WO2015156703A3 - Functional metallosiloxanes, products of their partial hydrolysis and their use - Google Patents

Functional metallosiloxanes, products of their partial hydrolysis and their use Download PDF

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Publication number
WO2015156703A3
WO2015156703A3 PCT/RU2015/000242 RU2015000242W WO2015156703A3 WO 2015156703 A3 WO2015156703 A3 WO 2015156703A3 RU 2015000242 W RU2015000242 W RU 2015000242W WO 2015156703 A3 WO2015156703 A3 WO 2015156703A3
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WO
WIPO (PCT)
Prior art keywords
metallosiloxanes
functional
products
partial hydrolysis
alkyl
Prior art date
Application number
PCT/RU2015/000242
Other languages
French (fr)
Other versions
WO2015156703A2 (en
Inventor
Aziz Mansurovich Muzafarov
Nadezhda Andreevna Tebeneva
Ivan Borisovich Meshkov
Alexander Nikolaevich TARASENKOV
Original Assignee
Enikolopov Institute Of Synthetic Polymeric Materials, A Foundation Of The Russian Academy Of Sciences (Ispm Ras)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enikolopov Institute Of Synthetic Polymeric Materials, A Foundation Of The Russian Academy Of Sciences (Ispm Ras) filed Critical Enikolopov Institute Of Synthetic Polymeric Materials, A Foundation Of The Russian Academy Of Sciences (Ispm Ras)
Publication of WO2015156703A2 publication Critical patent/WO2015156703A2/en
Publication of WO2015156703A3 publication Critical patent/WO2015156703A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/069—Aluminium compounds without C-aluminium linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04—Polysiloxanes
    • C08J2383/06—Polysiloxanes containing silicon bound to oxygen-containing groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Silicon Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to the field of chemical technology of organic silicon compounds, in particular, to functional metallosiloxanes, products of their partial hydrolysis, the method of their preparation, and to their use as crosslinking agents in compositions based on rubber. Disclosed are functional metallosiloxanes of the general formula (I): wherein M is a two-, three-or four-valent metal; p+m correspond to the valence of the metal, provided that p and m ≠ 0; n is 0 or 1; R represents C1-C4 alkyl; R' and R" are independently the same or different and represent C1 -C4 alkyl, C6H5-, CH2=CH- and NH2(CH2)x, where x has a value from 2 to 5; and Alk is a C1-C4 alkyl substituent. Also disclosed is the method for preparing functional metallosiloxanes, products of their partial hydrolysis and the method of their preparation, and their use as crosslinkers in curable compositions based on rubber, preferably silicone rubber.
PCT/RU2015/000242 2014-04-11 2015-04-13 Functional metallosiloxanes, products of their partial hydrolysis and their use WO2015156703A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2014114570A RU2649392C2 (en) 2014-04-11 2014-04-11 Functional metallosiloxanes, products of their partial hydrolysis and their application
RU2014114570 2014-04-11

Publications (2)

Publication Number Publication Date
WO2015156703A2 WO2015156703A2 (en) 2015-10-15
WO2015156703A3 true WO2015156703A3 (en) 2015-12-10

Family

ID=54064552

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2015/000242 WO2015156703A2 (en) 2014-04-11 2015-04-13 Functional metallosiloxanes, products of their partial hydrolysis and their use

Country Status (2)

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RU (1) RU2649392C2 (en)
WO (1) WO2015156703A2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102438946B1 (en) * 2015-11-26 2022-09-02 도레이 카부시키가이샤 Polymetaloxane, its manufacturing method, its composition, its cured film, its manufacturing method, and member and electronic component provided with the same
WO2019087286A1 (en) * 2017-10-31 2019-05-09 日立化成株式会社 Barrier material formation composition, barrier material, production method for barrier material, product, and production method for product
WO2019188835A1 (en) * 2018-03-29 2019-10-03 東レ株式会社 Polymetalloxane, composition, cured film, member, electronic component, fiber, binder for ceramic molding, cured film production method, and fiber production method
RU2767650C1 (en) * 2020-12-15 2022-03-18 Федеральное государственное бюджетное учреждение науки Институт синтетических полимерных материалов им. Н.С. Ениколопова Российской академии наук (ИСПМ РАН) Polysiloxane compositions and elastomeric materials with high dielectric permeability based thereon
RU2766219C1 (en) * 2020-12-30 2022-02-09 Федеральное государственное бюджетное учреждение науки Институт элементоорганических соединений им. А.Н. Несмеянова Российской академии наук (ИНЭОС РАН) Compositions for producing organosilicon materials with self-healing effect
US20240132675A1 (en) * 2021-03-22 2024-04-25 Toray Industries, Inc. Polymer having metal-oxygen-metal bond as primary chain, composition thereof, solid material and production method thereof, and electronic component and fiber

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JPH03122098A (en) * 1989-10-02 1991-05-24 Mitsubishi Materials Corp Composition for diffusing antimony
JPH11116240A (en) * 1997-10-15 1999-04-27 Nippon Shokubai Co Ltd Ultraviolet-ray absorbing fine particles and their use
EP1652891A1 (en) * 2003-07-18 2006-05-03 Konishi Co., Ltd. Curable resin composition and cold-setting adhesive

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US4528313A (en) 1984-06-15 1985-07-09 Dow Corning Corporation Polydimethylsiloxanes having improved thermal stability
JPH05254818A (en) * 1992-03-09 1993-10-05 Hitachi Chem Co Ltd Production of metallosiloxane sol solution and gelatinous polymer
US6037092A (en) 1999-08-17 2000-03-14 Xerox Corporation Stabilized fluorosilicone fuser members
US6336026B1 (en) 1999-08-17 2002-01-01 Xerox Corporation Stabilized fluorosilicone transfer members
US6297302B1 (en) 1999-08-17 2001-10-02 Xerox Corporation Stabilized fluorosilicone materials
RU2293746C1 (en) * 2005-12-29 2007-02-20 Институт синтетических полимерных материалов им. Н.С. Ениколопова РАН (ИСПМ им. Н.С. Ениколопова РАН) Functional polymetallosiloxanes
RU2296767C1 (en) * 2005-12-29 2007-04-10 Институт синтетических полимерных материалов (ИСПМ) им. Н.С. Ениколопова РАН Functional metallosiloxanes and method for their preparing
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Publication number Publication date
RU2649392C2 (en) 2018-04-03
WO2015156703A2 (en) 2015-10-15
RU2014114570A (en) 2015-10-20

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