WO2017066973A1 - Formule de mélange maître de couleur - Google Patents

Formule de mélange maître de couleur Download PDF

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Publication number
WO2017066973A1
WO2017066973A1 PCT/CN2015/092607 CN2015092607W WO2017066973A1 WO 2017066973 A1 WO2017066973 A1 WO 2017066973A1 CN 2015092607 W CN2015092607 W CN 2015092607W WO 2017066973 A1 WO2017066973 A1 WO 2017066973A1
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WO
WIPO (PCT)
Prior art keywords
parts
masterbatch
masterbatch formulation
formulation according
red
Prior art date
Application number
PCT/CN2015/092607
Other languages
English (en)
Chinese (zh)
Inventor
陈少双
黄怀光
黄海灏
黄怀裕
黄麒翁
Original Assignee
揭东巴黎万株纱华纺织有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 揭东巴黎万株纱华纺织有限公司 filed Critical 揭东巴黎万株纱华纺织有限公司
Priority to PCT/CN2015/092607 priority Critical patent/WO2017066973A1/fr
Publication of WO2017066973A1 publication Critical patent/WO2017066973A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1545—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers

Definitions

  • the invention relates to the field of plastic coloring technology, in particular to the field of high-speed textile fiber coloring technology, in particular to a masterbatch formula.
  • Masterbatch is a new coloring product for plastics and fibers developed in the 1960s. It is a composite of polymers prepared by uniformly loading pigments into a resin.
  • the masterbatch is mainly composed of a colorant, a carrier and a dispersant.
  • the average annual demand growth rate of masterbatch in other countries in Asia is about 7%-9%, but the average annual demand growth rate of masterbatch in China is about 20%.
  • China is expected to become the fastest growing market for masterbatch demand. Especially in color and adding masterbatch, China depends on imports. China has become the largest producer and consumer of the masterbatch market in Asia. Experts believe that the future masterbatch will develop towards multi-functionality, high color content and high technology content.
  • Color masterbatch coloring is the most commonly used plastic coloring method. It is crushed by high-speed kneading machine, crushed, and extruded into granules. The masterbatch has high concentration, good dispersibility, cleanness, etc. during plastic processing. Significant advantage. However, many of the existing masterbatch are difficult to be mixed with the product in actual production, and the color of the product is not uniform after coloring, which does not meet the required requirements.
  • the object of the present invention is to overcome the defects in the prior art and to provide a masterbatch formulation, which can be easily mixed with PET plastics to achieve uniform coloration. Not only improved dispersion, Tinting strength, hiding power, and weather resistance, acid resistance, heat resistance and cold resistance and chemical stability of the pigment.
  • the present invention provides a masterbatch formulation, which is composed of the following components, the content of each component is in parts by weight: 20-80 parts of the carrier, 5-30 parts of the toner, 5 to 25 parts of a dispersing agent, 1 to 8 parts of a heat stabilizer, 1 to 8 parts of an antibacterial agent, 1 to 8 parts of an antioxidant, and 1 to 5 parts of an additive.
  • the carrier is a mixture carrier prepared from the following raw materials by weight: 10-20 parts of polyolefin, 8-15 parts of polyterephthalate, 5 ⁇ 15 of polyamide resin 15 copies.
  • the present invention adopts a mixed carrier to make a synergistic effect between the mixed carrier and the dispersant and the heat stabilizer, ensuring the stability of the material during processing and long-term outdoor use, and the mechanics of the material. Better performance, using color masterbatch to achieve uniform dispersion.
  • the antibacterial agent, the antioxidant and the additive are added in the invention, the anti-aging property of the masterbatch can be further strengthened, the antibacterial property of the masterbatch is improved, and the antibacterial and antibacterial effects are achieved.
  • the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
  • the toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
  • the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
  • the heat stabilizer is epoxy glyceride, epoxy fatty ester, calcium stearate or zinc stearate.
  • the antibacterial agent is chitosan, carboxymethyl chitosan or nano silver.
  • the antioxidant is one or more of tea polyphenols, phytic acid, tocopherols, and flavonoids.
  • the additive is a mixture of a benzotriazole-based ultraviolet absorber and a brightener, and the benzotriazole-based ultraviolet absorber and the brightener are mixed at a mass ratio of 1:1. .
  • the invention adopts a mixed carrier to make a synergistic effect between the mixed carrier and the dispersant and the heat stabilizer, ensuring the stability of the material during the processing and in the long-term outdoor use, and the mechanical properties of the material are better, and the color is used.
  • the masterbatch coloring achieves the effect of uniform dispersion.
  • the antibacterial agent, antioxidant and additive are added to the invention, and the masterbatch resistance can be further strengthened. Aging performance, improve the antibacterial properties of masterbatch, and achieve antibacterial and antibacterial effects.
  • the present invention uses a plurality of dispersing agents to combine various dispersing agents and mixed carriers to produce a synergistic effect, improve dispersibility, tinting strength, hiding power of the masterbatch, and has weather resistance and acid resistance. , heat resistance and cold resistance properties and maintain the chemical stability of the pigment.
  • the invention uses a natural antibacterial agent and a natural antioxidant to make the masterbatch more environmentally friendly and healthier during use.
  • the invention also adds an anti-ultraviolet absorption additive, which can reduce the temperature of the colored product when used outdoors, and further strengthen the anti-aging property.
  • a masterbatch formulation is composed of the following components, the content of each component is in parts by weight: carrier 20-80 parts, toner 5-30 parts, dispersing agent 5-25 parts, heat stable 1 to 8 parts of the agent, 1 to 8 parts of the antibacterial agent, 1 to 8 parts of the antioxidant, and 1 to 5 parts of the additive.
  • a masterbatch formulation consisting of the following components in parts by weight: carrier 20 parts, toner 5 parts, dispersant 5 parts, epoxy glyceride 1 part, shell 1 part of polysaccharide, 1 part of tea polyphenol, 1 part of benzotriazole ultraviolet absorber and 1 part of brightener.
  • the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 10 parts of polyolefin, 8 parts of polyterephthalate, and 5 parts of polyamide resin.
  • the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
  • the toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
  • the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
  • a masterbatch formulation consisting of the following components in parts by weight: 40 parts of carrier, 10 parts of toner, 10 parts of dispersant, 3 parts of epoxy fatty ester, carboxy 3 parts of methyl chitosan, 3 parts of phytic acid, 2 parts of benzotriazole ultraviolet absorber and 2 parts of brightener.
  • the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 13 parts of polyolefin, 10 parts of polyterephthalate, and 8 parts of polyamide resin.
  • the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
  • the toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
  • the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
  • a masterbatch formulation consisting of the following components in parts by weight: 60 parts of carrier, 20 parts of toner, 20 parts of dispersing agent, 6 parts of calcium stearate, nanometer 6 parts of silver, 6 parts of tocopherol, 4 parts of benzotriazole ultraviolet absorber and 4 parts of brightener.
  • the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 16 parts of polyolefin, 13 parts of polyterephthalate, and 12 parts of polyamide resin.
  • the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
  • the toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
  • the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
  • a masterbatch formulation consisting of the following components in parts by weight: 80 parts of carrier, 30 parts of toner, 25 parts of dispersing agent, 8 parts of zinc stearate, shell 8 parts of polysaccharide, 8 parts of flavonoids, 5 parts of benzotriazole ultraviolet absorber and 5 parts of brightener.
  • the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 20 parts of polyolefin, 15 parts of polyterephthalate, and 15 parts of polyamide resin.
  • the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
  • the toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
  • the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
  • the masterbatch formulation provided by the present invention produces a synergistic effect between the mixed carrier and the dispersant and the heat stabilizer, ensuring the stability of the material during processing and long-term outdoor use, and the mechanics of the material.
  • Better performance use color masterbatch to achieve uniform dispersion effect; use synergistic dispersant and mixed carrier to produce synergistic effect, improve the dispersibility, tinting strength and hiding power of masterbatch; at the same time, add antibacterial agent, antioxidant and The additive can further strengthen the anti-aging property of the masterbatch, improve the antibacterial property of the masterbatch, and achieve the antibacterial and antibacterial effects.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

La présente invention concerne le domaine technique de la coloration de plastique, et en particulier le domaine technique de la coloration de fibre textile à grande vitesse. L'invention décrit une formule de mélange maître de couleur. La formule de mélange maître de couleur est composée des constituants suivants, en parties en poids pour la teneur de chaque constituant : 20 à 50 parties d'un polytéréphtalate, 5 à 30 parties d'un toner, 5 à 25 parties d'un agent dispersant, 1 à 8 parties d'un stabilisant thermique, 1 à 8 parties d'un agent antibactérien, 1 à 8 parties d'un antioxydant et 1 à 5 parties d'un additif. Par rapport à un mélange maître de couleur existant, le mélange maître de couleur décrit par la présente invention peut être facilement mélangé à un produit plastique en PET, et permet d'obtenir un effet de coloration uniforme. Le mélange maître de couleur non seulement améliore la dispersibilité, le pouvoir colorant et le pouvoir couvrant, mais présente également des performances de résistance aux intempéries, de résistance aux acides, de résistance à la chaleur et de résistance au froid, et maintient la stabilité chimique d'un pigment.
PCT/CN2015/092607 2015-10-23 2015-10-23 Formule de mélange maître de couleur WO2017066973A1 (fr)

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Application Number Priority Date Filing Date Title
PCT/CN2015/092607 WO2017066973A1 (fr) 2015-10-23 2015-10-23 Formule de mélange maître de couleur

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Application Number Priority Date Filing Date Title
PCT/CN2015/092607 WO2017066973A1 (fr) 2015-10-23 2015-10-23 Formule de mélange maître de couleur

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110003556A (zh) * 2019-04-12 2019-07-12 南京运昶高分子材料有限公司 一种耐候母粒及其制备方法
CN110527287A (zh) * 2019-09-30 2019-12-03 华南理工大学 一种聚酰胺色母粒及其制备方法
CN110628186A (zh) * 2019-09-18 2019-12-31 苏州宝丽迪材料科技股份有限公司 纤维用高浓度彩色抗菌母粒的制备方法
CN112321855A (zh) * 2020-12-03 2021-02-05 上海金发科技发展有限公司 一种四元复配色母及其制备方法
CN112457681A (zh) * 2020-11-19 2021-03-09 南通鹏翼精密机械有限公司 一种抗老化专用色母粒配方
CN113402796A (zh) * 2021-06-15 2021-09-17 安徽缤飞塑胶科技有限公司 一种耐高温色母粒及其干燥装置
CN113881206A (zh) * 2021-10-15 2022-01-04 明新孟诺卡(江苏)新材料有限公司 一种具备天然抗菌功能色母粒及其制备工艺
CN114539773A (zh) * 2022-03-29 2022-05-27 苏州世祥生物纤维有限公司 一种长效抗菌耐高温原液着色母粒及其制备方法和应用
CN114685910A (zh) * 2022-03-18 2022-07-01 金发科技股份有限公司 着色剂、着色材料及制备方法
CN114806152A (zh) * 2022-03-15 2022-07-29 金发科技股份有限公司 一种玻纤增强用着色母粒及其制备方法和应用
CN115975287A (zh) * 2022-12-19 2023-04-18 深圳市泰科科技有限公司 一种增强型高耐候的色母粒及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103360670A (zh) * 2013-06-03 2013-10-23 广东波斯科技股份有限公司 一种通用高光黑色母
CN103709489A (zh) * 2012-09-29 2014-04-09 青岛欣展塑胶有限公司 一种通用白色母粒及其制备方法
US20150294752A1 (en) * 2014-04-15 2015-10-15 Enerage Inc. Graphene masterbatch

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103709489A (zh) * 2012-09-29 2014-04-09 青岛欣展塑胶有限公司 一种通用白色母粒及其制备方法
CN103360670A (zh) * 2013-06-03 2013-10-23 广东波斯科技股份有限公司 一种通用高光黑色母
US20150294752A1 (en) * 2014-04-15 2015-10-15 Enerage Inc. Graphene masterbatch

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110003556A (zh) * 2019-04-12 2019-07-12 南京运昶高分子材料有限公司 一种耐候母粒及其制备方法
CN110628186A (zh) * 2019-09-18 2019-12-31 苏州宝丽迪材料科技股份有限公司 纤维用高浓度彩色抗菌母粒的制备方法
CN110527287A (zh) * 2019-09-30 2019-12-03 华南理工大学 一种聚酰胺色母粒及其制备方法
CN112457681A (zh) * 2020-11-19 2021-03-09 南通鹏翼精密机械有限公司 一种抗老化专用色母粒配方
CN112321855B (zh) * 2020-12-03 2022-11-18 上海金发科技发展有限公司 一种四元复配色母及其制备方法
CN112321855A (zh) * 2020-12-03 2021-02-05 上海金发科技发展有限公司 一种四元复配色母及其制备方法
CN113402796A (zh) * 2021-06-15 2021-09-17 安徽缤飞塑胶科技有限公司 一种耐高温色母粒及其干燥装置
CN113881206A (zh) * 2021-10-15 2022-01-04 明新孟诺卡(江苏)新材料有限公司 一种具备天然抗菌功能色母粒及其制备工艺
CN114806152B (zh) * 2022-03-15 2023-05-05 金发科技股份有限公司 一种玻纤增强用着色母粒及其制备方法和应用
CN114806152A (zh) * 2022-03-15 2022-07-29 金发科技股份有限公司 一种玻纤增强用着色母粒及其制备方法和应用
CN114685910A (zh) * 2022-03-18 2022-07-01 金发科技股份有限公司 着色剂、着色材料及制备方法
CN114685910B (zh) * 2022-03-18 2024-02-23 金发科技股份有限公司 着色剂、着色材料及制备方法
CN114539773A (zh) * 2022-03-29 2022-05-27 苏州世祥生物纤维有限公司 一种长效抗菌耐高温原液着色母粒及其制备方法和应用
CN114539773B (zh) * 2022-03-29 2024-01-09 苏州世祥生物纤维有限公司 一种长效抗菌耐高温原液着色母粒及其制备方法和应用
CN115975287A (zh) * 2022-12-19 2023-04-18 深圳市泰科科技有限公司 一种增强型高耐候的色母粒及其制备方法
CN115975287B (zh) * 2022-12-19 2024-02-27 深圳市泰科科技有限公司 一种增强型高耐候的色母粒及其制备方法

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