WO2016051788A1 - ガス吸着体、ガス吸着体の製造方法、及びガラスパネルユニット - Google Patents
ガス吸着体、ガス吸着体の製造方法、及びガラスパネルユニット Download PDFInfo
- Publication number
- WO2016051788A1 WO2016051788A1 PCT/JP2015/004964 JP2015004964W WO2016051788A1 WO 2016051788 A1 WO2016051788 A1 WO 2016051788A1 JP 2015004964 W JP2015004964 W JP 2015004964W WO 2016051788 A1 WO2016051788 A1 WO 2016051788A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- glass panel
- gas
- glass
- getter
- seal
- Prior art date
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28023—Fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0211—Compounds of Ti, Zr, Hf
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0214—Compounds of V, Nb, Ta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
- B01J20/0229—Compounds of Fe
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0248—Compounds of B, Al, Ga, In, Tl
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3204—Inorganic carriers, supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3234—Inorganic material layers
- B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3234—Inorganic material layers
- B01J20/3238—Inorganic material layers containing any type of zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3287—Layers in the form of a liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/66—Units comprising two or more parallel glass or like panes permanently secured together
- E06B3/6612—Evacuated glazing units
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
- B01D2253/1122—Metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/42—Materials comprising a mixture of inorganic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/249—Glazing, e.g. vacuum glazing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings
- Y02B80/22—Glazing, e.g. vaccum glazing
Definitions
- the present invention relates to a gas adsorber, a method for producing the gas adsorber, and a glass panel unit.
- Document 1 International Publication No. 2014/004936 discloses a multilayer glass.
- the multilayer glass disclosed in Document 1 includes two sheet glasses, a sealed space formed between the two sheet glasses, and an adsorbent disposed in the sealed space.
- the adsorbent is disposed in the sealed space in order to adsorb unnecessary gas in the sealed space.
- This adsorbent is formed by applying a solution obtained by dissolving an adsorbing substance in a solvent to one plate glass and drying it.
- the adsorbent may not have a desired shape, which has a problem in productivity.
- the problem to be solved by the present invention is to obtain a gas adsorbent having excellent productivity and high gas adsorption capacity.
- the gas adsorbent in the form according to the present invention is formed from a base material formed of inorganic material fibers or a porous body, and a liquid containing a getter attached to the base material.
- a gas adsorbent manufacturing method wherein the gas adsorbent manufacturing method includes preparing a substrate formed of fibers or a porous material of an inorganic material and a liquid containing a getter. A preparation step, and an attachment step of attaching the liquid to the substrate.
- the glass panel unit of the other form which concerns on this invention is the 1st glass panel, the 2nd glass panel arrange
- Embodiment] [1-1. Configuration of gas adsorber] 1 and 2 show a glass panel unit 10 including a gas adsorber 60 according to an embodiment of the present invention.
- the gas adsorber 60 of this embodiment is used for a glass panel unit.
- the gas adsorber 60 is formed of a base material 61 formed of inorganic material fibers or a porous material, and a liquid containing a getter attached to the base material 61.
- the gas adsorbent 60 includes a base 61 formed of inorganic material fibers or a porous body, and a getter fixed to the base 61.
- the gas adsorber 60 is long in this embodiment.
- the size of the gas adsorber 60 is appropriately set according to the glass panel unit to be used.
- the height is 0.1 mm to 1 cm
- the length is 10 cm to 3 m
- the width is 0.1 cm to 10 cm. is there.
- the substrate 61 is formed of inorganic material fibers. Or the base material 61 is formed with the porous body of an inorganic material.
- the base material 61 functions as a carrier that supports the getter.
- the inorganic material forming the substrate 61 may be glass or metal. Therefore, the fiber of the inorganic material which comprises the base material 61 may be a glass fiber or a metal fiber.
- the metal forming the substrate 61 is, for example, a stable metal that does not change, deform (melt), or the like at an activation temperature of the getter (for example, 350 ° C.) or higher.
- the substrate 61 may be a woven fabric, a nonwoven fabric, or a fiber bundle formed of inorganic material fibers.
- the substrate 61 may be, for example, glass cloth, glass wool, metal woven fabric, or metal wool.
- the porous body of the inorganic material that forms the substrate 61 may be porous glass or porous metal. More specifically, the porous body of the inorganic material may be a foam metal.
- the base material 61 formed of fibers or a porous body has a relatively large specific surface area.
- the base material 61 formed of inorganic material fibers or a porous body has a larger surface area even if it is the same size (or the same weight) as the base material 61 formed of an inorganic material plate. Therefore, a relatively large amount of getter is fixed to the substrate 61 formed of fibers or a porous body. Further, the getter fixed to the base member 61 comes into contact with more space, and it becomes easy to adsorb gas. Therefore, the gas adsorber 60 having the base material 61 formed of fibers or a porous body can have a high adsorption capacity.
- the base material 61 defines the shape of the gas adsorber 60. In this embodiment, since the gas adsorber 60 is long, the base 61 is also long.
- the size of the substrate 61 is, for example, 0.1 mm to 1 cm in height, 10 cm to 3 m in length, and 0.1 cm to 10 cm in width.
- the length of the fibers constituting the substrate 61 is, for example, 5 mm to 1 m, and the diameter is, for example, 0.1 ⁇ m to 1 cm.
- Getter is a material having the property of adsorbing molecules smaller than a predetermined size.
- the getter is a material that adsorbs gas.
- the getter is, for example, an evaporation type getter.
- the evaporable getter has a property of releasing adsorbed molecules when the temperature is higher than a predetermined temperature (activation temperature). Therefore, even if the adsorption ability of the evaporable getter is reduced, the adsorption ability of the evaporable getter can be recovered by heating the evaporable getter to the activation temperature or higher.
- the getter may be a non-evaporable getter.
- Non-evaporable getters unlike evaporative getters, have the property of not releasing molecules once adsorbed.
- the non-evaporable getter adsorbs a certain amount of molecules or more, even if the non-evaporable getter is heated to an activation temperature or higher, the adsorption ability is not recovered.
- the getter is a zeolite, an ion exchanged zeolite (eg, a copper ion exchanged zeolite), an Fe—V—Zr alloy, or a Ba—Al alloy.
- the manufacturing method of the gas adsorbent 60 according to the present embodiment includes a preparation process, an adhesion process, and a drying process.
- the drying step may be omitted.
- a base material 61 and a liquid containing a getter are prepared.
- the liquid containing the getter can be obtained by stirring the liquid obtained by adding the getter to the solvent.
- the liquid containing the getter is a getter solution.
- the solution containing the getter is a getter dispersion.
- the solvent is preferably a solvent that hardly reduces the adsorption ability of the getter.
- the solvent is, for example, water, alcohol, or an aqueous solution containing alcohol.
- the alcohol is, for example, ethanol, isopropyl alcohol, or terpineol.
- the solvent used in the present embodiment may have a relatively high volatility at room temperature and may have a boiling point of 70 ° C. or lower. Considering the affinity with the base material 61 (easiness of soaking when the liquid is attached to the base material 61), preferred solvents are ethanol and isopropyl alcohol.
- the specific gravity of the solvent is preferably smaller than the specific gravity of the getter. If a solvent having a specific gravity smaller than that of the getter is used, the specific gravity of the liquid can be made smaller than that of the getter, and the liquid can be easily penetrated into the substrate 61.
- a liquid containing a getter is attached to the substrate 61.
- a liquid containing getter is applied to the substrate 61.
- the substrate 61 is impregnated with a liquid containing a getter.
- a liquid containing a getter may be sprayed on the substrate 61.
- the substrate 61 to which the liquid containing the getter is attached is dried. That is, the solvent contained in the liquid containing the getter is volatilized. Drying of the substrate 61 (solvent volatilization) may be performed by natural drying, or may be performed by forced drying such as heating or blowing. As the solvent volatilizes, the getter is fixed to the substrate 61.
- the gas adsorbent 60 is obtained through the preparation process, the adhesion process, and the drying process described above.
- the gas adsorbent 60 is formed by using the base 61 having a relatively large specific surface area, which is made of inorganic fiber or porous material. Therefore, the gas adsorber 60 has a relatively large amount of getter, and this getter can contact a relatively large amount of space. Therefore, according to the present embodiment, it is possible to obtain the gas adsorbent 60 having a high adsorption capacity. Further, according to the present embodiment, the shape of the gas adsorber 60 is determined by the shape of the base material 61 to be prepared. Therefore, the gas adsorber 60 having a desired shape can be easily obtained with high productivity.
- the gas adsorber 60 of this embodiment is used for the glass panel unit 10.
- the glass panel unit 10 of this embodiment is a vacuum heat insulating glass unit.
- the vacuum heat insulating glass unit is a kind of multilayer glass panel including at least a pair of glass panels, and has a vacuum space between the pair of glass panels.
- the glass panel unit 10 includes a first glass panel 20, a second glass panel 30, a seal 40, a vacuum space 50, a gas adsorber 60, And a plurality of spacers 70.
- the first glass panel 20 includes a main body 21 that defines a planar shape of the first glass panel 20 and a coating 22.
- the main body 21 has a rectangular shape and has a first surface (a lower surface in FIG. 1) and a second surface (an upper surface in FIG. 1) parallel to each other in the thickness direction. Both the first surface and the second surface of the main body 21 are flat surfaces.
- the material of the main body 21 is, for example, soda lime glass, high strain point glass, chemically tempered glass, alkali-free glass, quartz glass, neoceram, or physically tempered glass.
- the coating 22 is formed on the first surface of the main body.
- the coating 22 is an infrared reflecting film.
- the coating 22 is not limited to the infrared reflecting film, and may be a film having desired physical characteristics.
- the second glass panel 30 includes a main body 31 that defines the planar shape of the second glass panel 30.
- the planar shape and planar size of the main body 31 are the same as those of the main body 21 (that is, the planar shape of the second glass panel 30 is the same as that of the first glass panel 20).
- the thickness of the main body 31 is the same as that of the main body 21.
- the material of the main body 31 is, for example, soda lime glass, high strain point glass, chemically tempered glass, alkali-free glass, quartz glass, neoceram, or physically tempered glass.
- the main body 31 has a rectangular shape and has a first surface (upper surface in FIG. 1) and a second surface (lower surface in FIG. 1) parallel to each other in the thickness direction. Both the first surface and the second surface of the main body 31 are flat surfaces.
- the second glass panel 30 is composed only of the main body 31. That is, the main body 31 is the second glass panel 30 itself.
- the second glass panel 30 is disposed so as to face the first glass panel 20.
- the first glass panel 20 and the second glass panel 30 are arranged such that the first surface of the main body 21 and the first surface of the main body 31 are parallel to and opposed to each other. That is, the second surface of the main body 21 is directed to the outside of the glass panel unit 10, and the first surface of the main body 21 is directed to the inside of the glass panel unit 10. Further, the first surface of the main body 31 is directed to the inside of the glass panel unit 10, and the second surface of the main body 31 is directed to the outside of the glass panel unit 10.
- the seal 40 is disposed between the first glass panel 20 and the second glass panel 30 and joins the first glass panel 20 and the second glass panel 30 in an airtight manner. As a result, a space surrounded by the seal 40, the first glass panel 20, and the second glass panel 30 is formed.
- the degree of vacuum (pressure) of this space is equal to or less than a predetermined value, and is referred to as a vacuum space 50.
- the seal 40 is formed of a thermal adhesive.
- the thermal adhesive is, for example, a glass frit.
- the glass frit is, for example, a low melting point glass frit.
- the low melting point glass frit is, for example, a bismuth glass frit, a lead glass frit, or a vanadium glass frit.
- the seal 40 has a rectangular frame shape.
- the planar shape of the seal 40 is the same as the main bodies 21 and 31, but the planar size of the seal 40 is smaller than the main bodies 21 and 31.
- the seal 40 is formed along the outer periphery of the second glass panel 30. That is, the seal 40 is formed so as to surround almost all the region on the second glass panel 30.
- the vacuum space 50 is a space whose degree of vacuum is a predetermined value or less, and the predetermined value is, for example, 0.1 Pa. Since the vacuum space 50 is completely sealed by the first glass panel 20, the second glass panel 30, and the seal 40, it is separated from the outside air.
- the plurality of spacers 70 are used to maintain the distance between the first glass panel 20 and the second glass panel 30 at a predetermined distance. That is, the plurality of spacers 70 are used to maintain the distance between the first glass panel 20 and the second glass panel 30 at a desired value.
- the plurality of spacers 70 are arranged in the vacuum space 50. Specifically, the plurality of spacers 70 are arranged at intersections of virtual rectangular grids. For example, the interval between the plurality of spacers 70 is 2 cm. However, the size of the spacers 70, the number of the spacers 70, the interval between the spacers 70, and the arrangement pattern of the spacers 70 can be selected as appropriate.
- the spacer 70 has a cylindrical shape having a height substantially equal to the predetermined interval.
- the spacer 70 has a diameter of 1 mm and a height of 100 ⁇ m.
- Each spacer 70 may have a desired shape such as a prismatic shape or a spherical shape.
- the spacer 70 is formed using a transparent material. However, each spacer 70 may be formed using an opaque material as long as it is sufficiently small.
- the spacer 70 is preferably less deformable than the seal 40.
- the material of the spacer 70 is selected to have a higher softening point (softening temperature) than the material of the seal 40.
- the gas adsorber 60 is disposed in the vacuum space 50. Specifically, the gas adsorber 60 has a long shape, and is arranged on one end side (left end side in FIG. 2) in the length direction of the second glass panel 30 in the width direction (FIG. 2). (Vertical direction). That is, the gas adsorber 60 is disposed at the end of the vacuum space 50. In this way, the gas adsorber 60 can be made inconspicuous.
- the gas adsorber 60 is fixed to the second glass panel 30. Further, the gas adsorber 60 is not in contact with the seal 40.
- the height of the gas adsorber 60 (the length in the vertical direction in FIG. 1) is smaller than the predetermined interval.
- the gas adsorber 60 is used for adsorbing unnecessary gas (residual gas or the like).
- the unnecessary gas is, for example, a gas released from the seal 40 when the material of the seal 40 is heated to form the seal 40 while airtightly bonding the first glass panel 20 and the second glass panel 30. is there.
- the gas adsorber 60 is less likely to be softened (not easily melted) than the seal 40 of the glass panel unit 10.
- the substrate 61 of the gas adsorber 60 is selected to have a higher softening point (melting point) than the material of the seal 40.
- the manufacturing method of the glass panel unit 10 of this embodiment includes first to sixth steps. Note that the order of the second to fourth steps may be changed as appropriate.
- the first step is a step of forming the first glass panel 20 and the second glass panel 30 (panel forming step).
- the first glass panel 20 and the second glass panel 30 are prepared.
- the first glass panel 20 and the second glass panel 30 are washed as necessary.
- the second step is a step of forming the seal 40 (a seal forming step).
- the material (thermal adhesive) of the seal 40 is applied onto the second glass panel 30 (the first surface of the main body 31) using a dispenser or the like.
- the third step is a step of arranging the gas adsorber 60 (gas adsorber arrangement step).
- the gas adsorber 60 is disposed at a predetermined position on the second glass panel 30 (the first surface of the main body 31).
- the gas adsorber 60 may be fixed as well as disposed on the second glass panel 30.
- the gas adsorber 60 manufactured by the above-described manufacturing method may be fixed to the second glass panel 30 using a thermal adhesive (for example, the glass frit).
- the material of the seal 40 thermal adhesive
- Adhesion (fixation) with a material is preferable because it is efficient.
- the base material 61 to which the liquid containing the getter is attached (that is, the base material 61 obtained through the above-described attachment process) is disposed on the second glass panel 30. Then, the substrate 61 is dried on the second glass panel 30. Thereby, the gas adsorber 60 is formed on the second glass panel 30 and further fixed.
- the fourth step is a step of forming the spacer 70 (spacer forming step).
- a plurality of spacers 70 are formed in advance, and the plurality of spacers 70 are arranged at predetermined positions on the second glass panel 30 using a chip mounter or the like.
- the plurality of spacers 70 may be formed using a photolithography technique and an etching technique. In this case, the plurality of spacers 70 are formed using a photocurable material or the like. Alternatively, the plurality of spacers 70 may be formed using a known thin film forming technique.
- the fifth step is a step (arrangement step) in which the first glass panel 20 and the second glass panel 30 are arranged.
- the first glass panel 20 and the second glass panel 30 are arranged so that the first surface of the main body 21 and the first surface of the main body 31 are parallel to and opposed to each other.
- the sixth step is a step of airtightly bonding the first glass panel 20 and the second glass panel 30 with the seal 40.
- the material of the seal 40 is heated and melted once while the first glass panel 20 is in contact with the material of the seal 40 applied to the second glass panel 30.
- sticker 40 is solidified and the seal
- an appropriate method can be used as a method of forming the vacuum space 50.
- an exhaust port is provided in any of the first glass panel 20, the second glass panel 30, and the seal 40. Then, in the sixth step, the space surrounded by the first glass panel 20, the second glass panel 30, and the seal 40 is exhausted from the exhaust port, and then the vacuum port 50 is formed by closing the exhaust port. Can do.
- the vacuum space 50 can be formed by airtightly bonding the first glass panel 20 and the second glass panel 30 under vacuum.
- the glass panel unit 10 is obtained through the first to sixth steps described above.
- Modification 1] 3 and 4 show a glass panel unit 10 including the gas adsorbent 60 of Modification 1 of the embodiment according to the present invention.
- the gas adsorber (60) of Modification 1 is fixed to the seal (40), unlike the gas adsorber (60) of FIGS. 1 and 2. That is, the gas adsorber (60) is in contact with the seal (40).
- the gas adsorbent (60) of Modification 1 can be formed by the same material and the same manufacturing method as those of the gas adsorbent (60) of FIGS.
- the gas adsorber 60 has a long shape (I shape), and the width of the second glass panel 30 on one end side in the length direction of the second glass panel 30 (left end side in FIG. 4). It arrange
- the gas adsorber 60 since the gas adsorber 60 having a desired shape can be easily obtained, the gas adsorber 60 is U-shaped along the three sides of the rectangular frame-shaped seal 40. Alternatively, it may be L-shaped along two sides.
- the gas adsorbent (60) of Modification 1 is disposed on the second glass panel (30) (the first surface of the main body (31)) so as to contact the material of the seal (40). The If it does in this way, in the 6th process, when the material of the applied seal (40) is heated and the 1st glass panel (20) and the 2nd glass panel (30) are joined airtightly, gas adsorption The body (60) can be secured to the seal (40).
- the gas adsorber (60) of Modification 2 is different from the gas adsorber (60) shown in FIGS. 1 to 4 in the first glass panel (20) and the second glass panel (30). It is sandwiched and fixed.
- the gas adsorber (60) of the modified example 2 can be formed by the same material and the same manufacturing method as the gas adsorber (60) of FIGS.
- the height (length in the vertical direction in FIG. 5) of the gas adsorbent (60) of Modification 2 is equal to the predetermined interval. Therefore, for example, in the sixth step, the first glass panel (20) and the second glass panel (30) so that the distance between the first glass panel (20) and the second glass panel (30) is the predetermined distance. And the gas adsorber (60) is sandwiched and fixed between the first glass panel (20) and the second glass panel (30). Note that the gas adsorbent (60) of Modification 2 may not be bonded to the second glass panel 30, but may be bonded.
- the gas adsorber (60) has a long shape, but may have other shapes. Further, the gas adsorber (60) does not necessarily have to be at the end of the vacuum space (50). 1 to 4, the gas adsorbent (60) is fixed to the second glass panel 30, but may be fixed to the first glass panel 20.
- the glass panel unit (10) has a rectangular shape, but the glass panel unit (10) may have a desired shape such as a circular shape or a polygonal shape. That is, the first glass panel (20), the second glass panel (30), and the seal (40) may have a desired shape such as a circular shape or a polygonal shape instead of a rectangular shape.
- size of a glass panel unit (10) are determined according to the use of a glass panel unit (10).
- first surface and the second surface of the main body (21) of the first glass panel (20) are not limited to flat surfaces.
- neither the first surface nor the second surface of the main body (31) of the second glass panel (30) is limited to a flat surface.
- main body (21) of the first glass panel (20) and the main body (31) of the second glass panel (30) may not have the same planar shape and planar size. Moreover, the main body (21) and the main body (31) may not have the same thickness. Moreover, the main body (21) and the main body (31) may not be formed of the same material.
- the seal (40) may not have the same planar shape as the first glass panel (20) and the second glass panel (30).
- the first glass panel (20) may further include a coating having desired physical properties and formed on the second plane of the main body (21).
- the first glass panel (20) may not include the coating (22). That is, the 1st glass panel (20) may be comprised only with the main body (21).
- the second glass panel (30) may further include a coating having desired physical characteristics.
- the coating only needs to include at least one of thin films formed on the first surface and the second surface of the main body (31), for example.
- the coating is, for example, a film that reflects light of a specific wavelength (infrared reflective film, ultraviolet reflective film).
- the glass panel unit (10) includes a plurality of spacers (70), but the glass panel unit (10) may include a single spacer (70). Alternatively, the glass panel unit (10) may not include the spacer (70).
- the gas adsorbent (60) includes a base material (61) formed of inorganic material fibers or a porous body, And a liquid containing a getter attached to the substrate (61).
- a gas adsorbent (60) having excellent productivity and high gas adsorption capacity can be obtained.
- the gas adsorber (60) of the second embodiment according to the present invention is realized by a combination with the first embodiment.
- the inorganic material is glass.
- the gas adsorbent (60) whose thermal expansion coefficient and thermal conductivity are close to the glass panels (20, 30) and the seal (40).
- the gas adsorber (60) of the third embodiment according to the present invention is realized by a combination with the first embodiment.
- the inorganic material is a metal.
- a gas adsorbent (60) having sufficient strength can be obtained.
- a method for producing a gas adsorbent according to a fourth aspect of the present invention is a method for producing a gas adsorbent (60) according to any one of the first to third aspects, and is a fiber or porous body of an inorganic material.
- the preparation process which prepares the base material (61) formed by (1) and the liquid containing a getter, and the adhesion process which adheres the said liquid to a base material (61) are included.
- a gas adsorbent (60) having excellent productivity and high gas adsorption capacity can be obtained.
- the glass panel unit (10) of the 5th form concerning the present invention is the 1st glass panel (20), the 2nd glass panel (30) arranged so as to oppose the 1st glass panel (20), Surrounded by a seal (40) that hermetically bonds the first glass panel (20) and the second glass panel (30), and the first glass panel (20), the second glass panel (30), and the seal (40). And a gas adsorbent (60) of any one of the first to third embodiments disposed in the vacuum space (50).
- the glass panel unit (10) including the gas adsorbent (60) having excellent productivity and high gas adsorbing ability.
- the glass panel unit (10) according to the sixth embodiment of the present invention is realized by a combination with the fifth embodiment.
- the gas adsorber (60) is fixed to the seal (40).
- the gas adsorber (60) can be easily fixed.
- the glass panel unit (10) of the seventh embodiment according to the present invention is realized by a combination with the fifth embodiment.
- the gas adsorber (60) is sandwiched and fixed between the first glass panel (20) and the second glass panel (30).
- the gas adsorber (60) can be easily fixed.
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Joining Of Glass To Other Materials (AREA)
- Securing Of Glass Panes Or The Like (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
[1-1.ガス吸着体の構成]
図1および図2は、本発明に係る一実施形態のガス吸着体60を備えるガラスパネルユニット10を示す。
次に、本実施形態のガス吸着体60の製造方法について説明する。
本実施形態のガス吸着体60は、ガラスパネルユニット10に用いられる。本実施形態のガラスパネルユニット10は、真空断熱ガラスユニットである。真空断熱ガラスユニットは、少なくとも一対のガラスパネルを備える複層ガラスパネルの一種であって、一対のガラスパネル間に真空空間を有している。
次に、本実施形態のガラスパネルユニット10の製造方法について説明する。本実施形態のガラスパネルユニット10の製造方法は、第1~第6工程を有する。なお、第2~第4工程の順番は、適宜変更してもよい。
図3および図4は、本発明に係る一実施形態の変形例1のガス吸着体60を備えるガラスパネルユニット10を示す。
図5および図6は、本発明に係る一実施形態の変形例2のガス吸着体(60)を備えるガラスパネルユニット10を示す。
上記実施形態では、ガス吸着体(60)は、長尺状であるが、他の形状であってもよい。また、ガス吸着体(60)は、必ずしも真空空間(50)の端にある必要はない。また、図1~4の例では、ガス吸着体(60)は第2ガラスパネル30に固定されているが、第1ガラスパネル20に固定されていてもよい。
以上述べた実施形態および変形例から明らかなように、本発明に係る第1の形態のガス吸着体(60)は、無機材料の繊維あるいは多孔質体で形成された基材(61)と、基材(61)に付着されたゲッタを含む液体とから形成される。
Claims (7)
- 無機材料の繊維あるいは多孔質体で形成された基材と、前記基材に付着されたゲッタを含む液体とから形成される、
ガス吸着体。 - 前記無機材料はガラスである、
請求項1に記載のガス吸着体。 - 前記無機材料は金属である、
請求項1に記載のガス吸着体。 - 請求項1~3のいずれか一項に記載のガス吸着体の製造方法であって、
無機材料の繊維あるいは多孔質体で形成された基材と、ゲッタを含む液体とを準備する準備工程と、
前記液体を前記基材に付着させる付着工程と、を含む
ガス吸着体の製造方法。 - 第1ガラスパネルと、
前記第1ガラスパネルに対向するように配置された第2ガラスパネルと、
前記第1ガラスパネルと前記第2ガラスパネルとを気密に接合するシールと、
前記第1ガラスパネルと前記第2ガラスパネルと前記シールとに囲まれた真空空間と、
前記真空空間内に配置される請求項1~3のいずれか一項に記載のガス吸着体と、
を備える、
ガラスパネルユニット。 - 前記ガス吸着体は前記シールに固定されている、
請求項5に記載のガラスパネルユニット。 - 前記ガス吸着体は前記第1ガラスパネルと前記第2ガラスパネルとに挟まれて固定されている、
請求項5に記載のガラスパネルユニット。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201580049833.XA CN107073441B (zh) | 2014-09-30 | 2015-09-30 | 气体吸附体、气体吸附体的制备方法、玻璃面板单元 |
US15/507,053 US10376863B2 (en) | 2014-09-30 | 2015-09-30 | Gas adsorbent, gas adsorbent manufacturing method, glass panel unit |
JP2016551551A JP6454947B2 (ja) | 2014-09-30 | 2015-09-30 | ガラスパネルユニット、及びガラスパネルユニットの製造方法 |
DE112015004489.2T DE112015004489T5 (de) | 2014-09-30 | 2015-09-30 | Gasadsorptionsmittel, Verfahren zur Herstellung eines Gasadsorptionsmittels, Glasplatteneinheit |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014200976 | 2014-09-30 | ||
JP2014-200976 | 2014-09-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2016051788A1 true WO2016051788A1 (ja) | 2016-04-07 |
Family
ID=55629855
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2015/004964 WO2016051788A1 (ja) | 2014-09-30 | 2015-09-30 | ガス吸着体、ガス吸着体の製造方法、及びガラスパネルユニット |
Country Status (5)
Country | Link |
---|---|
US (1) | US10376863B2 (ja) |
JP (1) | JP6454947B2 (ja) |
CN (1) | CN107073441B (ja) |
DE (1) | DE112015004489T5 (ja) |
WO (1) | WO2016051788A1 (ja) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102017217549A1 (de) | 2016-10-03 | 2018-04-05 | Hitachi Chemical Company, Ltd. | Unterdruckwärmeisolationselement, dafür verwendetes Abdichtungsmaterial und Herstellungsverfahren für das Unterdruckwärmeisolationselement |
EP3656748A1 (en) | 2018-11-26 | 2020-05-27 | Hitachi Chemical Company, Ltd. | Gas trapping member and vacuum heat insulation equipment |
US20210300822A1 (en) * | 2018-07-18 | 2021-09-30 | Panasonic Intellectual Property Management Co., Ltd. | Glass panel unit and method for manufacturing the glass panel unit |
WO2023157686A1 (ja) * | 2022-02-16 | 2023-08-24 | 日本板硝子株式会社 | 複層ガラスパネル |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2734069T3 (es) * | 2014-09-30 | 2019-12-04 | Panasonic Ip Man Co Ltd | Unidad de panel de vidrio y procedimiento de inspección de la misma |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1176719A (ja) * | 1997-09-12 | 1999-03-23 | Takasago Thermal Eng Co Ltd | 空気浄化フィルタ |
JP2002046198A (ja) * | 2000-08-03 | 2002-02-12 | Nichias Corp | ハニカム構造体及びその製造方法 |
JP2007063535A (ja) * | 2005-07-18 | 2007-03-15 | E I Du Pont De Nemours & Co | 雰囲気制御に使用するための事前水和された乾燥剤を含む厚膜ゲッターペースト組成物 |
JP2009167041A (ja) * | 2008-01-15 | 2009-07-30 | Panasonic Corp | ガラスパネル |
JP2012183534A (ja) * | 2005-12-20 | 2012-09-27 | Mitsubishi Chemicals Corp | 吸着シート、吸着素子およびその製造方法ならびにこれらの用途 |
JP2014126501A (ja) * | 2012-12-27 | 2014-07-07 | Mitsubishi Materials Corp | 放射性セシウムの吸着材およびその製造方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5360572A (en) * | 1991-11-29 | 1994-11-01 | The United States Of America As Represented By The Secretary Of The Air Force | Aerogel mesh getter |
WO1998033575A1 (fr) | 1997-01-31 | 1998-08-06 | Takasago Thermal Engineering Co., Ltd. | Appareil de nettoyage, filtre et procede de fabrication de ceux-ci |
JPH10331532A (ja) | 1997-05-30 | 1998-12-15 | Central Glass Co Ltd | 低圧複層ガラスの製造方法 |
JP2000215807A (ja) | 1999-01-22 | 2000-08-04 | Saes Getters Japan Co Ltd | ゲッタ材を収容した平板状パネル表示装置の製造方法 |
DE10311830A1 (de) | 2003-03-14 | 2004-09-23 | Ensinger Kunststofftechnologie Gbr | Abstandhalterprofil für Isolierglasscheiben |
JP4529956B2 (ja) | 2006-07-13 | 2010-08-25 | 旭硝子株式会社 | 複層ガラス用スペーサ、複層ガラス、および複層ガラス用スペーサの製造方法 |
JP2010083720A (ja) | 2008-09-30 | 2010-04-15 | Kyodo Printing Co Ltd | 複層ガラス |
US20130136678A1 (en) * | 2010-07-12 | 2013-05-30 | Konstantin Chuntonov | Plate getter composites |
MX2014015668A (es) | 2012-06-28 | 2015-07-14 | Univ Tulane | Composiciones polimerizables selectivamente y metodos de uso in vivo. |
HUE052292T2 (hu) | 2013-03-04 | 2021-04-28 | Panasonic Ip Man Co Ltd | Többszörös tábla és a többszörös tábla elõállítási eljárása |
-
2015
- 2015-09-30 CN CN201580049833.XA patent/CN107073441B/zh active Active
- 2015-09-30 US US15/507,053 patent/US10376863B2/en active Active
- 2015-09-30 DE DE112015004489.2T patent/DE112015004489T5/de not_active Withdrawn
- 2015-09-30 WO PCT/JP2015/004964 patent/WO2016051788A1/ja active Application Filing
- 2015-09-30 JP JP2016551551A patent/JP6454947B2/ja active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1176719A (ja) * | 1997-09-12 | 1999-03-23 | Takasago Thermal Eng Co Ltd | 空気浄化フィルタ |
JP2002046198A (ja) * | 2000-08-03 | 2002-02-12 | Nichias Corp | ハニカム構造体及びその製造方法 |
JP2007063535A (ja) * | 2005-07-18 | 2007-03-15 | E I Du Pont De Nemours & Co | 雰囲気制御に使用するための事前水和された乾燥剤を含む厚膜ゲッターペースト組成物 |
JP2012183534A (ja) * | 2005-12-20 | 2012-09-27 | Mitsubishi Chemicals Corp | 吸着シート、吸着素子およびその製造方法ならびにこれらの用途 |
JP2009167041A (ja) * | 2008-01-15 | 2009-07-30 | Panasonic Corp | ガラスパネル |
JP2014126501A (ja) * | 2012-12-27 | 2014-07-07 | Mitsubishi Materials Corp | 放射性セシウムの吸着材およびその製造方法 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102017217549A1 (de) | 2016-10-03 | 2018-04-05 | Hitachi Chemical Company, Ltd. | Unterdruckwärmeisolationselement, dafür verwendetes Abdichtungsmaterial und Herstellungsverfahren für das Unterdruckwärmeisolationselement |
US20210300822A1 (en) * | 2018-07-18 | 2021-09-30 | Panasonic Intellectual Property Management Co., Ltd. | Glass panel unit and method for manufacturing the glass panel unit |
EP3656748A1 (en) | 2018-11-26 | 2020-05-27 | Hitachi Chemical Company, Ltd. | Gas trapping member and vacuum heat insulation equipment |
JP2020081968A (ja) * | 2018-11-26 | 2020-06-04 | 日立化成株式会社 | ガス捕捉材および真空断熱機器 |
US11643867B2 (en) | 2018-11-26 | 2023-05-09 | Panasonic Holdings Corporation | Gas trapping member and vacuum heat insulation equipment |
WO2023157686A1 (ja) * | 2022-02-16 | 2023-08-24 | 日本板硝子株式会社 | 複層ガラスパネル |
Also Published As
Publication number | Publication date |
---|---|
JPWO2016051788A1 (ja) | 2017-08-31 |
US20170274353A1 (en) | 2017-09-28 |
CN107073441B (zh) | 2019-12-17 |
DE112015004489T5 (de) | 2017-06-22 |
JP6454947B2 (ja) | 2019-01-23 |
US10376863B2 (en) | 2019-08-13 |
CN107073441A (zh) | 2017-08-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6454947B2 (ja) | ガラスパネルユニット、及びガラスパネルユニットの製造方法 | |
WO2016084382A1 (ja) | ガラスパネルユニット | |
JP6471916B2 (ja) | ガラスパネルユニット、ガラスパネルユニットの仮組立て品、ガラスパネルユニットの組立て品、ガラスパネルユニットの製造方法 | |
JP6455791B2 (ja) | ガラスパネルユニット及びその検査方法 | |
JP6395080B2 (ja) | ガラスパネルユニット、ガラスパネルユニットの組立て品、ガラスパネルユニットの製造方法 | |
TWI666375B (zh) | 玻璃平板單元及玻璃窗 | |
JP2019178063A (ja) | ガラスパネルユニットの製造方法 | |
WO2016084383A1 (ja) | ガラスパネルユニット | |
JP6767702B2 (ja) | ガラスパネルユニットおよびガラス窓 | |
US20190084877A1 (en) | Manufacturing method of glass panel unit | |
WO2018062140A1 (ja) | ガラスパネルユニット、ガラス窓およびガラスパネルユニットの製造方法 | |
WO2019230218A1 (ja) | ガラスパネルユニットの製造方法 | |
JP6854453B2 (ja) | ガラスパネルユニットの製造方法およびガラス窓の製造方法 | |
WO2019188312A1 (ja) | ガラスパネルユニットの製造方法及びガラス窓の製造方法 | |
EP3950626A1 (en) | Glass panel unit and method for manufacturing glass panel unit | |
US11230878B2 (en) | Glass panel unit assembly and method for manufacturing glass panel unit | |
US20210254396A1 (en) | Production method of glass panel unit | |
WO2020017221A1 (ja) | ガラスパネルユニット、及びガラスパネルユニットの製造方法 | |
WO2019207971A1 (ja) | ガラスパネルユニット、ガラスパネルユニットの仕掛り品、ガラスパネルユニットの組立て品、ガラスパネルユニットの製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 15846106 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 15507053 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 2016551551 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 112015004489 Country of ref document: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 15846106 Country of ref document: EP Kind code of ref document: A1 |