WO2019069362A1 - Préparation cosmétique à base d'huile - Google Patents

Préparation cosmétique à base d'huile Download PDF

Info

Publication number
WO2019069362A1
WO2019069362A1 PCT/JP2017/035951 JP2017035951W WO2019069362A1 WO 2019069362 A1 WO2019069362 A1 WO 2019069362A1 JP 2017035951 W JP2017035951 W JP 2017035951W WO 2019069362 A1 WO2019069362 A1 WO 2019069362A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil
component
present
based cosmetic
mass
Prior art date
Application number
PCT/JP2017/035951
Other languages
English (en)
Japanese (ja)
Inventor
博久 日比
Original Assignee
株式会社日本色材工業研究所
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社日本色材工業研究所 filed Critical 株式会社日本色材工業研究所
Priority to PCT/JP2017/035951 priority Critical patent/WO2019069362A1/fr
Priority to JP2019546433A priority patent/JP7038133B2/ja
Publication of WO2019069362A1 publication Critical patent/WO2019069362A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips

Definitions

  • the present invention relates to an oily cosmetic.
  • Patent Document 1 an oil-in-water emulsion cosmetic containing a macrocapsule containing a pigment is known.
  • Patent Document 1 When the cosmetic is applied to the skin, the shear force acts on the macrocapsule to disintegrate the macrocapsule, releasing the pigment from the macrocapsule to change its color.
  • oil-in-water emulsion cosmetic contains a large amount of aqueous components, there is a problem that it is easy to dry and that gloss does not easily occur, for example, on the lips depending on the site to be applied.
  • the present invention has been made to solve the above-mentioned problems, and it is an object of the present invention to provide an oil-based cosmetic which changes its color rapidly and sufficiently upon application.
  • the present invention comprises the following components (a) to (e): (a) liquid oil, (b) solid oil or oil gelling agent, (c) microcapsules containing a pigment, (d) aqueous component, and (E) It is intended to provide an oil-based cosmetic comprising a lipophilic nonionic surfactant and / or a water repellent oil.
  • the component (d) is preferably water and / or a polyol.
  • the content of the component (d) is preferably 0.1 to 15% by mass.
  • the content of the component (e) is preferably 1 to 10% by mass.
  • the content of the component (a) is 40 to 95% by mass
  • the content of the component (b) is 0.1 to 20% by mass
  • the content of the component (c) Is preferably 0.1 to 10% by mass.
  • the oil-based cosmetic according to the present invention can be rapidly and sufficiently color-changed at the time of application while maintaining the characteristics unique to oil-based cosmetics.
  • the present invention comprises the following components: (a) to (e): (a) liquid oil, (b) solid oil or oil gelling agent, (c) microcapsules containing a pigment, (d) an aqueous component, and e) An oil-based cosmetic comprising a lipophilic nonionic surfactant and / or a water repellent oil.
  • the “liquid oil” of the component (a) in the present invention is an oil which is liquid at normal temperature to the manufacturing temperature of cosmetics (25 to 80 ° C.), and is a liquid oil generally used for cosmetics and quasi-drugs. It is not particularly limited as long as
  • the liquid oil used in the present invention includes, for example, liquid paraffin, hydrocarbons such as squalane, isopropyl myristate, octyldodecyl myristate, di 2-ethylhexyl sebacate, neopentyl glycol di 2-ethylhexanoate, dicapric acid Neopentyl glycol, glyceryl tri-2-ethylhexanoate, diglyceryl triisostearate, pentaerythritol tetra-2-ethylhexanoate, dipentaerythritol 2-ethylhexanoic acid, trimethylolpropane tri-2-eth
  • the content of the liquid oil (a) in the oil-based cosmetic of the present invention is preferably 40 to 95% by mass, particularly preferably 50 to 85% by mass, based on 100% of the total mass of the oil-based cosmetic. %. If it is said range, the cosmetic
  • the "solid oil” of the component (b) in the present invention is not particularly limited as long as it is a solid oil generally used for cosmetics and quasi drugs.
  • solid oils used in the present invention include fats and oils such as hardened oil and moclaw; hydrocarbons such as ceresin, microcrystalline wax, paraffin wax and polyethylene wax; waxes such as beeswax, candelilla wax and carnauba wax; Examples thereof include acids and higher fatty acids such as behenic acid; and higher alcohols such as cetanol.
  • semi-solid oil can also be used as a solid oil of the component (b) in this invention.
  • semi-solid oil components petrolatum, cholesteryl hydroxystearate, hydrogenated castor oil stearic acid, dipentaerythritol fatty acid (12-hydroxystearic acid, stearic acid, rosin acid etc.) ester and the like can be used.
  • the solid oil in the present invention can be used by optionally selecting one or more of the above.
  • examples of the oil gelling agent used in the present invention include crosslinked organopolysiloxane polymers, 12-hydroxystearic acid, dextrin fatty acid esters, metal soaps, organically modified clay minerals and the like.
  • the oil gelling agent in the present invention can be used by optionally selecting one or more of the above.
  • dextrin fatty acid ester an ester of dextrin and a higher fatty acid having 8 to 22 carbon atoms is preferable. Specifically, dextrin laurate, dextrin myristate, dextrin palmitate, dextrin stearate, dextrin behenate dextrin, coconut oil fatty acid Dextrin etc. are mentioned. These dextrin fatty acid esters are commercially available and, for example, Leopearl KE2, Leopearl KL2 and Leopearl TT2 (all manufactured by Chiba Powder Co., Ltd.) can be mentioned as preferable commercially available products.
  • the content of (b) solid oil or oil gelling agent in the oil-based cosmetic of the present invention is preferably 0.1 to 20% by mass, based on 100% of the total mass of the oil-based cosmetic, Preferably, it is 1 to 15% by mass. If it is said range, the cosmetic
  • the "pigment-containing microcapsule” of the component (c) in the present invention is a particle having a core containing at least one pigment and one or more outer coating layers.
  • the average particle size of the microcapsules containing the pigment in the present invention is preferably 10 to 300 ⁇ m, more preferably 10 to 70 ⁇ m.
  • the microcapsules containing a pigment in the present invention can be produced by methods of pelletizing, granulation, coating, which are known to those skilled in the art of coating / encapsulation, for example, WO 2011/027960.
  • the pigment and the polymer are dispersed in a solvent, the mixed solution is spray-dried to prepare core particles, and the obtained core particles and the second pigment are used in the same procedure as described in It can be manufactured by repeating.
  • the pigment inorganic pigments and organic pigments usually used for cosmetics can be used, and preferably, inorganic pigments such as iron oxide, titanium dioxide, zinc oxide and the like can be used.
  • microcapsules containing a pigment that can be used in the present invention are commercially available, and commercially available products can also be used in the present invention.
  • Commercially available products include, for example, MAGICOLOR (registered trademark) (Biogenics, Inc.), TagraCap (trademark) (TagraBiotechnology), Cameleon Caps (trademark) (TagraBiotechnology), MicroBeads (trademark) (Salvona Technologies), and the like.
  • the content of the microcapsule (c) containing the pigment in the oil-based cosmetic of the present invention is preferably 0.1 to 10% by mass, particularly preferably 100% by mass, based on 100% of the total mass of the oil-based cosmetic. , 1 to 8% by mass. Within the above range, a good color change of the cosmetic can be provided.
  • the "aqueous component" of the component (d) in the present invention is not particularly limited as long as it is an aqueous component generally used for cosmetics and quasi-drugs, but preferably either water or a polyol Or mixtures thereof can be used.
  • water: polyol 1: 5 to 5: 1 (mass ratio) is preferable, and 1: 3 to It is particularly preferable to use 3: 1 (mass ratio).
  • a polyhydric alcohol having preferably 2 to 8 carbon atoms, more preferably a polyhydric alcohol having 3 to 6 carbon atoms can be used.
  • the polyol in the present invention include glycerol, pentaerythritol, trimethylolpropane, ethylene glycol, propylene glycol, 1,3-butylene glycol, 1,3-propanediol, pentylene glycol, hexylene glycol, isoprene glycol, and di- Propylene glycol, diethylene glycol, 1,2-pentanediol, ethylhexyl glycerin, caprylyl glycol, polyethylene glycol, diglycerol, polyglycerol, glycol ether and the like can be mentioned.
  • the polyol in the present invention can be used by optionally selecting one or two or more of the above.
  • the content of the aqueous component (d) in the oil-based cosmetic of the present invention is preferably 0.1 to 15% by mass, particularly preferably 0. 1 to 15% by mass, based on 100% of the total mass of the oil-based cosmetic. It is 5 to 10% by mass. Within the above range, a good color change of the cosmetic can be provided.
  • lipophilic nonionic surfactant in the present invention means a nonionic surfactant having an HLB of 6 or less.
  • lipophilic nonionic surfactants in the present invention include sucrose fatty acid esters such as sucrose hexaisostearate (HLB 3.5), sucrose pentahydroxystearate (HLB 3.9), and polyglyceryl-2 isostearate (HLB).
  • polyglyceryl diisostearate (HLB 5.0), POE (2) stearyl ether (HLB 4.0), self-emulsifying propylene glycol monostearate (HLB 4.0), glyceryl myristate (HLB 3) .5), glyceryl monostearate (HLB 4.0), self-emulsifying glyceryl monostearate (HLB 4.0), glyceryl monoisostearate (HLB 4.0), glyceryl monooleate (HLB 2.5), Tristearin Hexaglyceryl (HLB 2.5), Decaglyceryl Pentastearate (HLB 3.5), Decaglyceryl Pentaisostearate (HLB 3.5), Decaglyceryl Pentaoleate (HLB 3.5), Monostearic acid Sorbitan (HLB 4.7), sorbitan tristearate (HLB 2.1), sorbitan monoisostearate (HLB 5.0), sorbit
  • the component (e) "water-retaining oil” in the present invention means an oil which can hold water equal to or more than its own weight, that is, a water-retaining capacity of 100% or more.
  • Examples of the water repellent oil in the present invention include cholesteryl hydroxystearate, dipentaerythrityl tripolyhydroxystearate, lauroyl glutamic acid di (phytosteryl / octyldodecyl) and the like.
  • the lipophilic nonionic surfactant in the present invention can be used by optionally selecting one or two or more of the above.
  • any one of a lipophilic nonionic surfactant and an aqueous oil, or a mixture thereof can be used.
  • the content of the (e) lipophilic nonionic surfactant and / or the water-repellent oil in the oil-based cosmetic of the present invention is preferably 1 to 10% by mass, based on 100% of the total mass of the oil-based cosmetic. And particularly preferably 3 to 8% by mass. If it is said range, the cosmetics excellent in color change, usability, and stability can be obtained.
  • the oily cosmetic composition of the present invention is a range not to impair the effects of the present invention, in addition to the above components (a) to (e), other components usually used in cosmetics, quasi-drugs, pharmaceutical compositions, etc. Can be appropriately blended.
  • the other components include powder components, surfactants other than the component (e), moisturizers, thickeners, water-soluble polymers, film-forming agents, water-insoluble polymers, dyes, pigments, Pearls, lower alcohols, sugars, ultraviolet light absorbers, amino acids, vitamins, skin lightening agents, skin enhancers, agents for promoting blood circulation, anti-inflammatory agents, etc., plant extracts, organic acids, organic amines, sequestering agents And pH adjusters, antioxidants, antibacterial agents, preservatives, astringents, refreshing agents, perfumes and the like.
  • the method for producing the oil-based cosmetic of the present invention is not particularly limited, and the oil-based cosmetic can be produced using a mixer or a grinder used for mixing, dispersing, and pulverizing a conventional oil-based cosmetic. Although it may be prepared by mixing all the components to be formulated in the oily cosmetic composition of the present invention at one time, it is preferable to mix the components (a), (b), (d) and (e) and then By adding and disperse
  • Examples of the shape of the oily cosmetic composition of the present invention include liquid, creamy and solid.
  • Specific product forms of the oil-based cosmetic of the present invention include, but are not limited to, for example, lipstick, lip gloss, lip cream, lip substrate, eye shadow, eye liner, cheek, foundation, concealer and the like.
  • the numerical values in the table are% by mass.
  • A Heat and dissolve an oily raw material and a surfactant (components 6 to 9) at 100 ° C.
  • B Add the aqueous component (components 10 to 13) to A and mix uniformly.
  • C Add pigment capsule (component 1 to 2), pigment and pearlescent agent (components 3 to 5), and other components (component 14) to B and mix uniformly.
  • D C was dissolved by heating to 80 ° C. to degas, filled into a container, and cooled to obtain lip gloss.
  • Emollient feeling of lips Ten panelists scored moisturizing feeling when applying each sample to the lips based on the following score. The average value of the scoring result by 10 panelists was evaluated as an evaluation value according to the following criteria. (Score) 0 point: very dry 1 point: slightly dry 2 points: neither good 3 points: slightly moist 4 points: very moist (evaluation criteria) ⁇ : 3 or more and less than 4 points ⁇ : 1 or more and less than 3 points ⁇ : less than 1 point
  • A Heat and dissolve oil-based material and surfactant / hydrophobic oil (components 8 to 22) at 100 ° C.
  • B Add the aqueous component (components 23 to 27) to A and mix uniformly.
  • C The powder component (components 6 to 7) is dispersed in B by a roll mill.
  • D Add pigment capsules (components 1 to 3), pearlescent agents (components 4 to 5) and other components (components 28 to 29) to C and mix uniformly.
  • E D was dissolved by heating to 80 ° C. to defoam, poured into a mold, and solidified by cooling to obtain a stick-like lipstick.
  • an oil-based cosmetic which exhibits a rapid and sufficient color change while maintaining excellent stability and usability. It became clear that it could be obtained.
  • cosmetic products such as lipsticks, lip glosses, eye shadows, cheeks, foundations, etc. that are excellent in gloss and feeling of use and that change color upon application.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une préparation cosmétique à base d'huile qui contient: (a) un composant d'huile liquide; (b) une huile solide ou un gélifiant d'huile; (c) une microcapsule contenant un pigment; (d) un composant aqueux; et (e) un tensioactif non ionique lipophile et/ou une huile de rétention d'eau.
PCT/JP2017/035951 2017-10-03 2017-10-03 Préparation cosmétique à base d'huile WO2019069362A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/JP2017/035951 WO2019069362A1 (fr) 2017-10-03 2017-10-03 Préparation cosmétique à base d'huile
JP2019546433A JP7038133B2 (ja) 2017-10-03 2017-10-03 油性化粧料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2017/035951 WO2019069362A1 (fr) 2017-10-03 2017-10-03 Préparation cosmétique à base d'huile

Publications (1)

Publication Number Publication Date
WO2019069362A1 true WO2019069362A1 (fr) 2019-04-11

Family

ID=65994728

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2017/035951 WO2019069362A1 (fr) 2017-10-03 2017-10-03 Préparation cosmétique à base d'huile

Country Status (2)

Country Link
JP (1) JP7038133B2 (fr)
WO (1) WO2019069362A1 (fr)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0525030A (ja) * 1991-07-24 1993-02-02 Club Kosumechitsukusu:Kk 皮膚化粧料
JP2001072887A (ja) * 1999-07-06 2001-03-21 Kao Corp カプセル化着色顔料
JP2004217612A (ja) * 2002-10-31 2004-08-05 Kansai Koso Kk 色変わり化粧料及びクレンジング用セット化粧料
JP2005035910A (ja) * 2003-07-18 2005-02-10 Suzuki Yushi Kogyo Kk ｐＨ感受溶解性マイクロカプセル及びこれを含有する化粧料
JP2008500341A (ja) * 2004-05-25 2008-01-10 イーエルシー マネージメント エルエルシー 新規なカラーコスメチック組成物
JP2008528686A (ja) * 2005-02-03 2008-07-31 ザ プロクター アンド ギャンブル カンパニー 少ない遊離染料を有する着色剤を含む化粧品組成物
JP2011079804A (ja) * 2009-10-09 2011-04-21 Daito Kasei Kogyo Kk 顔料内包マイクロカプセル及びこれを配合した化粧料
JP2012153684A (ja) * 2011-01-21 2012-08-16 Daito Kasei Kogyo Kk 顔料内包マイクロカプセル及びこれを配合した化粧料
JP2016500113A (ja) * 2012-11-30 2016-01-07 ロレアル 変色用組成物
JP2016175878A (ja) * 2015-03-20 2016-10-06 三粧化研株式会社 皮膚洗浄剤

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9186305B1 (en) * 2014-05-19 2015-11-17 Shiseido Company, Ltd. Sunscreen products in which excessive whiteness due to titanium dioxide and zinc oxide is visually masked upon skin application

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0525030A (ja) * 1991-07-24 1993-02-02 Club Kosumechitsukusu:Kk 皮膚化粧料
JP2001072887A (ja) * 1999-07-06 2001-03-21 Kao Corp カプセル化着色顔料
JP2004217612A (ja) * 2002-10-31 2004-08-05 Kansai Koso Kk 色変わり化粧料及びクレンジング用セット化粧料
JP2005035910A (ja) * 2003-07-18 2005-02-10 Suzuki Yushi Kogyo Kk ｐＨ感受溶解性マイクロカプセル及びこれを含有する化粧料
JP2008500341A (ja) * 2004-05-25 2008-01-10 イーエルシー マネージメント エルエルシー 新規なカラーコスメチック組成物
JP2008528686A (ja) * 2005-02-03 2008-07-31 ザ プロクター アンド ギャンブル カンパニー 少ない遊離染料を有する着色剤を含む化粧品組成物
JP2011079804A (ja) * 2009-10-09 2011-04-21 Daito Kasei Kogyo Kk 顔料内包マイクロカプセル及びこれを配合した化粧料
JP2012153684A (ja) * 2011-01-21 2012-08-16 Daito Kasei Kogyo Kk 顔料内包マイクロカプセル及びこれを配合した化粧料
JP2016500113A (ja) * 2012-11-30 2016-01-07 ロレアル 変色用組成物
JP2016175878A (ja) * 2015-03-20 2016-10-06 三粧化研株式会社 皮膚洗浄剤

Also Published As

Publication number Publication date
JPWO2019069362A1 (ja) 2020-10-22
JP7038133B2 (ja) 2022-03-17

Similar Documents

Publication Publication Date Title
JP6752650B2 (ja) 油中水型乳化固形化粧料
KR100697484B1 (ko) 액정 조성물 및 화장료
JPH07309717A (ja) 固体の親油性組成物およびその製造方法
KR20180120774A (ko) 수용성 염료를 포함하는 화장용 조성물
EP3769747A1 (fr) Produit cosmétique de type bâton à libération d'eau
CN112739312A (zh) 油包水型乳化固体化妆品
WO2006003733A1 (fr) Composition contenant une particule huileuse pour usage externe
JP3024084B2 (ja) 揮発性化合物とフェニル化シリコーン油との組み合わせおよび親水性成分を含有する組成物、およびその用途
JPH1067645A (ja) 親水性成分及び揮発性化合物とペースト状脂肪化合物との混合物を含有する組成物及び前記混合物の使用
JP5088766B2 (ja) 油の微細分散組成物
JP6109592B2 (ja) 油性化粧料
TW201900142A (zh) 水中油型乳化組合物
JP6170312B2 (ja) 含水粉末化粧料
JP2005036001A (ja) 油性粒子を含有する外用組成物
WO2018212222A1 (fr) Produit cosmétique en émulsion de type huile dans eau
JP7038133B2 (ja) 油性化粧料
JP2001072532A (ja) 水中油型乳化化粧料
JP2003113033A (ja) 油中水型化粧料
JP2010132620A (ja) 油中水型乳化化粧料
JP2003160430A (ja) 油性化粧料
WO2023127492A1 (fr) Préparation cosmétique sous forme d'émulsion eau-dans-huile
JP2003137734A (ja) 油中水型乳化口紅用組成物
JP2005089415A (ja) 固形状油性化粧料
WO2024014316A1 (fr) Matériau cosmétique solide émulsifié eau-dans-huile
CN117355291A (zh) 油包水型乳化固体化妆品

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17927958

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2019546433

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17927958

Country of ref document: EP

Kind code of ref document: A1