WO2018054396A1 - Composition bactéricide - Google Patents

Composition bactéricide Download PDF

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Publication number
WO2018054396A1
WO2018054396A1 PCT/CN2017/112390 CN2017112390W WO2018054396A1 WO 2018054396 A1 WO2018054396 A1 WO 2018054396A1 CN 2017112390 W CN2017112390 W CN 2017112390W WO 2018054396 A1 WO2018054396 A1 WO 2018054396A1
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Prior art keywords
zinc
mbit
bbit
bit
composition
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PCT/CN2017/112390
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English (en)
Chinese (zh)
Inventor
仲汉根
季自华
季红进
花伟
韦建峰
季定根
Original Assignee
江苏辉丰生物农业股份有限公司
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Publication of WO2018054396A1 publication Critical patent/WO2018054396A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A01N47/14—Di-thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2

Definitions

  • the invention belongs to the field of agricultural plant protection, in particular to a bactericidal composition with improved properties, in particular to a bactericidal composition comprising a benzisothiazolinone compound and one of dexamethasone or propyl zinc. .
  • Benzoisothiazolinones are a new type of broad-spectrum fungicide mainly used for the prevention and treatment of various bacterial and fungal diseases such as cereal crops, vegetables and fruits.
  • the mechanism of bactericidal action mainly includes destroying the nuclear structure of the pathogen, causing it to lose the heart part and failing to death and interfering with the metabolism of the pathogenic cells, causing its physiological disorder and ultimately leading to death. It can effectively protect plants from pathogens in the early stage of disease occurrence. Increasing the dosage after disease occurrence can obviously control the spread of pathogens, thus achieving the dual functions of protection and eradication.
  • Meiram is an excellent protective fungicide and a low-toxic pesticide. Because of its wide range of sterilization and resistance to resistance, the control effect is obviously superior to other similar fungicides, so the international use has always been a large tonnage product. It is currently a substitute for other protective fungicides. Most of the domestic compound fungicides are prepared by processing mancozeb, but manganese-zinc preparations cause poisoning of trace elements in crops. Black spot disease, apple spotted leaf disease, melon vegetable disease, downy mildew, field crop rust and other effects are remarkable, and no other fungicide can effectively control the occurrence of disease, and the quality is stable and reliable.
  • Propineb is a broad-spectrum, fast-acting protective fungicide. Suitable for crops such as tomatoes, cabbage, cucumbers, mangoes and flowers. Control cabbage downy mildew, cucumber downy mildew, tomato early and late blight, mango anthracnose. Propionate zinc is a fast-acting, long-lasting, broad-spectrum protective fungicide with good protection against downy mildew of vegetables, tobacco, hops and other crops, as well as early and late blight of tomato and potato, and Powdery mildew, rust and diseases caused by Botrytis are also inhibited. Safe for crops at recommended doses.
  • the object of the present invention is to solve the resistance of the bactericide in practical application and the problem of soil residue, and to screen out the fungicides with different sterilization principles to obtain a new fungicide composition, so as to improve the control effect of the bactericide and delay the resistance.
  • Sexual production reducing the amount of application, reducing the cost of prevention.
  • Another object of the present invention is to provide an application comprising a combination of two active ingredients A and B in the control of crop diseases in the agricultural sector.
  • the object of the invention can be achieved by the following measures:
  • a synergistic fungicide composition comprising two active components A and B, wherein the active component A is a structural compound having the formula (I), and the active component B is a derivative of the group One of the zinc.
  • R is selected from H or a C 1-10 alkyl group.
  • the C 1-8 alkyl group in the present invention means a linear or branched alkyl group having 1 to 8 carbon atoms, and includes a C 1 alkyl group such as a methyl group, a C 2 alkyl group such as an ethyl group, C 3 alkyl (such as n-propyl, isopropyl), C 4 alkyl (such as n-butyl, isobutyl, tert-butyl, sec-butyl), C 5 alkyl (such as n-pentyl, etc.), C 6 alkyl, C 7 alkyl, C 8 alkyl. It includes, but is not limited to, C 1-6 alkyl, C 1-5 alkyl, C 1-4 alkyl, and the like.
  • R is selected from H or a C 1 -C 4 alkyl group.
  • R is selected from the group consisting of H, -CH 3 or -C 4 H 9 .
  • A is 1,2-benzisothiazolin-3-one (abbreviated as BIT in the specification).
  • R is -CH 3
  • A is 2-methyl-1,2-benzisothiazolin-3-one (abbreviated as MBIT in the specification).
  • the inventors have found through experiments that the composition of the present invention is effective for controlling bacterial or fungal diseases of crops, and more importantly, the application amount is reduced and the use cost is lowered.
  • the compounds containing component A and component B have different structural types and different mechanisms of action. The combination of the two can expand the bactericidal spectrum, and can delay the generation and development of pathogen resistance to a certain extent, and component A and group There is no cross-resistance between points B.
  • the weight ratio between the two components in the bactericidal composition of the present invention is 1:4 to 175, so that the synergistic effect between the two components is more remarkable, and the weight of the component A and the component B are two.
  • the weight ratio between the points can be further optimized to 1:10 to 150.
  • the weight ratio between the two components of A and B can be arbitrarily adjusted within the range of the following ratios: 1:4, 1:5, 1:6, 1:7, 1:8 , 1:9, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, 1:20, 1 : 21, 1:22, 1:23, 1:24, 1:25, 1:26, 1:27, 1:28, 1:29, 1:30, 1:31, 1:32, 1:33 , 1:34, 1:35, 1:36, 1: 37, 1:38, 1:39, 1:40, 1:41, 1:42, 1:43, 1:44, 1:45, 1:46, 1:47, 1:48, 1:49, 1:50, 1:51, 1:52, 1:53, 1:54, 1:55, 1:56, 1:57, 1:58, 1:59, 1:60, 1:61, 1: 62, 1:63, 1:64, 1:65, 1:66, 1
  • composition of the present invention can be made into a pesticide-acceptable dosage form from the active ingredient and agrochemical adjuvant or adjuvant. Further, the composition comprises 10 to 90% by weight of the active ingredient and 90 to 10% by weight of the pesticide adjuvant to form a pesticide-acceptable dosage form.
  • the present invention provides the use of a bactericidal composition comprising component A and component B for controlling crop diseases in the agricultural sector, in particular for controlling fungal or bacterial diseases of certain crops.
  • composition may specifically comprise an agrochemical adjuvant or an auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant or a fertilizer.
  • auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant or a fertilizer.
  • auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant or a fertilizer.
  • auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant or a fertilizer.
  • Common auxiliaries can be mixed during the application.
  • auxiliaries or auxiliaries may be solid or liquid, they are usually materials commonly used in the processing of dosage forms, such as natural or regenerated minerals, solvents, dispersants, wetting agents, adhesives, thickeners, binders. .
  • the method of application of the compositions of the invention comprises the use of the compositions of the invention for aerial parts of plants, in particular leaves or foliage. You can choose to soak or apply to the surface of the control object.
  • the frequency of administration and the amount administered will depend on the biological and climatic conditions of the pathogen.
  • the plant growth site such as rice fields, may be wetted with a liquid formulation of the composition, or the composition may be applied to the soil in solid form, such as in the form of granules (soil application), the composition may be passed from the soil to the plant through the roots of the plant. In vivo (systemic action).
  • composition of the present invention can be prepared into various pesticide-acceptable dosage forms including, but not limited to, emulsifiable concentrates, suspending agents, wettable powders, water-dispersible granules, powders, granules, aqueous preparations, aqueous emulsions, microemulsions, poison baits.
  • the dosage form of the invention employs a wettable powder, a suspending agent, a water-dispersible granule, an aqueous emulsion or a microemulsion.
  • the compositions may be applied by spraying, misting, dusting, spreading or pouring, and the like.
  • composition of the present invention can be prepared into various dosage forms by a known method, and the active ingredient and the auxiliary agent, such as a solvent, a solid carrier, and, if necessary, can be uniformly mixed and ground together with the surfactant to prepare a desired preparation. Dosage form.
  • the above solvent may be selected from aromatic hydrocarbons, preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • aromatic hydrocarbons preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • Alkenes or paraffins, alcohols and glycols and their ethers and esters such as ethanol, ethylene glycol, ethylene glycol monomethyl
  • ketones such as cyclohexanone
  • highly polar solvents such as N-methyl-2 Pyrrolidone, dimethyl sulfoxide or dimethylformamide
  • vegetable or vegetable oils such as soybean oil.
  • the above solid carriers are typically natural mineral fillers such as talc, kaolin, montmorillonite or activated clay.
  • a highly dispersible silicic acid or a highly dispersible adsorbent polymer carrier such as a particulate adsorbent carrier or a non-adsorbing carrier, and a suitable particulate adsorbent carrier is porous, such as pumice, bentonite or Bentonite; a suitable non-adsorbing carrier such as calcite or sand.
  • a large amount of pre-granulated materials of inorganic or organic nature can be used as a carrier, in particular dolomite.
  • Suitable surfactants are lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, alkaline earth metal or amine salts, alkylarylsulfonates, alkyl groups Sulfates, alkyl sulfonates, fatty alcohol sulphates, fatty acids and sulfated fatty alcohol glycol ethers, as well as condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, naphthalene or naphthalene sulfonic acid with phenol and formaldehyde Condensate, polyoxyethylene octyl phenyl ether, ethoxylated isooctyl phenol, octyl phenol, nonyl phenol, alkyl aryl polyglycol ether, tributyl benzene poly
  • the active component A may be first dissolved in a basic substance to form a benzisothiazolin metal salt.
  • Suitable basic substances include: alkali metal carbonates, alkali metal hydroxides (such as hydroxides). Sodium, potassium hydroxide), alkali metal alkoxy carbonate, alkali metal alkoxide or magnesium methoxide.
  • the two active ingredients in the compositions of the present invention exhibit synergistic effects, the activity of which is more pronounced than the expected sum of activity using a single compound, and the individual activity of a single compound.
  • the synergistic effect is manifested by allowing for a reduced application rate, a broader fungicidal control profile, quicker effect, longer lasting control effect, better control of plant harmful fungi by only one or a few applications, and broadening of possible application. Intervals. These properties are particularly desirable in the practice of plant fungi control.
  • the bactericidal composition of the invention can be applied to the agricultural field for controlling crop diseases, and the specific diseases targeted include, but are not limited to, peach perforated bacterial perforation, tobacco wildfire, rice sheath blight, cucumber bacterial angular spot, cucumber Downy mildew, rice bacterial stripe disease, rice bacterial base rot, corn bacterial wilt, watermelon wilt, grape downy mildew, tomato bacterial wilt, eggplant bacterial wilt, rice blast, rice bacterium Stripe disease, pepper anthracnose, litchi ulcer disease, grape anthracnose, tobacco bacterial wilt, cucumber anthracnose, celery spot blotch, lotus root blight, strawberry powdery mildew, lettuce downy mildew, celery gray mold, Apricot bacterial perforation, peach tree canker, onion downy mildew, cotton bacterial angular spot, cucumber bacterial Leaf blight and so on.
  • the bactericidal composition of the present invention can be used in the agricultural field to control diseases such as downy mildew, late blight, anthracnose or ring rot.
  • the other characteristics exhibited by the bactericidal composition of the present invention are mainly as follows: 1.
  • the compounding of the composition of the present invention has obvious synergistic effect; 2. Since the chemical composition of the two single agents of the present composition is greatly different, the effect The mechanism is completely different, there is no cross-resistance, and the problem of resistance caused by the separate use of the two single agents can be delayed; 3.
  • the composition of the present invention is safe and safe for crops. It has been proved by experiments that the bactericidal composition of the invention has stable chemical properties, remarkable synergistic effect, and exhibits obvious synergistic effect and complementary effect on the control object.
  • the active ingredient active group A and the active component B, and the auxiliary agent and the filler are uniformly mixed according to the formula, and are pulverized into a wettable powder by a jet stream, and then added with a certain amount of water to be mixed and extruded, granulated, and dried and sieved.
  • a water dispersible granule product A water dispersible granule product.
  • Active component A BIT
  • Example 1 44% BIT ⁇ Dyson Water Dispersible Granules (1:10)
  • BIT 4% Daisenlian 40%, sodium alkylbenzene sulfonate 5%, magnesium silicate 6%, ammonium sulfate 5%, lignin naphthalene sulfonate 6%, attapulgite to 100%.
  • Example 2 51% BIT ⁇ Dyson Water Dispersible Granules (1:50)
  • Example 3 25.2% BIT ⁇ Dyson Water Dispersible Granules (1:125)
  • Active component A (MBIT) and Daisenlian to prepare water-dispersible granules
  • Active component A BBIT
  • Example 8 51% BBIT ⁇ Dyson Water Dispersible Granules
  • Example 10 44% BIT ⁇ Binson zinc water dispersible granules
  • Example 11 51% BIT ⁇ Binson zinc water dispersible granules
  • Example 12 25.2% BIT ⁇ Binson zinc water dispersible granules
  • Example 13 44% MBIT ⁇ Binson zinc water dispersible granules
  • Example 14 51% MBIT ⁇ Binson zinc water dispersible granules
  • Example 15 25.2% MBIT ⁇ Binson zinc water dispersible granules
  • Example 17 51% BBIT ⁇ Binson Zinc Water Dispersible Granules
  • Example 18 25.2% BBIT ⁇ Binson zinc water dispersible granules
  • the active ingredient active group A and the active component B, and the components such as a dispersing agent, a wetting agent, a thickener and water are uniformly mixed according to the formula, and after being sanded and/or sheared at a high speed, a semi-finished product is obtained. After the analysis, the water is mixed and evenly filtered to obtain the finished product.
  • Active component A (BIT) and Daisenlian to prepare suspension agent
  • Example 20 50.33% BIT ⁇ Dyson Suspension Suspension (1:150)
  • Example 21 20% BIT ⁇ Dyson Suspension Suspension (1:4)
  • BIT 4% Daisenlian 16%, fatty acid amide N-methyl taurine sodium salt 5%, xanthan gum 4%, ethylene glycol 6%, glacial acetic acid 2%, silicone oil 0.05%, water to 100% .
  • Active component A (MBIT) and Daisenlian preparation of suspending agent
  • the MBIT was 0.33%, the dexamethasone was 50%, and the remaining components were prepared in accordance with the method of Example 20.
  • Active component A BBIT
  • Example 28 26% BIT ⁇ propyl zinc suspension
  • Example 29 50.33% BIT ⁇ propyl zinc suspension
  • Example 30 20% BIT ⁇ propyl zinc suspension
  • Active component A (MBIT) and propionate zinc preparation suspension
  • Example 36 20% BBIT ⁇ propyl zinc suspension
  • the active ingredient A and the B active ingredient are sufficiently mixed with various auxiliary agents and fillers, and are pulverized by an ultrafine pulverizer to obtain a wettable powder.
  • Active component A BIT
  • Example 37 50.5% BIT ⁇ Desensen WP (1:100)
  • BIT 0.5% Daisenlian 50%, sodium dodecylbenzenesulfonate 5%, alkylnaphthalenesulfonate formaldehyde condensate 6%, magnesium silicate aluminum 3%, light calcium carbonate supplement to 100%.
  • Example 39 35.2% BIT ⁇ Desensen WP (1:175)
  • Example 40 50.5% MBIT ⁇ Desensen wettable powder
  • Example 41 76% MBIT ⁇ Desensen wettable powder
  • Example 42 35.2% MBIT ⁇ Desensen wettable powder
  • MBIT was 0.2%
  • Daisen was 35%
  • the remaining components were prepared in accordance with the procedure of Example 39.
  • Active component A BBIT
  • Example 43 50.5% BBIT ⁇ Desensen wettable powder
  • Example 44 76% BBIT ⁇ Desensen wettable powder
  • Example 45 35.2% BBIT ⁇ Desensen wettable powder
  • Active component A BIT
  • propionate zinc to prepare wettable powder
  • Example 46 50.5% BIT ⁇ Binson zinc wettable powder
  • Example 47 76% BIT ⁇ Binson zinc wettable powder
  • Example 48 35.2% BIT ⁇ Binson zinc wettable powder
  • Active component A (MBIT) and propionate zinc to prepare wettable powder
  • Example 49 50.5% MBIT ⁇ Binson zinc wettable powder
  • Example 50 76% MBIT ⁇ Binson zinc wettable powder
  • Example 51 35.2% MBIT ⁇ Binson Zinc Wettable Powder
  • Active component A BBIT
  • propionate zinc to prepare wettable powder
  • Example 52 50.5% BBIT ⁇ Binson zinc wettable powder
  • Example 53 76% BBIT ⁇ Binson zinc wettable powder
  • Example 54 35.2% BBIT ⁇ Binson zinc wettable powder
  • the control effect is converted into the probability value (y), the liquid height ( ⁇ g/ml) is converted into a logarithmic value (x), the virulence equation is calculated by the least squares method, and the neutral concentration EC50 is suppressed, and the virulence of the drug is calculated according to the method of Sun Yunpei. Exponential Co-toxicity Factor (CTC).
  • CTC Exponential Co-toxicity Factor
  • Measured virulence index (ATI) (standard drug EC50 / test drug EC50) * 100
  • Theoretical virulence index (TTI) A virulence index * Percentage of A in the mixture + B virulence index * Percentage of B in the mixture
  • CTC Co-toxicity coefficient [mixture measured virulence index (ATI) / mixed theory virulence index (TTI)] * 100
  • CTC ⁇ 80 the composition showed antagonism, 80 ⁇ CTC ⁇ 120, the composition showed an additive effect, CTC ⁇ 120, and the composition showed synergistic effect.
  • Test method In the early stage of the disease, the first spray was immediately performed, and after 7 days, the second application was carried out, each treatment of 4 cells, 20 square meters per cell. The incidence of the disease was investigated before the drug and 11 days after the second drug. Each plot was randomly sampled at 5 points, and 5 crops were investigated at each point. The percentage of the lesion area per leaf on the whole plant was counted and graded. Disease index and control effect.
  • Grade 1 less than 5 leaf lesions, less than 1 cm in length;
  • Grade 3 6-10 leaf lesions, some lesions are longer than 1 cm;
  • Grade 5 11-25 leaf lesions, some lesions are connected into pieces, and the lesion area accounts for 10-25% of the leaf area;
  • Grade 7 more than 26 leaf lesions, the lesions are connected into pieces, and the lesion area accounts for 26-50% of the leaf area;
  • Grade 9 The lesions are connected into pieces, and the area of the lesions accounts for more than 50% of the leaf area or the whole leaves are dead.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Cette invention concerne une composition bactéricide, comprenant deux principes efficaces, A et B, le principe actif A étant un composé répondant à la structure de formule (I), le principe actif B étant le métiram ou propineb, le rapport en poids des deux principes étant de 1:4-175. Un procédé de préparation de la composition et son utilisation sont en outre décrits. Les résultats des essais montrent que la composition bactéricide selon la présente invention se caractérise par une synergie significative et, plus important, par des quantités d'application réduites et des coûts d'utilisation réduits. La composition bactéricide permet de prévenir et de traiter efficacement certaines maladies fongiques spécifiques des cultures. La combinaison de bactéricides ayant des mécanismes et des modes d'action différents permet de réduire efficacement les quantités d'application des agents individuels, d'élargir le spectre bactéricide, de retarder l'apparition des champignons et la résistance fongique, et d'améliorer l'effet de prévention et de traitement.
PCT/CN2017/112390 2016-09-23 2017-11-22 Composition bactéricide WO2018054396A1 (fr)

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CN201610848159.8A CN106489965A (zh) 2016-09-23 2016-09-23 一种杀菌剂组合物

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019241058A1 (fr) * 2018-06-10 2019-12-19 Troy Corporation Conservateurs sans formaldéhyde pour produits hautement sensibles

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106489965A (zh) * 2016-09-23 2017-03-15 江苏辉丰农化股份有限公司 一种杀菌剂组合物

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103704234A (zh) * 2014-01-07 2014-04-09 中国农业科学院植物保护研究所 一种防治农业细菌性病害的组合物
CN106259387A (zh) * 2016-04-29 2017-01-04 江苏辉丰农化股份有限公司 一种杀菌剂组合物
CN106489965A (zh) * 2016-09-23 2017-03-15 江苏辉丰农化股份有限公司 一种杀菌剂组合物

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2707819C (fr) * 2007-06-21 2013-06-18 Rohm And Haas Company Composition microbicide comportant du n-methyl-1,2-benzisothiazolin-3-one et du formaldehyde
CN101984809B (zh) * 2010-07-22 2012-11-21 福建诺德生物科技有限责任公司 一种以松脂基植物油为载体的油悬制剂及其制备方法
CN101999372B (zh) * 2010-12-14 2015-11-25 陕西西大华特科技实业有限公司 含有噻霉酮和苯醚甲环唑的杀菌组合物
CN102172240B (zh) * 2011-03-01 2015-09-30 陕西西大华特科技实业有限公司 一种含有噻霉酮和甲氧基丙烯酸酯类杀菌剂的杀菌组合物
CN104488534A (zh) * 2014-12-31 2015-04-08 天津市金三农农业科技开发有限公司 一种温室种植山药的方法
CN105685061A (zh) * 2016-02-29 2016-06-22 陕西西大华特科技实业有限公司 噻霉酮在防治马铃薯种传病害及促根发芽上的应用

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103704234A (zh) * 2014-01-07 2014-04-09 中国农业科学院植物保护研究所 一种防治农业细菌性病害的组合物
CN106259387A (zh) * 2016-04-29 2017-01-04 江苏辉丰农化股份有限公司 一种杀菌剂组合物
CN106489965A (zh) * 2016-09-23 2017-03-15 江苏辉丰农化股份有限公司 一种杀菌剂组合物

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019241058A1 (fr) * 2018-06-10 2019-12-19 Troy Corporation Conservateurs sans formaldéhyde pour produits hautement sensibles

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