WO2015181754A3 - Obtención de un látex híbrido y su uso en recubrimientos hidrofóbicos y superhidrofóbicos - Google Patents

Obtención de un látex híbrido y su uso en recubrimientos hidrofóbicos y superhidrofóbicos Download PDF

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Publication number
WO2015181754A3
WO2015181754A3 PCT/IB2015/053987 IB2015053987W WO2015181754A3 WO 2015181754 A3 WO2015181754 A3 WO 2015181754A3 IB 2015053987 W IB2015053987 W IB 2015053987W WO 2015181754 A3 WO2015181754 A3 WO 2015181754A3
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WO
WIPO (PCT)
Prior art keywords
hydrophobic
water
obtaining
latex
hybrid latex
Prior art date
Application number
PCT/IB2015/053987
Other languages
English (en)
French (fr)
Other versions
WO2015181754A2 (es
Inventor
Julian Masasue GALVAN-MIYOSHI
Fabio PEZZOTTI-ROBLETO
Weihua Ming
Quanyuan ZHANG
Original Assignee
Centro De Investigacion En Polimeros, S. A. De C. V.
Georgia Southern University Research And Service Foundation, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centro De Investigacion En Polimeros, S. A. De C. V., Georgia Southern University Research And Service Foundation, Inc. filed Critical Centro De Investigacion En Polimeros, S. A. De C. V.
Priority to CA2950391A priority Critical patent/CA2950391A1/en
Priority to US15/314,287 priority patent/US20170121442A1/en
Publication of WO2015181754A2 publication Critical patent/WO2015181754A2/es
Publication of WO2015181754A3 publication Critical patent/WO2015181754A3/es

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
    • C08F283/124—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes on to polysiloxanes having carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/068—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D151/085—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds on to polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

La presente invención se refiere a un látex híbrido siliconado consistente en un copolímero metacrílico - polixilosano de la formula partiendo al menos de un monómero metacrínco parcialmente soluble en agua y al menos un macromonómero funcionalizado a base de silicón, insoluble en agua, altamente hidrofóbico y su uso en una formulación base agua, libre de compuestos fluorados, generando superficies altamente hidrofóbica ó superhidrofóbicas con propiedades de autolimpieza o de fácil limpieza.
PCT/IB2015/053987 2014-05-28 2015-05-27 Obtención de un látex híbrido y su uso en recubrimientos hidrofóbicos y superhidrofóbicos WO2015181754A2 (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CA2950391A CA2950391A1 (en) 2014-05-28 2015-05-27 Hybrid latex method for obtaining the same and its use as hydrophobic and superhydrophobic coatings
US15/314,287 US20170121442A1 (en) 2014-05-28 2015-05-27 Method for Obtaining a Hybrid Latex and Use Thereof in Hydrophobic and Superhydrophobic Coatings

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
MXMX/A/2014/006426 2014-05-28
MX2014006426 2014-05-28

Publications (2)

Publication Number Publication Date
WO2015181754A2 WO2015181754A2 (es) 2015-12-03
WO2015181754A3 true WO2015181754A3 (es) 2016-01-21

Family

ID=54699994

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2015/053987 WO2015181754A2 (es) 2014-05-28 2015-05-27 Obtención de un látex híbrido y su uso en recubrimientos hidrofóbicos y superhidrofóbicos

Country Status (3)

Country Link
US (1) US20170121442A1 (es)
CA (1) CA2950391A1 (es)
WO (1) WO2015181754A2 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015223246A1 (de) * 2015-11-24 2017-05-24 Wacker Chemie Ag Organocopolymer-Dispersionen
US10633539B2 (en) * 2016-03-10 2020-04-28 Momentive Performance Materials Inc. Composition comprising organosiloxane nano latex and preparation of organosiloxane nano latex
US10894903B2 (en) * 2016-06-16 2021-01-19 3M Innovative Properties Company Nanoparticle filled barrier adhesive compositions
CN111617304B (zh) * 2020-06-15 2022-01-14 江苏阳生生物股份有限公司 一种高吸湿创口敷料及其制备方法
CN112961552A (zh) * 2021-02-04 2021-06-15 几何智慧城市科技(广州)有限公司 一种水性超疏水涂料及其制备方法及应用
CN114560980B (zh) * 2022-02-14 2023-07-18 江苏金天辰新材料有限公司 一种应用于制备疏水铝箔的水性复合乳胶及其合成工艺
CN115197625B (zh) * 2022-07-20 2023-05-12 山东恒泰纺织有限公司 一种富含线圈状类液刷的自粘附超滑涂层及其制备方法与应用
CN115197362B (zh) * 2022-07-29 2023-11-03 同济大学 一种超疏水抗菌乳液及其制备和应用
CN115260863B (zh) * 2022-08-23 2023-09-19 广东多正树脂科技有限公司 一种斥水型水性丙烯酸树脂涂料及其制备方法与使用方法

Citations (1)

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Publication number Priority date Publication date Assignee Title
US20090064894A1 (en) * 2007-09-05 2009-03-12 Ashland Licensing And Intellectual Property Llc Water based hydrophobic self-cleaning coating compositions

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JP3543874B2 (ja) * 1995-06-26 2004-07-21 東亞合成株式会社 水性樹脂分散体の製造方法
US7666965B2 (en) * 2004-03-11 2010-02-23 Wacker Chemie Ag Method for production of mixed polymers containing silicon
DE102006037270A1 (de) * 2006-08-09 2008-02-14 Wacker Chemie Ag Selbstdispergierbare Silikoncopolymerisate und Verfahren zu deren Herstellung und deren Verwendung

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090064894A1 (en) * 2007-09-05 2009-03-12 Ashland Licensing And Intellectual Property Llc Water based hydrophobic self-cleaning coating compositions

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
RODRIGUEZ, R. ET AL.: "Correlation of Silicone Incorporation into Hybrid Acrylic Coatings with the Resulting Hydrophobic and Thermal Properties''.", MACROMOLECULES, vol. 41, no. 22, 2008, pages 8537 - 8546 *
SMITH, D. D. ET AL.: "Synthesis and characterization of poly(methyl methacrylate)-g-poly(dimethylsiloxane)copolymers. I. Bulk and surface characterization''.", MACROMOLECULES, vol. 25, no. 10, 1992, pages 2575 - 2581 *
STUMBÉ, J. ET AL.: "Synthesis of poly(methyl methacrylate)-g-poly(dimethyl siloxane) graft copolymers via a miniemulsion process''.", POLYMER BULLETIN, vol. 47, no. 3, 2001, pages 277 - 282, XP001111854, DOI: doi:10.1007/s289-001-8182-z *
ZHANG, Q. ET AL.: "Synthesis and surface properties of PDMS-containing latexes by emulsion polymerization using AIBN as the initiator''.", EUROPEAN POLYMER JOURNAL, vol. 49, no. 8, 2013, pages 2327 - 2333, XP028675116, DOI: doi:10.1016/j.eurpolymj.2013.05.018 *

Also Published As

Publication number Publication date
CA2950391A1 (en) 2015-12-03
WO2015181754A2 (es) 2015-12-03
US20170121442A1 (en) 2017-05-04

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