WO2018040411A1 - Super-concentrated multi-functional laundry detergent sheet and manufacturing method thereof - Google Patents

Super-concentrated multi-functional laundry detergent sheet and manufacturing method thereof Download PDF

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Publication number
WO2018040411A1
WO2018040411A1 PCT/CN2016/111947 CN2016111947W WO2018040411A1 WO 2018040411 A1 WO2018040411 A1 WO 2018040411A1 CN 2016111947 W CN2016111947 W CN 2016111947W WO 2018040411 A1 WO2018040411 A1 WO 2018040411A1
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Prior art keywords
mixture
super concentrated
multifunctional laundry
concentrated multifunctional
super
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PCT/CN2016/111947
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French (fr)
Chinese (zh)
Inventor
王洪祥
林梅平
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朱耀灯
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Publication of WO2018040411A1 publication Critical patent/WO2018040411A1/en

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0086—Laundry tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds

Definitions

  • the invention relates to the technical field of daily washing chemicals, in particular to a super concentrated multifunctional laundry tablet and a preparation method thereof.
  • the laundry tablet is a brand new washing product, which changes the shape of the previous washing product. Lightness is its biggest feature. Because it does not contain fluorescent brighteners, phosphorus and other harmful components, it gradually becomes popular in the European and American markets and becomes a new generation of washing products. It is a neutral synthetic detergent.
  • the quantitative washing realized by the washing sheet overcomes the cumbersome measurement of the traditional washing powder and the washing liquid, that is, the washing product is saved, and the environmental characteristics of the low foaming and super-concentration save water, and it is expected to be promoted in the country, with the people's life.
  • the development trend of the film The development trend of the film.
  • the technical problem to be solved by the present invention is to provide a super concentrated multifunctional laundry tablet which is convenient to use, safe, environmentally friendly and easy to carry, and a preparation method thereof, in view of the above-mentioned deficiencies of the prior art.
  • the invention provides a super concentrated multifunctional laundry tablet, the components and the weight percentage of the raw materials are:
  • Disintegrant 0.01% to 50%
  • Flavor oil 0.01% ⁇ 10%
  • the balance of water is the solvent.
  • the surfactant is one or more of sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium laureth sulfate, and cocamide DEA.
  • the disintegrant is dry starch.
  • the binder is one or more of cellulose, dentin, saccharide, polyethylene glycol, and polyvinyl alcohol.
  • the lubricant is one or more of magnesium stearate, silica, hydrogenated vegetable oil, isopropyl palmitate, glycerin, mineral oil.
  • solubilizer is one or both of PEG-400 and RH-40 hydrogenated sesame oil.
  • the invention provides a preparation method of a super concentrated multifunctional laundry tablet, comprising the following steps:
  • the fragrance oil and the solubilizer are added to the mixture B in the step (2), and the compatibilization and dispersion treatment is carried out to form the mixture C;
  • the hot water temperature in the step (1) is 60 to 100 °C.
  • the invention provides a super concentrated multifunctional laundry tablet which is convenient to use, safe, environmentally friendly and easy to carry.
  • the laundry tablet uses a surfactant as a main raw material and a scientific recovery of a detergent auxiliary, a tea saponin, a fragrance oil and a binder.
  • the prepared and prepared laundry tablets are super concentrated and multi-functional, which are superior to soap, washing powder, laundry detergent and other washing products, save water and not pollute the environment, and also conform to the concept of advocating nature and green environmental protection, and the preparation
  • the method has the characteristics of convenient production and cost, and is easy to realize industrial production.
  • a super concentrated multifunctional laundry tablet whose composition and raw material weight percentage are:
  • the balance of water is the solvent.
  • the surfactant is sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium laureth sulfate, and cocamide DEA, each of which has a weight ratio of 10:6:2: 1;
  • the disintegrant is dry starch.
  • the binder is cellulose and polyvinyl alcohol, each of which has a weight ratio of 1:9.
  • the lubricant is magnesium stearate and silica in a weight ratio of 1:5.
  • the solubilizing agent is PEG-400 and RH-40 hydrogenated sesame oil, each of which has a weight ratio of 1:3.
  • the invention provides a preparation method of a super concentrated multifunctional laundry tablet, comprising the following steps:
  • the fragrance oil and the solubilizer are added to the mixture B in the step (2), and the compatibilization and dispersion treatment is carried out to form the mixture C;
  • the hot water temperature in the step (1) is 60 °C.
  • the invention provides a super concentrated multifunctional laundry tablet which is convenient to use, safe, environmentally friendly and easy to carry.
  • the laundry tablet uses a surfactant as a main raw material and a scientific recovery of a detergent auxiliary, a tea saponin, a fragrance oil and a binder.
  • the prepared and prepared laundry tablets are super concentrated and multi-functional, which are superior to soap, washing powder, laundry detergent and other washing products, save water and not pollute the environment, and also conform to the concept of advocating nature and green environmental protection, and the preparation
  • the method has the characteristics of convenient production and cost, and is easy to realize industrial production.
  • a super concentrated multifunctional laundry tablet whose composition and raw material weight percentage are:
  • the balance of water is the solvent.
  • the surfactant is sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium laureth sulfate, and cocamide DEA, each of which has a weight ratio of 10:5:3: 1;
  • the disintegrant is dry starch.
  • the binder is polyvinyl alcohol.
  • the lubricant is glycerin, mineral oil, and silica in a weight ratio of 5:2:1.
  • the solubilizing agent is RH-40 hydrogenated sesame oil.
  • the invention provides a preparation method of a super concentrated multifunctional laundry tablet, comprising the following steps:
  • the fragrance oil and the solubilizer are added to the mixture B in the step (2), and the compatibilization and dispersion treatment is carried out to form the mixture C;
  • the hot water temperature in the step (1) is 90 °C.
  • a super concentrated multifunctional laundry tablet whose composition and raw material weight percentage are:
  • the balance of water is the solvent.
  • the surfactant is sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium laureth sulfate, and cocamide DEA, each of which has a weight ratio of 10:5:3: 1;
  • the disintegrant is dry starch.
  • the binder is polyvinyl alcohol.
  • the lubricant is glycerin, mineral oil, and silica in a weight ratio of 3:1:1.
  • the solubilizing agent is RH-40 hydrogenated sesame oil.
  • the invention provides a preparation method of a super concentrated multifunctional laundry tablet, comprising the following steps:
  • the fragrance oil and the solubilizer are added to the mixture B in the step (2), and the compatibilization and dispersion treatment is carried out to form the mixture C;
  • the hot water temperature in the step (1) is 98 °C.
  • the laundry tablets provided by the present invention are compared with the indexes of the washing powder and the laundry liquid, and the technical indexes have reached an advanced level, and under the premise of achieving the same laundry effect, the application
  • the laundry sheet has a great advantage, especially the best effect in the embodiment 1.
  • the invention provides a super concentrated multifunctional laundry tablet which is convenient to use, safe, environmentally friendly and easy to carry, and the laundry sheet is mainly composed of a surfactant. Washing auxiliaries, tea saponin, scented oil, adhesives, etc. are scientifically compounded, and the prepared laundry tablets are super concentrated, and the multifunctional functions are obviously superior to those of soap, washing powder, laundry detergent, etc. It does not pollute the environment, and it also conforms to the concept of advocating nature and green environmental protection. Moreover, the preparation method has the characteristics of easy production and cost, and is easy to realize industrial production.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

A super-concentrated multi-functional laundry detergent sheet comprises the following components and materials, in weight percentage: 0.02% to 30% of tea saponin, 1% to 65% of surface active agents, 0.01% to 50% of disintegrant, 0.01% to 30% of binder, 0.01% to 20% of lubricant, 0.01% to 10% of fragrance oil, 0.01% to 20% of solubilizer, with the balance being water as the solvent. The laundry detergent sheet is mainly made of surface active agents, has better effects than cleaning products such as soaps, laundry powder and liquid laundry detergent, saves water, and does not pollute the environment, thus conforming to the ideas of nature protection and going green. Also, the manufacturing method thereof has the advantage of easy production, and therefore facilitates industrial production.

Description

一种超浓缩多功能洗衣片及其制备方法Super concentrated multifunctional laundry tablet and preparation method thereof 技术领域Technical field
本发明涉及日常洗化用品技术领域，具体涉及一种超浓缩多功能洗衣片及其制备方法。The invention relates to the technical field of daily washing chemicals, in particular to a super concentrated multifunctional laundry tablet and a preparation method thereof.
背景技术Background technique
洗衣片是一种全新的洗涤产品，改变了以往洗涤产品的形态，轻便是它最大的特点，因其不含有荧光增白剂，磷等有害成分，逐渐风靡欧美市场，成为新一代洗涤产品，是一种中性的合成洗涤剂。The laundry tablet is a brand new washing product, which changes the shape of the previous washing product. Lightness is its biggest feature. Because it does not contain fluorescent brighteners, phosphorus and other harmful components, it gradually becomes popular in the European and American markets and becomes a new generation of washing products. It is a neutral synthetic detergent.
但是目前国内的许多洗涤市场却存在着不小的问题，目前市面上最常见的洗衣粉与洗衣液中，普遍含有荧光增白剂、蛋白水解酶、三聚磷酸钠等成分，其中的荧光增白剂危害最大，对老人或者小孩，一定要谨慎选择洗涤产品。However, there are still many problems in many domestic washing markets. Currently, the most common washing powders and laundry detergents on the market generally contain fluorescent whitening agents, proteolytic enzymes, sodium tripolyphosphate and other components. Whitening agents are the most harmful. For the elderly or children, be careful to choose washing products.
洗衣片实现的定量洗涤，克服了传统洗衣粉、洗衣液使用中计量的繁琐，即节约了洗涤用品，其低泡超浓缩的环保特性又节约了用水，有望在国内得到推广，随着人民生活水平的提高，人们对洗衣片产品质量的要求也越来越高，洗衣片的需求量将会越来越大，质量要求也越来越高，活性物高、多功能、使用简便将是洗衣片的发展趋势。The quantitative washing realized by the washing sheet overcomes the cumbersome measurement of the traditional washing powder and the washing liquid, that is, the washing product is saved, and the environmental characteristics of the low foaming and super-concentration save water, and it is expected to be promoted in the country, with the people's life. The improvement of the level, people's requirements for the quality of laundry products are getting higher and higher, the demand for laundry tablets will be more and more, the quality requirements are also higher and higher, the active matter is high, multi-functional, easy to use will be laundry. The development trend of the film.
发明内容Summary of the invention
本发明所要解决的技术问题是针对上述现有技术的不足而提供一种使用方便、安全环保、易于携带的超浓缩多功能洗衣片及其制备方法。The technical problem to be solved by the present invention is to provide a super concentrated multifunctional laundry tablet which is convenient to use, safe, environmentally friendly and easy to carry, and a preparation method thereof, in view of the above-mentioned deficiencies of the prior art.
本发明为解决上述问题所采用的技术方案为：The technical solution adopted by the present invention to solve the above problems is as follows:
本发明提供一种超浓缩多功能洗衣片，其组分及原料重量百分比为：The invention provides a super concentrated multifunctional laundry tablet, the components and the weight percentage of the raw materials are:
茶皂素 0.02％～30％、Tea saponin 0.02% to 30%,
表面活性剂 1％～65％、 Surfactant 1% to 65%,
崩解剂 0.01％～50％、Disintegrant 0.01% to 50%,
粘合剂 0.01％～30％、Adhesive 0.01% to 30%,
润滑剂 0.01％～20％、Lubricant 0.01% to 20%,
香氛油 0.01％～10％Flavor oil 0.01%~10%
增溶剂 0.01％～20％Solubilizer 0.01%～20%
余量水为溶剂。The balance of water is the solvent.
进一步地，所述表面活性剂为月桂醇硫酸酯钠、十二烷基苯磺酸钠、月桂醇聚醚硫酸酯钠和椰油酰胺DEA中的一种或几种。Further, the surfactant is one or more of sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium laureth sulfate, and cocamide DEA.
进一步地，所述崩解剂为干淀粉。Further, the disintegrant is dry starch.
进一步地，所述粘合剂为纤维素、麦牙糊精、糖类、聚乙二醇和聚乙烯醇中的一种或几种。Further, the binder is one or more of cellulose, dentin, saccharide, polyethylene glycol, and polyvinyl alcohol.
进一步地，所述润滑剂为硬脂酸镁、二氧化硅、氢化植物油、棕榈酸异丙酯、甘油、矿油中的一种或几种。Further, the lubricant is one or more of magnesium stearate, silica, hydrogenated vegetable oil, isopropyl palmitate, glycerin, mineral oil.
进一步地，所述增溶剂为PEG-400和RH-40氢化麻油中的一种或两种。Further, the solubilizer is one or both of PEG-400 and RH-40 hydrogenated sesame oil.
本发明提供一种超浓缩多功能洗衣片的制备方法，包括以下步骤：The invention provides a preparation method of a super concentrated multifunctional laundry tablet, comprising the following steps:
(1)将所述表面活性剂和茶皂素按照重量百分比加入到热水中进行混合并搅拌均匀形成混合物A；(1) The surfactant and tea saponin are added to hot water according to the weight percentage, mixed and stirred to form a mixture A;
(2)按照原料的重量百分比称取原崩解剂、粘合剂和润滑剂加入到混合物A中搅拌均匀形成混合物B；(2) according to the weight percent of the raw material weighed the original disintegrant, binder and lubricant added to the mixture A and stirred to form a mixture B;
(3)按照原料的重量百分比称取香氛油和增溶剂加入到步骤(2)中的混合物B中，进行增容分散处理形成混合物C；(3) According to the weight percentage of the raw material, the fragrance oil and the solubilizer are added to the mixture B in the step (2), and the compatibilization and dispersion treatment is carried out to form the mixture C;
(4)对步骤(3)中的混合物C进行性能测试、沐膜烘干成型、切片、封装、检验和入库处理，得到所需超浓缩多功能洗衣片。(4) Perform the performance test, the film drying molding, the slicing, the encapsulation, the inspection and the warehousing treatment of the mixture C in the step (3) to obtain the desired super concentrated multifunctional laundry sheet.
进一步地，步骤(1)中所述热水温度为60～100℃。 Further, the hot water temperature in the step (1) is 60 to 100 °C.
本发明的有益效果在于：The beneficial effects of the invention are:
本发明提供一种使用方便、安全环保、易于携带的超浓缩多功能洗衣片，该洗衣片以表面活性剂为主要原料与洗涤助剂、茶皂素、香氛油、粘合剂等科学复配，配制的洗衣片，其超浓缩，多功能功效性明显优于肥皂、洗衣粉、洗衣液等洗涤用品，省水且不污染环境，也符合人们崇尚自然，绿色环保的理念，而且该制备方法具有便于生产、成本的特点，易于实现工业化生产。The invention provides a super concentrated multifunctional laundry tablet which is convenient to use, safe, environmentally friendly and easy to carry. The laundry tablet uses a surfactant as a main raw material and a scientific recovery of a detergent auxiliary, a tea saponin, a fragrance oil and a binder. The prepared and prepared laundry tablets are super concentrated and multi-functional, which are superior to soap, washing powder, laundry detergent and other washing products, save water and not pollute the environment, and also conform to the concept of advocating nature and green environmental protection, and the preparation The method has the characteristics of convenient production and cost, and is easy to realize industrial production.
具体实施方式detailed description
下面结合具体阐明本发明的实施方式，这些实施例的给出仅仅是为了说明的目的，并不能理解为对本发明的限定，仅供参考和说明使用，不构成对本发明专利保护范围的限制，因为在不脱离本发明的精神和范围的基础上，可以对本发明进行许多改变。The embodiments of the present invention are specifically described below, and are not intended to limit the scope of the present invention. Many changes may be made to the invention without departing from the spirit and scope of the invention.
实施例1Example 1
一种超浓缩多功能洗衣片，其组分及原料重量百分比为：A super concentrated multifunctional laundry tablet whose composition and raw material weight percentage are:
茶皂素 2％、Tea saponin 2%,
表面活性剂 32％、Surfactant 32%,
崩解剂 15％、Disintegrant 15%,
粘合剂 15％、15% binder,
润滑剂 6％、Lubricant 6%,
香氛油 3％Fragrance oil 3%
增溶剂 10％Solubilizer 10%
余量水为溶剂。The balance of water is the solvent.
本实施例中，所述表面活性剂为月桂醇硫酸酯钠、十二烷基苯磺酸钠、月桂醇聚醚硫酸酯钠和椰油酰胺DEA，各占重量比为10：6：2：1；In this embodiment, the surfactant is sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium laureth sulfate, and cocamide DEA, each of which has a weight ratio of 10:6:2: 1;
本实施例中，所述崩解剂为干淀粉。In this embodiment, the disintegrant is dry starch.
本实施例中，所述粘合剂为纤维素和聚乙烯醇，各占重量比为1：9。In this embodiment, the binder is cellulose and polyvinyl alcohol, each of which has a weight ratio of 1:9.
本实施例中，所述润滑剂为硬脂酸镁、二氧化硅各占重量比为1：5。 In this embodiment, the lubricant is magnesium stearate and silica in a weight ratio of 1:5.
本实施例中，，所述增溶剂为PEG-400和RH-40氢化麻油，各各占重量比为1：3。In this embodiment, the solubilizing agent is PEG-400 and RH-40 hydrogenated sesame oil, each of which has a weight ratio of 1:3.
本发明提供一种超浓缩多功能洗衣片的制备方法，包括以下步骤：The invention provides a preparation method of a super concentrated multifunctional laundry tablet, comprising the following steps:
(1)将所述表面活性剂和差皂素按照重量百分比加入到热水中进行混合并搅拌均匀形成混合物A；(1) the surfactant and poor saponin are added to the hot water in a percentage by weight to mix and stir to form a mixture A;
(2)按照原料的重量百分比称取原崩解剂、粘合剂和润滑剂加入到混合物A中搅拌均匀形成混合物B；(2) according to the weight percent of the raw material weighed the original disintegrant, binder and lubricant added to the mixture A and stirred to form a mixture B;
(3)按照原料的重量百分比称取香氛油和增溶剂加入到步骤(2)中的混合物B中，进行增容分散处理形成混合物C；(3) According to the weight percentage of the raw material, the fragrance oil and the solubilizer are added to the mixture B in the step (2), and the compatibilization and dispersion treatment is carried out to form the mixture C;
(4)对步骤(3)中的混合物C进行性能测试、沐膜烘干成型、切片、封装、检验和入库处理，得到所需超浓缩多功能洗衣片。(4) Perform the performance test, the film drying molding, the slicing, the encapsulation, the inspection and the warehousing treatment of the mixture C in the step (3) to obtain the desired super concentrated multifunctional laundry sheet.
本实施例中，步骤(1)中所述热水温度为60℃。In this embodiment, the hot water temperature in the step (1) is 60 °C.
本发明提供一种使用方便、安全环保、易于携带的超浓缩多功能洗衣片，该洗衣片以表面活性剂为主要原料与洗涤助剂、茶皂素、香氛油、粘合剂等科学复配，配制的洗衣片，其超浓缩，多功能功效性明显优于肥皂、洗衣粉、洗衣液等洗涤用品，省水且不污染环境，也符合人们崇尚自然，绿色环保的理念，而且该制备方法具有便于生产、成本的特点，易于实现工业化生产。The invention provides a super concentrated multifunctional laundry tablet which is convenient to use, safe, environmentally friendly and easy to carry. The laundry tablet uses a surfactant as a main raw material and a scientific recovery of a detergent auxiliary, a tea saponin, a fragrance oil and a binder. The prepared and prepared laundry tablets are super concentrated and multi-functional, which are superior to soap, washing powder, laundry detergent and other washing products, save water and not pollute the environment, and also conform to the concept of advocating nature and green environmental protection, and the preparation The method has the characteristics of convenient production and cost, and is easy to realize industrial production.
实施例2Example 2
一种超浓缩多功能洗衣片，其组分及原料重量百分比为：A super concentrated multifunctional laundry tablet whose composition and raw material weight percentage are:
茶皂素 11％、Tea saponin 11%,
表面活性剂 40％、Surfactant 40%,
崩解剂 10％、Disintegrant 10%,
粘合剂 10％、10% binder,
润滑剂 8％、Lubricant 8%,
香氛油 2％、Fragrance oil 2%,
增溶剂 4％、 Solubilizer 4%,
余量水为溶剂。The balance of water is the solvent.
本实施例中，所述表面活性剂为月桂醇硫酸酯钠、十二烷基苯磺酸钠、月桂醇聚醚硫酸酯钠和椰油酰胺DEA，各占重量比为10：5：3：1；In this embodiment, the surfactant is sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium laureth sulfate, and cocamide DEA, each of which has a weight ratio of 10:5:3: 1;
本实施例中，所述崩解剂为干淀粉。In this embodiment, the disintegrant is dry starch.
本实施例中，所述粘合剂为聚乙烯醇。In this embodiment, the binder is polyvinyl alcohol.
本实施例中，所述润滑剂为甘油、矿油、二氧化硅各占重量比为5：2：1。In this embodiment, the lubricant is glycerin, mineral oil, and silica in a weight ratio of 5:2:1.
本实施例中，所述增溶剂为RH-40氢化麻油。In this embodiment, the solubilizing agent is RH-40 hydrogenated sesame oil.
本发明提供一种超浓缩多功能洗衣片的制备方法，包括以下步骤：The invention provides a preparation method of a super concentrated multifunctional laundry tablet, comprising the following steps:
(1)将所述表面活性剂和差皂素按照重量百分比加入到热水中进行混合并搅拌均匀形成混合物A；(1) the surfactant and poor saponin are added to the hot water in a percentage by weight to mix and stir to form a mixture A;
(2)按照原料的重量百分比称取原崩解剂、粘合剂和润滑剂加入到混合物A中搅拌均匀形成混合物B；(2) according to the weight percent of the raw material weighed the original disintegrant, binder and lubricant added to the mixture A and stirred to form a mixture B;
(3)按照原料的重量百分比称取香氛油和增溶剂加入到步骤(2)中的混合物B中，进行增容分散处理形成混合物C；(3) According to the weight percentage of the raw material, the fragrance oil and the solubilizer are added to the mixture B in the step (2), and the compatibilization and dispersion treatment is carried out to form the mixture C;
(4)对步骤(3)中的混合物C进行性能测试、沐膜烘干成型、切片、封装、检验和入库处理，得到所需超浓缩多功能洗衣片。(4) Perform the performance test, the film drying molding, the slicing, the encapsulation, the inspection and the warehousing treatment of the mixture C in the step (3) to obtain the desired super concentrated multifunctional laundry sheet.
本实施例中，步骤(1)中所述热水温度为90℃。In this embodiment, the hot water temperature in the step (1) is 90 °C.
实施例3Example 3
一种超浓缩多功能洗衣片，其组分及原料重量百分比为：A super concentrated multifunctional laundry tablet whose composition and raw material weight percentage are:
茶皂素 15％、Tea saponin 15%,
表面活性剂 35％、Surfactant 35%,
崩解剂 10％、Disintegrant 10%,
粘合剂 5％、Adhesive 5%,
润滑剂 10％、Lubricant 10%,
香氛油 2％Fragrance oil 2%
增溶剂 5％ Solubilizer 5%
余量水为溶剂。The balance of water is the solvent.
本实施例中，所述表面活性剂为月桂醇硫酸酯钠、十二烷基苯磺酸钠、月桂醇聚醚硫酸酯钠和椰油酰胺DEA，各占重量比为10：5：3：1；In this embodiment, the surfactant is sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium laureth sulfate, and cocamide DEA, each of which has a weight ratio of 10:5:3: 1;
本实施例中，所述崩解剂为干淀粉。In this embodiment, the disintegrant is dry starch.
本实施例中，所述粘合剂为聚乙烯醇。In this embodiment, the binder is polyvinyl alcohol.
本实施例中，所述润滑剂为甘油、矿油、二氧化硅各占重量比为3：1：1。In this embodiment, the lubricant is glycerin, mineral oil, and silica in a weight ratio of 3:1:1.
本实施例中，所述增溶剂为RH-40氢化麻油。In this embodiment, the solubilizing agent is RH-40 hydrogenated sesame oil.
本发明提供一种超浓缩多功能洗衣片的制备方法，包括以下步骤：The invention provides a preparation method of a super concentrated multifunctional laundry tablet, comprising the following steps:
(1)将所述表面活性剂和差皂素按照重量百分比加入到热水中进行混合并搅拌均匀形成混合物A；(1) the surfactant and poor saponin are added to the hot water in a percentage by weight to mix and stir to form a mixture A;
(2)按照原料的重量百分比称取原崩解剂、粘合剂和润滑剂加入到混合物A中搅拌均匀形成混合物B；(2) according to the weight percent of the raw material weighed the original disintegrant, binder and lubricant added to the mixture A and stirred to form a mixture B;
(3)按照原料的重量百分比称取香氛油和增溶剂加入到步骤(2)中的混合物B中，进行增容分散处理形成混合物C；(3) According to the weight percentage of the raw material, the fragrance oil and the solubilizer are added to the mixture B in the step (2), and the compatibilization and dispersion treatment is carried out to form the mixture C;
(4)对步骤(3)中的混合物C进行性能测试、沐膜烘干成型、切片、封装、检验和入库处理，得到所需超浓缩多功能洗衣片。(4) Perform the performance test, the film drying molding, the slicing, the encapsulation, the inspection and the warehousing treatment of the mixture C in the step (3) to obtain the desired super concentrated multifunctional laundry sheet.
本实施例中，步骤(1)中所述热水温度为98℃。In this embodiment, the hot water temperature in the step (1) is 98 °C.
表1Table 1
Figure PCTCN2016111947-appb-000001
Figure PCTCN2016111947-appb-000001
如表1所示，本发明所提供的洗衣片与洗衣粉和洗衣液各项指标参数对比发现，各项技术指标都达到了先进的水平，而且在达到相同洗衣效果的前提下，该申请的洗衣片具有较大的优势，尤其是实施例1中的效果最佳，发明提供一种使用方便、安全环保、易于携带的超浓缩多功能洗衣片，该洗衣片以表面活性剂为主要原料与洗涤助剂、茶皂素、香氛油、粘合剂等科学复配，配制的洗衣片，其超浓缩，多功能功效性明显优于肥皂、洗衣粉、洗衣液等洗涤用品，省水且不污染环境，也符合人们崇尚自然，绿色环保的理念，而且该制备方法具有便于生产、成本的特点，易于实现工业化生产。As shown in Table 1, the laundry tablets provided by the present invention are compared with the indexes of the washing powder and the laundry liquid, and the technical indexes have reached an advanced level, and under the premise of achieving the same laundry effect, the application The laundry sheet has a great advantage, especially the best effect in the embodiment 1. The invention provides a super concentrated multifunctional laundry tablet which is convenient to use, safe, environmentally friendly and easy to carry, and the laundry sheet is mainly composed of a surfactant. Washing auxiliaries, tea saponin, scented oil, adhesives, etc. are scientifically compounded, and the prepared laundry tablets are super concentrated, and the multifunctional functions are obviously superior to those of soap, washing powder, laundry detergent, etc. It does not pollute the environment, and it also conforms to the concept of advocating nature and green environmental protection. Moreover, the preparation method has the characteristics of easy production and cost, and is easy to realize industrial production.
上述实施例为本发明较佳的实施方式，但本发明的实施方式并不受上述实施例的限制，其他的任何未背离本发明的精神实质与原理下所作的改变、修饰、替代、组合、简化，均应为等效的置换方式，都包含在本发明的保护范围之内。 The above embodiments are preferred embodiments of the present invention, but the embodiments of the present invention are not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and combinations thereof may be made without departing from the spirit and scope of the invention. Simplifications should all be equivalent replacements and are included in the scope of the present invention.

Claims (8)

  1. 一种超浓缩多功能洗衣片，其特征在于，其组分及原料重量百分比为：A super concentrated multifunctional laundry tablet characterized in that the components and the weight percentage of the raw materials are:
    茶皂素0.02％～30％、Tea saponin 0.02% to 30%,
    表面活性剂1％～65％、Surfactant 1% to 65%,
    崩解剂0.01％～50％、Disintegrant 0.01% to 50%,
    粘合剂0.01％～30％、Adhesive 0.01% to 30%,
    润滑剂0.01％～20％、Lubricant 0.01% to 20%,
    香氛油0.01％～10％Flavor oil 0.01% to 10%
    增溶剂0.01％～20％Solubilizer 0.01% to 20%
    余量水为溶剂。The balance of water is the solvent.
  2. 根据权利要求1所述的一种超浓缩多功能洗衣片，其特征在于：所述表面活性剂为月桂醇硫酸酯钠、十二烷基苯磺酸钠、月桂醇聚醚硫酸酯钠和椰油酰胺DEA中的一种或几种。A super concentrated multifunctional laundry tablet according to claim 1, wherein the surfactant is sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium laureth sulfate and coconut. One or more of oleamide DEA.
  3. 根据权利要求1所述的一种超浓缩多功能洗衣片，其特征在于：所述崩解剂为干淀粉。A super concentrated multifunctional laundry tablet according to claim 1, wherein the disintegrant is dry starch.
  4. 根据权利要求1所述的一种超浓缩多功能洗衣片，其特征在于：所述粘合剂为纤维素、麦牙糊精、糖类、聚乙二醇和聚乙烯醇中的一种或几种。A super concentrated multifunctional laundry tablet according to claim 1, wherein the binder is one or more of cellulose, wheat amylin, saccharide, polyethylene glycol and polyvinyl alcohol. Kind.
  5. 根据权利要求1所述的一种超浓缩多功能洗衣片，其特征在于：所述润滑剂为硬脂酸镁、二氧化硅、氢化植物油、棕榈酸异丙酯、甘油、矿油中的一种或几种。The super concentrated multifunctional laundry tablet according to claim 1, wherein the lubricant is one of magnesium stearate, silicon dioxide, hydrogenated vegetable oil, isopropyl palmitate, glycerin and mineral oil. Kind or several.
  6. 根据权利要求1所述的一种超浓缩多功能洗衣片，其特征在于：所述增溶剂为PEG-400和RH-40氢化麻油中的一种或两种。A super concentrated multifunctional laundry tablet according to claim 1, wherein the solubilizing agent is one or both of PEG-400 and RH-40 hydrogenated sesame oil.
  7. 一种超浓缩多功能洗衣片的制备方法，其特征在于，包括以下步骤：A method for preparing a super concentrated multifunctional laundry tablet, comprising the steps of:
    (1)将所述表面活性剂和茶皂素按照重量百分比加入到热水中进行混合并搅拌均匀形成混合物A；(1) The surfactant and tea saponin are added to hot water according to the weight percentage, mixed and stirred to form a mixture A;
    (2)按照原料的重量百分比称取原崩解剂、粘合剂和润滑剂加入到混合物A中搅拌均匀形成混合物B； (2) according to the weight percent of the raw material weighed the original disintegrant, binder and lubricant added to the mixture A and stirred to form a mixture B;
    (3)按照原料的重量百分比称取香氛油和增溶剂加入到步骤(2)中的混合物B中，进行增容分散处理形成混合物C；(3) According to the weight percentage of the raw material, the fragrance oil and the solubilizer are added to the mixture B in the step (2), and the compatibilization and dispersion treatment is carried out to form the mixture C;
    (4)对步骤(3)中的混合物C进行性能测试、沐膜烘干成型、切片、封装、检验和入库处理，得到所需超浓缩多功能洗衣片。(4) Perform the performance test, the film drying molding, the slicing, the encapsulation, the inspection and the warehousing treatment of the mixture C in the step (3) to obtain the desired super concentrated multifunctional laundry sheet.
  8. 根据权利要求7所述的一种超浓缩多功能洗衣片制备方法，其特征在于：步骤(1)中所述热水温度为60～100℃。 The method for preparing a super concentrated multifunctional laundry tablet according to claim 7, wherein the hot water temperature in the step (1) is 60 to 100 °C.
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