WO2017066973A1 - Colour masterbatch formula - Google Patents

Colour masterbatch formula Download PDF

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Publication number
WO2017066973A1
WO2017066973A1 PCT/CN2015/092607 CN2015092607W WO2017066973A1 WO 2017066973 A1 WO2017066973 A1 WO 2017066973A1 CN 2015092607 W CN2015092607 W CN 2015092607W WO 2017066973 A1 WO2017066973 A1 WO 2017066973A1
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Prior art keywords
parts
masterbatch
masterbatch formulation
formulation according
red
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PCT/CN2015/092607
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French (fr)
Chinese (zh)
Inventor
陈少双
黄怀光
黄海灏
黄怀裕
黄麒翁
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揭东巴黎万株纱华纺织有限公司
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Priority to PCT/CN2015/092607 priority Critical patent/WO2017066973A1/en
Publication of WO2017066973A1 publication Critical patent/WO2017066973A1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1545—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers

Definitions

  • the invention relates to the field of plastic coloring technology, in particular to the field of high-speed textile fiber coloring technology, in particular to a masterbatch formula.
  • Masterbatch is a new coloring product for plastics and fibers developed in the 1960s. It is a composite of polymers prepared by uniformly loading pigments into a resin.
  • the masterbatch is mainly composed of a colorant, a carrier and a dispersant.
  • the average annual demand growth rate of masterbatch in other countries in Asia is about 7%-9%, but the average annual demand growth rate of masterbatch in China is about 20%.
  • China is expected to become the fastest growing market for masterbatch demand. Especially in color and adding masterbatch, China depends on imports. China has become the largest producer and consumer of the masterbatch market in Asia. Experts believe that the future masterbatch will develop towards multi-functionality, high color content and high technology content.
  • Color masterbatch coloring is the most commonly used plastic coloring method. It is crushed by high-speed kneading machine, crushed, and extruded into granules. The masterbatch has high concentration, good dispersibility, cleanness, etc. during plastic processing. Significant advantage. However, many of the existing masterbatch are difficult to be mixed with the product in actual production, and the color of the product is not uniform after coloring, which does not meet the required requirements.
  • the object of the present invention is to overcome the defects in the prior art and to provide a masterbatch formulation, which can be easily mixed with PET plastics to achieve uniform coloration. Not only improved dispersion, Tinting strength, hiding power, and weather resistance, acid resistance, heat resistance and cold resistance and chemical stability of the pigment.
  • the present invention provides a masterbatch formulation, which is composed of the following components, the content of each component is in parts by weight: 20-80 parts of the carrier, 5-30 parts of the toner, 5 to 25 parts of a dispersing agent, 1 to 8 parts of a heat stabilizer, 1 to 8 parts of an antibacterial agent, 1 to 8 parts of an antioxidant, and 1 to 5 parts of an additive.
  • the carrier is a mixture carrier prepared from the following raw materials by weight: 10-20 parts of polyolefin, 8-15 parts of polyterephthalate, 5 ⁇ 15 of polyamide resin 15 copies.
  • the present invention adopts a mixed carrier to make a synergistic effect between the mixed carrier and the dispersant and the heat stabilizer, ensuring the stability of the material during processing and long-term outdoor use, and the mechanics of the material. Better performance, using color masterbatch to achieve uniform dispersion.
  • the antibacterial agent, the antioxidant and the additive are added in the invention, the anti-aging property of the masterbatch can be further strengthened, the antibacterial property of the masterbatch is improved, and the antibacterial and antibacterial effects are achieved.
  • the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
  • the toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
  • the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
  • the heat stabilizer is epoxy glyceride, epoxy fatty ester, calcium stearate or zinc stearate.
  • the antibacterial agent is chitosan, carboxymethyl chitosan or nano silver.
  • the antioxidant is one or more of tea polyphenols, phytic acid, tocopherols, and flavonoids.
  • the additive is a mixture of a benzotriazole-based ultraviolet absorber and a brightener, and the benzotriazole-based ultraviolet absorber and the brightener are mixed at a mass ratio of 1:1. .
  • the invention adopts a mixed carrier to make a synergistic effect between the mixed carrier and the dispersant and the heat stabilizer, ensuring the stability of the material during the processing and in the long-term outdoor use, and the mechanical properties of the material are better, and the color is used.
  • the masterbatch coloring achieves the effect of uniform dispersion.
  • the antibacterial agent, antioxidant and additive are added to the invention, and the masterbatch resistance can be further strengthened. Aging performance, improve the antibacterial properties of masterbatch, and achieve antibacterial and antibacterial effects.
  • the present invention uses a plurality of dispersing agents to combine various dispersing agents and mixed carriers to produce a synergistic effect, improve dispersibility, tinting strength, hiding power of the masterbatch, and has weather resistance and acid resistance. , heat resistance and cold resistance properties and maintain the chemical stability of the pigment.
  • the invention uses a natural antibacterial agent and a natural antioxidant to make the masterbatch more environmentally friendly and healthier during use.
  • the invention also adds an anti-ultraviolet absorption additive, which can reduce the temperature of the colored product when used outdoors, and further strengthen the anti-aging property.
  • a masterbatch formulation is composed of the following components, the content of each component is in parts by weight: carrier 20-80 parts, toner 5-30 parts, dispersing agent 5-25 parts, heat stable 1 to 8 parts of the agent, 1 to 8 parts of the antibacterial agent, 1 to 8 parts of the antioxidant, and 1 to 5 parts of the additive.
  • a masterbatch formulation consisting of the following components in parts by weight: carrier 20 parts, toner 5 parts, dispersant 5 parts, epoxy glyceride 1 part, shell 1 part of polysaccharide, 1 part of tea polyphenol, 1 part of benzotriazole ultraviolet absorber and 1 part of brightener.
  • the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 10 parts of polyolefin, 8 parts of polyterephthalate, and 5 parts of polyamide resin.
  • the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
  • the toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
  • the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
  • a masterbatch formulation consisting of the following components in parts by weight: 40 parts of carrier, 10 parts of toner, 10 parts of dispersant, 3 parts of epoxy fatty ester, carboxy 3 parts of methyl chitosan, 3 parts of phytic acid, 2 parts of benzotriazole ultraviolet absorber and 2 parts of brightener.
  • the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 13 parts of polyolefin, 10 parts of polyterephthalate, and 8 parts of polyamide resin.
  • the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
  • the toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
  • the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
  • a masterbatch formulation consisting of the following components in parts by weight: 60 parts of carrier, 20 parts of toner, 20 parts of dispersing agent, 6 parts of calcium stearate, nanometer 6 parts of silver, 6 parts of tocopherol, 4 parts of benzotriazole ultraviolet absorber and 4 parts of brightener.
  • the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 16 parts of polyolefin, 13 parts of polyterephthalate, and 12 parts of polyamide resin.
  • the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
  • the toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
  • the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
  • a masterbatch formulation consisting of the following components in parts by weight: 80 parts of carrier, 30 parts of toner, 25 parts of dispersing agent, 8 parts of zinc stearate, shell 8 parts of polysaccharide, 8 parts of flavonoids, 5 parts of benzotriazole ultraviolet absorber and 5 parts of brightener.
  • the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 20 parts of polyolefin, 15 parts of polyterephthalate, and 15 parts of polyamide resin.
  • the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
  • the toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
  • the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
  • the masterbatch formulation provided by the present invention produces a synergistic effect between the mixed carrier and the dispersant and the heat stabilizer, ensuring the stability of the material during processing and long-term outdoor use, and the mechanics of the material.
  • Better performance use color masterbatch to achieve uniform dispersion effect; use synergistic dispersant and mixed carrier to produce synergistic effect, improve the dispersibility, tinting strength and hiding power of masterbatch; at the same time, add antibacterial agent, antioxidant and The additive can further strengthen the anti-aging property of the masterbatch, improve the antibacterial property of the masterbatch, and achieve the antibacterial and antibacterial effects.

Abstract

The present invention relates to the technical field of plastic colouration, and in particular to the technical field of high-speed textile fibre colouration. Disclosed is a colour masterbatch formula. The colour masterbatch formula is composed of the following components, in parts by weight for the content of each component: 20-50 parts of a polyterephthalate, 5-30 parts of a toner, 5-25 parts of a dispersing agent, 1-8 parts of a heat stabilizer, 1-8 parts of an antibacterial agent, 1-8 parts of an antioxidant and 1-5 parts of an additive. Compared with an existing colour masterbatch, the colour masterbatch disclosed by the present invention can be easily mixed with PET product plastics, and obtain the uniform colouring effect. The colour masterbatch not only improves the dispersibility, tinting strength and covering power, but also has performances of weather resistance, acid resistance, heat resistance and cold resistance, and keeps the chemical stability of a pigment.

Description

一种色母粒配方Masterbatch formula 技术领域Technical field
本发明涉及塑料着色技术领域，尤其是高速纺织纤维着色技术领域，具体涉及一种色母粒配方。The invention relates to the field of plastic coloring technology, in particular to the field of high-speed textile fiber coloring technology, in particular to a masterbatch formula.
背景技术Background technique
色母粒是20世纪60年代开发的一种塑料、纤维的着色新产品，它是把颜料超常量均匀的载附于树脂中而制得的聚合物的复合物。色母粒主要组成为着色剂、载体、分散剂三部分。Masterbatch is a new coloring product for plastics and fibers developed in the 1960s. It is a composite of polymers prepared by uniformly loading pigments into a resin. The masterbatch is mainly composed of a colorant, a carrier and a dispersant.
据相关资料获悉，亚洲地区的其他国家对色母粒的年均需求增长率约7％－9％，可我国对色母粒的年均需求增长率为20％左右。预计中国将成为色母粒需求量增长最快的市场。特别是彩色和添加母粒，我国要依赖进口。我国已成了亚洲地区色母粒市场的最大生产国和消耗国。有关专家认为，未来色母粒将朝着多功能化、高颜色含量和高技术含量方向发展。According to relevant information, the average annual demand growth rate of masterbatch in other countries in Asia is about 7%-9%, but the average annual demand growth rate of masterbatch in China is about 20%. China is expected to become the fastest growing market for masterbatch demand. Especially in color and adding masterbatch, China depends on imports. China has become the largest producer and consumer of the masterbatch market in Asia. Experts believe that the future masterbatch will develop towards multi-functionality, high color content and high technology content.
而且普通尼龙母粒添加到尼龙原料中，无法保证材料在加工中和户外使用中的稳定性，一般都会降低材料的力学性能，从而降低产品的设计和使用寿命。Moreover, the addition of ordinary nylon masterbatch to the nylon raw material cannot guarantee the stability of the material during processing and outdoor use, and generally reduces the mechanical properties of the material, thereby reducing the design and service life of the product.
在现有的色母粒制造过程中，需要应用到比较多的钛的化合物，而钛是一个非常重要的战略资源，在制作过程中，由于钛具有极其高的硬度，会对机器产生极大的磨损，而且制造出来的色母粒，在等量的情况下要实现分散性、着色力、遮盖力、耐候性、耐酸性、耐热性和耐寒性的性能，需要花费非常大的成本。In the existing masterbatch manufacturing process, it is necessary to apply a relatively large amount of titanium compound, and titanium is a very important strategic resource. In the production process, due to the extremely high hardness of titanium, it will be extremely great for the machine. The wear and the resulting masterbatch require a very large cost to achieve dispersibility, tinting strength, hiding power, weather resistance, acid resistance, heat resistance and cold resistance in an equal amount.
色母粒着色是现今最普遍采用的塑料着色法，通过高速混练机混炼后，破碎，挤出拉成粒，色母粒在塑料加工过程中，具有浓度高、分散性好、清洁等显著优点。但是，现有的很多色母粒运用到实际生产中却难以与制品混合，制品着色后颜色不均匀，达不到所需要的要求。Color masterbatch coloring is the most commonly used plastic coloring method. It is crushed by high-speed kneading machine, crushed, and extruded into granules. The masterbatch has high concentration, good dispersibility, cleanness, etc. during plastic processing. Significant advantage. However, many of the existing masterbatch are difficult to be mixed with the product in actual production, and the color of the product is not uniform after coloring, which does not meet the required requirements.
发明内容Summary of the invention
本发明的目的在于克服现有技术中的缺陷，提供一种色母粒配方，公开的色母粒能够与PET制品塑料容易混合，达到着色均匀的效果。不仅提高了分散性、 着色力、遮盖力，而且具有耐候性、耐酸性、耐热性和耐寒性的性能和保持颜料的化学稳定性。The object of the present invention is to overcome the defects in the prior art and to provide a masterbatch formulation, which can be easily mixed with PET plastics to achieve uniform coloration. Not only improved dispersion, Tinting strength, hiding power, and weather resistance, acid resistance, heat resistance and cold resistance and chemical stability of the pigment.
为了实现上述目的，本发明提供的一种色母粒配方，该色母粒配方由以下组分构成，各组分含量按重量份数计：载体20～80份，色粉5～30份，分散剂5～25份，热稳定剂1～8份，抗菌剂1～8份，抗氧化剂1～8份，添加剂1～5份。In order to achieve the above object, the present invention provides a masterbatch formulation, which is composed of the following components, the content of each component is in parts by weight: 20-80 parts of the carrier, 5-30 parts of the toner, 5 to 25 parts of a dispersing agent, 1 to 8 parts of a heat stabilizer, 1 to 8 parts of an antibacterial agent, 1 to 8 parts of an antioxidant, and 1 to 5 parts of an additive.
进一步的，所述的载体为混合物载体，该混合物载体由按重量份数计的以下原料制备而成：聚烯烃10～20份，聚对苯二甲酸脂8～15份，聚酰胺树脂5～15份。与现有色母粒相比，本发明采用混合型载体，使混合载体与分散剂、热稳定剂产生协同效应，确保材料在加工过程中和在户外长期使用中都能保证稳定性，材料的力学性能更佳，使用色母粒着色达到均匀分散的效果。同时，本发明中加入了抗菌剂、抗氧化剂和添加剂，可以进一步强化色母粒抗老化性能，提高色母粒的抗菌性能，达到抗菌、抑菌的作用。Further, the carrier is a mixture carrier prepared from the following raw materials by weight: 10-20 parts of polyolefin, 8-15 parts of polyterephthalate, 5~15 of polyamide resin 15 copies. Compared with the existing masterbatch, the present invention adopts a mixed carrier to make a synergistic effect between the mixed carrier and the dispersant and the heat stabilizer, ensuring the stability of the material during processing and long-term outdoor use, and the mechanics of the material. Better performance, using color masterbatch to achieve uniform dispersion. At the same time, the antibacterial agent, the antioxidant and the additive are added in the invention, the anti-aging property of the masterbatch can be further strengthened, the antibacterial property of the masterbatch is improved, and the antibacterial and antibacterial effects are achieved.
优选的，所述的聚对苯二甲酸脂为聚对苯二甲酸乙二酯、聚对苯二甲酸丁二酯或聚对苯二甲酸乙二醇酯。Preferably, the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
优选的，所述的色粉为酞菁红、酞菁蓝、酞菁绿、耐晒大红、大分子红、大分子黄、永固黄、永固紫、偶氮红中的一种。Preferably, the toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
优选的，所述的分散剂为聚乙烯蜡、乙烯-醋酸乙烯蜡、乙撑双硬酯酰胺、季戊四醇硬脂酸酯中的任意两种。Preferably, the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
优选的，所述的热稳定剂为环氧甘油酯、环氧脂肪酯、硬脂酸钙或硬脂酸锌。Preferably, the heat stabilizer is epoxy glyceride, epoxy fatty ester, calcium stearate or zinc stearate.
优选的，所述的抗菌剂为壳聚糖、羧甲基壳聚糖或纳米银。Preferably, the antibacterial agent is chitosan, carboxymethyl chitosan or nano silver.
优选的，所述的抗氧化剂为茶多酚、植酸、生育酚、黄酮类物质中的一种或几种。Preferably, the antioxidant is one or more of tea polyphenols, phytic acid, tocopherols, and flavonoids.
优选的，所述的添加剂为苯并***类紫外线吸收剂和增亮剂的混合物，苯并***类紫外线吸收剂和增亮剂按质量比为1:1混合。。Preferably, the additive is a mixture of a benzotriazole-based ultraviolet absorber and a brightener, and the benzotriazole-based ultraviolet absorber and the brightener are mixed at a mass ratio of 1:1. .
本发明的有益效果：The beneficial effects of the invention:
1、本发明采用混合型载体，使混合载体与分散剂、热稳定剂产生协同效应，确保材料在加工过程中和在户外长期使用中都能保证稳定性，材料的力学性能更佳，使用色母粒着色达到均匀分散的效果。1. The invention adopts a mixed carrier to make a synergistic effect between the mixed carrier and the dispersant and the heat stabilizer, ensuring the stability of the material during the processing and in the long-term outdoor use, and the mechanical properties of the material are better, and the color is used. The masterbatch coloring achieves the effect of uniform dispersion.
2、本发明中加入了抗菌剂、抗氧化剂和添加剂，可以进一步强化色母粒抗 老化性能，提高色母粒的抗菌性能，达到抗菌、抑菌的作用。2. The antibacterial agent, antioxidant and additive are added to the invention, and the masterbatch resistance can be further strengthened. Aging performance, improve the antibacterial properties of masterbatch, and achieve antibacterial and antibacterial effects.
3、本发明使用多种分散剂的复配，使各种分散剂和混合载体结合使用，产生协同效果，提高了色母粒的分散性、着色力、遮盖力，而且具有耐候性、耐酸性、耐热性和耐寒性的性能和保持颜料的化学稳定性。3. The present invention uses a plurality of dispersing agents to combine various dispersing agents and mixed carriers to produce a synergistic effect, improve dispersibility, tinting strength, hiding power of the masterbatch, and has weather resistance and acid resistance. , heat resistance and cold resistance properties and maintain the chemical stability of the pigment.
4、本发明使用天然的抗菌剂和天然抗氧化剂，使色母粒在使用过程中更环保、更健康。4. The invention uses a natural antibacterial agent and a natural antioxidant to make the masterbatch more environmentally friendly and healthier during use.
5、本发明同时添加了抗紫外吸收添加剂，可以降低着色制品在户外使用时的温度，进一步强化其抗老化性能。5. The invention also adds an anti-ultraviolet absorption additive, which can reduce the temperature of the colored product when used outdoors, and further strengthen the anti-aging property.
具体实施方式detailed description
以下对本发明的实施方式作详细说明。应该强调的是，下述说明仅仅是示例性的，而不是为了限制本发明的范围及其应用。Embodiments of the invention are described in detail below. It is to be understood that the following description is only illustrative, and is not intended to limit the scope of the invention.
一种色母粒配方，该色母粒配方由以下组分构成，各组分含量按重量份数计：载体20～80份，色粉5～30份，分散剂5～25份，热稳定剂1～8份，抗菌剂1～8份，抗氧化剂1～8份，添加剂1～5份。A masterbatch formulation, the masterbatch formulation is composed of the following components, the content of each component is in parts by weight: carrier 20-80 parts, toner 5-30 parts, dispersing agent 5-25 parts, heat stable 1 to 8 parts of the agent, 1 to 8 parts of the antibacterial agent, 1 to 8 parts of the antioxidant, and 1 to 5 parts of the additive.
实施例1Example 1
一种色母粒配方，该色母粒配方由以下组分构成，各组分含量按重量份数计：载体20份，色粉5份，分散剂5份，环氧甘油酯1份，壳聚糖1份，茶多酚1份，苯并***类紫外线吸收剂1份和增亮剂1份。A masterbatch formulation consisting of the following components in parts by weight: carrier 20 parts, toner 5 parts, dispersant 5 parts, epoxy glyceride 1 part, shell 1 part of polysaccharide, 1 part of tea polyphenol, 1 part of benzotriazole ultraviolet absorber and 1 part of brightener.
其中，载体为混合物载体，该混合物载体由按重量份数计的以下原料制备而成：聚烯烃10份，聚对苯二甲酸脂8份，聚酰胺树脂5份。所述的聚对苯二甲酸脂为聚对苯二甲酸乙二酯、聚对苯二甲酸丁二酯或聚对苯二甲酸乙二醇酯。Wherein the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 10 parts of polyolefin, 8 parts of polyterephthalate, and 5 parts of polyamide resin. The polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
所述的色粉为酞菁红、酞菁蓝、酞菁绿、耐晒大红、大分子红、大分子黄、永固黄、永固紫、偶氮红中的一种。The toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
所述的分散剂为聚乙烯蜡、乙烯-醋酸乙烯蜡、乙撑双硬酯酰胺、季戊四醇硬脂酸酯中的任意两种。The dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
实施例2Example 2
一种色母粒配方，该色母粒配方由以下组分构成，各组分含量按重量份数计：载体40份，色粉10份，分散剂10份，环氧脂肪酯3份，羧甲基壳聚糖3份，植酸3份，苯并***类紫外线吸收剂2份和增亮剂2份。 A masterbatch formulation consisting of the following components in parts by weight: 40 parts of carrier, 10 parts of toner, 10 parts of dispersant, 3 parts of epoxy fatty ester, carboxy 3 parts of methyl chitosan, 3 parts of phytic acid, 2 parts of benzotriazole ultraviolet absorber and 2 parts of brightener.
其中，载体为混合物载体，该混合物载体由按重量份数计的以下原料制备而成：聚烯烃13份，聚对苯二甲酸脂10份，聚酰胺树脂8份。所述的聚对苯二甲酸脂为聚对苯二甲酸乙二酯、聚对苯二甲酸丁二酯或聚对苯二甲酸乙二醇酯。Wherein the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 13 parts of polyolefin, 10 parts of polyterephthalate, and 8 parts of polyamide resin. The polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
所述的色粉为酞菁红、酞菁蓝、酞菁绿、耐晒大红、大分子红、大分子黄、永固黄、永固紫、偶氮红中的一种。The toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
所述的分散剂为聚乙烯蜡、乙烯-醋酸乙烯蜡、乙撑双硬酯酰胺、季戊四醇硬脂酸酯中的任意两种。The dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
实施例3Example 3
一种色母粒配方，该色母粒配方由以下组分构成，各组分含量按重量份数计：载体60份，色粉20份，分散剂20份，硬脂酸钙6份，纳米银6份，生育酚6份，苯并***类紫外线吸收剂4份和增亮剂4份。A masterbatch formulation consisting of the following components in parts by weight: 60 parts of carrier, 20 parts of toner, 20 parts of dispersing agent, 6 parts of calcium stearate, nanometer 6 parts of silver, 6 parts of tocopherol, 4 parts of benzotriazole ultraviolet absorber and 4 parts of brightener.
其中，载体为混合物载体，该混合物载体由按重量份数计的以下原料制备而成：聚烯烃16份，聚对苯二甲酸脂13份，聚酰胺树脂12份。所述的聚对苯二甲酸脂为聚对苯二甲酸乙二酯、聚对苯二甲酸丁二酯或聚对苯二甲酸乙二醇酯。Wherein the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 16 parts of polyolefin, 13 parts of polyterephthalate, and 12 parts of polyamide resin. The polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
所述的色粉为酞菁红、酞菁蓝、酞菁绿、耐晒大红、大分子红、大分子黄、永固黄、永固紫、偶氮红中的一种。The toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
所述的分散剂为聚乙烯蜡、乙烯-醋酸乙烯蜡、乙撑双硬酯酰胺、季戊四醇硬脂酸酯中的任意两种。The dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
实施例4Example 4
一种色母粒配方，该色母粒配方由以下组分构成，各组分含量按重量份数计：载体80份，色粉30份，分散剂25份，硬脂酸锌8份，壳聚糖8份，黄酮类物质8份，苯并***类紫外线吸收剂5份和增亮剂5份。A masterbatch formulation consisting of the following components in parts by weight: 80 parts of carrier, 30 parts of toner, 25 parts of dispersing agent, 8 parts of zinc stearate, shell 8 parts of polysaccharide, 8 parts of flavonoids, 5 parts of benzotriazole ultraviolet absorber and 5 parts of brightener.
其中，载体为混合物载体，该混合物载体由按重量份数计的以下原料制备而成：聚烯烃20份，聚对苯二甲酸脂15份，聚酰胺树脂15份。所述的聚对苯二甲酸脂为聚对苯二甲酸乙二酯、聚对苯二甲酸丁二酯或聚对苯二甲酸乙二醇酯。Wherein the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 20 parts of polyolefin, 15 parts of polyterephthalate, and 15 parts of polyamide resin. The polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate.
所述的色粉为酞菁红、酞菁蓝、酞菁绿、耐晒大红、大分子红、大分子黄、永固黄、永固紫、偶氮红中的一种。The toner is one of phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent yellow, permanent violet, and azo red.
所述的分散剂为聚乙烯蜡、乙烯-醋酸乙烯蜡、乙撑双硬酯酰胺、季戊四醇硬脂酸酯中的任意两种。 The dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearyl amide, and pentaerythritol stearate.
为验证本发明色母粒配方是否达到预期的发明效果，对本发明色母粒配方进行性能试验分析，结果如下所示：In order to verify whether the masterbatch formulation of the present invention achieves the intended effect of the invention, the performance test of the masterbatch formulation of the present invention is carried out, and the results are as follows:
Figure PCTCN2015092607-appb-000001
Figure PCTCN2015092607-appb-000001
从上表可以看出，本发明提供的色母粒配方使混合载体与分散剂、热稳定剂产生协同效应，确保材料在加工过程中和在户外长期使用中都能保证稳定性，材料的力学性能更佳，使用色母粒着色达到均匀分散的效果；使用复配分散剂和混合载体产生协同效果，提高了色母粒的分散性、着色力、遮盖力；同时，加入抗菌剂、抗氧化剂和添加剂，可以进一步强化色母粒抗老化性能，提高色母粒的抗菌性能，达到抗菌、抑菌的作用。As can be seen from the above table, the masterbatch formulation provided by the present invention produces a synergistic effect between the mixed carrier and the dispersant and the heat stabilizer, ensuring the stability of the material during processing and long-term outdoor use, and the mechanics of the material. Better performance, use color masterbatch to achieve uniform dispersion effect; use synergistic dispersant and mixed carrier to produce synergistic effect, improve the dispersibility, tinting strength and hiding power of masterbatch; at the same time, add antibacterial agent, antioxidant and The additive can further strengthen the anti-aging property of the masterbatch, improve the antibacterial property of the masterbatch, and achieve the antibacterial and antibacterial effects.
最后应说明的是：显然，上述实施例仅仅是为清楚地说明本发明所作的举例，而并非对实施方式的限定。对于所属领域的普通技术人员来说，在上述说明的基础上还可以做出其它不同形式的变化或变动。这里无需也无法对所有的实施方式予以穷举。而由此所引申出的显而易见的变化或变动仍处于本发明的保护范围之中。 It should be noted that the above-described embodiments are merely illustrative of the invention and are not intended to limit the embodiments. Other variations or modifications of the various forms may be made by those skilled in the art in light of the above description. There is no need and no way to exhaust all of the implementations. Obvious changes or variations resulting therefrom are still within the scope of the invention.

Claims (9)

  1. 一种色母粒配方，其特征在于，该色母粒配方由以下组分构成，各组分含量按重量份数计：载体20～80份，色粉5～30份，分散剂5～25份，热稳定剂1～8份，抗菌剂1～8份，抗氧化剂1～8份，添加剂1～5份。A masterbatch formulation, characterized in that the masterbatch formulation is composed of the following components, the content of each component is in parts by weight: carrier 20-80 parts, toner 5-30 parts, dispersing agent 5-25 Parts, heat stabilizer 1 to 8 parts, antibacterial agent 1 to 8 parts, antioxidant 1 to 8 parts, and additives 1 to 5 parts.
  2. 根据权利要求1所述的一种色母粒配方，其特征在于，所述的载体为混合物载体，该混合物载体由按重量份数计的以下原料制备而成：聚烯烃10～20份，聚对苯二甲酸脂8～15份，聚酰胺树脂5～15份。A masterbatch formulation according to claim 1, wherein the carrier is a mixture carrier prepared from the following raw materials in parts by weight: 10-20 parts of polyolefin, polymerized 8 to 15 parts of terephthalic acid ester and 5 to 15 parts of polyamide resin.
  3. 根据权利要求2所述的一种色母粒配方，其特征在于，所述的聚对苯二甲酸脂为聚对苯二甲酸乙二酯、聚对苯二甲酸丁二酯或聚对苯二甲酸乙二醇酯。A masterbatch formulation according to claim 2, wherein the polyterephthalate is polyethylene terephthalate, polybutylene terephthalate or poly(p-phenylene terephthalate). Ethylene glycolate.
  4. 根据权利要求1所述的一种色母粒配方，其特征在于，所述的色粉为酞菁红、酞菁蓝、酞菁绿、耐晒大红、大分子红、大分子黄、永固黄、永固紫、偶氮红中的一种。The masterbatch formulation according to claim 1, wherein the toner is phthalocyanine red, phthalocyanine blue, phthalocyanine green, light fast red, macromolecular red, macromolecular yellow, permanent One of yellow, permanent solid purple, and azo red.
  5. 根据权利要求1所述的一种色母粒配方，其特征在于，所述的分散剂为聚乙烯蜡、乙烯-醋酸乙烯蜡、乙撑双硬酯酰胺、季戊四醇硬脂酸酯中的任意两种。The masterbatch formulation according to claim 1, wherein the dispersing agent is any one of polyethylene wax, ethylene-vinyl acetate wax, ethylene bis-stearate, and pentaerythritol stearate. Kind.
  6. 根据权利要求1所述的一种色母粒配方，其特征在于，所述的热稳定剂为环氧甘油酯、环氧脂肪酯、硬脂酸钙或硬脂酸锌。A masterbatch formulation according to claim 1 wherein the heat stabilizer is an epoxy glyceride, an epoxy fatty ester, calcium stearate or zinc stearate.
  7. 根据权利要求1所述的一种色母粒配方，其特征在于，所述的抗菌剂为壳聚糖、羧甲基壳聚糖或纳米银。A masterbatch formulation according to claim 1, wherein the antibacterial agent is chitosan, carboxymethyl chitosan or nanosilver.
  8. 根据权利要求1所述的一种色母粒配方，其特征在于，所述的抗氧化剂为茶多酚、植酸、生育酚、黄酮类物质中的一种或几种。The masterbatch formulation according to claim 1, wherein the antioxidant is one or more of tea polyphenols, phytic acid, tocopherols, and flavonoids.
  9. 根据权利要求1所述的一种色母粒配方，其特征在于，所述的添加剂为苯并***类紫外线吸收剂和增亮剂的混合物，苯并***类紫外线吸收剂和增亮剂按质量比为1:1混合。 A masterbatch formulation according to claim 1, wherein said additive is a mixture of a benzotriazole-based ultraviolet absorber and a brightener, a benzotriazole-based ultraviolet absorber and a brightener. Mix by mass ratio of 1:1.
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CN112457681A (en) * 2020-11-19 2021-03-09 南通鹏翼精密机械有限公司 Special color master batch formula for aging resistance
CN113402796A (en) * 2021-06-15 2021-09-17 安徽缤飞塑胶科技有限公司 High temperature resistant masterbatch and drying device thereof
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CN110003556A (en) * 2019-04-12 2019-07-12 南京运昶高分子材料有限公司 A kind of weatherable master batch and preparation method thereof
CN110628186A (en) * 2019-09-18 2019-12-31 苏州宝丽迪材料科技股份有限公司 Preparation method of high-concentration colored antibacterial master batch for fibers
CN110527287A (en) * 2019-09-30 2019-12-03 华南理工大学 A kind of polyamide Masterbatch and preparation method thereof
CN112457681A (en) * 2020-11-19 2021-03-09 南通鹏翼精密机械有限公司 Special color master batch formula for aging resistance
CN112321855B (en) * 2020-12-03 2022-11-18 上海金发科技发展有限公司 Quaternary compound color master batch and preparation method thereof
CN112321855A (en) * 2020-12-03 2021-02-05 上海金发科技发展有限公司 Quaternary compound color master batch and preparation method thereof
CN113402796A (en) * 2021-06-15 2021-09-17 安徽缤飞塑胶科技有限公司 High temperature resistant masterbatch and drying device thereof
CN113881206A (en) * 2021-10-15 2022-01-04 明新孟诺卡(江苏)新材料有限公司 Color master batch with natural antibacterial function and preparation process thereof
CN114806152B (en) * 2022-03-15 2023-05-05 金发科技股份有限公司 Coloring master batch for glass fiber reinforcement and preparation method and application thereof
CN114806152A (en) * 2022-03-15 2022-07-29 金发科技股份有限公司 Coloring master batch for glass fiber reinforcement and preparation method and application thereof
CN114685910A (en) * 2022-03-18 2022-07-01 金发科技股份有限公司 Coloring agent, coloring material and preparation method
CN114685910B (en) * 2022-03-18 2024-02-23 金发科技股份有限公司 Colorant, coloring material and preparation method
CN114539773A (en) * 2022-03-29 2022-05-27 苏州世祥生物纤维有限公司 Long-acting antibacterial high-temperature-resistant stock solution coloring master batch and preparation method and application thereof
CN114539773B (en) * 2022-03-29 2024-01-09 苏州世祥生物纤维有限公司 Long-acting antibacterial high-temperature-resistant stock solution coloring master batch and preparation method and application thereof
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