WO2017166565A1 - Composition synergique de régulation de la croissance de plantes - Google Patents

Composition synergique de régulation de la croissance de plantes Download PDF

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Publication number
WO2017166565A1
WO2017166565A1 PCT/CN2016/094029 CN2016094029W WO2017166565A1 WO 2017166565 A1 WO2017166565 A1 WO 2017166565A1 CN 2016094029 W CN2016094029 W CN 2016094029W WO 2017166565 A1 WO2017166565 A1 WO 2017166565A1
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Prior art keywords
choline chloride
composition
active component
thiabendazole
composition according
Prior art date
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PCT/CN2016/094029
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English (en)
Chinese (zh)
Inventor
仲汉根
季红进
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江苏辉丰农化股份有限公司
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Publication of WO2017166565A1 publication Critical patent/WO2017166565A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/04—Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A01N37/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides containing at least one oxygen or sulfur atom being directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom

Definitions

  • the invention belongs to the field of agricultural plant protection, in particular to a plant growth regulator composition with improved properties, in particular to a composition comprising thidiazuron and choline chloride pesticide.
  • Choline chloride is also a plant photosynthesis promoter, which has a significant effect on increasing yield.
  • Spraying wheat and rice at the booting stage can promote the differentiation of spikelets and multi-tassel grains. Spraying at the filling stage can accelerate the filling rate, and the spikes are full, which can promote the 1000-grain weight increase.
  • It can also be used to increase the yield of corn, sugar cane, sweet potato, potato, radish, onion, cotton, tobacco, vegetables, grapes, mango, etc., and the effect is stable under different climatic and ecological environment conditions; the underground growth crops such as roots are applied at the initial stage of expansion, The effect of swelling and increasing yield is obvious; ornamental plants azalea, poinsettia, geranium, hibiscus and so on regulate growth; wheat, barley, oats are lodging resistance.
  • Pyraclostrobin is a new type of high-efficiency plant growth regulator. When it is absorbed by plants, it can promote the separation of petioles and stems and form natural shedding. It can be widely used in pesticides and fertilizers. It has strong biological activity, and its ability to induce plant cell division and callus formation is many times higher than that of general cytokinins. Improve crop absorptive capacity and increase photosynthesis, so as to increase production and enhance the purpose. It can be used in various kinds of melons, fruits, vegetables, seedlings, flowers, food, tobacco and other crops, and can also be used for tissue culture, genetic engineering, etc. In production, it can significantly improve crop yield, improve quality and use less, has no pollution to the ecological environment, and is non-toxic to humans, animals, birds, bees and natural enemies.
  • the plant growth regulators currently on the market are mainly based on a single agent, and the effect is single.
  • the inventors have found that choline chloride and thiabendazole have significant synergistic effects in regulating or promoting plant growth.
  • Another object of the present invention is to provide a process for the preparation of a composition comprising two active ingredients A and B plant growth regulators and for regulating and promoting the growth of crops in the agricultural field.
  • the object of the invention can be achieved by the following measures:
  • a synergistic plant growth regulator composition comprising two active components A and B, Wherein the active component A is thiabendazole, and the active component B is choline chloride or a derivative thereof, and the weight ratio between the two components is 1:0.02 of the active component A and the active component B. 500.
  • the weight ratio of the active component A to the active component B is 1:0.02 to 480, and the weight ratio may be further preferably 1:0.03 to 450 in order to make the effect more remarkable.
  • the weight ratio between the two components of A and B can be arbitrarily adjusted within the range of the following ratios: 1:0.02, 1:0.03, 1:0.04, 1:0.05, 1: 0.06, 1:0.07, 1:0.08, 1:0.09, 1:0.1, 1:0.2, 1:0.3, 1:0.4, 1:0.5, 1:0.6, 1:0.7, 1:0.8, 1:0.9, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:30, 1: 40, 1:50, 1:60, 1:70, 1:80, 1:90, 1:100, 1:150, 1:200, 1:250, 1:300, 1:350, 1:400, 1:410, 1:420, 1:430, 1:440, 1:450, 1:460, 1:470 or 1:480, and can also be selected within the range of any two of the above ratios.
  • Common choline chloride derivatives include chlorinated choline chloride and the like.
  • composition of the present invention is used for better regulating the growth of crops, promoting the improvement of crop health and quality, and improving crop yield; it can be applied to the agricultural field to promote or regulate plant growth.
  • the present invention provides the use of a composition comprising component A (thiabendazole) and component B (choline chloride or a derivative thereof) for regulating crop growth in the agricultural field, in particular for regulating crops in rice, wheat or fruit trees. Use for growth and other aspects of disease resistance.
  • component A thiabendazole
  • component B choline chloride or a derivative thereof
  • the composition of the present invention can be made into a pesticide-approved dosage form from active ingredients and auxiliaries, in particular, it can be combined with other pesticides (such as fungicides, insecticides, herbicides, plant growth regulators). Mixtures, fertilizers, etc. are used in combination, and these are mixed with commonly used pesticides or fertilizers disclosed in the prior art.
  • the composition of the present invention can also be used in combination with other pesticides (such as fungicides, insecticides, herbicides, plant growth regulators), fertilizers, etc., and these are mixed with Commonly used pesticides or fertilizers disclosed in the art.
  • composition of the present invention can be processed into a preparation of various dosage forms with a fertilizer, or co-administered or mixed with a fertilizer.
  • Suitable fertilizers include one or more of a large number of elements such as nitrogen, phosphorus, potassium, or the like, or one or more trace elements of copper, iron, manganese, zinc, boron, calcium, magnesium, sulfur, or the like, or A mixture of one or both of humic acid, amino acid or chitosan.
  • composition may specifically comprise an agrochemical auxiliary, such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant, etc., during the application process.
  • an agrochemical auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant, etc.
  • an agrochemical auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant, etc.
  • Suitable auxiliaries may be solid or liquid, they are usually materials commonly used in the processing of dosage forms, such as natural or regenerated minerals, solvents, dispersants, wetting agents, adhesives, thickeners, binders or fertilizers. .
  • the active ingredient may be present in the composition in an amount of from 0.5 to 95%, preferably from 0.5 to 80%, more preferably from 1 to 50%.
  • the method of application of the compositions of the invention comprises the use of the compositions of the invention for aerial parts of plants, in particular leaves or foliage. You can choose to soak or apply to the surface of the control object.
  • the frequency of administration and the amount administered will depend on the biological and climatic conditions of the pathogen.
  • the plant growth site such as rice fields, may be wetted with a liquid formulation of the composition, or the composition may be applied to the soil in solid form, such as in the form of granules (soil application), the composition may be passed from the soil to the plant through the roots of the plant. In vivo (systemic action).
  • compositions may be applied only with the active ingredient or may be mixed with an additive (agrochemical adjuvant).
  • composition of the present invention can be prepared into a pesticide-acceptable dosage form such as a liquid, a suspension, a soluble liquid, an oil suspension, a microcapsule, a microemulsion, a wettable powder and the like.
  • a pesticide-acceptable dosage form such as a liquid, a suspension, a soluble liquid, an oil suspension, a microcapsule, a microemulsion, a wettable powder and the like.
  • the compositions may be applied by spraying, misting, dusting, spreading or pouring, and the like.
  • Microcapsule dosage forms suitable for the present invention include: microcapsule suspension, microcapsule suspension-suspension, microcapsule suspension-water emulsion, etc., characterized in that the inner wall of the capsule (ie, the capsule core) contains choline chloride and thiophene as active ingredients.
  • the benzophenone is mixed in a certain proportion, that is, the two are mixed into a microcapsule.
  • the microcapsules are stably dispersed and suspended in a certain concentration to form a microcapsule suspending agent in water as a continuous phase.
  • one of the active ingredients is prepared as a microcapsule suspension, another active ingredient is prepared into an emulsion, and the prepared two components are mixed, stirred, and shaken to obtain a microcapsule suspension-suspension or microcapsule suspension.
  • Agent-water emulsion is a microcapsule suspension.
  • composition of the present invention can be prepared into various dosage forms by a known method, and the active ingredient and the auxiliary agent, such as a solvent, a solid carrier, and, if necessary, can be uniformly mixed and ground together with the surfactant to prepare a desired preparation. Dosage form.
  • the above solvent may be selected from aromatic hydrocarbons, preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • aromatic hydrocarbons preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • Alkenes or paraffins, alcohols and glycols and their ethers and esters such as ethanol, ethylene glycol, ethylene glycol monomethyl
  • ketones such as cyclohexanone
  • highly polar solvents such as N-methyl-2 Pyrrolidone, dimethyl sulfoxide or dimethylformamide
  • vegetable or vegetable oils such as soybean oil.
  • the above solid carriers are typically natural mineral fillers such as talc, kaolin, montmorillonite or activated clay.
  • a highly dispersible silicic acid or a highly dispersible adsorbent polymer carrier such as a particulate adsorbent carrier or a non-adsorbing carrier, and a suitable particulate adsorbent carrier is porous, such as pumice, bentonite or Bentonite; a suitable non-adsorbing carrier such as calcite or sand.
  • a large amount of pre-granulated materials of inorganic or organic nature can be used as a carrier, in particular dolomite.
  • Suitable surfactants are lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, alkaline earth metal or amine salts, alkylarylsulfonates, alkyl groups Sulfates, alkyl sulfonates, fatty alcohol sulphates, fatty acids and sulfated fatty alcohol glycol ethers, as well as condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, naphthalene or naphthalene sulfonic acid with phenol and formaldehyde Condensate, polyoxyethylene octyl phenyl ether, ethoxylated isooctyl phenol, octyl phenol, nonyl phenol, alkyl aryl polyglycol ether, tributyl benzene poly
  • Plants in the present invention include, but are not limited to, corn, wheat, rice, and the like.
  • the two active ingredients in the compositions of the present invention exhibit synergistic effects, the activity of which is more pronounced than the expected sum of activity using a single compound, and the individual activity of a single compound.
  • Other characteristics exhibited by the composition of the present invention are mainly as follows: 1.
  • the composition of the present invention has a significant synergistic effect; 2. Due to the large difference in the chemical structure of the two single agents of the composition, the effect The mechanism is completely different, there is no cross-resistance, which can delay the resistance problem caused by the two single agents alone; 3.
  • the composition of the invention can well regulate crop growth, improve disease resistance and stress resistance, and promote crop health effects. To increase crop yields.
  • the active ingredients choline chloride and thidiazepine, and the components such as dispersant, wetting agent, thickener and water are uniformly mixed according to the formula, and after sanding and/or high-speed shearing, semi-finished products are obtained. After the analysis, the water is mixed and evenly filtered to obtain the finished product.
  • Example 1 5.1% thidiazuron choline chloride suspension
  • Example 2 30.06% thiabendazole ⁇ chlorinated choline chloride suspension
  • Example 3 2.08% thidiazuron choline chloride suspension
  • Example 4 22.55% thidiazuron choline chloride suspension
  • the active ingredient thiablon and choline chloride are mixed in a certain ratio, that is, the two are mixed to form a microcapsule.
  • the microcapsules are stably dispersed and suspended in a certain concentration to form a microcapsule suspending agent in water as a continuous phase.
  • one of the active ingredients is prepared as a microcapsule suspension, another active ingredient is prepared into an emulsion, and the prepared two components are mixed, stirred, and shaken to obtain a microcapsule suspension-suspension or microcapsule suspension.
  • Agent-water emulsion Agent-water emulsion.
  • Example 5 1% thiabendazole ⁇ chlorinated choline microcapsule suspension
  • Example 6 25.1% thidiazuron choline chloride microcapsule suspension
  • Example 7 15.3% thidiazuron choline chloride microcapsule suspension
  • Example 8 30.1% thiabendazole ⁇ choline chloride sac suspension-suspending agent
  • Example 9 40.2% thidiazuron choline chloride microcapsule suspension
  • the active ingredient thiablon and choline chloride are placed in an enamel kettle according to a certain ratio of mixture, surfactant, auxiliary agent and water, and stirred under water bath conditions until a transparent liquid is obtained, that is, a soluble liquid agent is obtained.
  • Example 11 40.1% thiabendazole ⁇ choline chloride soluble solution
  • the active ingredient and the auxiliary agent are added to the reaction kettle, and the balance is made up with water and stirred uniformly to obtain a thiabendazole-choline chloride aqueous solution.
  • Example 12 10.4% thiabendazole-choline chloride aqueous solution
  • Example 13 45.3% thiabendazole-choline chloride aqueous solution
  • Example 14 38% thiabendazole-choline chloride aqueous solution
  • Example 15 20.2% thiabendazole-choline chloride aqueous solution
  • Example 16 52.65% thiabendazole-choline chloride aqueous solution
  • the thiabendazole and choline chloride were diluted with acetone at a certain concentration, and the crops were sprayed with stems and leaves.
  • the effects of various concentrations on the growth of the crops were determined in the field, including the plant height, plant diameter, root length and disease resistance of the crops. Comprehensive evaluation of fruit quality, yield, etc.
  • Plant height control rate (clear water control plant height - treated plant height) / clear water control plant height * 100%
  • stem diameter of clear water control plant - stem diameter of treated plant stem diameter of clear water control plant *100%
  • Grain 1000-grain weight increase rate (1000-grain weight of fresh water control - 1000-grain weight of treated grain) / 1000-grain weight of fresh water control *100%
  • the invention can effectively increase the plant diameter of the corn, improve the nutrient conduction capacity of the plant, and can improve the lodging resistance of the corn growth by promoting the plant diameter.
  • thiabendone has a certain disease resistance and anti-reverse effect on plant growth when used as a single agent, while choline chloride can inhibit C 3 photosynthesis in plants, promote root growth and development, and have certain immunity to crop diseases.
  • the invention can effectively regulate the control of the corn, that is, reduce the plant height and the ear position of the corn, and effectively balance the vegetative growth and the reproductive growth. To prevent lodging; 4, due to the synergistic effect of thiazolone and choline chloride in the early stage of corn growth, promote the nutrient transmission, disease resistance and resistance of maize plants.
  • the 1000-grain weight of corn and the yield per mu are significant.
  • the promotion effect of the yield per mu is up to 19.9%; 5, when the ratio of thidiazepine to choline chloride is 1: (25-150), the synergistic effect of the two is obvious.
  • the ratio of thiabendazole to choline chloride is lower than 25 or higher than 150, the synergistic effect of the two is not obvious.
  • the experimental data from Table 2 shows that the product of the present invention is applied during the flowering stage of barley, and can effectively regulate the healthy growth of barley.
  • the main performances are as follows: 1. It can increase the ear length of barley and increase the number of grains per spike; 2. It can significantly increase the weight of barley grain; 3. Thiabendazole can promote the growth of barley, while choline chloride can affect barley. Growth has certain resistance to disease and stress, and the two have a synergistic effect after compounding; 4.
  • the composition of the invention has a significant effect on the unit yield of barley.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne une composition synergique de régulation de la croissance de plantes. Les principes actifs de la composition comprennent des composants actifs A et B, le composant actif A étant du thidiazuron, et le composant actif B étant du chlorure de choline et un dérivé de celui-ci ; et le rapport pondéral du composant actif A par rapport au composant actif B étant de 1:0,02-500. L'invention concerne également l'utilisation de la composition. Les résultats expérimentaux indiquent que la composition peut efficacement réguler la croissance des cultures, augmenter la résistance aux maladies et la résistance au stress de celles-ci, favoriser la santé des cultures et augmenter le rendement des cultures.
PCT/CN2016/094029 2016-04-02 2016-08-08 Composition synergique de régulation de la croissance de plantes WO2017166565A1 (fr)

Applications Claiming Priority (2)

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CN201610204837.7 2016-04-02

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CN115119840A (zh) * 2022-01-18 2022-09-30 陕西美邦药业集团股份有限公司 一种用于调节葡萄着色的植物生长调节剂组合物
CN115281207A (zh) * 2022-03-31 2022-11-04 陕西美邦药业集团股份有限公司 一种用于调节花生生长的尿囊素组合物
CN115428636A (zh) * 2020-11-11 2022-12-06 河南省新乡市农业科学院 一种小麦叶面肥施用方法及其应用
EP4156928A4 (fr) * 2020-05-28 2024-04-17 Balchem Corporation Compositions de chlorure de choline

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CN106212492A (zh) * 2016-04-02 2016-12-14 江苏辉丰农化股份有限公司 具有增效作用的植物生长调节剂组合物
US20180325103A1 (en) * 2017-04-03 2018-11-15 Spogen Biotech Inc. Agricultural compositions for improved crop productivity and enhanced phenotypes
CN107616184B (zh) * 2017-10-09 2019-12-31 江苏辉丰生物技术有限公司 包含噻苯隆和聚谷氨酸的农药组合物
CN108477203A (zh) * 2018-04-20 2018-09-04 江苏辉丰生物农业股份有限公司 含有亚磷酸胆碱和噻苯隆的组合物

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