WO2015099315A1 - 무방향성 전기강판 및 그의 제조방법 - Google Patents
무방향성 전기강판 및 그의 제조방법 Download PDFInfo
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- WO2015099315A1 WO2015099315A1 PCT/KR2014/011931 KR2014011931W WO2015099315A1 WO 2015099315 A1 WO2015099315 A1 WO 2015099315A1 KR 2014011931 W KR2014011931 W KR 2014011931W WO 2015099315 A1 WO2015099315 A1 WO 2015099315A1
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- Prior art keywords
- steel sheet
- electrical steel
- manufacturing
- oriented electrical
- hot
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- 229910000565 Non-oriented electrical steel Inorganic materials 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 32
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 28
- 238000000137 annealing Methods 0.000 claims abstract description 28
- 239000010959 steel Substances 0.000 claims abstract description 28
- 238000005098 hot rolling Methods 0.000 claims abstract description 12
- 238000005097 cold rolling Methods 0.000 claims abstract description 10
- 239000012535 impurity Substances 0.000 claims abstract description 10
- 238000003303 reheating Methods 0.000 claims abstract description 6
- 229910000976 Electrical steel Inorganic materials 0.000 claims description 26
- 229910052787 antimony Inorganic materials 0.000 claims description 18
- 229910052718 tin Inorganic materials 0.000 claims description 16
- 229910052748 manganese Inorganic materials 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 238000009826 distribution Methods 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 7
- 239000010960 cold rolled steel Substances 0.000 claims description 6
- 230000009467 reduction Effects 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 abstract description 31
- 238000000034 method Methods 0.000 abstract description 19
- 238000001953 recrystallisation Methods 0.000 abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 63
- 230000004907 flux Effects 0.000 description 15
- 239000000463 material Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- 230000005389 magnetism Effects 0.000 description 7
- 238000005096 rolling process Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 5
- 238000005204 segregation Methods 0.000 description 5
- 238000007792 addition Methods 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 238000009628 steelmaking Methods 0.000 description 4
- 238000005275 alloying Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 230000008520 organization Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000010301 surface-oxidation reaction Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001887 electron backscatter diffraction Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
- H01F1/14766—Fe-Si based alloys
- H01F1/14775—Fe-Si based alloys in the form of sheets
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
- C21D8/1222—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
- C21D8/1233—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1261—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1272—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/004—Very low carbon steels, i.e. having a carbon content of less than 0,01%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/16—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets
Definitions
- Non-oriented electrical steel sheet and manufacturing method thereof are non-oriented electrical steel sheet and manufacturing method thereof.
- It relates to a non-oriented electrical steel sheet and a method of manufacturing the same.
- Non-oriented electrical steel sheet is mainly used in the equipment that converts electrical energy into mechanical energy, in the process requires excellent magnetic properties in order to exhibit high efficiency.
- Magnetic characteristics include iron loss and magnetic flux density. Low iron loss can reduce energy lost in energy conversion process, and high magnetic flux density can produce more power with small electric energy. Therefore, iron loss of non-oriented electrical steel sheet This low and high magnetic flux density can increase the motor's energy efficiency.
- high-frequency iron loss means iron loss at a frequency of 400 Hz or higher. In order to reduce this, it is important to increase the resistivity of the material.
- a commonly used method for increasing the magnetic properties of non-oriented electrical steel sheets is to add Si as an alloying element.
- the increase in the resistivity of steel through the addition of Si has the advantage of lowering the high frequency iron loss, but the magnetic flux density is inferior and the workability is deteriorated.
- non-oriented electrical steel sheets are also greatly influenced by the texture.
- Japanese Patent No. 2004-197217 proposes a method of cold rolling and recrystallization annealing by making the grain size 400 or more after hot-rolled sheet annealing.
- Japanese Patent 1996-088114 proposes a method of developing an aggregate structure advantageous to magnetic properties through two cold rolling methods including an intermediate annealing.
- all of these methods to improve the collective structure have a problem that the productivity is too low or the cost increases to be applied to the actual production process.
- One embodiment of the present invention to provide a non-oriented electrical steel sheet.
- Another embodiment of the present invention is to provide a method for producing a non-oriented electrical steel sheet.
- [Al], [Mn], [Sb], and [Sn] mean weight percent (%) of Al, Mn, Sb, and Sn, respectively.
- the thickness of the electrical steel sheet may be 0.15 to 0.35mm.
- the electrical steel sheet includes a composite inclusion including one or two selected from A1N and MnS, and the distribution density of the composite inclusions having a size of 10 nm or more is
- the average grain size of the electrical steel sheet may be 50 to 150.
- the electrical steel sheet may have a fraction of more than 25% of a structure in which ⁇ 001 ⁇ plane is parallel to the plate surface of the electrical steel sheet within 15 °.
- Si 2.5-3.5%
- Al 0.3-1.5%
- Mn 0.3-1.5%
- N 0.001-0.005%
- S 0.001-0.005%
- Sb 0.001-0.005%
- 0.02-0.25% and Sn contains one or two selected from 0.02 0.25%, the balance contains Fe and other inevitable impurities, the content of Al, Mn, Sb and Sn is represented by the following formulas 1 to 3 Manufacturing a slab satisfying the above; Reheating the slab and hot rolling to manufacture a hot rolled steel sheet; cold rolling the hot rolled steel sheet to manufacture a cold rolled steel sheet; And it provides a method for producing a non-oriented electrical steel sheet comprising the final annealing the cold rolled steel sheet.
- the final annealing electrical steel sheet comprises a composite inclusion including one or two selected from among A1N and MnS therein, the distribution density of inclusions having a size of 10nm or more 0.02 / mm May be 2 or less.
- the average grain size of the electrical steel sheet may be 50 to 150.
- the final annealing step of the electrical steel sheet may have a fraction of the tissue parallel to the plate surface of the ⁇ 001 ⁇ plane o electrical steel sheet within 15 ° 25% or more.
- the reheating may be carried out at a temperature of 1100 ° C to 1,200 ° C.
- the hot rolling may be finished at temperatures above 800 ° C.
- it may further comprise the step of annealing the hot rolled steel sheet.
- the hot rolled sheet annealing may be carried out at a temperature of 850 to 1150 ° C.
- the cold rolled steel sheet may be manufactured to a thickness of 0.15 to 0.35mm by applying a reduction ratio of 70 to 95%.
- the final annealing may be carried out at a temperature of 850 to 1 HKTC.
- the distribution density of the inclusions in the steel sheet is reduced to improve the iron loss, while the ⁇ 001 ⁇ plane is parallel to the plate surface of the electrical steel sheet within 15 °.
- the fraction of the structure forming the structure it is possible to provide a non-oriented electrical steel sheet having an excellent magnetic flux density. Accordingly, the efficiency of eco-friendly driving motors can be improved.
- Method for producing a non-oriented electrical steel sheet according to an embodiment of the present invention is increased by%
- Si 2.5-3.5%
- A1 0.3-1.5%
- Mn 0.3-1.5%
- N 0.001-0.005%
- S 0.001 0.005%
- Sb 0.02 0.25%
- Sn 02-0.25%
- the non-oriented electrical steel sheet may have a thickness of 0.15 to 0.35 mm.
- the non-oriented electrical steel sheet has a composite inclusion including at least one of AIN or MnS in the steel sheet, and the distribution density of inclusions having a size of 10 nm or more is 0.02 pieces / mm 2 .
- the magnetic flux density is high when manufacturing the product because the fraction of the tissue whose surface is parallel to the plate surface of the electrical steel sheet within 15 ° is 25% or more and the average grain size of the steel sheet is in the range of 50 to 150.
- Si 2.5-3.5 weight 0 /.
- Si plays a role of lowering iron loss by increasing the specific resistance of the material. When it is added below 2.5%, the effect of improving high frequency iron loss is insufficient, and when it is added above 3.5%, the hardness of the material increases and productivity and punchability are increased. It is not desirable because it causes heat. More specifically, it may be 2.7 to 3.4% by weight.
- A1 increases the resistivity of the material, lowers iron loss and forms nitride. If A1 is added below 0.3%, it is not effective in reducing high frequency iron loss, and nitride is finely formed, which deteriorates the magnetism. If it is added more than 1.5%, it causes problems in all processes such as steelmaking and continuous casting. Lowers. More specifically, it may be 0.5 1.0 increment 0 /.
- Mn improves iron resistivity and forms sulfides by increasing the specific resistance of the material, and when added below 0.3%, MnS is finely precipitated to deteriorate magnetism and hardly improve high frequency iron loss.
- Mn is added in excess of 1.5%, the amount of Mn added is 0.1-1.5% because the ⁇ 111 ⁇ surface, which is disadvantageous to magnetism, promotes the formation of a structure parallel to the plate surface of the electrical steel sheet within 15 0 . Limiting
- the weight may be 0.1 0.7 0/0.
- N forms fine and long A1N precipitates inside the base metal to suppress grain growth and infers iron loss
- the content of N is limited by grain boundary segregation elements.
- S forms fine precipitates, MnS and CuS, which deteriorate its magnetic properties. It is preferable to remove the refining process in steelmaking as an element if possible, Since the diffusion of S is limited by grain boundary segregation elements, the content is limited to 001 to 005%. More specifically, it may be 0.0019 to 0.0024%.
- Sn segregates on the surface and grain boundaries of the steel sheet to inhibit surface oxidation during annealing, impedes the diffusion of elements through the grain boundaries, and recrystallizes the structure where ⁇ 111 ⁇ plane is parallel to the plate surface of the electrical steel sheet within 15 °. Interfere to improve collective organization.
- toughness is reduced due to an increase in the amount of grain boundary segregation, which is not preferable because productivity is lowered compared to magnetic improvement. More specifically, it may be 0.03 0.12%.
- the reason for limiting ([Sb] + [Sn]) to 0.05 0.25% is that the effect of improving the magnetism is most excellent in this range. At 0.05% or less, there is no magnetic improvement effect. At 0.25% or more, the magnetism is deteriorated, and the toughness of the material is excessively lowered, which causes problems in productivity. More specifically, it may be 0.06 0.24%.
- elements such as C, Ti, and Nb may be included. Since C causes self aging, the C content should be limited to 0.004% or less, preferably 0.003% or less.
- Ti is an undesirable crystal orientation in non-oriented electrical steel sheet. It may be less than 0.004%, more preferably less than 0.002% because it promotes the growth of tissue parallel to the plate surface within 15 °.
- the controlled molten steel is uncoiled in a continuous casting process to produce slabs.
- the precipitate may be re-dissolved so that it may be finely precipitated after hot rolling, and then reheated at 1200 ° C or lower.
- the slab is reheated, it is then hot rolled. During hot rolling
- Hot and cold rolling is preferably carried out at a temperature of 800 ° C or more.
- Hot rolled hot rolled sheet is annealed at a temperature of 850 ⁇ 1150 ° C. If the hot-rolled sheet annealing temperature is less than 850 ° C, the structure does not grow or finely grow, so there is little synergy effect of the magnetic flux density. If the annealing temperature exceeds 1, 150 ° C, the magnetic properties deteriorate, Due to the poor rolling workability, the silver range is limited to 850 ⁇ 1,150 ° C. More preferred annealing temperature of the hot rolled sheet
- Hot-rolled sheet annealing is performed in order to increase the orientation favorable to magnetic as needed, but it is also possible to omit hot-rolled sheet annealing.
- the hot rolled sheet is annealed or black is omitted. Then, the hot rolled sheet is pickled and then cold rolled to a predetermined plate thickness.
- the hot rolling can be made cold rolled plate to a thickness of less than 0.35mm by applying a reduction ratio of about 70 ⁇ 95%. More specifically, it may be 0.15 to 0.35mtn. In case of less than 0.35mm, iron loss improvement and magnetic flux density of electrical steel sheet are excellent at high frequency.
- the reduction ratio means (thickness before rolling minus thickness after rolling) / (thickness before rolling).
- Cold rolled cold rolled plates are subjected to final annealing. If the final annealing temperature is less than 850 ° C, recrystallization does not occur sufficiently. If the final annealing silver exceeds 1100 ° C, the grain size becomes too large and the high frequency iron loss is opened. Preference is given to performing at a temperature of 100 ° C.
- the manufacturing method of the non-oriented electrical steel sheet according to the present invention through the embodiment. However, the following examples are merely to illustrate the invention, but the content of the present invention is not limited by the following examples.
- Vacuum dissolution in a laboratory produced a steel ingot of the same component as shown in Table 1 below. Impurities C, Ti, and Nb of the material were all controlled to 0.0025% or less. Each material was reheated to 1130 ° C and hot finished rolling at 87 C C to produce a 2.0 mm thick hot rolled sheet. The hot rolled hot rolled sheet was annealed and cold rolled at 1100 ° C, pickled and cold rolled to a thickness of 0.30 mm, and then subjected to final annealing at 980 ° C for 100 seconds.
- a 19 3.4 1.0 0.6 0.15 0.13 0.0020 0.0019 0.0020 0.0024 0.0020 Table shows the amount and percentage of major component additions, iron loss, magnetic flux density, inclusion distribution density, and ⁇ 001 ⁇ // ND fraction (the fraction of tissue where ⁇ 001 ⁇ plane is parallel to the plate surface of electrical steel within 15 °). 2 is shown. Magnetic properties were calculated by measuring the rolling direction and the vertical direction using a single sheet tester and averaging them. Sample preparation for observation of inclusions was carried out using a replica method, which is a common method for steel materials, and a transmission electron microscope was used as a device. At this time, the acceleration voltage was applied to 200kV. Aggregates were measured using EBSD, and the O001 was calculated to calculate the ⁇ 001 ⁇ // ND fraction, including the orientation within an error range of 15 °.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Electromagnetism (AREA)
- Manufacturing & Machinery (AREA)
- Power Engineering (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing Of Steel Electrode Plates (AREA)
- Soft Magnetic Materials (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
Description
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Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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US15/107,900 US10643771B2 (en) | 2013-12-23 | 2014-12-05 | Non-oriented electrical steel sheet and manufacturing method therefor |
JP2016560323A JP6596016B2 (ja) | 2013-12-23 | 2014-12-05 | 無方向性電磁鋼板およびその製造方法 |
CN201480070626.8A CN105849300B (zh) | 2013-12-23 | 2014-12-05 | 无取向性电工钢板及其制造方法 |
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KR10-2013-0161744 | 2013-12-23 | ||
KR1020130161744A KR20150073719A (ko) | 2013-12-23 | 2013-12-23 | 무방향성 전기강판 및 그의 제조방법 |
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WO2015099315A1 true WO2015099315A1 (ko) | 2015-07-02 |
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US (1) | US10643771B2 (ko) |
JP (1) | JP6596016B2 (ko) |
KR (1) | KR20150073719A (ko) |
CN (1) | CN105849300B (ko) |
WO (1) | WO2015099315A1 (ko) |
Cited By (3)
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KR102325011B1 (ko) * | 2019-12-20 | 2021-11-11 | 주식회사 포스코 | 무방향성 전기강판 및 그 제조방법 |
CN111304518B (zh) * | 2020-03-16 | 2021-04-09 | 新余钢铁股份有限公司 | 一种变频空调用无取向电工钢及其制造方法 |
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US10643771B2 (en) | 2020-05-05 |
KR20150073719A (ko) | 2015-07-01 |
CN105849300B (zh) | 2017-09-08 |
US20160322137A1 (en) | 2016-11-03 |
JP2017509799A (ja) | 2017-04-06 |
JP6596016B2 (ja) | 2019-10-23 |
CN105849300A (zh) | 2016-08-10 |
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