WO2017033470A1 - Additive composition for manufacturing new water and oil mixture fuel - Google Patents

Additive composition for manufacturing new water and oil mixture fuel Download PDF

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Publication number
WO2017033470A1
WO2017033470A1 PCT/JP2016/053209 JP2016053209W WO2017033470A1 WO 2017033470 A1 WO2017033470 A1 WO 2017033470A1 JP 2016053209 W JP2016053209 W JP 2016053209W WO 2017033470 A1 WO2017033470 A1 WO 2017033470A1
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component
oil
water
fuel
additive composition
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PCT/JP2016/053209
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French (fr)
Japanese (ja)
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純一 松尾
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株式会社ワールドビジネス
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Priority to SG11201604951WA priority Critical patent/SG11201604951WA/en
Priority to PH12016501231A priority patent/PH12016501231A1/en
Publication of WO2017033470A1 publication Critical patent/WO2017033470A1/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions

Definitions

  • the present invention relates to an additive composition for producing a water / oil mixed new fuel having a large total calorific value and a small specific gravity.
  • Patent Document 1 describes an apparatus for producing emulsion fuel by mixing water and an emulsifier with fuel oil.
  • Patent Document 2 describes an emulsion fuel oil obtained by mixing vegetable waste cooking oil and shochu liquor at a volume ratio of approximately 1: 1.
  • an apparatus has been developed for mixing fuel and water well at the finest possible level (eg, fine particle level) without using additives such as emulsifiers.
  • Patent Document 3 discloses a first injection unit that injects fuel oil or a mixed oil of fuel oil and water, a second injection unit that injects water, and a liquid that is positively injected from the first injection unit.
  • a direct current high voltage generator for applying a potential and applying a negative high potential to the water injected from the second injection unit, and generated by collision of the injected fuel oil or mixed oil and the injected water
  • a mixed oil processing unit that receives the mixed oil and delivers the mixed oil to the first injection unit.
  • Patent Document 4 includes a water softening unit that softens water to be mixed, a pure water purification unit that purifies soft water from the water softening unit, and pure water from the pure water purification unit.
  • the water ionization unit that negatively ionizes by the liquid magnetic processing device, the oil ionization unit that positively ionizes the oil to be mixed by the second liquid magnetic processing device, and the positive ionized oil from the oil ionization unit A potential applying portion for applying a potential, and spraying with the oil from the potential applying portion charged to a positive potential and spraying while charging the water from the water ionization portion to a negative potential and crossing these sprays.
  • Describes a microemulsion generator characterized by comprising a mixing section for mixing so that the liquid mixture becomes a microemulsion state.
  • the water-oil mixed fuel described in Patent Documents 1 and 2 has a milky white color, and has a problem that it does not look like fuel oil. There is also a problem that the total calorific value (calories) is small and the specific gravity is increased by the amount of water added.
  • the new fuel generators described in Patent Documents 3 to 4 are excellent in versatility, the composition of the additive used has not been optimized.
  • an object of the present invention is to provide an additive composition for producing a new water / oil mixed fuel that is transparent in appearance and has a large total calorific value and a small specific gravity.
  • the present invention Component (a): castor oil or olive oil; Component (b): a nonionic surfactant having an HLB of 8.0 to 15.5, Component (c): containing carbon,
  • the content of component (a) is 3 to 10% by weight, the content of component (b) is 3 to 10% by weight, and the content of component (c) is 20 to 40% by weight. It is an additive composition for water-oil mixed new fuel production.
  • Component (a) castor oil or olive oil
  • Component (b) a nonionic surfactant having an HLB of 8.0 to 15.5
  • Component (c) carbon
  • Component (d) An additive composition for producing a water / oil mixed new fuel containing a detergent having a surface tension at 25 ° C. of 25 to 70 dyne / cm.
  • Component (a) castor oil or olive oil
  • Component (b) a nonionic surfactant having an HLB of 8.0 to 15.5
  • Component (c) An additive composition for producing a new water / oil mixed fuel containing porous carbon having an average particle size of 10 to 70 ⁇ m.
  • an additive composition for producing a new water-oil mixed fuel that is transparent in appearance and has a large total calorific value and a small specific gravity.
  • the additive composition for producing a new fuel oil-mixed fuel comprises a nonionic interface having a castor oil or olive oil (component (a)) and an HLB of 8.0 to 15.5 in a hydrocarbon solvent.
  • An activator (component (b)) and carbon (component (c)) are contained.
  • Such an additive composition for producing a new water / oil mixed fuel is useful for producing a new water / oil mixed fuel having a transparent appearance and a large total calorific value and a small specific gravity.
  • the component (a) castor oil or olive oil is used. By containing the component (a), heat and solubility are improved. From the viewpoint of further improving the heat and solubility of the carbon chain length due to the difference in substituents, the component (a) is preferably castor oil.
  • a nonionic surfactant (nonionic surfactant) having an HLB of 8.0 to 15.5 is used.
  • the nonionic surfactant include ester type nonionic surfactants such as glyceryl laurate, glyceryl monostearate, sorbitan fatty acid ester, and sucrose fatty acid ester; polyoxyethylene alkyl ether, pentaethylene glycol monododecyl ether , Ether-type nonionic surfactants such as octaethylene glycol monododecyl ether, polyoxyethylene alkylphenyl ether, octylphenol ethoxylate, nonylphenol ethoxylate, polyoxyethylene polyoxypropylene glycol; polyoxyethylene sorbitan fatty acid ester, polyoxyethylene Ester ether type nonionic surface activity such as hexitan fatty acid
  • HLB is a value representing the degree of affinity of a surfactant with water and oil. It takes a value of 0 to 20, and the closer to 0, the higher the lipophilicity, and the closer to 20, the higher the hydrophilicity. To do.
  • the HLB can be calculated by the Griffin method, for example.
  • a nonionic surfactant having an HLB of 8.0 to 15.5 as the component (b)
  • the HLB of the nonionic surfactant as the component (b) is preferably 9.0 to 14.2, and more preferably 10.8 to 13.2.
  • Carbon is used as component (c).
  • affinity with water becomes high. From the standpoint that the affinity of water further increases via (c), it is preferable to use porous carbon having an average particle size of 10 to 70 ⁇ m as component (c).
  • a component (c) is removed from the water-oil mixed new fuel finally manufactured, and is reused as a solid fuel.
  • the hydrocarbon-based solvent is preferably a fuel that is a raw material for a new water-oil mixed fuel to be produced.
  • a fuel that is a raw material for a new water-oil mixed fuel to be produced.
  • gasoline, kerosene, light oil, or heavy oil including A heavy oil, B heavy oil, C heavy oil Is mentioned.
  • the content of each component can be set as appropriate.
  • the content of component (a) is preferably 3 to 10% by weight, more preferably 5 to 8% by weight, for example, 6% by weight.
  • the content of the component (b) is preferably 3 to 10% by weight, more preferably 5 to 8% by weight, for example, 6% by weight.
  • the content of component (c) is preferably 20 to 40% by weight, more preferably 25 to 35% by weight, and for example, 30% by weight.
  • the additive composition for producing a water / oil mixed new fuel according to the present invention preferably further contains, as component (d), a cleaning agent having a surface tension at 25 ° C. of 25 to 70 dyne / cm.
  • component (d) a cleaning agent having a surface tension at 25 ° C. of 25 to 70 dyne / cm.
  • the surface tension at 25 ° C. of the cleaning agent as the component (d) is preferably 28 to 50, more preferably 30 to 40.
  • component (d) include fluorine-based cleaning agents (for example, trade name: Elnova series manufactured by Asahi Kasei Chemicals), semi-aqueous cleaning agents (for example, product name: Elise M series manufactured by Asahi Kasei Chemicals), and water-based cleaning agents (for example, Asahi Kasei). Chemicals product name: Elise K series).
  • the content of component (d) is preferably 2% by weight or less, more preferably 0.5 to 1.5% by weight, for example, 1% by weight.
  • the additive composition for producing a new water-oil mixed new fuel according to the present invention as described above can be used as an additive for producing a new water-oil mixed new fuel.
  • an apparatus for producing a water-oil mixed new fuel for example, apparatuses described in Patent Documents 3 to 4 can be used, and a new fuel production apparatus having the configuration shown in FIG. 1 can also be used.
  • the 1 includes a first preparation tank 20, a second preparation tank 30, a powder separation apparatus 40, and a storage tank 50 connected in this order.
  • the storage tank 50 is connected as necessary.
  • the first mixing tank 20 is provided with a powder supply device for supplying powder, a fuel raw material supply device for supplying fuel raw material, and an additive supply device for supplying additive.
  • a powder supply device for supplying powder In the fuel production apparatus of FIG. 1, a hopper 10, a conveyor 11, a powder meter 12 and a warmer 13 are installed as powder supply apparatuses, and a fuel raw material supply line 22 and a pump 22p are provided as fuel raw material supply apparatuses.
  • an additive supply device an additive supply line 23 and a pump 23p are installed.
  • the powder is transported from the hopper 10 to the powder meter 12 by the conveyor 11, and the required amount is weighed. Then, it is transferred to the warmer 13 to be warmed and put into the first preparation tank 20.
  • the powder include porous powders such as carbon, silica, and alumina, and porous carbon is preferable.
  • the fuel material is fed from the fuel material tank (not shown) connected to the upstream side of the fuel material supply line 22 to the first preparation tank 20 by the pump 22p.
  • Petroleum fuels such as gasoline, kerosene, light oil, and heavy oil (including A heavy oil, B heavy oil, and C heavy oil) can be used as the fuel raw material.
  • the additive is introduced into the first preparation tank 20 from the additive tank (not shown) connected to the upstream side of the additive supply line 23 by the pump 23p.
  • the additive the above-described additive composition for producing a water-oil mixed new fuel according to the present invention is used.
  • the hydrocarbon solvent contained in the additive is preferably the same as the fuel material as described above.
  • the charged powder, fuel raw material, and additive are stirred and mixed by a stirring rod (homomixer) 21 to obtain a first mixture.
  • the mixing ratio of the powder, the fuel raw material, and the additive can be appropriately set according to the purpose, but 0.1 to 10 parts by weight of the powder and 0.1 to 10 parts by weight with respect to 100 parts by weight of the fuel raw material. It is preferred to mix parts by weight of additives.
  • the second mixing tank 30 is provided with a first mixture supply device that supplies the first mixture obtained in the first mixing tank 20, a water supply device that supplies water, and a circulation device that circulates the contents.
  • a first mixture transfer line 24 and a pump 24p are installed as a first mixture supply apparatus
  • a water supply line 32 and a pump 32p are installed as a water supply apparatus
  • a circulation line is used as a circulation apparatus.
  • 33 and a pump 33p are installed.
  • the particle-mixing mixer (nanobox) 26 which raises mixing of the oil and additive in a 1st mixture is installed in the middle of the 1st mixture transfer line 24. As shown in FIG. .
  • a first particleizing apparatus 36 that atomizes water is connected to the water supply apparatus in the middle of the water supply line 32.
  • the first particleizer 36 for example, as shown in FIG. 2, a device in which a high-pressure nozzle 36a and a particleizer 36b are connected in series can be used, and 3 to 5 sets of them are connected in parallel. Things can also be used. Thereby, water is atomized.
  • the high pressure nozzle 36a for example, one having a structure as shown in FIG. 3 can be used. Water is introduced into the high-pressure nozzle 36a at a pressure of, for example, 1 to 12 MPa by the pump 32p.
  • the particle mixer 36b for example, a mixing device (nano box) described in Patent Documents 1 and 2 can be used. More specifically, as shown in FIG. 4, the nano box has a structure in which the soft thin film layer 6 is disposed inside the outer case 5, and the inner spaces 1 and 2 surrounded by the outer case 5. Is hermetically sealed. The internal spaces 1 and 2 communicate with each other through a cut hole 6a (FIG. 5) formed in the soft thin film layer 6.
  • the cut hole 6a is preferably formed in a cross shape as shown in FIG.
  • the size W1 of the cut hole is preferably 1 to 20 ⁇ m, more preferably 5 to 15 ⁇ m, still more preferably 8 to 12 ⁇ m, for example, 10 ⁇ m.
  • the width w1 of the cut hole is preferably 1/5 to 1/20 of the size W1 of the cut hole, and can be, for example, 1/10 of the size W1 of the cut hole.
  • the supplied water preferably has a pH of 10 to 13.5 and an oxidation-reduction potential of ⁇ 600 to ⁇ 100 mV.
  • the pH of water can be adjusted, for example, by introducing ceramics into water.
  • the circulation device for example, in the middle of the circulation line 33, as in the fuel production device of FIG.
  • the second particleizing device 37 for example, as shown in FIG. 6, a device in which a particleizing mixer 37 a and a Venturi tube 37 b are connected in series can be used. It is also possible to use a system in which the particle mixer 37a and two to three venturi tubes 37b are connected in series.
  • the size W1 of the cut hole is preferably 50 to 500 ⁇ m, more preferably 100 to 300 ⁇ m, still more preferably 130 to 200 ⁇ m, for example 150 ⁇ m.
  • venturi tube 37b for example, a tube having a structure as shown in FIG. 7 can be used.
  • a spherical body is preferably put in the venturi tube 37b. By introducing the spherical body, the flow velocity increases as the pipe area decreases, and a homogenizing effect is obtained.
  • the contents of the second preparation tank 30 are introduced into the venturi pipe 37b by the pump 33p, for example, at a pressure of 0.1 to 1.0 MPa.
  • the first mixture obtained in the first mixing tank 20 and the water finely divided by the first particleizing device 36 are stirred and mixed by the stirring rod (homomixer) 31, and then the second mixing tank 30.
  • a mixture is obtained.
  • the second mixture is circulated by a circulation device and is atomized by a second particle formation device.
  • the mixing ratio of the second mixture and water can be appropriately set according to the purpose, but it is preferable to mix 10 to 70 ml of water, and 30 to 50 ml of water to 100 ml of the fuel raw material. More preferred.
  • the powder separator is connected to the second mixing tank 30 in a state where the second mixture obtained in the second mixing tank 30 can be supplied.
  • three particle stabilizers 40 are provided in the second preparation tank 30 via a second mixture transfer line 34 and a pump 34 p for transferring the second mixture obtained in the second preparation tank 30. Connected in parallel. Moreover, as shown in FIG. 1, it connects with the storage tank 50 with the filter 42 and the pump 43 through the product transfer line 41 which transfers a product to the downstream of the particle stabilizer 40 as needed. .
  • the powder separation device may be any device that can separate and remove the powder in the second mixture, and may be a filtration device or a centrifuge.
  • the component (c) contained in the additive composition for producing a water / oil mixed new fuel according to the present invention used as an additive is also separated and removed by the powder separation device.
  • the particle stabilizer 40 is used as a kind of stationary device. That is, by adjusting the size W1 of the cut hole in the particle mixer 36b or the particle mixer 37a, the mixing degree is increased.
  • the size W1 of the cut hole is preferably from 0.1 to 50 ⁇ m, more preferably from 0.5 to 30 ⁇ m, further preferably from 8 to 12 ⁇ m, for example, 10 ⁇ m.
  • the pressure can be, for example, 0.1 to 1.0 MPa, and more preferably 0.2 to 0.6 MPa.
  • the performance of the second mixture is improved by allowing it to stand for more than one day, conditions such that the second mixture stays in the powder separation device (particle stabilizer 40) (the flow rate of the second mixture, It is preferable to set the capacity of the powder separation device 40).
  • the obtained water / oil mixed new fuel is transferred to the storage tank 50 by the pump 43p via the filtration device 42 through the fuel transfer line 41, and stored as new fuel.
  • the water-oil mixed new fuel thus obtained can obtain a total calorific value equivalent to that of the fuel raw material, even though a predetermined amount of water is mixed with the fuel raw material. Further, it has a specific gravity equivalent to that of the fuel material. That is, it is possible to produce a water / oil mixed new fuel having a large total calorific value and a small specific gravity.
  • the obtained water-oil mixed new fuel was transparent, the total calorific value was 45.6 MJ / kg, and the specific gravity was 0.8428 g / cm 3 .
  • the total calorific value of general A heavy oil is about 45 MJ / kg and the specific gravity is about 0.87 g / cm 3 , the obtained water-oil mixed new fuel has a total calorific value equivalent to that of A heavy oil. It turns out that quantity and specific gravity are realizable.
  • Example 2 A water-oil mixed new fuel was produced in the same manner as in Example 1 except that the additive composition in which the component (b) was a nonionic surfactant (HLB: 10.8) was used.
  • the obtained water-oil mixed new fuel was transparent, the total calorific value was 44.5 MJ / kg, and the specific gravity was 0.865 g / cm 3 .
  • Example 3 A water-oil mixed new fuel was produced in the same manner as in Example 1 except that the additive composition in which the component (b) was a nonionic surfactant (HLB: 15.5) was used.
  • the obtained water-oil mixed new fuel was transparent, the total calorific value was 44.6 MJ / kg, and the specific gravity was 0.867 g / cm 3 .
  • Example 1 A water / oil mixed fuel was produced in the same manner as in Example 1 except that the additive composition in which the component (b) was a nonionic surfactant (HLB: 4.0) was used.
  • the obtained water / oil mixed fuel was milky white, had a total calorific value of 39.3 MJ / kg, and a specific gravity of 0.893 g / cm 3 .
  • Example 2 A water / oil mixed fuel was produced in the same manner as in Example 1 except that the additive composition in which the component (b) was a nonionic surfactant (HLB: 16.7) was used.
  • the obtained water / oil mixed fuel was milky white, had a total calorific value of 39.2 MJ / kg, and a specific gravity of 0.905 g / cm 3 .

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The present invention provides an additive composition for manufacturing a new water and oil mixture fuel which is visually transparent, has a high gross heating value and a low specific gravity. This additive composition for manufacturing the new water and oil mixture fuel includes, for example, in a hydrocarbon-based solvent, component (a) which is castor oil or olive oil, component (b) which is a nonionic surfactant having an HLB of 8.0-15.5, and component (c) which is carbon, the content of the component (a) being 3-10 weight%, the content of the component (b) being 3-10 weight%, and the content of the component (c) being 20-40 weight%.

Description

水油混合新燃料製造用添加剤組成物Additive composition for water / oil mixed new fuel production
　本発明は、総発熱量が大きく比重が小さい水油混合新燃料を製造するための添加剤組成物に関する。 The present invention relates to an additive composition for producing a water / oil mixed new fuel having a large total calorific value and a small specific gravity.
　近年、ガソリン、灯油、軽油、重油等の石油系燃料中に水を分散させた水油混合新燃料が注目されている。水油混合新燃料は、発生する有害物質が少ないため、環境保護に貢献できるとされている。 In recent years, a new water-oil mixed fuel in which water is dispersed in petroleum-based fuels such as gasoline, kerosene, light oil and heavy oil has attracted attention. The new water-oil mixed fuel is said to contribute to environmental protection because it produces less harmful substances.
　燃料に水を均一に混合する方法としては、乳化剤を代表とする添加剤を利用する方法が一般的である。特許文献１には、水と乳化剤を燃料油に混合させてエマルジョン燃料を製造する装置が記載されている。特許文献２には、植物性廃食用油と焼酎粕液とを、体積比で略１対１の割合で混合して成るエマルジョン燃料油が記載されている。 As a method for uniformly mixing water with fuel, a method using an additive typified by an emulsifier is common. Patent Document 1 describes an apparatus for producing emulsion fuel by mixing water and an emulsifier with fuel oil. Patent Document 2 describes an emulsion fuel oil obtained by mixing vegetable waste cooking oil and shochu liquor at a volume ratio of approximately 1: 1.
　また、乳化剤などの添加剤を用いずに、燃料及び水をできるだけ細かいレベル（例、微粒子レベル）で良好に混合するための装置も開発されている。 Also, an apparatus has been developed for mixing fuel and water well at the finest possible level (eg, fine particle level) without using additives such as emulsifiers.
　特許文献３には、燃料油または燃料油と水との混合油を噴射する第１噴射部と、水を噴射する第２噴射部と、前記第１噴射部から噴射される液体に正の高電位を付与し、前記第２噴射部から噴射される水に負の高電位を付与するための直流高電圧発生部と、噴射された燃料油または混合油と噴射された水との衝突により生成された混合油を受容すると共に、該混合油を前記第１噴射部に送出する混合油処理部とを具えたことを特徴とする混合燃料生成装置が記載されている。 Patent Document 3 discloses a first injection unit that injects fuel oil or a mixed oil of fuel oil and water, a second injection unit that injects water, and a liquid that is positively injected from the first injection unit. A direct current high voltage generator for applying a potential and applying a negative high potential to the water injected from the second injection unit, and generated by collision of the injected fuel oil or mixed oil and the injected water And a mixed oil processing unit that receives the mixed oil and delivers the mixed oil to the first injection unit.
　特許文献４には、混合しようとする水を軟水化する軟水化部と、該軟水化部からの軟水を純水化する純水化部と、該純水化部からの純水を第１の液体磁気処理装置によりマイナスイオン化する水イオン化部と、混合しようとする油を第２の液体磁気処理装置によりプラスイオン化する油イオン化部と、該油イオン化部からのプラスイオン化された油に正の電位を付与する電位付与部と、該電位付与部からの油を正電位に帯電させて噴霧すると共に前記水イオン化部からの水を負電位に帯電させて噴霧し、これら噴霧同士を交わらせることにより、混合液がマイクロエマルジョンの状態となるよう混合を行う混合部とを具えたことを特徴とするマイクロエマルジョン生成装置が記載されている。 Patent Document 4 includes a water softening unit that softens water to be mixed, a pure water purification unit that purifies soft water from the water softening unit, and pure water from the pure water purification unit. The water ionization unit that negatively ionizes by the liquid magnetic processing device, the oil ionization unit that positively ionizes the oil to be mixed by the second liquid magnetic processing device, and the positive ionized oil from the oil ionization unit A potential applying portion for applying a potential, and spraying with the oil from the potential applying portion charged to a positive potential and spraying while charging the water from the water ionization portion to a negative potential and crossing these sprays. Describes a microemulsion generator characterized by comprising a mixing section for mixing so that the liquid mixture becomes a microemulsion state.
特開２００７－１９７６４８号公報JP 2007-197648 A 特開２００８－１７４６９９号公報JP 2008-174699 A 特許第５７１１１８６号公報Japanese Patent No. 5711186 特許第５６１９２０４号公報Japanese Patent No. 5619204
　しかし、特許文献１～２に記載された水油混合燃料は乳白色を呈しており、見た目が燃料油らしくないという問題があった。また、添加した水の分だけ総発熱量（カロリー）が小さく、比重が大きくなってしまうという問題もあった。特許文献３～４に記載された新燃料生成装置は汎用性に優れているものの、使用する添加剤の組成については最適化されていなかった。 However, the water-oil mixed fuel described in Patent Documents 1 and 2 has a milky white color, and has a problem that it does not look like fuel oil. There is also a problem that the total calorific value (calories) is small and the specific gravity is increased by the amount of water added. Although the new fuel generators described in Patent Documents 3 to 4 are excellent in versatility, the composition of the additive used has not been optimized.
　そこで、本発明は、見た目が透明で、総発熱量が大きく比重が小さい水油混合新燃料を製造するための添加剤組成物を提供することを目的とする。 Therefore, an object of the present invention is to provide an additive composition for producing a new water / oil mixed fuel that is transparent in appearance and has a large total calorific value and a small specific gravity.
　本発明は、炭化水素系溶媒中に、
成分（ａ）：ヒマシ油又はオリーブ油と、
成分（ｂ）：ＨＬＢが８．０～１５．５であるノニオン性界面活性剤と、
成分（ｃ）：カーボンと
を含有し、
前記成分（ａ）の含有率が３～１０重量％であり、前記成分（ｂ）の含有率が３～１０重量％であり、前記成分（ｃ）の含有率が２０～４０重量％である水油混合新燃料製造用添加剤組成物である。 In the hydrocarbon solvent, the present invention
Component (a): castor oil or olive oil;
Component (b): a nonionic surfactant having an HLB of 8.0 to 15.5,
Component (c): containing carbon,
The content of component (a) is 3 to 10% by weight, the content of component (b) is 3 to 10% by weight, and the content of component (c) is 20 to 40% by weight. It is an additive composition for water-oil mixed new fuel production.
　また、本発明は、炭化水素系溶媒中に、
成分（ａ）：ヒマシ油又はオリーブ油と、
成分（ｂ）：ＨＬＢが８．０～１５．５であるノニオン性界面活性剤と、
成分（ｃ）：カーボンと、
成分（ｄ）：２５℃における表面張力が２５～７０ｄｙｎｅ／ｃｍの洗浄剤と
を含有する水油混合新燃料製造用添加剤組成物である。 In the present invention, in the hydrocarbon solvent,
Component (a): castor oil or olive oil;
Component (b): a nonionic surfactant having an HLB of 8.0 to 15.5,
Component (c): carbon,
Component (d): An additive composition for producing a water / oil mixed new fuel containing a detergent having a surface tension at 25 ° C. of 25 to 70 dyne / cm.
　また、本発明は、炭化水素系溶媒中に、
成分（ａ）：ヒマシ油又はオリーブ油と、
成分（ｂ）：ＨＬＢが８．０～１５．５であるノニオン性界面活性剤と、
成分（ｃ）：平均粒径１０～７０μｍの多孔質カーボンと
を含有する水油混合新燃料製造用添加剤組成物である。 In the present invention, in the hydrocarbon solvent,
Component (a): castor oil or olive oil;
Component (b): a nonionic surfactant having an HLB of 8.0 to 15.5,
Component (c): An additive composition for producing a new water / oil mixed fuel containing porous carbon having an average particle size of 10 to 70 μm.
　本発明によれば、見た目が透明で、総発熱量が大きく比重が小さい水油混合新燃料を製造するための添加剤組成物を提供できる。 According to the present invention, it is possible to provide an additive composition for producing a new water-oil mixed fuel that is transparent in appearance and has a large total calorific value and a small specific gravity.
新燃料製造装置の構成の一例を示す図である。It is a figure which shows an example of a structure of a new fuel manufacturing apparatus. 第一粒子化装置の構成の一例を示す図である。It is a figure which shows an example of a structure of a 1st particle-izing apparatus. 高圧ノズルの構成の一例を示す図である。It is a figure which shows an example of a structure of a high pressure nozzle. 粒子化混合器の構成の一例を示す図である。It is a figure which shows an example of a structure of a particle mixer. 軟質薄膜層に形成されるカット孔の一例を示す図である。It is a figure which shows an example of the cut hole formed in a soft thin film layer. 第二粒子化装置の構成の一例を示す図である。It is a figure which shows an example of a structure of a 2nd particle-izing apparatus. ベンチュリー管の構成の一例を示す図である。It is a figure which shows an example of a structure of a venturi pipe.
　本発明に係る水油混合新燃料製造用添加剤組成物は、炭化水素系溶媒中に、ヒマシ油又はオリーブ油（成分（ａ））と、ＨＬＢが８．０～１５．５であるノニオン性界面活性剤（成分（ｂ））と、カーボン（成分（ｃ））とを含有するものである。このような水油混合新燃料製造用添加剤組成物は、見た目が透明で、総発熱量が大きく比重が小さい水油混合新燃料を製造するのに有用である。 The additive composition for producing a new fuel oil-mixed fuel according to the present invention comprises a nonionic interface having a castor oil or olive oil (component (a)) and an HLB of 8.0 to 15.5 in a hydrocarbon solvent. An activator (component (b)) and carbon (component (c)) are contained. Such an additive composition for producing a new water / oil mixed fuel is useful for producing a new water / oil mixed fuel having a transparent appearance and a large total calorific value and a small specific gravity.
　成分（ａ）としては、ヒマシ油又はオリーブ油を用いる。成分（ａ）を含有することによって、熱・溶解性が向上する。炭素鎖長を置換基の違いにより熱・溶解性のさらなる向上をはかる観点から、成分（ａ）はヒマシ油が好ましい。 As the component (a), castor oil or olive oil is used. By containing the component (a), heat and solubility are improved. From the viewpoint of further improving the heat and solubility of the carbon chain length due to the difference in substituents, the component (a) is preferably castor oil.
　成分（ｂ）としては、ＨＬＢが８．０～１５．５であるノニオン性界面活性剤（非イオン性界面活性剤）を用いる。成分（ｂ）を含有することによって、水と燃料（油）がなじみやすくなる。ノニオン性界面活性剤の具体例としては、ラウリン酸グリセリン、モノステアリン酸グリセリン、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル等のエステル型ノニオン性界面活性剤；ポリオキシエチレンアルキルエーテル、ペンタエチレングリコールモノドデシルエーテル、オクタエチレングリコールモノドデシルエーテル、ポリオキシエチレンアルキルフェニルエーテル、オクチルフェノールエトキシレート、ノニルフェノールエトキシレート、ポリオキシエチレンポリオキシプロピレングリコール等のエーテル型ノニオン性界面活性剤；ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンヘキシタン脂肪酸エステル、ソルビタン脂肪酸エステルポリエチレングリコール等のエステルエーテル型ノニオン性界面活性剤；ラウリン酸ジエタノールアミド、オレイン酸ジエタノールアミド、ステアリン酸ジエタノールアミド、コカミドＤＥＡ等のアルカノールアミド型ノニオン性界面活性剤；オクチルグルコシド、デシルグルコシド、ラウリルグルコシド等のアルキルグリコシド型ノニオン性界面活性剤；ラウリルアルコール、セチルアルコール、セトステアリルアルコール、ステアリルアルコール、オレイルアルコール、カプリルアルコール、及びこれらのエチレンオキシド付加物等の高級アルコール型ノニオン性界面活性剤が挙げられる。 As the component (b), a nonionic surfactant (nonionic surfactant) having an HLB of 8.0 to 15.5 is used. By containing the component (b), the water and the fuel (oil) are easily mixed. Specific examples of the nonionic surfactant include ester type nonionic surfactants such as glyceryl laurate, glyceryl monostearate, sorbitan fatty acid ester, and sucrose fatty acid ester; polyoxyethylene alkyl ether, pentaethylene glycol monododecyl ether , Ether-type nonionic surfactants such as octaethylene glycol monododecyl ether, polyoxyethylene alkylphenyl ether, octylphenol ethoxylate, nonylphenol ethoxylate, polyoxyethylene polyoxypropylene glycol; polyoxyethylene sorbitan fatty acid ester, polyoxyethylene Ester ether type nonionic surface activity such as hexitan fatty acid ester and sorbitan fatty acid ester polyethylene glycol Alkanolamide type nonionic surfactants such as lauric acid diethanolamide, oleic acid diethanolamide, stearic acid diethanolamide, cocamide DEA; alkylglycoside type nonionic surfactants such as octyl glucoside, decyl glucoside, lauryl glucoside; lauryl alcohol Higher alcohol type nonionic surfactants such as cetyl alcohol, cetostearyl alcohol, stearyl alcohol, oleyl alcohol, capryl alcohol, and ethylene oxide adducts thereof.
　ＨＬＢは、界面活性剤の水と油への親和性の程度を表す値であり、０～２０の値を取り、０に近いほど親油性が高く、２０に近いほど親水性が高いことを意味する。ＨＬＢは、例えばグリフィン法で計算することができる。本発明では、成分（ｂ）としてＨＬＢが８．０～１５．５のノニオン性界面活性剤を選択することで、乳化することなく透明な水油混合新燃料を得ることができる。成分（ｂ）となるノニオン性界面活性剤のＨＬＢは９．０～１４．２が好ましく、１０．８～１３．２がより好ましい。 HLB is a value representing the degree of affinity of a surfactant with water and oil. It takes a value of 0 to 20, and the closer to 0, the higher the lipophilicity, and the closer to 20, the higher the hydrophilicity. To do. The HLB can be calculated by the Griffin method, for example. In the present invention, by selecting a nonionic surfactant having an HLB of 8.0 to 15.5 as the component (b), a transparent water-oil mixed new fuel can be obtained without emulsification. The HLB of the nonionic surfactant as the component (b) is preferably 9.0 to 14.2, and more preferably 10.8 to 13.2.
　成分（ｃ）としては、カーボンを用いる。成分（ｃ）を含有することによって、水との親和性が高くなる。水がさらに（ｃ）を介して親和性が非常に高くなる観点から、成分（ｃ）として、平均粒径１０～７０μｍの多孔質カーボンを用いることが好ましい。なお、成分（ｃ）は、最終的に製造される水油混合新燃料からは除去され、固形燃料として再利用される。 Carbon is used as component (c). By containing a component (c), affinity with water becomes high. From the standpoint that the affinity of water further increases via (c), it is preferable to use porous carbon having an average particle size of 10 to 70 μm as component (c). In addition, a component (c) is removed from the water-oil mixed new fuel finally manufactured, and is reused as a solid fuel.
　炭化水素系溶媒としては、製造する水油混合新燃料の原料である燃料とすることが好ましく、具体的には、ガソリン、灯油、軽油、又は重油（Ａ重油、Ｂ重油、Ｃ重油を含む）が挙げられる。 The hydrocarbon-based solvent is preferably a fuel that is a raw material for a new water-oil mixed fuel to be produced. Specifically, gasoline, kerosene, light oil, or heavy oil (including A heavy oil, B heavy oil, C heavy oil) Is mentioned.
　各成分の含有率に関しては、適宜設定することができる。成分（ａ）の含有率は、３～１０重量％とすることが好ましく、５～８重量％とすることがより好ましく、例えば６重量％とすることができる。成分（ｂ）の含有率は、３～１０重量％とすることが好ましく、５～８重量％とすることがより好ましく、例えば６重量％とすることができる。成分（ｃ）の含有率は、２０～４０重量％とすることが好ましく、２５～３５重量％とすることがより好ましく、例えば３０重量％とすることができる。 The content of each component can be set as appropriate. The content of component (a) is preferably 3 to 10% by weight, more preferably 5 to 8% by weight, for example, 6% by weight. The content of the component (b) is preferably 3 to 10% by weight, more preferably 5 to 8% by weight, for example, 6% by weight. The content of component (c) is preferably 20 to 40% by weight, more preferably 25 to 35% by weight, and for example, 30% by weight.
　本発明に係る水油混合新燃料製造用添加剤組成物は、更に、成分（ｄ）として、２５℃における表面張力が２５～７０ｄｙｎｅ／ｃｍの洗浄剤を含有することが好ましい。成分（ｄ）を含有することによって、水の油に対する濡れ性を改善することができる。成分（ｄ）となる洗浄剤の２５℃における表面張力は、２８～５０が好ましく、３０～４０がより好ましい。成分（ｄ）の具体例としては、フッ素系洗浄剤（例えば旭化成ケミカルズ製商品名：エルノバシリーズ）、準水系洗浄剤（例えば旭化成ケミカルズ製商品名：エリーズＭシリーズ）、水系洗浄剤（例えば旭化成ケミカルズ製商品名：エリーズＫシリーズ）が挙げられる。 The additive composition for producing a water / oil mixed new fuel according to the present invention preferably further contains, as component (d), a cleaning agent having a surface tension at 25 ° C. of 25 to 70 dyne / cm. By containing the component (d), the wettability of water with respect to oil can be improved. The surface tension at 25 ° C. of the cleaning agent as the component (d) is preferably 28 to 50, more preferably 30 to 40. Specific examples of the component (d) include fluorine-based cleaning agents (for example, trade name: Elnova series manufactured by Asahi Kasei Chemicals), semi-aqueous cleaning agents (for example, product name: Elise M series manufactured by Asahi Kasei Chemicals), and water-based cleaning agents (for example, Asahi Kasei). Chemicals product name: Elise K series).
　成分（ｄ）の含有率は、２重量％以下であることが好ましく、０．５～１．５重量％であることがより好ましく、例えば１重量％とすることができる。 The content of component (d) is preferably 2% by weight or less, more preferably 0.5 to 1.5% by weight, for example, 1% by weight.
　以上のような本発明に係る水油混合新燃料製造用添加剤組成物は、水油混合新燃料を製造する際の添加剤として利用することができる。水油混合新燃料を製造するための装置としては、例えば特許文献３～４に記載された装置を用いることができ、また図１に示す構成の新燃料製造装置を用いることもできる。 The additive composition for producing a new water-oil mixed new fuel according to the present invention as described above can be used as an additive for producing a new water-oil mixed new fuel. As an apparatus for producing a water-oil mixed new fuel, for example, apparatuses described in Patent Documents 3 to 4 can be used, and a new fuel production apparatus having the configuration shown in FIG. 1 can also be used.
　図１の燃料製造装置は、第一調合タンク２０と、第二調合タンク３０と、粉体分離装置４０と、貯蔵タンク５０とが、この順に接続されている。なお、貯蔵タンク５０は、必要に応じて接続される。 1 includes a first preparation tank 20, a second preparation tank 30, a powder separation apparatus 40, and a storage tank 50 connected in this order. The storage tank 50 is connected as necessary.
　第一調合タンク２０には、粉体を供給する粉体供給装置、燃料原料を供給する燃料原料供給装置、及び添加剤を供給する添加剤供給装置が設置される。図１の燃料製造装置では、粉体供給装置として、ホッパー１０、コンベア１１、粉体計量器１２、及び加温器１３が設置され、燃料原料供給装置として、燃料原料供給ライン２２及びポンプ２２ｐが設置され、添加剤供給装置として、添加剤供給ライン２３及びポンプ２３ｐが設置されている。 The first mixing tank 20 is provided with a powder supply device for supplying powder, a fuel raw material supply device for supplying fuel raw material, and an additive supply device for supplying additive. In the fuel production apparatus of FIG. 1, a hopper 10, a conveyor 11, a powder meter 12 and a warmer 13 are installed as powder supply apparatuses, and a fuel raw material supply line 22 and a pump 22p are provided as fuel raw material supply apparatuses. As an additive supply device, an additive supply line 23 and a pump 23p are installed.
　粉体は、ホッパー１０からコンベア１１により粉体計量器１２に運ばれて、必要量が計量される。その後、加温器１３に移送されて加温され、第一調合タンク２０に投入される。粉体としては、カーボン、シリカ、アルミナ等の多孔質粉体が挙げられるが、多孔質カーボンが好ましい。 The powder is transported from the hopper 10 to the powder meter 12 by the conveyor 11, and the required amount is weighed. Then, it is transferred to the warmer 13 to be warmed and put into the first preparation tank 20. Examples of the powder include porous powders such as carbon, silica, and alumina, and porous carbon is preferable.
　燃料原料は、燃料原料供給ライン２２の上流側に接続された燃料原料タンク（不図示）からポンプ２２ｐにより第一調合タンク２０に投入される。燃料原料としては、ガソリン、灯油、軽油、重油（Ａ重油、Ｂ重油、Ｃ重油を含む）等の石油系燃料を用いることができる。 The fuel material is fed from the fuel material tank (not shown) connected to the upstream side of the fuel material supply line 22 to the first preparation tank 20 by the pump 22p. Petroleum fuels such as gasoline, kerosene, light oil, and heavy oil (including A heavy oil, B heavy oil, and C heavy oil) can be used as the fuel raw material.
　添加剤は、添加剤供給ライン２３の上流側に接続された添加剤タンク（不図示）からポンプ２３ｐにより第一調合タンク２０に投入される。添加剤としては、上述した本発明に係る水油混合新燃料製造用添加剤組成物を用いる。なお、添加剤に含まれる炭化水素系溶媒は、上述のとおり燃料原料と同じであることが好ましい。 The additive is introduced into the first preparation tank 20 from the additive tank (not shown) connected to the upstream side of the additive supply line 23 by the pump 23p. As the additive, the above-described additive composition for producing a water-oil mixed new fuel according to the present invention is used. The hydrocarbon solvent contained in the additive is preferably the same as the fuel material as described above.
　第一調合タンク２０では、投入された粉体、燃料原料、及び添加剤が、撹拌棒（ホモミキサー）２１により撹拌・混合されて、第一混合物が得られる。粉体、燃料原料、及び添加剤の配合比は、目的に応じて適宜設定することができるが、燃料原料１００重量部に対し、０．１～１０重量部の粉体及び０．１～１０重量部の添加剤を混合することが好ましい。 In the first preparation tank 20, the charged powder, fuel raw material, and additive are stirred and mixed by a stirring rod (homomixer) 21 to obtain a first mixture. The mixing ratio of the powder, the fuel raw material, and the additive can be appropriately set according to the purpose, but 0.1 to 10 parts by weight of the powder and 0.1 to 10 parts by weight with respect to 100 parts by weight of the fuel raw material. It is preferred to mix parts by weight of additives.
　第二調合タンク３０には、第一調合タンク２０で得られた第一混合物を供給する第一混合物供給装置、水を供給する水供給装置、及び内容物を循環させる循環装置が設置される。図１の燃料製造装置では、第一混合物供給装置として、第一混合物移送ライン２４及びポンプ２４ｐが設置され、水供給装置として、水供給ライン３２及びポンプ３２ｐが設置され、循環装置として、循環ライン３３及びポンプ３３ｐが設置されている。また、図１に示すように、第一混合物移送ライン２４の途中には、第一混合物中の油と添加剤の混合を高める粒子化混合器（ナノＢｏｘ）２６が設置されていることが好ましい。 The second mixing tank 30 is provided with a first mixture supply device that supplies the first mixture obtained in the first mixing tank 20, a water supply device that supplies water, and a circulation device that circulates the contents. In the fuel production apparatus of FIG. 1, a first mixture transfer line 24 and a pump 24p are installed as a first mixture supply apparatus, a water supply line 32 and a pump 32p are installed as a water supply apparatus, and a circulation line is used as a circulation apparatus. 33 and a pump 33p are installed. Moreover, as shown in FIG. 1, it is preferable that the particle-mixing mixer (nanobox) 26 which raises mixing of the oil and additive in a 1st mixture is installed in the middle of the 1st mixture transfer line 24. As shown in FIG. .
　ここで、水供給装置には、図１の燃料製造装置のように、例えば、水供給ライン３２の途中に、水を微粒子化する第一粒子化装置３６が接続されている。第一粒子化装置３６としては、例えば、図２に示すように、高圧ノズル３６ａと粒子化混合器３６ｂが直列に接続されたものを用いることができ、これが３～５セット並列に接続されたものを用いることもできる。これにより、水が微粒子化される。 Here, as in the fuel production apparatus of FIG. 1, for example, a first particleizing apparatus 36 that atomizes water is connected to the water supply apparatus in the middle of the water supply line 32. As the first particleizer 36, for example, as shown in FIG. 2, a device in which a high-pressure nozzle 36a and a particleizer 36b are connected in series can be used, and 3 to 5 sets of them are connected in parallel. Things can also be used. Thereby, water is atomized.
　高圧ノズル３６ａとしては、例えば、図３に示すような構造を有するものを用いることができる。高圧ノズル３６ａには、ポンプ３２ｐにより、例えば１～１２ＭＰａの圧力で水が導入される。 As the high pressure nozzle 36a, for example, one having a structure as shown in FIG. 3 can be used. Water is introduced into the high-pressure nozzle 36a at a pressure of, for example, 1 to 12 MPa by the pump 32p.
　粒子化混合器３６ｂとしては、例えば、特許文献１及び２に記載された混合装置（ナノＢｏｘ）を用いることができる。より具体的には、ナノＢｏｘは、図４に示すように、外ケース５の内部に軟質薄膜層６が配置された構造を有しており、外ケース５に囲まれた内部空間１及び２は密閉されている。内部空間１及び２は、軟質薄膜層６に形成されているカット孔６ａ（図５）によって連通している。カット孔６ａは、例えば、図５に示すように十字形状に形成されていることが好ましい。カット孔の大きさＷ１は、１～２０μｍが好ましく、５～１５μｍがより好ましく、８～１２μｍがさらに好ましく、例えば１０μｍとすることができる。カット孔の幅ｗ１は、カット孔の大きさＷ１の１／５～１／２０とすることが好ましく、例えば、カット孔の大きさＷ１の１／１０とすることができる。 As the particle mixer 36b, for example, a mixing device (nano box) described in Patent Documents 1 and 2 can be used. More specifically, as shown in FIG. 4, the nano box has a structure in which the soft thin film layer 6 is disposed inside the outer case 5, and the inner spaces 1 and 2 surrounded by the outer case 5. Is hermetically sealed. The internal spaces 1 and 2 communicate with each other through a cut hole 6a (FIG. 5) formed in the soft thin film layer 6. For example, the cut hole 6a is preferably formed in a cross shape as shown in FIG. The size W1 of the cut hole is preferably 1 to 20 μm, more preferably 5 to 15 μm, still more preferably 8 to 12 μm, for example, 10 μm. The width w1 of the cut hole is preferably 1/5 to 1/20 of the size W1 of the cut hole, and can be, for example, 1/10 of the size W1 of the cut hole.
　供給する水は、ｐＨが１０～１３．５であることが好ましく、酸化還元電位が－６００～－１００ｍＶであることが好ましい。水のｐＨは、例えば、水にセラミックスを投入することで調整できる。 The supplied water preferably has a pH of 10 to 13.5 and an oxidation-reduction potential of −600 to −100 mV. The pH of water can be adjusted, for example, by introducing ceramics into water.
　また、循環装置には、図１の燃料製造装置のように、例えば、循環ライン３３の途中に、第二調合タンク３０の内容物を微粒子化する第二粒子化装置３７が接続されている。第二粒子化装置３７としては、例えば、図６に示すように、粒子化混合器３７ａとベンチュリー管３７ｂが直列に接続されたものを用いることができる。粒子化混合器３７ａと２～３個のベンチュリー管３７ｂとが直列に接続されたものを用いることもできる。 1 is connected to the circulation device, for example, in the middle of the circulation line 33, as in the fuel production device of FIG. As the second particleizing device 37, for example, as shown in FIG. 6, a device in which a particleizing mixer 37 a and a Venturi tube 37 b are connected in series can be used. It is also possible to use a system in which the particle mixer 37a and two to three venturi tubes 37b are connected in series.
　粒子化混合器３７ａとしては、上記の粒子化混合器３６ｂと同様のものを用いることができる。ただし、カット孔の大きさＷ１については、５０～５００μｍとすることが好ましく、１００～３００μｍとすることがより好ましく、１３０～２００μｍとすることがさらに好ましく、例えば１５０μｍとすることができる。 As the particle mixer 37a, the same one as the particle mixer 36b can be used. However, the size W1 of the cut hole is preferably 50 to 500 μm, more preferably 100 to 300 μm, still more preferably 130 to 200 μm, for example 150 μm.
　ベンチュリー管３７ｂとしては、例えば、図７に示すような構造を有するものを用いることができる。ベンチュリー管３７ｂには、図７に示すように、球状体が投入されていることが好ましい。球状体が投入されることで、パイプ面積の減少に応じて流速が大きくなり、ホモジナイズ効果が得られる。ベンチュリー管３７ｂには、ポンプ３３ｐにより、例えば０．１～１．０ＭＰａの圧力で第二調合タンク３０の内容物が導入される。 As the venturi tube 37b, for example, a tube having a structure as shown in FIG. 7 can be used. As shown in FIG. 7, a spherical body is preferably put in the venturi tube 37b. By introducing the spherical body, the flow velocity increases as the pipe area decreases, and a homogenizing effect is obtained. The contents of the second preparation tank 30 are introduced into the venturi pipe 37b by the pump 33p, for example, at a pressure of 0.1 to 1.0 MPa.
　第二調合タンク３０では、第一調合タンク２０で得られた第一混合物及び第一粒子化装置３６により微粒子化された水が、撹拌棒（ホモミキサー）３１により撹拌・混合されて、第二混合物が得られる。さらに、第二混合物は、循環装置により循環し、第二粒子化装置により微粒子化される。第二混合物及び水の配合比は、目的に応じて適宜設定することができるが、燃料原料１００ｍｌに対し、１０～７０ｍｌの水を混合することが好ましく、３０～５０ｍｌの水を混合することがより好ましい。 In the second mixing tank 30, the first mixture obtained in the first mixing tank 20 and the water finely divided by the first particleizing device 36 are stirred and mixed by the stirring rod (homomixer) 31, and then the second mixing tank 30. A mixture is obtained. Furthermore, the second mixture is circulated by a circulation device and is atomized by a second particle formation device. The mixing ratio of the second mixture and water can be appropriately set according to the purpose, but it is preferable to mix 10 to 70 ml of water, and 30 to 50 ml of water to 100 ml of the fuel raw material. More preferred.
　粉体分離装置は、第二調合タンク３０で得られた第二混合物を供給可能な状態で、第二調合タンク３０と接続されている。図１の燃料製造装置では、第二調合タンク３０に、第二調合タンク３０で得られた第二混合物を移送する第二混合物移送ライン３４及びポンプ３４ｐを介して３つの粒子化安定器４０が並列に接続されている。また、図１に示すように、必要に応じて、粒子化安定器４０の下流側に、製品を移送する製品移送ライン４１を介してろ過器４２及びポンプ４３と共に貯蔵タンク５０に接続されている。 The powder separator is connected to the second mixing tank 30 in a state where the second mixture obtained in the second mixing tank 30 can be supplied. In the fuel production apparatus of FIG. 1, three particle stabilizers 40 are provided in the second preparation tank 30 via a second mixture transfer line 34 and a pump 34 p for transferring the second mixture obtained in the second preparation tank 30. Connected in parallel. Moreover, as shown in FIG. 1, it connects with the storage tank 50 with the filter 42 and the pump 43 through the product transfer line 41 which transfers a product to the downstream of the particle stabilizer 40 as needed. .
　粉体分離装置としては、第二混合物中の粉体を分離・除去できるものであればよく、濾過装置でもよく、遠心分離機でもよい。添加剤として使用した本発明に係る水油混合新燃料製造用添加剤組成物に含まれる成分（ｃ）も、この粉体分離装置により分離・除去される。図１において、粒子化安定器４０は、一種の静止装置として使用されている。すなわち、上記の粒子化混合器３６ｂ又は粒子化混合器３７ａにおけるカット孔の大きさＷ１を調整することで、混合度を高める機能となる。具体的には、カット孔の大きさＷ１は、０．１～５０μｍが好ましく、０．５～３０μｍがより好ましく、８～１２μｍがさらに好ましく、例えば１０μｍとすることができる。圧力は、例えば０．１～１．０ＭＰａとすることができ０．２～０．６Ｍｐａがより好ましい。 The powder separation device may be any device that can separate and remove the powder in the second mixture, and may be a filtration device or a centrifuge. The component (c) contained in the additive composition for producing a water / oil mixed new fuel according to the present invention used as an additive is also separated and removed by the powder separation device. In FIG. 1, the particle stabilizer 40 is used as a kind of stationary device. That is, by adjusting the size W1 of the cut hole in the particle mixer 36b or the particle mixer 37a, the mixing degree is increased. Specifically, the size W1 of the cut hole is preferably from 0.1 to 50 μm, more preferably from 0.5 to 30 μm, further preferably from 8 to 12 μm, for example, 10 μm. The pressure can be, for example, 0.1 to 1.0 MPa, and more preferably 0.2 to 0.6 MPa.
　なお、第二混合物は、一日以上放置することで性能が向上することから、第二混合物が粉体分離装置（粒子化安定器４０）内で滞留するような条件（第二混合物の流量、粉体分離装置４０の容量など）に設定することが好ましい。 Since the performance of the second mixture is improved by allowing it to stand for more than one day, conditions such that the second mixture stays in the powder separation device (particle stabilizer 40) (the flow rate of the second mixture, It is preferable to set the capacity of the powder separation device 40).
　そして、粒子化安定器４０で静止された水油混合新燃料が得られる条件が整う。得られた水油混合新燃料は、燃料移送ライン４１によりろ過装置４２を経由してポンプ４３ｐで貯蔵タンク５０に移送されて、新燃料となり貯蔵される。 Then, the conditions for obtaining a new water-oil mixed fuel stationary by the particle stabilizer 40 are established. The obtained water / oil mixed new fuel is transferred to the storage tank 50 by the pump 43p via the filtration device 42 through the fuel transfer line 41, and stored as new fuel.
　こうして得られる水油混合新燃料は、燃料原料に所定量の水が混合されているにも関わらず、燃料原料と同等の総発熱量を得ることができる。また、燃料原料と同等の比重を有する。すなわち、総発熱量が大きく比重が小さい水油混合新燃料を製造することができる。 The water-oil mixed new fuel thus obtained can obtain a total calorific value equivalent to that of the fuel raw material, even though a predetermined amount of water is mixed with the fuel raw material. Further, it has a specific gravity equivalent to that of the fuel material. That is, it is possible to produce a water / oil mixed new fuel having a large total calorific value and a small specific gravity.
　＜実施例１＞
　図１に示す装置を用いて水油混合新燃料を製造した。なお、燃料原料としてはＡ重油を用い、粉体としては多孔質カーボン（見かけ密度：０．３３ｋｇ／ｌ）を用い、添加剤としては、以下の成分を含有する添加剤組成物を用いた。配合比は、Ａ重油：水：添加剤：粉体＝７０：３０：０．３５：０．１２（容積比）とした。
　・成分（ａ）：ヒマシ油　　　　　　　　　　　　　　　　　６重量％
　・成分（ｂ）：ノニオン性界面活性剤（ＨＬＢ：８．０）　　６重量％
　・成分（ｃ）：多孔質カーボン（平均粒径５０μｍ）　　　３０重量％
　・成分（ｄ）：洗浄剤（２５℃における表面張力：３３）　　１重量％
　・炭化水素系溶媒：Ａ重油　　　　　　　　　　　　　　　５７重量％ <Example 1>
A water-oil mixed new fuel was produced using the apparatus shown in FIG. In addition, A heavy oil was used as the fuel material, porous carbon (apparent density: 0.33 kg / l) was used as the powder, and an additive composition containing the following components was used as the additive. The blending ratio was A heavy oil: water: additive: powder = 70: 30: 0.35: 0.12 (volume ratio).
Ingredient (a): castor oil 6% by weight
Component (b): Nonionic surfactant (HLB: 8.0) 6% by weight
Component (c): porous carbon (average particle size 50 μm) 30% by weight
Component (d): Cleaning agent (surface tension at 25 ° C .: 33) 1% by weight
・ Hydrocarbon solvent: Heavy oil A 57% by weight
　得られた水油混合新燃料は透明を呈しており、総発熱量は４５．６ＭＪ／ｋｇであり、比重は０．８４２８ｇ／ｃｍ３であった。なお、一般的なＡ重油の総発熱量は４５ＭＪ／ｋｇ程度であり、比重は０．８７ｇ／ｃｍ３程度であることから、得られた水油混合新燃料は、Ａ重油と同等の総発熱量及び比重が実現できていることが分かる。 The obtained water-oil mixed new fuel was transparent, the total calorific value was 45.6 MJ / kg, and the specific gravity was 0.8428 g / cm 3 . In addition, since the total calorific value of general A heavy oil is about 45 MJ / kg and the specific gravity is about 0.87 g / cm 3 , the obtained water-oil mixed new fuel has a total calorific value equivalent to that of A heavy oil. It turns out that quantity and specific gravity are realizable.
　＜実施例２＞
　成分（ｂ）がノニオン性界面活性剤（ＨＬＢ：１０．８）である添加剤組成物を用いたこと以外は、実施例１と同様にして水油混合新燃料を製造した。得られた水油混合新燃料は透明を呈しており、総発熱量は４４．５ＭＪ／ｋｇであり、比重は０．８６５ｇ／ｃｍ３であった。 <Example 2>
A water-oil mixed new fuel was produced in the same manner as in Example 1 except that the additive composition in which the component (b) was a nonionic surfactant (HLB: 10.8) was used. The obtained water-oil mixed new fuel was transparent, the total calorific value was 44.5 MJ / kg, and the specific gravity was 0.865 g / cm 3 .
　＜実施例３＞
　成分（ｂ）がノニオン性界面活性剤（ＨＬＢ：１５．５）である添加剤組成物を用いたこと以外は、実施例１と同様にして水油混合新燃料を製造した。得られた水油混合新燃料は透明を呈しており、総発熱量は４４．６ＭＪ／ｋｇであり、比重は０．８６７ｇ／ｃｍ３であった。 <Example 3>
A water-oil mixed new fuel was produced in the same manner as in Example 1 except that the additive composition in which the component (b) was a nonionic surfactant (HLB: 15.5) was used. The obtained water-oil mixed new fuel was transparent, the total calorific value was 44.6 MJ / kg, and the specific gravity was 0.867 g / cm 3 .
　＜比較例１＞
　成分（ｂ）がノニオン性界面活性剤（ＨＬＢ：４．０）である添加剤組成物を用いたこと以外は、実施例１と同様にして水油混合燃料を製造した。得られた水油混合燃料は乳白色を呈しており、総発熱量は３９．３ＭＪ／ｋｇであり、比重は０．８９３ｇ／ｃｍ３であった。 <Comparative Example 1>
A water / oil mixed fuel was produced in the same manner as in Example 1 except that the additive composition in which the component (b) was a nonionic surfactant (HLB: 4.0) was used. The obtained water / oil mixed fuel was milky white, had a total calorific value of 39.3 MJ / kg, and a specific gravity of 0.893 g / cm 3 .
　＜比較例２＞
　成分（ｂ）がノニオン性界面活性剤（ＨＬＢ：１６．７）である添加剤組成物を用いたこと以外は、実施例１と同様にして水油混合燃料を製造した。得られた水油混合燃料は乳白色を呈しており、総発熱量は３９．２ＭＪ／ｋｇであり、比重は０．９０５ｇ／ｃｍ３であった。 <Comparative Example 2>
A water / oil mixed fuel was produced in the same manner as in Example 1 except that the additive composition in which the component (b) was a nonionic surfactant (HLB: 16.7) was used. The obtained water / oil mixed fuel was milky white, had a total calorific value of 39.2 MJ / kg, and a specific gravity of 0.905 g / cm 3 .
１　　　第一内部空間
２　　　第二内部空間
５　　　外ケース
６　　　軟質薄膜層
６ａ　　カット孔
Ｗ１　　カット孔の大きさ
ｗ１　　カット孔の幅
１０　　ホッパー
１１　　コンベア
１２　　粉体計量器
１３　　加温器
２０　　第一調合タンク
２１　　撹拌棒（ホモミキサー）
２２　　燃料原料供給ライン
２２ｐ　ポンプ
２３　　添加剤供給ライン
２３ｐ　ポンプ
２４　　第一混合物移送ライン
２４ｐ　ポンプ
２６　　粒子化混合器（ナノＢｏｘ）
３０　　第二調合タンク
３１　　撹拌棒（ホモミキサー）
３２　　水供給ライン
３２ｐ　ポンプ
３３　　循環ライン
３３ｐ　ポンプ
３４　　第二混合物移送ライン
３４ｐ　ポンプ
３６　　第一粒子化装置
３６ａ　高圧ノズル
３６ｂ　粒子化混合器
３７　　第二粒子化装置
３７ａ　粒子化混合器
３７ｂ　ベンチュリー管
４０　　粒子化安定器（又は静止装置）
４１　　燃料移送ライン
４２　　ろ過装置
４３ｐ　ポンプ
５０　　貯蔵タンク DESCRIPTION OF SYMBOLS 1 1st internal space 2 2nd internal space 5 Outer case 6 Soft thin film layer 6a Cut hole W1 Cut hole size w1 Cut hole width 10 Hopper 11 Conveyor 12 Powder meter 13 Heater 20 First preparation tank 21 Stir bar (homomixer)
22 Fuel raw material supply line 22p Pump 23 Additive supply line 23p Pump 24 First mixture transfer line 24p Pump 26 Particulate mixer (Nano Box)
30 Second mixing tank 31 Stir bar (homomixer)
32 Water supply line 32p Pump 33 Circulation line 33p Pump 34 Second mixture transfer line 34p Pump 36 First particleizer 36a High pressure nozzle 36b Particleizer 57 Second particleizer 37a Particleizer 37b Venturi tube 40 Particleization Ballast (or stationary device)
41 Fuel transfer line 42 Filtration device 43p Pump 50 Storage tank

Claims (7)

  1. 　炭化水素系溶媒中に、
    成分（ａ）：ヒマシ油又はオリーブ油と、
    成分（ｂ）：ＨＬＢが８．０～１５．５であるノニオン性界面活性剤と、
    成分（ｃ）：カーボンと
    を含有し、
    前記成分（ａ）の含有率が３～１０重量％であり、前記成分（ｂ）の含有率が３～１０重量％であり、前記成分（ｃ）の含有率が２０～４０重量％である水油混合新燃料製造用添加剤組成物。     In hydrocarbon solvents,
    Component (a): castor oil or olive oil;
    Component (b): a nonionic surfactant having an HLB of 8.0 to 15.5,
    Component (c): containing carbon,
    The content of component (a) is 3 to 10% by weight, the content of component (b) is 3 to 10% by weight, and the content of component (c) is 20 to 40% by weight. Additive composition for water / oil mixed new fuel production.
  2. 　成分（ｄ）：２５℃における表面張力が２５～７０ｄｙｎｅ／ｃｍの洗浄剤
    を更に含有する請求項１に記載の水油混合新燃料製造用添加剤組成物。     Component (d): The additive composition for producing a new water / oil mixed fuel according to claim 1, further comprising a cleaning agent having a surface tension at 25 ° C of 25 to 70 dyne / cm.
  3. 　炭化水素系溶媒中に、
    成分（ａ）：ヒマシ油又はオリーブ油と、
    成分（ｂ）：ＨＬＢが８．０～１５．５であるノニオン性界面活性剤と、
    成分（ｃ）：カーボンと、
    成分（ｄ）：２５℃における表面張力が２５～７０ｄｙｎｅ／ｃｍの洗浄剤と
    を含有する水油混合新燃料製造用添加剤組成物。     In hydrocarbon solvents,
    Component (a): castor oil or olive oil;
    Component (b): a nonionic surfactant having an HLB of 8.0 to 15.5,
    Component (c): carbon,
    Component (d): An additive composition for producing a water / oil mixed new fuel comprising a cleaning agent having a surface tension at 25 ° C. of 25 to 70 dyne / cm.
  4. 　前記成分（ｄ）の含有率が２重量％以下である請求項２又は３に記載の水油混合新燃料製造用添加剤組成物。 The additive composition for producing a new mixed oil / water fuel according to claim 2 or 3, wherein the content of the component (d) is 2% by weight or less.
  5. 　前記成分（ｃ）が、平均粒径１０～７０μｍの多孔質カーボンである請求項１～３のいずれか１項に記載の水油混合新燃料製造用添加剤組成物。 4. The additive composition for producing a new water / oil mixed fuel according to claim 1, wherein the component (c) is porous carbon having an average particle size of 10 to 70 μm.
  6. 　炭化水素系溶媒中に、
    成分（ａ）：ヒマシ油又はオリーブ油と、
    成分（ｂ）：ＨＬＢが８．０～１５．５であるノニオン性界面活性剤と、
    成分（ｃ）：平均粒径１０～７０μｍの多孔質カーボンと
    を含有する水油混合新燃料製造用添加剤組成物。     In hydrocarbon solvents,
    Component (a): castor oil or olive oil;
    Component (b): a nonionic surfactant having an HLB of 8.0 to 15.5,
    Component (c): An additive composition for producing a water-oil mixed new fuel containing porous carbon having an average particle size of 10 to 70 μm.
  7. 　前記炭化水素系溶媒が、ガソリン、灯油、軽油、又は重油である請求項１、３又は６に記載の水油混合新燃料製造用添加剤組成物。 The additive composition for water / oil mixed new fuel production according to claim 1, wherein the hydrocarbon solvent is gasoline, kerosene, light oil, or heavy oil.
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS606987B2 (en) * 1981-02-24 1985-02-21 角岡 孝逸 Combustion aid additive
JPS609553B2 (en) * 1980-10-22 1985-03-11 パウロ エス テ− フオン Surfactant used in emulsified fuel composition
JP2001011477A (en) * 1999-06-30 2001-01-16 Goro Ishida Surface active agent composition and emulsified fuel containing the same
JP2005133031A (en) * 2003-10-31 2005-05-26 Masayuki Furuno Additive for oil/water mixed fuel
JP2010275380A (en) * 2009-05-27 2010-12-09 Nakai Giken:Kk Emulsion fuel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS609553B2 (en) * 1980-10-22 1985-03-11 パウロ エス テ− フオン Surfactant used in emulsified fuel composition
JPS606987B2 (en) * 1981-02-24 1985-02-21 角岡 孝逸 Combustion aid additive
JP2001011477A (en) * 1999-06-30 2001-01-16 Goro Ishida Surface active agent composition and emulsified fuel containing the same
JP2005133031A (en) * 2003-10-31 2005-05-26 Masayuki Furuno Additive for oil/water mixed fuel
JP2010275380A (en) * 2009-05-27 2010-12-09 Nakai Giken:Kk Emulsion fuel

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