JP2005013925A - Reduced water generation member - Google Patents

Reduced water generation member Download PDF

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JP2005013925A
JP2005013925A JP2003184231A JP2003184231A JP2005013925A JP 2005013925 A JP2005013925 A JP 2005013925A JP 2003184231 A JP2003184231 A JP 2003184231A JP 2003184231 A JP2003184231 A JP 2003184231A JP 2005013925 A JP2005013925 A JP 2005013925A
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water
bag
reduced water
generating member
reduced
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Japanese (ja)
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Ikuko Uragami
郁子 浦上
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a reduced water generation member which generates reduced water only by being charged to water filled into a vessel or the like. <P>SOLUTION: A reduced water generation tool 1 is obtained by filling a mixture of a ceramic granular body 4 formed by sintering fine powder essentially consisting of BAKUHANSEKI (a kind of granite porphyry), a magnesium granular body 5 as a hydrogen generation source and a chlorine remover granular body 6 into a bag consisting of a flexible stock having water permeability and gas permeability (such as nonwoven fabric) with a part of the content volume of the bag 2 left. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

【0001】
【産業上の利用分野】
この発明は、水を活性化するために、容器などに満たされた飲料水、浴槽などに満たされた生活用水、養殖場の水槽、池、生け簀などに満たされた水などに投入して用いられる部材であって、特にこの発明は、活性水素が豊富に含まれる酸化還元電位の低い水(以下、「還元水」という。)を生成するための還元水生成部材に関する。
【0002】
【発明の属する技術分野】
例えば、各浄水場では、近年の水質の悪化に鑑み、塩素などの多量の薬品を用いて水の浄化と滅菌とを行うことにより短時間で大量の水を供給するようにしている。この濾過方式は、最初に取水した原水に液体塩素を注入して処理し(前塩素処理)、その処理済の水を最後に再び塩素で処理するものである(後塩素処理)。
【0003】
このような方式で得られた水道水には、当然のことながら、多量の塩素が含まれる。ところが、塩素が体内に摂取されると、食べ物中のビタミン類を破壊したり、皮膚に浸透して細胞を破壊したり、体内の有用な微生物を死滅させたり、水中の有機物質(フミン酸)と反応してトリハロメタンのような発ガン性を有する有機塩素化合物を生成したりするなどのおそれがある。
また、塩素は酸化剤であるので、水道水は酸化力の強い水、換言すれば、酸化還元電位の高い水となり、万病の原因である活性酸素の発生を助長し、酸化障害(病気)を引き起こすという問題がある。
【0004】
そこで、一般家庭では、塩素除去のために、水道の蛇口に浄水器を取り付けることが行われている。この種の浄水器には種々のものがあり、例えば、濾過材として麦飯石を用いたものでは、麦飯石の吸着性能を利用して水道水中の塩素や不純物(雑菌や重金属を含む)を吸着し、また、麦飯石に含まれるカルシウム、鉄、ナトリウムなどのミネラル分を供給している。
ところが、この種の浄水器は、水道水中の塩素を除去できても、活性水素が豊富に含まれる酸化還元電位の低い水(還元水)が生成できるわけではない。
【0005】
この種の浄水器とは別に、従来よりアルカリイオン整水器と呼ばれる還元水生成装置も製品化されている。
このアルカリイオン整水器は、水道水に含まれる塩素を濾過部材で除去した後、濾過処理後の水に電気分解を施して還元水を生成するものである。このアルカリイオン整水器では、正負の電極板間に直流電圧がかけられており、陰極側の電極板に集まったアルカリイオン水を還元水として取り出している。前記陰極側の電極板には、Mg2+,Ca2+,Na2+,Hが集まり、電極板から飛び出た電子(e)がHと結びついてHとなり、空気中に逃げるため、OHが増えてアルカリ性となる。このアルカリイオン水は、活性水素を多く含み、酸化還元電位が低いので、万病の原因である活性酸素が還元されて消去される。
【0006】
【発明が解決しようとする課題】
しかしながら、上記したアルカリイオン整水器は、電極板に電圧を印加して水の電気分解を行うから、電源が必要であって取扱が簡易でなく、還元水の生成に時間がかかるという問題がある。
【0007】
この発明は、上記問題に着目してなされたもので、容器などに満たされた水に投入するだけで還元水を生成可能となすことにより、取扱が容易でありかつ時間をかけずに還元水が生成できる還元水生成部材を提供することを目的とする。
【0008】
【課題を解決するための手段】
この発明による還元水生成部材は、通水性と通気性とを有する柔軟な素材より成る袋の内部に、麦飯石を主成分とする微粉末を焼結して形成されたセラミックの粒状体と水素発生源としてのマグネシウムの粒状体と塩素除去剤の粒状体との混合物が、袋の内容積の一部を残して充填されて成るものである。
【0009】
この発明の好ましい一実施態様においては、前記袋は不織布によって形成されているが、適度な通水性と通気性とを有する柔軟な素材であれば、必ずしも不織布に限られない。
【0010】
さらに好ましい実施態様では、発生した水素が袋内に溜まるように、前記袋に袋の内容積の1/2〜2/3を残して前記混合物が充填されている。
【0011】
さらに好ましい実施態様では、還元水生成部材が水中で浮くときに、水中において起立した姿勢で浮くように、袋が筒袋状に形成されている。
【0012】
この発明の好ましい一実施態様においては、前記塩素除去剤として、亜硫酸カルシウムのようなカルシウム化合物を用いるが、必ずしもカルシウム化合物に限定されるものではない。
【0013】
この発明による還元水生成部材は、その用途に応じて、袋に浮きまたは錘を取り付けることにより、水面付近で浮くようにするか、または水中の適当な深さの位置で浮くようにしてもよい。
【0014】
【作用】
容器などに満たされた水に還元水生成部材が投入されると、袋内に滲入した水がセラミックの粒状体、マグネシウムの粒状体、および塩素除去剤の粒状体と接触する。セラミックの粒状体と水との摩擦、さらにはセラミックの粒状体同志の衝突によって静電気が発生し、これが水の解離作用を促し、水のクラスターを小さくする。また、塩素除去剤の粒状体は水中の塩素を吸着などにより除去する。マグネシウムの粒状体は水と反応して水素を発生させる。発生した水素は袋内に一旦溜まるので、還元水生成部材は水中で浮き上がる。袋内に溜まった水素は袋の外部へ急速に漏れ出ることなく徐々に漏れ出て水に作用する。その結果、活性水素が豊富に含まれる酸化還元電位の低い還元水が徐々にかつ長時間にわたって生成される。
【0015】
マグネシウムが次第に酸化され、マグネシウムの粒状体の表面に酸化被膜が形成されると、水素の発生が鈍り、還元水生成部材は水中を徐々に沈み込んでゆく。この状態に至ると、水中より還元水生成部材を取り出して手で揉むようにする。これにより、袋内でマグネシウムの粒状体がセラミックの粒状体と衝突して表面が擦られ、酸化被膜が削り取られるので、還元水生成部材を再利用できる。
【0016】
【発明の実施の形態】
図1は、この発明の一実施例である還元水生成部材1の使用態様を示す。同図中、10はペットボトルと呼ばれる合成樹脂製の透明容器である。この容器10の内部には飲料用の水が充填されているが、水以外の飲料(例えば、茶など)であってもよい。
【0017】
図示例の還元水生成部材1は、容器10の内部に満たされた水の中に投入されて用いられるもので、そのために、容器10の口部aより投入し得る大きさに形成されている。この還元水生成部材1は、図2に示すように、不織布より成る袋2の内部に、麦飯石を主原料としたセラミックの粒状体4とマグネシウムの粒状体5と亜硫酸カルシウムの粒状体6との混合物が、袋2の内容積の1/2〜2/3を残して充填されて密封されたものである。このように、袋2の内部に混合物が余裕のある状態で装填されているので、袋2の内部で各粒状体4,5,6が移動可能であり、また、発生した水素が袋2の内部に溜まることが可能となる。
【0018】
前記袋2は、細長い筒袋状であって、筒状に巻いたものの両端の開放部分を封着して形成されている。なお図中、3は封着された両端部を示し、両端部3の幅yが2cm、両端部3,3間の長さxが9cmである。袋2の素材として用いる不織布は、袋2の内部に水が滲入して混合物に触れるように通水性を有し、また、発生した水素が袋2の外部へ漏れ出て水に作用するように通気性を有している。さらに袋2は、発生した水素が袋2内に一旦溜まった後、外部へ徐々に漏れ出るような通気度に設定されている。さらにまた、袋2は、発生した水素が袋2内に溜まって浮き上がったとき、水素が空気中に逃げないように、全体が水面下にあるように袋2の通気度を設定することが望ましい。
【0019】
実験によると、袋2の素材としての不織布は、濾過度が1.8〜2.7sec/500ccの範囲内であって、望ましくは、1.88sec/500cc前後の値に設定する。また、通気度は200〜360cc/cm/secの範囲内であって、望ましくは、318cc/cm/secの前後の値に設定する。
なお、前記の「濾過度」は、不織布の水の通りにくさを表しており、500ccの水を単位面積の試料に対して自然落下させたときに、その水が試料を通過するのに要する時間を意味する。
【0020】
前記セラミックの粒状体4は直径が1〜2mmの小球体である。亜硫酸カルシウムの粒状体6は直径が1〜2.5mmの小球状である。マグネシウムの粒状体5は1〜3mm角であって厚みが0.5mmの薄片である。
前記セラミックの粒状体4は、麦飯石、ボーキサイト、結晶質シリカ、酸化チタンなどを所定の比率で混合して焼結することにより形成されている。具体的には、まず、麦飯石とボーキサイトとを混合し、高温で焼成した後に急冷して再結晶化する。また、麦飯石と酸化チタンとを混合し、高温で焼成した後に急冷して再結晶化する。これらを細かく粉砕したものに結晶質シリカを調合し、有機バインダーによって所定サイズの小球体に整形する。この小球体は自然乾燥した後、1300℃前後で還元焼成する。その後、小球体の表面を研磨してセラミックの粒状体4を得る。セラミックの粒状体4は、初期の摩耗を軽減するためにその表面を研磨しているのである。
【0021】
セラミックの粒状体4は、水との摩擦や粒状体同志の衝突によってエネルギー(静電気)を発生する。セラミックの粒状体4は焦電性が高いので、発生したエネルギーは吸収されずに外部に放出される。その結果、水分子集団(クラスター)が細分化されるとともに、水素Hと水酸イオンOHへの水の解離が促される。
【0022】
前記マグネシウムの粒状体5は、水との接触によって反応し、水酸化マグネシウムMg(OH)と水素Hとが生成される。その水素Hが水に作用すると、水の酸化還元電位が下がり、活性水素が豊富に含まれた還元水が得られる。
前記亜硫酸カルシウムの粒状体6は、水中の塩素を吸着して除去するもので、pHを調節する機能があり、飲料に適した水が得られる。
【0023】
実験によると、1リットルの水道水が満たされたペットボトルに還元電位生成部材1を投入したところ、当初、酸化還元電位が780mVであったものが、15分経過後には210mV、30分経過後には187mV、1時間経過後には120mVに低下した。また、pHは当初、7であったものが、15分経過後および30分経過後には7.3になり、1時間経過後には7.5になった。また、オルトトルジン試薬を用いて塩素の有無を調べたところ、当初は塩素の存在が確認し得たが、15分経過後には塩素が消失した。なお、この実験で用いた還元電位生成部材1は、袋2内に4.5gのセラミックの粒状体4と、1.5gのマグネシウムの粒状体5と、0.8gの亜硫酸カルシウムの粒状体6とが充填されたものである。
上記したとおり、還元電位生成部材1の投入後、15分を経過した時点で、生体内の電位(200mV以下)とほぼ同じの酸化還元電位であって、塩素を含まない弱アルカリ性の飲料水が得られた。
【0024】
つぎに、上記した実施例の作用を説明すると、水道水が満たされたペットボトル10の内部へ還元水生成部材1を投入すると、袋2内に滲入した水がセラミックの粒状体4、マグネシウムの粒状体5、および亜硫酸カルシウムの粒状体6と接触する。セラミックの粒状体4と水との摩擦、さらにはセラミックの粒状体4同志の衝突によって静電気が発生し、これが水の解離作用を促し、水のクラスターを小さくする。また、亜硝酸カルシウムの粒状体6は水中の塩素を吸着などにより除去する。マグネシウムの粒状体5は水と反応して水素を発生させる。発生した水素は袋2内に一旦溜まるので、還元水生成部材1は水中で浮き上がる。
【0025】
図1は、還元水生成部材1が水面S近くまで浮き上がった状態を示している。この実施例の還元水生成部材1は、袋2が細長い筒袋状であるので、水中で起立した姿勢で浮いている。この浮き上がった状態では、還元水生成部材1は有効に機能しており、袋2内に溜まった水素が袋2の外部へ急速に漏れ出ることなく徐々に漏れ出て水に作用し、その結果、活性水素が豊富に含まれる酸化還元電位の低い還元水が徐々にかつ長時間にわたって生成される。
【0026】
マグネシウムが次第に酸化されてマグネシウムの粒状体5の表面に酸化被膜が形成されると、水素の発生が鈍り、還元水生成部材1は水中を徐々に沈み込んでゆく。この状態では、マグネシウムMgは、Mg2++2e2−となって還元剤となって働いている。このように還元水生成部材1の機能が低下したときは、水中より還元水生成部材1を取り出して手で揉むと、袋2内でマグネシウムの粒状体5がセラミックの粒状体4と衝突して表面が擦られ、酸化被膜が削り取られる。その結果、還元水生成部材1の再利用が可能となる。
【0027】
上記した実施例の還元水生成部材1は、容器に満たされた飲料水に投入して用いられるものであるが、浴槽などに満たされた生活用水、養殖場の水槽、池、生け簀などに満たされた水などに投入して用いられるものとして形成してもよい。また、水中へ投入する以外に、例えば、水を含んだ土壌中に埋め込んで土壌改良に用いられるものとして形成してもよい。
いずれの場合も、その用途に応じて、袋2の形状や大きさ、充填される混合物の量などを選択するが、用途によっては、必要に応じて袋2に浮きや錘を取り付けることにより、水面付近で浮くようにするか、または水中の適当な深さの位置で浮くようにする。
【0028】
【発明の効果】
この発明によれば、容器などに満たされた水に投入するだけで還元水の生成が可能であるので、取扱がきわめて容易であり、しかも、時間をかけずに還元水を生成できる。また、袋内に溜まった水素は袋の外部へ徐々に漏れ出て水に作用するので、活性水素が豊富に含まれる酸化還元電位の低い還元水が徐々にかつ長時間にわたって生成できる。さらに、袋内で水素が発生するとき水中で浮き上がるので、還元水生成部材が有効に機能しているかどうかを容易に判別できる。さらにまた、マグネシウムの酸化により水素の発生が鈍ったとき、水中より取り出して手で揉むことにより表面の酸化被膜を除去でき、その結果、還元水生部材1を再利用できる。
【図面の簡単な説明】
【図1】この発明の一実施例である還元水生成部材を容器に投入した状態を示す正面図である。
【図2】袋の一部を破断した状態で示す還元水生成部材の正面図である。
【符号の説明】
1 還元水生成具
2 袋
4 セラミックの粒状体
5 マグネシウムの粒状体
6 亜硫酸カルシウムの粒状体
[0001]
[Industrial application fields]
In order to activate the water, the present invention is used by throwing it into drinking water filled in a container or the like, domestic water filled in a tub or the like, water filled in an aquarium, pond, ginger etc. In particular, the present invention relates to a reduced water generating member for generating water having a low oxidation-reduction potential rich in active hydrogen (hereinafter referred to as “reduced water”).
[0002]
BACKGROUND OF THE INVENTION
For example, each water purification plant supplies a large amount of water in a short time by purifying and sterilizing water using a large amount of chemicals such as chlorine in view of the recent deterioration of water quality. In this filtration method, liquid chlorine is injected into the first raw water that has been taken in and treated (pre-chlorination), and the treated water is finally treated again with chlorine (post-chlorination).
[0003]
The tap water obtained by such a method naturally contains a large amount of chlorine. However, when chlorine is taken into the body, it destroys vitamins in food, penetrates the skin to destroy cells, kills useful microorganisms in the body, and organic substances in the water (humic acid) There is a risk of producing an organic chlorine compound having carcinogenic properties such as trihalomethane.
In addition, since chlorine is an oxidizing agent, tap water becomes highly oxidative water, in other words, water with a high oxidation-reduction potential, which promotes the generation of active oxygen, which is the cause of all diseases, and prevents oxidative damage (disease). There is a problem of causing.
[0004]
Therefore, in general households, a water purifier is attached to a faucet for removing chlorine. There are various types of water purifiers of this type. For example, in the case of using barley stone as filter material, chlorine and impurities (including bacteria and heavy metals) in tap water are adsorbed using the barley stone adsorption performance. In addition, it supplies minerals such as calcium, iron, and sodium contained in barley stone.
However, even though this type of water purifier can remove chlorine from tap water, it cannot produce water having a low oxidation-reduction potential (reduced water) rich in active hydrogen.
[0005]
Apart from this type of water purifier, a reduced water generating device called an alkali ion water conditioner has been commercialized.
In this alkaline ionized water device, chlorine contained in tap water is removed by a filtration member, and electrolyzed water is produced after filtration treatment to produce reduced water. In this alkaline ionized water device, a DC voltage is applied between the positive and negative electrode plates, and the alkaline ionized water collected on the cathode-side electrode plate is taken out as reduced water. Mg 2+ , Ca 2+ , Na 2+ , and H + gather on the electrode plate on the cathode side, and electrons (e ) ejected from the electrode plate are combined with H + to become H 2 , and escape into the air. - it is alkaline increasing. This alkaline ionized water contains a large amount of active hydrogen and has a low oxidation-reduction potential, so that active oxygen that causes all diseases is reduced and eliminated.
[0006]
[Problems to be solved by the invention]
However, since the alkaline ionized water device described above performs electrolysis of water by applying a voltage to the electrode plate, there is a problem that it requires a power source, is not easy to handle, and takes time to generate reduced water. is there.
[0007]
The present invention has been made by paying attention to the above-mentioned problem. By making it possible to generate reduced water simply by putting it into water filled in a container or the like, the reduced water can be handled easily and without taking time. It aims at providing the reduced water production | generation member which can produce | generate.
[0008]
[Means for Solving the Problems]
The reduced water generating member according to the present invention comprises ceramic particles and hydrogen formed by sintering fine powder mainly composed of barley stone in a bag made of a flexible material having water permeability and air permeability. A mixture of magnesium granules as a generation source and chlorine removal granules is filled so as to leave a part of the inner volume of the bag.
[0009]
In a preferred embodiment of the present invention, the bag is formed of a non-woven fabric, but is not necessarily limited to a non-woven fabric as long as it is a flexible material having appropriate water permeability and air permeability.
[0010]
In a more preferred embodiment, the bag is filled with the mixture leaving 1/2 to 2/3 of the inner volume of the bag so that the generated hydrogen accumulates in the bag.
[0011]
In a more preferred embodiment, the bag is formed in a cylindrical bag shape so that when the reduced water generating member floats in water, it floats in an upright posture.
[0012]
In a preferred embodiment of the present invention, a calcium compound such as calcium sulfite is used as the chlorine removing agent, but it is not necessarily limited to a calcium compound.
[0013]
The reduced water generating member according to the present invention may be floated near the water surface by floating or attaching a weight to the bag, or may be floated at an appropriate depth in water, depending on the application. .
[0014]
[Action]
When the reduced water generating member is put into the water filled in the container or the like, the water that has penetrated into the bag comes into contact with the ceramic granules, the magnesium granules, and the chlorine remover granules. Static electricity is generated by friction between ceramic particles and water, and collision between ceramic particles, which promotes water dissociation and reduces water clusters. Moreover, the granular material of a chlorine removal agent removes chlorine in water by adsorption or the like. Magnesium granules react with water to generate hydrogen. Since the generated hydrogen is temporarily accumulated in the bag, the reduced water generating member floats in water. The hydrogen accumulated in the bag gradually leaks to the outside of the bag without leaking and acts on the water. As a result, reduced water containing a large amount of active hydrogen and having a low redox potential is gradually generated over a long period of time.
[0015]
When magnesium is gradually oxidized and an oxide film is formed on the surface of the magnesium granules, the generation of hydrogen becomes dull and the reduced water generating member gradually sinks in water. When this state is reached, the reduced water generating member is taken out of the water and rubbed by hand. As a result, the magnesium granular material collides with the ceramic granular material in the bag, the surface is rubbed, and the oxide film is scraped off, whereby the reduced water generating member can be reused.
[0016]
DETAILED DESCRIPTION OF THE INVENTION
FIG. 1 shows a usage mode of a reduced water generating member 1 according to an embodiment of the present invention. In the figure, reference numeral 10 denotes a synthetic resin transparent container called a PET bottle. The container 10 is filled with drinking water, but may be a beverage other than water (for example, tea).
[0017]
The reducing water generating member 1 in the illustrated example is used by being poured into water filled in the container 10, and for that purpose, is formed in a size that can be charged from the mouth portion a of the container 10. . As shown in FIG. 2, the reduced water generating member 1 includes a ceramic granule 4, a magnesium granule 5, and a calcium sulfite granule 6, which are mainly made of barley stone, in a bag 2 made of a nonwoven fabric. The mixture was filled and sealed, leaving 1/2 to 2/3 of the inner volume of the bag 2. As described above, since the mixture is loaded in the bag 2 with a margin, each granular material 4, 5, 6 can move inside the bag 2, and the generated hydrogen is stored in the bag 2. It becomes possible to accumulate inside.
[0018]
The bag 2 has an elongated cylindrical bag shape, and is formed by sealing open portions at both ends of a cylindrically wound bag. In the figure, reference numeral 3 denotes sealed ends, where the width y of the ends 3 is 2 cm, and the length x between the ends 3 is 3 cm. The non-woven fabric used as the material of the bag 2 has water permeability so that water penetrates into the bag 2 and touches the mixture, and the generated hydrogen leaks out of the bag 2 and acts on the water. It has air permeability. Further, the bag 2 is set to an air permeability such that the generated hydrogen once accumulates in the bag 2 and then gradually leaks to the outside. Furthermore, it is desirable that the air permeability of the bag 2 is set so that the whole is below the water surface so that hydrogen does not escape into the air when the generated hydrogen collects and floats in the bag 2. .
[0019]
According to the experiment, the non-woven fabric as the material of the bag 2 has a filtration degree in the range of 1.8 to 2.7 sec / 500 cc, and is preferably set to a value around 1.88 sec / 500 cc. Further, the air permeability is in the range of 200 to 360 cc / cm 2 / sec, and is desirably set to a value around 318 cc / cm 2 / sec.
The “filtering degree” represents the difficulty of the nonwoven fabric, and when 500 cc of water is naturally dropped onto a sample of a unit area, the water needs to pass through the sample. Means time.
[0020]
The ceramic granule 4 is a small sphere having a diameter of 1 to 2 mm. The calcium sulfite granules 6 are small spheres having a diameter of 1 to 2.5 mm. The magnesium granular body 5 is a thin piece having a size of 1 to 3 mm square and a thickness of 0.5 mm.
The ceramic granule 4 is formed by mixing and sintering barleystone, bauxite, crystalline silica, titanium oxide, and the like at a predetermined ratio. Specifically, first, barley stone and bauxite are mixed, fired at a high temperature, rapidly cooled, and recrystallized. In addition, barley stone and titanium oxide are mixed, baked at a high temperature, and then rapidly cooled and recrystallized. Crystalline silica is blended into a finely pulverized product and shaped into small spheres of a predetermined size with an organic binder. The small spheres are naturally dried and then reduced and fired at around 1300 ° C. Thereafter, the surface of the small sphere is polished to obtain the ceramic granule 4. The surface of the ceramic granule 4 is polished to reduce initial wear.
[0021]
The ceramic granular material 4 generates energy (static electricity) by friction with water or collision between the granular materials. Since the ceramic granular material 4 has high pyroelectricity, the generated energy is not absorbed but released to the outside. As a result, the water molecule group (cluster) is subdivided and the dissociation of water into hydrogen H + and hydroxide ions OH is promoted.
[0022]
The magnesium granule 5 reacts by contact with water to produce magnesium hydroxide Mg (OH) 2 and hydrogen H 2 . When the hydrogen H 2 acts on water, the oxidation-reduction potential of water decreases, and reduced water rich in active hydrogen is obtained.
The calcium sulfite granules 6 adsorb and remove chlorine in water, have a function of adjusting pH, and obtain water suitable for beverages.
[0023]
According to the experiment, when the reduction potential generating member 1 was put into a plastic bottle filled with 1 liter of tap water, the oxidation reduction potential was initially 780 mV, but after 210 minutes, 210 mV, after 30 minutes. Decreased to 187 mV and 120 mV after 1 hour. The pH was 7 at the beginning, but became 7.3 after 15 minutes and 30 minutes, and 7.5 after 1 hour. Further, when the presence or absence of chlorine was examined using an orthotoludin reagent, the presence of chlorine could be confirmed initially, but the chlorine disappeared after 15 minutes. The reduction potential generating member 1 used in this experiment has 4.5 g of ceramic granules 4, 1.5 g of magnesium granules 5, and 0.8 g of calcium sulfite granules 6 in a bag 2. And are filled.
As described above, at the time when 15 minutes have elapsed after the reduction potential generating member 1 is put in, the weakly alkaline drinking water that has substantially the same oxidation-reduction potential as the in vivo potential (200 mV or less) and does not contain chlorine. Obtained.
[0024]
Next, the operation of the above-described embodiment will be described. When the reducing water generating member 1 is introduced into the inside of the PET bottle 10 filled with tap water, the water that has infiltrated into the bag 2 is made of ceramic particles 4 and magnesium. It contacts the granular material 5 and the granular material 6 of calcium sulfite. Static electricity is generated by the friction between the ceramic granule 4 and water, and also by the collision between the ceramic granule 4, which promotes the dissociation of water and reduces the water cluster. The granular body 6 of calcium nitrite removes chlorine in water by adsorption or the like. The magnesium granule 5 reacts with water to generate hydrogen. Since the generated hydrogen is temporarily accumulated in the bag 2, the reduced water generating member 1 floats in water.
[0025]
FIG. 1 shows a state where the reduced water generating member 1 is lifted up to the vicinity of the water surface S. The reduced water generating member 1 of this embodiment floats in an upright posture in the water because the bag 2 has an elongated cylindrical bag shape. In this lifted state, the reduced water generating member 1 functions effectively, and hydrogen accumulated in the bag 2 gradually leaks out of the bag 2 without rapidly leaking and acts on the water. As a result, Then, reduced water having a low oxidation-reduction potential and containing abundant active hydrogen is produced gradually and over a long period of time.
[0026]
When magnesium is gradually oxidized and an oxide film is formed on the surface of the magnesium granular material 5, the generation of hydrogen becomes dull, and the reduced water generating member 1 gradually sinks in water. In this state, magnesium Mg acts as a reducing agent as Mg 2+ + 2e 2− . Thus, when the function of the reduced water production | generation member 1 falls, if the reduced water production | generation member 1 is taken out from water and it rubs by hand, the magnesium granule 5 will collide with the ceramic granule 4 within the bag 2. FIG. The surface is rubbed and the oxide film is scraped off. As a result, the reduced water generating member 1 can be reused.
[0027]
The reduced water generating member 1 of the above-described embodiment is used by being poured into drinking water filled in a container, but is filled with water for daily life filled in a bathtub or the like, a fish tank in a farm, a pond, a sacrifice, etc. You may form as what is thrown into used water etc. and used. Moreover, you may form as what is embedded in the soil containing water other than throwing in water and used for soil improvement, for example.
In any case, depending on the application, the shape and size of the bag 2 and the amount of the mixture to be filled are selected, but depending on the application, by attaching a float or weight to the bag 2 as necessary, Float near the surface of the water or float at a suitable depth in the water.
[0028]
【The invention's effect】
According to the present invention, reducing water can be generated simply by putting it into water filled in a container or the like, so that it is very easy to handle, and reducing water can be generated without taking time. Further, since the hydrogen accumulated in the bag gradually leaks to the outside of the bag and acts on the water, reduced water having a low oxidation-reduction potential and rich in active hydrogen can be generated gradually and over a long period of time. Furthermore, since hydrogen floats in water when hydrogen is generated in the bag, it can be easily determined whether or not the reduced water generating member functions effectively. Furthermore, when the generation of hydrogen becomes dull due to the oxidation of magnesium, the oxide film on the surface can be removed by taking out from the water and rubbing it by hand, and as a result, the reduced aquatic member 1 can be reused.
[Brief description of the drawings]
FIG. 1 is a front view showing a state in which a reduced water generating member according to one embodiment of the present invention is put into a container.
FIG. 2 is a front view of a reduced water generating member shown in a state where a part of the bag is broken.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Reduced water generator 2 Bag 4 Ceramic granule 5 Magnesium granule 6 Calcium sulfite granule

Claims (6)

通水性と通気性とを有する柔軟な素材より成る袋の内部に、麦飯石を主成分とする微粉末を焼結して形成されたセラミックの粒状体と水素発生源としてのマグネシウムの粒状体と塩素除去剤の粒状体との混合物が、袋の内容積の一部を残して充填されて成る還元水生成部材。Inside the bag made of a flexible material having water permeability and air permeability, ceramic particles formed by sintering fine powder mainly composed of barley stone and magnesium particles as a hydrogen generation source A reduced water generating member formed by filling a mixture of a chlorine removing agent and granular material, leaving a part of the inner volume of the bag. 前記袋は、不織布によって形成されている請求項1に記載された還元水生成部材。The reduced water generating member according to claim 1, wherein the bag is formed of a nonwoven fabric. 前記袋には、袋の内容積の1/2〜2/3を残して前記混合物が充填されている請求項1または2に記載された還元水生成部材。The reduced water production | generation member described in Claim 1 or 2 with which the said bag is filled with the said mixture, leaving 1/2 to 2/3 of the internal volume of a bag. 前記袋は、筒袋状に形成されている請求項1〜3のいずれかに記載された還元水生成部材。The reduced water generating member according to claim 1, wherein the bag is formed in a cylindrical bag shape. 前記塩素除去剤は、カルシウム化合物である請求項1に記載された還元水生成部材。The reduced water generating member according to claim 1, wherein the chlorine removing agent is a calcium compound. 請求項1〜5のいずれかに記載された還元水生成部材であって、前記袋に浮きまたは錘が取り付けられている還元水生成部材。The reduced water generating member according to claim 1, wherein a floating or weight is attached to the bag.
JP2003184231A 2003-06-27 2003-06-27 Reduced water generation member Pending JP2005013925A (en)

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Cited By (12)

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Publication number Priority date Publication date Assignee Title
WO2006098405A1 (en) * 2005-03-17 2006-09-21 Seiki Shiga Process and kit for formation of active hydrogen water, gypsum feeder for the formation, active hydrogen forming materials and process for the production of the materials
WO2006098003A1 (en) * 2005-03-15 2006-09-21 The Zendama Club Company, Ltd. Structure for producing water containing hydrogen at high concentration
JP2006334505A (en) * 2005-06-01 2006-12-14 Sunfu:Kk Water modifying catalyst, water modifying device, and water modifying method, and functional water
JP2007153667A (en) * 2005-12-05 2007-06-21 Saiseiko Kk Hydrogen generator and fuel cell
JP2007167696A (en) * 2005-11-22 2007-07-05 Hidemitsu Hayashi Method and material for modifying drinking water
JP2011200826A (en) * 2010-03-26 2011-10-13 National Institute For Materials Science Reduced hydrogen water-forming agent
JP2011255360A (en) * 2010-06-11 2011-12-22 Nagano Ceramics Corp Agent for generating reduced water
JP2012005393A (en) * 2010-06-23 2012-01-12 It Concept Co Ltd Ballast for water tank
US20120263629A1 (en) * 2010-10-25 2012-10-18 Fumitake Satoh Selective hydrogen adding equipment for living organism applicable fluid
US20130019757A1 (en) * 2011-07-15 2013-01-24 Miz Co., Ltd. Selective hydrogen adding equipment for living organism applicable fluid
US20140010483A1 (en) * 2012-07-06 2014-01-09 Kyowa Co., Ltd. Sealing Bag for Hydrogen Gas, and Method for Dissolving Hydrogen Gas
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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006098003A1 (en) * 2005-03-15 2006-09-21 The Zendama Club Company, Ltd. Structure for producing water containing hydrogen at high concentration
WO2006098405A1 (en) * 2005-03-17 2006-09-21 Seiki Shiga Process and kit for formation of active hydrogen water, gypsum feeder for the formation, active hydrogen forming materials and process for the production of the materials
JP2006334505A (en) * 2005-06-01 2006-12-14 Sunfu:Kk Water modifying catalyst, water modifying device, and water modifying method, and functional water
JP2007167696A (en) * 2005-11-22 2007-07-05 Hidemitsu Hayashi Method and material for modifying drinking water
JP2007153667A (en) * 2005-12-05 2007-06-21 Saiseiko Kk Hydrogen generator and fuel cell
JP2011200826A (en) * 2010-03-26 2011-10-13 National Institute For Materials Science Reduced hydrogen water-forming agent
JP2011255360A (en) * 2010-06-11 2011-12-22 Nagano Ceramics Corp Agent for generating reduced water
JP2012005393A (en) * 2010-06-23 2012-01-12 It Concept Co Ltd Ballast for water tank
US20120263629A1 (en) * 2010-10-25 2012-10-18 Fumitake Satoh Selective hydrogen adding equipment for living organism applicable fluid
US9120672B2 (en) * 2010-10-25 2015-09-01 Miz Co., Ltd. Selective hydrogen adding equipment for living organism applicable fluid
US20130019757A1 (en) * 2011-07-15 2013-01-24 Miz Co., Ltd. Selective hydrogen adding equipment for living organism applicable fluid
US9149774B2 (en) * 2011-07-15 2015-10-06 Miz Co. Ltd. Selective hydrogen adding equipment for living organism applicable fluid
US10238232B2 (en) 2011-07-15 2019-03-26 Miz Co., Ltd. Selective hydrogen adding equipment for living organism applicable fluid
US20140010483A1 (en) * 2012-07-06 2014-01-09 Kyowa Co., Ltd. Sealing Bag for Hydrogen Gas, and Method for Dissolving Hydrogen Gas
CN103523389A (en) * 2012-07-06 2014-01-22 株式会社光未来 Dissolution method of hydrogen and hydrogen in a sealed bag
US10023360B2 (en) * 2012-07-06 2018-07-17 Hirakimirai Co. Ltd. Sealing bag for hydrogen gas, and method for dissolving hydrogen gas
WO2014017608A1 (en) * 2012-07-25 2014-01-30 株式会社光未来 Airtight container for hydrogen gas

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