WO2015178179A1 - 蒸留装置 - Google Patents
蒸留装置 Download PDFInfo
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- WO2015178179A1 WO2015178179A1 PCT/JP2015/062845 JP2015062845W WO2015178179A1 WO 2015178179 A1 WO2015178179 A1 WO 2015178179A1 JP 2015062845 W JP2015062845 W JP 2015062845W WO 2015178179 A1 WO2015178179 A1 WO 2015178179A1
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- Prior art keywords
- output fluid
- valve
- working medium
- circulation
- distillation apparatus
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- 238000004821 distillation Methods 0.000 title claims abstract description 49
- 239000012530 fluid Substances 0.000 claims abstract description 183
- 239000007788 liquid Substances 0.000 claims abstract description 58
- 238000011084 recovery Methods 0.000 claims abstract description 45
- 230000007423 decrease Effects 0.000 claims abstract description 33
- 230000007246 mechanism Effects 0.000 claims abstract description 12
- 238000001514 detection method Methods 0.000 claims description 26
- 238000010438 heat treatment Methods 0.000 claims description 26
- 239000002826 coolant Substances 0.000 claims description 21
- 238000001816 cooling Methods 0.000 claims description 6
- 238000011144 upstream manufacturing Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 5
- 230000003247 decreasing effect Effects 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 102100035353 Cyclin-dependent kinase 2-associated protein 1 Human genes 0.000 description 3
- 102100029860 Suppressor of tumorigenicity 20 protein Human genes 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 101000760620 Homo sapiens Cell adhesion molecule 1 Proteins 0.000 description 1
- 101000661807 Homo sapiens Suppressor of tumorigenicity 14 protein Proteins 0.000 description 1
- 101000585359 Homo sapiens Suppressor of tumorigenicity 20 protein Proteins 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/42—Regulation; Control
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/007—Energy recuperation; Heat pumps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/32—Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/42—Regulation; Control
- B01D3/4211—Regulation; Control of columns
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Definitions
- the present invention relates to a distillation apparatus.
- Patent Document 1 discloses a separation process module including a separator, a compressor, a heat exchanger, and a cooler.
- the separator separates an input fluid including a first component and a second component different from the first component into a first output fluid including the first component and a second output fluid including the second component.
- the compressor compresses the first output fluid separated by the separator.
- the heat exchanger exchanges heat between the first output fluid compressed by the compressor and the second output fluid separated by the separator.
- the cooler cools the first output fluid after heat exchange with the heat exchanger. The first output fluid flowing out from the cooler and the second output fluid flowing out from the heat exchanger are respectively returned to the separator.
- the heat energy of the first output fluid flowing out from the separator is input to the heat exchanger, whereby the second output fluid flowing out from the separator is heated in the heat exchanger. That is, the effective use of the heat energy of the first output fluid reduces the heat energy required for heating the second output fluid (energy saving).
- the first output fluid flowing out from the separator is compressed by a compressor and then introduced into a heat exchanger, thereby recovering the thermal energy of the first output fluid. ing. Therefore, when the first output fluid contains, as the first component, a component that is difficult to be directly compressed (for example, a component that becomes very unstable at high pressure or a component that swells the seal portion of the compressor). It is difficult to use the separation process module.
- the thermal energy of the top vapor is input to the storage evaporator by using a heat pump. That is, in the distillation plant of Patent Document 2, the thermal energy of the fluid flowing out from the top of the column (separator) is indirectly recovered by using a heat pump without directly compressing the fluid with a compressor. .
- Patent Document 3 the thermal energy of the top vapor is indirectly recovered by a distillation reboiler by using a heat pump using water as a medium.
- Patent Document 3 describes that the load adjustment of the heat pump is performed by adjusting the opening of the compressor bypass valve and the inlet vane or by controlling the rotation speed of the compressor.
- the object of the present invention is to effectively recover the thermal energy of the first output fluid even when the first output fluid flowing out of the separator contains a component that is difficult to be directly compressed. And it is providing the distillation apparatus which can collect
- a distillation apparatus includes a separator that separates an input fluid including a first component and a second component into a first output fluid including the first component and a second output fluid including the second component.
- a cooler for cooling the first output fluid flowing out from the separator, a heater for heating the second output fluid flowing out from the separator, and a working medium, Thermal energy received from the first output fluid by exchanging heat with the first output fluid in a cooler, and the second output fluid by exchanging heat with the second output fluid by the working medium in the heater.
- a heat recovery circuit for supplying the heat medium to the heat recovery circuit, wherein the heat recovery circuit connects the cooler and the heater and circulates the working medium, and the cooler cools the first output fluid and heat.
- a circulation amount adjusting unit, and the circulation amount adjusting unit includes the working medium stored in the storage unit so that the circulation amount increases or decreases in accordance with an increase or decrease in the flow rate of the first output fluid. The outflow amount to the circulation channel or the inflow amount to the storage part of the working medium circulating in the circulation channel is adjusted.
- the distillation apparatus includes a separator 22, a cooler 24 that cools the first output fluid that flows out of the separator 22, and heating that heats the second output fluid that flows out of the separator 22. And a heat recovery circuit 30.
- This distillation apparatus is an apparatus that can indirectly input the heat energy of the relatively low temperature first output fluid to the relatively high temperature second output fluid through the working medium.
- the separator 22 separates the input fluid containing the first component and the second component different from the first component into the first output fluid containing the first component and the second output fluid containing the second component.
- the first output fluid is a distillate vapor (distillate) containing a large amount of a component having a low boiling point (high volatility) as the first component.
- the second output fluid is a bottomed liquid containing a lot of components having a boiling point higher than that of the first component (having volatility lower than that of the first component) as the second component.
- the input fluid flows into the separator 22 through the input flow path 11.
- the first output fluid flows into the cooler 24 through the output flow path 12, and the second output fluid flows into the heater 26 through the output flow path 15.
- the cooler 24 cools the first output fluid by exchanging heat between the first output fluid and the working medium of the heat recovery circuit 30. A part of the first output fluid cooled by exchanging heat with the working medium in the cooler 24 is output to the outside through the output flow path 13, and the rest is supplied to the upper portion of the separator 22 through the recharging flow path 14. Returned.
- the cooler 24 is configured so that a cooling medium (cooling water or the like) can be supplied into the cooler 24 from an external cooling source (not shown).
- the cooler 24 has a coolant flow path 25 that can be connected to a coolant supply path (not shown) for supplying a coolant from a cooling source to the cooler 24.
- the cooling medium flow path 25 has a connection portion 25a that can be connected to the cooling medium supply flow path. That is, in the present embodiment, the first output fluid can be cooled in the cooler 24 by both the working medium and the cooling medium. However, the cooling medium flow path 25 may be omitted.
- the heater 26 heats the second output fluid by exchanging heat between the second output fluid and the working medium of the heat recovery circuit 30. A part of the second output fluid heated by exchanging heat with the working medium in the heater 26 is output to the outside through the output channel 16, and the rest is supplied to the lower part of the separator 22 through the re-input channel 17. Returned.
- the heater 26 is configured to be able to supply a heating medium (such as steam) from an external heat source (not shown) into the heater 26.
- the heater 26 has a heating medium channel 27 that can be connected to a heating medium supply channel (not shown) for supplying a heating medium from a heat source to the heater 26.
- the heating medium flow path 27 has a connection portion 27a that can be connected to the heating medium supply flow path. That is, in the present embodiment, the second output fluid can be heated by both the working medium and the heating medium in the heater 26. However, the heating medium flow path 27 may be omitted.
- the heat recovery circuit 30 uses the heat energy received by the working medium from the first output fluid by the heat exchange between the first output fluid and the working medium in the cooler 24 as the working medium and the second output fluid in the heater 26. This is a circuit to be given to the second output fluid by heat exchange with. That is, the heat recovery circuit 30 functions as a so-called heat pump that transfers heat from the relatively low temperature first output fluid to the relatively high temperature second output fluid via the working medium.
- the heat recovery circuit 30 includes a circulation channel 32 through which the working medium circulates, a compressor 34 that compresses the working medium, and an expansion mechanism 36 that expands the working medium.
- the circulation channel 32 connects the cooler 24, the compressor 34, the heater 26, and the expansion mechanism 36 in series in this order without being connected to the channel through which the first output fluid and the second output fluid flow.
- a gas-liquid separator 37 is provided at a portion of the circulation channel 32 between the cooler 24 and the compressor 34. The gas-liquid separator 37 may be omitted.
- the compressor 34 is provided in the circulation channel 32 at a site downstream of the cooler 24 and upstream of the heater 26.
- the compressor 34 raises the temperature by compressing the gaseous working medium flowing out of the cooler 24.
- the gaseous working medium that has flowed out of the compressor 34 flows into the heater 26 and becomes liquid by exchanging heat with the second output fluid in the heater 26.
- the expansion mechanism 36 is provided in a portion of the circulation channel 32 that is downstream of the heater 26 and upstream of the cooler 24.
- the expansion mechanism 36 decompresses the liquid working medium flowing out of the heater 26 by expanding it.
- the liquid working medium that has flowed out of the expansion mechanism 36 flows into the cooler 24, and becomes gaseous by exchanging heat with the first output fluid in the cooler 24.
- the heat energy of the first output fluid flowing out from the separator 22 is not directly input to the second output fluid by the first output fluid itself, but the circulation channel.
- the second output fluid is indirectly charged through the working medium circulating in the fluid 32.
- the thermal energy of the first output fluid is recovered by the working medium by heat exchange between the first output fluid and the working medium in the cooler 24, and then the working medium and the second in the heater 26. It is given to the second output fluid by heat exchange with the output fluid. That is, in this distillation apparatus, the first output fluid itself is not compressed by the compressor 34 as a heat energy transfer medium, but the working medium circulating in the circulation channel 32 is compressed by the compressor 34 as the transfer medium. The Therefore, even when the first output fluid contains a component that is difficult to be directly compressed as the first component, the thermal energy of the first output fluid can be effectively recovered through the working medium. (The heat energy supplied to the heater 26 can be reduced).
- the heat recovery circuit 30 of the present embodiment further includes means for increasing / decreasing the total amount of the working medium circulating in the circulation passage 32 (hereinafter referred to as “circulation amount”) in accordance with the increase / decrease of the flow rate of the first output fluid.
- circulation amount means for increasing / decreasing the total amount of the working medium circulating in the circulation passage 32 (hereinafter referred to as “circulation amount”) in accordance with the increase / decrease of the flow rate of the first output fluid. I have.
- the heat recovery circuit 30 of the present embodiment includes a storage unit 40 connected to the circulation channel 32, a circulation amount adjustment unit 50 capable of adjusting the circulation amount of the working medium that circulates in the circulation channel 32, Is further provided.
- the storage unit 40 includes a storage channel 42 connected to the circulation channel 32 and a tank 44 provided in the storage channel 42.
- the storage flow path 42 is connected to the circulation flow path 32 so as to be parallel to a portion of the circulation flow path 32 where the liquid working medium flows.
- the upstream end portion of the storage channel 42 is connected to a portion of the circulation channel 32 that is downstream of the heater 26 and upstream of the expansion mechanism 36.
- the downstream end of the storage channel 42 is between the expansion mechanism 36 and the connection portion of the circulation channel 32 between the circulation channel 32 and the upstream end of the storage channel 42.
- the storage channel 42 stores a liquid working medium condensed by exchanging heat with the second output fluid in the heater 26.
- the tank 44 stores a liquid working medium.
- the tank 44 is provided with a detector 44 a that can detect the amount of the working medium stored in the tank 44.
- the liquid working medium separated by the gas-liquid separator 37 flows into the tank 44 through the flow path 38.
- the circulation amount adjusting unit 50 increases or decreases the circulation amount of the circulation channel 32 in accordance with the increase or decrease of the flow rate of the first output fluid. Specifically, the circulation amount adjusting unit 50 moves to the circulation passage 32 of the working medium stored in the storage passage 42 and the tank 44 so that the circulation amount increases or decreases as the flow rate of the first output fluid increases or decreases. Or the inflow amount of the working medium circulating in the circulation passage 32 into the storage passage 42 and the tank 44 is adjusted.
- the circulation amount adjusting unit 50 includes the flow rate sensor 18, the first on-off valve 51, the second on-off valve 52, the first pump 53, the second pump 54, and the control unit 55. ing.
- the flow sensor 18 is a sensor that can detect the flow rate of the first output fluid.
- the flow sensor 18 is provided in the output flow path 12 that connects the separator 22 and the cooler 24.
- the flow rate sensor 18 includes both the output flow path 13 for outputting to the outside from the cooler 24 and the recharging flow path 14 for returning the first output fluid flowing out from the cooler 24 to the separator 22. May be provided. In this case, the flow rate of the first output fluid is calculated from the sum of these detection values.
- the first on-off valve 51 is provided in a portion of the storage channel 42 upstream of the portion where the tank 44 is provided.
- the second on-off valve 52 is provided in a part of the storage channel 42 on the downstream side of the part where the tank 44 is provided.
- the first pump 53 is provided in a portion between the first on-off valve 51 and the tank 44 in the storage channel 42.
- the first pump 53 pressurizes the liquid working medium to a predetermined pressure and sends it to the downstream side (tank 44 side) of the first pump 53 in the storage flow path 42. That is, the first pump 53 is a pump for causing the liquid working medium to flow from the circulation channel 32 into the storage channel 42 and the tank 44.
- the first pump 53 may be provided in a portion of the storage channel 42 on the upstream side of the first on-off valve 51.
- the second pump 54 is provided in a portion of the storage channel 42 between the tank 44 and the second on-off valve 52.
- the second pump 54 pressurizes the liquid working medium to a predetermined pressure and sends it to the downstream side (second open / close valve 52 side) of the second pump 54 in the storage flow path 42. That is, the second pump 54 is a pump for causing the liquid working medium to flow out from the storage flow path 42 and the tank 44 to the circulation flow path 32.
- the second pump 54 may be provided at a site on the downstream side of the second opening / closing valve 52 in the storage channel 42.
- first pump 53 and the second pump 54 a centrifugal pump having an impeller as a rotor, a gear pump having a rotor composed of a pair of gears, or the like is used.
- Each of the first pump 53 and the second pump 54 can be driven at an arbitrary rotational speed.
- the controller 55 is connected to the flow sensor 18, the first on-off valve 51, the second on-off valve 52, the first pump 53, the second pump 54, the detector 44a, and the compressor 34.
- the control unit 55 increases the circulation amount when the flow rate of the first output fluid (detected value of the flow rate sensor 18) increases, and decreases the circulation amount when the flow rate of the first output fluid decreases.
- the opening / closing of the on-off valves 51, 52, the rotational speeds of the pumps 53, 54 and the rotational speed of the compressor 34 are adjusted.
- control contents of the control unit 55 will be described with reference to FIG.
- the control unit 55 detects the detection value of the flow rate sensor 18 (step ST11), and based on the detection value, the reference value (hereinafter referred to as the circulation amount) for circulating the circulation flow path 32. "Threshold value Q L-SV ”) is determined (step ST12).
- the threshold value Q L-SV is set to such an amount that the working medium can recover as much heat energy as possible from the first output fluid in the cooler 24.
- This threshold value Q L-SV exchanges the working medium with the first output fluid substantially only with latent heat in the cooler 24 (the working medium flows into the cooler 24 in a liquid state and is not overheated or slightly heated). It is preferable to set the amount of gas that has been superheated to the temperature of the cooler 24).
- control unit 55 stores data of the optimum threshold value Q L-SV corresponding to the detection value of the flow sensor 18 in advance, and the control unit 55 refers to the data to detect the detection.
- a threshold value Q L-SV corresponding to the value is determined.
- control unit 55 determines the rotation speed of the compressor 34 so that the circulating amount of the working medium circulating in the circulation flow path 32 can be set to the threshold value Q L-SV (step ST13).
- the control unit 55 determines the flow rate of the heating medium supplied from the outside to the heating medium flow path 27 in order to compensate for the shortage (step ST14).
- the cooling amount of the first output fluid in the cooler 24 may be insufficient with only the amount of heat recovered from the cooler 24 via the working medium.
- the control unit 55 determines the flow rate of the cooling medium supplied from the outside to the cooling medium flow path 25 in order to compensate for the shortage (step ST15).
- control unit 55 detects the storage amount Q VS-PV of the working medium in the tank 44 from the detection value of the detector 44a, and from the total amount Q total of the working medium measured in advance, the storage amount Q VS- By subtracting PV , a current circulation amount Q L-PV that is a circulation amount of the working medium circulating through the circulation flow path 32 at that time is calculated (step ST16).
- control unit 55 determines whether or not the current circulation amount Q L-PV of the circulation channel 32 is insufficient, that is, the value obtained by subtracting the storage amount Q VS-PV from the total amount Q total of the working medium is the threshold value Q L. -It is determined whether it is less than SV (step ST17).
- step ST17 when the current circulation amount Q L-PV is insufficient (Yes in step ST17), the control unit 55 closes the first on-off valve 51, stops the first pump 53, and stops the second pump 54. And the second on-off valve 52 is opened (step ST18). Then, the liquid working medium stored in the storage flow path 42 and the tank 44 flows out to the circulation flow path 32, thereby increasing the circulation amount of the working medium in the circulation flow path 32. Then, it returns to step ST11.
- Step ST17 if not insufficient current circulation amount Q L-PV, the control unit 55, the current circulation rate Q L-PV excess whether, i.e., the total amount Q total working medium It is determined whether or not a value obtained by subtracting the storage amount Q VS-PV from the threshold value Q L-SV is larger than the threshold value Q L-SV (step ST19).
- step ST19 when the current circulation amount Q L-PV is excessive (Yes in step ST19), the control unit 55 opens the first on-off valve 51, adjusts the rotation speed of the first pump 53, and The pump 54 is stopped and the second on-off valve 52 is closed (step ST20). Then, the liquid working medium flows from the circulation flow path 32 into the storage flow path 42 and the tank 44, thereby reducing the circulation amount of the working medium in the circulation flow path 32. Then, it returns to step ST11.
- step ST19 if the current circulation amount Q L-PV is not excessive (in the case of No in step ST19), that is, if the current circulation amount Q L-PV and the threshold value Q L-SV match, the process directly goes to step ST11. Return.
- the thermal energy of the first output fluid is effectively adjusted according to the variation. It can be recovered. That is, since this apparatus has the storage part 40 (the storage flow path 42 and the tank 44) and the circulation amount adjustment part 50, the heat
- the circulation amount increases / decreases in accordance with the increase / decrease of the flow rate of the first output fluid (detected value of the flow rate sensor 18)
- the recovery efficiency of the thermal energy of the first output fluid is further improved.
- the circulation amount is increased, that is, when the first on-off valve 51 is closed and the second on-off valve 52 is open
- the working medium flows out from the storage passage 42 and the tank 44 to the circulation passage 32.
- the second pump 54 is driven so as to be promoted.
- the circulation amount is decreased, that is, when the first on-off valve 51 is open and the second on-off valve 52 is closed, the working medium flows from the circulation passage 32 into the storage passage 42 and the tank 44.
- the first pump 53 is driven so as to be promoted.
- the first pump 53 and the second pump 54 promote the outflow of the working medium from the storage unit 40 to the circulation channel 32 or the inflow of the working medium from the circulation channel 32 to the storage unit 40.
- what is necessary is just to provide at least one among the 1st pump 53 and the 2nd pump 54, and the 2nd pump 54 is provided desirably.
- the control unit 55 closes the first on-off valve 51 and opens the second on-off valve 52 when the circulation amount is smaller than the threshold value Q L-SV , and the circulation amount is the threshold value Q L- When larger than SV , the first on-off valve 51 is opened and the second on-off valve 52 is closed. For this reason, the circulation amount follows the threshold value Q L-SV determined as needed based on the detection value of the flow sensor 18. In the present embodiment, since the amount of the working medium that can recover as much heat energy as possible from the first output fluid is set as the threshold value Q L-SV , the recovery efficiency of the heat energy of the first output fluid is further increased. Get higher.
- the flow rate of the working medium that can be stored increases. That is, a larger amount of working medium can be stored than when the gaseous working medium is stored in the storage unit 40.
- the storage part 40 since the storage part 40 has the tank 44, more flexible follow-up to the fluctuation
- the tank 44 may be omitted.
- the heater 26 has a heating medium flow path 27. For this reason, even if the heating amount of the second output fluid in the heater 26 is insufficient only by the amount of heat input to the heater 26 through the working medium, the heating medium is supplied to the heater 26 from the outside. By doing so, the shortage can be compensated.
- the cooler 24 has a cooling medium flow path 25. For this reason, even if only the amount of heat recovered from the cooler 24 via the working medium is insufficient to cool the first output fluid in the cooler 24, the cooling medium is supplied to the cooler 24 from the outside. By doing so, the shortage can be compensated.
- a pressure sensor 32 a and a fifth on-off valve 33 provided in the circulation flow path 32, and a sixth on-off valve 39 provided in the flow path 38 connecting the gas-liquid separator 37 and the tank 44 are further provided.
- the liquid level sensor 24 a detects the storage amount of the liquid working medium in the cooler 24.
- the fifth on-off valve 33 is provided in the circulation channel 32 between the gas-liquid separator 37 and the compressor 34.
- the pressure sensor 32 a is provided in the circulation channel 32 between the gas-liquid separator 37 and the fifth on-off valve 33.
- the control contents of the control unit 55 when starting up (starting up) the heat recovery circuit 30 in the distillation apparatus of the present embodiment will be described with reference to FIG.
- the compressor 34, the first pump 53, and the second pump 54 are stopped, and the fifth on-off valve 33 and the sixth on-off valve 39 are closed. Further, the third open / close valve 28 is opened in order to cool the first output fluid in the cooler 24.
- the control unit 55 first reads the detection value Q TOP of the flow sensor 18 (step ST31), and determines whether or not the detection value Q TOP is larger than a preset operating value Q ST ( Step ST32).
- the operating value Q ST is set to an amount that allows the heat recovery circuit 30 to operate, that is, an amount that allows the working medium to give the thermal energy received from the first output fluid to the second output fluid by driving the compressor 34. Is done.
- Step ST32 If the detected value Q TOP is equal to or less than the operating value Q ST (No in Step ST32), the process returns to Step ST31, while the detected value Q TOP is larger than the operating value Q ST (Yes in Step ST32).
- the control unit 55 closes the third on-off valve 28 (step ST33) and opens the sixth on-off valve 39 (step ST34).
- the third on-off valve 28 is closed because the first output fluid can be cooled by the liquid working medium in the cooler 24.
- the reason for opening the sixth open / close valve 39 is to introduce the liquid working medium accumulated in the gas-liquid separator 37 into the tank 44.
- control unit 55 reads a detection value L2 of the liquid level sensor 24a (step ST35), and determines whether the detected value L2 is larger than the reference amount L ST set in advance (step ST36).
- the reference amount LST is set to such an amount that a gaseous working medium in an amount that can stably rotate the compressor 34 (at the minimum rotation speed N MIN or more) can be obtained.
- step ST36 of No when the detected value L2 is equal to or less than the reference amount L ST, the control unit 55, after opening the second shut-off valve 52 with adjusting the rotation speed of the second pump 54 (step ST37 ), The process returns to step ST35. Then, the liquid working medium flows out from the tank 44 to the circulation flow path 32, thereby increasing the amount of the liquid working medium in the cooler 24.
- step ST36 when the detected value L2 is larger than the reference amount L ST (Yes in step ST36), the control unit 55, the second on-off valve 52 is closed to stop the second pump 54 (step ST37).
- control unit 55 closes the sixth on-off valve 39 (step ST39).
- the sixth on-off valve 39 is closed by shutting off the communication between the gas-liquid separator 37 and the tank 44 to remove the gaseous working medium between the cooler 24 and the fifth on-off valve 33 in the circulation flow path 32. This is to keep it in space.
- control unit 55 reads a detection value P V of the pressure sensor 32a (step ST40), greater than the lower limit pressure P MIN that the detected value P V is set in advance, and whether less than the upper pressure P MAX Is determined (step ST41).
- step ST41 when the detected value P V is lower than the lower limit pressure P MIN or higher than the upper limit pressure P MAX (in the case of No in step ST41), the process returns to step ST40.
- the detected value P V is greater than the lower limit pressure P MIN and less than the upper limit pressure P MAX (Yes in step ST41)
- the fifth on-off valve 33 is opened and the compressor 34 is driven (step ST42). ). Thereby, the heat recovery circuit 30 starts up. Thereafter, the process proceeds to step ST11.
- control content of the control unit 55 when the heat recovery circuit 30 is lowered (stopped) will be described with reference to FIG.
- the same contents as the control contents of the control unit 55 of the first embodiment are denoted by the same reference numerals as those of the first embodiment, and the description thereof is omitted.
- Control unit 55 after determining the rotational speed N c of the compressor 34 (step ST13), a decision is made as to whether the rotational speed N c is larger than the lower limit rotation speed N MIN (step ST51).
- the lower limit rotation speed N MIN is set to a lower limit value in a rotation speed range in which the compressor 34 can stably rotate.
- step ST51 When the rotational speed N c is larger than the lower limit rotation speed N MIN (Yes in step ST51), the control unit 55 proceeds to step ST14. Since the control contents of steps ST14 to ST20 are the same as those of the first embodiment, description thereof is omitted.
- step ST51 said when the rotation speed N c is less than the lower limit engine speed N MIN, the control unit 55 stops the compressor 34 (step ST52). Further, the control unit 55 determines the flow rate of the heating medium supplied to the heater 26, opens the fourth on-off valve 29 at the opening degree (step ST53), and determines the flow rate of the cooling medium supplied to the cooler 24. Then, the third on-off valve 28 is opened at the opening (step ST54).
- control unit 55 drives the first pump 53 until the detection value L1 of the detector 44a reaches a preset upper limit value (step ST56). As a result, the heat recovery circuit 30 falls in a state where a predetermined amount of liquid working medium is stored in the tank 44.
- the shutdown of the heat recovery circuit 30 described above may be performed manually.
- the compressor 34 is stopped by operating an operation button (not shown) for manually operating the driving and stopping of the compressor 34.
- the control content of the control unit 55 after the compressor 34 is stopped is the same as the above-described steps ST53 to ST56.
- control unit 55 drives the compressor 34 when the detected value Q TOP of the flow sensor 18 becomes larger than the operating value Q ST, so the detected value Q TOP is the operating value.
- automatically heat recovery circuit 30 rises when it becomes larger than Q ST (start). Therefore, the thermal energy possessed by the first output fluid can be recovered more effectively.
- control unit 55 controls the compressor 34 when the detected value Q TOP becomes larger than the operating value Q ST and the detected value L2 of the liquid level sensor 24a becomes larger than the reference amount L ST.
- To drive That is, the amount of the liquid working medium that evaporates by receiving thermal energy from the first output fluid in the cooler 24, that is, the amount of the gaseous working medium that evaporates in the cooler 24 and flows into the compressor 34.
- the compressor 34 is driven after it is sufficiently secured. Therefore, the start-up of the heat recovery circuit 30 is stabilized.
- the controller 55 stops the compressor 34 when the rotation speed N C of the compressor 34 becomes smaller than the lower limit rotation speed N MIN , the rotation speed N C is smaller than the lower limit rotation speed N MIN.
- the heat recovery circuit 30 automatically falls (stops). Therefore, since the stable drive state of the compressor 34 is ensured, the drive in the unstable state of the heat recovery circuit 30 can be avoided.
- the control unit 55 determines the threshold value Q L-SV corresponding to the detection value of the flow sensor 18 at any time by referring to data stored in the control unit 55.
- the method for determining the threshold value Q L-SV is not limited to this.
- certain settings based on the total amount Q total such fluctuation range and the working medium of the first output fluid may be set.
- the control unit 55 closes the first on-off valve 51 and opens the second on-off valve 52, and when the detected value is smaller than the set value.
- the first on-off valve 51 may be opened and the second on-off valve 52 may be closed.
- the distillation apparatus of the above embodiment includes a separator that separates an input fluid including a first component and a second component into a first output fluid including the first component and a second output fluid including the second component; A cooler for cooling the first output fluid flowing out from the separator; a heater for heating the second output fluid flowing out from the separator; and a working medium, the working medium being the cooler
- the working medium gives heat energy received from the first output fluid by exchanging heat with the first output fluid to the second output fluid by exchanging heat with the second output fluid by the heater.
- a heat recovery circuit wherein the heat recovery circuit connects the cooler and the heater and circulates the working medium, and exchanges heat with the first output fluid by the cooler.
- An amount adjustment unit, and the circulation amount adjustment unit includes the circulation flow of the working medium stored in the storage unit so that the circulation amount increases or decreases in accordance with an increase or decrease in the flow rate of the first output fluid.
- the outflow amount to the path or the inflow amount to the storage part of the working medium circulating in the circulation flow path is adjusted.
- the thermal energy of the first output fluid flowing out from the separator is not directly input to the second output fluid by the first output fluid itself, but via the working medium circulating in the circulation flow path. Indirectly into the second output fluid. Specifically, the thermal energy of the first output fluid is recovered by the working medium by heat exchange between the first output fluid and the working medium in the cooler, and then the working medium and the second output fluid in the heater. Heat exchange with the second output fluid. That is, in this apparatus, the first output fluid itself is not compressed by the compressor as a heat energy transfer medium, but the working medium circulating in the circulation channel is compressed by the compressor as the transfer medium. Therefore, even when the first output fluid contains a component that is difficult to be directly compressed as the first component, the thermal energy of the first output fluid can be effectively recovered through the working medium. (Reducing the heat energy supplied to the heater).
- the thermal energy of the first output fluid can be effectively recovered according to the variation. That is, as the flow rate of the first output fluid increases or decreases, the thermal energy that can be recovered from the first output fluid also increases or decreases, but this device adjusts the amount of circulation and the reservoir that can store the liquid working medium. And the circulation amount adjusting unit that recovers the thermal energy of the first output fluid effectively in accordance with the fluctuation of the flow rate. More specifically, since the liquid working medium is stored in the storage unit, a larger amount of the working medium can be stored than when the gaseous working medium is stored in the storage unit. Therefore, it is possible to flexibly cope with large fluctuations in the flow rate of the first output fluid.
- the storage section has a storage flow path connected to the circulation flow path so as to be parallel to a portion of the circulation flow path through which the liquid working medium flows, and the circulation flow path.
- the amount adjustment unit includes: a first on-off valve provided in the storage channel; and a second on-off valve provided in a portion of the storage channel downstream of the portion where the first on-off valve is provided.
- a flow rate sensor capable of detecting a flow rate of the first output fluid flowing into the cooler or a flow rate of the first output fluid flowing out of the cooler, and the first opening and closing according to a detection value of the flow rate sensor
- a control unit that controls opening and closing of the valve and the second on-off valve, and the control unit closes the first on-off valve and closes the first on-off valve so that the circulation amount increases or decreases in accordance with the increase or decrease of the detection value.
- opening the second on-off valve or opening the first on-off valve Preferably the second shut-off valve closed as well.
- the circulation amount adjusting unit causes the liquid working medium to flow out from the storage channel to the circulation channel when the first on-off valve is closed and the second on-off valve is open. And an accelerating portion that promotes the inflow of the liquid working medium from the circulation channel to the storage channel when the first on-off valve is open and the second on-off valve is closed. It is preferable to provide.
- the promotion unit causes the liquid working medium to flow out of the storage channel to the circulation channel. Promote.
- the accelerating unit is configured to transfer the liquid working medium from the circulation passage to the storage passage. Promote inflow. For this reason, the amount of circulation smoothly increases and decreases according to the increase and decrease of the flow rate of the first output fluid. Therefore, the recovery efficiency of the thermal energy of the first output fluid is further increased.
- control unit closes the first on-off valve and opens the second on-off valve when the circulation amount is smaller than a threshold value determined based on the detection value, and the circulation amount is It is preferable that the first on-off valve is opened and the second on-off valve is closed when larger than the threshold value.
- the circulation amount follows the threshold value determined as needed based on the detection value of the flow sensor.
- this threshold value the operation capable of recovering as much heat energy as possible from the first output fluid.
- the recovery efficiency of the thermal energy of the first output fluid is further increased.
- the storage section further includes a tank provided in a portion of the storage channel between the first on-off valve and the second on-off valve and storing the liquid working medium. It is preferable.
- the heater has a heating medium flow path that can be connected to a heating medium supply flow path for supplying a heating medium to the heater.
- the cooler has a coolant flow path that can be connected to a coolant supply flow path for supplying a coolant to the cooler.
- control unit drives the compressor when a detection value of the flow sensor becomes larger than a preset operation value.
- the heat recovery circuit automatically starts up (starts up) when the detection value of the flow sensor becomes larger than the operating value, so that the thermal energy of the first output fluid can be recovered more effectively. Can do.
- the heat recovery circuit further includes a liquid level sensor capable of detecting a storage amount of the liquid working medium in the cooler, and the control unit has a detection value of the flow rate sensor that is greater than the operating value.
- the compressor is driven when the detected value of the liquid level sensor becomes larger than a preset reference amount.
- the amount of the liquid working medium that evaporates by receiving heat energy from the first output fluid in the cooler that is, the amount of the gaseous working medium that flows into the compressor after evaporating in the cooler. Since the compressor is driven after a sufficient amount is secured, the start of the heat recovery circuit is stabilized.
- control unit stops the compressor when the rotation speed of the compressor becomes smaller than a preset lower limit rotation speed.
- the heat recovery circuit automatically falls (stops) when the rotation speed of the compressor becomes lower than the lower limit rotation speed.
- the lower limit rotation speed can be driven stably.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Abstract
Description
本発明の第一実施形態の蒸留装置について、図1及び図2を参照しながら説明する。
次に、本発明の第二実施形態の蒸留装置について、図3~図5を参照しながら説明する。なお、この第二実施形態では、第一実施形態と異なる部分についてのみ説明を行い、第一実施形態と同じ構造、作用及び効果の説明は省略する。
Claims (10)
- 第一成分及び第二成分を含む入力流体を前記第一成分を含む第一出力流体と前記第二成分を含む第二出力流体とに分離する分離器と、
前記分離器から流出した前記第一出力流体を冷却するための冷却器と、
前記分離器から流出した前記第二出力流体を加熱するための加熱器と、
作動媒体を含み当該作動媒体が前記冷却器で前記第一出力流体と熱交換することによって当該第一出力流体から受け取った熱エネルギーを、当該作動媒体が前記加熱器で前記第二出力流体と熱交換することによって当該第二出力流体に与える熱回収回路と、を備え、
前記熱回収回路は、前記冷却器及び前記加熱器を接続しており前記作動媒体を循環させる循環流路と、前記冷却器で前記第一出力流体と熱交換することによって当該第一出力流体から前記熱エネルギーを受け取った後の作動媒体を圧縮する圧縮機と、前記加熱器で前記第二出力流体と熱交換することによって当該第二出力流体に前記熱エネルギーを与えた後の作動媒体を膨張させる膨張機構と、前記循環流路に接続されており液状の作動媒体を貯留可能な貯留部と、前記循環流路を循環している作動媒体の総量である循環量を調整する循環量調整部と、を有し、
前記循環量調整部は、前記第一出力流体の流量の増減に合わせて前記循環量が増減するように、前記貯留部に貯留されている作動媒体の前記循環流路への流出量又は前記循環流路を循環している作動媒体の前記貯留部への流入量を調整する蒸留装置。 - 請求項1に記載の蒸留装置において、
前記貯留部は、前記循環流路のうち前記液状の作動媒体が流れる部位に対して並列となるように当該循環流路に接続された貯留流路を有しており、
前記循環量調整部は、前記貯留流路に設けられた第一開閉弁と、前記貯留流路のうち前記第一開閉弁が設けられた部位よりも下流側の部位に設けられた第二開閉弁と、前記冷却器に流入する前記第一出力流体の流量、または前記冷却器から流出した前記第一出力流体の流量を検出可能な流量センサと、前記流量センサの検出値に応じて前記第一開閉弁及び前記第二開閉弁の開閉を制御する制御部と、を含み、
前記制御部は、前記検出値の増減に合わせて前記循環量が増減するように、前記第一開閉弁を閉じるとともに前記第二開閉弁を開く、または前記第一開閉弁を開くとともに前記第二開閉弁を閉じる蒸留装置。 - 請求項2に記載の蒸留装置において、
前記循環量調整部は、前記第一開閉弁が閉じており前記第二開閉弁が開いているときに前記貯留流路から前記循環流路への前記液状の作動媒体の流出を促進させ、かつ、前記第一開閉弁が開いており前記第二開閉弁が閉じているときに前記循環流路から前記貯留流路への前記液状の作動媒体の流入を促進させる促進部をさらに備える蒸留装置。 - 請求項2又は3に記載の蒸留装置において、
前記制御部は、前記循環量が前記検出値に基づいて決定される閾値よりも小さいときに前記第一開閉弁を閉じるとともに前記第二開閉弁を開き、前記循環量が前記閾値よりも大きいときに前記第一開閉弁を開くとともに前記第二開閉弁を閉じる蒸留装置。 - 請求項2に記載の蒸留装置において、
前記貯留部は、前記貯留流路のうち前記第一開閉弁と前記第二開閉弁との間の部位に設けられており前記液状の作動媒体を貯留するタンクをさらに備える蒸留装置。 - 請求項1に記載の蒸留装置において、
前記加熱器は、当該加熱器に加熱媒体を供給するための加熱媒体供給流路と接続可能な加熱媒体流路を有している蒸留装置。 - 請求項1に記載の蒸留装置において、
前記冷却器は、当該冷却器に冷却媒体を供給するための冷却媒体供給流路と接続可能な冷却媒体流路を有している蒸留装置。 - 請求項1に記載の蒸留装置において、
前記制御部は、前記流量センサの検出値が予め設定された稼働値よりも大きくなったときに前記圧縮機を駆動する蒸留装置。 - 請求項8に記載の蒸留装置において、
前記熱回収回路は、前記冷却器内における前記液状の作動媒体の貯留量を検出可能な液面センサをさらに備え、
前記制御部は、前記流量センサの検出値が前記稼働値よりも大きくなり、かつ前記液面センサの検出値が予め設定された基準量よりも大きくなったときに前記圧縮機を駆動する蒸留装置。 - 請求項1に記載の蒸留装置において、
前記制御部は、前記圧縮機の回転数が予め設定された下限回転数よりも小さくなったときに当該圧縮機を停止する蒸留装置。
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US15/303,454 US10272358B2 (en) | 2014-05-23 | 2015-04-28 | Distillation apparatus |
SA516380144A SA516380144B1 (ar) | 2014-05-23 | 2016-10-25 | جهاز تقطير قادر على تجميع الطاقة الحرارية بفعالية لمائع المخرجات الأول |
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