WO2017080357A8 - Application of aiegens doping with polymers: detection of glass transition temperatures and visualization of phase-separated morphology - Google Patents

Application of aiegens doping with polymers: detection of glass transition temperatures and visualization of phase-separated morphology Download PDF

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Publication number
WO2017080357A8
WO2017080357A8 PCT/CN2016/103149 CN2016103149W WO2017080357A8 WO 2017080357 A8 WO2017080357 A8 WO 2017080357A8 CN 2016103149 W CN2016103149 W CN 2016103149W WO 2017080357 A8 WO2017080357 A8 WO 2017080357A8
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WIPO (PCT)
Prior art keywords
glass transition
phase
transition temperatures
aiegens
visualization
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Application number
PCT/CN2016/103149
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French (fr)
Other versions
WO2017080357A1 (en
Inventor
Benzhong Tang
Zijie QIU
King Kei CHU
Ni XIE
Ting HAN
Jesse ROOSE
Chen GUI
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The Hong Kong University Of Science And Technology
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Application filed by The Hong Kong University Of Science And Technology filed Critical The Hong Kong University Of Science And Technology
Priority to CN201680065650.1A priority Critical patent/CN108291874B/en
Publication of WO2017080357A1 publication Critical patent/WO2017080357A1/en
Publication of WO2017080357A8 publication Critical patent/WO2017080357A8/en

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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64—Fluorescence; Phosphorescence
    • G01N21/645—Specially adapted constructive features of fluorimeters
    • G01N21/6456—Spatial resolved fluorescence measurements; Imaging
    • G01N21/6458—Fluorescence microscopy
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
    • C07F7/0816—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring said ring comprising Si as a ring atom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1003—Carbocyclic compounds
    • C09K2211/1007—Non-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1003—Carbocyclic compounds
    • C09K2211/1014—Carbocyclic compounds bridged by heteroatoms, e.g. N, P, Si or B
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1029—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1029—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom
    • C09K2211/1033—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom with oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1044—Heterocyclic compounds characterised by ligands containing two nitrogen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1096—Heterocyclic compounds characterised by ligands containing other heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14—Macromolecular compounds
    • C09K2211/1408—Carbocyclic compounds
    • C09K2211/1425—Non-condensed systems
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64—Fluorescence; Phosphorescence
    • G01N21/6428—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
    • G01N2021/6439—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes" with indicators, stains, dyes, tags, labels, marks

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Pathology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
  • Investigating Or Analyzing Materials Using Thermal Means (AREA)
  • Luminescent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Provided are a new detection method for glass transition temperatures of polymeric materials and a facile visualization method for the phase-separated morphology of polymer blends in spin-coated thin films by utilizing Aggregation-Induced Emission dyes as fluorescent probes. A prototype device for measurement of glass transition temperature is also designed and developed.
PCT/CN2016/103149 2015-11-10 2016-10-25 Detection of glass transition temperatures and visualization of phase-separated morphology WO2017080357A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201680065650.1A CN108291874B (en) 2015-11-10 2016-10-25 Aggregation-induced emission is applied to doped polymers: detection of glass transition temperature and visualization of phase separation morphology

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201562285826P 2015-11-10 2015-11-10
US62/285,826 2015-11-10
US201662494044P 2016-07-26 2016-07-26
US62/494,044 2016-07-26

Publications (2)

Publication Number Publication Date
WO2017080357A1 WO2017080357A1 (en) 2017-05-18
WO2017080357A8 true WO2017080357A8 (en) 2017-11-23

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2016/103149 WO2017080357A1 (en) 2015-11-10 2016-10-25 Detection of glass transition temperatures and visualization of phase-separated morphology

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CN (1) CN108291874B (en)
WO (1) WO2017080357A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107793652A (en) * 2017-11-23 2018-03-13 贵州理工学院 Thin polymer film with changing color resulting from acid and aggregation-induced emission performance and preparation method thereof
KR102513131B1 (en) 2018-09-18 2023-03-23 후지필름 가부시키가이샤 Composition, film, optical filter, solid-state imaging device, infrared sensor, optical filter manufacturing method, camera module, compound, and dispersion composition
CN109400519B (en) * 2018-11-21 2019-08-30 广东工业大学 A kind of tetraphenyl ethylene-benzophenone-carbazole derivates, crystal and the preparation method and application thereof
CN110143765A (en) * 2019-05-16 2019-08-20 辽宁师范大学 With the fluorescent silicon dioxide film and preparation method of the preparation of amphipathic AIE molecule
JP7407020B2 (en) * 2020-03-04 2023-12-28 株式会社日立ハイテクサイエンス Control unit of thermal analysis device and thermal analysis device
CN112816446B (en) * 2020-12-24 2022-02-01 四川长虹电器股份有限公司 Method for detecting powder decay of fluorescent wheel based on fluorescence spectrum
CN113571625B (en) * 2021-06-08 2022-09-30 广东省大湾区华南理工大学聚集诱导发光高等研究院 Aggregation-induced emission fluorescent powder packaged LED light source and preparation method thereof
RU2771440C1 (en) * 2021-07-14 2022-05-04 федеральное государственное автономное образовательное учреждение высшего образования "Казанский (Приволжский) федеральный университет" (ФГАОУ ВО КФУ) Method for detecting the glass transition temperature of nanoscale polymer materials and a thermo-plasmonic heater for implementing the method
CN114609102B (en) * 2022-03-09 2023-07-28 四川大学 Method for in-situ monitoring polymer film forming process by using fluorescent probe

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102516282B (en) * 2011-11-19 2014-09-17 浙江大学 Aldehyde-substituted active silole, and preparation method and application thereof
CN103558201B (en) * 2013-11-12 2015-07-22 中山大学 Method for sensitively detecting glass transition of polymer
CN104447582B (en) * 2014-10-24 2017-07-07 浙江大学 Tetraphernl pyrazine small molecule derivative, tetraphernl pyrazine polymer and gathering induced luminescence material

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Publication number Publication date
CN108291874A (en) 2018-07-17
WO2017080357A1 (en) 2017-05-18
CN108291874B (en) 2021-07-27

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