WO2019062800A1 - 玻璃基板的制备方法、玻璃基板及智能移动终端 - Google Patents

玻璃基板的制备方法、玻璃基板及智能移动终端 Download PDF

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WO2019062800A1
WO2019062800A1 PCT/CN2018/107887 CN2018107887W WO2019062800A1 WO 2019062800 A1 WO2019062800 A1 WO 2019062800A1 CN 2018107887 W CN2018107887 W CN 2018107887W WO 2019062800 A1 WO2019062800 A1 WO 2019062800A1
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glass substrate
optical effect
effect film
film
protective layer
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PCT/CN2018/107887
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English (en)
French (fr)
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罗海宝
曾翠霞
彭世晓
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惠州Tcl移动通信有限公司
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Publication of WO2019062800A1 publication Critical patent/WO2019062800A1/zh

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment

Definitions

  • the present application relates to the field of intelligent terminals, and in particular, to a method for preparing a glass substrate, a glass substrate, and an intelligent mobile terminal.
  • the traditional mobile phone covers are mostly made of metal or plastic. Therefore, when the functional innovation is gradually limited by the technical constraints, the major mobile phone giants have turned to the appearance of innovation, the appearance of mobile phone glass casing, Bringing consumers a different visual experience, including 2D, 2.5D and 3D different appearance glasses, and with the promotion of the subsequent 5G, due to the electromagnetic shielding of the metal casing, which affects the communication signal of the mobile phone, the glass The application of the material shell will become more and more extensive.
  • the color is generally single, and the color cannot be changed in real time.
  • optical coating it is usually realized by optical coating.
  • the traditional coating process is optical coating on the PET film. Then cover the bottom color, and finally apply a protective layer, and then attach the film to the glass through optical transparent glue, so the transmittance of PET is very high, not only the cost is relatively high, the process is complicated, and some colors are difficult to realize. .
  • the technical problem to be solved by the present application is to provide a method for preparing a glass substrate, a glass substrate and an intelligent mobile terminal, which solves the problem of high cost of optical coating on the glass, lack of a bright color range, and difficulty in realizing color change.
  • an intelligent mobile terminal which comprises a glass substrate, the glass substrate comprises: an optical effect film, and the optical effect film comprises a three-dimensional regular arrangement of nano microspheres.
  • Photonic crystal structure the size of the nano microspheres is 100-1000 nm; the protective layer is disposed on the first side of the optical effect film; the second side of the optical effect film is bonded to the glass substrate, and the optical effect film is optically transparent The second side of the film is attached to the glass substrate.
  • a glass substrate which comprises: an optical effect film comprising a photonic crystal structure formed by three-dimensional regular arrangement of nano microspheres; a protective layer; The first surface of the optical effect film is disposed; the second surface of the optical effect film is bonded to the glass substrate.
  • another technical solution adopted by the present application is to provide a method for preparing a glass substrate, which comprises: preparing an optical effect film comprising a photonic crystal structure formed by three-dimensional regular arrangement of nano microspheres. Providing protection on the first side of the optical effect film; bonding the second side of the optical effect film to the glass substrate.
  • FIG 3 is a schematic structural view of another embodiment of a glass substrate provided by the present application.
  • polystyrene silicon dioxide, ferroferric oxide, polymethyl methacrylate (PMMA), polyethyl acrylate (PEA), indium tin oxide (ITO), arsenic trioxide (ATO)
  • the core materials such as gold and silver
  • the core material and the crosslinking agent are mixed at 60-90 ° C, made into nano-spheres and dried, and then the nano-spheres are added with an organic solvent or specific
  • a mixture having a certain fluidity is formed, coated on the base film (such as a release film), and the coated base film is placed in a UV curing box, and taken out after curing at 200-350 nm, and the cured base film is removed.
  • the optical effect film is obtained by pressing with a micro-stress roll to flatten the upper and lower surfaces thereof.
  • the nano microspheres in this embodiment include a core layer, a transition layer, and a shell layer.
  • the core layer has a high refractive index and a high optical reflectance
  • the shell has a low refractive index. Therefore, the optical effect can be improved by increasing the refractive index ratio of the core layer to the shell layer according to actual needs.
  • the optical effect film prepared by using the nano microspheres in the embodiment changes its color with the change of the incident angle of the light, thereby achieving a good color effect similar to the optical coating, and can be presented from different angles. Different color effects and a wider range of colors.
  • the core material of the above nano microspheres comprises an organic material or an inorganic material
  • the shell material of the nano microspheres comprises a polymer elastomer material
  • the size of the nano microspheres prepared by the above method is 100-1000 nm.
  • the optical effect film only needs to face the user side (ie, the second side, the same below) needs to display the colorful effect, so it is necessary to protect the side facing the user (ie, the first side, the same below).
  • the release protective film is first peeled off, and then the PET film is pasted on the first side of the optical effect film using an optically transparent adhesive.
  • the PET film only functions to protect the optical effect film, and thus The light transmittance of the PET film is not required, which saves cost.
  • the conventional PET film needs to achieve a light transmittance of more than 90% in order to display a bright color effect.
  • the transmittance of the PET film can be any light transmittance PET film, for example, 90%, 70. % or 50% or even lower.
  • the PET film in this embodiment also has an explosion-proof effect.
  • the first side of the optical effect film may be covered with ink for protection, and the operation is simpler and lower than the above-described protection by attaching the PET film.
  • the step of bonding the second surface of the optical effect film to the glass substrate comprises: bonding the second surface of the optical effect film to the glass substrate using an optically transparent adhesive, and the glass substrate in the embodiment comprises 2D glass. , 2.5D glass and 3D glass.
  • FIG. 2 is a schematic structural view of an embodiment of a glass substrate provided by the present application.
  • the glass substrate includes: glass S201, optical transparent adhesive S204, optical effect film S202, ordinary double-sided tape S205, and PET film S203.
  • the optical effect film S202 is obtained by any of the above preparation methods.
  • the specific structure of the glass substrate comprises: bonding the first surface of the ordinary double-sided tape S205 with the PET film S203, the PET film S203 protecting the optical effect film S202, and the glass S201 and the optical effect film through the optical transparent adhesive S204
  • the second side of the S202 is bonded, wherein the glass S201 comprises 2D glass, 2.5D glass or 3D glass, and the user can see the colorful effect of the optical effect film S202 through the glass S201 and through the optical transparent adhesive S204, and Different colors are displayed depending on the angle of incidence of the light and the angle of view of the user.
  • FIG. 3 is a schematic structural diagram of another embodiment of a glass substrate provided by the present application.
  • the glass substrate includes glass S301, optical transparent adhesive S304, optical effect film S302, and ink S303.
  • the optical effect film S202 is obtained by any of the above preparation methods.
  • the first surface of the optical effect film S302 is coated with an ink S303, and the ink S303 protects the optical effect film S302.
  • the second surface of the glass S301 and the optical effect film S302 is bonded by the optical transparent adhesive S304.
  • the glass S301 comprises 2D glass, 2.5D glass or 3D glass, and the user can see through the glass S301 and through the optical transparent adhesive S304.
  • the color effect of the optical effect film S302 is different depending on the incident angle of the light and the angle of view of the user.
  • the glass substrate prepared above can be used for a back cover of a smart mobile terminal, such as a mobile phone, a tablet computer, or the like.
  • the glass substrate of the intelligent mobile terminal of the present application can achieve a bright effect similar to the optical coating, and overcome the bright effect of the optical coating.
  • Some colors are difficult to realize and the cost is high, and the viewing is from different angles. It can also present different color effects and a wider range of colors, giving consumers more choices and benefits to enhance the user experience.

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Abstract

一种玻璃基板的制备方法、玻璃基板及智能移动终端,包括:制备光学效果薄膜,光学效果薄膜包括具有纳米微球三维规整排列形成的光子晶体结构;在光学效果薄膜的第一面设置保护层;将光学效果薄膜的第二面贴合在玻璃基板上。采用该方案可以很好的实现类似光学镀膜的炫彩效果,且克服了光学镀膜的炫彩效果有些颜色难以实现及成本高的困难,从不同角度观看还可以呈现不同的颜色效果,且颜色范围也更丰富,给消费者带来了更多选择和实惠,提升用户体验。

Description

玻璃基板的制备方法、玻璃基板及智能移动终端 【技术领域】
本申请涉及智能终端领域,特别是涉及一种玻璃基板的制备方法、玻璃基板及智能移动终端。
【背景技术】
随着智能手机的设计越发趋同,传统手机盖板大多用的是金属或者塑料,因此,在功能创新方面受技术限制渐遇瓶颈时,各大手机巨头纷纷转向外观创新,手机玻璃外壳的出现,给消费者带来了不一样的视觉体验,包括2D、2.5D和3D不同的外观玻璃,而且,随着后续5G的推广应用,由于金属外壳有电磁屏蔽,从而影响到手机的通信信号,玻璃材质外壳的应用会越来越广泛。
但是,目前玻璃除了能实现高亮效果外,色彩一般都比较单一,且颜色无法实时变换,要实现炫彩效果,通常是通过光学镀膜来实现,传统镀膜工艺是在PET膜上做光学镀膜,然后盖底色,最后涂保护层,再通过光学透明胶将膜贴合到玻璃上,因此对PET的透光率要求很高,不仅成本相对较高,工艺复杂,而且有的颜色实现较为困难。
【发明内容】
本申请主要解决的技术问题是提供一种玻璃基板的制备方法、玻璃基板及智能移动终端,解决玻璃上光学镀膜成本高、炫彩颜色范围欠缺、且难以实现色彩多变。
为解决上述技术问题,本申请采用的一个技术方案是提供一种智能移动终端,该智能移动终端包括玻璃基板,玻璃基板包括:光学效果膜,光学效果薄膜包括具有纳米微球三维规整排列形成的光子晶体结构,纳米微球的尺寸为100-1000纳米;保护层,设置于光学效果膜的第一面;光学效果膜的第二面与玻璃基板贴合,并使用光学透明胶将光学效果薄膜的第二面贴合在玻璃基板上。
为解决上述技术问题,本申请采用的又一技术方案是提供一种玻璃基板,该玻璃基板包括:光学效果膜,光学效果薄膜包括具有纳米微球三维规整排列形成的光子晶体结构;保护层,设置于光学效果膜的第一面;光学效果膜的第二面与玻璃基板贴合。
为解决上述技术问题,本申请采用的另一技术方案是提供一种玻璃基板的制备方法,该制备方法包括:制备光学效果薄膜,光学效果薄膜包括具有纳米微球三维规整排列形成的光子晶体结构;在光学效果薄膜的第一面设置保护;将光学效果薄膜的第二面贴合在玻璃基板上。
区别现有技术,本申请提供一种玻璃基板的制备方法、玻璃基板及智能移动终端,该玻璃基板可以很好的实现类似光学镀膜的炫彩效果,且克服了光学镀膜的炫彩效果有些颜色难以实现及成本高的困难,从不同角度观看还可以呈现不同的颜色效果,且颜色范围也更丰富,给消费者带来了更多选择和实惠,提升用户体验。
【附图说明】
图1是本申请提供的一种玻璃基板的制备方法一实施例的流程示意图;
图2是本申请提供的一种玻璃基板一实施例的结构示意图;
图3是本申请提供的一种玻璃基板另一实施例的结构示意图。
【具体实施方式】
下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,均属于本申请保护的范围。
参阅图1,图1是本申请提供的一种玻璃基板的制备方法一实施例的流程示意图。玻璃基板的制备方法包括如下步骤:
S101:制备光学效果薄膜,所述光学效果薄膜包括具有纳米微球三维规整排列形成的光子晶体结构。
根据外观炫彩颜色效果要求,选择聚苯乙烯、二氧化硅、四氧化三铁、聚甲基丙烯酸甲酯(PMMA)、聚丙烯酸乙酯(PEA)、氧化铟锡(ITO)、三氧化二砷(ATO)、金和银等核心材料中的一种或几种成分,将核心材料和交联剂在60-90℃下混合,制作成纳米微球并干燥,然后纳米微球在添加有机溶剂或特定单体后形成具有一定流动性的混合物,涂覆在基膜上(如离型膜),将涂好的基膜放入UV固化箱中,200-350nm固化后取出,将固化后的基膜用微应力辊挤压 使其上下表面平整,即得到所述光学效果薄膜。本实施例中的纳米微球包括核心层、过渡层和壳层。其中核心层的光折射率高且光学反射比高,壳层的光折射率低,因此,可以根据实际需要,通过提高核心层与壳层的折射率比来提高光学效果。使用本实施例中的纳米微球制备而成的光学效果薄膜,其颜色会随着光线入射角度的变化而变化,从而达到很好的类似光学镀膜的炫彩效果,从不同角度观看,可以呈现不同的颜色效果,且颜色范围也更丰富。
上述纳米微球的核心材料包括有机材料或无机材料,且纳米微球的壳层材料包括聚合物弹性体材料,经过上述方法制得的纳米微球的尺寸为100-1000纳米。
S102:在所述光学效果薄膜的第一面设置保护层。
本实施例中的光学效果薄膜是批量生产的,通常情况下制备完成后不会马上进行下一步的工序,因此有必要在制备光学效果薄膜,光学效果薄膜包括具有纳米微球三维规整排列形成的光子晶体结构步骤之后包括如下步骤:在光学效果薄膜上贴附离型保护膜。进一步的,当需要进行下一步工序时,在光学效果薄膜的第一面设置保护层的步骤之前包括如下步骤:去除贴附在所述光学效果薄膜第一面上的离型保护膜。离型保护膜具有保护光学效果薄膜的清洁和表面平整,便于后面的使用。
根据实际用途,光学效果薄膜只有面对用户的那一面(即第二面,下同)需要进行炫彩效果展示,因此需要对背对用户的那一面(即第一面,下同)进行保护。在一个具体的实施方式中,先剥离离型保护膜,然后使用光学透明胶在光学效果薄膜的第一面粘贴PET膜,此处的PET膜仅仅是起保护光学效果薄膜的作用,因此对该PET膜的透光率没有要求,这样节约了成本。传统的PET膜需要做到90%以上的透光率才能很好显示出炫彩效果,而本实施例中,PET膜的透光率可以是任意透光率的PET膜,例如90%、70%或50%,甚至更低。此外,本实施例中的PET膜还具有防爆的作用。
在其他实施例中,也可以用油墨覆盖所述光学效果薄膜第一面来进行保护,与上述通过贴附PET膜来进行保护相比,操作跟简单,成本更低。
S103:将所述光学效果薄膜的第二面贴合在玻璃基板上。
将光学效果薄膜的第二面贴合在玻璃基板上的步骤具体包括:使用光学透明胶将所述光学效果薄膜的第二面贴合在玻璃基板上,本实施例中的玻璃基板包括2D玻璃、2.5D玻璃及3D玻璃等。
区别现有技术,使用本申请玻璃基板的制备方法所制备的玻璃基板,可以很好的实现类似光学镀膜的炫彩效果,且克服了光学镀膜的炫彩效果有些颜色难以实现及成本高的困难,从不同角度观看还可以呈现不同的颜色效果,且颜色范围也更丰富,给消费者带来了更多选择和实惠,提升用户体验。
参阅图2,图2是本申请提供的一种玻璃基板一实施例的结构示意图。
玻璃基板包括:玻璃S201、光学透明胶S204、光学效果薄膜S202、普通双面胶S205、PET膜S203。其中,所述光学效果薄膜S202是通过上述任一制备方法所制得。玻璃基板具体结构包括:使用普通双面胶S205将的第一面与PET膜S203粘接起来,PET膜S203对光学效果薄膜S202起到保护作用,通过光学透明胶S204将玻璃S201和光学效果薄膜S202的第二面粘接起来,其中玻璃S201包括2D玻璃、2.5D玻璃或3D玻璃,用户透过玻璃S201并穿过光学透明胶S204便可看到光学效果薄膜S202的炫彩效果,且随着光线入射角和用户的视角的不同而显示出不同的色彩。
参阅图3,图3是本申请提供的一种玻璃基板另一实施例的结构示意图。
玻璃基板包括:玻璃S301、光学透明胶S304、光学效果薄膜S302、油墨S303。其中,所述光学效果薄膜S202是通过上述任一制备方法所制得。光学效果薄膜S302的第一面涂覆油墨S303,油墨S303对光学效果薄膜S302起到保护作用。通过光学透明胶S304将玻璃S301和光学效果薄膜S302的第二面粘接起来,玻璃S301包括2D玻璃、2.5D玻璃或3D玻璃,用户透过玻璃S301并穿过光学透明胶S304便可看到光学效果薄膜S302的炫彩效果,且随着光线入射角和用户的视角的不同而显示出不同的色彩。
上述制备的玻璃基板可以用于智能移动终端的背盖,例如手机、平板电脑等。
区别与现有技术,本申请智能移动终端的玻璃基板可以很好的实现类似光学镀膜的炫彩效果,且克服了光学镀膜的炫彩效果有些颜色难以实现及成本高的困难,从不同角度观看还可以呈现不同的颜色效果,且颜色范围也更丰富,给消费者带来了更多选择和实惠,提升用户体验。
以上所述仅为本申请的实施方式,并非因此限制本申请的专利范围,凡是利用本申请说明书及附图内容所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本申请的专利保护范围内。

Claims (20)

  1. 一种智能移动终端,其中,所述智能移动终端包括玻璃基板,所述玻璃基板包括:
    光学效果膜,所述光学效果薄膜包括具有纳米微球三维规整排列形成的光子晶体结构,所述纳米微球的尺寸为100-1000纳米;
    保护层,设置于所述光学效果膜的第一面;
    所述光学效果膜的第二面与所述玻璃基板贴合,并使用光学透明胶将所述光学效果薄膜的第二面贴合在所述玻璃基板上。
  2. 如权利要求1所述的智能移动终端,其中,所述保护层为PET膜。
  3. 如权利要求2所述的智能移动终端,其中,使用光学透明胶在所述光学效果薄膜的第一面粘贴PET膜。
  4. 如权利要求2所述的智能移动终端,其中,所述PET膜的透光率低于90%。
  5. 如权利要求1所述的智能移动终端,其中,所述保护层为油墨。
  6. 一种玻璃基板,其中,所述玻璃基板包括:
    光学效果膜,所述光学效果薄膜包括具有纳米微球三维规整排列形成的光子晶体结构;
    保护层,设置于所述光学效果膜的第一面;
    所述光学效果膜的第二面与所述玻璃基板贴合。
  7. 如权利要求6所述的玻璃基板,其中,使用光学透明胶将所述光学效果薄膜的第二面贴合在所述玻璃基板上。
  8. 如权利要求6所述的玻璃基板,其中,所述保护层为PET膜。
  9. 如权利要求8所述的玻璃基板,其中,使用光学透明胶在所述光学效果薄膜的第一面粘贴PET膜。
  10. 如权利要求8所述的玻璃基板,其中,所述PET膜的透光率低于90%。
  11. 如权利要求6所述的玻璃基板,其中,所述保护层为油墨。
  12. 如权利要求6所述的玻璃基板,其中,所述纳米微球的尺寸为100-1000纳米。
  13. 一种玻璃基板的制备方法,其中,包括:
    制备光学效果薄膜,所述光学效果薄膜包括具有纳米微球三维规整排列形成的光子晶体结构;
    在所述光学效果薄膜的第一面设置保护层;
    将所述光学效果薄膜的第二面贴合在玻璃基板上。
  14. 如权利要求13所述玻璃基板的制备方法,其中,所述将所述光学效果薄膜的第二面贴合在玻璃基板上的步骤具体包括:使用光学透明胶将所述光学效果薄膜的第二面贴合在玻璃基板上。
  15. 如权利要求13所述玻璃基板的制备方法,其中,所述在所述光学效果薄膜的第一面设置保护层的步骤具体包括:在所述光学效果薄膜的第一面粘贴PET膜。
  16. 如权利要求15所述玻璃基板的制备方法,其中,所述在所述光学效果薄膜的第一面粘贴PET膜的步骤具体包括:使用光学透明胶在所述光学效果薄膜的第一面粘贴PET膜。
  17. 如权利要求15所述玻璃基板的制备方法,其中,所述PET膜的透光率低于90%。
  18. 如权利要求13所述玻璃基板的制备方法,其中,所述在所述光学效果薄膜的第一面设置保护层的步骤具体包括:用油墨覆盖所述光学效果薄膜第一面。
  19. 如权利要求13所述玻璃基板的制备方法,其特征在于,在所述制备光学效果薄膜,所述光学效果薄膜包括具有纳米微球三维规整排列形成的光子晶体结构步骤之后包括如下步骤:在所述光学效果薄膜上贴附离型保护膜;
    在所述光学效果薄膜的第一面设置保护层的步骤之前包括如下步骤:去除贴附在所述光学效果薄膜第一面上的离型保护膜。
  20. 如权利要求13所述玻璃基板的制备方法,其特征在于,所述纳米微球的尺寸为100-1000纳米。
PCT/CN2018/107887 2017-09-28 2018-09-27 玻璃基板的制备方法、玻璃基板及智能移动终端 WO2019062800A1 (zh)

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