WO2015022254A1 - Récipient en matière plastique pour aérosol fabriqué à partir d'un copolyester contenant un isosorbide et distributeur d'aérosol comprenant ledit récipient en matière plastique pour aérosol - Google Patents

Récipient en matière plastique pour aérosol fabriqué à partir d'un copolyester contenant un isosorbide et distributeur d'aérosol comprenant ledit récipient en matière plastique pour aérosol Download PDF

Info

Publication number
WO2015022254A1
WO2015022254A1 PCT/EP2014/066958 EP2014066958W WO2015022254A1 WO 2015022254 A1 WO2015022254 A1 WO 2015022254A1 EP 2014066958 W EP2014066958 W EP 2014066958W WO 2015022254 A1 WO2015022254 A1 WO 2015022254A1
Authority
WO
WIPO (PCT)
Prior art keywords
container
aerosol
isosorbide
copolyester
preform
Prior art date
Application number
PCT/EP2014/066958
Other languages
English (en)
Inventor
Laurent Degroote
Alain Dessaint
Cor Jansen
Original Assignee
La Seda De Barcelona S.A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by La Seda De Barcelona S.A filed Critical La Seda De Barcelona S.A
Priority to MX2016001991A priority Critical patent/MX2016001991A/es
Priority to JP2016533893A priority patent/JP2016529171A/ja
Priority to BR112016002884A priority patent/BR112016002884A2/pt
Priority to CA2919889A priority patent/CA2919889A1/fr
Priority to US14/911,540 priority patent/US20160185510A1/en
Priority to RU2016108984A priority patent/RU2016108984A/ru
Priority to CN201480050690.XA priority patent/CN105658539A/zh
Priority to AU2014307974A priority patent/AU2014307974A1/en
Publication of WO2015022254A1 publication Critical patent/WO2015022254A1/fr
Priority to ZA2016/00794A priority patent/ZA201600794B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/38—Details of the container body
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00—Details of bottles or jars not otherwise provided for
    • B65D23/10—Handles
    • B65D23/102—Gripping means formed in the walls, e.g. roughening, cavities, projections
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/16—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant characterised by the actuating means
    • B65D83/20—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant characterised by the actuating means operated by manual action, e.g. button-type actuator or actuator caps
    • B65D83/205—Actuator caps, or peripheral actuator skirts, attachable to the aerosol container
    • B65D83/206—Actuator caps, or peripheral actuator skirts, attachable to the aerosol container comprising a cantilevered actuator element, e.g. a lever pivoting about a living hinge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/44—Valves specially adapted therefor; Regulating devices
    • B65D83/48—Lift valves, e.g. operated by push action

Definitions

  • the present invention relates to a novel injection stretch blow molded aerosol container and to a novel plastic preform suitable to be stretch blow molded in order to form an aerosol container.
  • the invention also relates to a novel aerosol plastic dispenser for dispensing an aerosol or other comparably pressurized product.
  • Aerosol dispensers are well known in the art. More especially, aerosol dispensers comprise an aerosol container that contains an aerosol (or other comparably pressurized product), and that is fitted with a valve dispensing device for dispensing the aerosol. Aerosol dispensers comprising an aerosol container made of plastic are for example disclosed in US patent application US 2004/0149781 and in PCT application WO 2007/140407.
  • aerosol used herein encompasses both aerosol, literally, and also other liquids or flowable products that can be dispensed from pressurized containers in a manner comparable to aerolized products.
  • Such other liquids or flowable products include but are not limited to foam or gel preparations or to liquid products delivered from pressurized containers but not necessarily in a pulverized form.
  • Examples of typical aerosol compositions can be notably but not exhaustively insecticides, insect repellents, hairsprays, cosmetic sprays, air fresheners, cleaning preparation, shave preparations including foams and gels.
  • plastic aerosol dispensers have to fulfill the technical requirements of standard FEA 621 of March 2007 meeting the provisions of the Aerosol Dispensers Directive 75/324/EEC of May 1975 and related to the measurement of internal pressure resistance of empty containers without valves.
  • PET Polyethylene Terephthalate
  • ISBM Injection Stretched Blow Molded
  • polyesters like for example PET homo or copolymers, can advantageously exhibit strain-induced crystallization upon substantial orientation, in a region above the Natural Stretch Ratio (NSR) of the polymer.
  • NSR Natural Stretch Ratio
  • the NSR of a polymer can be knowingly determined in a free- blowing experiment.
  • Free-blowing of thermoplastics, in particular PET and PET copolymers is a well known technique used to obtain empirical data on the stretching behavior of a particular resin formulation.
  • the method of free blowing PET preforms is described in "Blow Molding Handbook", edited by Donald V. Rosato, Dominick V. Rosato, Kunststoff 1989.
  • the terrrffree-blowing means that a preform is blow-molded without using a mold.
  • Free-blowing a bottle from a preform involves heating the preform to a temperature above its glass transition temperature and then expanding the preform outside of a mold so that it is free to expand without restriction until the onset of strain hardening.
  • Strain hardening can be detected in a stress-strain curve as an upswing in stress following the flow plateau. To a large extent the strain hardening is associated with molecular ordering processes in the resin. If the blow pressure and heating of the preform is properly set for a given preform, it will continue to expand until all of the PET is oriented to the point that stretching will stop at about the natural stretch ratio, or slightly beyond.
  • Standard ISBM grade PET even in the strain-hardening region, is however generally not suitable for making pressure-resistant ISBM aerosol containers that withstand high internal pressure, and more generally for making pressure-resistant ISBM aerosol containers that would fulfill the technical requirements of standard FEA 621 of March 2007.
  • the diol 1 ,4:3,6-dianhydro-D-sorbitol referred to hereinafter as isosorbide, the structure of which is illustrated below, is readily made from renewable resources, such as sugars and starches, in particular natural starch extracted from maize, wheat, potatoes and peas.
  • isosorbide can be made from D-glucose by hydrogenation followed by acid-catalyzed dehydration.
  • Isosorbide has been already used as a monomer for incorporation into polyesters such as PET at low levels.
  • the incorporation of isosorbide as comonomer in a copolyester knowingly reduces the intrinsic viscosity of the copolyester.
  • Isosorbide containing copolyesters and in particular Polyethylene Terephthalate containing Isosorbide (PEIT) polymers, as well as their process of manufacturing by melt polymerization or by solvent polymerization are thus well-known in the art.
  • PEIT Polyethylene Terephthalate containing Isosorbide
  • Isosorbide containing copolyesters and in particular Polyethylene Terephthalate containing Isosorbide (PEIT) polymers, are used to date in many applications, and for example for making films or containers.
  • PEIT Polyethylene Terephthalate containing Isosorbide
  • PEIT can be used for making hot-fillable containers that withstand high temperatures.
  • Polyethylene Terephthalate containing Isosorbide (PEIT) polymers can be used to date in many applications, one cannot find on the market ISBM aerosol containers made form a isosorbide containing copolyesters and in particular made from a PEIT polymer.
  • ISBM pressure-resistant aerosol containers made from an isosorbide containing copolyester and in particular made from a PEIT polymer.
  • a main objective of the invention is thus to propose a novel pressure-resistant aerosol plastic container made from an isosorbide containing copolyester, and in particular (but not only) made from a PEIT polymer.
  • a first object of the invention is a plastic preform adapted to be stretch blow molded in order to form an aerosol container or an injection stretch blow molded aerosol container, said preform or aerosol container being made from a polymeric material that comprises a copolyester including at least 1 mole % of isosorbide as comonomer and having an intrinsic viscosity of at least 0.7 dL/g.
  • the ISBM aerosol container of the invention exhibit very good mechanical properties, and in particular can advantageously withstand high internal pressure.
  • Aerosol containers are generally containers of small volumes, typically not more than 750ml. Consequently, when aerosol containers are made by using ISBM technology, only low stretch ratios can be practiced.
  • isosorbide as comonomer in a copolyester has a strong impact on the onset of the strain-hardening region of the copolyester, and more particularly increases the NSR of the copolyester. Otherwise stated, isosorbide containing copolyesters, and in particular Polyethylene Terephthalate containing Isosorbide (PEIT) polymers, require a much higher elongation for reaching the strain-hardening region than a standard PET homopolymer.
  • PEIT Polyethylene Terephthalate containing Isosorbide
  • the invention removed this prejudice by increasing the intrinsic viscosity of the isosorbide containing copolyester, for example by carrying out a Solid State Polymerization (SSP) of the copolyester for a period sufficient to achieve an IV of at least 0.7dl_/g.
  • SSP Solid State Polymerization
  • This increase of IV advantageously decreases the NSR of the copolyester and enables to obtain a copolyester combining a high level of isosorbide and a lower NSR and suitable for making pressure-resistant ISBM aerosol containers.
  • the preform or ISBM aerosol container of the invention can have any one of the following optional characteristics:
  • the preform or container is essentially made from a copolyester including at least 1 mole % of isosorbide as comonomer and having an intrinsic viscosity of at least about 0.7 dL/g.
  • the copolyester is Polyethylene Terephthalate containing Isosorbide (PEIT).
  • the copolyester includes at least 3 mole % of isosorbide as comonomer, and more particularly at least 5 mole % of isosorbide as comonomer.
  • the copolyester includes not more than 15 mole % of isosorbide as comonomer, and preferably not more than 8 mole % of isosorbide as comonomer.
  • the intrinsic viscosity of the copolyester is at least 0.8.dl_/g, more particularly at least. 0.9.dL/g.
  • the intrinsic viscosity of the copolyester is not more than 2.dl_/g.
  • the injection stretch blow molded aerosol container has an axial stretch ratio (S a ) of not more than 3, and preferably of not more than 2.55.
  • the injection stretch blow molded aerosol container has a radial stretch ratio (S r ) of not more than 2.5, and preferably of not more than 2.4.
  • the injection stretch blow molded aerosol container has an overall stretch ratio (S) of not more than 9, and preferably of not more than 7.
  • S overall stretch ratio
  • the injection stretch blow molded plastic container has a concave sidewall gripping portion.
  • the injection stretch blow molded plastic container has a volume of not more than 750ml, and preferably of not more than 500ml.
  • the invention also relates to an aerosol dispenser comprising the aforesaid injection stretch blow molded aerosol container and a valve dispensing device suitable for dispensing an aerosol contained in the aerosol container.
  • FIG. 1 is a longitudinal cross-section view of preform suitable to be stretch blow molded in order to form a pressure-resistant aerosol plastic container.
  • FIG. 2 is a longitudinal cross-section view of an aerosol dispenser comprising an ISBM aerosol container that has been obtained by biaxially stretch blow molding the preform of figure 1 , and that is fitted with a valve dispensing device suitable for dispensing an aerosol contained in the aerosol container.
  • the aerosol dispenser 2 comprises a pressure resistant aerosol container 20 which is knowingly hermetically closed by a valve dispensing device 21 .
  • Said valve dispensing device 21 comprises a closure 210 that is covering the top opening 200 of the aerosol container 20, and that is sealingly attached to the neck 201 of the aerosol container 20.
  • Said closure 210 includes a valve member 21 1 having an axially extending valve stem 212 which can be either depressed or tilted to release the aerosol contained within the container 20.
  • the structure and functioning of the valve dispensing device 21 are well known in the art and will not be described in details. One skilled in the art can besides refer to the disclosure of US 2004/0149781 .
  • the pressure resistant plastic aerosol container 20 is an injection stretch blow molded container.
  • Figure 1 shows a plastic preform 1 suitable to be stretch blow molded in order to form a pressure-resistant aerosol plastic container
  • This preform 1 is made of a substantially tubular body of axial length Li, which is closed at its bottom end and has a pouring opening at its upper end. More especially, said preform 1 comprises a neck portion 10 terminated by a pouring opening 100, a so-called gate portion 12 forming a closed bottom end, and a body portion 1 1 that is extending between said gate portion 12 and said neck portion 10.
  • the neck portion 10 comprises a protruding neck support ring 101 of bigger diameter.
  • the body portion 1 1 comprises a main cylindrical portion 1 10 of substantially constant wall thickness WT and an upper transition portion 1 1 1 .
  • the inner face of the main portion 1 10 can be also conical.
  • the gate portion 12 is made of a convex portion having substantially a hemi-spherical shape, and terminated by a small central protruding injection point 20.
  • the size of this injection point 20 corresponds to the size of the output orifice of the hot runner nozzle that is being used for injecting the plastic material in the mould.
  • the shape of the gate portion 12 is not necessarily hemi-spherical, but the gate portion 12 can have any other shape, and in particular can be for example conical.
  • this preform 1 is biaxially stretch blow molded in a mould
  • the neck portion 10 is used for maintaining the preform in the blowing mould, and is thus not stretched.
  • the body portion 1 1 is biaxially stretched (in a longitudinal direction X and in a radial direction Y) in order to form a container body of higher volume.
  • the gate portion 12 is also biaxially stretched in order to form typically the bottom base of the injection stretch blow molded container.
  • a "one stage process” or a "two stages process” can be used.
  • the stretch-blow moulding step of the preform is performed in line immediately after the first injection step (preform injection).
  • the stretch- blow moulding step of the preform is postponed, and a reheating of the preform is performed prior to this stretch-blow molding step.
  • the final shape and size of the container will depend of the blow mold that is being used and of the stretch ratios that are practiced.
  • the preform 1 can thus be stretch blow molded in order to make the pressure-resistant aerosol container 20 of figure 2.
  • the invention is however not limited to the particular shape or dimensions of the aerosol container 20 of figure 2.
  • the base 202 (figure 2) of the aerosol container 20 is not necessarily spherical like the container depicted on figure 2, but can be of any shape. More especially, the base 202 of the aerosol container 20 can also be a base including an inwardly-oriented central dome, also commonly called “champagne " base, or can be a "petaloid " base like for example the base of the container of figure 8D of WO 2007/140407.
  • the sidewall of the container comprises a main central portion 203 which is concave and forms a kind of hyperboloid configuration, which provides a very ergonomic structure that can be easily handled by a user.
  • the sidewall of the container 2 can have any other shape, including straight wall portion, convex wall portions, etc...
  • the polymeric material used for making the preform 1 or container 2 is a copolyester including at least 1 mole % of isosorbide as comonomer and having an intrinsic viscosity of at least 0.7 dL/g, more preferably of at least 0.8 dL/g, and even more preferably of at least 0.9 dL/g.
  • a copolyester including at least 1 mole % of isosorbide as comonomer and having an intrinsic viscosity of at least 0.7 dL/g, more preferably of at least 0.8 dL/g, and even more preferably of at least 0.9 dL/g.
  • the intrinsic viscosity of the Isosorbide containing copolyester has generally to be increased for example by carrying out a Solid State Polymerization (SSP) of the copolyester for a period sufficient to achieve the required minimum IV.
  • SSP Solid State Polymerization
  • This increase of IV enables advantageously to lower the NSR of the isosorbide containing polyester and to at least partially compensate the increase of the NSR caused by the incorporation of isosorbide in the copolyester.
  • the required IV level can however also be obtained directly, i.e. without a SSP post-treatment, by carrying out a suitable polymerization process.
  • the isosorbide containing polyester comprises a copolyester that includes at least 5 mole % of isosorbide as comonomer.
  • the isosorbide containing polyester comprises a copolyester that includes not more than 15 mole % of isosorbide as comonomer, and even more preferably not more than 8 mole % of isosorbide as comonomer.
  • the isosorbide containing copolyester may be formed by any method known in the art.
  • the polyester is formed by solvent or melt polymerization.
  • the isosorbide containing copolyester is Polyethylene
  • PET Terephtalate containing Isosorbide
  • the isosorbide containing copolyester comprises terephthaloyl moieties; optionally, one or more other aromatic diacid moieties; ethylene glycol moieties; isosorbide moieties; and, optionally one or more other diol moieties.
  • terephthaloyl moieties can be derived from terephthalic acid or dimethyl terephthalate.
  • isosorbide containing copolyester can further comprise diethylene glycol moieties
  • Aforesaid one or more other diol moieties can be derived from aliphatic alkylene glycols or branched aliphatic glycols having from 3-12 carbon atoms and having the empirical formula HO-CnH2n-OH, where n is an integer from 3-12; including branched diols such as 2,2-dimethyl-1 ,3- propanediol; cis or trans-1 , 4-cyclohexanedimethanol and mixtures of the cis and trans isomers; triethylene glycol; 2,2-bis [4- (2- hydroxyethoxy) phenyl] propane; 1 ,1 -bis [4- (2- hydroxyethoxy) phenyl] cyclohexane; 9,9- bis [4- (2hydroxyethoxy) phenyl] fluorene; 1 ,4: 1 ,4: 3,6-dianhydromannitol; 1 ,4: 1 ,4: 3,6-dianhydroidito
  • the number of terephthaloyl moieties in the polymer is in the range of about 25% to about 75 mole % (mole % of the total polymer).
  • ethylene glycol monomer units are present in amounts of about 5 mole % to about 49.75 mole %.
  • the polymer may also contain diethylene glycol moieties. Depending on the method of manufacture, the amount of diethylene glycol moieties is for example in the range of about 0.0 mole % to about 25 mole %.
  • the mold blowing step was performed with an axial stretch ratio S a around 2.4mm.
  • This axial stretch ratio (S a ) is knowingly defined in a standard way by formula: wherein : L is the container developed length (figure 2) and I is the preform neutral fibre developed length ( figure 1 ) .
  • the radial stretch ratio (S r ) was around 2.55mm. This radial stretch ratio (S r ) is knowingly defined in a standard way by formula : S
  • the overall stretch ratio (S) of the aerosol containers was around 6.
  • PEIT Polyethylene Terephthalate containing Isosorbide
  • said PEIT was containing 5.8mole% of Isosorbide (5.8 mole %PEIT).
  • This 5.8 mole% PEIT was obtained in a known way by melt polymerization.
  • This 5.8 mole% PEIT issued from the melt polymerization was subjected to a SSP during a period of time sufficient to raise the IV of the Isosorbide containing copolyester up to about 0.95 dL/g.
  • the second batch (Ref B) of ISBM aerosol containers was made from a PET resin of standard grade having an intrinsic viscosity of about 0.86 dL/g.
  • the third batch (Ref;C) of ISBM aerosol containers was made from a PET resin having an intrinsic viscosity of about 0.95 dL/g.
  • Said PET resin was a copolymer PET commercialized by Artenius Tech Polymers under commercial reference "Artenius HOT”.
  • the intrinsic viscosity (IV) of the resin before injection was measured pursuant to following method based on the ISO 1628 standard:
  • the solvent is DCA (dichloroacetic acid).
  • the solution is measured in a dedicated capillary viscometer and the IV is calculated according to the ISO 1628 standard, taking in to account the solvent that is used.
  • the intrinsic viscosity (IV) of the preforms of the three batches was also measured by carrying out the aforesaid method with m-cresol as solvent. The results showed an IV drop due to a degradation of the polymer during the injection process.
  • the IV of the preforms of the first batch (Ref.A) was around 0.8dl_/g.
  • the IV of the preforms of the second batch (Ref.B) was around 0.73dL/g.
  • the IV of the preforms of the third batch (Ref.C) was around 0.78dl_/g.
  • the glass transition temperature (Tg) of the resins was knowingly measured by Differential Scanning Calorimetry (DSC) with an equipment DSC 821 e from Mettler Toledo.
  • the Tg of the 5.8 mole% PEIT ( Ref.A) was around 89.6°C.
  • the Tg of the PET resin of the second batch (Ref.B) was around 79.6C.
  • the Tg of the PET resin of the third batch (Ref.C) was around t 79.5°C.
  • Test pressure needs to be 50% higher than the internal pressure in the container at 50°C.
  • Calculation for the pressure (P) used for the hydraulic test The pressure at 50°C is defined, using the perfect gas low.
  • T° Absolu T° (°K)
  • the test is then performed as follows :
  • the goal of this test is to evaluate the container when it is dropped from a height of 1 .8m to a concrete floor and this at different temperatures. Ensure that the orientation, of the test container at drop is statistically random, but that direct impact on the valve or valve closure is avoided.
  • Aerosol containers must be designed that it shall not break or leak.
  • Aerosol containers needs to be tested at 3 different temperature conditions :
  • the goal of this test is to evaluate the ability of an aerosol container to withstand to a certain internal pressure. Pressure at which the container is bursting needs to be minimum 20% higher than the test pressure.
  • Burst pressure for all the containers needs to be above 14.4 bar.
  • the goal of this test is to indicate the temperature where the deformation of the container is induced. Temperature for this test is 7°C lower than Tg with a max. test temperature of 75°C and min temperature of 65°C. It is allowed that the containers deform, but without breakage or leakage creating a hazardous environment.
  • the goal of this test is to evaluate the aerosol containers resistance to a vertical load before its first deformation.
  • Equipment used for this test is the INSTRON 3366 Top load tester with a load cell of 5000N. The result is the maximum compressive load (in kgf) a container can withstand before it loses 1 % of the compressive load applied. Test is done with a speed of 50mm/min.
  • the objective of the accelerated stress cracking is to simulate stress experienced by containers during pressure filling, shipping and storage.
  • the test is performed as follows :
  • the goal of this test is to measure the Oxygen transmission rate of the aerosol container.
  • Equipment used to determine the permeation is the MOCON Oxtran 2/20 that uses a Coulometric Sensor (Coulox) to determine the 02 concentration.
  • Test method used is derived from the ASTM D 3985 and the ASTM F 1307.
  • the Aerosol container is mounted on a metal fixture and flushed with N2 to purge the air out of the bottle. As the outside of the bottle is in contact with ambient air (20.9% O2), O2 permeates trough the bottle wall and is transported with the N2 flow to the Coulox Sensor.
  • the test is performed as follows :
  • the invention is not limited to an injection stretch blow molded aerosol container made from a copolyester including at least 1 mole % of isosorbide as comonomer and having an intrinsic viscosity of at least about 0.7 dL/g.
  • the invention can be also practiced with a polymer blend comprising said copolyester including at least 1 mole % of isosorbide as comonomer and having an intrinsic viscosity of at least about 0.7 dL/g and another polymer, in particular another polyester.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne une préforme en matière plastique appropriée pour être moulée par soufflage bi-orienté de façon à former un récipient pour aérosol (20) ou un récipient pour aérosol moulé par injection-soufflage avec bi-étirage (20), la préforme ou le récipient étant fabriqué d'une matière polymère qui comprend un copolyester comprenant au moins 1 % en mole d'isosorbide comme co-monomère et ayant une viscosité intrinsèque d'au moins 0,7 dL/g.
PCT/EP2014/066958 2013-08-14 2014-08-07 Récipient en matière plastique pour aérosol fabriqué à partir d'un copolyester contenant un isosorbide et distributeur d'aérosol comprenant ledit récipient en matière plastique pour aérosol WO2015022254A1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
MX2016001991A MX2016001991A (es) 2013-08-14 2014-08-07 Contenedor de plastico de aerosol hecho de un copoliester que contiene isosorbida y dispensador de aerosol que comprende dicho contenedor de plastico de aerosol.
JP2016533893A JP2016529171A (ja) 2013-08-14 2014-08-07 イソソルビド含有コポリエステルから形成されたエアロゾルプラスチック容器及び前記エアロゾルプラスチック容器を含むエアロゾルディスペンサー
BR112016002884A BR112016002884A2 (pt) 2013-08-14 2014-08-07 pré-forma plástica, recipiente de aerossol e distribuidor de aerossol
CA2919889A CA2919889A1 (fr) 2013-08-14 2014-08-07 Recipient en matiere plastique pour aerosol fabrique a partir d'un copolyester contenant un isosorbide et distributeur d'aerosol comprenant ledit recipient en matiere plastique pour aerosol
US14/911,540 US20160185510A1 (en) 2013-08-14 2014-08-07 Aerosol plastic container made from an isosorbide containing copolyester and aerosol dispenser comprising said aerosol plastic container
RU2016108984A RU2016108984A (ru) 2013-08-14 2014-08-07 Пластиковый аэрозольный контейнер, изготовленный из сополиэфира, содержащего изосорбид, и аэрозольный дозатор, содержащий указанный пластиковый аэрозольный контейнер аэрозоля
CN201480050690.XA CN105658539A (zh) 2013-08-14 2014-08-07 由包含异山梨醇的共聚酯制成的气溶胶塑料容器和包括所述气溶胶塑料容器的气溶胶分配器
AU2014307974A AU2014307974A1 (en) 2013-08-14 2014-08-07 Aerosol plastic container made from an isosorbide containing copolyester and aerosol dispenser comprising said aerosol plastic container
ZA2016/00794A ZA201600794B (en) 2013-08-14 2016-02-04 Aerosol plastic container made from an isosorbide containing copolyester and aerosol dispenser comprising said aerosol plastic container

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13180376.9 2013-08-14
EP20130180376 EP2837581A1 (fr) 2013-08-14 2013-08-14 Récipient en plastique d'aérosol fabriqué à partir d'un copolyester contenant de l'isosorbide et distributeur d'aérosol comprenant ledit récipient

Publications (1)

Publication Number Publication Date
WO2015022254A1 true WO2015022254A1 (fr) 2015-02-19

Family

ID=48985624

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2014/066958 WO2015022254A1 (fr) 2013-08-14 2014-08-07 Récipient en matière plastique pour aérosol fabriqué à partir d'un copolyester contenant un isosorbide et distributeur d'aérosol comprenant ledit récipient en matière plastique pour aérosol

Country Status (11)

Country Link
US (1) US20160185510A1 (fr)
EP (1) EP2837581A1 (fr)
JP (1) JP2016529171A (fr)
CN (1) CN105658539A (fr)
AU (1) AU2014307974A1 (fr)
BR (1) BR112016002884A2 (fr)
CA (1) CA2919889A1 (fr)
MX (1) MX2016001991A (fr)
RU (1) RU2016108984A (fr)
WO (1) WO2015022254A1 (fr)
ZA (1) ZA201600794B (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018024987A1 (fr) * 2016-08-02 2018-02-08 Roquette Freres Polyester thermoplastique semi-cristallin pour la fabrication de contenant d'aerosol
WO2018024988A1 (fr) * 2016-08-02 2018-02-08 Roquette Freres Polyester thermoplastique semi-cristallin pour la fabrication de corps creux bi-etires

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3019803B1 (fr) * 2014-04-10 2016-12-23 Fareva Generateur aerosol en matiere plastique
WO2017111370A1 (fr) 2015-12-24 2017-06-29 에스케이케미칼주식회사 Résine de polyester, son procédé de production, et produit moulé en résine formé à partir de celle-ci
US20170341849A1 (en) * 2016-05-27 2017-11-30 S.C. Johnson & Son, Inc. Plastic bottle and base cup for a pressurized dispensing system
FR3054804B1 (fr) * 2016-08-05 2019-07-12 Roquette Freres Utilisation d'un polyester thermoplastique pour la fabrication de pieces injectees
KR102568743B1 (ko) 2017-05-31 2023-08-22 에스케이케미칼 주식회사 폴리에스테르 수지, 이의 제조 방법 및 이로부터 형성된 수지 성형품
US11492444B2 (en) 2017-06-22 2022-11-08 Sk Chemicals Co., Ltd. Polyester container and manufacturing method therefor
US11396579B2 (en) 2017-06-26 2022-07-26 Sk Chemicals Co., Ltd. Polyester film and manufacturing method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999054533A1 (fr) * 1998-04-23 1999-10-28 E.I. Du Pont De Nemours And Company Recipient en polyester et son procede de fabrication
US20050127022A1 (en) * 2003-12-16 2005-06-16 Flashinski Stanley J. Pressurized plastic bottle with reinforced neck and shoulder for dispensing an aerosol
JP2006089629A (ja) * 2004-09-24 2006-04-06 Mitsubishi Chemicals Corp ポリエステル樹脂

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2129745Y (zh) * 1992-04-10 1993-04-14 天津印铁制罐公司 双室气雾容器
CN1659088A (zh) * 2002-06-11 2005-08-24 依普技术有限公司 分配器
US7028866B2 (en) 2003-01-31 2006-04-18 S.C. Johnson & Son, Inc. Pressurized plastic bottle for dispensing an aerosol
JP2006070101A (ja) 2004-08-31 2006-03-16 Mitsubishi Chemicals Corp ポリエステル樹脂および樹脂組成物ならびに延伸ブロー成形用プリフォーム及び中空容器
AR061217A1 (es) 2006-05-31 2008-08-13 Clorox Co Recipiente para aerosol de plastico ergonomico
KR20110028696A (ko) * 2009-09-14 2011-03-22 에스케이케미칼주식회사 아이소소바이드와 1,4-사이클로헥산디메탄올이 공중합된 폴리에스테르 수지 및 그 제조방법
PT2739551T (pt) 2011-08-01 2017-10-19 Graham Packaging Co Recipiente plástico de aerossol e método de fabrico

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999054533A1 (fr) * 1998-04-23 1999-10-28 E.I. Du Pont De Nemours And Company Recipient en polyester et son procede de fabrication
US20050127022A1 (en) * 2003-12-16 2005-06-16 Flashinski Stanley J. Pressurized plastic bottle with reinforced neck and shoulder for dispensing an aerosol
JP2006089629A (ja) * 2004-09-24 2006-04-06 Mitsubishi Chemicals Corp ポリエステル樹脂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 200627, 26 March 2013 Derwent World Patents Index; AN 2006-258070, XP002718169 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018024987A1 (fr) * 2016-08-02 2018-02-08 Roquette Freres Polyester thermoplastique semi-cristallin pour la fabrication de contenant d'aerosol
WO2018024988A1 (fr) * 2016-08-02 2018-02-08 Roquette Freres Polyester thermoplastique semi-cristallin pour la fabrication de corps creux bi-etires
FR3054830A1 (fr) * 2016-08-02 2018-02-09 Roquette Freres Polyester thermoplastique semi-cristallin pour la fabrication de corps creux bi-etires
FR3054831A1 (fr) * 2016-08-02 2018-02-09 Roquette Freres Polyester thermoplastique semi-cristallin pour la fabrication de contenant d'aerosol
US20190169367A1 (en) * 2016-08-02 2019-06-06 Roquette Freres Semi-crystalline thermoplastic polyester for producing an aerosol container

Also Published As

Publication number Publication date
JP2016529171A (ja) 2016-09-23
EP2837581A1 (fr) 2015-02-18
BR112016002884A2 (pt) 2017-08-01
CA2919889A1 (fr) 2015-02-19
MX2016001991A (es) 2016-05-18
ZA201600794B (en) 2017-04-26
US20160185510A1 (en) 2016-06-30
CN105658539A (zh) 2016-06-08
AU2014307974A1 (en) 2016-02-18
RU2016108984A (ru) 2017-09-19

Similar Documents

Publication Publication Date Title
EP2837581A1 (fr) Récipient en plastique d'aérosol fabriqué à partir d'un copolyester contenant de l'isosorbide et distributeur d'aérosol comprenant ledit récipient
US5780130A (en) Container and method of making container from polyethylene naphthalate and copolymers thereof
EP2029456B1 (fr) Distributeur en plastique sous pression
US7572493B2 (en) Low IV pet based copolymer preform with enhanced mechanical properties and cycle time, container made therewith and methods
CN113715193B (zh) 呋喃酸聚合物预成型件、容器和加工
HU225712B1 (en) Pressurized refill container and method of making
KR20050073598A (ko) 기계적 성질 및 신장률이 강화된 ｐｅｔ 공중합체 조성물,그 제품 및 제조 방법
NZ278214A (en) Multilayered container and preform having a polyethylene naphthalate layer
MX2007013958A (es) Recipiente de copolimero de pet moldeado por soplado mediante estiramiento de peso ligero y preforma para crear el mismo.
MX2007013957A (es) Preforma moldeada por inyeccion, recipiente moldeado por soplado mediante estiramiento y metodo para reducir el tiempo de ciclo para crearlos.
EP2168752A2 (fr) Procédé de moulage par étirage-soufflage et récipient
EP1651527B1 (fr) Composition servant a produire un article d'emballage ayant des proprietes desoxygenantes et un faible trouble
CN110225867B (zh) 用于加压分配***的塑料瓶
CN111448145B (zh) 瓶、其制造方法以及fdca和二醇单体在该瓶中的用途
EP2029455B1 (fr) Distributeur sous pression plastique non rond
CN111465558A (zh) 瓶、其制造方法以及fdca和二醇单体在该瓶中的用途
JP2021533222A (ja) ポリエステル製プリフォーム
JPH02229023A (ja) 中間層を内表面側に偏らせて配置した多層延伸成形容器の製造方法
JP3719882B2 (ja) 耐圧性ポリエステル製ボトル
JPH0524815B2 (fr)
JP4430833B2 (ja) ポリエステル組成物製ボトルおよびその製造方法
EP3458246B1 (fr) Procédé de fabrication d'une bouteille en matériau polymère et bouteille
JP4174851B2 (ja) 自立構造型エアゾール容器
CN115485122A (zh) 多层预成型件和容器
JP2021133987A (ja) ポリエステル製容器及びその製造方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 14750194

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2919889

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 16031290

Country of ref document: CO

WWE Wipo information: entry into national phase

Ref document number: 14911540

Country of ref document: US

ENP Entry into the national phase

Ref document number: 2016533893

Country of ref document: JP

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: MX/A/2016/001991

Country of ref document: MX

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2014307974

Country of ref document: AU

Date of ref document: 20140807

Kind code of ref document: A

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: 112016002884

Country of ref document: BR

ENP Entry into the national phase

Ref document number: 2016108984

Country of ref document: RU

Kind code of ref document: A

122 Ep: pct application non-entry in european phase

Ref document number: 14750194

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 112016002884

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20160211