WO2015196318A1 - 一种合成革用变色抛光处理剂及其制备方法 - Google Patents

一种合成革用变色抛光处理剂及其制备方法 Download PDF

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WO2015196318A1
WO2015196318A1 PCT/CN2014/000918 CN2014000918W WO2015196318A1 WO 2015196318 A1 WO2015196318 A1 WO 2015196318A1 CN 2014000918 W CN2014000918 W CN 2014000918W WO 2015196318 A1 WO2015196318 A1 WO 2015196318A1
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weight
parts
treatment agent
synthetic leather
polishing treatment
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陈勇刚
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江苏宝泽高分子材料股份有限公司
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11Compounds containing epoxy groups or precursors thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/05Cellulose or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain

Definitions

  • the present invention relates to the field of surface treatment agents for synthetic leather, and in particular to a color-changing polishing treatment agent for synthetic leather used in the post-production printing process of synthetic leather, and to a method for preparing the color-changing polishing treatment agent for synthetic leather.
  • the synthetic leather surface treatment agent can be surface-coated according to the type of the product, which can improve the brightness, color and feel of the synthetic leather.
  • the synthetic leather surface treatment agent can be surface-coated according to the type of the product, which can improve the brightness, color and feel of the synthetic leather.
  • it is necessary not only to increase the feel of synthetic leather, but also to ensure the brightness and color of the surface of synthetic leather.
  • the existing surface treatment agent can not meet the increasing requirements of consumers for the brightness and feel of synthetic leather. Therefore, there is an urgent need for a combination of the effect of improving the synthetic leather and improving the oil wax effect of synthetic leather, brightness, gloss and the like. The effect of the treatment agent.
  • an object of the present invention is to provide a color changing polishing treatment agent for synthetic leather.
  • a color-changing polishing treatment agent for synthetic leather which is used for the back-end printing process of synthetic leather, comprising the following components, modified polyurethane, nitrocellulose, dimethylformamide, butyl ester, silica matting powder, epoxy Soybean oil, silicone oil.
  • the components are as follows: 26 to 29 parts by weight of the modified polyurethane, 5 to 8 parts by weight of the nitrocellulose, 21 to 23 parts by weight of dimethylformamide, and 26 to 28 parts by weight of the butyl ester, 4 to 6 parts by weight of the silica matting powder, 8 to 10 parts by weight of the epoxidized soybean oil, and 0.2 to 1 part by weight of the silicone oil.
  • the components are as follows: 27 to 29 parts by weight of the modified polyurethane, 6 to 8 parts by weight of the nitrocellulose, 22 to 23 parts by weight of the dimethylformamide, and 27 to 28 parts by weight of the butyl ester, 5 to 6 parts by weight of the silica matting powder, 9 to 10 parts by weight of the epoxy soybean oil, and 0.3 to 1 part by weight of the silicone oil.
  • the components are as follows: 28 parts by weight of modified polyurethane, 6 parts by weight of nitrocellulose, 22 parts by weight of dimethylformamide, 28 parts by weight of butyl ester, and 5 parts by weight of silica matting powder. 10 parts by weight of epoxidized soybean oil and 1 part by weight of silicone oil.
  • Another object of the present invention is to provide a method for preparing the above-mentioned color-changing polishing treatment agent for synthetic leather, which comprises the following steps:
  • the components are as follows: 26 to 29 parts by weight of modified polyurethane, 5 to 8 parts by weight of nitrocellulose, and dimethylformamide 21 to 23
  • the parts by weight include 26 to 28 parts by weight of butyl ester, 4 to 6 parts by weight of silica matting powder, 8 to 10 parts by weight of epoxidized soybean oil, and 0.2 to 1 part by weight of silicone oil.
  • all the steps of the method for preparing the synthetic leather color changing polishing treatment agent are carried out under normal temperature and normal pressure.
  • the present invention has the following advantages compared with the prior art:
  • the discoloration polishing treatment agent for synthetic leather according to the present invention is an environmentally-friendly material and meets environmental protection standards of the European Union;
  • the components of the discoloration polishing treatment agent for synthetic leather according to the present invention are coordinated and act together, and the polished surface and the oil wax have good effect after polishing, and the hand feel is smooth, and the leather gloss made by the treatment agent is natural and clear in color. , the leather effect is strong, the comprehensive effect is good;
  • the color changing polishing treatment agent of the invention is a novel material for the latter stage printing, can be used in the existing synthetic leather production line, has a simple process, does not need to change the production equipment, and does not increase the production cost.
  • the color changing polishing treatment agent for synthetic leather is composed of the following components: 26 parts by weight of modified polyurethane, 5 parts by weight of nitrocellulose, 21 parts by weight of dimethylformamide, 26 parts by weight of butyl ester, and silica matting powder 4 Parts by weight, 8 parts by weight of epoxidized soybean oil, and 0.2 parts by weight of silicone oil.
  • the above-mentioned method for preparing a color-changing polishing treatment agent for synthetic leather is: 13 parts by weight of modified polyurethane, 5 parts by weight of nitrocellulose, 21 parts by weight of dimethylformamide, and 26 parts by weight of dibutyl at normal temperature and pressure.
  • the ester and 4 parts by weight of the silica matting powder are mixed, stirred for at least 30 minutes until the mixture is uniformly mixed, and the mixture is subjected to grinding filtration, and the filter residue is discarded; 8 parts by weight of epoxidized soybean oil and 0.2 are added to the obtained mixture.
  • the parts by weight of the silicone oil is stirred for at least 30 minutes until the mixture is uniformly mixed; finally, the remaining 13 parts by weight of the modified polyurethane is added to the obtained mixture, and the mixture is uniformly stirred to obtain a color-changing polishing treatment agent for the synthetic leather.
  • the performance indexes of the obtained color-changing polishing treatment agent for synthetic leather are shown in Table 1.
  • the color changing polishing treatment agent for synthetic leather is composed of the following components: 28 parts by weight of modified polyurethane, 6 parts by weight of nitrocellulose, 22 parts by weight of dimethylformamide, 28 parts by weight of butyl ester, and silica matting powder 5 Parts by weight, 10 parts by weight of epoxidized soybean oil, and 1 part by weight of silicone oil.
  • the above-mentioned method for preparing a color-changing polishing treatment agent for synthetic leather is: 14 parts by weight of modified polyurethane, 6 parts by weight of nitrocellulose, 22 parts by weight of dimethylformamide, and 28 parts by weight of dibutyl at normal temperature and normal pressure.
  • the color changing polishing treatment agent for synthetic leather is composed of the following components: 29 parts by weight of modified polyurethane, 8 parts by weight of nitrocellulose, 23 parts by weight of dimethylformamide, 27 parts by weight of butyl ester, and silica matting powder 6 Parts by weight, 9 parts by weight of epoxidized soybean oil, and 0.6 parts by weight of silicone oil.
  • the above-mentioned color changing polishing treatment agent for synthetic leather is prepared by subjecting 14.5 parts by weight of modified polyurethane, 8 parts by weight of nitrocellulose, 23 parts by weight of dimethylformamide, and 27 parts by weight of dibutyl at normal temperature and pressure.
  • the ester and 6 parts by weight of the silica matting powder were mixed, stirred for at least 30 minutes until the mixture was uniformly mixed, and the mixture was subjected to grinding filtration, and the residue was discarded; 9 parts by weight of epoxidized soybean oil and 0.6 were added to the obtained mixture.
  • the parts by weight of the silicone oil are stirred for at least 30 minutes until the mixture is uniformly mixed; finally, the remaining 14.5 parts by weight of the modified polyurethane is added to the obtained mixture, and the mixture is uniformly stirred to obtain a color-changing polishing treatment agent for the synthetic leather.
  • the performance indexes of the obtained color-changing polishing treatment agent for synthetic leather are shown in Table 1.
  • Example 1 Example 2 Example 3 pH value 5.2 5.9 6.2 Exterior Yellowish viscous liquid Yellowish viscous liquid Yellowish viscous liquid stability No precipitation, no discoloration No precipitation, no discoloration No precipitation, no discoloration Viscosity (cps/25°C) 1250 1350 1400

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明涉及一种合成革用变色抛光处理剂及其制备方法,该处理剂包含以下组分:改性聚氨酯,硝化棉,二甲基甲酰胺,丁酯,二氧化硅消光粉,环氧大豆油,有机硅油。本发明的变色抛光处理剂是后段印刷的一种新型材料,该处理剂的各组分相互协调、共同作用,抛光后亮面和油蜡效果佳,手感滑爽,用此种处理剂做出的革光泽自然,色泽清晰,真皮效果强,综合效果佳。

Description

一种合成革用变色抛光处理剂及其制备方法 技术领域
本发明涉及合成革用表面处理剂领域,具体地,涉及一种用于合成革后段印刷工艺的合成革用变色抛光处理剂,本发明同时涉及该合成革用变色抛光处理剂的制备方法。
背景技术
合成革表面处理剂可以根据产品的类别进行表面涂饰,其可以改善合成革的亮度、色泽以及手感。然而,随着消费者对皮革表面的色泽和手感要求越来越高,不但要增加合成革的手感,还要保证合成革表面的亮度及色泽度等。而现有的表面处理剂已经不能满足消费者对合成革的亮度及手感日益增加的要求,因此急需一种既能提高合成革手感,又能提高合成革的油蜡效果,亮度、光泽等综合效果的处理剂。
发明内容
为了解决上述问题及缺陷,本发明的目的是提供一种合成革用变色抛光处理剂。
本发明的合成革用变色抛光处理剂通过以下技术方案实现:
一种合成革用变色抛光处理剂,其用于合成革的后段印刷工艺,包含以下组分,改性聚氨酯,硝化棉,二甲基甲酰胺,丁酯,二氧化硅消光粉,环氧大豆油,有机硅油。
进一步地,所述各组分的配比如下:改性聚氨酯26~29重量份,硝化棉5~8重量份,二甲基甲酰胺21~23重量份,丁酯26~28重量份,二氧化硅消光粉4~6重量份,环氧大豆油8~10重量份,有机硅油0.2~1重量份。
进一步地,所述各组分的配比如下:改性聚氨酯27~29重量份,硝化棉6~8重量份,二甲基甲酰胺22~23重量份,丁酯27~28重量份,二氧化硅消光粉5~6重量份,环氧大豆油9~10重量份,有机硅油0.3~1重量份。
进一步地,所述各组分的配比如下:改性聚氨酯28重量份,硝化棉6重量份,二甲基甲酰胺22重量份,丁酯28重量份,二氧化硅消光粉5重量份,环氧大豆油10重量份,有机硅油1重量份。
本发明的另一目的是提供一种上述合成革用变色抛光处理剂的制备方法,该方法包含以下步骤:
1)按比例称取各组分物质,将二分之一重量的改性聚氨酯,和硝化棉,二甲基甲酰胺,丁酯,二氧化硅消光粉搅拌后研磨过滤,弃去滤渣;
2)在步骤1)所得的混合物中加入环氧大豆油,有机硅油搅拌均匀;
3)在步骤2)所得的混合物中加入剩余的二分之一重量的改性聚氨酯,搅拌均匀,即得所述合成革用变色抛光处理剂。
本发明所提供的合成革用变色抛光处理剂的制备方法中,各组分的配比如下:改性聚氨酯26~29重量份,硝化棉5~8重量份,二甲基甲酰胺21~23重量份,丁酯26~28重量份,二氧化硅消光粉4~6重量份,环氧大豆油8~10重量份,有机硅油0.2~1重量份。
在本发明的一个实施例中,合成革用变色抛光处理剂的制备方法的所有步骤均在常温常压下进行。
由于采用以上技术方案,本发明与现有技术相比具有如下优点:
本发明所述的合成革用变色抛光处理剂为环保型材料,符合欧盟的环保标准;
本发明所述的合成革用变色抛光处理剂的各组分相互协调、共同作用,抛光后亮面和油蜡效果佳,手感滑爽,用此种处理剂做出的革光泽自然,色泽清晰,真皮效果强,综合效果佳;
本发明的变色抛光处理剂是后段印刷的一种新型材料,能够用于现有的合成革生产线,工艺简单,无需改变生产设备,不会增加生产成本。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白,下面结合实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本发明,并不用于限定本发明。
实施例1
合成革用变色抛光处理剂由以下配比的组分组成:改性聚氨酯26重量份,硝化棉5重量份,二甲基甲酰胺21重量份,丁酯26重量份,二氧化硅消光粉4重量份,环氧大豆油8重量份,有机硅油0.2重量份。
上述合成革用变色抛光处理剂的制备方法是:在常温常压下,将13重量份的改性聚氨酯、5重量份的硝化棉、21重量份的二甲基甲酰胺、26重量份的丁酯、4重量份的二氧化硅消光粉混合,搅拌至少30分钟至混合物混合均匀后,将混合物进行研磨过滤,弃去滤渣;在得到的上述混合物中加入8重量份的环氧大豆油和0.2重量份的有机硅油搅拌至少30分钟至混合物混合均匀;最后,在所得的上述混合物中加入剩余的13重量份的改性聚氨酯,搅拌均匀,即得所述合成革用变色抛光处理剂。所得到的合成革用变色抛光处理剂的性能指标见表1。
上述制备过程中所采用的搅拌、过滤等方法均为本领域内惯用的方法。
实施例2
合成革用变色抛光处理剂由以下配比的组分组成:改性聚氨酯28重量份,硝化棉6重量份,二甲基甲酰胺22重量份,丁酯28重量份,二氧化硅消光粉5重量份,环氧大豆油10重量份,有机硅油1重量份。
上述合成革用变色抛光处理剂的制备方法是:在常温常压下,将14重量份的改性聚氨酯、6重量份的硝化棉、22重量份的二甲基甲酰胺、28重量份的丁酯、5重量份的二氧化硅消光粉混合,搅拌至少30分钟 至混合物混合均匀后,将混合物进行研磨过滤,弃去滤渣;在得到的上述混合物中加入10重量份的环氧大豆油和1重量份的有机硅油搅拌至少30分钟至混合物混合均匀;最后,在所得的上述混合物中加入剩余的14重量份的改性聚氨酯,搅拌均匀,即得所述合成革用变色抛光处理剂。所得到的合成革用变色抛光处理剂的性能指标见表1。
上述制备过程中所采用的搅拌、过滤等方法均为本领域内惯用的方法。
实施例3
合成革用变色抛光处理剂由以下配比的组分组成:改性聚氨酯29重量份,硝化棉8重量份,二甲基甲酰胺23重量份,丁酯27重量份,二氧化硅消光粉6重量份,环氧大豆油9重量份,有机硅油0.6重量份。
上述合成革用变色抛光处理剂的制备方法是:在常温常压下,将14.5重量份的改性聚氨酯、8重量份的硝化棉、23重量份的二甲基甲酰胺、27重量份的丁酯、6重量份的二氧化硅消光粉混合,搅拌至少30分钟至混合物混合均匀后,将混合物进行研磨过滤,弃去滤渣;在得到的上述混合物中加入9重量份的环氧大豆油和0.6重量份的有机硅油搅拌至少30分钟至混合物混合均匀;最后,在所得的上述混合物中加入剩余的14.5重量份的改性聚氨酯,搅拌均匀,即得所述合成革用变色抛光处理剂。所得到的合成革用变色抛光处理剂的性能指标见表1。
上述制备过程中所采用的搅拌、过滤等方法均为本领域内惯用的方法。
表1
  实施例1 实施例2 实施例3
pH值 5.2 5.9 6.2
外观 微黄粘稠液体 微黄粘稠液体 微黄粘稠液体
稳定性 无沉淀、不变色 无沉淀、不变色 无沉淀、不变色
粘度(cps/25℃) 1250 1350 1400
固含量(%) 29 30 31
以上所述仅为本发明的较佳实施例,并非用来限定本发明的实施范围;如果不脱离本发明的精神和范围,对本发明进行修改或者等同替换,均应涵盖在本发明权利要求的保护范围当中。

Claims (7)

  1. 一种合成革用变色抛光处理剂,其用于合成革的后段印刷工艺,其特征在于:包含以下组分,改性聚氨酯,硝化棉,二甲基甲酰胺,丁酯,二氧化硅消光粉,环氧大豆油,有机硅油。
  2. 根据权利要求1所述的合成革用变色抛光处理剂,其特征在于,所述各组分的配比如下:改性聚氨酯26~29重量份,硝化棉5~8重量份,二甲基甲酰胺21~23重量份,丁酯26~28重量份,二氧化硅消光粉4~6重量份,环氧大豆油8~10重量份,有机硅油0.2~1重量份。
  3. 根据权利要求2所述的合成革用变色抛光处理剂,其特征在于,所述各组分的配比如下:改性聚氨酯27~29重量份,硝化棉6~8重量份,二甲基甲酰胺22~23重量份,丁酯27~28重量份,二氧化硅消光粉5~6重量份,环氧大豆油9~10重量份,有机硅油0.3~1重量份。
  4. 根据权利要求2所述的合成革用变色抛光处理剂,其特征在于,所述各组分的配比如下:改性聚氨酯28重量份,硝化棉6重量份,二甲基甲酰胺22重量份,丁酯28重量份,二氧化硅消光粉5重量份,环氧大豆油10重量份,有机硅油1重量份。
  5. 一种上述权利要求所述的合成革用变色抛光处理剂的制备方法,其特征在于,包含以下步骤:
    1)按比例称取各组分物质,将二分之一重量的改性聚氨酯,和硝化棉,二甲基甲酰胺,丁酯,二氧化硅消光粉搅拌后研磨过滤,弃去滤渣;
    2)在步骤1)所得的混合物中加入环氧大豆油,有机硅油搅拌均匀;
    3)在步骤2)所得的混合物中加入剩余的二分之一重量的改性聚氨酯,搅拌均匀,即得所述合成革用变色抛光处理剂。
  6. 根据权利要求5所述的合成革用变色抛光处理剂的制备方法,其特征在于,各组分的配比如下:改性聚氨酯26~29重量份,硝化棉5~8 重量份,二甲基甲酰胺21~23重量份,丁酯26~28重量份,二氧化硅消光粉4~6重量份,环氧大豆油8~10重量份,有机硅油0.2~1重量份。
  7. 根据权利要求5所述的合成革用变色抛光处理剂的制备方法,其特征在于,所有步骤均在常温常压下进行。
PCT/CN2014/000918 2014-06-26 2014-10-17 一种合成革用变色抛光处理剂及其制备方法 WO2015196318A1 (zh)

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