WO2013141527A1 - 이차전지용 전지케이스 - Google Patents
이차전지용 전지케이스 Download PDFInfo
- Publication number
- WO2013141527A1 WO2013141527A1 PCT/KR2013/002116 KR2013002116W WO2013141527A1 WO 2013141527 A1 WO2013141527 A1 WO 2013141527A1 KR 2013002116 W KR2013002116 W KR 2013002116W WO 2013141527 A1 WO2013141527 A1 WO 2013141527A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- die
- punch
- sheet
- base material
- battery case
- Prior art date
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- 239000000463 material Substances 0.000 claims abstract description 83
- 238000000034 method Methods 0.000 claims description 61
- 230000008569 process Effects 0.000 claims description 39
- 238000004519 manufacturing process Methods 0.000 claims description 38
- 238000003825 pressing Methods 0.000 claims description 32
- 239000002952 polymeric resin Substances 0.000 claims description 10
- 229920003002 synthetic resin Polymers 0.000 claims description 10
- 238000007373 indentation Methods 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 7
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- 230000037303 wrinkles Effects 0.000 claims description 7
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 5
- 229910001416 lithium ion Inorganic materials 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0436—Small-sized flat cells or batteries for portable equipment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/105—Pouches or flexible bags
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/117—Inorganic material
- H01M50/119—Metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/121—Organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
- H01M50/126—Primary casings; Jackets or wrappings characterised by the material having a layered structure comprising three or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/02—Stamping using rigid devices or tools
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
Definitions
- the present invention relates to a battery case for a secondary battery having a novel structure, and more particularly, includes an accommodating part into which an electrode assembly may be embedded, and the accommodating part formed by the deformation of a sheet-like base material forms one or more accommodating parts. It relates to a battery case, characterized in that the edge and / or surface is deformed to form a stepped structure.
- Secondary batteries are widely used as a power source for mobile devices such as mobile phones, laptops and camcorders.
- the use of lithium secondary batteries is rapidly increasing due to the advantages of high operating voltage and high energy density per unit weight.
- the lithium secondary battery may be classified into a lithium ion battery, a lithium ion polymer battery, a lithium polymer battery, and the like according to the composition of the electrode and the electrolyte, and among them, the amount of leakage of the electrolyte is less likely, and the amount of the lithium ion polymer battery that is easy to manufacture is used. This is increasing.
- a lithium ion polymer battery (LiPB) is a structure in which an electrolyte solution is impregnated into an electrode assembly in which electrodes (anode and cathode) and a separator are heat-sealed, and is mainly used in a form in which the electrode assembly is sealed in a pouch type case of an aluminum laminate sheet.
- lithium ion polymer batteries are often referred to as pouch cells.
- FIG. 1 schematically illustrates a general structure of a representative secondary battery including a stacked electrode assembly.
- the secondary battery 10 includes an electrode assembly 30 formed of a positive electrode, a negative electrode, and a separator disposed therebetween in a pouch-type battery case 20, and a positive electrode and a negative electrode thereof.
- the tabs 31 and 32 are welded to the two electrode leads 40 and 41, respectively, and are sealed (sealed) to be exposed to the outside of the battery case 20.
- the battery case 20 is made of a soft packaging material such as an aluminum laminate sheet, and includes a case main body 21 and a main body 21 including a recess 23 having a concave shape in which the electrode assembly 30 can be seated. One side is made of a cover 22 is connected.
- the electrode assembly 30 used in the secondary battery 10 may have a jelly roll structure or a stack / folding structure in addition to the stacked structure as shown in FIG. 1.
- a plurality of positive electrode tabs 31 and a plurality of negative electrode tabs 32 are welded to the electrode leads 40 and 41, respectively.
- the secondary battery cell case 20 uses a rectangular parallelepiped punch corresponding to the housing 23 to press and deform a sheet-like base material, for example, an aluminum laminate sheet, to deform the storage part 23. It is produced by cutting the size of the lid in the longitudinal direction and the size corresponding to the gas pocket in the width direction.
- the secondary battery covers the cover after seating the electrode assembly in the receiving portion After sealing and heat-sealing the contact area with the main body, it goes through activation and aging steps.
- the battery case with the gas pocket is first sealed and activated to remove the gas through the gas pocket.
- the gas pocket is cut out again after being sealed to a size corresponding to the housing.
- the thickness direction of the accommodating part refers to a vertical direction or a direction in which electrodes of the electrode assembly are stacked on the accommodating part
- the forming width refers to a width formed in a direction perpendicular to the thickness direction of the accommodating part.
- the present invention aims to solve the problems of the prior art as described above and the technical problems that have been requested from the past.
- An object of the present invention is to provide a battery case including accommodating parts corresponding to electrode assemblies having various shapes so as to exhibit high output or high capacity characteristics.
- Still another object of the present invention is to provide a battery case in which the storage portion is formed by pressing using a punch having a novel shape in a portion where the housing portion is to be formed in the sheet-like base material, thereby increasing the accuracy of the storage portion and ensuring safety.
- the battery case according to the present invention for achieving the above object, includes an accommodating portion in which the electrode assembly can be built, wherein the accommodating portion formed by the deformation of the sheet-like base material has one or more edges and / or faces forming the shape of the accommodating portion. It is deformed to form a stepped structure.
- the accommodating part of the electrode assembly has a symmetrical structure in the inner circumferential surface of the accommodating part based on the central axis of the accommodating part in a planar shape, or a vertical cross-sectional shape is made of a straight line based on a flat side surface and a bottom surface.
- the planar shape is a symmetrical circular shape
- the vertical cross-sectional shape is made of a straight line on the side and bottom surface.
- the planar shape is a symmetrical square or rectangle
- the vertical cross-sectional shape is composed of a straight line on the side and bottom surface.
- the battery case of the present invention has one or more edges and / or surfaces deformed to form a stepped structure.
- the edge and / or the surface is deformed means that the inner circumferential surface of the housing is not symmetrical with respect to the center axis of the housing in a planar shape, and / or at least one of the side and bottom surfaces. It means that the vertical cross-sectional shape of is not made of a straight line.
- the base material may be, for example, a laminate sheet including a metal layer and a resin layer suitable for a pouch-type battery, and specifically, an upper layer of the first polymer resin, an intermediate layer of the barrier metal, and a lower layer of the second polymer resin.
- the first polymer resin layer may be specifically a heat sealable polymer resin, for example, an unstretched polypropylene resin.
- the barrier metal may be, for example, aluminum, and the second polymer resin may be a nylon resin, a polyethylene terephthalate resin, a polyethylene naphthalate resin, or the like as a resin having excellent weather resistance.
- the type of material is not limited to the above examples.
- the thickness of the base material to which the present invention is applied may be specifically within the range of 0.3 mm to 6 mm.
- the side wall of the accommodating part has a staircase structure including at least two or more steps, and the height of the step may be a structure that becomes smaller as it is deeper in the depth direction of the accommodating part.
- the heights of the steps become smaller toward the depth direction of the accommodating portion, it is possible to minimize the change in thickness of the accommodating portion that is elongated in the process of forming the accommodating portion.
- the n-th step is located at the lowest end in the depth direction of the housing, and the n-th step is located at the top of the n-th step, and the height of the n-th step is It may be a structure smaller than the height of the n-1 step.
- the first step is formed at the bottom end in the depth direction of the storage portion, and the second step is located above the first step, and the second step is The height may be smaller than the height of the first step.
- the third step may be located above the second step, and the height of the third step may be smaller than the height of the second step. Therefore, the first step, the second step, and the third step may have a structure in which the height of the step is sequentially reduced.
- the height of the n-th step may be 50 to 90% of the height of the n-th step. That is, the height of the second step may be 50 to 90% of the height of the first step, and the height of the third step may be 50 to 90% of the height of the second step.
- "there is a difference in height between each step” may mean that the elongation of the sheet-like base material forming the accommodating part is different in the process of forming each step.
- the thickness of the accommodating sidewall at the n-th step portion may be 90 to 99% of the thickness of the accommodating sidewall at the n-th step portion. That is, the thickness of the accommodating sidewall at the second step portion may be 90 to 99% of the thickness of the accommodating sidewall at the first step portion, and the thickness of the accommodating sidewall at the third step portion is the accommodating portion at the second step portion. It can be 90 to 99% of the thickness of the sidewalls. This, even if the housing includes a plurality of steps and is formed deep, since the thickness of the side wall of the housing is formed relatively constant, it can ensure the overall durability of the battery case.
- the present invention also provides a method of manufacturing a battery cell incorporating an electrode assembly in the battery case.
- the groove of the die may be formed in a shape corresponding to the shape of the punch so that the sheet-like base material can match the outer shape of the punch when the sheet-like base material contacts the punch and the groove of the die.
- the punch may have various shapes as a three-dimensional shape.
- the punch may have a shape in which a lower horizontal plane forms a stepped structure in the pressing direction.
- the stepped structure may be formed based on the center, one side, or one corner of the lower horizontal surface of the punch.
- other structures may be possible as well, and may be formed, for example, with a slight deflection from the center on the bottom horizontal plane of the punch.
- the battery case may be pressed by the punch of the stepped structure, and its receiving portion may be molded into a stepped structure of a shape corresponding to the punch.
- step (b) and step (c) a step of vacuuming the space between the die and the sheet-like base material may be added so that the sheet-like base material can be brought into close contact with the groove of the die.
- step (b) the sheet-like base material is pressed by the punch, and further, by making a vacuum between the die and the sheet-like base material, the sheet-like base material is pulled into the groove of the die.
- the sheet-like base material can more precisely match the shape of the groove of the die.
- forces can be applied to the sheet-like base material from each of the punches and dies, allowing the receiver to more precisely match the contours of the punches and dies, as well as more uniform force distribution to the sheet-like base material during the pressing process.
- an accommodating part and a battery case can be made free of wrinkles and whitening.
- the vacuum can be applied at any stage of the process of pressurizing using different punches. In particular, it can be applied not only to the whole process but also to only one process using a particular punch.
- the die is formed with an indentation of a stepped structure consisting of an upper end, a middle end, and a lower end, wherein the punch is a first punch corresponding to the shape of the upper end of the die, the shape of the middle of the die And a third punch corresponding to the shape of the lower end of the die.
- the second punch may be formed in a shape corresponding to the shape of the top and the middle of the die
- the third punch may be made in a shape corresponding to the shape of the top, middle, and bottom of the die.
- the battery case molding method has an effect of maximally preventing a shape where stress is concentrated at each corner of each step when the battery case is molded in a stepped structure including two or more steps. That is, in order to form a battery case having a stepped structure, when each side wall is formed in the accommodating part, one side wall is formed and then one side wall is formed, thereby minimizing stress applied while the base material is stretched. Can be. In addition, in order to further improve such effects, stress concentration may be further suppressed by forming corners forming the stepped structure of the punch in a round shape.
- a step of making the space between the die and the sheet-like base material into a vacuum state can be added so that the sheet-like base material can be closely adhered to the groove of the die.
- the punch consists of two or more punches having different widths and heights
- the die has a stepped inner surface structure consisting of a step of a shape corresponding to each of the punches, and the receiving portion is punched. It can be formed while being transformed into a stepped structure by the die.
- the stepped structure of the accommodating portion may be formed by performing pressing by the widest punch among two or more punches, and then pressing the punches in order of relatively smaller widths, and having a relatively wide width. As the pressure is applied in the order of the smaller punches, the pressing depth can be smaller.
- the pressing depth by the n-th punch may be 60 to 90% of the pressing depth by the n-th punch.
- the thickness of the side wall of the accommodating portion may be relatively constant, thereby manufacturing a battery case having durability.
- the present invention also provides a battery case manufacturing apparatus for manufacturing the battery case.
- the battery case manufacturing apparatus The battery case manufacturing apparatus,
- a first die including a punching die having a punch pressurizing the sheet for battery case mounted on a lower surface thereof, and a stripper for fixing the sheet for battery case between the following fixing dies in a drawing process;
- the battery case manufacturing apparatus is operated by a specific combination of various dies such that the drawing process is performed by closely contacting a portion where the electrode assembly accommodating portion of the battery case sheet is formed in a vertical process in a series of processes, thereby manufacturing a battery case.
- the drawing process is performed by closely contacting a portion where the electrode assembly accommodating portion of the battery case sheet is formed in a vertical process in a series of processes, thereby manufacturing a battery case.
- FIG. 1 is an exploded view of a conventional lithium secondary battery
- FIG. 2 and 3 are partially enlarged views of the housing of FIG. 1;
- FIG. 4 is a schematic view of a punch, a base material and a die for manufacturing a battery case according to an embodiment of the present invention
- FIG. 5 is a vertical cross-sectional view of a battery case according to another embodiment of the present invention.
- FIG. 6 is a schematic view of a battery case manufacturing process according to another embodiment of the present invention.
- FIG. 7 and 8 are partially enlarged views of FIG. 6;
- FIG. 9 is a schematic view illustrating a battery case manufacturing process of FIG. 5;
- FIG. 10 is a vertical cross-sectional view of a battery case manufacturing apparatus equipped with a punch according to an embodiment of the present invention
- FIG. 11 illustrates a structure of a first electrode group according to an embodiment of the present invention
- FIG. 12 illustrates a structure of a second electrode group according to an embodiment of the present invention
- FIG. 13 is a schematic view showing a stacked electrode assembly according to an embodiment of the present invention.
- FIG. 14 is a schematic view of a fixing structure of the first electrode group of FIG. 12;
- 15 is a manufacturing process diagram of the first electrode group according to an embodiment of the present invention.
- Figure 4 is a schematic diagram of a punch, a base material and a die for manufacturing a battery case according to an embodiment of the present invention.
- the sheet-like base material 200 is a laminate sheet including a resin layer and a metal layer, and includes a top layer of a first polymer resin, an intermediate layer of a barrier metal, and a bottom layer of a second polymer resin.
- the upper layer of the first polymer resin is heat-sealed with each other during the manufacturing of the battery to provide a sealability.
- the method for manufacturing a battery case using a punch 100 of a shape corresponding to an accommodating part (not shown) in which the electrode assembly may be embedded in the base material 200 first, on the die 300.
- the sheet-like base material 200 is mounted.
- the die 300 is provided with a groove (not shown) in which an inner surface shape corresponding to the shape of the punch 100 is carved. Therefore, an accommodating part (not shown) is formed by pressing the base material 200 using the punch 100.
- the method for forming the accommodating portion comprises using one punch and pressing the punch once against the sheet-like base material to form the accommodating portion. Due to the punch of the novel structure, the receiving portion can be formed without wrinkles and whitening.
- the punch 100 has a stepped structure 110 formed on one side edge on a lower horizontal plane based on the pressing direction (arrow direction).
- the stepped structure 110 may be formed at the center, side, or one edge of the punch.
- the step of applying a vacuum to the die 300 may be further included. More specifically, the space between the sheet-shaped base material 200 and the die 300 may be made in a vacuum state. Therefore, an opening (not shown) may be formed at one side of the groove of the die 300 to remove air from the space between the die 300 and the sheet-like base material 200.
- the sheet-like base material 200 is pressurized by the punch 100 in the above-described manner, and the sheet-like base material 200 is made into a vacuum state between the die 300 and the sheet-like base material 200, so that the sheet-like base material 200 is a groove of the die 300. Will be pulled out.
- the sheet-like base material can more precisely match the shape of the groove of the die 300.
- FIG. 5 is a vertical cross-sectional view of a battery case according to another embodiment of the present invention.
- the battery case 400 includes an accommodating part 410 having a structure indented in an arrow direction, and the accommodating part 410 includes a first step 411, a second step 412, and a first step. It consists of a staircase structure including three steps 413. The heights H1, H2, H3 of the steps 411, 412, 413 become smaller in the direction of the arrow.
- the height H2 of the second step 412 is formed to be 50 to 90% of the height H1 of the first step 411, and the height H3 of the third step 413 is the second step 412. 50% to 90% of the height H2).
- the thickness T1 of the second step 412 is formed to be 90 to 99% of the thickness T1 of the first step 411, and the thickness T3 of the third step 413 is the second step. 90-99% of the thickness T2 of 412. Therefore, since the thickness of the side wall of the housing 410 is formed to be relatively constant, it is possible to ensure the overall durability of the battery case 400.
- FIG. 6 is a schematic view illustrating a battery case manufacturing process according to still another embodiment of the present invention, and FIGS. 7 and 8 are partially enlarged views of FIG. 6.
- three steps of drawing processes 510, 520, and 530 are performed to manufacture the battery case 542 having three steps.
- three punches 511, 521, and 531 corresponding to each of the three steps may be fixed die 501.
- the fixed die 501 has an indentation formed in the shape of a stepped structure having a top, a middle portion, and a bottom.
- the first punch 511 having the widest width and the lowest height performs the drawing process 510 first.
- the outer surface of the first punch 511 has a shape that matches the shape of the upper end of the fixed die 501. It is then performed in a relatively wide and low height punches order 521-> 531.
- Each of the punches 521 and 531 performed after the first drawing process 510 may have a shape that matches not only the step to be formed but also the steps that are already formed. That is, the outer surface of the next punch to be applied after one step is formed coincides with the step to be formed, and the shape also matches the step already formed. In this way, the base material that has already been stretched or deformed to form the step can be re- imprinted in shape by each of the following processes.
- the outer surface of the second punch 521 has a shape that matches not only the top shape of the fixed die 501 but also the interrupted shape, and the outer surface of the third punch 531 is the top, middle, and Consists of a shape that matches all of the bottom shape.
- the drawing processes 510, 520, and 530 which are performed separately for each step, the shape in which the stress is concentrated at each corner of the step may be suppressed as much as possible.
- the method of using the apparatus disclosed in FIG. 6 is as follows.
- the sheet 512 is placed on the fixed die 501.
- the sheet-like base material 512 is pressed between the stationary die 501 and the first punch 511, and is formed to match the shape of the upper end of the staircase structure. Therefore, the sheet-like base material 512 is formed of the sheet-like base material 522.
- the sheet-like base material 522 is pressed between the stationary die 501 and the second punch 521, so as to conform to the shape of the top and the middle of the staircase structure. Therefore, the sheet-like base material 522 is formed of the sheet-like base material 532.
- the sheet-like base material 532 is pressed between the fixed die 501 and the third punch 531, and is formed to match the shape of the top, middle, and bottom of the staircase structure. Therefore, the sheet-like base material 532 is formed of the sheet-like base material 542.
- the accommodating part of the staircase structure is formed in the sheet-like base material 542.
- the edges 502, 503 abutting the sheet for battery case (not shown) among the corners forming the outline of the punches 511, 521, 531 and the fixing die 501. , 504 and 505 are formed in a round shape (R).
- the method of using the device disclosed in FIG. 6 may include applying a vacuum to the fixing device 501 described above in connection with the embodiment disclosed in FIG. 4 above.
- the vacuum can be applied at any stage of the process of pressurizing using different punches. In particular, it can be applied not only to the whole process but also to only one process using a particular punch.
- FIG. 9 is a schematic view of the battery case manufacturing process of FIG.
- three steps of drawing processes 610, 620, and 630 are performed to manufacture the battery case 642 having three steps 710, 720, and 730.
- Three punches 611, 621, and 631 corresponding to each of the three steps 710, 720, and 730 are used in each of the three-step drawing processes 610, 620, and 630.
- the first step 710 is pressed by pressing the sheet-like base material 612 with the first punch 611.
- the battery case 622 is formed.
- the depth D2 pressed by the second punch 621 is 60 to 90% of the depth D1 pressed by the first punch 611.
- the depth D3 pressed by the third punch 631 is 60 to 90% of the depth D2 pressed by the second punch 621.
- the edges contacting the sheet for the battery case may also include a structure formed in a round shape.
- FIG. 10 is a vertical cross-sectional view schematically showing a battery case manufacturing apparatus according to an embodiment of the present invention.
- the battery case manufacturing apparatus 800 includes a second die 820 on which a variable die 830 including a block 821 is mounted, and an agent for pressing a sheet for a battery case (not shown). 1 die 810 is included.
- the first die 810 includes a punching die 813.
- a punch 811 is formed below the punching die 813 in the first die 810 to form an accommodating portion of an electrode assembly (not shown).
- the stripper 814 By sequentially mounting the stripper 814 on which the 812 is formed, the stripper 814 directly presses the sheet for battery case (not shown).
- the second die 820 has a mounting die 824 in which the variable die 830 is mounted and the indentation 825 is formed, and the second die 820 is inserted therein so that the block 821 of the variable die 830 can be inserted therein. It comprises a fixed die 823 formed with an opening 822. Block 821 is formed to correspond to the shape of the punch 811.
- a substantially rectangular indentation 825 is formed in the mounting die 824 of the second die 820, and the indentation 825 is variable in the variable die 830 with respect to the mounting die 824.
- Two through holes 826 are formed into which each mounting shaft 832 of the variable die 830 is inserted so that the motion can be induced. Accordingly, the indentation 825 and the through hole 826 may be mounted so that the variable die 830 may be reciprocated vertically, and the battery case sheet (not shown) may be mounted on the upper surface of the second die 820. Is supplied in one direction.
- variable die 830 can be easily reciprocated in the second die 820.
- corner portions of the punches and dies are shown in a rectangular shape, the punches and dies disclosed in FIG. 10 have rounded corners, as described in FIGS. 7 and 8.
- a sheet for a battery case (not shown) is supplied from the side to the upper surface of the second die 820 of the battery case manufacturing apparatus 800 according to the present invention.
- the first die 810 moves downward toward the second die 820, so that the stripper 814 of the first die 810 adheres and fixes the sheet for the battery case.
- the stripper 814 Prior to punching or sheet formation, the stripper 814 can be moved independently from the first die 810.
- the stiffener 814 may press and secure the sheet between the stationary die 823. Then, by the continuous downward movement of the first die 810, the punch 811 of the punching die 813 is introduced into the second through opening 822 of the fixing die 824 while pressing the sheet for battery case.
- the block die 831 is elastically moved downwardly from the second through opening 822 and the indentation 825 toward the mounting die 824 by the physical downward introduction of the punch 811.
- An accommodating portion is formed in a drawing manner.
- the block die 831 is restored to its original position, whereby the sheet for battery case in which the accommodating portion is formed is extracted from the second die 820.
- the method using the apparatus disclosed in FIG. 10 may include applying the vacuum described above in FIG. 4 to block 821.
- the electrode assembly is composed of a positive electrode, a cathode and a separator disposed between them, and consists of a structure that is welded to the two electrode terminals of the protruding.
- the plurality of electrodes may be formed in a plate shape, and the plate-shaped electrodes may be stacked along a central axis of the electrode assembly.
- the asymmetrical structure with respect to the central axis may be formed on at least one surface that forms the outer circumferential surface of the electrode assembly.
- the surface area of each plate-shaped electrode of the electrode assembly may be defined as the surface area on a horizontal plane perpendicular to the central axis.
- One surface area of the plate-shaped electrodes may be smaller than the surface area of the other plate-shaped electrodes.
- the electrode assembly may be jelly-rolled or stacked, but is not particularly limited.
- the stacked electrode assembly may include a first electrode group having a structure in which any one of a positive electrode plate and a negative electrode plate is interposed between the separator plates, and the positive electrode plate, the negative electrode plate, and the separator plates are laminated in a stacked state. have.
- the stacked electrode assembly may include a second electrode group which is laminated in a state in which a positive electrode plate, a negative electrode plate, and a separator plate are laminated so that the separator plates constitute an outermost part.
- the first electrode group may have a structure in which a cathode plate, a separator plate, a cathode plate, and a separator plate are sequentially stacked in a stacked state, or a cathode plate, separator plate, a cathode plate, and a separator plate are sequentially stacked. It may be a structure.
- only the first electrode groups may be stacked.
- the stack type electrode assembly may include a third unit cell that is joined in a state in which a positive electrode plate, a negative electrode plate, and a separator plate are laminated so that the positive electrode plate and the negative electrode plate constitute an outermost part and the separator plate is interposed between the positive electrode plate and the negative electrode plate.
- the stacked electrode group may include a fourth electrode group which is joined in a state in which any one of the positive electrode plate and the negative electrode plate and one separator plate are stacked.
- the stacked electrode group may have a structure in which only the first electrode groups are stacked, a structure in which only the second electrode group is stacked, a structure in which only the third electrode groups are stacked, or a fourth electrode group. Only these may be a laminated structure, or a combination thereof may be used.
- the second electrode group may be stacked on the uppermost or lowermost end of the first electrode group.
- any one of a positive electrode plate and a negative electrode plate may be interposed between the second electrode groups.
- Fixing members may be further added to the first to fourth electrode groups to further secure the stack structure of the positive electrode plate, the separator plate, and the negative electrode plate.
- the fixing member may be an outer member separate from the first to fourth electrode groups, and may be an adhesive tape or an adhesive tape covering part or all of the outer circumferential surface of the electrode groups.
- the outer circumferential surface of the electrode group may be a concept including all of the side, the plane, the front side, and the rear side of the electrode group.
- the fixing member may be a part of the separator constituting the first electrode group to the fourth electrode group, and in this case, the first electrode group to the fourth electrode group may be fixed by thermally fusion bonding the ends of the separator plate.
- the first electrode group to the fourth electrode group may be fixed by thermally fusion bonding the ends of the separator plate.
- it is not limited thereto.
- the ends of the separating plate may extend longer than the size of the positive electrode plate and the negative electrode plate, that is, the length or length.
- the ends of the elongated separator plates may be thermally fused to each other.
- the fixing member includes all members capable of functioning to fix the first to fourth electrode groups.
- the stacked electrode assembly including the first electrode group and the second electrode group
- mass productivity and yield can be improved compared to the stacked electrode assembly having a structure in which a positive electrode plate, a negative electrode plate, and a separator plate are simply stacked. have.
- the positive electrode plate, the separator plate, and the negative electrode plate are bonded to each other by the first electrode group, there is an advantage of minimizing volume expansion due to swelling.
- the stacked electrode assembly including the first electrode group and the second electrode group
- an alignment defect or processing equipment of the electrode assembly implemented by the folding process is removed, and only one laminator is used to remove the first electrode group.
- the electrode damage generated during the folding process can be reduced, the electrolyte wettability can be improved, and the separator is exposed to the outside. Since it is possible to apply a single-sided organic-inorganic composite separator (SRS separator) it is possible to reduce the thickness of the cell and at the same time reduce the process cost.
- SRS separator single-sided organic-inorganic composite separator
- the first electrode group has a structure in which a separator plate 310, a cathode plate 320, a separator plate 330, and a cathode plate 340 are laminated in a stacked state.
- the second electrode group has a structure in which the separator 410, the cathode plate 420, and the separator 430 are laminated in a stacked state.
- FIG. 13 illustrates a stacked electrode assembly having a structure in which the second electrode group of FIG. 12 is stacked on the top of the first electrode group stack in which the first electrode groups of FIG. 11 are stacked.
- FIG. 14 illustrates an embodiment in which a fixing member is further added to the first electrode group of FIG. 11. Specifically, the fixing member T1 is further added to the side surface or the front surface of the first electrode group 300.
- fixing may be performed by using a separate member on the side of the stacked structure, and the fixing member may include the first electrode as shown in FIG.
- the front surface of the group 300 may be implemented by taping, or as shown in 14 (b), it may be implemented by a fixing member (T2) for fixing only the side of the first electrode group (300).
- 15 is a process schematic diagram illustrating a manufacturing process of the first electrode group according to the present invention.
- the material of the separator 310, the anode plate 320, the separator 330, and the cathode plate 340 (using a loading unit loaded in a sheet-like structure) is simultaneously loaded and used as an intermediate layer (
- the cutting plate 320 is cut into a designed size, and then the separator plates 310 and 330 disposed at the top and the bottom thereof are simultaneously loaded, and the negative plate 340 material is loaded together with the laminators L1 and L2.
- the laminator implements a structure in which two electrode plates and two separation plates are bonded to each other by heat and pressure, that is, a first electrode group, and then cuts through a cutter C3 to complete the first electrode group, and then inspects the thickness (a). Inspection process, such as vision inspection (b), short inspection (c) may be further performed.
- the first electrode group thus formed is fixed using a fixing member, or formed into a structure in which a plurality of first electrode groups are stacked by stacking, and then, the second electrode group of FIG. 12 is stacked and through the fixing member.
- the fixing process is to complete the stacked electrode assembly.
- the number of electrode groups having different plane sizes included in the electrode assembly can be flexibly adjusted by the person skilled in the art according to the shape and required capacity of the device on which the electrode group is mounted.
- the electrode assembly composed of two to three electrode groups, as well as the electrode assembly consisting of four or more electrode groups may be configured.
- the one or more corners and / or the surface forming the shape of the housing is deformed to form a stepped structure, corresponding to the storage of the electrode assembly of various shapes It is possible to provide a battery case including a portion, thereby maximally improving the capacity per device volume.
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Abstract
Description
Claims (23)
- 전극조립체가 내장될 수 있는 수납부를 포함하고 있고, 시트형 모재의 변형으로 형성된 상기 수납부는 수납부의 형상을 이루는 하나 이상의 모서리 및/또는 면이 변형되어 계단형 구조를 이루고 있는 것을 특징으로 하는 전지케이스.
- 제 1 항에 있어서, 상기 모재는 수지층과 금속층을 포함하는 라미네이트 시트로 이루어진 것을 특징으로 하는 전지케이스.
- 제 2 항에 있어서, 상기 모재는 제 1 고분자 수지의 상층, 차단성 금속의 중간층, 및 제 2 고분자 수지의 하층으로 이루어진 것을 특징으로 하는 전지케이스.
- 제 1 항에 있어서, 상기 모재의 두께는 0.3 내지 6 mm의 범위인 것을 특징으로 하는 전지케이스.
- 제 1 항에 있어서, 상기 수납부의 측벽은 적어도 둘 이상의 단차들(steps)을 포함하는 계단 구조로 이루어져 있으며, 상기 단차들의 높이는 수납부의 깊이 방향으로 깊어질수록 작아지는 것을 특징으로 하는 전지케이스.
- 제 5 항에 있어서, 상기 계단 구조가 n개의 단차들을 포함하고 있을 때, 제 n 단차는 수납부의 깊이 방향에서 최하단에 위치하고 제 n 단차의 상부에 제 n-1 단차가 위치하며, 제 n 단차의 높이는 제 n-1 단차의 높이 보다 작은 것을 특징으로 하는 전지케이스.
- 제 6 항에 있어서, 상기 제 n 단차의 높이는 제 n-1 단차의 높이의 50 내지 90%인 것을 특징으로 하는 전지케이스.
- 제 6 항에 있어서, 상기 제 n 단차 부위에서 수납부 측벽의 두께는 제 n-1 단차 부위에서 수납부 측벽의 두께의 90 내지 99%인 것을 특징으로 하는 전지케이스.
- 제 1 항 내지 제 8 항 중 어느 하나에 따른 전지케이스에 전극조립체를 내장하는 전지셀을 제조하는 방법으로서,(a) 시트형 모재를 홈이 형성되어 있는 다이 상에 위치시키는 단계;(b) 상기 시트형 모재로부터 형성되는 수납부의 모서리에 주름 및 백화 현상이 없도록, 외면이 비대칭 구조로 이루어져 있는 펀치를 이용하여, 상기 시트형 모재를 상기 모재의 홈으로 가압하는 단계;(c) 전극조립체를 상기 수납부에 장착하는 단계; 및(d) 상기 수납부에 덮개를 덮어 밀봉하는 단계;를 포함하고,상기 다이의 홈은, 시트형 모재가 펀치 및 다이의 홈과 접촉할 때 시트형 모재가 펀치의 외면 형상과 일치할 수 있도록, 펀치의 형상에 대응하는 형상으로 이루어져 있는 것을 특징으로 하는 전지셀 제조 방법.
- 제 9 항에 있어서, 상기 펀치의 하단 수평면 상의 형상은 계단형 구조로 이루어져 있는 것을 특징으로 하는 전지셀 제조 방법.
- 제 10 항에 있어서, 상기 계단형 구조는 펀치의 하단 수평면 상의 중앙, 일측변, 또는 일측 모서리에 형성되어 있는 것을 특징으로 하는 전지셀 제조 방법.
- 제 9 항에 있어서, 상기 시트형 모재를 다이의 홈에 밀착시킬 수 있도록, 다이와 시트형 모재 사이의 공간을 진공 상태로 만드는 단계를 추가로 포함하는 것을 특징으로 하는 전지셀 제조 방법.
- 제 9 항에 있어서, 상기 다이에는 상단, 중단, 및 하단으로 이루어져 있는 계단형 구조의 만입부가 형성되어 있고;상기 다이의 상단의 형상에 대응하는 제 1 펀치, 상기 다이의 중단의 형상에 대응하는 제 2 펀치, 및 상기 다이의 하단의 형상에 대응하는 제 3 펀치를 포함하는 것을 특징으로 하는 전지셀 제조 방법.
- 제 13 항에 있어서, 상기 제 2 펀치는 상기 다이의 상단 및 중단의 형상에 대응하는 형상으로 이루어져 있고, 상기 제 3 펀치는 다이의 상단, 중단, 및 하단의 형상에 대응하는 형상으로 이루어져 있는 것을 특징으로 하는 전지셀 제조 방법.
- 제 14 항에 있어서,(i) 상기 다이의 상단의 형상이 전사될 수 있도록 제 1 펀치로 시트형 모재를 가압하는 단계;(ii) 상기 다이의 상단 및 중단의 형상이 전사될 수 있도록 제 2 펀치로 시트형 모재를 가압하는 단계; 및(iii) 상기 다이의 상단, 중단, 및 하단의 형상이 전사될 수 있도록 제 3 펀치로 시트형 모재를 가압하는 단계;를 추가로 포함하는 것을 특징으로 하는 전지셀 제조 방법.
- 제 15 항에 있어서, 상기 시트형 모재를 다이의 홈에 밀착시킬 수 있도록, 다이와 시트형 모재 사이의 공간을 진공 상태로 만드는 단계를 추가로 포함하는 것을 특징으로 하는 전지셀 제조 방법.
- 제 9 항에 있어서, 상기 펀치의 외면과 다이의 내면을 이루고 있는 모서리들은 둥근 형태로 형성되어 있는 것을 특징으로 하는 전지셀 제조 방법.
- 제 9 항에 있어서, 상기 펀치는 각기 다른 폭과 높이를 갖는 둘 이상의 펀치들로 이루어져 있고, 상기 다이는 펀치들 각각에 대응하는 형상의 단차로 이루어져 있는 계단형 내면 구조를 가지며, 상기 수납부는 펀치와 다이에 의해 계단형 구조로 변형되면서 형성되는 것을 특징으로 하는 전지셀 제조 방법.
- 제 18 항에 있어서, 상기 수납부의 계단형 구조는, 둘 이상의 펀치들 중에서 폭이 가장 넓은 펀치에 의해 가압을 수행한 후, 상대적으로 폭이 작아지는 펀치들의 순으로 가압을 각각 수행하여 형성되는 것을 특징으로 하는 전지셀 제조 방법.
- 제 19 항에 있어서, 상대적으로 폭이 작아지는 펀치들의 순으로 가압할수록, 가압 깊이가 작아지는 것을 특징으로 하는 전지셀 제조 방법.
- 제 20 항에 있어서, 상기 펀치가 n 개로 이루어져 있을 때, 제 n 펀치에 의한 가압 깊이는 제 n-1 펀치에 의한 가압 깊이의 60 내지 90%인 것을 특징으로 하는 전지셀 제조 방법.
- 제 21 항에 있어서, 상기 펀치의 외면과 다이의 내면을 이루고 있는 모서리들은 둥근 형태로 형성되어 있는 것을 특징으로 하는 전지셀 제조 방법.
- 제 1 항 내지 제 9 항 중 어느 하나에 따른 전지케이스를 제조하는 장치로서,전지케이스용 시트를 가압하는 펀치가 하면에 장착되어 있는 펀칭 다이, 및 드로잉 가공 과정에서 하기 고정 다이와의 사이에 전지케이스용 시트를 고정하는 스트리퍼를 포함하는 제 1 다이; 및상기 펀치에 대응하는 블록이 상면에 장착되어 있는 블록 다이, 상기 스트리퍼와의 사이에 전지케이스용 시트를 고정하는 고정 다이, 및 상기 블록 다이가 가변적으로 장착되는 만입부가 형성되어 있는 장착 다이를 포함하는 제 2 다이;를 포함하는 것을 특징으로 하는 전지케이스 제조 장치.
Priority Applications (6)
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CN201380009696.8A CN104303330B (zh) | 2012-03-23 | 2013-03-15 | 用于二次电池的电池壳体 |
US13/839,783 US20130252081A1 (en) | 2012-03-23 | 2013-03-15 | Battery case for secondary battery |
JP2014558690A JP5908128B2 (ja) | 2012-03-23 | 2013-03-15 | 二次電池用電池ケース |
EP13764010.8A EP2802023B1 (en) | 2012-03-23 | 2013-03-15 | Battery case for secondary battery |
US14/315,023 US9716253B2 (en) | 2012-03-23 | 2014-06-25 | Battery case for secondary battery |
US14/315,006 US9531032B2 (en) | 2012-03-23 | 2014-06-25 | Battery case for secondary battery |
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KR1020120029643A KR101192619B1 (ko) | 2012-03-23 | 2012-03-23 | 전지케이스 |
KR10-2012-0029643 | 2012-03-23 |
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US13/839,783 Continuation US20130252081A1 (en) | 2012-03-23 | 2013-03-15 | Battery case for secondary battery |
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WO2013141527A1 true WO2013141527A1 (ko) | 2013-09-26 |
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US (1) | US9531032B2 (ko) |
EP (1) | EP2802023B1 (ko) |
JP (1) | JP5908128B2 (ko) |
KR (1) | KR101192619B1 (ko) |
CN (1) | CN104303330B (ko) |
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JP2015531988A (ja) * | 2013-09-27 | 2015-11-05 | エルジー・ケム・リミテッド | 二次電池用単位体積層装置及び積層方法 |
EP4039438A4 (en) * | 2019-11-26 | 2022-12-14 | LG Energy Solution, Ltd. | POCKET-TYPE HOUSING MOLDING APPARATUS AND POCKET-TYPE HOUSING MANUFACTURING METHOD USING THE SAME |
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EP2802023A1 (en) | 2014-11-12 |
JP2015511388A (ja) | 2015-04-16 |
KR101192619B1 (ko) | 2012-10-18 |
JP5908128B2 (ja) | 2016-04-26 |
EP2802023A4 (en) | 2015-09-30 |
CN104303330A (zh) | 2015-01-21 |
US9531032B2 (en) | 2016-12-27 |
US20140304980A1 (en) | 2014-10-16 |
CN104303330B (zh) | 2018-03-23 |
EP2802023B1 (en) | 2017-02-08 |
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