (ja) * | 2011-09-30 | 2013-05-09 | Fujifilm Corp | 発光装置 |
JP5992208B2 (ja) * | 2012-05-30 | 2016-09-14 | 富士フイルム株式会社 | 熱電変換素子の製造方法 |
KR101592147B1 (ko) * | 2015-08-19 | 2016-02-04 | 이대석 | 알루미늄 기판의 산화막 형성방법 |
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TW201928125A (zh) | 2019-07-16 |
SG11202003710SA (en) | 2020-05-28 |
KR102443973B1 (ko) | 2022-09-16 |
TWI772489B (zh) | 2022-08-01 |
CN111344836A (zh) | 2020-06-26 |
US20200354850A1 (en) | 2020-11-12 |
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