WO2014017608A1 - Airtight container for hydrogen gas - Google Patents

Airtight container for hydrogen gas Download PDF

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Publication number
WO2014017608A1
WO2014017608A1 PCT/JP2013/070233 JP2013070233W WO2014017608A1 WO 2014017608 A1 WO2014017608 A1 WO 2014017608A1 JP 2013070233 W JP2013070233 W JP 2013070233W WO 2014017608 A1 WO2014017608 A1 WO 2014017608A1
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Prior art keywords
hydrogen gas
container
liquid
hydrogen
sealed
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PCT/JP2013/070233
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French (fr)
Japanese (ja)
Inventor
文士 張
直之 矢田
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株式会社光未来
株式会社協和
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Publication of WO2014017608A1 publication Critical patent/WO2014017608A1/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • B65D85/72—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for for edible or potable liquids, semiliquids, or plastic or pasty materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
    • B65D1/04—Multi-cavity bottles

Definitions

  • the present invention relates to a container capable of dissolving hydrogen gas in the contained contents.
  • Active oxygen plays an important role in producing ATP (adenosine triphosphate) in the citrate cycle, and is essential for life support and also plays a role in eliminating foreign substances that have entered the body. I understand. However, on the other hand, surplus active oxygen that has not been used in the reaction in the living body is usually decomposed by an enzyme present in the cell, but the amount that cannot be decomposed damages the cell. As a result, it causes diseases such as cancer and lifestyle-related diseases and aging. For this reason, it is considered good for health to eliminate excess active oxygen.
  • ATP adenosine triphosphate
  • hydrogen gas is used for reducing active oxygen because it has a very low molecular weight and is easily absorbed by the body, and even when hydrogen reacts with active oxygen, water is only generated and is safe. This is because of its high nature.
  • ingestion of hydrogen gas has useful effects such as disease prevention and health promotion, but it is difficult to maintain a high dissolved hydrogen amount as it is after hydrogen gas is dissolved in a liquid.
  • a plastic container such as a PET (polyethylene terephthalate) bottle
  • most of the hydrogen escapes within a few days even in a sealed state. Even if taken, high efficacy cannot be obtained.
  • Patent Document 1 a liquid container having a flexible exterior is encapsulated with a liquid in which hydrogen molecules are dissolved, a pressure member is attached to a part or the whole of the liquid container, and pressure is applied from the outside. A method for maintaining the amount of dissolved hydrogen by maintaining the added state has been proposed.
  • Patent Document 1 focuses on the proportional relationship between gas solubility and pressure (Henry's law), and by applying pressure from the outside to a container containing a hydrogen-dissolved liquid, Is trying to maintain a high amount of dissolved hydrogen.
  • an object of the present invention is to provide a container in which hydrogen gas is dissolved in contents such as liquid stored in the container, and the dissolved degree of hydrogen gas in the contents can be maintained at a high level. .
  • a hydrogen gas sealed container is a container that dissolves hydrogen gas in the contents in the container, and the contents storage unit for storing the contents in the container And a hydrogen gas storage part that is partitioned from the content storage part by a hydrogen permeable material that allows hydrogen gas to permeate to the outside, and that can be hermetically filled with hydrogen gas.
  • the sealed container referred to here includes a container having a predetermined shape as well as a bag-like one, and widely refers to a container that can accommodate a liquid, hydrogen gas, or the like.
  • the hydrogen gas storage portion may be a sealed bag made of a hydrogen permeable film, and may be integrally attached to the container in the container.
  • the container may be made of a hydrogen non-permeable material that does not allow hydrogen gas to permeate.
  • the hydrogen gas in the hydrogen gas storage unit can be dissolved in the stored liquid or the like only by storing the content such as the liquid in the content storage unit of the container.
  • a sealed container 1 is a bottle-shaped container, and can be freely opened and closed to a bottle body 10 that contains a liquid such as a beverage, and the bottle body 10. It is comprised from the cap 11 which covers.
  • the bottle main body 10 is a container having a hollow inside, and an opening 10a for pouring and taking out a liquid such as a beverage is provided at one end.
  • the interior of the bottle body 10 is partitioned into a liquid storage part 131 and a hydrogen gas storage part 132 by a partition 12.
  • the liquid storage part 131 is a space that is formed by the inner wall of the bottle body 10 and the partition 12, and is opened by the opening 10a, and stores a liquid such as a beverage. Liquid can be poured into the liquid storage part 131 through the opening 10a, and conversely, the liquid stored inside can be discharged through the opening 10a.
  • the hydrogen gas storage part 132 is a sealed space formed by the inner wall of the bottle main body 10 and the partition 12, and is filled with hydrogen gas.
  • the bottle body 10 can use a synthetic resin material such as PET (Polyethylene Terephthalate), but preferably prevents hydrogen gas from permeating to the outside. Therefore, a material having a low hydrogen gas permeability and at least a hydrogen gas permeability lower than that of the partition 12 or a material that does not allow hydrogen gas to permeate is used. For example, aluminum or steel is used.
  • the material of the bottle body 10 it is preferable to use a material having a low hydrogen gas permeability as described above, or a material that does not allow hydrogen gas to permeate, and the entire bottle body 10 is made of such a material.
  • a material having a low hydrogen gas permeability as described above, or a material that does not allow hydrogen gas to permeate
  • the entire bottle body 10 is made of such a material.
  • at least a part constituting the hydrogen gas storage part 132 integrally with the partition 12 is made of such a material.
  • hydrogen gas permeates to the outside by laminating a laminated film including an aluminum foil, an aluminum vapor deposition film, an aluminum oxide vapor deposition film, or a silica vapor deposition film on a portion constituting the hydrogen gas storage portion 132 integrally with the partition 12. You may be prevented from doing it.
  • PE Polyethylene
  • aluminum, steel, etc. can be used according to the material of the bottle main body 10.
  • the partition 12 is made of a material that is permeable to hydrogen gas, and at least a material having a hydrogen gas permeability that is at least equal to that of the bottle body 10, for example, silicone rubber, SBR (styrene-butadiene rubber), EPDM (ethylene -Propylene rubber), PE (polyethylene), PET (polyethylene terephthalate), LDPE (low density polyethylene), PP (polypropylene), nylon and the like are used.
  • the partition 12 made of such a material can be configured as a thin plate or a thin film (film).
  • the hydrogen gas in the hydrogen gas storage unit 132 is partitioned. 12 and dissolves in the liquid in the liquid container 131.
  • hydrogen gas permeate transmits into the liquid storage part 131 from the hydrogen gas storage part 132, the dissolved degree of the hydrogen gas in a liquid can be maintained in a high state.
  • hydrogen can be taken into the body at a very high concentration through the beverage.
  • the hydrogen gas storage unit 132 is filled with, for example, a hydrogen gas inlet for a check valve provided in advance in the partition 12 or a part of the bottle body 10 forming the hydrogen gas storage unit 132.
  • the hydrogen gas can be injected from the hydrogen gas inlet.
  • the hydrogen gas storage part 132 can be filled with hydrogen gas by attaching the partition 12 to the inner wall of the bottle body 10 in a hydrogen gas atmosphere.
  • the size or volume of the hydrogen gas storage portion 132 is not particularly limited, and can be set to an arbitrary size. Further, the amount of the hydrogen gas stored in the hydrogen gas storage unit 132 is not particularly limited, and may be compressed and filled to a high concentration.
  • the sealed bag 2 is a sealed bag-like body having a hollow inside.
  • the airtight bag 2 is provided with a partition 21 inside the main body 20.
  • One of the two spaces partitioned by the partition 21 configures a liquid storage unit 221 for storing a liquid, and the other configures a hydrogen gas storage unit 222 for hermetically filling hydrogen gas.
  • the main body 20 is a film having flexibility, has a low hydrogen gas permeability, and is at least more permeable to hydrogen gas than the partition 21.
  • a low material or a material that does not transmit hydrogen gas is used.
  • a laminated film including an aluminum foil, an aluminum vapor deposition film, an aluminum oxide vapor deposition film, or a silica vapor deposition film is used.
  • the partition 21 is made of a material that is permeable to hydrogen gas, and a material that is at least as permeable as hydrogen gas as the main body 20.
  • silicone rubber SBR (styrene-butadiene rubber), EPDM (ethylene -Propylene rubber), PE (polyethylene), PET (polyethylene terephthalate), LDPE (low density polyethylene), PP (polypropylene), nylon and other films are used.
  • the sealed bag 2 having the above configuration is also filled with hydrogen gas in the hydrogen gas storage unit 222, and when a liquid such as a beverage is stored in the liquid storage unit 221, the hydrogen gas storage unit 222.
  • the hydrogen gas inside passes through the partition 21 and dissolves in the liquid in the liquid container 221.
  • hydrogen gas continues permeate
  • the airtight bag 2 similarly to the airtight container 1, filling of the hydrogen gas into the hydrogen gas accommodating portion 222 is provided in advance in, for example, the partition 21 or a part of the main body 20 that forms the hydrogen gas accommodating portion 222. Hydrogen gas is filled from the hydrogen gas inlet of the check valve, or the partition 21 is attached to the inside of the main body 20 in a hydrogen gas atmosphere, so that the hydrogen gas storage unit 222 is filled with hydrogen gas. You can also do it.
  • the sealed bag 3 is a sealed bag-like body having a hollow inside.
  • the hermetic bag 3 is integrally attached to the main body 30 inside the main body 30 with a bag-like hydrogen gas containing bag 31 smaller than the main body 30 and having a hollow inside.
  • the inside of the main body 30 constitutes a liquid containing part 321 in which a liquid such as a beverage is contained, and the hydrogen gas containing bag 31 constitutes a hydrogen gas containing part 322 in which hydrogen gas is hermetically filled.
  • the main body 30 is a flexible film-like material, has a low hydrogen gas permeability, and at least contains hydrogen gas more than the hydrogen gas containing bag 31.
  • a material with low permeability or a material that does not allow hydrogen gas to permeate is used.
  • a laminated film including an aluminum foil, an aluminum vapor deposition film, an aluminum oxide vapor deposition film, or a silica vapor deposition film is used.
  • the hydrogen gas containing bag 31 is made of a material that is permeable to hydrogen gas, and a material that has at least a hydrogen gas permeability equal to or higher than that of the main body 30.
  • silicone rubber SBR (styrene-butadiene rubber), EPDM (ethylene-propylene rubber), PE (polyethylene), PET (polyethylene terephthalate), LDPE (low density polyethylene), PP (polypropylene), nylon, and other films are used.
  • the sealed bag 3 having the above configuration is filled with hydrogen gas in the hydrogen gas storage unit 322, and when a liquid such as a beverage is stored in the liquid storage unit 321, the hydrogen gas storage unit 222.
  • the hydrogen gas inside passes through the hydrogen gas storage bag 31 and dissolves in the liquid in the liquid storage portion 321.
  • hydrogen gas continues permeate
  • the sealing bag 3 filled with hydrogen gas in the hydrogen gas containing part 322 is filled with hydrogen gas in the hydrogen gas containing bag 31 in advance, and the hydrogen gas containing bag 31 filled with the hydrogen gas is used.
  • the main body 30 is manufactured by being integrally attached to the main body 30 by heat welding, an adhesive, or the like.
  • the bottle main body 10 or the main body 20 constituting the hydrogen gas storage portions 132 and 222 may be provided with a hydrogen gas inlet for a check valve so that hydrogen gas can be filled from the outside. Thereby, when hydrogen gas runs out, it can be refilled.
  • the hydrogen gas sealed container 1 and the sealed bags 2 and 3 described above are not only liquids such as beverages, but also foods such as retort foods, confections such as potato chips, seasonings such as soy sauce, infusions, eye drops, etc. Can be used as a bag or a container for enclosing them in beauty products such as pharmaceuticals and lotions.
  • beauty products such as pharmaceuticals and lotions.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Packages (AREA)
  • Package Specialized In Special Use (AREA)
  • Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

[Problem] The purpose of the present invention is to provide a container for dissolving hydrogen gas in contents such as a liquid held in the container and that is capable of maintaining hydrogen gas in the contents in a high degree of dissolution. [Solution] Provided is a container for dissolving hydrogen gas in contents in a container, wherein an airtight container (1) for hydrogen gas has: a liquid-accommodating part (131) for accommodating contents in the container; and a hydrogen gas-accommodating part (132) capable of having hydrogen gas filled therein in an airtight manner, the hydrogen gas-accommodating part (132) being partitioned from the liquid-accommodating part (131) by a partition (12) composed of a hydrogen-permeable material through which hydrogen gas is allowed to permeate to the exterior.

Description

水素ガスの密閉容器Hydrogen gas sealed container
　本発明は、収容した内容物中に水素ガスを溶解させられる容器に関する。 The present invention relates to a container capable of dissolving hydrogen gas in the contained contents.
　近年、水やお茶といった飲料に水素ガスを充填した清涼飲料水などが販売されている。これは、液体に充填させた水素ガスを摂取することにより、人間の体内に存在する活性酸素を還元させることを目的としている。 In recent years, soft drinks such as water and tea filled with hydrogen gas have been sold. This is intended to reduce active oxygen present in the human body by ingesting hydrogen gas filled in a liquid.
　活性酸素は、クエン酸サイクルでＡＴＰ（アデノシン三リン酸）を作り出すときに重要な役割を果たすなど、生命維持に必須であるとともに、体内へ侵入してきた異物を排除する役割も担っていることが判ってきている。しかしながらその一方において、生体内の反応で用いられなかった余剰の活性酸素は通常、細胞内に存在する酵素によって分解されるが、分解しきれなかった分は細胞を損傷させてしまう。その結果、癌や生活習慣病などの疾病、及び老化などを招来する原因となっている。そのため、余分な活性酸素は排除することが健康のためによいと考えられている。 Active oxygen plays an important role in producing ATP (adenosine triphosphate) in the citrate cycle, and is essential for life support and also plays a role in eliminating foreign substances that have entered the body. I understand. However, on the other hand, surplus active oxygen that has not been used in the reaction in the living body is usually decomposed by an enzyme present in the cell, but the amount that cannot be decomposed damages the cell. As a result, it causes diseases such as cancer and lifestyle-related diseases and aging. For this reason, it is considered good for health to eliminate excess active oxygen.
　また、活性酸素の還元に水素ガスが用いられているのは、水素の分子量が極めて小さく体内に吸収しやすいこと、及び、水素と活性酸素が反応しても水は発生するに過ぎず、安全性が高いこと等が理由である。 In addition, hydrogen gas is used for reducing active oxygen because it has a very low molecular weight and is easily absorbed by the body, and even when hydrogen reacts with active oxygen, water is only generated and is safe. This is because of its high nature.
　このように、特段の害もなく、病気予防や健康増進につながると考えられる水素水の病理学的な有効性については、非特許文献１～１０など多くの学術誌等で報告されており、枚挙にいとまがない。 In this way, the pathological effectiveness of hydrogen water, which is thought to lead to disease prevention and health promotion without any particular harm, has been reported in many academic journals such as Non-Patent Documents 1 to 10, There's no point in enumerating.
　上述のとおり、水素ガスの摂取は、病気予防や健康増進といった有用な効果を奏する反面、水素ガスを液体中に溶解させた後、そのまま高い溶存水素量を維持することは難しい。例えば、ＰＥＴ（ポリエチレンテレフタラート）ボトル等のプラスチック容器内に、水素ガスを充填した水を保存した場合には、密封した状態であっても数日間で大部分の水素が抜けてしまい、これを摂取しても高い効能を得えることができない。 As described above, ingestion of hydrogen gas has useful effects such as disease prevention and health promotion, but it is difficult to maintain a high dissolved hydrogen amount as it is after hydrogen gas is dissolved in a liquid. For example, when water filled with hydrogen gas is stored in a plastic container such as a PET (polyethylene terephthalate) bottle, most of the hydrogen escapes within a few days even in a sealed state. Even if taken, high efficacy cannot be obtained.
　この点、特許文献１では、可撓性の外装を有する液体容器に水素分子を溶解させた液体を内包させ、前記液体容器の一部又は全体に対して加圧部材を取り付け、外部から圧力を加えた状態を保つことにより、溶存水素量を維持する方法が提案されている。 In this regard, in Patent Document 1, a liquid container having a flexible exterior is encapsulated with a liquid in which hydrogen molecules are dissolved, a pressure member is attached to a part or the whole of the liquid container, and pressure is applied from the outside. A method for maintaining the amount of dissolved hydrogen by maintaining the added state has been proposed.
特開２０１１－１３６７２７号公報JP 2011-136727 A
　上記特許文献１記載の技術は、気体の溶解度と圧力の比例関係（ヘンリーの法則）に着目して、水素を溶解させた液体を入れた容器に外部から圧力を加えておくことで、液体中の溶存水素量を高い状態に維持しようとしている。 The technique described in Patent Document 1 focuses on the proportional relationship between gas solubility and pressure (Henry's law), and by applying pressure from the outside to a container containing a hydrogen-dissolved liquid, Is trying to maintain a high amount of dissolved hydrogen.
　しかしながら、この方法を採用する場合、容器に対して圧力を加えておくための機構が必要になる。また、容器の材料は、この圧力に耐え得るものでなければならないし、外部からの圧力を内部圧力に転化させることのできる可撓性材料である必要がある。さらには、液体を入れておく容器自体について、その密閉性が高い、あるいは気体の透過性が低くないと、外部圧力によって逆に、液体中の水素ガスを外部に漏出又は透過させてしまうおそれがある。 However, when this method is adopted, a mechanism for applying pressure to the container is required. Also, the material of the container must be able to withstand this pressure, and it must be a flexible material that can convert external pressure into internal pressure. Furthermore, if the container itself for storing the liquid is not highly sealed or has low gas permeability, the hydrogen pressure in the liquid may be leaked or permeated to the outside due to the external pressure. is there.
　そこで、本発明は、容器内に収容した液体等の内容物中に水素ガスを溶解させると共に、当該内容物中の水素ガスの溶存度を高い状態に維持できる容器を提供することを目的とする。 Accordingly, an object of the present invention is to provide a container in which hydrogen gas is dissolved in contents such as liquid stored in the container, and the dissolved degree of hydrogen gas in the contents can be maintained at a high level. .
　上記目的を達成するため、本発明に係る水素ガスの密閉容器は、容器内の内容物中に、水素ガスを溶解させる容器であって、容器内に、上記内容物を収容する内容物収容部と、水素ガスを外部に透過させられる水素透過性材料によって上記内容物収容部と仕切られ、内部に水素ガスを密閉充填可能な水素ガス収容部と、を有することを特徴とする。
　なお、ここでいう密閉容器には、所定の形状をなした容器のほか、袋状のものも含み、広く、液体や水素ガスなどを収容可能なものをいう。 In order to achieve the above object, a hydrogen gas sealed container according to the present invention is a container that dissolves hydrogen gas in the contents in the container, and the contents storage unit for storing the contents in the container And a hydrogen gas storage part that is partitioned from the content storage part by a hydrogen permeable material that allows hydrogen gas to permeate to the outside, and that can be hermetically filled with hydrogen gas.
In addition, the sealed container referred to here includes a container having a predetermined shape as well as a bag-like one, and widely refers to a container that can accommodate a liquid, hydrogen gas, or the like.
　また、上記水素ガス収容部は、水素透過性フィルムからなる密閉袋であって、容器内において、容器に一体的に取り付けられているものとしてもよい。 Further, the hydrogen gas storage portion may be a sealed bag made of a hydrogen permeable film, and may be integrally attached to the container in the container.
　また、上記容器は、水素ガスを透過させない水素非透過性材料からなるものとしてもよい。 The container may be made of a hydrogen non-permeable material that does not allow hydrogen gas to permeate.
　本発明によれば、容器の内容物収容部に液体等の内容物を収容しておくだけで、当該収容された液体等の中に、水素ガス収容部の水素ガスを溶解させることができる。 According to the present invention, the hydrogen gas in the hydrogen gas storage unit can be dissolved in the stored liquid or the like only by storing the content such as the liquid in the content storage unit of the container.
本発明の実施形態に係る水素ガスの密閉容器を示す断面図である。It is sectional drawing which shows the airtight container of the hydrogen gas which concerns on embodiment of this invention. 本発明の第二の実施形態に係る水素ガスの密閉袋を示す断面図である。It is sectional drawing which shows the airtight bag of hydrogen gas which concerns on 2nd embodiment of this invention. 本発明の第三の実施形態に係る水素ガスの密閉袋を示す断面図である。It is sectional drawing which shows the airtight bag of hydrogen gas which concerns on 3rd embodiment of this invention.
　次に、本発明の実施形態に係る水素ガスの密閉容器について、図を参照して説明する。
　図１に示されるように、本発明の第一の実施形態に係る密閉容器１は、ボトル状の容器であって、飲料等の液体を収容するボトル本体１０と、ボトル本体１０に開閉自在に蓋をするキャップ１１とから構成される。 Next, a hydrogen gas sealed container according to an embodiment of the present invention will be described with reference to the drawings.
As shown in FIG. 1, a sealed container 1 according to a first embodiment of the present invention is a bottle-shaped container, and can be freely opened and closed to a bottle body 10 that contains a liquid such as a beverage, and the bottle body 10. It is comprised from the cap 11 which covers.
　ボトル本体１０は、内部が中空の容器であって、一端部に、飲料等の液体を注ぎ入れたり出したりするための開口部１０ａが設けられている。
　このボトル本体１０の内部は、間仕切り１２によって、液体収容部１３１と、水素ガス収容部１３２とに仕切られている。 The bottle main body 10 is a container having a hollow inside, and an opening 10a for pouring and taking out a liquid such as a beverage is provided at one end.
The interior of the bottle body 10 is partitioned into a liquid storage part 131 and a hydrogen gas storage part 132 by a partition 12.
　液体収容部１３１は、ボトル本体１０の内壁と間仕切り１２によって形成されると共に、開口部１０ａによって開口している空間であって、飲料等の液体が収容される。この液体収容部１３１には、開口部１０ａを通じて、液体を注ぎ入れることができ、また逆に、開口部１０ａを通じて、内部に収容されていた液体を外に出すことができる。 The liquid storage part 131 is a space that is formed by the inner wall of the bottle body 10 and the partition 12, and is opened by the opening 10a, and stores a liquid such as a beverage. Liquid can be poured into the liquid storage part 131 through the opening 10a, and conversely, the liquid stored inside can be discharged through the opening 10a.
　水素ガス収容部１３２は、ボトル本体１０の内壁と間仕切り１２によって形成された密閉空間であって、水素ガスが充填される。 The hydrogen gas storage part 132 is a sealed space formed by the inner wall of the bottle main body 10 and the partition 12, and is filled with hydrogen gas.
　ここで、密閉容器１を構成する各部材の材質について、ボトル本体１０はＰＥＴ（Polyethylene Terephthalate）などの合成樹脂材料を用いることができるが、好適には、水素ガスが外部に透過するのを防ぐべく、水素ガスの透過性が低く、少なくとも間仕切り１２よりも水素ガスの透過性の低い材料、あるいは水素ガスを透過させない材料が用いられる。このようなものとしては例えば、アルミやスチールなどが用いられる。 Here, as for the material of each member constituting the sealed container 1, the bottle body 10 can use a synthetic resin material such as PET (Polyethylene Terephthalate), but preferably prevents hydrogen gas from permeating to the outside. Therefore, a material having a low hydrogen gas permeability and at least a hydrogen gas permeability lower than that of the partition 12 or a material that does not allow hydrogen gas to permeate is used. For example, aluminum or steel is used.
　なお、ボトル本体１０の材料には、上記のように水素ガスの透過性が低い、又は水素ガスが透過しない材料を用いることが好適であり、ボトル本体１０全体をこのような材料で構成してもよいが、少なくとも、間仕切り１２と一体的に水素ガス収容部１３２を構成する部分について、このような材料で構成されているとよい。また、間仕切り１２と一体的に水素ガス収容部１３２を構成する部分について、アルミ箔、アルミニウム蒸着膜、酸化アルミニウム蒸着膜又はシリカ蒸着膜を含む積層フィルムを積層させることにより、外部へ水素ガスが透過するのを防いでもよい。
　また、キャップ１１については特に限定されないが、ボトル本体１０の材料に応じて、ＰＥ（Polyethylene）、アルミやスチールなどを用いることができる。 As the material of the bottle body 10, it is preferable to use a material having a low hydrogen gas permeability as described above, or a material that does not allow hydrogen gas to permeate, and the entire bottle body 10 is made of such a material. However, it is preferable that at least a part constituting the hydrogen gas storage part 132 integrally with the partition 12 is made of such a material. Further, hydrogen gas permeates to the outside by laminating a laminated film including an aluminum foil, an aluminum vapor deposition film, an aluminum oxide vapor deposition film, or a silica vapor deposition film on a portion constituting the hydrogen gas storage portion 132 integrally with the partition 12. You may be prevented from doing it.
Moreover, although it does not specifically limit about the cap 11, PE (Polyethylene), aluminum, steel, etc. can be used according to the material of the bottle main body 10. FIG.
　間仕切り１２には水素ガスが透過可能な材料、少なくともボトル本体１０と同等以上の水素ガスの透過性を有する材料が用いられており、例えば、シリコーンゴム、ＳＢＲ（スチレン-ブタジエンゴム）、ＥＰＤＭ（エチレン-プロピレンゴム）、ＰＥ（ポリエチレン）、ＰＥＴ（ポリエチレンテレフタラート）、ＬＤＰＥ（低密度ポリエチレン）、ＰＰ（ポリプロピレン）、ナイロン等が用いられる。
　このような材料からなる間仕切り１２は、薄板状のものや、薄膜状のもの（フィルム）として構成することができる。 The partition 12 is made of a material that is permeable to hydrogen gas, and at least a material having a hydrogen gas permeability that is at least equal to that of the bottle body 10, for example, silicone rubber, SBR (styrene-butadiene rubber), EPDM (ethylene -Propylene rubber), PE (polyethylene), PET (polyethylene terephthalate), LDPE (low density polyethylene), PP (polypropylene), nylon and the like are used.
The partition 12 made of such a material can be configured as a thin plate or a thin film (film).
　以上の構成からなる密閉容器１では、水素ガス収容部１３２に水素ガスが充填されると共に、液体収容部１３１に飲料等の液体が収容されると、水素ガス収容部１３２内の水素ガスが間仕切り１２を透過して液体収容部１３１内の液体中に溶解する。
　このように、水素ガス収容部１３２から液体収容部１３１内へ水素ガスが透過し続けるため、液体中の水素ガスの溶存度を高い状態に維持することができる。特に、液体たる飲料を飲む際、密閉容器１を振れば、飲料を介して、非常に高い濃度で水素を体内に取り込むことができる。 In the sealed container 1 having the above configuration, when the hydrogen gas storage unit 132 is filled with hydrogen gas and a liquid such as a beverage is stored in the liquid storage unit 131, the hydrogen gas in the hydrogen gas storage unit 132 is partitioned. 12 and dissolves in the liquid in the liquid container 131.
Thus, since hydrogen gas permeate | transmits into the liquid storage part 131 from the hydrogen gas storage part 132, the dissolved degree of the hydrogen gas in a liquid can be maintained in a high state. In particular, when drinking a beverage that is a liquid, if the sealed container 1 is shaken, hydrogen can be taken into the body at a very high concentration through the beverage.
　なお、水素ガス収容部１３２中への水素ガスの充填は例えば、間仕切り１２、あるいは水素ガス収容部１３２を形成するボトル本体１０の一部に、逆止弁の水素ガス注入口を予め設けておき、当該水素ガス注入口から水素ガスを注入するものとすることができる。また、他の例では、水素ガス雰囲気中で、ボトル本体１０の内壁に間仕切り１２を取り付けることで、水素ガス収容部１３２内に水素ガスが充填されるようにすることもできる。 The hydrogen gas storage unit 132 is filled with, for example, a hydrogen gas inlet for a check valve provided in advance in the partition 12 or a part of the bottle body 10 forming the hydrogen gas storage unit 132. The hydrogen gas can be injected from the hydrogen gas inlet. In another example, the hydrogen gas storage part 132 can be filled with hydrogen gas by attaching the partition 12 to the inner wall of the bottle body 10 in a hydrogen gas atmosphere.
　また、水素ガス収容部１３２の大きさ又は体積は特に限定されるものではなく、任意の大きさとすることができる。また、水素ガス収容部１３２に収容する水素ガスの量についても特に限定されるものではなく、高濃度に圧縮して充填してもよい。 Further, the size or volume of the hydrogen gas storage portion 132 is not particularly limited, and can be set to an arbitrary size. Further, the amount of the hydrogen gas stored in the hydrogen gas storage unit 132 is not particularly limited, and may be compressed and filled to a high concentration.
　次に、本発明の第二の実施形態に係る水素ガスの密閉袋について、図を参照して説明する。
　図２に示されるように、本実施形態に係る密閉袋２は、内部が中空の密閉された袋状体である。
　この密閉袋２は、本体２０の内部に、間仕切り２１が設けられている。間仕切り２１によって仕切られた二つの空間は、一方が液体を収容するための液体収容部２２１を構成し、他方が水素ガスを密封充填するための水素ガス収容部２２２を構成する。 Next, a hydrogen gas sealing bag according to a second embodiment of the present invention will be described with reference to the drawings.
As shown in FIG. 2, the sealed bag 2 according to the present embodiment is a sealed bag-like body having a hollow inside.
The airtight bag 2 is provided with a partition 21 inside the main body 20. One of the two spaces partitioned by the partition 21 configures a liquid storage unit 221 for storing a liquid, and the other configures a hydrogen gas storage unit 222 for hermetically filling hydrogen gas.
　ここで、密閉袋２を構成する各部材の材料について、本体２０には可撓性を有するフィルム状のものであり、水素ガスの透過性が低く、少なくとも間仕切り２１よりも水素ガスの透過性の低い材料、あるいは水素ガスを透過させない材料が用いられる。このようなものとしては例えば、アルミ箔、アルミニウム蒸着膜、酸化アルミニウム蒸着膜又はシリカ蒸着膜を含む積層フィルムなどが用いられる。 Here, regarding the material of each member constituting the airtight bag 2, the main body 20 is a film having flexibility, has a low hydrogen gas permeability, and is at least more permeable to hydrogen gas than the partition 21. A low material or a material that does not transmit hydrogen gas is used. For example, a laminated film including an aluminum foil, an aluminum vapor deposition film, an aluminum oxide vapor deposition film, or a silica vapor deposition film is used.
　間仕切り２１には、水素ガスが透過可能な材料、少なくとも本体２０と同等以上の水素ガスの透過性を有する材料が用いられており、例えば、シリコーンゴム、ＳＢＲ（スチレン-ブタジエンゴム）、ＥＰＤＭ（エチレン-プロピレンゴム）、ＰＥ（ポリエチレン）、ＰＥＴ（ポリエチレンテレフタラート）、ＬＤＰＥ（低密度ポリエチレン）、ＰＰ（ポリプロピレン）、ナイロン等のフィルムが用いられる。 The partition 21 is made of a material that is permeable to hydrogen gas, and a material that is at least as permeable as hydrogen gas as the main body 20. For example, silicone rubber, SBR (styrene-butadiene rubber), EPDM (ethylene -Propylene rubber), PE (polyethylene), PET (polyethylene terephthalate), LDPE (low density polyethylene), PP (polypropylene), nylon and other films are used.
　以上の構成からなる密閉袋２も、密閉容器１と同様、水素ガス収容部２２２に水素ガスが充填されると共に、液体収容部２２１に飲料等の液体が収容されると、水素ガス収容部２２２内の水素ガスが間仕切り２１を透過して液体収容部２２１内の液体中に溶解する。
　このように、水素ガス収容部２２２から液体収容部２２１内へ水素ガスが透過し続けるため、液体中の水素ガスの溶存度を高い状態に維持することができる。 Similarly to the sealed container 1, the sealed bag 2 having the above configuration is also filled with hydrogen gas in the hydrogen gas storage unit 222, and when a liquid such as a beverage is stored in the liquid storage unit 221, the hydrogen gas storage unit 222. The hydrogen gas inside passes through the partition 21 and dissolves in the liquid in the liquid container 221.
Thus, since hydrogen gas continues permeate | transmitting from the hydrogen gas accommodating part 222 in the liquid accommodating part 221, the dissolved degree of hydrogen gas in a liquid can be maintained in a high state.
　なお、密閉袋２についても、密閉容器１と同様、水素ガス収容部２２２中への水素ガスの充填は例えば、間仕切り２１、あるいは水素ガス収容部２２２を形成する本体２０の一部に予め設けた逆止弁の水素ガス注入口から、水素ガスを注入するものとしたり、水素ガス雰囲気中で、本体２０の内側に間仕切り２１を取り付けることで、水素ガス収容部２２２内に水素ガスが充填されるようにしたりすることもできる。 As for the airtight bag 2, similarly to the airtight container 1, filling of the hydrogen gas into the hydrogen gas accommodating portion 222 is provided in advance in, for example, the partition 21 or a part of the main body 20 that forms the hydrogen gas accommodating portion 222. Hydrogen gas is filled from the hydrogen gas inlet of the check valve, or the partition 21 is attached to the inside of the main body 20 in a hydrogen gas atmosphere, so that the hydrogen gas storage unit 222 is filled with hydrogen gas. You can also do it.
　次に、本発明の第三の実施形態に係る水素ガスの密閉袋について、図を参照して説明する。
　図３に示されるように、本実施形態に係る密閉袋３は、内部が中空の密閉された袋状体である。
　この密閉袋３は、本体３０の内側に、本体３０よりも小さく、内部が中空の袋状の水素ガス収容袋３１が、本体３０に一体的に取り付けられている。
　本体３０の内部は、飲料等の液体が収容される液体収容部３２１を構成し、水素ガス収容袋３１内は、水素ガスが密封充填される水素ガス収容部３２２を構成する。 Next, a hydrogen gas sealing bag according to a third embodiment of the present invention will be described with reference to the drawings.
As shown in FIG. 3, the sealed bag 3 according to the present embodiment is a sealed bag-like body having a hollow inside.
The hermetic bag 3 is integrally attached to the main body 30 inside the main body 30 with a bag-like hydrogen gas containing bag 31 smaller than the main body 30 and having a hollow inside.
The inside of the main body 30 constitutes a liquid containing part 321 in which a liquid such as a beverage is contained, and the hydrogen gas containing bag 31 constitutes a hydrogen gas containing part 322 in which hydrogen gas is hermetically filled.
　ここで、密閉袋３を構成する各部材の材料について、本体３０には可撓性を有するフィルム状のものであり、水素ガスの透過性が低く、少なくとも水素ガス収容袋３１よりも水素ガスの透過性の低い材料、あるいは水素ガスを透過させない材料が用いられる。このようなものとしては例えば、アルミ箔、アルミニウム蒸着膜、酸化アルミニウム蒸着膜又はシリカ蒸着膜を含む積層フィルムなどが用いられる。 Here, regarding the material of each member constituting the airtight bag 3, the main body 30 is a flexible film-like material, has a low hydrogen gas permeability, and at least contains hydrogen gas more than the hydrogen gas containing bag 31. A material with low permeability or a material that does not allow hydrogen gas to permeate is used. For example, a laminated film including an aluminum foil, an aluminum vapor deposition film, an aluminum oxide vapor deposition film, or a silica vapor deposition film is used.
　水素ガス収容袋３１には、水素ガスが透過可能な材料、少なくとも本体３０と同等以上の水素ガスの透過性を有する材料が用いられており、例えば、シリコーンゴム、ＳＢＲ（スチレン-ブタジエンゴム）、ＥＰＤＭ（エチレン-プロピレンゴム）、ＰＥ（ポリエチレン）、ＰＥＴ（ポリエチレンテレフタラート）、ＬＤＰＥ（低密度ポリエチレン）、ＰＰ（ポリプロピレン）、ナイロン等のフィルムが用いられる。 The hydrogen gas containing bag 31 is made of a material that is permeable to hydrogen gas, and a material that has at least a hydrogen gas permeability equal to or higher than that of the main body 30. For example, silicone rubber, SBR (styrene-butadiene rubber), EPDM (ethylene-propylene rubber), PE (polyethylene), PET (polyethylene terephthalate), LDPE (low density polyethylene), PP (polypropylene), nylon, and other films are used.
　以上の構成からなる密閉袋３も、密閉容器１と同様、水素ガス収容部３２２に水素ガスが充填されると共に、液体収容部３２１に飲料等の液体が収容されると、水素ガス収容部２２２内の水素ガスが水素ガス収容袋３１を透過して液体収容部３２１内の液体中に溶解する。
　このように、水素ガス収容部３２２から液体収容部３２１内へ水素ガスが透過し続けるため、液体中の水素ガスの溶存度を高い状態に維持することができる。 Similarly to the sealed container 1, the sealed bag 3 having the above configuration is filled with hydrogen gas in the hydrogen gas storage unit 322, and when a liquid such as a beverage is stored in the liquid storage unit 321, the hydrogen gas storage unit 222. The hydrogen gas inside passes through the hydrogen gas storage bag 31 and dissolves in the liquid in the liquid storage portion 321.
Thus, since hydrogen gas continues permeate | transmitting from the hydrogen gas accommodating part 322 in the liquid accommodating part 321, the dissolved degree of hydrogen gas in a liquid can be maintained in a high state.
　なお、水素ガス収容部３２２中に水素ガスが充填された密閉袋３は例えば、予め水素ガス収容袋３１に水素ガスを充填しておき、当該水素ガスが充填された水素ガス収容袋３１を、本体３０の内部に熱溶着や接着剤等によって、本体３０に一体的に取り付けることによって作製される。 In addition, the sealing bag 3 filled with hydrogen gas in the hydrogen gas containing part 322 is filled with hydrogen gas in the hydrogen gas containing bag 31 in advance, and the hydrogen gas containing bag 31 filled with the hydrogen gas is used. The main body 30 is manufactured by being integrally attached to the main body 30 by heat welding, an adhesive, or the like.
　また、以上の実施形態において、水素ガス収容部１３２、２２２を構成するボトル本体１０あるいは本体２０に、逆止弁の水素ガス注入口を設け、外部から水素ガスを充填可能としてもよい。これにより、水素ガスがなくなった際に、再充填させることができる。 In the above embodiment, the bottle main body 10 or the main body 20 constituting the hydrogen gas storage portions 132 and 222 may be provided with a hydrogen gas inlet for a check valve so that hydrogen gas can be filled from the outside. Thereby, when hydrogen gas runs out, it can be refilled.
　以上のとおり説明した水素ガスの密閉容器１、密閉袋２、３は、飲料等の液体のみならず、レトルト食品等の食品、ポテトチップス等の菓子、醤油等の調味料、点滴液や目薬などの医薬品、化粧水などの美容用品などにおいて、これらを封入する袋や容器として用いることができる。このような場面において本発明を応用することで、食品等の鮮度を保ったり、医薬品や美容用品の変質を防いだりすることができるほか、医薬品や美容用品等の効用も高まる。 The hydrogen gas sealed container 1 and the sealed bags 2 and 3 described above are not only liquids such as beverages, but also foods such as retort foods, confections such as potato chips, seasonings such as soy sauce, infusions, eye drops, etc. Can be used as a bag or a container for enclosing them in beauty products such as pharmaceuticals and lotions. By applying the present invention in such a situation, the freshness of foods and the like can be maintained, and the quality of medicines and beauty products can be prevented, and the utility of medicines and beauty products can be enhanced.
　１　　　密閉容器
　１０　　ボトル本体
　１０ａ　開口部
　１１　　キャップ
　１２　　間仕切り
　１３１　液体収容部
　１３２　水素ガス収容部
　２　　　密閉袋
　２０　　本体
　２１　　間仕切り
　２２１　液体収容部
　２２２　水素ガス収容部
　３　　　密閉袋
　３０　　本体
　３１　　水素ガス収容袋
　３２１　液体収容部
　３２２　水素ガス収容部 DESCRIPTION OF SYMBOLS 1 Airtight container 10 Bottle main body 10a Opening part 11 Cap 12 Partition 131 Liquid storage part 132 Hydrogen gas storage part 2 Sealed bag 20 Main body 21 Partition 221 Liquid storage part 222 Hydrogen gas storage part 3 Sealed bag 30 Main body 31 Hydrogen gas storage bag 321 Liquid Housing unit 322 Hydrogen gas housing unit

Claims (3)

  1. 　容器内の内容物中に、水素ガスを溶解させる容器であって、
    　容器内に、
    　上記内容物を収容する内容物収容部と、
    　水素ガスを外部に透過させられる水素透過性材料によって上記内容物収容部と仕切られ、内部に水素ガスを密閉充填可能な水素ガス収容部と、を有する、
    　ことを特徴とする水素ガスの密閉容器。     A container for dissolving hydrogen gas in the contents of the container,
    In the container,
    A content storage unit for storing the content;
    A hydrogen gas storage portion that is partitioned from the content storage portion by a hydrogen permeable material that allows hydrogen gas to permeate outside, and that can be hermetically filled with hydrogen gas.
    A sealed hydrogen gas container.
  2. 　上記水素ガス収容部は、水素透過性フィルムからなる密閉袋であって、容器内において、容器に一体的に取り付けられている、
    　請求項１記載の水素ガスの密閉容器。     The hydrogen gas storage part is a sealed bag made of a hydrogen permeable film, and is integrally attached to the container in the container.
    The hydrogen gas sealed container according to claim 1.
  3. 　上記容器は、水素ガスを透過させない水素非透過性材料からなる、
    　請求項１又は２記載の水素ガスの密閉容器。     The container is made of a hydrogen non-permeable material that does not allow hydrogen gas to permeate.
    The hydrogen gas sealed container according to claim 1 or 2.
PCT/JP2013/070233 2012-07-25 2013-07-25 Airtight container for hydrogen gas WO2014017608A1 (en)

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