WO2018055111A1 - Solid particulate compositions comprising water-soluble carrier polymer and perfume - Google Patents
Solid particulate compositions comprising water-soluble carrier polymer and perfume Download PDFInfo
- Publication number
- WO2018055111A1 WO2018055111A1 PCT/EP2017/074099 EP2017074099W WO2018055111A1 WO 2018055111 A1 WO2018055111 A1 WO 2018055111A1 EP 2017074099 W EP2017074099 W EP 2017074099W WO 2018055111 A1 WO2018055111 A1 WO 2018055111A1
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- Prior art keywords
- composition
- water
- oil
- perfume
- composition according
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 140
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- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000012243 magnesium silicates Nutrition 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- 239000001683 mentha spicata herb oil Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- UNSKAUSCLTVFGO-KCDKBNATSA-N methyl (2s,3r,4s,5r)-2,3,4,5-tetrahydroxy-6-oxohexanoate Chemical compound COC(=O)[C@@H](O)[C@H](O)[C@H](O)[C@@H](O)C=O UNSKAUSCLTVFGO-KCDKBNATSA-N 0.000 description 1
- 229940102396 methyl bromide Drugs 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- SBENKNZHVXGNTP-UHFFFAOYSA-N methylconiferyl ether Natural products COCC=CC1=CC=C(O)C(OC)=C1 SBENKNZHVXGNTP-UHFFFAOYSA-N 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ALHUZKCOMYUFRB-UHFFFAOYSA-N muskone Natural products CC1CCCCCCCCCCCCC(=O)C1 ALHUZKCOMYUFRB-UHFFFAOYSA-N 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical group CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229910021527 natrosilite Inorganic materials 0.000 description 1
- ZYTMANIQRDEHIO-UHFFFAOYSA-N neo-Isopulegol Natural products CC1CCC(C(C)=C)C(O)C1 ZYTMANIQRDEHIO-UHFFFAOYSA-N 0.000 description 1
- 235000019720 niaouli oil Nutrition 0.000 description 1
- XJHRZBIBSSVCEL-UHFFFAOYSA-N non-6-en-1-ol Chemical compound CCC=CCCCCCO XJHRZBIBSSVCEL-UHFFFAOYSA-N 0.000 description 1
- 229910000273 nontronite Inorganic materials 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- KKVZAVRSVHUSPL-UHFFFAOYSA-N o-methoxycinnamic aldehyde Natural products COC1=CC=CC=C1C=CC=O KKVZAVRSVHUSPL-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- HEKJOMVJRYMUDB-UHFFFAOYSA-N octahydro-6-isopropyl-2(1h)-naphthalenone Chemical compound C1C(=O)CCC2CC(C(C)C)CCC21 HEKJOMVJRYMUDB-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 229930007459 p-menth-8-en-3-one Natural products 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- LVECZGHBXXYWBO-UHFFFAOYSA-N pentadecanolide Natural products CC1CCCCCCCCCCCCC(=O)O1 LVECZGHBXXYWBO-UHFFFAOYSA-N 0.000 description 1
- 125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229960003742 phenol Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000001738 pogostemon cablin oil Substances 0.000 description 1
- 229920002553 poly(2-methacrylolyloxyethyltrimethylammonium chloride) polymer Polymers 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 235000020777 polyunsaturated fatty acids Nutrition 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000010491 poppyseed oil Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- 239000008171 pumpkin seed oil Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 239000010668 rosemary oil Substances 0.000 description 1
- 229940058206 rosemary oil Drugs 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000010670 sage oil Substances 0.000 description 1
- 239000010671 sandalwood oil Substances 0.000 description 1
- 229910000276 sauconite Inorganic materials 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 229910052616 serpentine group Inorganic materials 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229940074386 skatole Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000019721 spearmint oil Nutrition 0.000 description 1
- 239000012177 spermaceti Substances 0.000 description 1
- 229940084106 spermaceti Drugs 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- QJVXKWHHAMZTBY-GCPOEHJPSA-N syringin Chemical compound COC1=CC(\C=C\CO)=CC(OC)=C1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 QJVXKWHHAMZTBY-GCPOEHJPSA-N 0.000 description 1
- 235000010491 tara gum Nutrition 0.000 description 1
- 239000000213 tara gum Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- MBDOYVRWFFCFHM-UHFFFAOYSA-N trans-2-hexenal Natural products CCCC=CC=O MBDOYVRWFFCFHM-UHFFFAOYSA-N 0.000 description 1
- DKZBBWMURDFHNE-UHFFFAOYSA-N trans-coniferylaldehyde Natural products COC1=CC(C=CC=O)=CC=C1O DKZBBWMURDFHNE-UHFFFAOYSA-N 0.000 description 1
- NSSALFVIQPAIQK-UHFFFAOYSA-N trans-non-2-en-1-ol Natural products CCCCCCC=CCO NSSALFVIQPAIQK-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- USFMMZYROHDWPJ-UHFFFAOYSA-N trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium Chemical compound CC(=C)C(=O)OCC[N+](C)(C)C USFMMZYROHDWPJ-UHFFFAOYSA-N 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- WJUFSDZVCOTFON-UHFFFAOYSA-N veratraldehyde Chemical compound COC1=CC=C(C=O)C=C1OC WJUFSDZVCOTFON-UHFFFAOYSA-N 0.000 description 1
- 235000020047 vermouth Nutrition 0.000 description 1
- 239000010679 vetiver oil Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 239000009637 wintergreen oil Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- OJYLAHXKWMRDGS-UHFFFAOYSA-N zingerone Chemical compound COC1=CC(CCC(C)=O)=CC=C1O OJYLAHXKWMRDGS-UHFFFAOYSA-N 0.000 description 1
- 229930007850 β-damascenone Natural products 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
Definitions
- the present invention relates to a solid, particulate composition
- a solid, particulate composition comprising at least one water-soluble or water-dispersible carrier polymer, at least one perfume and from 1, 1 to 40.0 wt .-% phyllosilicate.
- the invention relates to processes for the preparation of the solid composition, as well as a detergent or cleaning agent containing the solid
- composition contains. Moreover, the present invention also relates to the use of such a washing or cleaning agent for cleaning textiles or hard surfaces and corresponding methods for cleaning textiles or hard surfaces using such a washing or cleaning agent. The invention also relates to solid, particulate compositions which have been prepared by the process according to the invention.
- the consumer In the use of detergents and cleaners, the consumer not only aims to wash, cleanse or care for the objects to be treated, but also desires that the treated objects, e.g. Textiles, after the treatment, for example after the wash, smell pleasant. For this reason in particular, most commercially available detergents and cleaners contain fragrances.
- fragrances are used in the form of perfume particles either as an integral part of a washing or cleaning agent, or dosed directly into the washing drum at the beginning of a wash cycle in a separate form. In this way, the consumer can control the fragrance of the laundry to be washed by individual dosage. By replacing the wash liquor several times in the course of a wash cycle, however, the majority of the metered perfume particles is dissolved, even before the last rinse, whereby only an insufficient scenting of the washed laundry can be achieved.
- compositions which, in the case of objects to be treated, preferably textiles, enable improved scenting of the object, with the scent intensity as well as the sense of freshness over a long period of time being to be perceived as pleasant.
- fragrance compositions are already known in the art. They are usually prepared as a melt and then dropped by means of a nozzle on a cooling belt, where they should solidify as quickly as possible and take a nice geometric figure. With conventional products, it is frequently observed that their melt, after being dropped on the cooling belt, runs off into unsightly particles with a small layer thickness. Thus, it is problematic to produce uniform products, let alone for the consumer visually appealing products.
- lozenges having a height / diameter ratio of 0.5, since this example, a
- melt products have the disadvantage that they can break during transport and storage or that caused by breaking the thin edges much unwanted abrasion.
- a solid, particulate composition comprising at least one water-soluble or water-dispersible carrier polymer having a
- the inventors of the present invention have surprisingly found that the incorporation of 1, 1 to 40.0 wt .-% phyllosilicate can eliminate the problems described above.
- the composition gives an aesthetic and abrasion-resistant product.
- washing process improved.
- the inventors have found that the washed textiles not only smoother, but are also softer than textiles washed with comparable detergents. Without wishing to be bound by theory, this could be due to a prolonged release of the phyllosilicate, which surprisingly is achieved by incorporation into the solid, particulate composition.
- the present invention is directed to the use of the solid composition as described herein as a fabric care, preferably fragrance and / or fabric softener, conditioner and / or conditioner for fabrics.
- the present invention is further directed to a laundry or cleaning composition comprising a solid composition as described herein and a method of making the compositions of the invention.
- compositions of the invention are also hereby disclosed for the other aspects of the invention.
- At least one refers to 1 or more, for example, 1, 2, 3, 4, 5, 6, 7, 8, 9 or more, more particularly, this indication refers to the type of agent / compound and not the absolute number of molecules. "At least one perfume”, therefore, means that at least one type of perfume is detected but may also contain 2 or more different types of perfume.
- a first object of the present invention is a solid, particulate composition
- a solid, particulate composition comprising at least one water-soluble or water-dispersible carrier polymer having a Melting point> 30 ° C to 250 ° C, preferably> 40 ° C to 150 ° C, preferably selected from polyalkylene glycols, more preferably polyethylene glycol, and at least one perfume, characterized in that the composition 1, 1 to 40.0 wt. % Phyllosilicate.
- at least one inorganic salt is further included.
- layered silicate refers to silicates whose silicate anions consist of layers of corner-sharing SiC tetrahedra, which layers are not linked to each other by further Si-O bonds to form scaffolds to avoid misunderstanding, zeolites not covered by the term layered silicate
- Phyllosilicates include important groups of rock-forming minerals such.
- the technically important and in sedimentary rocks widespread clay minerals are also phyllosilicates.
- Phyllosilicate preferably the clay mineral, is present in an amount of from 1.1% to 40.0% by weight, preferably from 1.5 to 38% by weight, more preferably from 5 to 35% by weight. %, more preferably from 15 to 30 wt .-%, in particular from 18 to 22 wt .-% in each case based on the total solid composition.
- composition may comprise a layered silicate or a mixture of multiple layered silicates, as long as the limits described herein are not exceeded.
- crystalline layered silicates of general formula NaMSix02x + i ⁇ y H2O are used, wherein M is sodium or hydrogen, x is a number from 1, 9 to 22, preferably from 1: 9 to 4, particularly preferred values for x being 2, 3 or 4, and y is a number from 0 to 33, preferably from 0 to 20.
- the crystalline layered silicates of the formula NaMSix02x + i ⁇ y H2O for example, by Clariant GmbH (Germany) under the trade name Na-SKS.
- silicates Na-SKS-1 (Na2Si22045 ⁇ x H2O, kenyaite), Na-SKS-2 (Na2 Sii40 2 9 ⁇ x H2O, magadiite), Na-SKS-3 (Na 2 Si 8 0i7 ⁇ x H2O) or Na-SKS-4 (Na 2 Si 4 09 ⁇ x H20, Makatite).
- a montmorillonite-based clay mineral in particular a bentonite
- a bentonite is used as the silicate.
- An equally suitable clay material is, for example, a smectite clay.
- Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof.
- Montmorillonite clays are the preferred clays.
- Bentonites contain mainly montmorillonites. The bentonites can be used as powder or crystals.
- Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa.
- the layered silicate comprises clay, especially selected from the group consisting of smectites, montmorillonites, bentonites, kaolinites, saponite, hectorite and / or mixtures thereof.
- the layered silicate is native layered silicate and / or organo-modified layered silicate.
- the layered silicate is native layered silicate and / or organo-modified layered silicate.
- the layered silicate is native layered silicate and / or organo-modified layered silicate.
- the layered silicate is native layered silicate and / or organo-modified layered silicate.
- the layered silicate is native layered silicate and / or organo-modified layered silicate.
- the layered silicate is native layered silicate and / or organo-modified layered silicate.
- organomodified phyllosilicate
- layered silicate is meant layered silicate which has not been subjected to any particular organomodification.
- the layered silicate comprises clay, in particular selected from the group consisting of smectites, montmorillonites, bentonites, kaolinites, saponite, hectorite and / or mixtures thereof, and the phyllosilicate is native phyllosilicate and / or organomodified phyllosilicate.
- the composition is characterized in that the layered silicate is selected from the group consisting of magnesium or sodium magnesium phyllosilicates.
- Clay minerals such as montmorillonites are particularly preferred according to the invention.
- particularly preferred sheet silicates are the magnesium available under the trade name Laponite ® or sodium magnesium layer silicates from Solvay Alkali, in particular Laponite ® RD or Laponite ® RDS, and magnesium silicates from Süd-Chemie, especially the Optigel® ® SH.
- the composition is characterized in that the composition further contains no inorganic salts.
- the composition is characterized in that the composition further contains an inorganic salt.
- the at least one inorganic salt contained in preferred embodiments may be any inorganic salt consisting of at least one cationic component and at least one anionic component.
- the cationic component may be selected from the metals of Groups 1-15 of the Periodic Table (CAS Groups IA, IIA, INA, IVA, VA, HIB, IVB, VB, VIB, VIIB, VIIIB, IB, IIB and main groups IV and transition metals, respectively ). In various embodiments, it is mono-, di- or trivalent cations.
- the cationic component is selected from Na + , K + , Mg 2+ , Al 3+ , Ca 2+ , Fe 2+ , Fe 3+ , Cu + , Cu 2+ , and Zn 2+ . In further embodiments, the cationic component is selected from Na + , K + , Mg 2+ , Ca 2+ , especially Na + and K + .
- the anionic component may be any anion selected, without limitation, from the group consisting of inorganic anions such as P, Cr, Br, I “ , OH “ , HSOs “ , SOs 2" , SC 2 " , HSOv, N0 2 - , NOs, "PC 3", HPO 4 2 -, H2PO4-, BPr, PF 6 ", CIO4" S1O4 "HCO3- and C0 3 2_.
- the anionic component is preferably halide, SO4 2 " , PO4 3" , HCO3 " and
- the at least one inorganic salt is preferably selected from the group consisting of alkali or alkaline earth metal salts, especially carbonates, sulfates, halides or phosphates. Particularly preferred is selected from sodium sulfate, sodium carbonate, sodium bicarbonate, sodium diphosphate and
- sodium aluminosilicates of the formula (Na 2 O) x. Al 2 O 3. (SiO 2) y . (H 2 O) z , where x is a number from 0.7 to 1.5, y is a number from 1.3 to 4 and z is one Number is from 1 to 6, and magnesium silicate.
- the corresponding potassium salts can also be used.
- mixtures of one or more of the aforementioned inorganic salts are also be used.
- the inorganic salt is not the layered silicate of the present invention.
- the at least one inorganic salt as defined herein is present in an amount of 0.01 to 30% by weight, preferably in an amount of 1 to 30% by weight, based on the total weight of the composition , used. In various embodiments, the at least one inorganic salt is included in the composition in an amount of 10 to 25 weight percent.
- composition of the invention does not comprise
- compositions according to the invention does not comprise a polysaccharide.
- the composition according to the invention does not comprise fumed silica.
- the composition of the invention comprises no precipitated silica.
- the composition of the invention may not comprise polysaccharide, fumed silica, and precipitated silica.
- the composition comprises at least one polysaccharide, at least one fumed silica and / or at least one precipitated silica.
- the at least one polysaccharide which may be included in the composition according to the present invention may be of plant or animal origin or a product of the metabolism of microorganisms as well as a degradation and modification product thereof.
- the polysaccharide is selected from the group consisting of glycogen, starch, callose, cellulose, tunicin, pectin, algin, inulin, chitin, chitosan, heparin, carrageenan, agar, gum arabic, tragacanth, locust bean gum, karaya gum, ghatti - Rubber, Guar Gum, Tara Gum, Gellan, Xanthan, Dextran, Sucrose, Nigeran and
- Pentosans such as xylan and araban, derivatives or mixtures thereof.
- Glycogen starch (amylose and amylopectin), callose, cellulose, tunicin, pectin (s), algin, inulin, chitin, chitosan, heparin, carrageenan, agar, gum arabic, tragacanth, locust bean gum, karaya gum, ghatti gum, guar gum Gum, tara gum, gellan, xanthan, dextran, sucrose, nigeran and pentosans such as xylan and araban, the main constituents of which are D-glucuronic acid, D-galacturonic acid, D-galacturonic acid methyl ester, D-mannuronic acid, L-guluronic acid, D- and L- Galactose, 3,6-anhydro-D-galactose, L-arabinose, L-rhamnose, D-glucuronic acid, D-xylose, L-fucose, D-mannose
- chemically modified polysaccharides include, without limitation, propylcellulose, methylethylcellulose, carboxymethylcellulose,
- Hydroxypropylcellulose hydroxypropylmethylcellulose, carboxymethylhydroxyethylcellulose, sulfoethylcellulose, carboxymethylsulfoethylcellulose, hydroxypropylsulfoethylcellulose,
- Hydroxyethylsulfoethylcellulose methylethylhydroxyethylcellulose, methylsulfoethylcellulose and ethylsulfoethylcellulose.
- the at least one polysaccharide is preferably starch, thermally and / or mechanically treated starch, oxidatively, hydrolytically or oxidized enzymatically degraded starches, oxidized hydrolytic or oxidized enzymatically degraded starches and chemically modified starches.
- starch may be, without limitation, corn, wheat, rice, peas, barley, rye, manioc, tapioca, sweet potatoes, or potatoes.
- native starch is preferably used. As native starch is called starch, as it is accessible from natural, for example, the aforementioned, sources. Native starch is a commercial product and thus easily accessible.
- the at least one polysaccharide is maize, wheat, rice, pea, barley, rye, manioc, tapioca, sweet potato or potato starch.
- the at least one polysaccharide is the corresponding native starch of the abovementioned type. Mixtures of the abovementioned are also suitable.
- the at least one polysaccharide is preferably maize starch, in particular native maize starch. Most preferred is the corn starch Collamyl 8412 from Agrabne Wien.
- fumed silicas are those marketed by Evonik under the trade name Aerosil ® products, in particular of the type Aerosil ® 200; examples for
- inventively preferred precipitated silicas are for example marketed by Evonik under the trade name Sipernat ® products, in particular of the Sipernat ® 22S.
- the fused bodies of the invention contain only each one of these ingredients.
- the at least one polysaccharide is included in the composition in an amount of 10 to 25% by weight, especially 20 to 25% by weight.
- the fumed or precipitated silica is included in the composition in an amount of 1 to 10 wt%, especially 2 to 7 wt%.
- the main component of the solid particulate composition according to the present invention is at least one water-soluble or water-dispersible one Carrier polymer. In various embodiments, this is characterized by at least one
- Carrier polymer characterized in that it has a melting point of 48 ° C to 120 ° C, preferably from 48 ° C to 80 ° C.
- Water Soluble as used herein means a solubility in water at 20 ° C of at least 1 g / L, preferably at least 10 g / L, more preferably at least 50 g / L.
- Water-dispersible as used herein means that the carrier polymer can be dispersed by known methods in water at a temperature of 20 ° C.
- the at least one carrier polymer is preferably selected from polyalkylene glycols.
- those polyalkylene glycols are suitable which have an average molar mass of> 1000 g / mol, in particular> 1500 g / mol, preferably between 3000 and 15,000, more preferably an average molar mass between 4000 and 13000 and
- an average molar mass is between 9,000 and 13,000, most preferably 1,000 to 13,000 or 1,500 to 12,500.
- polyalkyl glycols are suitable which have a melting point between 40 ° C and 90 ° C, in particular in the range of 45 to 70 ° C. examples for
- Polyalkylene glycols suitable in the context of the present invention are:
- Polyalkylene glycols in particular the aforementioned.
- polyalkylene glycols which have an average molar mass of> 1000 g / mol, in particular> 1500 g / mol, preferably between 3000 and 15,000, more preferably an average molar mass between 3000 and 13000 and particularly preferably one average molar mass between 3,000 and 9,000, more preferably an average molar mass between preferably 3,500 to 9,000, in particular between 4,000 to 8,000, most preferably between 6,000 to 8,000.
- those polyalkyl glycols are suitable which have a
- polyalkylene glycols useful in the context of the present invention are polypropylene glycol and polyethylene glycol, as well as block copolymers of various types
- Polyalkylene glycols in particular the aforementioned.
- Preferred commercial products are e.g. Pluriol E 4000, Pluriol E 6000 and Pluriol E 8000 (BASF).
- the at least one carrier polymer is preferably polyethylene glycol.
- the at least one carrier polymer is a polyethylene glycol having an average molar mass of> 1500 g / mol, preferably between 3,000 and 15,000, more preferably with an average molar mass between 4,000 and 13,000, and most preferably with an intermediate molar Mass between 6,000 and 8,000 or 9,000 to 13,000.
- the at least one carrier polymer is a polyethylene glycol having an average molar mass of> 1500 g / mol, preferably between 3,000 and 15,000, more preferably with an average molar mass between 4,000 and 13,000, and most preferably with an intermediate molar Mass between 6,000 and 8,000 or 9,000 to 13,000.
- the at least one carrier polymer is a polyethylene glycol having an average molar mass of> 1,500 g / mol, preferably between 3,000 and 15,000, especially between 3,500 and 13,000, more preferably an average molar mass between preferably 3,500 to 9,000 , in particular between 4,000 and 8,000, very particularly preferably between 6,000 and 8,000.
- the at least one carrier polymer is preferably polyethylene glycol having an average molecular weight of from 10,000 to 15,000, preferably from 1,000 to 13,000, most preferably from 1,500 to 12,500.
- such a polyethylene glycol is characterized by a
- Melting point in the range of 45 to 70 ° C, preferably 50 to 65 ° C, more preferably 50 to 60 ° C.
- compositions as a carrier polymer in addition to the polyethylene glycol according to the invention or also in place of which at least one alkoxy block copolymer.
- Alkoxy block polymers which are suitable according to the invention are preferably of alternating type
- alkoxy block polymers of the formulas HO- (EO) x (PO) y (EO) z -H, HO- (PO) x (EO) y (PO) z -H, HO- (EO) x (PO) y ( PO) zH, HO- (EO) x (EO) y (PO) zH, HO- (EO) x (BO) y (EO) zH, HO- (EO) x (BO) y (EO) z -H, HO- (BO) x (EO) y (BO) z -H, HO- (EO) x (BO) y (BO) zH, HO- (EO) x (BO) y (BO) zH, HO- (EO) x (BO) y (BO) zH, HO- (EO) x (EO) y (BO) zH, HO- (EO) x (EO) y (BO)
- the block polymers preferably have molecular weights between 4,000 and 20,000, in particular 5,000 to 7,000 g / mol.
- Particular preferred are pure EO-PO block copolymers as for example marketed by BASF under the trade name Pluronic ®.
- Pluronic ® PE 6800 is an inventively particularly preferred Alkoxyblockcopolymer.
- the solid compositions contain as carrier polymer at least one polyethylene glycol having an average molar mass of 10,000 to 15,000 and are optionally formulated free of EO-PO block copolymers. It may likewise be preferred according to the invention if the solid preparations comprise at least one EO-PO block copolymer as the carrier polymer and are optionally formulated free of polyethylene glycols having an average molar mass of from 10,000 to 15,000. In a third embodiment, however, it may also be preferred for the solid compositions to contain as carrier material a mixture of at least one EO-PO block copolymer and at least one polyethylene glycol having an average molar mass of from 10,000 to 15,000.
- the at least one carrier polymer or the mixture of various carrier polymers is in an amount of 30 to 95 wt .-%, preferably from 35 to 85 wt .-%, for example 40 to 80 or 40 to 78 wt .-% in the Composition based on the total weight of the composition.
- water-soluble carrier polymer is a polyalkylene glycol, particularly preferably from the
- Polyethylene glycols having an average molar mass in the range of 10,000 to 15,000, preferably from 1 1 .000 to 13,000, most preferably from 1 1 .500 to 12,500, and the composition further comprises at least one active ingredient selected from the group of Polyethlyenglykole with a average molar mass greater than 16,000, the fatty alcohol alkoxylates having at least 10 C atoms in the fatty chain and at least 10 alkoxy units, the alkoxylated castor oils having at least 5 alkoxy units and the alkoxy block copolymers.
- a fragrance is an odor-causing chemical substance.
- the chemical substance should be at least partially redistributable in the air, ie the fragrance should be volatile at 25 ° C, at least to a small extent. If the fragrance is now very volatile, the odor intensity then quickly decreases again. At a lower volatility, the smell impression is more sustainable, ie it does not disappear so quickly.
- the perfume has a melting point that is within the range of -100 ° C to 100 ° C, preferably from -80 ° C to 80 ° C more preferably from -20 ° C to 50 ° C, especially from -30 ° C to 20 ° C.
- the fragrance has a boiling point ranging from 25 ° C to 400 ° C, preferably from 50 ° C to 380 ° C, more preferably from 75 ° C to 350 ° C, especially from 100 ° C to 330 ° C lies.
- the fragrance has a molecular weight of 40 to 700 g / mol, more preferably 60 to 400 g / mol.
- fragrance The smell of a fragrance is perceived by most people as pleasant and often corresponds to the smell of, for example, flowers, fruits, spices, bark, resin, leaves, grasses, mosses and roots. Thus, fragrances can also be used to superimpose unpleasant odors or even to provide a non-smelling substance with a desired odor.
- perfumes individual perfume compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and type
- Hydrocarbons are used.
- Fragrance compounds of the aldehyde type are, for example, adoxal (2,6,10-trimethyl-9-undecenal), anisaldehyde (4-methoxybenzaldehyde), cymal (3- (4-isopropyl-phenyl) -2-methylpropanal), ethylvanillin, florhydral ( 3- (3-isopropylphenyl) butanal), helional (3- (3,4-methylenedioxyphenyl) -2-methylpropanal), heliotropin, hydroxycitronellal, lauraldehyde, lyral (3- and 4- (4-hydroxy-4-methylpentyl) - 3-cyclohexene-1-carboxaldehyde), methylnonylacetaldehyde, lilial (3- (4-tert-butylphenyl) -2-methylpropanal), phenylacetaldehyde, undecylenealdehyde, vanill
- Ketone-type perfume compounds are, for example, methyl-beta-naphthyl ketone, muskedanone-1-one (2,3,3,6,7-hexahydro-1,1,3,3,3-pentamethyl-4H-inden-4-one), Tonalid (6-acetyl-1,1,1,4,4,7-hexamethyltetralin), alpha-damascone, beta-damascone, delta-damascone, iso-damascone, damascenone, methyldihydrojasmonate, menthone, carvone, camphor, koavon (3 , 4,5,6,6-pentamethylhept-3-en-2-one), fenchone, alpha-ionone, beta- lonone, gamma-methyl-ionone, fleuramon (2-heptylcyclopentanone), dihydrojasmon, cis-jasmone , Iso-E-
- Fragrance compounds of the alcohol type are, for example, 10-undecen-1-ol, 2,6-dimethylheptan-2-ol, 2-methylbutanol, 2-methylpentanol, 2-phenoxyethanol, 2-phenylpropanol, 2-tert-butycyclohexanol, 3,5,5-trimethylcyclohexanol, 3-hexanol, 3-methyl-5-phenyl-pentanol, 3 Octanol, 3-phenyl-propanol, 4-heptenol, 4-isopropyl-cyclohexanol, 4-tert-butylcyclohexanol, 6,8-dimethyl-2-nonanol, 6-nonene-1-ol, 9-decene-1 -ol, ⁇ -methylbenzyl alcohol, ⁇ -terpineol,
- Fragrance type ester compounds are e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate,
- DMBCA dimethylbenzylcarbinylacetate
- Ethers include, for example, benzyl ethyl ether and ambroxan.
- Hydrocarbons mainly include terpenes such as limonene and pinene.
- perfume oils may also contain natural perfume mixtures as are available from plant sources.
- Fragrances of plant origin include essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, champacilla oil, citrus oil, fir pine oil, pinecone oil, elemi oil, eucalyptus oil, fennel oil, pine needle oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil, gurdy balm oil, helichrysum oil, Ho oil , Ginger oil, iris oil, jasmin oil, cajeput oil,
- Methyl anthranilate p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-beta-naphthyl ketone, methyl-n-nonylacetaldehyde, methyl n-nonyl ketone, muscone, beta-naphthol ethyl ether, beta-naphthol methyl ether, nerol, n-nonyl aldehyde, nonyl alcohol, n-octylaldehyde, p-oxyacetophenone, pentadecanolide, beta-phenylethyl alcohol, phenylacetic acid, pulegone, safrole, isoamyl salicylate, methyl salicylate, salicylic acid hexyl ester, cyclohexyl salicylate, santalol, sandelice, skatole, terpine
- Cinnamic acid ethyl ester Cinnamic acid ethyl ester, cinnamic acid benzyl ester, diphenyloxide, limonene, linalool, linalyl acetate and propionate, melusate, menthol, menthone, methyl-n-heptenone, pinene, phenylacetaldehyde,
- perfume precursor or in encapsulated form (perfume capsules), especially in microcapsules.
- the microcapsules may be water-soluble and / or water-insoluble microcapsules.
- melamine-urea-formaldehyde microcapsules, melamine-formaldehyde microcapsules, urea-formaldehyde microcapsules, or starch microcapsules can be used.
- Perfume precursor refers to compounds that undergo chemical conversion / cleavage, typically by the action of light or other environmental conditions, such as pH, temperature, etc., to release the actual fragrance Such compounds are often referred to as fragrance or "fragrance fragrance".
- the amount of perfume in the composition according to the present invention is preferably between 1 and 20% by weight, preferably between 1 and 15% by weight, in particular between 3 and 10% by weight. based on the
- the solid preparation may contain at least one amorphous silicate or zeolite.
- amorphous sodium silicates with a Na 2 U: SiO 2 modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8, and in particular from 1: 2 to 1: 2.6.
- the term "amorphous" is understood to mean that the silicates do not yield sharp X-ray reflections in X-ray diffraction experiments, as they are typical for crystalline substances, but instead possibly one or more maxima of the scattered X-radiation, which have a width of several degrees of the diffraction angle, cause.
- X-ray-amorphous silicates are used whose silicate particles give washed-out or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of the size of ten to a few hundred nm, with values of up to max. 50 nm and in particular up to max. 20 nm are preferred.
- Such X-ray amorphous silicates also have a dissolution delay compared to conventional water glasses. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.
- the fuser composition as described herein may further comprise at least one fabric conditioning compound.
- a textile care compound is understood to mean any compound which gives textile fabrics treated therewith a beneficial effect, such as, for example, a textile softening effect, crease resistance or the harmful or negative effects which result during cleaning and / or conditioning and / or or wearing, such as
- the fabric care composition may preferably be made of fabric softening compounds, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, wrinkle inhibitors, color transfer inhibitors, antimicrobials, germicides, fungicides, antioxidants, antistatic agents, ironing aids, phobizers and the like Impregnating agents, swelling and slipping agents, UV absorbers and mixtures thereof are selected.
- the fabric care compound is a fabric softening compound. It is most preferred that the fabric softening compound is selected from polysiloxanes, fabric softening clays, cationic polymers and mixtures thereof.
- the use of polysiloxanes and / or cationic polymers as a fabric care compound in the fuser composition is advantageous because it not only exhibits a softening effect but also enhances the perfume impression on the wash.
- the use of softening clays as textile-care compound in the melted body composition is advantageous because they additionally have a water-softening effect and thus, for example, limescale deposits on the laundry can be prevented.
- the fusible composition contain a combination of at least two fabric care compounds.
- the fused-state composition according to the invention contains such textile-care compounds, it is used in particular as a textile care agent or softener or as a constituent of such an agent or else as a constituent of a detergent.
- Such a fabric conditioner may be in the main wash of an automatic washing or
- the enamel composition may be added to the drum or dispenser compartment of a washing machine along with the detergent or cleaning agent. This has the advantage that no additional rinse is necessary and no unsightly deposits occur in the dispenser
- Laundry cleaning process can be used and so the textile-care compound and the perfume already at the beginning of the washing process to transport laundry, so as to be able to develop their full potential.
- the enamel composition according to the invention is simpler and easier to handle than liquid compositions, since no drops remain on the edge of the bottle, which lead to edges on the substrate during subsequent storage of the bottle or to unsightly deposits in the region of the closure. The same is true in the case where some of the enamel body composition is accidentally spilled during dosing. The spilled amount can also be removed easier and cleaner.
- a preferably usable polysiloxane has at least the following structural unit
- R independently of one another C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
- n 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.
- polysiloxane additionally has the following structural unit:
- R is C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
- R 2 , R 3 independently of one another are H or optionally substituted, linear or branched C 1 -C 30 -alkyl, preferably C 1 -C 30 -alkyl which is substituted by amino groups, especially
- x 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.
- Polydimethylpolysiloxanes are known as efficient fabric care compounds.
- Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50,
- polysiloxane contains the structural units a) and b).
- a particularly preferred polysiloxane has the following structure:
- Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention are also suitable for example the products commercially available Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).
- Suitable textile-softening clays are the smectite clays already described above, in particular bentonite.
- Suitable cationic polymers include, in particular, those described in "CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, JM Nikitakis, et al., Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991, and the collective name "Polyquaternium Below are some of the more suitable Polyquaternium compounds.
- Celquat® H 100 or Celquat® L200 available as Celquat® H 100 or Celquat® L200 (ex National Starch)
- POLYQUATERNIUM-1 1 (CAS number: 53633-54-8) Definition: Quaternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate.
- Quaternary ammonium polymer salt obtainable by reaction of the ethyl methacrylate / -abietyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate
- Polymeric quaternary ammonium salt which is obtainable by reaction of azelaic acid and dimethylaminopropylamine with dichloroethyl ether.
- Polymeric quaternary ammonium salt which is obtainable by reaction of polyvinyl alcohol with 2,3-epoxypropylamine.
- Polymeric quaternary ammonium salt obtainable by reaction of polyvinyl octadecyl ether with 2,3-epoxypropylamine.
- POLYQUATERNIUM-21 (CAS number: 102523-94-4)
- Synthalen® CR (ex 3V Sigma)
- the melted body composition contains a fabric softening compound and one or more other fabric care compounds.
- the amount of fabric care compound in the fuser composition may, in various embodiments, be from 0.1 to 15 weight percent, and preferably from 2 to 12 weight percent.
- the fuser composition may optionally contain other ingredients. To the application-technical and / or aesthetic characteristics independently of her
- Purpose to improve these additional ingredients are preferably selected from the group consisting of dyes, pearlescing agents, skin-care compounds, bittering agents and mixtures thereof.
- the enamel composition In order to improve the aesthetic impression of the enamel composition, it can be colored with suitable dyes.
- Preferred dyes the selection of which presents no difficulty to the skilled person, should have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
- the enamel composition may also contain a pearlescer to increase gloss.
- suitable pearlescing agents are ethylene glycol mono- and distearate and PEG-3-distearate.
- the enamel composition may comprise a skin care compound.
- a skin care compound is a compound or mixture of
- the skin care compound is preferably hydrophobic, may be liquid or solid, and must be compatible with the other ingredients of the solid fused body composition.
- the skin care compound a) waxes such as carnauba, spermaceti, beeswax, lanolin, derivatives thereof and mixtures thereof;
- Plant extracts for example vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil, hazelnut oil , Jojoba oil or canola oil, chamomile, aloe vera and mixtures thereof;
- vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil, hazelnut oil , Jojoba oil or canola oil, chamomile, aloe vera and mixtures thereof
- higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid or polyunsaturated fatty acids
- higher fatty alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol,
- esters such as cetyloctanoate, lauryl lactate, myristyl lactate, cetyl lactate, isopropyl myristate,
- Cholesterol isostearate glycerol monostearate, glyceryl distearate, glycerol tristearate, alkyl lactate, alkyl citrate or alkyl tartrate;
- hydrocarbons such as paraffins, mineral oils, squalane or squalene
- vitamins such as vitamins A, C or E or vitamin alkyl esters
- sunscreens such as octyl methoxyl cinnamate and butyl methoxybenzoyl methane;
- silicone oils such as linear or cyclic polydimethylsiloxanes, amino-, alkyl-, alkylaryl- or aryl-substituted silicone oils and
- the amount of skin-care compound is preferably between 0.01 and 10% by weight, preferably between 0.1 and 5% by weight and very particularly preferably between 0.3 and 3% by weight, based on the total weight of the enamel body. Composition. It may be that the skin-nourishing compound additionally has a textile care effect.
- the enamel composition may contain a bittering agent such as Bitrex®.
- Example formulations of suitable enamel compositions include the following ingredients:
- phyllosilicate preferably clay mineral, more preferably bentonite, 0.00 to 30, preferably 10 to 25 wt .-% of an inorganic salt, in particular
- Polysaccharide in particular starch, or from 0.0030 to 30, preferably from 1 to 10, more preferably from 2 to 7,% by weight of a pyrogenic or precipitated silica,
- polyethylene glycol having 4,000 to 15,000 g / mol, preferably 9,000 to 13,000 g / mol as a water-soluble or water-dispersible carrier polymer.
- the fused-state composition according to the present invention is a solid, particulate composition.
- the individual particles of the composition can be referred to as a melting body, which are solid at room temperature and temperatures up to 30 ° C, preferably up to 40 ° C.
- a process for producing such fused bodies can be carried out by means of known batch processes in which the ingredients are mixed and heated together, or one or more of the ingredients are initially charged and heated and then the remaining ingredients are added successively.
- the melt thus obtained can then be subjected to cooling and reshaping.
- methods may be used which include the following steps:
- the at least one polysaccharide (s), and optionally the at least one inorganic salt in step (a), in step (b) or one or more separate steps (b1), (b2), etc., respectively or after step (b) or (c) can be metered.
- the mixing step (c) can then take place after each metering step or only after one or more metering steps.
- the fusible bodies produced in this way can have any desired shape.
- the shaping takes place in particular in step (d) of the described method.
- solid, particulate forms are preferred, such as, for example, substantially spherical, figural, flaky, cuboid, cylindrical, conical, spherical cap or lenticular, hemispherical, disc or needle-shaped particles or even figurative forms.
- the particles may have a gummy-like, figurative design.
- the maximum extent of the particles in a spatial dimension is preferably from 0.5 to 10 mm, in particular 0.8 to 8 mm, particularly preferably 1 to 7 mm and most preferably 2 to 6 mm.
- the diameter of the particles is from 0.5 to 10 mm, in particular 0.8 to 8 mm, more preferably 1 to 7 mm and most preferably 2 to 6 mm.
- the height of the particles is preferably from 0.5 to 6 mm, in particular 0.8 to 5 mm, particularly preferably 1 to 4 mm and very particularly preferably 1 to 5 to 3 mm ,
- the weight of the individual particles is between 2 and 150 mg, preferably between 5 and 10 mg.
- carrier polymer As used herein, when referring to carrier polymer is meant the water-soluble or water-dispersible carrier polymer of the present invention unless the context implies otherwise.
- the melting in step (a) of the processes described herein is accomplished by heating to a temperature not more than 20 ° C above the melting point of the carrier polymer.
- the melting can be carried out using all customary methods and devices known to the person skilled in the art.
- the melt containing the at least one carrier polymer is produced, for example, continuously by the at least one carrier polymer and optionally further constituents of the melt body being continuously fed to a corresponding device in which it is heated and the melt thus produced is further conveyed, for example pumped.
- the at least one perfume can then be added continuously to the melt.
- the at least one perfume is preferably used in liquid form, for example as perfume oil, solution in a suitable solvent or as a slurry of perfume capsules in a typically water-containing solvent.
- "Liquid” as used in this context means liquid under the conditions of use , preferably liquid at 20 ° C.
- the flow can optionally be measured by measuring the flow rate of the individual metered streams, i. the melt, the perfume stream and possibly other ingredient streams are controlled. This also allows, for example, the proportions of the individual metered streams, i. the melt, the perfume stream and possibly other ingredient streams are controlled. This also allows, for example, the proportions of the individual metered streams, i. the melt, the perfume stream and possibly other ingredient streams are controlled. This also allows, for example, the proportions of the individual metered streams, i. the melt, the perfume stream and possibly other ingredient streams are controlled. This also allows, for example, the proportions of the individual
- the ingredients besides the carrier polymer (s) and fragrances can either be produced directly with the carrier polymer together as a melt, be dosed with the fragrances together or separately to the melt. In the latter alternative the metered addition can be carried out before or after addition of the fragrances.
- pyrogenic / precipitated silica and optionally also the at least one inorganic salt are added together or separately from one another in step (a) or step (b) or one or more further steps. It is also possible to choose one of the two aforementioned
- the mixing of the combined metering streams can then be carried out in each case directly after metering or downstream after metering in several or all of the ingredients with suitable mixers, such as customary static or dynamic mixing units.
- the melt which contains the carrier polymer, the fragrances and the phyllosilicate and optionally further ingredients, in particular at least one polysaccharide and / or the at least one pyrogenic or precipitated silica, and / or inorganic salts, is cooled and optionally subjected to transformation fed, where the melt solidifies and receives its final shape.
- suitable methods for shaping are known to the person skilled in the art. Usual forms have already been described above.
- the invention also relates to the use of the solid particulate described herein
- Composition as a textile care agent, preferably fragrancing and / or fabric softener, for scenting and / or conditioning textile fabrics.
- the enamel bodies may be a textile treatment agent, such as, for example, a fabric softener or a part of such an agent.
- the invention relates to a washing or cleaning agent comprising the composition according to the invention.
- composition of the invention By introducing the composition of the invention into a washing or
- Detergent is the consumer a textile-care washing or cleaning agent ("2in1" washing or cleaning agent) available and he does not need to dose two agents and no separate rinse Since the compositions according to the invention are perfumed, not washing This not only results in lower costs, but is also beneficial for consumers with sensitive skin and / or allergies.
- 2in1 textile-care washing or cleaning agent
- the fused-state compositions described herein are particularly suitable for conditioning textile fabrics and are used together with a conventional washing or cleaning agents in the (main) wash of a conventional washing and cleaning process brought into contact with the fabrics.
- Detergent a solid detergent or cleaning agent is preferably mixed with 1 to 20 wt .-%, in particular with 5 to 15 wt .-%, of the composition according to the invention.
- compositions according to the invention are also based on processes for the preparation thereof, the washing and cleaning compositions containing them
- the present invention also relates to fused bodies which have been produced by the process according to the invention.
- Example 1 Formulation of Enamel Formulations
- the layered silicates were incorporated under high shear (5 min Ultra-Turrax at 6500 min "1 ) into the melt of the PEG at 80 ° C.
- the melt viscosity is determined using a rotary rheometer (TA-Instruments, AR G2) with a PP measuring system 40 mm at a shear stress of 3 Pa and at a temperature of 60 ° C.
- Pastilles were prepared from the formulations by dropping the melts through a 2 mm diameter die at a temperature of 60 ° C. from a height of 2 cm onto a steel sheet tempered to 25 ° C.
- the resulting pastilles have on average the following dimensions:
- formulations according to the invention have a more favorable diameter / height ratio.
- E1 and E2 provide almost hemispherical lozenges. Thus, they are subject to a lower edge breakage and act more aesthetically.
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Abstract
The invention relates to a solid, particulate composition comprising at least one water-soluble or water-dispersible carrier polymer, at least one fragrance, and 1.1 to 40 wt% layer silicate. The invention further relates to a method for producing the solid composition, and to a washing or cleaning agent containing the solid composition. The invention further relates to the use of such a washing or cleaning agent for cleaning textiles or hard surfaces, and to corresponding methods for cleaning textiles or hard surfaces using such a washing or cleaning agent.
Description
FESTE PARTIKULÄRE ZUSAMMENSETZUNGEN ENTHALTEND WASSERLÖSLICHES TRÄGERPOLYMER UND PARFÜM SOLID PARTICULAR COMPOSITIONS CONTAINING WATERPROOF CARRIER POLYMER AND PERFUME
Die vorliegende Erfindung betrifft eine feste, partikuläre Zusammensetzung umfassend mindestens ein wasserlösliches oder wasserdispergierbares Trägerpolymer, mindestens einen Duftstoff sowie 1 ,1 bis 40,0 Gew.-% Schichtsilikat. Des Weiteren betrifft die Erfindung Verfahren zur Herstellung der festen Zusammensetzung, sowie ein Wasch- oder Reinigungsmittel, das die feste The present invention relates to a solid, particulate composition comprising at least one water-soluble or water-dispersible carrier polymer, at least one perfume and from 1, 1 to 40.0 wt .-% phyllosilicate. Furthermore, the invention relates to processes for the preparation of the solid composition, as well as a detergent or cleaning agent containing the solid
Zusammensetzung enthält. Darüber hinaus betrifft die vorliegende Erfindung auch die Verwendung eines solchen Wasch- oder Reinigungsmittels zum Reinigen von Textilien oder harten Oberflächen sowie entsprechende Verfahren zum Reinigen von Textilien oder harten Oberflächen unter Verwendung eines solchen Wasch- oder Reinigungsmittels. Ebenfalls betrifft die Erfindung feste, partikuläre Zusammensetzungen, die mittels dem erfindungsgemäßen Verfahren hergestellt worden sind. Composition contains. Moreover, the present invention also relates to the use of such a washing or cleaning agent for cleaning textiles or hard surfaces and corresponding methods for cleaning textiles or hard surfaces using such a washing or cleaning agent. The invention also relates to solid, particulate compositions which have been prepared by the process according to the invention.
Bei der Anwendung von Wasch- und Reinigungsmitteln verfolgt der Verbraucher nicht nur das Ziel, die zu behandelnden Objekte zu waschen, zu reinigen oder zu pflegen, sondern er wünscht sich auch, dass die behandelten Objekte, wie z.B. Textilien, nach der Behandlung, beispielsweise nach der Wäsche, angenehm riechen. Insbesondere aus diesem Grunde enthalten die meisten kommerziell verfügbaren Wasch- und Reinigungsmittel Duftstoffe. In the use of detergents and cleaners, the consumer not only aims to wash, cleanse or care for the objects to be treated, but also desires that the treated objects, e.g. Textiles, after the treatment, for example after the wash, smell pleasant. For this reason in particular, most commercially available detergents and cleaners contain fragrances.
Die meisten der Duftstoffe sind jedoch leichtflüchtig. Aus diesem Grund verbleibt beim Einsatz herkömmlicher Wasch- oder Reinigungsmittel nach der Anwendung, insbesondere nach dem Waschen, nur ein geringer Anteil des eingesetzten Duftstoffes auf dem behandelten Objekt. Most of the fragrances, however, are volatile. For this reason, when using conventional washing or cleaning agents after use, especially after washing, only a small proportion of the fragrance used remains on the treated object.
Dadurch geht oft nur ein schwacher Duft von dem behandelten Objekt, wie insbesondere der Wäsche, aus, welcher dann bereits nach kurzer Zeit immer schwächer wird. So verschwindet das angenehme Frischegefühl des behandelten Objekts schon nach kurzer Zeit. As a result, often only a faint scent of the treated object, especially the laundry, goes out, which then already weaker after a short time. Thus, the pleasant feeling of freshness of the treated object disappears after a short time.
Oftmals werden Duftstoffe in Form von Duftstoffpartikeln entweder als integraler Bestandteil eines Wasch- oder Reinigungsmittels verwendet, oder aber direkt zu Beginn eines Waschgangs in separater Form in die Waschtrommel dosiert. Auf diese Weise kann der Verbraucher durch individuelle Dosierung die Beduftung der zu waschenden Wäsche kontrollieren.
Durch mehrmaliges Austauschen der Waschflotte im Laufe eines Waschzyklus wird jedoch der Großteil der dosierten Duftstoffpartikel aufgelöst, noch bevor der letzte Spülgang erfolgt, wodurch nur eine unzureichende Beduftung der gewaschenen Wäsche erzielt werden kann. Often fragrances are used in the form of perfume particles either as an integral part of a washing or cleaning agent, or dosed directly into the washing drum at the beginning of a wash cycle in a separate form. In this way, the consumer can control the fragrance of the laundry to be washed by individual dosage. By replacing the wash liquor several times in the course of a wash cycle, however, the majority of the metered perfume particles is dissolved, even before the last rinse, whereby only an insufficient scenting of the washed laundry can be achieved.
Es besteht somit weiterhin ein Bedürfnis nach Zusammensetzungen, welche bei zu behandelnden Objekten, bevorzugt bei Textilien, eine verbesserte Objektbeduftung ermöglichen, wobei besonders die Duftintensität sowie auch das Frischeempfinden über einen langen Zeitraum als angenehm empfunden werden sollen. There is therefore still a need for compositions which, in the case of objects to be treated, preferably textiles, enable improved scenting of the object, with the scent intensity as well as the sense of freshness over a long period of time being to be perceived as pleasant.
Derartige Duftzusammensetzungen sind bereits im Stande der Technik bekannt. Sie werden üblicherweise als Schmelze zubereitet und dann mittels einer Düse auf ein Kühlband getropft, wo sie möglichst schnell erstarren und eine schöne geometrische Figur einnehmen sollen. Bei herkömmlichen Produkten ist häufig zu beobachten, dass deren Schmelze nach dem sie auf das Kühlband getropft sind zu unansehnlichen Partikeln mit geringer Schichtdicke zerlaufen. Dadurch ist es problematisch, einheitliche Produkte, geschweige denn für den Verbraucher optisch ansprechende Produkte herzustellen. Such fragrance compositions are already known in the art. They are usually prepared as a melt and then dropped by means of a nozzle on a cooling belt, where they should solidify as quickly as possible and take a nice geometric figure. With conventional products, it is frequently observed that their melt, after being dropped on the cooling belt, runs off into unsightly particles with a small layer thickness. Thus, it is problematic to produce uniform products, let alone for the consumer visually appealing products.
Besonders wünschenswert wäre es in diesem Zusammenhang, Pastillen herzustellen, die ein Höhen/Durchmesser -Verhältnis von 0,5 aufweisen, da dies beispielsweise einer It would be particularly desirable in this context to produce lozenges having a height / diameter ratio of 0.5, since this example, a
halbkugelförmigen Form entspricht, die vom Verbraucher besonders gut akzeptiert wird. hemispherical shape, which is particularly well accepted by the consumer.
Zudem haben die bekannten Schmelzprodukte den Nachteil, dass sie bei dem Transport und der Lagerung zerbrechen können beziehungsweise, dass durch Abbrechen der dünnen Kanten viel unerwünschter Abrieb entsteht. In addition, the known melt products have the disadvantage that they can break during transport and storage or that caused by breaking the thin edges much unwanted abrasion.
Aufgabe der vorliegenden Erfindung war es daher, die vorstehend genannten Probleme zu überwinden u d geometrisch ansprechende Pastillen zur Objektbeduftung bereit zu stellen ohne deren wäschepflegenden und/oder wäschebduftenden Eigenschaften negativ zu beeinflussen. It was therefore an object of the present invention to overcome the abovementioned problems and to provide geometrically pleasing pastilles for object scenting without negatively influencing their laundry-care and / or laundry-scented properties.
Gelöst werden diese Aufgaben durch eine feste, partikuläre Zusammensetzung umfassend mindestens ein wasserlösliches oder wasserdispergierbares Trägerpolymer mit einem These objects are achieved by a solid, particulate composition comprising at least one water-soluble or water-dispersible carrier polymer having a
Schmelzpunkt >30°C bis 250°C, vorzugsweise >40°C bis 150°C, vorzugsweise ausgewählt aus Polyalkylenglykolen, besonders bevorzugt Polyethylenglykol, und mindestens einen Duftstoff, dadurch gekennzeichnet, dass die Zusammensetzung 1 , 1 bis 40,0 Gew.-% Schichtsilikat umfasst. Melting point> 30 ° C to 250 ° C, preferably> 40 ° C to 150 ° C, preferably selected from polyalkylene glycols, more preferably polyethylene glycol, and at least one perfume, characterized in that the composition 1, 1 to 40.0 wt. % Phyllosilicate.
Die Erfinder der der vorliegenden Erfindung haben überraschend festgestellt, dass sich durch die Einarbeitung von 1 , 1 bis 40,0 Gew.-% Schichtsilikat die oben beschriebenen Probleme beseitigen lassen. Die Zusammensetzung ergibt ein ästhetisches und abriebarmes Produkt.
Das Dufterlebnis des Verbrauchers bei der Verwendung der Zusammensetzung in einem The inventors of the present invention have surprisingly found that the incorporation of 1, 1 to 40.0 wt .-% phyllosilicate can eliminate the problems described above. The composition gives an aesthetic and abrasion-resistant product. The fragrance experience of the consumer when using the composition in one
Waschverfahren verbessert. Überraschender Weise haben die Erfinder festgestellt, dass die gewaschenen Textilien nicht nur angenehmer duften, sondern auch weicher als mit vergleichbaren Waschmitteln gewaschene Textilien sind. Ohne an eine Theorie gebunden sein zu wollen, könnte dies an einer langanhaltenden Freisetzung des Schichtsilikats liegen, die überraschender weise durch die Einarbeitung in die feste, partikuläre Zusammensetzung erzielt wird. Washing process improved. Surprisingly, the inventors have found that the washed textiles not only smoother, but are also softer than textiles washed with comparable detergents. Without wishing to be bound by theory, this could be due to a prolonged release of the phyllosilicate, which surprisingly is achieved by incorporation into the solid, particulate composition.
In einem weiteren Aspekt richtet sich die vorliegende Erfindung auf die Verwendung der festen Zusammensetzung, wie hierin beschrieben, als Textilpflegemittel, vorzugsweise Beduftungsmittel und/oder Weichspüler, zum Beduften und/oder Konditionieren von textilen Flächengebilden. In another aspect, the present invention is directed to the use of the solid composition as described herein as a fabric care, preferably fragrance and / or fabric softener, conditioner and / or conditioner for fabrics.
In noch einem Aspekt richtet sich die vorliegende Erfindung weiterhin auf ein Wasch- oder Reinigungsmittel, umfassend eine feste Zusammensetzung, wie hierin beschrieben und ein Verfahren zur Herstellung der erfindungsgemäßen Zusammensetzungen. In yet another aspect, the present invention is further directed to a laundry or cleaning composition comprising a solid composition as described herein and a method of making the compositions of the invention.
Die hierinstehende Offenbarung zu den erfindungsgemäßen Zusammensetzungen wird hiermit auch für die anderen Aspekte der Erfindung offenbart. The disclosure herein relating to the compositions of the invention is also hereby disclosed for the other aspects of the invention.
Diese und weitere Aspekte, Merkmale und Vorteile der Erfindung werden für den Fachmann aus dem Studium der folgenden detaillierten Beschreibung und Ansprüche ersichtlich. Dabei kann jedes Merkmal aus einem Aspekt der Erfindung in jedem anderen Aspekt der Erfindung eingesetzt werden. Ferner ist es selbstverständlich, dass die hierin enthaltenen Beispiele die Erfindung beschreiben und veranschaulichen sollen, diese aber nicht einschränken und insbesondere die Erfindung nicht auf diese Beispiele beschränkt ist. These and other aspects, features, and advantages of the invention will become apparent to those skilled in the art from a study of the following detailed description and claims. Any feature of one aspect of the invention may be employed in any other aspect of the invention. Further, it is to be understood that the examples contained herein are intended to describe and illustrate the invention, but not to limit it, and in particular that the invention is not limited to these examples.
Alle Prozentangaben sind, sofern nicht anders angegeben, Gewichts-%. Numerische Bereiche, die in dem Format„von x bis y" angegeben sind, schließen die genannten Werte ein. Wenn mehrere bevorzugte numerische Bereiche in diesem Format angegeben sind, ist es selbstverständlich, dass alle Bereiche, die durch die Kombination der verschiedenen Endpunkte entstehen, ebenfalls erfasst werden. All percentages are by weight unless otherwise specified. Numeric ranges specified in the format "from x to y" include the above values.If multiple preferred numeric ranges are specified in this format, it is understood that all ranges resulting from the combination of the various endpoints, also be recorded.
„Mindestens ein", wie hierin verwendet, bezieht sich auf 1 oder mehr, beispielsweise 1 , 2, 3, 4, 5, 6, 7, 8, 9 oder mehr. Insbesondere bezieht sich diese Angabe auf die Art des Mittels/der Verbindung und nicht die absolute Zahl der Moleküle.„Mindestens ein Duftstoff", bedeutet daher, dass mindestens eine Art von Duftstoff erfasst wird, aber auch 2 oder mehr verschiedene Arten von Duftstoffen enthalten sein können. "At least one" as used herein refers to 1 or more, for example, 1, 2, 3, 4, 5, 6, 7, 8, 9 or more, more particularly, this indication refers to the type of agent / compound and not the absolute number of molecules. "At least one perfume", therefore, means that at least one type of perfume is detected but may also contain 2 or more different types of perfume.
Ein erster Gegenstand der vorliegenden Erfindung ist eine feste, partikuläre Zusammensetzung umfassend mindestens ein wasserlösliches oder wasserdispergierbares Trägerpolymer mit einem
Schmelzpunkt >30°C bis 250°C, vorzugsweise >40°C bis 150°C, vorzugsweise ausgewählt aus Polyalkylenglykolen, besonders bevorzugt Polyethylenglykol, und mindestens einen Duftstoff, dadurch gekennzeichnet, dass die Zusammensetzung 1 , 1 bis 40,0 Gew.-% Schichtsilikat umfasst. In bevorzugten Ausführungsformen ist ferner mindestens ein anorganisches Salz enthalten. A first object of the present invention is a solid, particulate composition comprising at least one water-soluble or water-dispersible carrier polymer having a Melting point> 30 ° C to 250 ° C, preferably> 40 ° C to 150 ° C, preferably selected from polyalkylene glycols, more preferably polyethylene glycol, and at least one perfume, characterized in that the composition 1, 1 to 40.0 wt. % Phyllosilicate. In preferred embodiments, at least one inorganic salt is further included.
Der Begriff„Schichtsilikat", wie er hierin verwendet wird, bezeichnet Silikate, deren Silikatanionen aus Schichten eckenverknüpfter SiC -Tetraeder bestehen. Diese Schichten oder Doppelschichten sind untereinander nicht über weitere Si-O-Bindungen zu Gerüsten verknüpft. Zur Vermeidung von Missverständnissen, Zeolithe werden nicht von dem Begriff Schichtsilikat erfasst. Zu den As used herein, the term "layered silicate" refers to silicates whose silicate anions consist of layers of corner-sharing SiC tetrahedra, which layers are not linked to each other by further Si-O bonds to form scaffolds to avoid misunderstanding, zeolites not covered by the term layered silicate
Schichtsilikaten zählen bedeutende Gruppen gesteinsbildender Minerale wie z. B. die Phyllosilicates include important groups of rock-forming minerals such. B. the
Glimmergruppe, Chloritgruppe, Kaolin und Serpentingruppe. Die technisch wichtigen und in Sedimentgesteinen verbreiteten Tonminerale sind ebenfalls Schichtsilikate. Mica group, chlorite group, kaolin and serpentine group. The technically important and in sedimentary rocks widespread clay minerals are also phyllosilicates.
Schichtsilikat, vorzugsweise das Tonmineral, liegt in einer Menge von 1 , 1 Gew.-% bis zu 40,0 Gew.-% vor, vorzugsweise von 1 ,5 bis 38 Gew.-%, mehr bevorzugt von 5 bis 35 Gew.-%, besonders bevorzugt von 15 bis 30 Gew.-%, insbesondere von 18 bis 22 Gew.-% jeweils bezogen auf die gesamte feste Zusammensetzung. Phyllosilicate, preferably the clay mineral, is present in an amount of from 1.1% to 40.0% by weight, preferably from 1.5 to 38% by weight, more preferably from 5 to 35% by weight. %, more preferably from 15 to 30 wt .-%, in particular from 18 to 22 wt .-% in each case based on the total solid composition.
Die Zusammensetzung kann ein Schichtsilikat oder eine Mischung mehrerer Schichtsilikate umfassen, solange die hierin beschriebenen Grenzen nicht überschritten werden. The composition may comprise a layered silicate or a mixture of multiple layered silicates, as long as the limits described herein are not exceeded.
Mit Vorzug werden kristalline schichtförmige Silikate der allgemeinen Formel NaMSix02x+i ■ y H2O eingesetzt, worin M Natrium oder Wasserstoff darstellt, x eine Zahl von 1 ,9 bis 22, vorzugsweise von 1 ,9 bis 4, wobei besonders bevorzugte Werte für x 2, 3 oder 4 sind, und y für eine Zahl von 0 bis 33, vorzugsweise von 0 bis 20 steht. Die kristallinen schichtförmigen Silikate der Formel NaMSix02x+i ■ y H2O werden beispielsweise von der Firma Clariant GmbH (Deutschland) unter dem Handelsnamen Na-SKS vertrieben. Beispiele für diese Silikate sind Na-SKS-1 (Na2Si22045■ x H2O, Kenyait), Na-SKS-2 (Na2Sii4029 ■ x H2O, Magadiit), Na-SKS-3 (Na2Si80i7 ■ x H2O) oder Na- SKS-4 (Na2Si409 ■ x H20, Makatit). With preferred crystalline layered silicates of general formula NaMSix02x + i ■ y H2O are used, wherein M is sodium or hydrogen, x is a number from 1, 9 to 22, preferably from 1: 9 to 4, particularly preferred values for x being 2, 3 or 4, and y is a number from 0 to 33, preferably from 0 to 20. The crystalline layered silicates of the formula NaMSix02x + i ■ y H2O, for example, by Clariant GmbH (Germany) under the trade name Na-SKS. Examples of these silicates are Na-SKS-1 (Na2Si22045 ■ x H2O, kenyaite), Na-SKS-2 (Na2 Sii40 2 9 ■ x H2O, magadiite), Na-SKS-3 (Na 2 Si 8 0i7 ■ x H2O) or Na-SKS-4 (Na 2 Si 4 09 ■ x H20, Makatite).
Für die Zwecke der vorliegenden Erfindung besonders geeignet sind kristalline Schichtsilikate der Formel NaMSix02x+i ■ y H2O, in denen x für 2 steht. Insbesondere sind sowohl ß- als auch - Natriumdisilikate Na2Si20s■ y H2O sowie weiterhin vor allem Na-SKS-5 (-Na2Si20s), Na-SKS-7 (ß- Na2Si205, Natrosilit), Na-SKS-9 (NaHSi205 ■ H2O), Na-SKS-10 (NaHSi205 ■ 3 H2O, Kanemit), Na- SKS-1 1 (t-Na2Si205) und Na-SKS-13 (NaHSi205), insbesondere aber Na-SKS-6 (-Na2Si205) bevorzugt. Particularly suitable for the purposes of the present invention crystalline phyllosilicates of the formula NaMSi x 02x + i ■ y H2O, where x is the second In particular, both .beta.- and - sodium disilicates Na2Si20s ■ y H2O and further especially Na-SKS-5 (-Na2Si20s), Na-SKS-7 (.beta.-Na2 Si2 05, natrosilite), Na-SKS-9 ( NaHSi 2 O 5 ■ H 2 O), Na-SKS-10 (NaHSi 2 O 5 · 3 H 2 O, kanemite), Na SKS-1 1 (t-Na 2 Si 2 05) and Na-SKS-13 (NaHSi 2 O 5 ), but especially Na-SKS-6 (-Na 2 Si 2 05) is preferred.
Weiterhin besonders bevorzugt kann es sein, wenn als Silikat ein auf Montmorillonite basierendes Tonmineral, wie insbesondere ein Bentonite eingesetzt wird. Ein ebenfalls geeignetes Tonmaterial
ist beispielsweise ein Smectit-Ton. Bevorzugte Smectit-Tone sind Beidellit-Tone, Hectorit-Tone, Laponit-Tone, Montmorillonit-Tone, Nontronit-Tone, Saponit-Tone, Sauconit-Tone und Mischungen daraus. Montmorillonit-Tone sind die bevorzugten Tone. Bentonite enthalten hauptsächlich Montmorillonite. Die Bentonite können als Pulver oder Kristalle eingesetzt werden. It may furthermore be particularly preferred if a montmorillonite-based clay mineral, in particular a bentonite, is used as the silicate. An equally suitable clay material is, for example, a smectite clay. Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof. Montmorillonite clays are the preferred clays. Bentonites contain mainly montmorillonites. The bentonites can be used as powder or crystals.
Geeignete Bentonite werden beispielsweise unter den Bezeichnungen Laundrosil® von der Firma Süd-Chemie oder unter der Bezeichnung Detercal von der Firma Laviosa vertrieben. Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa.
In einigen Ausführungsformen der Zusammensetzung umfasst das Schichtsilikat Ton, insbesondere ausgewählt aus der Gruppe bestehend aus Smektite, Montmorillonite, Bentonite, Kaolinite, Saponit, Hectorit und/oder Mischungen davon. In some embodiments of the composition, the layered silicate comprises clay, especially selected from the group consisting of smectites, montmorillonites, bentonites, kaolinites, saponite, hectorite and / or mixtures thereof.
In einigen Ausführungsformen der Zusammensetzung ist das Schichtsilikat natives Schichtsilikat und/oder organomodifiziertes Schichtsilikat. Vorzugsweise ist das Schichtsilikat In some embodiments of the composition, the layered silicate is native layered silicate and / or organo-modified layered silicate. Preferably, the layered silicate
organomodifiziertes Schichtsilikat. organomodified phyllosilicate.
Mit„nativem" Schichtsilikat ist Schichtsilikat gemeint, das keiner besonderen Organomodifikation unterworfen wurde. By "native" layered silicate is meant layered silicate which has not been subjected to any particular organomodification.
In einigen Ausführungsformen der Zusammensetzung umfasst das Schichtsilikat Ton, insbesondere ausgewählt aus der Gruppe bestehend aus Smektite, Montmorillonite, Bentonite, Kaolinite, Saponit, Hectorit und/oder Mischungen davon, und ist das Schichtsilikat natives Schichtsilikat und/oder organomodifiziertes Schichtsilikat. In some embodiments of the composition, the layered silicate comprises clay, in particular selected from the group consisting of smectites, montmorillonites, bentonites, kaolinites, saponite, hectorite and / or mixtures thereof, and the phyllosilicate is native phyllosilicate and / or organomodified phyllosilicate.
In weiteren Ausführungsformen ist die Zusammensetzung dadurch gekennzeichnet, dass das Schichtsilikat ausgewählt wird aus der Gruppe bestehend aus Magnesium- oder Natrium- Magnesium- Schichtsilikate. In further embodiments, the composition is characterized in that the layered silicate is selected from the group consisting of magnesium or sodium magnesium phyllosilicates.
Erfindungsgemäß besonders bevorzugt sind Tonmineralien wie Montmorillonite. Erfindungsgemäß besonders bevorzugte Schichtsilikate sind die unter dem Handelsnamen Laponite® erhältlichen Magnesium- oder Natrium-Magnesium- Schichtsilikate der Firma Solvay Alkali, insbesondere das Laponite® RD oder auch Laponite® RDS, sowie die Magnesiumsilikate der Firma Süd-Chemie, vor allem das Optigel® SH. Clay minerals such as montmorillonites are particularly preferred according to the invention. According to the invention particularly preferred sheet silicates are the magnesium available under the trade name Laponite ® or sodium magnesium layer silicates from Solvay Alkali, in particular Laponite ® RD or Laponite ® RDS, and magnesium silicates from Süd-Chemie, especially the Optigel® ® SH.
In bestimmten Ausführungsformen der vorliegenden Erfindung, ist die Zusammensetzung dadurch gekennzeichnet, dass die Zusammensetzung ferner kein anorganisches Salzen enthält. In certain embodiments of the present invention, the composition is characterized in that the composition further contains no inorganic salts.
In einigen Ausführungsformen ist die Zusammensetzung dadurch gekennzeichnet, dass die Zusammensetzung ferner ein anorganisches Salzen enthält.
Das in bevorzugten Ausführungsformen enthaltene mindestens eine anorganische Salz kann ein beliebiges anorganisches Salz bestehend aus zumindest einer kationischen Komponente und zumindest einer anionischen Komponente sein. Die katonische Komponente kann ausgewählt sein aus den Metallen der Gruppen 1-15 des Periodensystems (CAS Gruppen IA, IIA, INA, IVA, VA, HIB, IVB, VB, VIB, VIIB, VIIIB, IB, IIB bzw. Hauptgruppen l-V und Übergangsmetalle). In verschiedenen Ausführungsformen handelt es sich um ein-, zwei- oder dreiwertige Kationen. In verschiedenen Ausführungsformen ist die kationische Komponente ausgewählt aus Na+, K+, Mg2+, Al3+, Ca2+, Fe2+, Fe3+, Cu+, Cu2+, und Zn2+. In weiteren Ausführungsformen wird die kationische Komponente ausgewählt aus Na+, K+, Mg2+, Ca2+, insbesondere aus Na+ und K+. Die anionische Komponente kann ein beliebiges Anion sein, ausgewählt, ohne Einschränkung, aus der Gruppe bestehend aus anorganischen Anionen wie P, Cr, Br, I", OH", HSOs", SOs2", SC 2", HSOv, N02-, NOs", PC 3", HPO42-, H2PO4-, BPr, PF6 ", CIO4", S1O4", HCO3- und C03 2_. In einigen Ausführungsformen handelt es sich bei der anionischen Komponente vorzugsweise um Halogenid, SO42", PO43", HCO3" und In some embodiments, the composition is characterized in that the composition further contains an inorganic salt. The at least one inorganic salt contained in preferred embodiments may be any inorganic salt consisting of at least one cationic component and at least one anionic component. The cationic component may be selected from the metals of Groups 1-15 of the Periodic Table (CAS Groups IA, IIA, INA, IVA, VA, HIB, IVB, VB, VIB, VIIB, VIIIB, IB, IIB and main groups IV and transition metals, respectively ). In various embodiments, it is mono-, di- or trivalent cations. In various embodiments, the cationic component is selected from Na + , K + , Mg 2+ , Al 3+ , Ca 2+ , Fe 2+ , Fe 3+ , Cu + , Cu 2+ , and Zn 2+ . In further embodiments, the cationic component is selected from Na + , K + , Mg 2+ , Ca 2+ , especially Na + and K + . The anionic component may be any anion selected, without limitation, from the group consisting of inorganic anions such as P, Cr, Br, I " , OH " , HSOs " , SOs 2" , SC 2 " , HSOv, N0 2 - , NOs, "PC 3", HPO 4 2 -, H2PO4-, BPr, PF 6 ", CIO4" S1O4 "HCO3- and C0 3 2_. In some embodiments, the anionic component is preferably halide, SO4 2 " , PO4 3" , HCO3 " and
In einigen Ausführungsformen wird das mindestens eine anorganische Salz vorzugsweise ausgewählt aus der Gruppe bestehend aus Alkali- oder Erdalkalimetallsalzen, insbesondere aus Carbonaten, Sulfaten, Halogeniden oder Phosphaten. Besonders bevorzugt wird ausgewählt aus Natriumsulfat, Natriumcarbonat, Natriumhydrogencarbonat, Natriumdiphosphat und In some embodiments, the at least one inorganic salt is preferably selected from the group consisting of alkali or alkaline earth metal salts, especially carbonates, sulfates, halides or phosphates. Particularly preferred is selected from sodium sulfate, sodium carbonate, sodium bicarbonate, sodium diphosphate and
Natriumtripolyphosphat. Sodium tripolyphosphate.
Weiterhin geeignet sind Natriumalumosilikate der Formel (Na20)x · AI2O3 · (Si02)y · (H20)z, wobei x eine Zahl von 0,7 bis 1 ,5 ist, y eine Zahl von 1 ,3 bis 4 ist und z eine Zahl von 1 bis 6 ist, und Magnesiumsilikat. Anstelle der beschriebenen Natriumsalze können auch die entsprechenden Kaliumsalze eingesetzt werden. Ebenso geeignet sind Mischungen aus ein oder mehreren der vorgenannten anorganischen Salze. Also suitable are sodium aluminosilicates of the formula (Na 2 O) x. Al 2 O 3. (SiO 2) y . (H 2 O) z , where x is a number from 0.7 to 1.5, y is a number from 1.3 to 4 and z is one Number is from 1 to 6, and magnesium silicate. Instead of the sodium salts described, the corresponding potassium salts can also be used. Also suitable are mixtures of one or more of the aforementioned inorganic salts.
Das anorganische Salz ist nicht das Schichtsilikat der vorliegenden Erfindung. The inorganic salt is not the layered silicate of the present invention.
Gemäß einer Ausführungsform der vorliegenden Erfindung wird das mindestens eine anorganische Salz, wie hierin definiert, in einer Menge von 0,01 bis 30 Gew.-%, vorzugsweise in einer Menge von 1 bis 30 Gew.-%, basierend auf dem Gesamtgewicht der Zusammensetzung, verwendet. In verschiedenen Ausführungsformen ist das mindestens eine anorganische Salz in einer Menge von 10 bis 25 Gew.-% in der Zusammensetzung enthalten. According to one embodiment of the present invention, the at least one inorganic salt as defined herein is present in an amount of 0.01 to 30% by weight, preferably in an amount of 1 to 30% by weight, based on the total weight of the composition , used. In various embodiments, the at least one inorganic salt is included in the composition in an amount of 10 to 25 weight percent.
In einigen Ausführungsformen umfasst die erfindungsgemäße Zusammensetzung kein In some embodiments, the composition of the invention does not comprise
Polysaccharid, keine pyrogene Kieselsäure und/oder keine Fällungskieselsäure. Dabei kann es sein, dass die erfindungsgemäße Zusammensetzung kein Polysaccharid umfasst. Ebenso kann es
sein, dass die erfindungsgemäße Zusammensetzung keine pyrogene Kieselsäure umfasst. Ferner kann es sein, dass die erfindungsgemäße Zusammensetzung keine Fällungskieselsäure umfasst. Schließlich kann es sein, dass die erfindungsgemäße Zusammensetzung kein Polysaccharid, keine pyrogene Kieselsäure und keine Fällungskieselsäure umfasst. Polysaccharide, no fumed silica and / or no precipitated silica. It may be that the composition according to the invention does not comprise a polysaccharide. Likewise it can be that the composition according to the invention does not comprise fumed silica. Furthermore, it may be that the composition of the invention comprises no precipitated silica. Finally, the composition of the invention may not comprise polysaccharide, fumed silica, and precipitated silica.
Andererseits ist es möglich, dass die Zusammensetzung mindestens ein Polysaccharid, mindestens eine pyrogene Kieselsäure und/oder mindestens eine Fällungskieselsäure umfasst. On the other hand, it is possible that the composition comprises at least one polysaccharide, at least one fumed silica and / or at least one precipitated silica.
Das mindestens eine Polysaccharid, welches in der Zusammensetzung gemäß der vorliegenden Erfindung enthalten sein kann, kann pflanzlichen oder tierischen Ursprungs oder ein Produkt des Stoffwechsels von Mikroorganismen sowie ein Abbau- und Modifizierungsprodukt davon sein. The at least one polysaccharide which may be included in the composition according to the present invention may be of plant or animal origin or a product of the metabolism of microorganisms as well as a degradation and modification product thereof.
In einigen Ausführungsformen wird das Polysaccharid ausgewählt wird aus der Gruppe bestehend aus Glycogen, Stärke, Callose, Cellulose, Tunicin, Pektin, Algin, Inulin, Chitin, Chitosan, Heparin, Carrageenan, Agar, Gummiarabicum, Traganth, Johannisbrotkernmehl, Karaya-Gummi, Ghatti- Gummi, Guar-Gummi, Tara-Gummi, Gellan, Xanthan, Dextran, Saccharose, Nigeran und In some embodiments, the polysaccharide is selected from the group consisting of glycogen, starch, callose, cellulose, tunicin, pectin, algin, inulin, chitin, chitosan, heparin, carrageenan, agar, gum arabic, tragacanth, locust bean gum, karaya gum, ghatti - Rubber, Guar Gum, Tara Gum, Gellan, Xanthan, Dextran, Sucrose, Nigeran and
Pentosanen wie Xylan und Araban, Derivaten oder Mischungen davon. Pentosans such as xylan and araban, derivatives or mixtures thereof.
Gemäß einigen Ausführungsformen kann es sich beispielsweise, ohne Einschränkung, um For example, in some embodiments, without limitation
Glycogen, Stärke (Amylose und Amylopektin), Callose, Cellulose, Tunicin, Pektin(e), Algin, Inulin, Chitin, Chitosan, Heparin, Carrageenan, Agar, Gummiarabicum, Traganth, Johannisbrotkernmehl, Karaya-Gummi, Ghatti-Gummi, Guar-Gummi, Tara-Gummi, Gellan, Xanthan, Dextran, Saccharose, Nigeran und Pentosane wie Xylan und Araban, deren Hauptbestandteile aus D-Glukuronsäure, D- Galakturonsäure, D-Galakturonsäuremethylester, D-Mannuronsäure, L-Guluronsäure, D- und L- Galaktose, 3,6-Anhydro-D-Galaktose, L-Arabinose, L-Rhamnose, D-Glucoronsäure, D-Xylose, L- Fucose, D-Mannose, D-Fructose und D-Glucose, 2-Amino-2-desoxi-D-glukose und 2-Amino-2- desoxi-D-galaktose sowie deren N-Acetylderivate, bestehen, handeln. Auch Derivate der vorgenannten, wie beispielsweise chemisch modifizierte Polysaccharide, sowie Mischungen der vorgenannten sind geeignet. Zu chemisch modifizierten Polysacchariden gehören beispielsweise, ohne Einschränkung, Propylcellulose, Methylethylcellulose, Carboxymethylcellulose, Glycogen, starch (amylose and amylopectin), callose, cellulose, tunicin, pectin (s), algin, inulin, chitin, chitosan, heparin, carrageenan, agar, gum arabic, tragacanth, locust bean gum, karaya gum, ghatti gum, guar gum Gum, tara gum, gellan, xanthan, dextran, sucrose, nigeran and pentosans such as xylan and araban, the main constituents of which are D-glucuronic acid, D-galacturonic acid, D-galacturonic acid methyl ester, D-mannuronic acid, L-guluronic acid, D- and L- Galactose, 3,6-anhydro-D-galactose, L-arabinose, L-rhamnose, D-glucuronic acid, D-xylose, L-fucose, D-mannose, D-fructose and D-glucose, 2-amino-2- desoxi-D-glucose and 2-amino-2-deoxy-D-galactose and their N-acetyl derivatives. Also derivatives of the aforementioned, such as chemically modified polysaccharides, as well as mixtures of the above are suitable. For example, chemically modified polysaccharides include, without limitation, propylcellulose, methylethylcellulose, carboxymethylcellulose,
Hydroxyethylcellulose, Methylhydroxyethylcellulose, Ethylhydroxyethylcellulose, Hydroxyethylcellulose, methylhydroxyethylcellulose, ethylhydroxyethylcellulose,
Hydroxypropylcellulose, Hydroxypropylmethylcellulose, Carboxymethylhydroxyethylcellulose, Sulfoethylcellulose, Carboxymethylsulfoethylcellulose, Hydroxypropylsulfoethylcellulose, Hydroxypropylcellulose, hydroxypropylmethylcellulose, carboxymethylhydroxyethylcellulose, sulfoethylcellulose, carboxymethylsulfoethylcellulose, hydroxypropylsulfoethylcellulose,
Hydroxyethylsulfoethylcellulose, Methylethylhydroxyethylcellulose, Methlylsulfoethylcellulose und Ethylsulfoethylcellulose. Hydroxyethylsulfoethylcellulose, methylethylhydroxyethylcellulose, methylsulfoethylcellulose and ethylsulfoethylcellulose.
Gemäß einigen Ausführungsformen handelt es sich bei dem mindestens einen Polysaccharid vorzugsweise um Stärke, thermisch und/oder mechanisch behandelte Stärke, oxidativ, hydrolytisch oder oxidierte enzymatisch abgebaute Stärken, oxidierte hydrolytisch oder oxidierte enzymatisch
abgebaute Stärken sowie chemisch modifizierte Stärken. In diesem Zusammenhang sind prinzipiell alle Stärken geeignet. Gemäß einigen Ausführungsformen kann es sich beispielsweise, ohne Einschränkung, um Stärke aus Mais, Weizen, Reis, Erbsen, Gerste, Roggen, Maniok, Tapioka, Süßkartoffeln oder Kartoffeln handeln. In einigen Ausführungsformen wird vorzugsweise native Stärke eingesetzt. Als native Stärke wird Stärke bezeichnet, wie sie aus natürlichen, beispielsweise den vorgenannten, Quellen zugänglich ist. Native Stärke ist ein handelsübliches Produkt und damit leicht zugänglich. In some embodiments, the at least one polysaccharide is preferably starch, thermally and / or mechanically treated starch, oxidatively, hydrolytically or oxidized enzymatically degraded starches, oxidized hydrolytic or oxidized enzymatically degraded starches and chemically modified starches. In principle, all strengths are suitable in this context. For example, in some embodiments, starch may be, without limitation, corn, wheat, rice, peas, barley, rye, manioc, tapioca, sweet potatoes, or potatoes. In some embodiments, native starch is preferably used. As native starch is called starch, as it is accessible from natural, for example, the aforementioned, sources. Native starch is a commercial product and thus easily accessible.
Gemäß einer Ausführungsform handelt es sich bei dem mindestens einen Polysaccharid um Mais-, Weizen-, Reis-, Erbsen-, Gerste-, Roggen-, Maniok-, Tapioka-, Süßkartoffel- oder Kartoffelstärke. Gemäß einer Ausführungsform handelt es sich bei dem mindestens einen Polysaccharid um die entsprechende native Stärke der vorgenannten Art. Auch Mischungen der vorgenannten sind geeignet. Gemäß einer Ausführungsform handelt es sich bei dem mindestens einen Polysaccharid vorzugsweise um Maisstärke, insbesondere native Maisstärke. Am meisten bevorzugt ist die Maisstärke Collamyl 8412 der Firma Agrabne Wien. In one embodiment, the at least one polysaccharide is maize, wheat, rice, pea, barley, rye, manioc, tapioca, sweet potato or potato starch. According to one embodiment, the at least one polysaccharide is the corresponding native starch of the abovementioned type. Mixtures of the abovementioned are also suitable. According to one embodiment, the at least one polysaccharide is preferably maize starch, in particular native maize starch. Most preferred is the corn starch Collamyl 8412 from Agrabne Wien.
Beispiele für pyrogene Kieselsäuren sind die von der Firma Evonik unter der Handelsbezeichnung Aerosil® vertriebenen Produkte, insbesondere vom Typ Aerosil® 200; Beispiele für Examples of fumed silicas are those marketed by Evonik under the trade name Aerosil ® products, in particular of the type Aerosil ® 200; examples for
erfindungsgemäß bevorzugte Fällungskieselsäuren, sind beispielsweise die von der Firma Evonik unter der Handelsbezeichnung Sipernat® vertriebenen Produkte, insbesondere vom Typ Sipernat® 22S. inventively preferred precipitated silicas are for example marketed by Evonik under the trade name Sipernat ® products, in particular of the Sipernat ® 22S.
Obwohl erfindungsgemäß erfasst ist, dass zwei oder alle drei der genannten Inhaltsstoffe, d.h. Polysaccharid, pyrogene Kieselsäure und Fällungskieselsäure in dem Schmelzkörper enthalten sind, ist es bevorzugt, dass die Schmelzkörper der Erfindung nur jeweils einen dieser Inhaltsstoffe enthalten. Although it is recognized in the invention that two or all three of the ingredients mentioned, i. Polysaccharide, fumed silica and precipitated silica are contained in the fusible body, it is preferred that the fused bodies of the invention contain only each one of these ingredients.
Gemäß einer Ausführungsform der vorliegenden Erfindung wird das mindestens eine According to one embodiment of the present invention, the at least one
Polysaccharid, die mindestens eine pyrogene Kieselsäure oder die mindestens eine Polysaccharide containing at least one fumed silica or the at least one
Fällungskieselsäure oder eine Mischung davon, wie hierin definiert, in einer Menge von 0,01 bis 30 Gew.-%, vorzugsweise in einer Menge von 1 bis 30 Gew.-%, basierend auf dem Gesamtgewicht der Zusammensetzung, verwendet. In verschiedenen Ausführungsformen ist das mindestens eine Polysaccharid in einer Menge von 10 bis 25 Gew.-%, insbesondere 20 bis 25 Gew.-% in der Zusammensetzung enthalten. In verschiedenen anderen Ausführungsformen ist die pyrogene oder Fällungskieselsäure in einer Menge von 1 bis 10 Gew.-%, insbesondere 2 bis 7 Gew.-% in der Zusammensetzung enthalten. Precipitated silica or a mixture thereof, as defined herein, in an amount of 0.01 to 30 wt .-%, preferably in an amount of 1 to 30 wt .-%, based on the total weight of the composition used. In various embodiments, the at least one polysaccharide is included in the composition in an amount of 10 to 25% by weight, especially 20 to 25% by weight. In various other embodiments, the fumed or precipitated silica is included in the composition in an amount of 1 to 10 wt%, especially 2 to 7 wt%.
Bei der Hauptkomponente der festen, partikulären Zusammensetzung gemäß der vorliegenden Erfindung handelt es sich um mindestens ein wasserlösliches oder wasserdispergierbares
Trägerpolymer. In verschiedenen Ausführungsformen zeichnet sich das mindestens eine The main component of the solid particulate composition according to the present invention is at least one water-soluble or water-dispersible one Carrier polymer. In various embodiments, this is characterized by at least one
Trägerpolymer dadurch aus, dass es einen Schmelzpunkt von 48°C bis 120°C, vorzugsweise von 48°C bis 80°C aufweist.„Wasserlöslich", wie hierin verwendet, bedeutet eine Löslichkeit in Wasser bei 20°C von mindestens 1 g/L, vorzugsweise mindestens 10 g/L, noch bevorzugter mindestens 50 g/L.„Wasserdispergierbar", wie hierin verwendet, bedeutet, dass sich das Trägerpolymer mit bekannten Verfahren in Wasser bei einer Temperatur von 20°C dispergieren lässt. Carrier polymer characterized in that it has a melting point of 48 ° C to 120 ° C, preferably from 48 ° C to 80 ° C. "Water Soluble" as used herein means a solubility in water at 20 ° C of at least 1 g / L, preferably at least 10 g / L, more preferably at least 50 g / L. "Water-dispersible" as used herein means that the carrier polymer can be dispersed by known methods in water at a temperature of 20 ° C.
Gemäß der vorliegenden Erfindung ist das mindestens eine Trägerpolymer vorzugsweise ausgewählt aus Polyalkylenglykolen. According to the present invention, the at least one carrier polymer is preferably selected from polyalkylene glycols.
Im Kontext der vorliegenden Erfindung sind solche Polyalkylenglykole geeignet, die eine mittlere molare Masse von >1000 g/mol, insbesondere >1500 g/mol, vorzugsweise zwischen 3.000 und 15.000, noch bevorzugter eine mittlere molare Masse zwischen 4.000 und 13.000 und In the context of the present invention, those polyalkylene glycols are suitable which have an average molar mass of> 1000 g / mol, in particular> 1500 g / mol, preferably between 3000 and 15,000, more preferably an average molar mass between 4000 and 13000 and
insbesondere bevorzugt eine mittlere molare Masse zwischen 9.000 und 13.000, am meisten bevorzugt 1 1.000 bis 13.000 oder 1 1.500 bis 12.500 aufweisen. Gemäß der vorliegenden Erfindung sind insbesondere solche Polyalkylglykole geeignet, die einen Schmelzpunkt zwischen 40 °C und 90 °C aufweisen, insbesondere im Bereich von 45 bis 70°C. Beispiele für more preferably, an average molar mass is between 9,000 and 13,000, most preferably 1,000 to 13,000 or 1,500 to 12,500. According to the present invention, in particular those polyalkyl glycols are suitable which have a melting point between 40 ° C and 90 ° C, in particular in the range of 45 to 70 ° C. examples for
Polyalkylenglykole, die im Kontext der vorliegenden Erfindung geeignet sind, sind Polyalkylene glycols suitable in the context of the present invention are
Polypropylenglykol und Polyethylenglykol, sowie Blockcopolymere verschiedener Polypropylene glycol and polyethylene glycol, and block copolymers of various
Polyalkylenglykole, insbesondere der vorgenannten. Polyalkylene glycols, in particular the aforementioned.
Ebenso im Kontext der vorliegenden Erfindung sind solche Polyalkylenglykole geeignet, die eine mittlere molare Masse von >1000 g/mol, insbesondere >1500 g/mol, vorzugsweise zwischen 3.000 und 15.000, noch bevorzugter eine mittlere molare Masse zwischen 3.000 und 13.000 und insbesondere bevorzugt eine mittlere molare Masse zwischen 3.000 und 9.000, noch mehr bevorzugt eine mittlere molare Masse zwischen bevorzugt 3.500 bis 9.000, insbesondere zwischen 4.000 bis 8.000, ganz besonders bevorzugt zwischen 6.000 bis 8.000 aufweisen. Gemäß der vorliegenden Erfindung sind insbesondere solche Polyalkylglykole geeignet, die einen Also suitable in the context of the present invention are those polyalkylene glycols which have an average molar mass of> 1000 g / mol, in particular> 1500 g / mol, preferably between 3000 and 15,000, more preferably an average molar mass between 3000 and 13000 and particularly preferably one average molar mass between 3,000 and 9,000, more preferably an average molar mass between preferably 3,500 to 9,000, in particular between 4,000 to 8,000, most preferably between 6,000 to 8,000. According to the present invention, in particular those polyalkyl glycols are suitable which have a
Schmelzpunkt zwischen 40 °C und 90 °C aufweisen, insbesondere im Bereich von 45 bis 70°C. Beispiele für Polyalkylenglykole, die im Kontext der vorliegenden Erfindung geeignet sind, sind Polypropylenglykol und Polyethylenglykol, sowie Blockcopolymere verschiedener Melting point between 40 ° C and 90 ° C, in particular in the range of 45 to 70 ° C. Examples of polyalkylene glycols useful in the context of the present invention are polypropylene glycol and polyethylene glycol, as well as block copolymers of various types
Polyalkylenglykole, insbesondere der vorgenannten. Bevorzugte Handelsprodukte sind z.B. Pluriol E 4000, Pluriol E 6000 und Pluriol E 8000 (BASF). Polyalkylene glycols, in particular the aforementioned. Preferred commercial products are e.g. Pluriol E 4000, Pluriol E 6000 and Pluriol E 8000 (BASF).
Wenn im Rahmen dieser Anmeldung von„mittlere molare Masse von If in the context of this application of "average molar mass of
Polyalkylenglykolen" gesprochen wird, so beziehen sich diese Angaben jeweils auf die Werte, die sich rechnerisch aus der OH-Zahl gemessen gemäß DIN 53240-1 :2012-07 ergeben.
Gemäß einigen Ausführungsformen handelt es sich bei dem mindestens einen Trägerpolymer vorzugsweise um Polyethylenglykol. Polyalkylenglykolen "is spoken, then these data in each case refer to the values calculated from the OH number measured in accordance with DIN 53240-1: 2012-07. In some embodiments, the at least one carrier polymer is preferably polyethylene glycol.
In einigen Ausführungsformen handelt es sich bei dem mindestens einen Trägerpolymer um ein Polyethylenglykol mit einer mittleren molaren Masse von >1500 g/mol, vorzugsweise zwischen 3.000 und 15.000, noch bevorzugter mit einer mittleren molaren Masse zwischen 4.000 und 13.000 und insbesondere bevorzugt mit einer mittleren molaren Masse zwischen 6.000 und 8.000 oder 9.000 bis 13.000. In some embodiments, the at least one carrier polymer is a polyethylene glycol having an average molar mass of> 1500 g / mol, preferably between 3,000 and 15,000, more preferably with an average molar mass between 4,000 and 13,000, and most preferably with an intermediate molar Mass between 6,000 and 8,000 or 9,000 to 13,000.
In einigen Ausführungsformen handelt es sich bei dem mindestens einen Trägerpolymer um ein Polyethylenglykol mit einer mittleren molaren Masse von >1500 g/mol, vorzugsweise zwischen 3.000 und 15.000, noch bevorzugter mit einer mittleren molaren Masse zwischen 4.000 und 13.000 und insbesondere bevorzugt mit einer mittleren molaren Masse zwischen 6.000 und 8.000 oder 9.000 bis 13.000. In some embodiments, the at least one carrier polymer is a polyethylene glycol having an average molar mass of> 1500 g / mol, preferably between 3,000 and 15,000, more preferably with an average molar mass between 4,000 and 13,000, and most preferably with an intermediate molar Mass between 6,000 and 8,000 or 9,000 to 13,000.
In einigen Ausführungsformen handelt es sich bei dem mindestens einen Trägerpolymer um ein Polyethylenglykol mit einer mittleren molaren Masse von >1500 g/mol, vorzugsweise zwischen 3.000 und 15.000, besonders zwischen 3.500 und 13.000, noch mehr bevorzugt einer mittleren molaren Masse zwischen bevorzugt 3.500 bis 9.000, insbesondere zwischen 4.000 bis 8.000, ganz besonders bevorzugt zwischen 6.000 bis 8.000. In some embodiments, the at least one carrier polymer is a polyethylene glycol having an average molar mass of> 1,500 g / mol, preferably between 3,000 and 15,000, especially between 3,500 and 13,000, more preferably an average molar mass between preferably 3,500 to 9,000 , in particular between 4,000 and 8,000, very particularly preferably between 6,000 and 8,000.
Gemäß einigen Ausführungsformen handelt es sich bei dem mindestens einen Trägerpolymer vorzugsweise um Polyethylenglykol mit einer mittleren molaren Masse von 10.000 bis 15.000, vorzugsweise von 1 1 .000 bis 13.000, ganz besonders bevorzugt von 1 1.500 bis 12.500. In some embodiments, the at least one carrier polymer is preferably polyethylene glycol having an average molecular weight of from 10,000 to 15,000, preferably from 1,000 to 13,000, most preferably from 1,500 to 12,500.
In einigen Ausführungsformen zeichnet sich ein solches Polyethylenglykol durch einen In some embodiments, such a polyethylene glycol is characterized by a
Schmelzpunkt im Bereich von 45 bis 70°C, vorzugsweise 50 bis 65°C aus, noch bevorzugter 50 bis 60°C. Melting point in the range of 45 to 70 ° C, preferably 50 to 65 ° C, more preferably 50 to 60 ° C.
In einer weiteren bevorzugten Ausführungsform können die erfindungsgemäßen In a further preferred embodiment, the inventive
Zusammensetzungen als Trägerpolymer zusätzlich zu dem erfindungsgemäßen Polyethylenglykol oder auch an stelle dessen mindestens ein Alkoxyblockcopolymer enthalten. Compositions as a carrier polymer in addition to the polyethylene glycol according to the invention or also in place of which at least one alkoxy block copolymer.
Erfindungsgemäß geeignete Alkoxyblockpolymere sind vorzugsweise aus alternierenden Alkoxy block polymers which are suitable according to the invention are preferably of alternating type
Ethylenoxid (EO)-, Propylenoxid (PO)- und/oder Butylenoxid (BU)-Einheiten aufgebaut. Bevorzugt sind Alkoxyblockpolymere der Formeln HO-(EO)x(PO)y(EO)z-H, HO-(PO)x(EO)y(PO)z-H, HO- (EO)x(PO)y(PO)z-H, HO-(EO)x(EO)y(PO)z-H, HO-(EO)x(BO)y(EO)z-H, HO-(BO)x(EO)y(BO)z-H, HO- (EO)x(BO)y(BO)z-H, HO-(EO)x(EO)y(BO)z-H, HO-(BO)x(PO)y(BO)z-H, HO-(PO)x(BO)y(PO)z-H, HO- (BO)x(PO)y(PO)z-H und HO-(BO)x(BO)y(PO)z-H, in welchen die Indizes unabhängig voneinander
die Werte 1 , 2, 3, 4, 5, 6, 7, 8, 9, 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20 bis 100 annehmen. Die Blockpolymere weisen vorzugsweise Molmassen zwischen 4.000 und 20. 000, insbesondere 5.000 bis 7.000 g/mol auf. Erfindungsgemäß besonders bevorzugt sind dabei reine EO-PO- Blockcopolymere, wie sie beispielsweise von der Firma BASF unter der Handelsbezeichnung Pluronic® vertrieben werden. Pluronic® PE 6800 ist ein erfindungsgemäß ganz besonders bevorzugtes Alkoxyblockcopolymer. Composed of ethylene oxide (EO), propylene oxide (PO) and / or butylene oxide (BU) units. Preference is given to alkoxy block polymers of the formulas HO- (EO) x (PO) y (EO) z -H, HO- (PO) x (EO) y (PO) z -H, HO- (EO) x (PO) y ( PO) zH, HO- (EO) x (EO) y (PO) zH, HO- (EO) x (BO) y (EO) z -H, HO- (BO) x (EO) y (BO) z -H, HO- (EO) x (BO) y (BO) zH, HO- (EO) x (EO) y (BO) zH, HO- (BO) x (PO) y (BO) z -H, HO- (PO) x (BO) y (PO) z -H, HO- (BO) x (PO) y (PO) z -H and HO- (BO) x (BO) y (PO) z -H in which the indices are independent of each other the values 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 1, 1, 12, 13, 14, 15, 16, 17, 18, 19, 20 to 100 assume. The block polymers preferably have molecular weights between 4,000 and 20,000, in particular 5,000 to 7,000 g / mol. According to the invention particularly preferred are pure EO-PO block copolymers as for example marketed by BASF under the trade name Pluronic ®. Pluronic ® PE 6800 is an inventively particularly preferred Alkoxyblockcopolymer.
Es kann erfindungsgemäß besonders bevorzugt sein, dass die festen Zusammensetzungen als Trägerpolymer mindestens ein Polyethlyenglykol mit einer mittleren molaren Masse von 10.000 bis 15.000 enthalten und ggf. frei von EO-PO-Blockcopolymeren formuliert sind. Ebenso kann es erfindungsgemäß bevorzugt sein, wenn die festen Zubereitungen als Trägerpolymer mindestens ein EO-PO-Blockcopolymer enthalten und ggf. frei von Polyethylenglykolen mit einer mittleren molaren Masse von 10.000 bis 15.000 formuliert sind. In einer dritten Ausführungsform kann es aber auch bevorzugt sein, wenn die festen Zusammensetzungen als Trägermaterial eine Mischung aus mindestens einem EO-PO-Blockcopolymer und mindestens einem Polyethlyenglykol mit einer mittleren molaren Masse von 10.000 bis 15.000 enthalten. It may be particularly preferred according to the invention that the solid compositions contain as carrier polymer at least one polyethylene glycol having an average molar mass of 10,000 to 15,000 and are optionally formulated free of EO-PO block copolymers. It may likewise be preferred according to the invention if the solid preparations comprise at least one EO-PO block copolymer as the carrier polymer and are optionally formulated free of polyethylene glycols having an average molar mass of from 10,000 to 15,000. In a third embodiment, however, it may also be preferred for the solid compositions to contain as carrier material a mixture of at least one EO-PO block copolymer and at least one polyethylene glycol having an average molar mass of from 10,000 to 15,000.
In verschiedenen Ausführungsformen ist das mindestens eine Trägerpolymer bzw. die Mischung verschiedener Trägerpolymere in einer Menge von 30 bis 95 Gew.-%, vorzugsweise von 35 bis 85 Gew.-%, beispielsweise 40 bis 80 oder 40 bis 78 Gew.-% in der Zusammensetzung enthalten, basierend auf dem Gesamtgewicht der Zusammensetzung. In various embodiments, the at least one carrier polymer or the mixture of various carrier polymers is in an amount of 30 to 95 wt .-%, preferably from 35 to 85 wt .-%, for example 40 to 80 or 40 to 78 wt .-% in the Composition based on the total weight of the composition.
In einer bevorzugten Ausführungsform der Zusammensetzung ist das mindestens eine In a preferred embodiment of the composition, this is at least one
wasserlösliche Trägerpolymer ein Polyalkylenglykol, besonders bevorzugt aus den water-soluble carrier polymer is a polyalkylene glycol, particularly preferably from the
Polyethylenglykolen mit einer mittleren molaren Masse im Bereich von 10.000 bis 15.000, vorzugsweise von 1 1 .000 bis 13.000, ganz besonders bevorzugt von 1 1 .500 bis 12.500, und weist die Zusammensetzung weiterhin mindestens einen Wirkstoff auf ausgewählt aus der Gruppe der Polyethlyenglykole mit einer mittleren molaren Masse größer als 16.000, der Fettalkoholalkoxylate mit mindestens 10 C-Atomen in der Fettkette und mindestens 10 Alkoxyeinheiten, der alkoxylierten Castoröle mit mindestens 5 Alkoxyeinheiten und den Alkoxyblockcopolymeren. Polyethylene glycols having an average molar mass in the range of 10,000 to 15,000, preferably from 1 1 .000 to 13,000, most preferably from 1 1 .500 to 12,500, and the composition further comprises at least one active ingredient selected from the group of Polyethlyenglykole with a average molar mass greater than 16,000, the fatty alcohol alkoxylates having at least 10 C atoms in the fatty chain and at least 10 alkoxy units, the alkoxylated castor oils having at least 5 alkoxy units and the alkoxy block copolymers.
Eine weitere Komponente der festen, partikulären Zusammensetzung gemäß der vorliegenden Erfindung ist mindestens ein Duftstoff. Bei einem Duftstoff handelt es sich um eine den Geruchsinn anregende, chemische Substanz. Um den Geruchssinn anregen zu können, sollte die chemische Substanz zumindest teilweise in der Luft verteilbar sein, d.h. der Duftstoff sollte bei 25°C zumindest in geringem Maße flüchtig sein. Ist der Duftstoff nun sehr flüchtig, klingt die Geruchsintensität dann schnell wieder ab. Bei einer geringeren Flüchtigkeit ist der Gerucheindruck jedoch nachhaltiger, d.h. er verschwindet nicht so schnell. In einer Ausführungsform weist der Duftstoff daher einen Schmelzpunkt auf, der im Bereich von -100°C bis 100°C, bevorzugt von -80°C bis 80°C, noch
bevorzugter von -20°C bis 50°C, insbesondere von -30°C bis 20°C liegt. In einer weiteren Another component of the solid particulate composition according to the present invention is at least one perfume. A fragrance is an odor-causing chemical substance. In order to stimulate the sense of smell, the chemical substance should be at least partially redistributable in the air, ie the fragrance should be volatile at 25 ° C, at least to a small extent. If the fragrance is now very volatile, the odor intensity then quickly decreases again. At a lower volatility, the smell impression is more sustainable, ie it does not disappear so quickly. Thus, in one embodiment, the perfume has a melting point that is within the range of -100 ° C to 100 ° C, preferably from -80 ° C to 80 ° C more preferably from -20 ° C to 50 ° C, especially from -30 ° C to 20 ° C. In another
Ausführungsform weist der Duftstoff einen Siedepunkt auf, der im Bereich von 25°C bis 400°C, bevorzugt von 50°C bis 380°C, mehr bevorzugt von 75°C bis 350°C, insbesondere von 100°C bis 330°C liegt. In the embodiment, the fragrance has a boiling point ranging from 25 ° C to 400 ° C, preferably from 50 ° C to 380 ° C, more preferably from 75 ° C to 350 ° C, especially from 100 ° C to 330 ° C lies.
Insgesamt sollte eine chemische Substanz eine bestimmte Molekülmasse nicht überschreiten, um als Duftstoff zu fungieren, da bei zu hoher Molekülmasse die erforderliche Flüchtigkeit nicht mehr gewährleitstet werden kann. In einer Ausführungsform weist der Duftstoff eine Molekülmasse von 40 bis 700 g/mol, noch bevorzugter von 60 bis 400 g/mol auf. Overall, a chemical substance should not exceed a certain molecular weight to act as a fragrance, since too high molecular weight, the required volatility can no longer be ensured. In one embodiment, the fragrance has a molecular weight of 40 to 700 g / mol, more preferably 60 to 400 g / mol.
Der Geruch eines Duftstoffes wird von den meisten Menschen als angenehm empfunden und entspricht häufig dem Geruch nach beispielsweise Blüten, Früchten, Gewürzen, Rinde, Harz, Blättern, Gräsern, Moosen und Wurzeln. So können Duftstoffe auch dazu verwendet werden, um unangenehme Gerüche zu überlagern oder aber auch um einen nicht riechenden Stoff mit einem gewünschten Geruch zu versehen. Als Duftstoffe können einzelne Riechstoffverbindungen, z.B. die synthetischen Produkte vom Typ der Ester, Ether, Aldehyde, Ketone, Alkohole und The smell of a fragrance is perceived by most people as pleasant and often corresponds to the smell of, for example, flowers, fruits, spices, bark, resin, leaves, grasses, mosses and roots. Thus, fragrances can also be used to superimpose unpleasant odors or even to provide a non-smelling substance with a desired odor. As perfumes, individual perfume compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and type
Kohlenwasserstoffe verwendet werden. Hydrocarbons are used.
Duftstoffverbindungen vom Typ der Aldehyde sind beispielsweise Adoxal (2,6, 10-Trimethyl-9- undecenal), Anisaldehyd (4-Methoxybenzaldehyd), Cymal (3-(4-lsopropyl-phenyl)-2- methylpropanal), Ethylvanillin, Florhydral (3-(3-isopropylphenyl)butanal), Helional (3-(3,4- Methylendioxyphenyl)-2-methylpropanal), Heliotropin, Hydroxycitronellal, Lauraldehyd, Lyral (3- und 4-(4-Hydroxy-4-methylpentyl)-3- cyclohexen-1-carboxaldehyd), Methylnonylacetaldehyd, Lilial (3-(4-tert-Butylphenyl)-2-methylpropanal), Phenylacetaldehyd, Undecylenaldehyd, Vanillin, 2,6, 10- Trimethyl-9-undecenal, 3-Dodecen-1-al, alpha-n-Amylzimtaldehyd, Melonal (2,6-Dimethyl-5- heptenal), 2,4-Di-methyl-3-cyclohexen-1-carboxaldehyd (Triplal), 4-Methoxybenzaldehyd, Benzaldehyd, 3-(4-tert- Butylphenyl)-propanal, 2-Methyl-3-(para-methoxyphenyl)propanal, 2- Methyl-4-(2,6,6-timethyl-2(1 )-cyclohexen-1-yl)butanal, 3-Phenyl-2-propenal, cis-/trans-3,7- Dimethyl-2,6-octadien-1-al, 3,7-Dimethyl-6-octen-1-al, [(3,7-Dimethyl-6-octenyl)oxy]acetaldehyd, 4- Isopropylbenzylaldehyd, 1 ,2,3,4, 5,6J,8-Octahydro-8,8-dimethyl-2-naphthaldehyd, 2,4-Dimethyl-3- cyclohexen-1-carboxaldehyd, 2-Methyl-3-(isopropylphenyl)propanal, 1-Decanal, 2,6-Dimethyl-5- heptenal, 4-(Tricyclo[5.2.1.0(2,6)]-decyliden-8)-butanal, Octahydro-4,7-methan-1 H- indencarboxaldehyd, 3-Ethoxy-4-hydroxybenzaldehyd, para-Ethyl-alpha,alpha- dimethylhydrozimtaldehyd, alpha-Methyl-3,4-(methylendioxy)-hydrozimtaldehyd, 3,4- Methylendioxybenzaldehyd, alpha-n-Hexylzimtaldehyd, m-Cymen-7-carboxaldehyd, alpha- Methylphenylacetaldehyd, 7-Hydroxy-3J-dimethyloctanal, Undecenal, 2,4,6-Trimethyl-3- cyclohexen-1-carboxaldehyd, 4-(3)(4-Methyl-3-pentenyl)-3-cyclohexencarboxaldehyd, 1- Dodecanal, 2,4-Dimethylcyclohexen-3-carboxaldehyd, 4-(4-Hydroxy-4-methylpentyl)-3-cylohexen- 1-carboxaldehyd, 7-Methoxy-3,7-dimethyloctan-1-al, 2-Methyl- undecanal, 2-Methyldecanal, 1-
Nonanal, 1-Octanal, 2,6,10-Trimethyl-5,9-undecadienal, 2-Methyl-3-(4-tert-butyl)propanal, Dihydrozimtaldehyd, 1-Methyl-4-(4-methyl-3-pentenyl)-3-cyclohexen-1-carboxaldehyd, 5- oder 6- Methoxyhexahydro-4,7-methanindan-1 - oder -2-carboxaldehyd, 3,7-Dimethyloctan-1-al, 1 - Undecanal, 10-Undecen-1-al, 4-Hydroxy-3-methoxybenzaldehyd, 1-Methyl-3-(4-methylpentyl)-3- cyclohexencarboxaldehyd, 7-Hydroxy-3J-dimethyl-octanal, trans-4-Decenal, 2,6-Nonadienal, para- Tolylacetaldehyd, 4-Methylphenylacetaldehyd, 2-Methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2- butenal, ortho-Methoxyzimtaldehyd, 3,5,6-Trimethyl-3-cyclohexen- carboxaldehyd, 3J-Dimethyl-2- methylen-6-octenal, Phenoxyacetaldehyd, 5,9-Dimethyl-4,8- decadienal, Päonienaldehyd (6,10- Dimethyl-3-oxa-5,9-undecadien-1-al), Hexahydro-4,7-methanindan-1 -carboxaldehyd, 2- Methyloctanal, alpha-Methyl-4-(1-methylethyl)benzolacetaldehyd, 6,6-Dimethyl-2-norpinen-2- propionaldehyd, para-Methylphenoxyacetaldehyd, 2-Methyl-3-phenyl-2-propen-1-al, 3,5,5- Trimethylhexanal, Hexahydro-8,8-dimethyl-2-naphthaldehyd, 3-Propyl-bicyclo-[2.2.1]-hept-5-en-2- carbaldehyd, 9-Decenal, 3-Methyl-5-phenyl-1-pentanal, Methylnonylacetaldehyd, Hexanal und trans-2-Hexenal. Fragrance compounds of the aldehyde type are, for example, adoxal (2,6,10-trimethyl-9-undecenal), anisaldehyde (4-methoxybenzaldehyde), cymal (3- (4-isopropyl-phenyl) -2-methylpropanal), ethylvanillin, florhydral ( 3- (3-isopropylphenyl) butanal), helional (3- (3,4-methylenedioxyphenyl) -2-methylpropanal), heliotropin, hydroxycitronellal, lauraldehyde, lyral (3- and 4- (4-hydroxy-4-methylpentyl) - 3-cyclohexene-1-carboxaldehyde), methylnonylacetaldehyde, lilial (3- (4-tert-butylphenyl) -2-methylpropanal), phenylacetaldehyde, undecylenealdehyde, vanillin, 2,6, 10-trimethyl-9-undecenal, 3-dodecene 1-al, alpha-n-amylcinnamaldehyde, melonal (2,6-dimethyl-5-heptenal), 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde (triplalite), 4-methoxybenzaldehyde, benzaldehyde, 3 (4-tert-butylphenyl) -propanal, 2-methyl-3- (para-methoxyphenyl) propanal, 2-methyl-4- (2,6,6-timethyl-2 (1) -cyclohexen-1-yl) butanal , 3-phenyl-2-propenal, cis- / trans-3,7-dimethyl-2,6-octadiene-1-al, 3,7-dimethyl-6-octene-1-al, [(3,7-) dimethyl-6-octenyl) oxy ] acetaldehyde, 4-isopropylbenzylaldehyde, 1, 2,3,4, 5,6J, 8-octahydro-8,8-dimethyl-2-naphthaldehyde, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde, 2-methyl -3- (isopropylphenyl) propanal, 1-decanal, 2,6-dimethyl-5-heptenal, 4- (tricyclo [5.2.1.0 (2,6)] decylidene-8) -butanal, octahydro-4,7- methane-1H-indenecarboxaldehyde, 3-ethoxy-4-hydroxybenzaldehyde, para-ethyl-alpha, alpha-dimethylhydrocinnamaldehyde, alpha-methyl-3,4- (methylenedioxy) -hydrocinnamaldehyde, 3,4-methylenedioxybenzaldehyde, alpha-n-hexylcinnamaldehyde , m-cymene-7-carboxaldehyde, alpha-methylphenylacetaldehyde, 7-hydroxy-3J-dimethyloctanal, undecenal, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, 4- (3) (4-methyl-3 pentenyl) -3-cyclohexene carboxaldehyde, 1-dodecanal, 2,4-dimethylcyclohexene-3-carboxaldehyde, 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde, 7-methoxy-3,7- dimethyloctane-1-al, 2-methyl-undecanal, 2-methyldecanal, 1- Nonanal, 1-octanal, 2,6,10-trimethyl-5,9-undecadienal, 2-methyl-3- (4-tert-butyl) propanal, dihydrocinnamaldehyde, 1-methyl-4- (4-methyl-3-) pentenyl) -3-cyclohexene-1-carboxaldehyde, 5- or 6-methoxy-hexahydro-4,7-methanindan-1 or 2-carboxaldehyde, 3,7-dimethyloctan-1-al, 1-undecanal, 10-undecene 1-al, 4-hydroxy-3-methoxybenzaldehyde, 1-methyl-3- (4-methylpentyl) -3-cyclohexenecarboxaldehyde, 7-hydroxy-3J-dimethyl-octanal, trans-4-decenal, 2,6-nonadienal, para-tolylacetaldehyde, 4-methylphenylacetaldehyde, 2-methyl-4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -2-butenal, ortho-methoxycinnamaldehyde, 3,5,6-trimethyl-3-yl cyclohexene-carboxaldehyde, 3J-dimethyl-2-methylene-6-octenal, phenoxyacetaldehyde, 5,9-dimethyl-4,8-decadienal, peonyaldehyde (6,10-dimethyl-3-oxa-5,9-undecadiene-1 al), hexahydro-4,7-methanindane-1-carboxaldehyde, 2-methyloctanal, alpha-methyl-4- (1-methylethyl) benzeneacetaldehyde, 6,6-dimethyl-2-norpinen-2-propionaldehyde, para-methylphenoxyacetaldehyde, 2-methyl-3-phenyl-2-propene-1-al, 3,5, 5-trimethylhexanal, hexahydro-8,8-dimethyl-2-naphthaldehyde, 3-propyl-bicyclo [2.2.1] -hept-5-en-2-carbaldehyde, 9-decenal, 3-methyl-5-phenyl 1-pentanal, methylnonylacetaldehyde, hexanal and trans-2-hexenal.
Duftstoffverbindungen vom Typ der Ketone sind beispielsweise Methyl-beta-naphthylketon, Moschusindanon (1 ,2,3,5,6,7-Hexahydro-1 , 1 ,2,3,3- pentamethyl-4H-inden-4-on), Tonalid (6-Acetyl- 1 ,1 ,2,4,4,7-hexamethyltetralin), alpha-Damascon, beta-Damascon, delta-Damascon, iso- Damascon, Damascenon, Methyldihydrojasmonat, Menthon, Carvon, Kampfer, Koavon (3,4,5,6,6- Pentamethylhept-3-en-2-on), Fenchon, alpha-lonon, beta- lonon, gamma-Methyl-lonon, Fleuramon (2-heptylcyclopen-tanon), Dihydrojasmon, cis-Jasmon, iso-E-Super (1-(1 ,2,3,4,5,6J,8-octahydro- 2,3,8,8-tetramethyl-2-naphthalenyl)-ethan-1-on (und Isomere)), Methylcedrenylketon, Ketone-type perfume compounds are, for example, methyl-beta-naphthyl ketone, muskedanone-1-one (2,3,3,6,7-hexahydro-1,1,3,3,3-pentamethyl-4H-inden-4-one), Tonalid (6-acetyl-1,1,1,4,4,7-hexamethyltetralin), alpha-damascone, beta-damascone, delta-damascone, iso-damascone, damascenone, methyldihydrojasmonate, menthone, carvone, camphor, koavon (3 , 4,5,6,6-pentamethylhept-3-en-2-one), fenchone, alpha-ionone, beta- lonone, gamma-methyl-ionone, fleuramon (2-heptylcyclopentanone), dihydrojasmon, cis-jasmone , Iso-E-Super (1- (1,2,3,4,5,6J, 8-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl) -ethan-1-one (and isomers) ), Methyl cydrenyl ketone,
Acetophenon, Methylacetophenon, para-Methoxyacetophenon, Methyl-beta-naphtylketon, Benzylaceton, Benzophenon, para-Hydroxyphenylbutanon, Sellerie- Keton(3-methyl-5-propyl-2- cyclohexenon), 6-lsopropyldecahydro-2-naphton, Dimethyloctenon, Frescomenthe (2-butan-2-yl- cyclohexan-1-οη), 4-(1 -Ethoxyvinyl)-3,3,5,5-tetramethylcyclohexanon, Methylheptenon, 2-(2-(4- Methyl-3-cyclohexen-1-yl)propyl)cyclopentanon, 1-(p-Menthen-6(2)yl)-1-propanon, 4-(4-Hydroxy-3- methoxyphenyl)-2-butanon, 2-Acetyl-3,3-dimethylnorbornan, 6,7- Dihydro-1 , 1 ,2,3, 3-pentamethyl- 4(5H)-indanon, 4-Damascol, Dulcinyl(4-(1 ,3-benzodioxol-5-yl) butan-2-οη), Hexalon (1-(2,6,6- trimethyl-2-cyclohexene-1 -yl)-1 ,6-heptadien-3-on), lsocyclemonE(2-acetonaphthon-1 ,2,3,4,5,6,7,8- octahydro-2,3,8,8-tetramethyl), Methylnonylketon, Methylcyclocitron, Methyllavendelketon, Orivon (4-tert-Amyl-cyclohexanon), 4-tert-Butylcyclohexanon, Delphon (2-pentyl-cyclopentanon), Muscon (CAS 541-91-3), Neobutenon (1-(5,5-dimethyl-1- cyclohexenyl)pent-4-en-1-on), Plicaton (CAS 41724-19-0), Velouton (2,2,5-Trimethyl-5- pentylcyclopentan-1-on),2,4,4,7-Tetramethyl-oct-6-en-3- on und Tetrameran (6, 10- Dimethylundecen-2-οη). Acetophenone, methylacetophenone, para-methoxyacetophenone, methyl-beta-naphthyl ketone, benzylacetone, benzophenone, para-hydroxyphenylbutanone, celery-ketone (3-methyl-5-propyl-2-cyclohexenone), 6-isopropyldecahydro-2-naphthone, dimethyloctenone, Frescomenthe (2-butan-2-yl-cyclohexan-1-one), 4- (1-ethoxyvinyl) -3,3,5,5-tetramethylcyclohexanone, methylheptenone, 2- (2- (4-methyl-3-cyclohexene) 1-yl) propyl) cyclopentanone, 1- (p-menthene-6 (2) yl) -1-propanone, 4- (4-hydroxy-3-methoxyphenyl) -2-butanone, 2-acetyl-3,3- dimethylnorbornane, 6,7-dihydro-1, 1, 2,3, 3-pentamethyl-4 (5H) -indanone, 4-damascol, dulcinyl (4- (1,3-benzodioxol-5-yl) butan-2-one οη), hexalon (1- (2,6,6-trimethyl-2-cyclohexene-1-yl) -1, 6-heptadien-3-one), isocyclone E (2-acetonaphthone-1, 2,3,4, 5,6,7,8-octahydro-2,3,8,8-tetramethyl), methyl nonyl ketone, methylcyclocitron, methylene lavender ketone, orivone (4-tert-amylcyclohexanone), 4-tert-butylcyclohexanone, 2-pentylcyclohexanone cyclopentanone), Muscon (CAS 541-91-3), neobutenone (1- (5,5-dimethyl-1-cyclohex enyl) pent-4-en-1-one), Plicaton (CAS 41724-19-0), Veloutone (2,2,5-trimethyl-5-pentylcyclopentan-1-one), 2,4,4,7- Tetramethyl-oct-6-en-3-one and tetrameran (6, 10-dimethylundecen-2-one).
Duftstoffverbindungen vom Typ der Alkohole sind beispielsweise 10-Undecen-1-ol, 2,6- Dimethylheptan-2-ol, 2-Methyl-butanol, 2-Methylpentanol, 2- Phenoxyethanol, 2-Phenylpropanol, 2- tert.-Butycyclohexanol, 3,5,5-Trimethylcyclohexanol, 3-Hexanol, 3-Methyl-5-phenyl-pentanol, 3-
Octanol, 3-Phenyl-propanol, 4-Heptenol, 4-lsopropyl- cyclohexanol, 4-tert.-Butycyclohexanol, 6,8- Dimethyl-2-nona-nol, 6-Nonen-1-ol, 9-Decen-1-ol, α-Methylbenzylalkohol, a-Terpineol, Fragrance compounds of the alcohol type are, for example, 10-undecen-1-ol, 2,6-dimethylheptan-2-ol, 2-methylbutanol, 2-methylpentanol, 2-phenoxyethanol, 2-phenylpropanol, 2-tert-butycyclohexanol, 3,5,5-trimethylcyclohexanol, 3-hexanol, 3-methyl-5-phenyl-pentanol, 3 Octanol, 3-phenyl-propanol, 4-heptenol, 4-isopropyl-cyclohexanol, 4-tert-butylcyclohexanol, 6,8-dimethyl-2-nonanol, 6-nonene-1-ol, 9-decene-1 -ol, α-methylbenzyl alcohol, α-terpineol,
Amylsalicylat, Benzylalkohol, Benzylsalicylat, ß-Terpineol, Butylsalicylat, Citronellol, Amyl salicylate, benzyl alcohol, benzyl salicylate, β-terpineol, butyl salicylate, citronellol,
Cyclohexylsalicylat, Decanol, Di-hydromyrcenol, Dimethylbenzylcarbinol, Dimethylheptanol, Dimethyloctanol, Ethylsalicylat, Ethylvanilin, Eugenol, Farnesol, Geraniol, Heptanol, Hexylsalicylat, Isoborneol, Isoeugenol, Isopulegol, Linalool, Menthol, Myrtenol, n-Hexanol, Nerol, Nonanol, Octanol, p-Menthan-7-ol, Phenylethylalkohol, Phenol, Phenylsalicylat, Tetrahydrogeraniol, Tetrahydrolinalool, Thymol, trans-2-cis-6-Nonadicnol, trans-2-Nonen-1-ol, trans-2-Octenol, Undecanol, Vanillin, Champiniol, Hexenol und Zimtalkohol. Cyclohexyl salicylate, decanol, di-hydromyrcenol, dimethylbenzylcarbinol, dimethylheptanol, dimethyloctanol, ethyl salicylate, ethylvaniline, eugenol, farnesol, geraniol, heptanol, hexyl salicylate, isoborneol, isoeugenol, isopulegol, linalool, menthol, myrtenol, n-hexanol, nerol, nonanol, octanol, p-menthan-7-ol, phenylethyl alcohol, phenol, phenyl salicylate, tetrahydrogeraniol, tetrahydrolinalool, thymol, trans-2-cis-6-nonadicnol, trans-2-nonen-1-ol, trans-2-octenol, undecanol, vanillin, Champiniol, hexenol and cinnamyl alcohol.
Duftstoffverbindungen vom Typ der Ester sind z.B. Benzylacetat, Phenoxyethylisobutyrat, p-tert- Butylcyclohexylacetat, Linalylacetat, Dimethylbenzylcarbinylacetat (DMBCA), Phenylethylacetat, Benzylacetat, Ethylmethylphenyl- glycinat, Allylcyclohexylpropionat, Styrallylpropionat, Fragrance type ester compounds are e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate,
Benzylsalicylat, Cyclohexylsalicylat, Floramat, Melusat und Jasmacyclat. Benzyl salicylate, cyclohexyl salicylate, floramate, melusate and jasmacycate.
Zu den Ethern zählen beispielsweise Benzylethylether und Ambroxan. Zu den Ethers include, for example, benzyl ethyl ether and ambroxan. To the
Kohlenwasserstoffen gehören hauptsächlich Terpene wie Limonen und Pinen. Hydrocarbons mainly include terpenes such as limonene and pinene.
Bevorzugt werden Mischungen verschiedener Duftstoffe verwendet, die gemeinsam eine ansprechende Duftnote erzeugen. Ein derartiges Gemisch an Duftstoffen kann auch als Parfüm oder Parfümöl bezeichnet werden. Solche Parfümöle können auch natürliche Duftstoffgemische enthalten, wie sie aus pflanzlichen Quellen zugänglich sind. Preference is given to using mixtures of different fragrances which together produce an attractive fragrance. Such a mixture of perfumes may also be referred to as perfume or perfume oil. Such perfume oils may also contain natural perfume mixtures as are available from plant sources.
Zu den Duftstoffen pflanzlichen Ursprungs zählen ätherische Öle wie Angelikawurzelöl, Anisöl, Arnikablütenöl, Basilikumöl, Bayöl, Champacablütenöl, Citrusöl, Edeltannenöl, Edeltannenzapfenöl, Elemiöl, Eukalyptusöl, Fenchelöl, Fichtennadelöl, Galbanumöl, Geraniumöl, Gingergrasöl, Guajakholzöl, Gurjunbalsamöl, Helichrysumöl, Ho-Öl, Ingweröl, Irisöl, jasminöl, Kajeputöl, Fragrances of plant origin include essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, champacilla oil, citrus oil, fir pine oil, pinecone oil, elemi oil, eucalyptus oil, fennel oil, pine needle oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil, gurdy balm oil, helichrysum oil, Ho oil , Ginger oil, iris oil, jasmin oil, cajeput oil,
Kalmusöl, Kamillenöl, Kampferöl, Kanagaöl, Kardamomenöl, Kassiaöl, Kiefernnadelöl, Calamus oil, chamomile oil, camphor oil, kanga oil, cardamom oil, cassia oil, pine needle oil,
Kopaivabalsamöl, Korianderöl, Krauseminzeöl, Kümmelöl, Kuminöl, Labdanumöl, Lavendelöl, Lemongrasöl, Lindenblütenöl, Limettenöl, Mandarinenöl, Melissenöl, Minzöl, Moschuskörneröl, Muskatelleröl, Myrrhenöl, Nelkenöl, Neroliöl, Niaouliöl, Olibanumöl, Orangenblütenöl, Copaiba balsam, coriander oil, spearmint oil, caraway oil, cumin oil, labdanum oil, lavender oil, lemongrass oil, lime blossom oil, lime oil, tangerine oil, lemon balm oil, mint oil, musk oil, myrrh oil, clove oil, neroli oil, niaouli oil, olibanum oil, orange blossom oil,
Orangenschalenöl, Origanumöl, Palmarosaöl, Patschuliöl, Perubalsamöl, Petitgrainöl, Pfefferöl, Pfefferminzöl, Pimentöl, Pine-Öl, Rosenöl, Rosmarinöl, Salbeiöl, Sandelholzöl, Sellerieöl, Spiköl, Sternanisöl, Terpentinöl, Thujaöl, Thymianöl, Verbenaöl, Vetiveröl, Wacholderbeeröl, Wermutöl, Wintergrünöl, Ylang-Ylang-Öl, Ysop-Öl, Zimtöl, Zimtblätteröl, Zitronellöl, Zitronenöl sowie Orange peel oil, Origanum oil, Palmarosa oil, Patchouli oil, Peruvian balsam oil, Petitgrain oil, Pepper oil, Peppermint oil, Pimento oil, Pine oil, Rose oil, Rosemary oil, Sage oil, Sandalwood oil, Celery oil, Spik oil, Star aniseed oil, Turpentine oil, Thuja oil, Thyme oil, Verbena oil, Vetiver oil, Juniper berry oil, Vermouth oil, Wintergreen oil, ylang-ylang oil, hyssop oil, cinnamon oil, cinnamon oil, lemon oil, lemon oil as well
Zypressenöl sowie Ambrettolid, Ambroxan, alpha-Amylzimtaldehyd, Anethol, Anisaldehyd, Anisalkohol, Anisol, Anthranilsäuremethylester, Acetophenon, Benzylaceton, Benzaldehyd, Benzoesäureethylester, Benzophenon, Benzylalkohol, Benzylacetat, Benzylbenzoat, Cypress oil and ambrettolide, ambroxan, alpha-amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, benzyl acetate, benzyl benzoate,
Benzylformiat, Benzylvalerianat, Borneol, Bornylacetat, Boisambrene forte, alpha-Bromstyrol, n-
Decylaldehyd, n-Dodecylaldehyd, Eugenol, Eugenolmethylether, Eukalyptol, Farnesol, Fenchon, Fenchylacetat, Geranylacetat, Geranylformiat, Heliotropin, Heptincarbonsäuremethylester, Heptaldehyd, Hydrochinon-Dimethylether, Hydroxyzimtaldehyd, Hydroxyzimtalkohol, Indol, Iron, Isoeugenol, Isoeugenolmethylether, Isosafrol, Jasmon, Kampfer, Karvakrol, Karvon, p- Kresolmethylether, Cumarin, p-Methoxyacetophenon, Methyl-n-amylketon, Benzyl formate, benzyl valerate, borneol, bornyl acetate, Boisambrene forte, alpha-bromostyrene, n- Decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmon, camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl n-amyl ketone,
Methylanthranilsäuremethylester, p-Methylacetophenon, Methylchavikol, p-Methylchinolin, Methyl- beta-naphthylketon, Methyl-n-nonylacetaldehyd, Methyl-n-nonylketon, Muskon, beta- Naphtholethylether, beta-Naphthol-methylether, Nerol, n-Nonylaldehyd, Nonylalkohol, n- Octylaldehyd, p-Oxy-Acetophenon, Pentadekanolid, beta-Phenylethylalkohol, Phenylessigsäure, Pulegon, Safrol, Salicylsäureisoamylester, Salicylsäuremethylester, Salicylsäurehexylester, Salicylsäurecyclohexylester, Santalol, Sandelice, Skatol, Terpineol, Thymen, Thymol, Troenan, gamma-Undelacton, Vanillin, Veratrumaldehyd, Zimtaldehyd, Zimtalkohol, Zimtsäure, Methyl anthranilate, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-beta-naphthyl ketone, methyl-n-nonylacetaldehyde, methyl n-nonyl ketone, muscone, beta-naphthol ethyl ether, beta-naphthol methyl ether, nerol, n-nonyl aldehyde, nonyl alcohol, n-octylaldehyde, p-oxyacetophenone, pentadecanolide, beta-phenylethyl alcohol, phenylacetic acid, pulegone, safrole, isoamyl salicylate, methyl salicylate, salicylic acid hexyl ester, cyclohexyl salicylate, santalol, sandelice, skatole, terpineol, thymes, thymol, troenan, gamma undelactone, vanillin, Veratrumaldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid,
Zimtsäureethylester, Zimtsäurebenzylester, Diphenyloxid, Limonen, Linalool, Linalylacetat und - Propionat, Melusat, Menthol, Menthon, Methyl-n-heptenon, Pinen, Phenylacetaldehyd, Cinnamic acid ethyl ester, cinnamic acid benzyl ester, diphenyloxide, limonene, linalool, linalyl acetate and propionate, melusate, menthol, menthone, methyl-n-heptenone, pinene, phenylacetaldehyde,
Terpinylacetat, Citral, Citronellal, sowie Mischungen daraus. Terpinyl acetate, citral, citronellal, and mixtures thereof.
In einer alternativen Ausführungsform kann es bevorzugt sein, dass zumindest ein Teil des Duftstoffs als Duftstoffvorläufer oder in verkapselter Form (Duftstoffkapseln), insbesondere in Mikrokapseln, eingesetzt wird. Bei den Mikrokapseln kann es sich um wasserlösliche und/oder wasserunlösliche Mikrokapseln handeln. Es können beispielsweise Melamin-Harnstoff- Formaldehyd-Mikrokapseln, Melamin-Formaldehyd-Mikrokapseln, Harnstoff-Formaldehyd- Mikrokapseln oder Stärke-Mikrokapseln eingesetzt werden.„Duftstoffvorläufer" bezieht sich auf Verbindungen, die erst nach chemischer Umwandlung/Spaltung, typischerweise durch Einwirkung von Licht oder anderen Umgebungsbedingungen, wie pH-Wert, Temperatur, etc., den eigentlichen Duftstoff freisetzen. Derartige Verbindungen werden häufig auch als Duftspeicherstoffe oder„Pro- Fragrance" bezeichnet. In an alternative embodiment, it may be preferred that at least a portion of the perfume is used as a perfume precursor or in encapsulated form (perfume capsules), especially in microcapsules. The microcapsules may be water-soluble and / or water-insoluble microcapsules. For example, melamine-urea-formaldehyde microcapsules, melamine-formaldehyde microcapsules, urea-formaldehyde microcapsules, or starch microcapsules can be used. "Perfume precursor" refers to compounds that undergo chemical conversion / cleavage, typically by the action of light or other environmental conditions, such as pH, temperature, etc., to release the actual fragrance Such compounds are often referred to as fragrance or "fragrance fragrance".
Unabhängig davon in welcher Form sie eingesetzt werden, beträgt die Menge an Duftstoff in der Zusammensetzung gemäß der vorliegenden Erfindung vorzugsweise zwischen 1 bis 20 Gew.-%, vorzugsweise 1 bis 15 Gew.-%, insbesondere von 3 bis 10 Gew.-%, bezogen auf das Regardless of the form in which they are used, the amount of perfume in the composition according to the present invention is preferably between 1 and 20% by weight, preferably between 1 and 15% by weight, in particular between 3 and 10% by weight. based on the
Gesamtgewicht der Zusammensetzung. Total weight of the composition.
Weiterhin kann die feste Zubereitung mindestens ein amorphes Silikat oder Zeolith enthalten. Furthermore, the solid preparation may contain at least one amorphous silicate or zeolite.
Einsetzbar sind amorphe Natriumsilikate mit einem Modul Na2Ü : S1O2 von 1 :2 bis 1 :3,3, vorzugsweise von 1 :2 bis 1 :2,8 und insbesondere von 1 :2 bis 1 :2,6. Im Rahmen dieser Erfindung wird unter dem Begriff "amorph" verstanden, dass die Silikate bei Röntgenbeugungsexperimenten keine scharfen Röntgenreflexe liefern, wie sie für kristalline Substanzen typisch sind, sondern
allenfalls ein oder mehrere Maxima der gestreuten Röntgenstrahlung, die eine Breite von mehreren Gradeinheiten des Beugungswinkels aufweisen, hervorrufen. It is possible to use amorphous sodium silicates with a Na 2 U: SiO 2 modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8, and in particular from 1: 2 to 1: 2.6. In the context of this invention, the term "amorphous" is understood to mean that the silicates do not yield sharp X-ray reflections in X-ray diffraction experiments, as they are typical for crystalline substances, but instead possibly one or more maxima of the scattered X-radiation, which have a width of several degrees of the diffraction angle, cause.
Alternativ oder in Kombination mit den vorgenannten amorphen Natriumsilikaten werden röntgenamorphe Silikate eingesetzt, deren Silikatpartikel bei Elektronenbeugungsexperimenten verwaschene oder sogar scharfe Beugungsmaxima liefern. Dies ist so zu interpretieren, dass die Produkte mikrokristalline Bereiche der Größe zehn bis einige Hundert nm aufweisen, wobei Werte bis max. 50 nm und insbesondere bis max. 20 nm bevorzugt sind. Derartige röntgenamorphe Silikate, weisen ebenfalls eine Löseverzögerung gegenüber den herkömmlichen Wassergläsern auf. Insbesondere bevorzugt sind verdichtete/kompaktierte amorphe Silikate, compoundierte amorphe Silikate und übertrocknete röntgenamorphe Silikate. Alternatively or in combination with the abovementioned amorphous sodium silicates, X-ray-amorphous silicates are used whose silicate particles give washed-out or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of the size of ten to a few hundred nm, with values of up to max. 50 nm and in particular up to max. 20 nm are preferred. Such X-ray amorphous silicates also have a dissolution delay compared to conventional water glasses. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.
In verschiedenen Ausführungsformen kann die Schmelzkörper-Zusammensetzung, wie hierin beschrieben, ferner mindestens eine Textil-pflegende Verbindung umfassen. Unter einer Textil- pflegenden Verbindung wird in diesem Zusammenhang jede Verbindung verstanden, die damit behandelten textilen Flächengebilden einen vorteilhaften Effekt vermittelt, wie beispielsweise einen Textil-weichmachenden Effekt, Knitterfestigkeit bzw. die schädliche oder negative Effekte, die beim Reinigen und/oder Konditionieren und/oder Tragen auftreten können, wie beispielsweise In various embodiments, the fuser composition as described herein may further comprise at least one fabric conditioning compound. In this context, a textile care compound is understood to mean any compound which gives textile fabrics treated therewith a beneficial effect, such as, for example, a textile softening effect, crease resistance or the harmful or negative effects which result during cleaning and / or conditioning and / or or wearing, such as
Verblassen, Vergrauung, usw., reduziert. Fading, graying, etc., reduced.
Die Textil-pflegende Verbindung kann vorzugsweise aus Textil-weichmachenden Verbindungen, Bleichmitteln, Bleichaktivatoren, Enzymen, Silikonölen, Antiredepositionsmittel, optischen Aufheller, Vergrauungsinhibitoren, Einlaufverhinderer, Knitterschutzmittel, Farbübertragungsinhibitoren, antimikrobiellen Wirkstoffen, Germiziden, Fungiziden, Antioxidantien, Antistatika, Bügelhilfsmitteln, Phobier- und Imprägniermitteln, Quell- und Schiebefestmitteln, UV-Absorber sowie Mischungen daraus ausgewählt werden. The fabric care composition may preferably be made of fabric softening compounds, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, wrinkle inhibitors, color transfer inhibitors, antimicrobials, germicides, fungicides, antioxidants, antistatic agents, ironing aids, phobizers and the like Impregnating agents, swelling and slipping agents, UV absorbers and mixtures thereof are selected.
Es ist insbesondere bevorzugt, dass die Textil-pflegende Verbindung eine Textil-weichmachende Verbindung ist. Dabei ist ganz besonders bevorzugt, dass die Textil-weichmachende Verbindung aus Polysiloxanen, Textil-weichmachenden Tonen, kationischen Polymeren und Mischungen daraus ausgewählt ist. It is particularly preferred that the fabric care compound is a fabric softening compound. It is most preferred that the fabric softening compound is selected from polysiloxanes, fabric softening clays, cationic polymers and mixtures thereof.
Die Verwendung von Polysiloxanen und/oder kationischen Polymeren als Textil-pflegende Verbindung in der Schmelzkörper-Zusammensetzung ist vorteilhaft, da diese nicht nur einen weichmachenden Effekt zeigen, sondern auch den Parfümeindruck auf der Wäsche verstärken. Die Verwendung von weichmachenden Tonen als Textil-pflegende Verbindung in der Schmelzkörper- Zusammensetzung ist vorteilhaft, da diese zusätzlich einen Wasser-enthärtenden Effekt aufweisen und so beispielsweise Kalkablagerungen auf der Wäsche verhindert werden können. Um eine
optimale Leistung zu erzielen, kann es bevorzugt sein, dass die Schmelzkörper-Zusammensetzung eine Kombination von wenigstens zwei Textil-pflegenden Verbindungen enthält. The use of polysiloxanes and / or cationic polymers as a fabric care compound in the fuser composition is advantageous because it not only exhibits a softening effect but also enhances the perfume impression on the wash. The use of softening clays as textile-care compound in the melted body composition is advantageous because they additionally have a water-softening effect and thus, for example, limescale deposits on the laundry can be prevented. To one For optimum performance, it may be preferred that the fusible composition contain a combination of at least two fabric care compounds.
Wenn die erfindungsgemäße Schmelzkörper-Zusammensetzung derartige Textil-pflegende Verbindungen enthält, wird sie insbesondere als Textilpflegemittel oder Weichspüler oder als Bestandteil eines solchen Mittels oder auch als Bestandteil eines Waschmittels eingesetzt. When the fused-state composition according to the invention contains such textile-care compounds, it is used in particular as a textile care agent or softener or as a constituent of such an agent or else as a constituent of a detergent.
Ein solcher Weichspüler kann im Hauptwaschgang eines automatischen Wasch- oder Such a fabric conditioner may be in the main wash of an automatic washing or
Reinigungsverfahrens eingesetzt werden. Die Schmelzkörper-Zusammensetzung kann beispielsweise zusammen mit dem Wasch- oder Reinigungsmittel in die Trommel oder die Einspülkammer einer Waschmaschine gegeben werden. Dies hat den Vorteil, dass kein zusätzlicher Spülgang notwendig ist und keine unschönen Ablagerungen in der Einspülkammer auftreten Cleaning process can be used. For example, the enamel composition may be added to the drum or dispenser compartment of a washing machine along with the detergent or cleaning agent. This has the advantage that no additional rinse is necessary and no unsightly deposits occur in the dispenser
Weiterhin kann eine solche Schmelzkörper-Zusammensetzung im Waschgang eines Furthermore, such a melted body composition in the wash of a
Wäschereinigungsverfahrens eingesetzt werden und so die Textil-pflegende Verbindung und das Parfüm bereits direkt zu Beginn des Waschverfahrens zur Wäsche transportieren, um so ihr volles Potential entfalten zu können. Weiterhin ist die erfindungsgemäße Schmelzkörper- Zusammensetzung einfacher und besser zu handhaben als flüssige Zusammensetzungen, da keine Tropfen am Flaschenrand zurückbleiben, die bei der anschließenden Lagerung der Flasche zu Rändern auf dem Untergrund oder zu unschönen Ablagerungen im Bereich des Verschlusses führen. Dasselbe gilt für den Fall, dass bei der Dosierung etwas von der Schmelzkörper- Zusammensetzung versehentlich verschüttet wird. Die verschüttete Menge kann auch einfacher und sauberer entfernt werden. Laundry cleaning process can be used and so the textile-care compound and the perfume already at the beginning of the washing process to transport laundry, so as to be able to develop their full potential. Furthermore, the enamel composition according to the invention is simpler and easier to handle than liquid compositions, since no drops remain on the edge of the bottle, which lead to edges on the substrate during subsequent storage of the bottle or to unsightly deposits in the region of the closure. The same is true in the case where some of the enamel body composition is accidentally spilled during dosing. The spilled amount can also be removed easier and cleaner.
Ein bevorzugt einsetzbares Polysiloxan weist zumindest folgende Struktureinheit auf A preferably usable polysiloxane has at least the following structural unit
mit With
R = unabhängig von einander Ci-C3o-Alkyl, vorzugsweise Ci-C4-Alkyl, insbesondere Methyl oder Ethyl, R = independently of one another C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
n = 1 bis 5000, vorzugsweise 10 bis 2500, insbesondere 100 bis 1500. n = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.
Es kann bevorzugt sein, dass das Polysiloxan zusätzlich auch folgende Struktureinheit aufweist:
It may be preferred that the polysiloxane additionally has the following structural unit:
mit With
R = Ci-C3o-Alkyl, vorzugsweise Ci-C4-Alkyl, insbesondere Methyl oder Ethyl, R is C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
Y = ggf. substituiertes, lineares oder verzweigtes Ci-C2o-Alkylen, vorzugsweise -(CH2)m- mit m= 1 bis 16, vorzugsweise 1 bis 8, insbesondere 2 bis 4, im speziellen 3, Y = optionally substituted, linear or branched C 1 -C 20 -alkylene, preferably - (CH 2) m - with m = 1 to 16, preferably 1 to 8, in particular 2 to 4, in particular 3,
R2, R3 = unabhängig voneinander H oder gegebenenfalls substituiertes, lineares oder verzweigtes Ci-C3o-Alkyl, vorzugsweise mit Aminogruppen substituiertes Ci-C3o-Alkyl, besonders R 2 , R 3 = independently of one another are H or optionally substituted, linear or branched C 1 -C 30 -alkyl, preferably C 1 -C 30 -alkyl which is substituted by amino groups, especially
bevorzugt -(CH2)b-NH2 mit b = 1 bis 10, äußerst bevorzugt b = 2, preferably - (CH 2) b -NH 2 where b = 1 to 10, very preferably b = 2,
x = 1 bis 5000, vorzugsweise 10 bis 2500, insbesondere 100 bis 1500. x = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.
Weist das Polysiloxan nur die Struktureinheit a) mit R = Methyl auf, handelt es sich um ein Poly- dimethylsiloxan. Polydimethylpolysiloxane sind als effiziente Textil-pflegende Verbindungen bekannt. If the polysiloxane has only the structural unit a) with R = methyl, then it is a poly-dimethylsiloxane. Polydimethylpolysiloxanes are known as efficient fabric care compounds.
Geeignete Polydimethysiloxane umfassen DC-200 (ex Dow Corning), Baysilone® M 50, Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50,
Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 oder Baysilone® M 5000 (alle ex GE Bayer Silicones). Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone® M 5000 (all ex GE Bayer Silicones).
Es kann allerdings auch bevorzugt sein, dass das Polysiloxan die Struktureinheiten a) und b) enthält. Ein besonders bevorzugtes Polysiloxan weist die folgende Struktur auf: However, it may also be preferred that the polysiloxane contains the structural units a) and b). A particularly preferred polysiloxane has the following structure:
(CH3)3Si-[0-Si(CH3)2]n-[0-Si(CH3){(CH2)3-NH-(CH2)2-NH2}]x-OSi(CH3)3 wobei die Summe n + x eine Zahl zwischen 2 und 10.000 ist. (CH 3 ) 3 Si - [0-Si (CH 3) 2] n - [O-Si (CH 3 ) {(CH 2 ) 3 -NH- (CH 2) 2 -NH 2}] x -OSi (CH 3 ) 3 where the sum n + x is a number between 2 and 10,000.
Geeignete Polysiloxane mit den Struktureinheiten a) und b) sind beispielsweise kommerziell unter den Markennamen DC2-8663, DC2-8035, DC2-8203, DC05-7022 oder DC2-8566 (alle ex Dow Corning) erhältlich. Erfindungsgemäß ebenfalls geeignet sind beispielsweise die im Handel erhältlichen Produkte Dow Corning® 7224, Dow Corning® 929 Cationic Emulsion oder Formasil 410 (GE Silicones). Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention are also suitable for example the products commercially available Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).
Als Textil-weichmachende Tone sind insbesondere die bereits oben beschriebenen Smectit-Tone geeignet und hier insbesondere Bentonit.
Geeignete kationische Polymere umfassen insbesondere solche, die in "CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, J. M. Nikitakis, et al, Editors, veröffentlicht durch die Cosmetic, Toiletry, and Frag ra nee Association, 1991 beschrieben sind und unter der Sammelbezeichnung„Polyquaternium" zusammengefasst sind. Im Folgenden sind einige geeignete Polyquaternium-Verbindungen genauer aufgeführt. Particularly suitable textile-softening clays are the smectite clays already described above, in particular bentonite. Suitable cationic polymers include, in particular, those described in "CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, JM Nikitakis, et al., Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991, and the collective name "Polyquaternium Below are some of the more suitable Polyquaternium compounds.
POLYQUATERNIUM-1 (CAS-Nummer: 68518-54-7) POLYQUATERNIUM-1 (CAS number: 68518-54-7)
Definition: {(HOCH2CH2)3N+-CH2CH=CHCH2-[N+(CH3)2-CH2CH=CHCH2]x-N+(CH2CH20H)3}[Cr]x+2 POLYQUATERNIUM-2 (CAS-Nummer: 63451-27-4) Definition: {(HOCH2CH2) 3N + -CH 2 CH = CHCH 2 [N + (CH 3) 2 CH 2 CH = CHCH 2] xN + (CH2CH20H) 3} [Cr] x + 2 POLYQUATERNIUM-2 (CAS Number: 63451-27 -4)
Definition: [-N(CH3)2-CH 2CH2CH2-NH-C(0)-NH-CH2CH 2CH2-N(CH3)2-CH2CH20CH2CH2-]2+ (Cl")2 POLYQUATERNIUM-3 Definition: [-N (CH 3) 2 -CH 2 CH 2 CH 2 -NH-C (0) -NH-CH 2 CH 2 CH 2 N (CH 3) 2-CH2CH20CH2CH2-] 2+ (Cl ") 2 Polyquaternium 3
Definition: Copolymer von Acrylamid und Trimethylammoniumethylmethacrylatmethosulfat POLYQUATERNIUM-4 (CAS-Nummer: 92183-41 -0) Definition: Copolymer of acrylamide and trimethylammoniumethylmethacrylate methosulphate POLYQUATERNIUM-4 (CAS Number: 92183-41 -0)
Definition: Copolymer von Hydroxyethylcellulose und Diallyldimethylammoniumchlorid Definition: Copolymer of hydroxyethylcellulose and diallyldimethylammonium chloride
Beispielsweise erhältlich als Celquat® H 100 oder Celquat® L200 (ex National Starch) For example, available as Celquat® H 100 or Celquat® L200 (ex National Starch)
POLYQUATERNIUM-5 (CAS-Nummer: 26006-22-4) POLYQUATERNIUM-5 (CAS number: 26006-22-4)
Definition: Copolymer von Acrylamid und ß-Methacrylyloxyethyltrimethylammoniummethosulfat. Definition: Copolymer of acrylamide and β-methacrylyloxyethyltrimethylammonium methosulfate.
POLYQUATERNIUM-6 (CAS-Nummer: 26062-79-3) POLYQUATERNIUM-6 (CAS number: 26062-79-3)
Definition: Polymer von Dimethyldiallylammoniumchlorid Definition: Polymer of dimethyldiallylammonium chloride
POLYQUATERNIUM-7 (CAS-Nummer: 26590-05-6) POLYQUATERNIUM-7 (CAS number: 26590-05-6)
Definition: Polymeres quaternäres Ammoniumsalz bestehend aus Acrylamid- und Definition: Polymeric quaternary ammonium salt consisting of acrylamide and
Dimethyldiallylammoniumchlorid-Monomeren. Dimethyldiallylammonium chloride monomers.
POLYQUATERNIUM-8 Polyquaternium-8
Definition: Polymeres quaternäres Ammoniumsalz von Methyl- und Stearyldimethylaminoethyl- methacrylat, welches mit Dimethylsulfat quaternierte wurde Definition: Polymeric quaternary ammonium salt of methyl and stearyldimethylaminoethyl methacrylate, which was quaternized with dimethyl sulfate
POLYQUATERNIUM-9 Polyquaternium-9
Definition: Polymeres quaternäres Ammoniumsalz von Polydimethylaminoethylmethacrylat, welches mit Methyl bromid quaternierte wurde Definition: Polymeric quaternary ammonium salt of polydimethylaminoethyl methacrylate quaternized with methyl bromide
POLYQUATERNIUM-1 1 (CAS-Nummer: 53633-54-8)
Definition: Quaternäres Ammoniumpolymer, welches durch Umsetzung von Diethylsulfat mit dem Copolymer von Vinylpyrrolidon und Dimethylaminoethylmethacrylat gebildet wird. POLYQUATERNIUM-1 1 (CAS number: 53633-54-8) Definition: Quaternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate.
POLYQUATERNIUM-12 (CAS-Nummer: 68877-50-9) POLYQUATERNIUM-12 (CAS number: 68877-50-9)
Definition: Quaternäres Ammoniumpolymersalz, welches durch Umsetzung des Ethylmethacrylat/- Abietylmethacrylat/Diethylaminoethylmethacrylat-Copolymers mit Dimethylsulfat erhältlich ist Definition: Quaternary ammonium polymer salt obtainable by reaction of the ethyl methacrylate / -abietyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate
POLYQUATERNIUM-13 (CAS Nummer: 68877-47-4) POLYQUATERNIUM-13 (CAS number: 68877-47-4)
Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung des Definition: Polymeric quaternary ammonium salt obtained by reaction of the
Ethylmethacrylat/Oleylmethacrylat/Diethylaminoethylmethacrylat-Copolymers mit Dimethylsulfat erhältlich ist Ethyl methacrylate / oleyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate is available
POLYQUATERNIUM-14 (CAS-Nummer: 27103-90-8) POLYQUATERNIUM-14 (CAS number: 27103-90-8)
Definition: Polymeres quaternäres Ammoniumsalz der Formel -{-CH2-C-(CH3)-[C(0)0-CH2CH2- N(CH3)31}x+ [CH3S04]-x Definition: Polymeric quaternary ammonium salt of the formula - {- CH 2 -C- (CH 3 ) - [C (O) O-CH 2 CH 2 -N (CH 3 ) 3 1} x + [CH 3 SO 4 ] -x
POLYQUATERNIUM-15 (CAS-Nummer: 35429-19-7) POLYQUATERNIUM-15 (CAS number: 35429-19-7)
Definition: Copolymer von Acrylamid und ß-Methacrylyloxyethyltrimethylammoniumchlorid POLYQUATERNIUM-16 (CAS-Nummer: 95144-24-4) Definition: Copolymer of acrylamide and β-methacrylyloxyethyltrimethylammonium chloride POLYQUATERNIUM-16 (CAS number: 95144-24-4)
Definition: Polymeres quaternäres Ammoniumsalz, gebildet aus Methylvinylimidazoliumchlorid und Vinylpyrrolidon Definition: Polymeric quaternary ammonium salt formed from methylvinylimidazolium chloride and vinylpyrrolidone
POLYQUATERNIUM-17 (CAS-Nummer: 90624-75-2) POLYQUATERNIUM-17 (CAS number: 90624-75-2)
Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Adipinsäure und Dimethylaminopropylamin mit Dichlorethylether erhältlich ist. Definition: Polymeric quaternary ammonium salt obtainable by reaction of adipic acid and dimethylaminopropylamine with dichloroethyl ether.
POLYQUATERNIUM-18 Polyquaternium-18
Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Azelainsäure und Dimethylaminopropylamin mit Dichlorethylether erhältlich ist. Definition: Polymeric quaternary ammonium salt, which is obtainable by reaction of azelaic acid and dimethylaminopropylamine with dichloroethyl ether.
POLYQUATERNIUM-19 Polyquaternium-19
Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Polyvinylalkohol mit 2,3-Epoxypropylamin erhältlich ist. Definition: Polymeric quaternary ammonium salt, which is obtainable by reaction of polyvinyl alcohol with 2,3-epoxypropylamine.
POLYQUATERNIUM-20 Polyquaternium-20
Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Polyvinylocta- decylether mit 2,3-Epoxypropylamin erhältlich ist.
POLYQUATERNIUM-21 (CAS-Nummer: 102523-94-4) Definition: Polymeric quaternary ammonium salt obtainable by reaction of polyvinyl octadecyl ether with 2,3-epoxypropylamine. POLYQUATERNIUM-21 (CAS number: 102523-94-4)
Definition: Polysiloxan/Polydimethyldialkylammoniumacetat-Copolymer Definition: polysiloxane / polydimethyldialkylammonium acetate copolymer
POLYQUATERNIUM-22 (CAS-Nummer: 53694-17-0) POLYQUATERNIUM-22 (CAS number: 53694-17-0)
Definition: Dimethyldiallylammoniumchlorid/Acrylsäure-Copolymer Definition: dimethyldiallylammonium chloride / acrylic acid copolymer
POLYQUATERNIUM-24 (CAS-Nummer: 107987-23-5) POLYQUATERNIUM-24 (CAS number: 107987-23-5)
Definition: Polymeres quaternäres Ammoniumsalz aus der Umsetzung von Hydroxyethylcellulose mit einem mit Lauryldimethylammonium substituierten-Epoxid Definition: Polymeric quaternary ammonium salt from the reaction of hydroxyethylcellulose with a lauryldimethylammonium substituted epoxide
POLYQUATERNIUM-27 Polyquaternium-27
Definition: Blockcopolymer aus der Umsetzung von Polyquaternium-2 mit Polyquaternium-17. POLYQUATERNIUM-28 (CAS-Nummer: 131954-48-8) Definition: Block copolymer from the reaction of Polyquaternium-2 with Polyquaternium-17. POLYQUATERNIUM-28 (CAS number: 131954-48-8)
Definition: Vinylpyrrolidon/Methacrylamidopropyltrimethylammoniumchlorid-Copolymer POLYQUATERNIUM-29 Definition: vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymer POLYQUATERNIUM-29
Definition: Chitosan, welches mit Propylenoxid umgesetzt und mit Epichlorhydrin quaternisiert wurde Definition: Chitosan, which was reacted with propylene oxide and quaternized with epichlorohydrin
POLYQUATERNIUM-30 Polyquaternium-30
Definition: Polymeres quaternäres Ammoniumsalz der Formel: -[CH2C(CH3)(C(0)OCH3)]x- [CH2C(CH3)(C(0) OCH2CH2N+(CH3)2CH2COO-)]y- Definition: Polymeric quaternary ammonium salt of the formula: - [CH 2 C (CH 3) (C (O) OCH 3)] x- [CH 2 C (CH 3) (C (O) OCH 2 CH 2 N + (CH 3) 2 CH 2 COO-)] y -
POLYQUATERNIUM-31 (CAS-Nummer. 136505-02-7) POLYQUATERNIUM-31 (CAS number: 136505-02-7)
POLYQUATERNIUM-32 (CAS-Nummer: 35429-19-7) POLYQUATERNIUM-32 (CAS number: 35429-19-7)
Definition: Polymer von N,N,N-Trimethyl-2-[(2-methyl-1 -oxo-2-propenyl)oxy]-ethanaminiumchlorid mit 2-Propenamid Definition: Polymer of N, N, N-trimethyl-2 - [(2-methyl-1-oxo-2-propenyl) oxy] -ethanaminium chloride with 2-propenamide
POLYQUATERNIUM-37 (CAS-Nummer: 26161-33-1 ) POLYQUATERNIUM-37 (CAS number: 26161-33-1)
Definition: Homopolymer von Methacryloyltrimethylchlorid Definition: homopolymer of methacryloyltrimethyl chloride
Beispielsweise erhältlich als Synthalen® CR (ex 3V Sigma) For example, available as Synthalen® CR (ex 3V Sigma)
POLYQUATERNIUM-44 (CAS-Nummer: 150595-70-5) POLYQUATERNIUM-44 (CAS number: 150595-70-5)
Definition: Quaternäres Ammoniumsalz des Copolymers von Vinylpyrrolidon und quaternisiertem Imidazolin Definition: Quaternary ammonium salt of the copolymer of vinylpyrrolidone and quaternized imidazoline
POLYQUATERNIUM-68 (CAS-Nummer: 827346-45-2)
Definition: Quaternisiertes Copolymer von Vinylpyrrolidon, Methacrylamid, Vinylimidazol und quaternisiertem Vinylimidazol POLYQUATERNIUM-68 (CAS-Number: 827346-45-2) Definition: Quaternized copolymer of vinylpyrrolidone, methacrylamide, vinylimidazole and quaternized vinylimidazole
Es kann bevorzugt sein, dass die Schmelzkörper-Zusammensetzung eine Textil-weichmachende Verbindung und eine oder mehr weitere Textil-pflegende Verbindung(en) enthält. It may be preferred that the melted body composition contains a fabric softening compound and one or more other fabric care compounds.
Die Menge an Textil-pflegender Verbindung in der Schmelzkörper-Zusammensetzung kann, in verschiedenen Ausführungsformen, 0,1 bis 15 Gew.-% und bevorzugt 2 bis 12 Gew.-% betragen. The amount of fabric care compound in the fuser composition may, in various embodiments, be from 0.1 to 15 weight percent, and preferably from 2 to 12 weight percent.
Die Schmelzkörper-Zusammensetzung kann optional weitere Inhaltsstoffe enthalten. Um die anwendungstechnischen und/oder ästhetischen Eigenschaften unabhängig von ihrem The fuser composition may optionally contain other ingredients. To the application-technical and / or aesthetic characteristics independently of her
Einsatzzweck zu verbessern, werden diese zusätzliche Inhaltsstoffe vorzugsweise ausgewählt aus der Gruppe bestehend aus Farbstoffen, Perlglanzmitteln, Haut-pflegenden Verbindungen, Bitterstoffen und Mischungen daraus. Purpose to improve these additional ingredients are preferably selected from the group consisting of dyes, pearlescing agents, skin-care compounds, bittering agents and mixtures thereof.
Um den ästhetischen Eindruck der Schmelzkörper-Zusammensetzung zu verbessern, kann sie mit geeigneten Farbstoffen eingefärbt werden. Bevorzugte Farbstoffe, deren Auswahl dem Fachmann keinerlei Schwierigkeit bereitet, sollten eine hohe Lagerstabilität und Unempfindlichkeit gegenüber den übrigen Inhaltsstoffen der Wasch- oder Reinigungsmittel und gegen Licht sowie keine ausgeprägte Substantivität gegenüber Textilfasern aufweisen, um diese nicht anzufärben. In order to improve the aesthetic impression of the enamel composition, it can be colored with suitable dyes. Preferred dyes, the selection of which presents no difficulty to the skilled person, should have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
Die Schmelzkörper-Zusammensetzung kann zur Erhöhung des Glanzes auch ein Perlglanzmittel enthalten. Beispiele für geeignete Perlglanzmittel sind Ethylenglykolmono- und -distearat sowie PEG-3-distearat. The enamel composition may also contain a pearlescer to increase gloss. Examples of suitable pearlescing agents are ethylene glycol mono- and distearate and PEG-3-distearate.
Weiterhin kann die Schmelzkörper-Zusammensetzung eine hautpflegende Verbindung umfassen. Furthermore, the enamel composition may comprise a skin care compound.
Unter einer hautpflegenden Verbindung wird eine Verbindung oder eine Mischung aus A skin care compound is a compound or mixture of
Verbindungen verstanden, die bei Kontakt eines Textils mit dem Waschmittel auf das Textil aufziehen und bei Kontakt des Textils mit Haut der Haut einen Vorteil verleihen verglichen mit einem Textil, welche nicht mit der erfindungsgemäßen Schmelzkörper-Zusammensetzung behandelt wurde. Dieser Vorteil kann beispielsweise den Transfer der hautpflegenden Verbindung vom Textil auf die Haut, einen geringeren Wassertransfer von der Haut auf das Textil oder eine geringere Reibung auf der Hautoberfläche durch das Textil umfassen. Compounds understood, which attract on contact of a textile with the detergent on the textile and confer an advantage on contact of the textile with skin skin compared to a textile which has not been treated with the inventive fused body composition. This benefit may include, for example, the transfer of the skin care compound from the textile to the skin, less water transfer from the skin to the textile, or less friction on the skin surface through the textile.
Die hautpflegende Verbindung ist vorzugsweise hydrophob, kann flüssig oder fest sein und muss kompatibel mit den anderen Inhaltsstoffen der festen Schmelzkörper-Zusammensetzung sein. Die hautpflegende Verbindung kann beispielsweise
a) Wachse wie Carnauba, Spermaceti, Bienenwachs, Lanolin, Derivate davon sowie Mischungen daraus; The skin care compound is preferably hydrophobic, may be liquid or solid, and must be compatible with the other ingredients of the solid fused body composition. For example, the skin care compound a) waxes such as carnauba, spermaceti, beeswax, lanolin, derivatives thereof and mixtures thereof;
b) Pflanzenextrakte, zum Beispiel pflanzliche Öle wie Avokadoöl, Olivenöl, Palmöl, Palmenkernöl, Rapsöl, Leinöl, Sojaöl, Erdnussöl, Korianderöl, Ricinusöl, Mohnöl, Kakaoöl, Kokosnussöl, Kürbiskernöl, Weizenkeimöl, Sesamöl, Sonnenblumenöl, Mandelöl, Macadamianussöl, Aprikosenkernöl, Haselnussöl, Jojobaöl oder Canolaöl, Kamille, Aloe Vera sowie Mischungen daraus; b) Plant extracts, for example vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil, hazelnut oil , Jojoba oil or canola oil, chamomile, aloe vera and mixtures thereof;
c) höhere Fettsäuren wie Laurinsäure, Myristinsäure, Palmitinsäure, Stearinsäure, Behensäure, Ölsäure, Linolsäure, Linolensäure, Isostearinsäure oder mehrfach ungesättigte Fettsäuren; d) höhere Fettalkohole wie Laurylalkohol, Cetylalkohol, Stearylalkohol, Oleylalkohol, c) higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid or polyunsaturated fatty acids; d) higher fatty alcohols, such as lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol,
Behenylalkohol oder 2-Hexadecanol, Behenyl alcohol or 2-hexadecanol,
e) Ester wie Cetyloctanoat, Lauryllactat, Myristyllactat, Cetyllactat, Isopropylmyristat, e) esters such as cetyloctanoate, lauryl lactate, myristyl lactate, cetyl lactate, isopropyl myristate,
Myristylmyristat, Isopropylpalmitat, Isopropyladipat, Butylstearat, Decyloleat, Myristyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl oleate,
Cholesterolisostearat, Glycerolmonostearat, Glyceroldistearat, Glyceroltristearat, Alkyllactat, Alkylcitrat oder Alkyltartrat; Cholesterol isostearate, glycerol monostearate, glyceryl distearate, glycerol tristearate, alkyl lactate, alkyl citrate or alkyl tartrate;
f) Kohlenwasserstoffe wie Paraffine, Mineralöle, Squalan oder Squalen; f) hydrocarbons such as paraffins, mineral oils, squalane or squalene;
g) Lipide; g) lipids;
h) Vitamine wie Vitamin A, C oder E oder Vitaminalkylester; h) vitamins such as vitamins A, C or E or vitamin alkyl esters;
i) Phospholipide; i) phospholipids;
j) Sonnenschutzmittel wie Octylmethoxylcinnamat und Butylmethoxybenzoylmethan; j) sunscreens such as octyl methoxyl cinnamate and butyl methoxybenzoyl methane;
k) Silikonöle wie lineare oder cyclische Polydimethylsiloxane, Amino-, Alkyl-, Alkylaryl- oder Aryl- substituierte Silikonöle und k) silicone oils such as linear or cyclic polydimethylsiloxanes, amino-, alkyl-, alkylaryl- or aryl-substituted silicone oils and
I) Mischungen daraus I) mixtures thereof
umfassen. include.
Die Menge an hautpflegender Verbindung beträgt vorzugsweise zwischen 0,01 und 10 Gew.-%, vorzugsweise zwischen 0,1 und 5 Gew.-% und ganz besonders bevorzugt zwischen 0,3 und 3 Gew.-% bezogen auf das Gesamtgewicht der Schmelzkörper-Zusammensetzung. Es kann sein, dass die Haut-pflegende Verbindung zusätzlich auch einen Textil-pflegenden Effekt besitzt. The amount of skin-care compound is preferably between 0.01 and 10% by weight, preferably between 0.1 and 5% by weight and very particularly preferably between 0.3 and 3% by weight, based on the total weight of the enamel body. Composition. It may be that the skin-nourishing compound additionally has a textile care effect.
Um eine orale Aufnahme der Schmelzkörper-Zusammensetzung durch Menschen, insbesondere Kinder, oder Tiere zu verhindern, kann diese einen Bitterstoff wie Bitrex® enthalten. To prevent oral ingestion of the enamel composition by humans, especially children, or animals, it may contain a bittering agent such as Bitrex®.
Beispielrezepturen geeigneter Schmelzkörper-Zusammensetzungen umfassen die folgenden Inhaltsstoffe: Example formulations of suitable enamel compositions include the following ingredients:
0,01 bis 20, insbesondere 0,1 bis 20 Gew.-% Parfümöl und/oder Duftstoffkapseln, 0.01 to 20, in particular 0.1 to 20 wt .-% perfume oil and / or perfume capsules,
1 ,1 bis 40,0 Gew.-% Schichtsilikat, vorzugsweise Tonmineral, mehrbevorzugt Bentonit,
0,00 bis 30, vorzugsweise 10 bis 25 Gew.-% eines anorganischen Salzes, insbesondere 1, 1 to 40.0% by weight of phyllosilicate, preferably clay mineral, more preferably bentonite, 0.00 to 30, preferably 10 to 25 wt .-% of an inorganic salt, in particular
Natriumsulfat, Sodium sulfate,
0,00 bis 30, vorzugsweise 10 bis 25 Gew.-%, noch bevorzugter 20 bis 25 Gew.-% eines From 0.00 to 30, preferably from 10 to 25 weight percent, more preferably from 20 to 25 weight percent of a
Polysaccharids, insbesondere Stärke, oder 0,00 bis 30, vorzugsweise 1 bis 10, noch bevorzugter 2 bis 7 Gew.-% einer pyrogenen oder Fällungskieselsäure, Polysaccharide, in particular starch, or from 0.0030 to 30, preferably from 1 to 10, more preferably from 2 to 7,% by weight of a pyrogenic or precipitated silica,
0,0001-1-% Farbstoff , 0.0001-1% dye,
bis zu 0,002 % Aktivsubstanzgehalt Bitrex®, up to 0.002% active ingredient content Bitrex ® ,
ad 100 Gew.-% Polyethylenglykol mit 4000 bis 15.000 g/mol, vorzugsweise 9.000 bis 13.000 g/mol als wasserlösliches oder wasserdispergierbares Trägerpolymer. to 100% by weight of polyethylene glycol having 4,000 to 15,000 g / mol, preferably 9,000 to 13,000 g / mol as a water-soluble or water-dispersible carrier polymer.
Bei der Schmelzkörper-Zusammensetzung gemäß der vorliegenden Erfindung handelt es sich um eine feste, partikuläre Zusammensetzung. Die einzelnen Partikel der Zusammensetzung können dabei als Schmelzkörper bezeichnet werden, die bei Raumtemperatur und Temperaturen bis 30°C, vorzugsweise bis 40°C fest sind. The fused-state composition according to the present invention is a solid, particulate composition. The individual particles of the composition can be referred to as a melting body, which are solid at room temperature and temperatures up to 30 ° C, preferably up to 40 ° C.
Ein Verfahren zur Herstellung derartiger Schmelzkörper kann mittels bekannter Batch-Verfahren, in denen die Inhaltsstoffe gemischt und gemeinsam erwärmt bzw. einer oder mehrere der Inhaltstoffe vorgelegt und erwärmt und dann sukzessive die übrigen Inhaltsstoffe zugegeben werden, erfolgen. Die so erhaltenen Schmelze kann dann einer Abkühlung und Umformung unterzogen werden. Alternativ können auch Verfahren eingesetzt werden, die die folgenden Schritte umfassen: A process for producing such fused bodies can be carried out by means of known batch processes in which the ingredients are mixed and heated together, or one or more of the ingredients are initially charged and heated and then the remaining ingredients are added successively. The melt thus obtained can then be subjected to cooling and reshaping. Alternatively, methods may be used which include the following steps:
(a) kontinuierliches Fördern einer Schmelze umfassend das mindestens eine (a) continuously conveying a melt comprising the at least one
wasserlösliche oder wasserdispergierbare Trägerpolymer sowie das Schichtsilikat; water-soluble or water-dispersible carrier polymer and the layered silicate;
(b) kontinuierliches Zudosieren des mindestens einen Duftstoffs zu der Schmelze (b) continuously metering the at least one perfume to the melt
umfassend das mindestens eine wasserlösliche oder wasserdispergierbare Trägerpolymer; comprising the at least one water-soluble or water-dispersible carrier polymer;
(c) Mischen der Schmelze umfassend das mindestens eine wasserlösliche oder (c) mixing the melt comprising the at least one water-soluble or
wasserdispergierbare Trägerpolymer und des mindestens einen Duftstoffs; und water-dispersible carrier polymer and the at least one perfume; and
(d) Abkühlen und optional Umformen der Mischung um parfümhaltige Schmelzkörper zu erhalten. (d) cooling and optionally forming the mixture to obtain perfume-containing fused bodies.
Optional können auch das mindestens eine Polysaccharid/die mindestens eine Kieselsäure und optional das mindestens eine anorganische Salz in Schritt (a), in Schritt (b) oder einem oder mehreren separaten Schritten (b1 ), (b2), etc., die jeweils vor oder nach Schritt (b) oder (c) durchgeführt werden können, zudosiert werden. Der Mischschritt (c) kann dann nach jedem Zudosierschritt oder nur nach einem oder mehreren Zudosierschritten erfolgen. Optionally, the at least one polysaccharide (s), and optionally the at least one inorganic salt in step (a), in step (b) or one or more separate steps (b1), (b2), etc., respectively or after step (b) or (c) can be metered. The mixing step (c) can then take place after each metering step or only after one or more metering steps.
Die so hergestellten Schmelzkörper können jede beliebige Form haben. Die Formgebung erfolgt dabei insbesondere in Schritt (d) des beschriebenen Verfahrens. Bevorzugt sind dementsprechend feste, partikuläre Formen, wie beispielsweise im Wesentlichen sphärische, figurlich, schuppen-,
quader-, zylinder-, kegel-, kugelkalotten- bzw. linsen-, hemisphären-, scheibchen- oder nadeiförmige Partikel oder auch figürliche Formen. Beispielsweise können die Partikel eine Gummibärchen-artige, figürliche Ausgestaltung haben. Dabei beträgt die maximale Ausdehnung der Partikel in einer räumlichen Dimension vorzugsweise von 0,5 bis 10 mm, insbesondere 0,8 bis 8 mm, besonders bevorzugt 1 bis 7 mm und ganz besonders bevorzugt 2 bis 6 mm. Das bedeutet, dass, beispielsweise im Falle von sphärischen Partikeln, der Durchmesser der Partikel von 0,5 bis 10 mm, insbesondere 0,8 bis 8 mm, besonders bevorzugt 1 bis 7 mm und ganz besonders bevorzugt 2 bis 6 mm beträgt. Das bedeutet, dass, beispielsweise im Falle von sphärischen Partikeln, die Höhe der Partikel vorzugsweise von 0,5 bis 6 mm, insbesondere 0,8 bis 5 mm, besonders bevorzugt 1 bis 4 mm und ganz besonders bevorzugt 1 ,5 bis 3 mm beträgt. The fusible bodies produced in this way can have any desired shape. The shaping takes place in particular in step (d) of the described method. Accordingly, solid, particulate forms are preferred, such as, for example, substantially spherical, figural, flaky, cuboid, cylindrical, conical, spherical cap or lenticular, hemispherical, disc or needle-shaped particles or even figurative forms. For example, the particles may have a gummy-like, figurative design. The maximum extent of the particles in a spatial dimension is preferably from 0.5 to 10 mm, in particular 0.8 to 8 mm, particularly preferably 1 to 7 mm and most preferably 2 to 6 mm. This means that, for example in the case of spherical particles, the diameter of the particles is from 0.5 to 10 mm, in particular 0.8 to 8 mm, more preferably 1 to 7 mm and most preferably 2 to 6 mm. This means that, for example in the case of spherical particles, the height of the particles is preferably from 0.5 to 6 mm, in particular 0.8 to 5 mm, particularly preferably 1 to 4 mm and very particularly preferably 1 to 5 to 3 mm ,
Üblicherweise liegt das Gewicht der einzelnen Partikel zwischen 2 bis 150 mg, vorzugsweise zwischen 5 bis 10 mg. Usually, the weight of the individual particles is between 2 and 150 mg, preferably between 5 and 10 mg.
Wenn hierin die Rede von Trägerpolymer ist, ist das erfindungsgemäße wasserlösliche oder wasserdispergierbare Trägerpolymer gemeint, es sei denn, es ergibt sich aus dem Zusammenhang etwas Anderes. As used herein, when referring to carrier polymer is meant the water-soluble or water-dispersible carrier polymer of the present invention unless the context implies otherwise.
In verschiedenen Ausführungsformen erfolgt das Schmelzen in Schritt (a) der hierin beschriebenen Verfahren durch Erwärmen auf eine Temperatur, die nicht mehr als 20 °C über dem Schmelzpunkt des Trägerpolymers liegt. Das Schmelzen kann mit allen üblichen und den Fachmann bekannten Verfahren und Vorrichtungen erfolgen. Die Schmelze, die das mindestens eine Trägerpolymer enthält, wird beispielsweise kontinuierlich erzeugt, indem das mindestens eine Trägerpolymer und ggf. weitere Bestandteile des Schmelzkörpers kontinuierlich einer entsprechenden Vorrichtung zugeführt werden, in welcher sie erwärmt und die so erzeugte Schmelze weitergefördert, beispielsweise gepumpt wird. In various embodiments, the melting in step (a) of the processes described herein is accomplished by heating to a temperature not more than 20 ° C above the melting point of the carrier polymer. The melting can be carried out using all customary methods and devices known to the person skilled in the art. The melt containing the at least one carrier polymer is produced, for example, continuously by the at least one carrier polymer and optionally further constituents of the melt body being continuously fed to a corresponding device in which it is heated and the melt thus produced is further conveyed, for example pumped.
In einem nächsten Schritt kann dann der mindestens eine Duftstoff kontinuierlich zu der Schmelze zudosiert. Dazu wird der mindestens eine Duftstoff vorzugsweise in flüssiger Form eingesetzt, beispielsweise als Parfümöl, Lösung in einem geeigneten Lösungsmittel oder als Aufschlämmung von Parfümkapseln in einem, typischerweise wasser-haltigen, Lösungsmittel.„Flüssig" wie in diesem Zusammenhang verwendet, bedeutet unter den Einsatzbedingungen flüssig, vorzugsweise bei 20°C flüssig. In a next step, the at least one perfume can then be added continuously to the melt. For this purpose, the at least one perfume is preferably used in liquid form, for example as perfume oil, solution in a suitable solvent or as a slurry of perfume capsules in a typically water-containing solvent. "Liquid" as used in this context means liquid under the conditions of use , preferably liquid at 20 ° C.
Bei der Herstellung kann der Durchfluss optional mittels Durchflussmengenmessung der einzelnen Dosierströme, d.h. der Schmelze, des Duftstoffstroms und ggf. weitere Inhaltsstoffströme gesteuert werden. Hierüber lassen sich beispielsweise auch die Mengenverhältnisse der einzelnen During production, the flow can optionally be measured by measuring the flow rate of the individual metered streams, i. the melt, the perfume stream and possibly other ingredient streams are controlled. This also allows, for example, the proportions of the individual
Bestandteile einstellen. Die Inhaltstoffe neben dem Trägerpolymer(en) und den Duftstoffen können entweder direkt mit dem Trägerpolymer zusammen als Schmelze erzeugt werden, mit den Duftstoffen zusammen oder separat zu der Schmelze zudosiert werden. Bei letzterer Alternative
kann die Zudosierung vor oder nach Zudosierung der Duftstoffe erfolgen. Wie bereits oben beschrieben, können so das mindestens eine Polysaccharid/die mindestens eine Set components. The ingredients besides the carrier polymer (s) and fragrances can either be produced directly with the carrier polymer together as a melt, be dosed with the fragrances together or separately to the melt. In the latter alternative the metered addition can be carried out before or after addition of the fragrances. As already described above, so the at least one polysaccharide / at least one
pyrogene/Fällungskieselsäure sowie optional auch das mindestens eine anorganische Salz gemeinsam oder getrennt voneinander in Schritt (a) oder Schritt (b) oder einem oder mehreren weiteren Schritten zudosiert werden. Es ist auch möglich, eine der beiden vorgenannten pyrogenic / precipitated silica and optionally also the at least one inorganic salt are added together or separately from one another in step (a) or step (b) or one or more further steps. It is also possible to choose one of the two aforementioned
Komponenten in einem Schritt und die andere der beiden vorgenannten Komponenten in einem anderen Schritt hinzu zu dosieren. Add components in one step and the other of the two aforementioned components in another step.
Das Mischen der vereinigten Dosierströme kann dann jeweils direkt nach dem Zudosieren oder stromabwärts nach Zudosierung mehrerer oder aller Inhaltsstoffe mit geeigneten Mischern, wie üblichen statischen oder dynamischen Mischaggregaten erfolgen. The mixing of the combined metering streams can then be carried out in each case directly after metering or downstream after metering in several or all of the ingredients with suitable mixers, such as customary static or dynamic mixing units.
Nach dem Mischen wird die Schmelze, die das Trägerpolymer, die Duftstoffe und das Schichtsilikat sowie ggf. weitere Inhaltsstoffe, wie insbesondere mindestens eine Polysaccharid und/oder die mindestens eine pyrogene oder Fällungskieselsäure, und/oder anorganische Salze, enthält, abgekühlt und optional der Umformung zugeführt, wo die Schmelze erstarrt und ihre endgültige Form erhält. Geeignete Verfahren zur Formgebung sind dem Fachmann bekannt. Übliche Formen wurden bereits oben beschrieben. After mixing, the melt, which contains the carrier polymer, the fragrances and the phyllosilicate and optionally further ingredients, in particular at least one polysaccharide and / or the at least one pyrogenic or precipitated silica, and / or inorganic salts, is cooled and optionally subjected to transformation fed, where the melt solidifies and receives its final shape. Suitable methods for shaping are known to the person skilled in the art. Usual forms have already been described above.
Die Erfindung betrifft auch die Verwendung der hierin beschriebenen festen, partikulären The invention also relates to the use of the solid particulate described herein
Zusammensetzung (Schmelzkörper) als Textilpflegemittel, vorzugsweise Beduftungsmittel und/oder Weichspüler, zum Beduften und/oder Konditionieren von textilen Flächengebilden. Die Schmelzkörper können dabei ein Textilbehandlungsmittel, wie beispielsweise ein Weichspüler oder ein Teil eines solchen Mittels sein. Composition (melting body) as a textile care agent, preferably fragrancing and / or fabric softener, for scenting and / or conditioning textile fabrics. The enamel bodies may be a textile treatment agent, such as, for example, a fabric softener or a part of such an agent.
Ferner betrifft die Erfindung ein Wasch- oder Reinigungsmittel, umfassend die erfindungsgemäße Zusammensetzung. Furthermore, the invention relates to a washing or cleaning agent comprising the composition according to the invention.
Durch das Einbringen der erfindungsgemäßen Zusammensetzung in ein Wasch- oder By introducing the composition of the invention into a washing or
Reinigungsmittel steht dem Verbraucher ein Textil-pflegendes Wasch- oder Reinigungsmittel („2in1 "-Wasch- oder Reinigungsmittel) zur Verfügung und er braucht nicht zwei Mittel zu dosieren sowie keinen separaten Spülgang. Da die erfindungsgemäß hergestellten Zusammensetzungen parfümiert sind, muss nicht auch das Wasch- oder Reinigungsmittel parfümiert werden. Dies führt nicht nur zu geringeren Kosten, sondern ist auch für Verbraucher mit empfindlicher Haut und/oder Allergien vorteilhaft. Detergent is the consumer a textile-care washing or cleaning agent ("2in1" washing or cleaning agent) available and he does not need to dose two agents and no separate rinse Since the compositions according to the invention are perfumed, not washing This not only results in lower costs, but is also beneficial for consumers with sensitive skin and / or allergies.
Die hierin beschriebenen Schmelzkörper-Zusammensetzungen eignen sich insbesondere zum Konditionieren von textilen Flächengebilden und werden dazu zusammen mit einem
herkömmlichen Wasch- oder Reinigungsmittel im (Haupt)Waschgang eines herkömmlichen Wasch- und Reinigungsprozesses mit den textilen Flächengebilden in Kontakt gebracht. The fused-state compositions described herein are particularly suitable for conditioning textile fabrics and are used together with a conventional washing or cleaning agents in the (main) wash of a conventional washing and cleaning process brought into contact with the fabrics.
Ist die erfindungsgemäße Schmelzkörper-Zusammensetzung Teil eines Wasch- oder Is the enamel composition of the invention part of a washing or
Reinigungsmittels, kann ein festes Wasch- oder Reinigungsmittel vorzugsweise mit 1 bis 20 Gew.-%, insbesondere mit 5 bis 15 Gew.-%, der erfindungsgemäßen Zusammensetzung gemischt werden. Detergent, a solid detergent or cleaning agent is preferably mixed with 1 to 20 wt .-%, in particular with 5 to 15 wt .-%, of the composition according to the invention.
Die im Zusammenhang mit den erfindungsgemäßen Zusammensetzungen beschriebenen sind ebenso auf Verfahren zur Herstellung derselben, die diese enthaltenden Wasch- und The ones described in connection with the compositions according to the invention are also based on processes for the preparation thereof, the washing and cleaning compositions containing them
Reinigungsmittel sowie die hierin beschriebenen Verwendungen übertragbar und umgekehrt. Detergent and the uses described herein transferable and vice versa.
Ebenfalls betrifft die vorliegende Erfindung Schmelzkörper, die nach dem erfindungsgemäßen Verfahren hergestellt worden sind.
The present invention also relates to fused bodies which have been produced by the process according to the invention.
Beispiele Examples
Die Verarbeitbarkeit der erfindungsgemäßen festen Zubereitungen zu Pastillen wurde verglichen. Beispiel 1 : Rezeptur von Schmelzkörperformulierungen The processability of the solid preparations according to the invention into pastilles was compared. Example 1: Formulation of Enamel Formulations
Tabelle 1 : Beispielrezepturen (Mengen in Gew.-%) Table 1: Example formulations (amounts in% by weight)
Zur Herstellung wurden die Schichtsilicate unter hoher Scherung (5 min Ultra-Turrax bei 6500 min"1 ) in die Schmelze des PEG bei 80°C eingearbeitet. For preparation, the layered silicates were incorporated under high shear (5 min Ultra-Turrax at 6500 min "1 ) into the melt of the PEG at 80 ° C.
Die Schmelzviskosität wird bestimmt mit einem Rotationsrheometer (TA-Instruments, AR G2) mit PP-Messystem 40 mm bei einer Schubspannung von 3 Pa und bei einer Temperatur von 60°C. The melt viscosity is determined using a rotary rheometer (TA-Instruments, AR G2) with a PP measuring system 40 mm at a shear stress of 3 Pa and at a temperature of 60 ° C.
Man sieht, wie in den erfindungsgemäßen Rezepturen die Schmelzviskosität gegenüber dem Vergleichsbeispiel erhöht ist. Dies führt zu einem höheren Höhe/Durchmesserverhältnis bei der Pastillierung dieser Rezepturen. It can be seen how in the formulations according to the invention the melt viscosity is increased compared to the comparative example. This leads to a higher height / diameter ratio in the pastillation of these formulations.
Aus den Rezepturen wurden Pastillen hergestellt, indem die Schmelzen durch eine Düse mit einem Durchmesser von 2 mm bei einer Temperatur von 60°C aus einer Höhe von 2 cm auf ein auf 25°C temperiertes Stahlblech getropft wurden.
Die resultierenden Pastillen weisen im Mittel folgende Dimensionen auf: Pastilles were prepared from the formulations by dropping the melts through a 2 mm diameter die at a temperature of 60 ° C. from a height of 2 cm onto a steel sheet tempered to 25 ° C. The resulting pastilles have on average the following dimensions:
h/d = Mittelwert des Verhältnisses Höhe/ Durchmesser h / d = average of the ratio height / diameter
Man erkennt, dass die erfindungsgemäßen Rezepturen ein günstigeres Durchmesser/Höhe- Verhältnis aufweisen. E1 und E2 liefern fast halbkugelförmige Pastillen. Damit unterliegen diese einem geringeren Kantenbruch und wirken insgesamt ästhetischer. It can be seen that the formulations according to the invention have a more favorable diameter / height ratio. E1 and E2 provide almost hemispherical lozenges. Thus, they are subject to a lower edge breakage and act more aesthetically.
Ebenfalls offenbart werden die folgenden Rezepturen: Also disclosed are the following formulations:
Inhaltsstoffe ingredients
E3 E4 E3 E4
[Gew.-%] [Wt .-%]
PEG 12000 72,70 72,70 PEG 12,000 72,70 72,70
Bentonit (Bentone Bentonite (Bentone
20,20 20.20
LT) LT)
Laponit (Laponite Laponite (Laponite
20,20 20.20
RD) RD)
Parfüm 3,00 3,00 Perfume 3.00 3.00
Parfümkapseln perfume capsules
4,00 4,00 4.00 4.00
(Slurry) (Slurry)
Farbstoff 0, 10 0, 10 Dye 0, 10 0, 10
Summe 100,00 100,00
Total 100.00 100.00
Claims
1. Feste, partikuläre Zusammensetzung umfassend mindestens ein wasserlösliches oder wasserdispergierbares Trägerpolymer mit einem Schmelzpunkt >30°C bis 250°C, vorzugsweise >40°C bis 150°C, vorzugsweise ausgewählt aus Polyalkylenglykolen, besonders bevorzugt Polyethylenglykol, und mindestens einen Duftstoff, dadurch gekennzeichnet, dass die Zusammensetzung von 1 , 1 bis 40,0 Gew.-% Schichtsilikat umfasst. 1. Solid, particulate composition comprising at least one water-soluble or water-dispersible carrier polymer having a melting point> 30 ° C to 250 ° C, preferably> 40 ° C to 150 ° C, preferably selected from polyalkylene glycols, more preferably polyethylene glycol, and at least one perfume, characterized characterized in that the composition comprises from 1, 1 to 40.0 wt .-% phyllosilicate.
2. Die Zusammensetzung gemäß Anspruch 1 , dadurch gekennzeichnet, dass das 2. The composition according to claim 1, characterized in that the
Schichtsilikat phyllosilicate
a) Tonmaterial umfasst, insbesondere ausgewählt aus der Gruppe bestehend aus Smektite, Montmorillonite, Bentonite, Kaolinite, Saponit, Hectorit und/oder Mischungen davon, a) comprises clay material, in particular selected from the group consisting of smectites, montmorillonites, bentonites, kaolinites, saponite, hectorite and / or mixtures thereof,
b) natives Schichtsilikat und/oder organomodifiziertes Schichtsilikat ist, und/oder c) in Mengen von 1 ,5 bis 38 Gew.-%, bevorzugt 5 bis 35 Gew.-%besonders bevorzugt von 15 bis 30 Gew.-%, insbesondere 18 bis 22 Gew.-% jeweils bezogen auf die gesamte feste Zusammensetzung vorliegt. b) native phyllosilicate and / or organo-modified phyllosilicate, and / or c) in amounts of from 1.5 to 38% by weight, preferably from 5 to 35% by weight, more preferably from 15 to 30% by weight, in particular 18 to 22 wt .-% in each case based on the total solid composition is present.
3. Die Zusammensetzung gemäß einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, dass das Schichtsilikat ausgewählt wird aus der Gruppe bestehend aus Magnesium- oder Natrium-Magnesium- Schichtsilikate. 3. The composition according to any one of claims 1 or 2, characterized in that the sheet silicate is selected from the group consisting of magnesium or sodium magnesium phyllosilicates.
4. Die Zusammensetzung gemäß einem der voranstehenden Ansprüche, dadurch 4. The composition according to any one of the preceding claims, characterized
gekennzeichnet, dass die Zusammensetzung ferner ein anorganisches Salzen enthält, wobei das mindestens eine anorganische Salz vorzugsweise ausgewählt ist aus der Gruppe bestehend aus Alkali- oder Erdalkalimetallsalzen, insbesondere aus Carbonaten, Sulfaten, Halogeniden oder Phosphaten, besonders bevorzugt aus Natriumsulfat, Natriumcarbonat, Natriumhydrogencarbonat, Natriumdiphosphat und characterized in that the composition further contains an inorganic salt, wherein the at least one inorganic salt is preferably selected from the group consisting of alkali or alkaline earth metal salts, especially from carbonates, sulfates, halides or phosphates, more preferably from sodium sulfate, sodium carbonate, sodium bicarbonate, sodium diphosphate and
Natriumtripolyphosphat. Sodium tripolyphosphate.
5. Die Zusammensetzung gemäß einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass a) die Zusammensetzung kein Polysaccharid, keine pyrogene Kieselsäure und/oder keine Fällungskieselsäure umfasst. 5. The composition according to any one of claims 1 to 4, characterized in that a) the composition comprises no polysaccharide, no fumed silica and / or no precipitated silica.
6. Die Zusammensetzung gemäß einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass die Zusammensetzung mindestens ein Polysaccharid, mindestens eine pyrogene Kieselsäure und/oder mindestens eine Fällungskieselsäure umfasst, wobei vorzugsweise das Polysaccharid ausgewählt wird aus der Gruppe bestehend aus Glycogen, Stärke, Callose, Cellulose, Tunicin, Pektin, Algin, Inulin, Chitin, Chitosan, Heparin, Carrageenan,
Agar, Gummiarabicum, Traganth, Johannisbrotkernmehl, Karaya-Gummi, Ghatti-Gummi, Guar-Gummi, Tara-Gummi, Gellan, Xanthan, Dextran, Saccharose, Nigeran und 6. The composition according to any one of claims 1 to 4, characterized in that the composition comprises at least one polysaccharide, at least one fumed silica and / or at least one precipitated silica, wherein preferably the polysaccharide is selected from the group consisting of glycogen, starch, callose , Cellulose, tunicin, pectin, algin, inulin, chitin, chitosan, heparin, carrageenan, Agar, gum arabic, tragacanth, locust bean gum, karaya gum, ghatti gum, guar gum, tare gum, gellan, xanthan, dextran, sucrose, nigeran and
Pentosanen wie Xylan und Araban, Derivaten oder Mischungen davon. Pentosans such as xylan and araban, derivatives or mixtures thereof.
7. Die Zusammensetzung nach einem der voranstehenden Ansprüche, dadurch 7. The composition according to any one of the preceding claims, characterized
gekennzeichnet, dass das wasserlösliche oder wasserdispergierbare Trägerpolymer in that the water-soluble or water-dispersible carrier polymer
(A) einen Schmelzpunkt von 48°C bis 120°C, vorzugsweise von 48°C bis 80°C aufweist; und/oder (A) has a melting point of 48 ° C to 120 ° C, preferably from 48 ° C to 80 ° C; and or
(B) in einer Menge von 30 bis 95 Gew.-% bezogen auf das Gesamtgewicht der (B) in an amount of 30 to 95 wt .-% based on the total weight of
Zusammensetzung, in dieser enthalten ist; und/oder Composition included in this; and or
(C) ein Polyethylenglykol mit einer mittleren molaren Masse von >1500 g/mol, (C) a polyethylene glycol having an average molar mass of> 1500 g / mol,
vorzugsweise zwischen 3.000 und 15.000, noch bevorzugter mit einer mittleren molaren Masse zwischen 4.000 und 13.000 und insbesondere bevorzugt mit einer mittleren molaren Masse zwischen 6.000 und 8.000 oder 9.000 und 13.000 und einem preferably between 3,000 and 15,000, more preferably with an average molar mass between 4,000 and 13,000, and most preferably with an average molar mass between 6,000 and 8,000 or 9,000 and 13,000 and one
Schmelzpunkt im Bereich von 45 bis 70°C, vorzugsweise 50 bis 65°C ist. Melting point in the range of 45 to 70 ° C, preferably 50 to 65 ° C.
8. Die Zusammensetzung nach einem der voranstehenden Ansprüche, dadurch 8. The composition according to any one of the preceding claims, characterized
gekennzeichnet, dass der mindestens eine Duftstoff characterized in that the at least one perfume
(A) in einer Menge von 0, 1 bis 20 Gew.-% in der Zusammensetzung enthalten ist; und/oder (A) is contained in an amount of 0.1 to 20% by weight in the composition; and or
(B) in Form von Duftstoffkapseln und/oder Parfümölen eingesetzt wird. (B) is used in the form of perfume capsules and / or perfume oils.
9. Die Zusammensetzung nach einem der voranstehenden Ansprüche, dadurch 9. The composition according to any one of the preceding claims, characterized
gekennzeichnet, dass die Zusammensetzung als das mindestens eine wasserlösliche oder wasserdispergierbare Trägerpolymer ein Polyalkylenglykol, besonders bevorzugt aus den Polyethylenglykolen mit einer mittleren molaren Masse im Bereich von 10.000 bis 15.000, aufweist und weiterhin mindestens einen Wirkstoff enthält ausgewählt aus der Gruppe der Polyethlyenglykole mit einer mittleren molaren Masse größer als 16.000, der in that the composition comprises, as the at least one water-soluble or water-dispersible carrier polymer, a polyalkylene glycol, particularly preferably from the polyethylene glycols having an average molar mass in the range from 10,000 to 15,000, and further comprises at least one active ingredient selected from the group consisting of polyethylene glycols having a middle molar mass Mass greater than 16,000, the
Fettalkoholalkoxylate mit mindestens 10 C-Atomen in der Fettkette und mindestens 10 Alkoxyeinheiten, der alkoxylierten Castoröle mit mindestens 5 Alkoxyeinheiten und den Alkoxyblockcopolymeren. Fatty alcohol alkoxylates having at least 10 C atoms in the fatty chain and at least 10 alkoxy units, the alkoxylated castor oils having at least 5 alkoxy units and the alkoxy block copolymers.
10. Die Zusammensetzung nach einem der voranstehenden Ansprüche, dadurch 10. The composition according to any one of the preceding claims, characterized
gekennzeichnet, dass die Partikel im Wesentlichen sphärische, figürlich, schuppen-, quader-, zylinder-, kegel-, kugelkalotten- bzw. linsen-, hemisphären-, scheibchen- oder nadeiförmige Partikel sind oder figürliche Formen haben, wobei die maximale Ausdehnung in einer räumlichen Dimension vorzugsweise im Bereich von 0,5 bis 10 mm, insbesondere 0,8 bis 8 mm, besonders bevorzugt 1 bis 7 mm und ganz besonders bevorzugt 2 bis 6 mm beträgt.
in that the particles are essentially spherical, figurative, scale, cuboid, cylindrical, conical, spherical cap or lenticular, hemispherical, disc or needle-shaped particles or have figural shapes, wherein the maximum extent in one spatial dimension preferably in the range of 0.5 to 10 mm, in particular 0.8 to 8 mm, more preferably 1 to 7 mm and most preferably 2 to 6 mm.
1 1. Zusammensetzung gemäß einem der Ansprüche 1 bis 10, dadurch gekennzeichnet, dass die Zusammensetzung ferner mindestens eine Textil-pflegende Verbindung enthält, wobei diese vorzugsweise ausgewählt wird aus Textil-weichmachenden Verbindungen, A composition according to any one of claims 1 to 10, characterized in that the composition further contains at least one textile-care compound, which is preferably selected from textile-softening compounds,
Silikonölen, Antiredepositionsmitteln, optischen Aufhellern, Vergrauungsinhibitoren, Einlaufverhinderern, Knitterschutzmitteln, Farbübertragungsinhibitoren, antimikrobiellen Wirkstoffen, Germiziden, Fungiziden, Antioxidantien, Antistatika, Bügelhilfsmitteln, Phobier- und Imprägniermitteln, Quell- und Schiebefestmitteln, UV-Absorber sowie Mischungen daraus ausgewählt ist. Silicone oils, anti-redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-wrinkling agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing auxiliaries, repellents and impregnating agents, swelling and anti-slip agents, UV absorbers and mixtures thereof.
12. Verwendung der festen Zusammensetzung gemäß einem der Ansprüche 1 bis 1 1 als 12. Use of the solid composition according to any one of claims 1 to 1 1 as
Textilpflegemittel, vorzugsweise Beduftungsmittel und/oder Weichspüler, zum Beduften und/oder Konditionieren von textilen Flächengebilden. Fabric care products, preferably fragrancing and / or softener, for scenting and / or conditioning textile fabrics.
13. Wasch- oder Reinigungsmittel, umfassend eine feste Zusammensetzung gemäß einem der Ansprüche 1 bis 1 1. 13. A washing or cleaning composition comprising a solid composition according to any one of claims 1 to 1 1st
14. Ein Verfahren zur Herstellung einer festen, partikuläre Zusammensetzung gemäß einem der Ansprüche 1 bis 1 1 , dadurch gekennzeichnet, dass es die die folgenden Schritte umfasst: 14. A process for producing a solid, particulate composition according to any one of claims 1 to 1 1, characterized in that it comprises the following steps:
a) kontinuierliches Fördern einer Schmelze umfassend das mindestens eine a) continuously conveying a melt comprising the at least one
wasserlösliche oder wasserdispergierbare Trägerpolymer sowie das Schichtsilikat; b) kontinuierliches Zudosieren des mindestens einen Duftstoffs zu der Schmelze water-soluble or water-dispersible carrier polymer and the layered silicate; b) continuous metering of the at least one perfume to the melt
umfassend das mindestens eine wasserlösliche oder wasserdispergierbare comprising the at least one water-soluble or water-dispersible
Trägerpolymer; Carrier polymer;
c) Mischen der Schmelze umfassend das mindestens eine wasserlösliche oder c) mixing the melt comprising the at least one water-soluble or
wasserdispergierbare Trägerpolymer und des mindestens einen Duftstoffs; und d) Abkühlen und optional Umformen der Mischung um parfümhaltige Schmelzkörper zu erhalten. water-dispersible carrier polymer and the at least one perfume; and d) cooling and optionally forming the mixture to obtain perfume-containing fusible bodies.
15. Feste, partikuläre Zusammensetzung hergestellt nach dem Verfahren gemäß Anspruch 14.
15. Solid, particulate composition prepared by the process according to claim 14.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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EP17776991.6A EP3516031A1 (en) | 2016-09-26 | 2017-09-22 | Solid particulate compositions comprising water-soluble carrier polymer and perfume |
Applications Claiming Priority (22)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016218483.0 | 2016-09-26 | ||
DE102016218480 | 2016-09-26 | ||
DE102016218483 | 2016-09-26 | ||
DE102016218480.6 | 2016-09-26 | ||
DE102016219296.5A DE102016219296A1 (en) | 2016-09-26 | 2016-10-05 | Perfume-containing enamel body |
DE102016219296.5 | 2016-10-05 | ||
DE102016219294.9A DE102016219294A1 (en) | 2016-09-26 | 2016-10-05 | Process for the preparation of bitter-bodied enamel bodies |
DE102016219295.7 | 2016-10-05 | ||
DE102016219294.9 | 2016-10-05 | ||
DE102016219293.0 | 2016-10-05 | ||
DE102016219293.0A DE102016219293A1 (en) | 2016-09-26 | 2016-10-05 | Processing-friendly mass for the production of enamel bodies |
DE102016219295.7A DE102016219295A1 (en) | 2016-09-26 | 2016-10-05 | Continuous process for the preparation of perfume-containing fused bodies |
DE102016219570.0 | 2016-10-07 | ||
DE102016219570.0A DE102016219570A1 (en) | 2016-10-07 | 2016-10-07 | Processing-friendly mass for the production of enamel bodies |
DE102017203494.7 | 2017-03-03 | ||
DE102017203496.3 | 2017-03-03 | ||
DE102017203501.3 | 2017-03-03 | ||
DE102017203496 | 2017-03-03 | ||
DE102017203494 | 2017-03-03 | ||
DE102017203500.5 | 2017-03-03 | ||
DE102017203501 | 2017-03-03 | ||
DE102017203500 | 2017-03-03 |
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WO2018055111A1 true WO2018055111A1 (en) | 2018-03-29 |
Family
ID=61690197
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Application Number | Title | Priority Date | Filing Date |
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PCT/EP2017/074099 WO2018055111A1 (en) | 2016-09-26 | 2017-09-22 | Solid particulate compositions comprising water-soluble carrier polymer and perfume |
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EP (1) | EP3516031A1 (en) |
WO (1) | WO2018055111A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3722399A1 (en) * | 2019-04-12 | 2020-10-14 | Henkel AG & Co. KGaA | Solid composition containing perfume |
EP3722405A1 (en) * | 2019-04-12 | 2020-10-14 | Henkel AG & Co. KGaA | Fixed composition containing perfume |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3722399A1 (en) * | 2019-04-12 | 2020-10-14 | Henkel AG & Co. KGaA | Solid composition containing perfume |
EP3722405A1 (en) * | 2019-04-12 | 2020-10-14 | Henkel AG & Co. KGaA | Fixed composition containing perfume |
US11549085B2 (en) | 2019-04-12 | 2023-01-10 | Henkel Ag & Co. Kgaa | Solid perfume-containing composition |
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