WO2018122532A1 - Composition de mascara et conditionnement - Google Patents
Composition de mascara et conditionnement Download PDFInfo
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- WO2018122532A1 WO2018122532A1 PCT/FR2017/053851 FR2017053851W WO2018122532A1 WO 2018122532 A1 WO2018122532 A1 WO 2018122532A1 FR 2017053851 W FR2017053851 W FR 2017053851W WO 2018122532 A1 WO2018122532 A1 WO 2018122532A1
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- Prior art keywords
- polymer
- composition
- mascara
- weight
- particles
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/025—Explicitly spheroidal or spherical shape
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/87—Application Devices; Containers; Packaging
Definitions
- the present application relates to the field of makeup or care of eyelashes, and more specifically relates to a mascara composition containing a high proportion of waxes.
- This composition comprises at least one liquid phase in which are dispersed waxes, solid particles of at least one first polymer, solid particles of at least one second polymer, and pigments.
- the invention also relates to an assembly comprising a mascara composition and a packaging.
- the waxes form a structuring network that gives consistency to the liquid in which they are dispersed.
- This network of wax crystals has a tendency to irreversibly weaken over time, which decreases the quality of the makeup as and when used. The need therefore remains to provide a mascara whose structure is stable in the packaging over time, so as to maintain optimal makeup throughout the use of the product.
- the present invention describes a composition for makeup or care of the eyelashes comprising a liquid, such as water or an oil, in which waxes, solid particles of at least a first polymer, solid particles of water are dispersed. at least one second polymer, and pigments, the first polymer being chosen from cross-linked polyurethanes, and the second polymer being chosen from cross-linked polymethylsilsesquioxanes and polymethyl methacrylates.
- the invention also discloses a make-up product comprising a makeup composition placed in a packaging and application assembly having a flexible wall which can be deformed by exerting hand pressure, said composition comprising a liquid in which are dispersed waxes and solid particles of at least one polymer, the polymer being selected from crosslinked polyurethanes, polymethylsilsesquioxanes, crosslinked polymethyl methacrylates, and mixtures thereof.
- the invention also describes an eyelash makeup process, which comprises at least the following steps:
- a high-wax mascara composition containing a polymer selected from cross-linked polyurethanes, polymethylsilsesquioxanes, cross-linked polymethyl methacrylates and mixtures thereof, said composition being packaged in a packaging and application package comprising i) a container provided with a dewatering means and a flexible portion on at least one of its internal or external surfaces and ii) a plug which is secured to an application brush which is immersed in the composition,
- the particular combination of the two polymers, or the particular combination of a polymer and a package advantageously allows a formula to be softened just before being applied to the eyelashes.
- This relaxation can be obtained by exerting pressure on a deformable part of the packaging.
- Mascara which has a high viscosity due to a high concentration of waxes, can be applied more evenly, lead to a smoother lash coverage, and allow greater lash thickening from the first application.
- the combination of the two polymers, or the combination of a polymer and a packaging assembly, proposed in the context of the invention, makes it possible to restructure the wax network, so as to increase the volumizing effect with each application. and throughout the life of product use.
- the volumizing effect can further extend during the day over a longer duration than the mascaras of the prior art.
- the present invention also describes a composition intended for makeup or care of eyelashes comprising a liquid, waxes, solid particles of at least one first polymer, solid particles of at least a second polymer different from the first, and pigments.
- the particles of the first polymer being elastic, and the particles of the second polymer having very low oil absorption and water absorption properties.
- This composition may more specifically comprise the association of first solid particles deforming under mechanical stress and at least partially recovering their shape after cancellation of the stress, and second solid particles, different from the first, non-porous and having no affinity. with the liquid dispersion medium, which retain their shape regardless of the mechanical stress exerted.
- This mixing has several consequences, such as maintaining the structure of the wax network during the shelf life and use of the product, easier application of the product on the eyelashes, and obtaining a immediate and important volumizing makeup result.
- the product has a creamy texture without affecting the application qualities. It is thick without being heavy and brings a lot of materials.
- the invention relates to a mascara composition
- a mascara composition comprising at least one liquid phase, waxes, solid particles of at least one first polymer, solid particles of at least one second polymer, and pigments,
- liquid phase representing from 30% to 60% by weight, preferably from 40% to 55% by weight
- the waxes represent from 15 to 40% by weight, preferably from 25 to 40% by weight,
- the pigments represent from 5 to 15% by weight
- the first polymer is selected from crosslinked polyurethanes
- the second polymer is selected from polymethylsilsesquioxanes
- the texture of the product of the invention provides an improved volumizing effect, moreover immediate, which is maintained more during the day.
- the lashes are much thicker, longer, well curved, soft, soft and comfortable.
- the mascara of the invention uniformly covers the eyelashes from the root to the tip. The successive deposits of product overlap well passage passage, and the load is satisfactory from the first brushing.
- the present application also describes a mascara composition
- a mascara composition comprising at least one liquid phase, waxes, solid particles of at least one first polymer, solid particles of at least one second polymer, and pigments, the particles of the first polymer. being elastic, and the particles of the second polymer having very low oil absorption and water absorption properties.
- the first polymer is advantageously in the form of microspheres which have a fairly low hardness (also called compressibility) that can be measured by different methods.
- the hardness of the particles of the first polymer may be less than 10 N / mm 2 , in measuring the force required to obtain a 10% deformation of the K index (denoted K (10%)), with a reference compression apparatus Shimadzu Microcompression Testing Machine MCTM-500.
- the hardness of the particles, evaluated by measuring the force required to obtain a deformation of 10% of the index K (denoted by K (10%)), is advantageously between 0.01 and 1 N / mm 2 , more preferably between 0.1 and 0.5 N / mm 2 . This method also makes it possible to evaluate the percentage of elastic deformation of said particles: the latter is preferably greater than 10%.
- the hardness of the particles of the first polymer may be less than 10 ° D, preferably less than 1 ° D.
- the particles of the first polymer are advantageously elastic, the value of their elasticity, which can be determined by various methods known to those skilled in the art.
- the elasticity of the particles can be measured with a Shimadzu Microcompression Testing Machine MCTM-500 reference compression apparatus.
- the elastic deformation ratio is preferably greater than 5%, more preferably greater than 10%, 15%, 20%, 25%, 30% or even 35%, especially when the compressive force exerted corresponds to K (10). %) previously mentioned.
- the elasticity of the particles of the first polymer may further be characterized by a modulus of elasticity, measured according to ISO 178 (2010), of less than 1000 MPa, preferably less than 500 MPa, more preferably less than 100 MPa.
- the second polymer is preferably in the form of microspheres whose specific surface area is less than 30 m 2 / g, the specific surface being measured by a method known to those skilled in the art, in particular the ISO 9277 (2010) standard.
- the particles of the second polymer preferably have very low water absorption and oil absorption capabilities.
- the oil absorption of the particles of the second polymer can be measured at 25 ° C. according to a method known to those skilled in the art: it ranges, for example, from 0 to 0.9 g / l of oil under the conditions of the ASTM D281-8.
- the oil absorption of the particles of the second polymer measured at 25 ° C. according to this method, ranges from 0 to 0.6 g / l of oil.
- the water absorption of the particles of the second polymer evaluated at 20 ° C by DIN 53 472, can be less than 1%.
- the water absorption value of the particles can be less than 1% as well.
- the particles of the first polymer may have oil and water absorption properties greater or less than those of the second polymer particles.
- the particles of the second polymer have a much higher hardness and a much lower elasticity than the particles of the first polymer. It is also preferred that the particles of the second polymer be solid and nonporous
- the product according to the invention has a more or less fluid creamy texture: its viscosity is preferably greater than 150,000 mPa.s, and advantageously between 200,000 and 600,000 mPa.s.
- the viscosity of the composition can be measured at 25 ° C. using a Rheomat 180 (Company LAMY) equipped with a mobile MS-R1, MS-R2, MS-R3, MS-R4 or MS-R5 chosen depending on the consistency of the composition, rotating at a speed of rotation of 200 t.min "1. The measurement is taken after 10 minutes of rotation.
- the composition may contain one or more liquid phases, which may be fatty or aqueous.
- the composition contains a single liquid phase comprising water or a single liquid phase comprising at least one oil.
- the composition may be anhydrous in the sense that water is not added during its manufacturing process.
- the composition may also be an emulsion of two liquid phases, including water and a liquid fatty phase comprising oils.
- the composition may be a water-in-oil emulsion or an oil-in-water emulsion.
- the composition may also contain at least one other phase which is solid and dispersed in at least one of the liquid phases.
- the composition is for example a dispersion of solid particles in an aqueous liquid phase, or in an oily liquid phase.
- the oils may be chosen from volatile or non-volatile dimethicones, cyclomethicones, isododecane, isohexadecane or isodecane, paraffin oil, hydrogenated polydecene, propylene glycol, isotretecyl sononanoate or isostearyl neopentanoate. , tridecyl neopentanoate, cetyl octanoate), non-volatile silicone oils, especially phenyltrimethicones.
- the liquid fatty phase comprises predominantly or exclusively volatile oils in the form of a gel, such as volatile dimethicones, cyclomethicones, isododecane, isohexadecane or isodecane, gelled with an organomodified clay.
- the liquid phase or the mixture of liquid phases represents for example from 30% to 60% by weight, preferably from 40% to 55% by weight relative to the mass of the mascara composition.
- the liquid phase is preferably water or isododecane.
- water or isododecane is from 30% to 60% by weight, preferably from 40% to 55% by weight, based on the weight of the mascara composition.
- the liquid represents from 40% to 55% by weight
- the waxes represent from 20% to 25% by weight
- the pigments represent from 8% to 12% by weight.
- the first polymer may be in the form of particles consisting of one or more polyurethane polymers, or in the form of composite particles comprising an organic or inorganic non-polyurethane core and a polyurethane bark.
- the polyurethane may be a polyurethane polymer or a copolymer comprising in part urethane units.
- polyurethanes used in the composition of the particles of the first polymer are crosslinked.
- the particles of the first polymer consist, for example, of a core of polymethyl methacrylate coated with polyurethane, or of a polyurethane-coated silica core.
- the particles of the first polymer may also be made of polyurethane.
- the particles of the first polymer have elastic properties.
- the first polymer is not a urethane-acrylate copolymer whose elasticity is zero.
- the relative amount of the core and the coating will be adjusted so as to obtain satisfactory elasticity and hardness.
- Polyurethane within the meaning of the invention is not introduced into the composition in the form of an aqueous dispersion of anionic polyurethane, such as polyurethane latices commonly used as film-forming polymer in the formulation of mascaras.
- the first polymer may be in the form of microspheres of a crosslinked polyurethane obtained by copolymerization of an aliphatic diisocyanate (typically of molecular weight between 100 and 300 g.mol -1 ), preferably linear, of an aliphatic triol, of preferably low molecular weight (typically between 100 and 150 g, mol -1 ) and optionally a lactone.
- a non-INCI HDI / TRI ETHYLOL HEXYLLACTONE CROSSPOLYMER polymer may be used as the first polymer.
- Such a polymer is marketed under the trademark Plastic Powder® D-400.
- a molar ratio between the diisocyanate monomer and the triol monomer will be used to obtain the desired compressibility properties.
- the polyurethane particles are preferably manufactured by polycondensation of the monomers mentioned above in a lipophilic solvent.
- the percentage of the particles of the first polymer, preferably crosslinked polyurethane, is for example between 0.01 and 5% by weight, preferably between 0.05 and 2% by weight, between 0.08 and 1.5% by weight. weight, between 0.1 and 1.5% by weight, even between 0.2 and 1.0% or between 0.2 and 0.5% by weight.
- the particles of the first polymer have an average size ranging from 1 to 40 microns, preferably from 1 to 25 microns. They are preferably in the form of microspheres.
- the particles of the second polymer have an average size ranging from 1 to 40 microns, preferably from 1 to 25 microns. They are preferably in the form of microspheres.
- the particles of the first polymer and the particles of the second polymer preferably have an average size ranging from 1 to 25 microns.
- the polyurethane is preferably of a lipophilic nature and dispersed in the waxes of the composition.
- the second polymer may be in the form of particles consisting of one or more polymethylsilsesquioxane polymers, or in the form of composite particles comprising a non-polymethylsilsesquioxane core (such as an acrylic polymer) and a polyimethylsilsesquioxane bark.
- the second polymer is a crosslinked polymethylsilsesquioxane, preferably highly crosslinked.
- the polymethylsilsesquioxane is preferably lipophilic, and does not exhibit amphiphilic or emulsifying properties.
- Examples of Silderm Emulsifying® BG or Silderm Emulsifying® CS polymethylsilsesquioxane amphiphilic silicone resins are therefore not part of the present invention.
- the term "lipophilic” means a polymer that is compatible with the fat or lipophilic ingredients of the composition, such as waxes. A lipophilic polymer within the meaning of the invention
- the polymethylsilsesquioxane of lipophilic nature is thus advantageously dispersed in the waxes.
- the same is true of the first polymer.
- the particles of the second polymer advantageously have a capacity for absorbing liquids such as oils and the very low water of in order to maintain their intrinsic hardness once introduced into the composition, and to knead the other ingredients of the composition, in particular the waxes, under the effect of a mechanical stress.
- the values of the oil absorption and water absorption capacities of the particles of the second polymer, as well as their measurement method, may be in accordance with the description which has been made previously.
- the particles of the second polymer have an oil absorption measured according to ASTM D281-84 of less than 1 g / lg, more preferably less than 0.60 g / lg.
- the second polymer can correspond to commercial products
- Tospearl® which are in the form of hydrophobic microspheres of average size ranging from 2.0 to 6.0 microns.
- the percentage of the particles of the second polymer is for example between 0.01 and 5% by weight, preferably between 0.05 and 2% by weight, between 0.08 and 1.5%, between 0.1 and 1.5% by weight, even between 0.2 and 1.0% or between 0.2 and 0.5% by weight.
- the sum of the quantity of the first polymer and the amount of the second polymer is, for example, between 0.01 and 5% by weight, preferably between 0.05 and 2% by weight, between 0.08 and 1.5%. between 0.1 and 1.5% by weight, even between 0.2 and 1.0% or between 0.2 and 0.5% by weight.
- the mass ratio between the particles of the first polymer and the particles of the second polymer may be between 1/5 and 5/1, between 1/2 and 4/1, preferably between 1/2 and 3/1.
- the waxes are known to those skilled in the art and may be chosen from beeswax, carnauba wax, carnauba wax, candelilla wax, hydrogenated jojoba wax, hydrogenated palm oil, rice bran wax, ceresin waxes, ontan wax, ozokerite waxes, microcrystalline waxes, polyethylene waxes, alcohol-polyethylene waxes, solid fatty alcohols such as stearic alcohol and behenic alcohol, polyalkylene glycol derivatives of the aforementioned waxes such as polyoxyethylenated derivatives (PEG 6-20) of beeswax or carnauba wax, triglycerides of solid fatty acids and mixtures thereof.
- PEG 6-20 polyoxyethylenated derivatives
- a wax which is understood by a person skilled in the art is a compound of solid appearance at 25 ° C. which comprises crystalline phases. Its melting temperature can be defined as the melting point corresponding to the beginning of the melting of this compound or the temperature corresponding to the endothermic peak of the compound, these quantities being able to be measured by DSC (Differential Scanning Calorimetry) according to the ISO 11357-3 standard. .
- the melting temperature of a wax is preferably greater than or equal to 30 ° C.
- the wax used to make the mascara may be mixed with the other ingredients of the composition in the form of a microdispersion in water, in the form of powder or pellets.
- the waxes represent from 18 to 40% by weight, preferably from 25 to 35% by weight, more preferably from 28 to 32% by weight, based on the weight of the composition.
- the mascara composition comprises pigments representing from 5 to 15% by weight, for example from 8 to 12% by weight of the composition.
- the pigments are preferably chosen from titanium dioxide, zinc oxides, iron oxides (black, yellow or red), manganese violet, ultramarine blue, chromium hydrate and ferric blue, the powders metallic like aluminum powder, copper powder.
- organic pigments mention may be made of carbon black, D & C type pigments, and lacquers. Reflective pigments and pearlescent pigments may also be mentioned.
- the composition may contain at least one film-forming polymer for increasing the lining of the eyelashes.
- the amount of film-forming polymer can range from 0.1 to 12%, preferably from 5 to 10% and better still from 6 to 8% by weight, relative to the total weight of the composition.
- VP vinylpyrrolidone
- cellulose polymers such as hydroxyethylcellulose, vinyl polymers such as polyvinylpyrrolidones, gum arabic, guar gum, xanthan derivatives and mixtures thereof.
- compositions may contain adjuvants customary in the cosmetic field, such as tenioactives, hydrophilic or lipophilic gelling agents, hydrophilic or lipophilic active agents, fatty compounds in the form of paste, preservatives, antioxidants, pH adjusters and perfumes. .
- the surfactants preferably used in the composition according to the invention are chosen, for example, from oxyethylenated and / or oxypropylenated ethers, fatty acid and polyethylene glycol esters, polyethylene glycol / polypropylene glycol polycondensates, esters and ethers.
- the present application describes a set of conditioning and application of a mascara which may or may not contain one of the compositions described above.
- Said set comprises:
- a hollow container for containing the mascara having a wall defining an interior space and an opening, at least a first part of the wall being rigid, and at least a second part of the wall being more flexible than the first rigid and suitable part to be moved from an expanded position to a forced position,
- closure means for removably closing said opening
- An applicator head carried by a rod secured to the closure means, said applicator head being mounted to be, in the closed position of the closure means, adapted to be placed in contact with the mascara inside said hollow container.
- Pressing the second flexible portion of the wall allows the user to knead the mascara, which is generally thixotropic, in order to break its rest viscosity and to ensure efficient fluidification, thus satisfactory loading. the mascara brush and a better distribution of the mascara in the container.
- a rigid portion is a portion configured to remain substantially at rest and maintain its shape when a user exerts manual pressure on that portion.
- deformation of the rigid portion when manual pressure is applied may be invisible to the naked eye. Deformation may be considered invisible to the naked eye if it is less than half a millimeter.
- the manual pressure may be a pressure that can be exerted, for example, by the fingers of a user, in particular by two opposite fingers.
- a flexible portion is a portion configured to deform substantially, particularly visibly to the naked eye, when manual pressure is applied thereto.
- the expanded position and the forced position can be distinguished with the naked eye.
- the expanded position and the forced position are separated, at least at one point, by a distance of at least half a millimeter.
- the first rigid portion has at least one window closed by the second flexible portion.
- the wall is flexible. The user knows which easily where she can exert pressure to achieve the kneading effect previously explained.
- the first rigid portion delimits the window axially and circumferentially. It is understood that the window is entirely surrounded by the first rigid portion, which ensures that the container maintains its shape despite the possible deformations of the second flexible portion of the wall.
- the rod is configured so that in the closed position of the closure means, the applicator head is at least partly facing, axially, the window.
- the applicator head in said closed position, is positioned axially so as to face the window. Thanks to these provisions, the kneading effect can be obtained directly in the vicinity of the applicator head.
- the pressure exerted on the second flexible portion may allow the user to directly deposit the product on the applicator.
- the applicator head in the closed position of the closing means, the applicator head can also be entirely facing, axially, the window.
- the first rigid portion is assembled to the second flexible portion in a sealed manner to form a sealed wall for the container.
- the second flexible portion may be heat sealed to the first rigid portion.
- the wall comprises a tubular body forming the first rigid portion.
- the wall comprises a membrane forming the second flexible portion.
- the membrane is assembled on the tubular body radially outside the tubular body.
- the second flexible portion may form the outside of the wall.
- the tubular body comprises a ring and a skirt recessed, radially, with respect to said ring.
- the skirt can extend axially from the ring.
- the ring and the skirt may be connected by a frustoconical portion and / or a shoulder.
- the window may be provided in the skirt.
- the membrane can be arranged in the axial extension of the ring, radially outside the skirt.
- the assembly further comprises at least one collar secured to said wall.
- the assembly further comprises at least one wiping means integral with said neck.
- said applicator head is a flocked feather, a felt, a brush, or a brush.
- the first rigid portion comprises a material selected from the group consisting of polyethylenes such as low density polyethylenes, high density polyethylenes, and mixtures of polyethylenes of different densities; polyoxymethylenes; polypropylene; polyvinyl chloride; polyesters; polyamides; Nylon; and blends of other plastics such as blends of polycarbonate and polypropylene; and their mixtures.
- said material is polyoxymethylene.
- the second flexible portion comprises an elastomeric or thermoplastic material, such as a silicone, a fluorinated silicone, a butyl rubber, a nitrile rubber, the VTTON, a vinyl ethylene acetate copolymer (EVA), a polyether amide block copolymer , polyester elastomer, ethylene propylene rubber, polyurethane, styrene - ethylene styrene (SES), styrene - butadiene - styrene (SBS), styrene - isoprene - styrene, styrene / butylene - ethylene / styrene , a latex, synthetic or not, and a rubber, and mixtures thereof.
- an elastomeric or thermoplastic material such as a silicone, a fluorinated silicone, a butyl rubber, a nitrile rubber, the VTTON,
- a set of packaging and application of mascara comprises a hollow container for containing the mascara, means for closing said container and an applicator head.
- the hollow container has a wall defining an interior space and an opening, the opening being in this case defined by a neck.
- the wall comprises a first relatively rigid portion and a second relatively flexible portion.
- the first relatively rigid portion is formed, in this case, by a tubular body.
- the tubular body extends along an axial direction and comprises successively, in the axial direction, the aforementioned neck, a ring, a skirt and a bottom wall.
- the ring is substantially cylindrical. It will be recalled that a cylinder is a surface defined by a fixed direction line (generator) describing a closed curve of any shape. In this case, the ring may be a circular base cylinder trunk.
- Windows are formed in the tubular body, specifically in the skirt. In this embodiment, two windows are provided in the skirt. However, any number of windows could be provided. In this embodiment, the windows are diametrically opposed in a radial direction, that is to say in a direction perpendicular to the aforementioned axial direction. Moreover, each window can be of curved or polygonal shape with rounded or non-rounded corners. For example, a window may be rectangular, oval, oblong, or elliptical.
- the skirt is substantially cylindrical, for example with a circular base.
- the bottom wall is provided at an axial end of the tubular body, in particular of the skirt, on the side opposite the neck.
- the bottom wall blocks the tubular body.
- the bottom wall may extend substantially radially.
- the bottom wall may be flat, at least on the side towards the interior of the container, so as to avoid the accumulation of mascara in inaccessible areas.
- the side of the bottom wall facing the outside of the container may be flat or have a desired shape, for example to improve the stability of the container.
- the second relatively flexible portion is formed, in this case, by a membrane, preferably an elastic membrane. It is understood that the elastic limit of the membrane is such that the membrane remains in its elastic deformation range when it is biased between the expanded position and the forced position.
- the membrane seals the windows provided in the tubular body.
- the container wall is reduced to its second flexible portion. More particularly, at the windows, the container wall consists solely of the membrane.
- the second flexible portion is able to be moved from an expanded position to a forced position.
- This setting in motion of the second flexible part can be carried out directly or indirectly.
- the windows are provided wider than an average human finger, at least in one direction, so that a finger can exert pressure by pressing the membrane.
- the windows may extend at least substantially one centimeter in width.
- the pressure can be exerted on the second flexible portion indirectly via movable buttons, articulated or not, transmitting, possibly with reduction, a force or displacement to the second flexible portion.
- the membrane in particular to facilitate the assembly of the membrane to the tubular body, the membrane is configured to conform to less in part the outer shape of the tubular body, and at least in part the portion of the tubular body that includes the windows. More particularly, here, the membrane conforms to the shape of the skirt and the bottom wall, in particular on the outside thereof. It is understood that the membrane does not include an opening where the windows are provided, so as to ensure the tightness of the container wall.
- the membrane is substantially symmetrical in shape.
- the membrane comprises a cylindrical section and a closure disk provided at the end of the cylindrical section.
- the cylindrical section is provided in the axial extension of the ring of the tubular body.
- the inside of the cylindrical section is in contact with the outside of the skirt.
- the skirt is recessed, radially, with respect to the ring, by a distance substantially equal to the radial thickness of the membrane, in particular of the cylindrical section.
- the thickness of the membrane may vary, especially with respect to the windows.
- the second flexible portion can be thinned next to the windows.
- the second part of the wall may comprise decorative motifs, for example drawn, etched, printed, or made by any other method known per se.
- the wall forms a tight assembly in itself.
- the first rigid portion is assembled to the second flexible portion sealingly.
- the tubular body and the membrane are assembled in a sealed manner, for example heat-sealed to one another.
- the closure means for removably sealing said opening may be, for example, a cap to clip, screw or engage the container, in particular on its neck.
- the container or the neck may include clipping means, face or engagement complementary.
- Other closure means are known to those skilled in the art.
- These closure means may comprise sealing means, examples of which are known to those skilled in the art.
- the applicator head is carried by a rod secured to the closure means, said applicator head being mounted so as to be closed in the closed position, able to be brought into contact with the mascara inside said hollow container.
- the present application further describes an eyelash makeup product comprising a package containing a composition according to one aspect of the first subject of the invention described above.
- a mascara product comprising:
- a mascara composition comprising at least one liquid phase, waxes, solid particles of a polymer, and pigments,
- the liquid phase represents from 30 to 60% by weight
- the waxes represent from 15 to 40% by weight, preferably from 20 to 35% by weight,
- the pigments represent from 5 to 15% by weight
- the polymer being chosen from polymethylsilsesquioxanes, crosslinked polymethyl methacrylates and crosslinked polyurethanes, and the polymer representing between 0.01 and 5% by weight,
- a set of packaging and application having a flexible wall that can be deformed by exerting a pressure of the hand, so as to create a mixing of said composition which! contains.
- the packaging may be in accordance with the description that has been made previously.
- ingredients of the composition may also be consistent with the description that has been made previously.
- Another part of the description of the present application relates to an eyelash makeup process comprising the application on said eyelashes of the composition according to the present application.
- This method may consist of a makeup process which comprises at least the following steps:
- a packaged mascara composition in a packaging and application pack comprising i) a container having a squeezing means and a flexible portion on at least one of its internal surfaces or external and ii) a cap which is secured to an application brush which is immersed in the composition, said composition being in accordance with one of the descriptions which has been made above.
- the brush may be a charging brush known to those skilled in the art, such as a brush type brush nylon® fibers held by a twisted wire, or a brush obtained by thermoplastic molding of synthetic materials (HDPE, LDPE, silicone derivatives, POM).
- the brush can be connected to the cap by a flexible rod.
- the following mascara composition was prepared.
- the weight percentage of the ingredients and their order of incorporation into the composition are detailed in Table 1.
- composition was prepared according to the following method.
- Example 1 of the invention was evaluated by a panel, according to a blind test, for a duration of use of one week, once a day, under conditions of conventional applications, and compared to a reference product.
- the panel consisted of 59 women, aged 26 to 45, equally distributed, regular users of selective market mascaras.
- the mascara covers the eyelashes from the root to the tip evenly, overlaps well application in application, the eyelashes are immediately covered
- the following mascara composition was prepared.
- the weight percentage of the ingredients and their order of incorporation into the composition are detailed in Table 2.
- composition was prepared according to the following method.
- the following mascara composition was prepared.
- the weight percentage of the ingredients and their order of incorporation into the composition are detailed in Table 3.
- composition was prepared according to the following method:
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Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US16/474,494 US20190350834A1 (en) | 2016-12-30 | 2017-12-27 | Mascara composition and packaging |
JP2019535259A JP2020503328A (ja) | 2016-12-30 | 2017-12-27 | マスカラ組成物及びパッケージング |
EP17832540.3A EP3562556A1 (fr) | 2016-12-30 | 2017-12-27 | Composition de mascara et conditionnement |
CN201780085858.4A CN110290836A (zh) | 2016-12-30 | 2017-12-27 | 睫毛膏组合物和包装 |
KR1020197020182A KR20190102001A (ko) | 2016-12-30 | 2017-12-27 | 마스카라 조성물 및 패키징 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1663569 | 2016-12-30 | ||
FR1663569A FR3061432B1 (fr) | 2016-12-30 | 2016-12-30 | Composition de mascara et conditionnement |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2018122532A1 true WO2018122532A1 (fr) | 2018-07-05 |
Family
ID=58645176
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2017/053851 WO2018122532A1 (fr) | 2016-12-30 | 2017-12-27 | Composition de mascara et conditionnement |
Country Status (7)
Country | Link |
---|---|
US (1) | US20190350834A1 (fr) |
EP (1) | EP3562556A1 (fr) |
JP (1) | JP2020503328A (fr) |
KR (1) | KR20190102001A (fr) |
CN (1) | CN110290836A (fr) |
FR (1) | FR3061432B1 (fr) |
WO (1) | WO2018122532A1 (fr) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060067960A1 (en) * | 2004-09-30 | 2006-03-30 | Russ Julio G | Color cosmetic compositions |
US20060067904A1 (en) * | 2004-09-30 | 2006-03-30 | Russ Julio G | Cosmetic compositions containing amphiphilic silicone resin emulsifier |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1112132A (ja) * | 1997-06-24 | 1999-01-19 | Kose Corp | 睫用化粧料 |
US6158912A (en) * | 1999-05-24 | 2000-12-12 | Color Access, Inc. | Flexible wall cosmetic container |
US8080257B2 (en) * | 2000-12-12 | 2011-12-20 | L'oreal S.A. | Cosmetic compositions containing at least one hetero polymer and at least one film-forming silicone resin and methods of using |
KR100964022B1 (ko) * | 2003-01-17 | 2010-06-15 | 주식회사 엘지생활건강 | 마스카라 화장료 조성물 |
FR2873030A1 (fr) * | 2004-07-16 | 2006-01-20 | Oreal | Produit cosmetique bicouche comprenant un polymere de silicone |
FR2903599B1 (fr) * | 2006-07-13 | 2012-08-31 | Oreal | Composition cosmetique a phase continue aqueuse comprenant au moins un polymere thermogelifiant, au moins un solvant organique volatil miscible dans l'eau et au moins un agent absorbant les radiations uv. |
US20080019932A1 (en) * | 2006-07-20 | 2008-01-24 | Laura Louise Crosby | Color Cosmetic Compositions |
JP6158552B2 (ja) * | 2012-03-30 | 2017-07-05 | 株式会社コーセー | 化粧料 |
FR3011738B1 (fr) * | 2013-10-11 | 2015-10-23 | Oreal | Composition cosmetique de revetement des fibres keratiniques |
BR112017011830B1 (pt) * | 2014-12-18 | 2021-12-14 | L'oreal | Composição e processo para a maquiagem e/ou cuidados para os materiais de queratina |
-
2016
- 2016-12-30 FR FR1663569A patent/FR3061432B1/fr active Active
-
2017
- 2017-12-27 CN CN201780085858.4A patent/CN110290836A/zh active Pending
- 2017-12-27 JP JP2019535259A patent/JP2020503328A/ja active Pending
- 2017-12-27 US US16/474,494 patent/US20190350834A1/en not_active Abandoned
- 2017-12-27 WO PCT/FR2017/053851 patent/WO2018122532A1/fr unknown
- 2017-12-27 KR KR1020197020182A patent/KR20190102001A/ko active IP Right Grant
- 2017-12-27 EP EP17832540.3A patent/EP3562556A1/fr active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060067960A1 (en) * | 2004-09-30 | 2006-03-30 | Russ Julio G | Color cosmetic compositions |
US20060067904A1 (en) * | 2004-09-30 | 2006-03-30 | Russ Julio G | Cosmetic compositions containing amphiphilic silicone resin emulsifier |
Non-Patent Citations (1)
Title |
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EMULSIFYING BG: "Product Name/Identifier SilDerm Emulsifying BG Product Code 30314 Recommended Use Topical Cosmetic Use Restrictions on Use None Supplier/Manufacturing Site Active Concepts Safety Data Sheet", 23 January 2015 (2015-01-23), XP055396498, Retrieved from the Internet <URL:http://activeconceptsllc.com/wp-content/uploads/2015/12/30314-SilDerm®-Emulsifying-BG-GHS-SDS-v4.pdf> [retrieved on 20170807] * |
Also Published As
Publication number | Publication date |
---|---|
US20190350834A1 (en) | 2019-11-21 |
KR20190102001A (ko) | 2019-09-02 |
FR3061432B1 (fr) | 2020-05-29 |
CN110290836A (zh) | 2019-09-27 |
FR3061432A1 (fr) | 2018-07-06 |
JP2020503328A (ja) | 2020-01-30 |
EP3562556A1 (fr) | 2019-11-06 |
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