WO2013141448A1 - Liquid dispensing device - Google Patents
Liquid dispensing device Download PDFInfo
- Publication number
- WO2013141448A1 WO2013141448A1 PCT/KR2012/006138 KR2012006138W WO2013141448A1 WO 2013141448 A1 WO2013141448 A1 WO 2013141448A1 KR 2012006138 W KR2012006138 W KR 2012006138W WO 2013141448 A1 WO2013141448 A1 WO 2013141448A1
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- WIPO (PCT)
- Prior art keywords
- unit
- liquid
- disposed
- dispensing
- housing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/008—Liquid distribution
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/32—Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/141—Fractional distillation or use of a fractionation or rectification column where at least one distillation column contains at least one dividing wall
Definitions
- the present invention relates to a liquid dispensing apparatus, and more particularly, to a liquid dispensing apparatus which is disposed inside the distillation column and can be continuously supplied after precisely adjusting the supply ratio of the liquid.
- a liquid distributor is a liquid distributor used in petroleum refining, petrochemical and fine chemicals, washing towers and absorption towers based on distillation, absorption, and cooling for the removal of harmful gases or organics.
- a device for distillation, absorption, and cooling which is currently used industrially, is a column, which separates a desired substance through gas-liquid contact. Recently, a dividing wall column is used to save energy and reduce investment cost. It is a structure in which two columns are combined into one column, and the liquid at the upper side is distributed to the lower two separation walls at a desired ratio. In this case, the liquid distribution device adjusts the supply ratio of the liquid.
- liquid distribution device was placed outside of the distillation column, a component was needed to connect the distillation column and the liquid distribution device. In addition, space was required for installation of the liquid dispensing apparatus.
- the present invention has been made to solve the above problems, and an object thereof is to provide a liquid dispensing apparatus in which a configuration for dispensing liquid can be disposed inside the distillation column, whereby the overall installation space can be reduced.
- the present invention is a housing disposed inside the distillation column; Upper and lower grids arranged in the upper and lower portions of the housing, respectively; A collector tray disposed at an inner upper portion of the housing and configured to guide liquid introduced through the upper grid; A porous plate disposed on the collector tray and having a plurality of through holes for lowering the induced liquid; Dispensing is disposed in the lower portion of the porous plate and distributes the liquid lowered through the porous plate to the outside of the housing through the outlet pipe connected to both sides; A liquid distributor disposed at a lower portion of the distribution box to uniformly distribute the liquid dispensed in the distribution box to the lower side; A connecting tube connecting the dispensing box and the liquid dispensing to allow fluid movement; An inlet pipe through which liquid is introduced into the liquid distribution part from the outside of the housing; And a partition wall disposed vertically under the housing to divide the lower space of the housing into the first and second chambers.
- the collector tray may include a body plate, a plurality of risers formed through the body plate to facilitate gas movement between the upper and lower parts of the body plate, and inclined toward the porous plate on the upper portion of the riser. It may include a hat to prevent the liquid introduced through the upper grid to enter the riser.
- ' ⁇ ' may further include a sump (sump) connecting the body plate and the porous plate.
- the distribution box has a rectangular parallelepiped shape, an upper portion of which is open, a first unit partition wall disposed inside the box body to separate the inside of the box body into first and second unit chambers, It may include a second unit partition wall connecting the one unit partition wall and the inner wall of the box body to form a unit separation space.
- the height of the first unit partition wall may be lower than the height of the box body, and the height of the second unit partition wall may be lower than the height of the first unit partition wall.
- the first and second unit partitions may be disposed to be symmetrical to both inner ends of the box body.
- the outflow pipe may be connected to outflow the liquid on the unit separation space to the outside, and the outflow pipe may be connected to the inflow pipe so that the outflow liquid flows into the liquid distribution unit.
- the liquid dispensing unit is formed in a hexahedral shape and is opened up and down to be symmetrical with each other in the first and second chambers, and a plurality of dispensing units are arranged in both sides of the first unit dispensing unit. And a second unit dispensing unit which is always connected to the first unit dispensing unit and the liquid movement.
- the connecting pipe may connect the first unit distribution unit and the lower part of the first and second unit chambers.
- the configuration of the liquid dispensing apparatus for dispensing liquid can be arranged inside the distillation column can reduce the overall installation space.
- FIG. 1 is a perspective view showing the configuration of a liquid dispensing apparatus according to an embodiment of the present invention.
- FIG. 2 is a perspective view illustrating the configuration of the porous plate illustrated in FIG. 1 in more detail.
- FIG. 3 is a perspective view showing the configuration of the distribution box shown in FIG.
- FIG. 1 is a perspective view showing the configuration of a liquid dispensing apparatus according to an embodiment of the present invention.
- the liquid dispensing apparatus 100 includes a housing 110, upper and lower grids 120A and 120B, a collector tray 130, a porous plate 150, and a dispensing box. 160, liquid distributor 170, and separation wall 190.
- a distillation column to which the present invention is applied is a device for separating a desired substance through gas-liquid contact, and thus a detailed description thereof will be omitted.
- the housing 110 is disposed inside the distillation column, so that the other components in the distillation column and the components described below are isolated from each other.
- the housing 110 is configured in a substantially cylindrical shape, but may be formed in various forms according to the needs of the user.
- Upper and lower grids 120A and 120B are disposed at inner upper and lower ends of the housing 110, respectively.
- the upper and lower grids 120A, 120B are fabricated in a grid shape. At this time, the grid shape and the arrangement state of the upper and lower grids (120A, 120B) can be variously set according to the needs of the user.
- the upper and lower grids 120A and 120B are fixedly disposed at the inner upper and lower ends of the housing 110, respectively.
- the upper and lower grids 120A and 120B are preferably shaped to correspond to the inner shape of the housing 110.
- a packing bed (not shown) filled with a packing at a predetermined height may be disposed above the upper grid 120A and below the lower grid 120B.
- the upper grid 120A and the lower grid 120B may serve to fix and support a packing bed disposed at the upper and lower portions, respectively.
- the collector tray 130 is disposed at the lower end of the upper grid 120A.
- the collector tray 130 is a component that collects liquid for liquid distribution for the purpose of side-draw.
- the collector tray 130 is formed in a form corresponding to the inner shape of the housing 110. In this embodiment, since the housing 110 is cylindrical, the collector tray 130 is preferably circular.
- the collector tray 130 is spaced apart at a predetermined distance from the body plate 132 formed in a circular shape in a plate shape, a plurality of risers 134 and the riser 134 disposed on the body plate 132.
- the body plate 132 is circular, and the porous plate 150 described later is disposed in the center.
- a plurality of risers 134 and hats 136 are disposed on both sides of the porous plate 150.
- the riser 134 is formed to penetrate the gas on the body plate 132. That is, the riser 134 is a component that allows the air between the upper and lower parts of the main body plate 132 to move smoothly, and may uniformize the pressures of the upper and lower parts of the main body plate 132.
- the riser 134 is formed in a rectangular shape, but may be formed in other shapes such as a circle or a square according to a user's needs.
- the gas can be moved through the riser 134, when the liquid descends through the porous plate 150, which will be described later, the gas under the porous plate 150 rises through the riser 134 and the pressure inside the housing 110. This is uniformly adjusted throughout.
- the riser 134 is preferably formed to a predetermined height in order to prevent the liquid introduced from the upper portion to pass.
- the hat 136 is disposed above the riser 134.
- the hat 136 prevents liquid flowing through the upper grid 120A from descending through the riser 134.
- the hat 136 is disposed to be inclined toward the porous plate 150 to be described later to allow the liquid introduced through the upper grid 120A to move toward the porous plate 150 to be described later.
- a sump 140 is disposed at the center of the collector tray 130.
- the sump 140 is formed in a cross-sectional shape of ' ⁇ ' to collect the liquid lowered to the collector tray 130.
- the sump 140 extends from one side of the collector tray 130 to the other side through the center.
- the jaw having a predetermined height is formed at the connection portion between the body plate 132 and the sump 140, and when the liquid introduced through the upper grid 120A reaches a predetermined amount, the jaw moves through the upper portion of the jaw.
- the height of the jaw is preferably formed lower than the height of the hat (136). However, the jaw may not be formed depending on the needs of the user.
- Both ends of the sump 140 may be provided with a reinforcing bar 142 for the connection of the porous plate 150 to be described later.
- the porous plate 150 is disposed at the lower end of the sump 140.
- FIG. 2 is a perspective view showing the configuration of the porous plate 150 shown in FIG. 1 in more detail.
- the porous plate 150 may collect liquid guided by risers and hats on both sides of the porous plate 150.
- the porous plate 150 is in the form of a rectangular plate, and a plurality of holes 152 are formed.
- the size and arrangement of the hole 152 may be changed according to the user's needs (dispensing ratio and flow rate to be applied by the user).
- the porous plate 150 is disposed on the lower end side of the sump 140, but may be disposed directly on the body plate 132 without the arrangement of the sump 140.
- the distribution box 160 is disposed below the porous plate 150.
- FIG. 3 is a perspective view showing the configuration of the distribution box 160 shown in FIG.
- the distribution box 160 is a rectangular parallelepiped shape having a predetermined size, the upper portion is preferably an open form.
- the liquid supplied through the hole 152 may be introduced through an open portion of the upper portion of the distribution box 160.
- the size of the distribution box 160 may be changed according to a user's needs, the size of the distribution box 160 may be such that the liquid supplied through the hole 152 on the porous plate 150 may be collected without loss.
- a plurality of unit partitions are disposed at the inner center of the distribution box 160.
- first and second unit partitions 162A and 162B having different heights and shapes are disposed inside the distribution box 160.
- the first unit partition wall 162A has a substantially ' ⁇ ' shape, and both ends thereof are disposed to contact both inner walls of the distribution box 160.
- the interior of the distribution box 160 may be divided into first and second unit chambers 164A and 164B by the first unit partition wall 162A.
- the height of the first unit partition wall 162A is preferably lower than the height of the distribution box 160.
- One end of the second unit partition wall 162B is connected to the outer side of the bent portion of the first unit partition wall 162A, and the other end is in contact with the inner wall of the distribution box 160.
- the height of the second unit partition wall 162B is preferably lower than the height of the first unit partition wall 162A.
- the heights of the first and second unit partitions 162A and 162B may be reversed as necessary.
- the first and second unit partitions 162A and 162B are disposed in a substantially 'H' shape inside the distribution box 160.
- first and second unit partitions 162A and 162B are disposed, but the number and shape of the unit partitions may be changed according to the needs of the user.
- the outlet pipe 164 On both sides of the distribution box 160 is connected to the outlet pipe 164 for discharging the dispensed liquid to the outside. That is, the outlet pipe 164 allows the liquid located in the space formed between the first unit partition 162A and the second unit partition 162B to flow out of the housing 110.
- the outlet pipe 164 is preferably provided with a valve (not shown) that can control the outflow of the liquid. Accordingly, when the valve is closed, the liquid overflows through the upper end of the first unit partition 162A to both inner sides of the distribution box 160, that is, the first and second unit chambers 164A and 164B.
- outlet pipe 164 is connected to the inlet pipe 166, it is preferable to be able to dispense within the housing 110 without consuming the spilled liquid.
- Connection pipes 168 are respectively connected to lower portions of both sides of the distribution box 160, that is, lower portions of the first and second unit chambers 164A and 164B to move the liquid to the liquid distributor 170, which will be described later.
- two connecting pipes 168 are respectively connected to one end of the distribution box 160, but the number of connections may be changed according to the needs of the user.
- the partition wall 190 bisects the space inside the lower portion of the housing 110.
- the separating wall 190 is a plate shape having a predetermined size, it is preferably disposed on the central axis of the housing 110.
- the partition wall 190 may be disposed to be eccentric.
- the dividing wall 190 may divide the lower grid 120B.
- the liquid distributor 170 is disposed below the dispensing box 160.
- the liquid distributor 170 evenly distributes the liquid dispensed at a predetermined ratio in the dispensing box 160 to a packing bed under the housing 110.
- the liquid distributors 170 are disposed in the spaces separated by the separating walls 190 which are disposed vertically at the inner lower center of the housing 110.
- the liquid distributor 170 has an upper side and a lower side, and is symmetrical to both sides of the first unit dispensing unit 172 and the first unit dispensing unit 172 which are formed in a hexahedron shape having a predetermined width, length, and height. And a second unit dispensing unit 174 in which a plurality are disposed.
- the first unit distribution units 172 are disposed in the spaces separated by the partition walls 190, respectively, and are disposed in a direction orthogonal to the partition walls 190.
- the second unit distribution unit 174 is disposed on both sides of the first unit distribution unit 172.
- the second unit distribution unit 174 is movably connected to the first unit distribution unit 172 and the liquid.
- the second unit distribution unit 174 is preferably arranged in a symmetrical form.
- the second unit distribution unit 174 is preferably disposed at a position higher than the lower grid 120B.
- the liquid (reflux) discharged from the distillation column is introduced into the housing 110 through the packing bed on the upper side and the upper grid 120A.
- the introduced liquid diffuses through the upper surface of the collector tray 130.
- the liquid lowered into the dispensing box 160 moves from the first and second unit chambers 164A and 164B to the liquid distributor 170 through the connecting pipe 168.
- the liquid lowered into the distribution box 160 flows into the space between the first unit partition 162A and the second unit partition 162B through the upper end of the second unit partition 162B, and then the outlet pipe ( 164 is discharged to the outside.
- the discharge of the liquid can be controlled by controlling the opening and closing of the valve on the outlet pipe 164.
- the liquid discharged to the outside through the outlet pipe 164 the liquid may be introduced through the inlet pipe 166.
- the liquid introduced through the inlet pipe 164 and the liquid introduced through the connecting pipe 168 are positioned on the first unit distribution unit 172 and the second unit distribution unit 174.
- the liquid on the first unit dispensing unit 172 and the second unit dispensing unit 174 descends through the lower grid 120B to the lower packing bed.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Devices For Dispensing Beverages (AREA)
Abstract
Description
Claims (10)
- 증류 컬럼 내부에 배치되는 하우징; A housing disposed inside the distillation column;상기 하우징의 상부와 하부 내측에 각각 배치되는 격자 형태의 상부 및 하부 그리드; Upper and lower grids arranged in the upper and lower portions of the housing, respectively;상기 하우징의 내측 상부에 배치되고 상기 상부 그리드를 통해 유입된 액체를 유도하는 콜렉터 트레이;A collector tray disposed at an inner upper portion of the housing and configured to guide liquid introduced through the upper grid;상기 콜렉터 트레이 상에 배치되고 상기 유도된 액체를 하강시키는 복수개의 통공이 형성되는 다공판;A porous plate disposed on the collector tray and having a plurality of through holes for lowering the induced liquid;상기 다공판의 하부에 배치되고 상기 다공판을 통해 하강한 액체를 양측으로 연결된 유출관을 통해 상기 하우징 외부로 분배하는 분배함; Dispensing is disposed in the lower portion of the porous plate and distributes the liquid lowered through the porous plate to the outside of the housing through the outlet pipe connected to both sides;상기 분배함의 하부에 배치되어 상기 분배함에서 분배된 액체를 하부측으로 균일하게 분배하여 배출하는 액체 분배부; A liquid distributor disposed at a lower portion of the distribution box to uniformly distribute the liquid dispensed in the distribution box to the lower side;상기 분배함 및 액체 분배부 간의 유체 이동이 가능하도록 연결하는 연결관; A connecting tube connecting the dispensing box and the liquid dispensing to allow fluid movement;상기 하우징의 외부에서 상기 액체 분배부로 액체가 유입되도록 하는 유입관; 및An inlet pipe through which liquid is introduced into the liquid distribution part from the outside of the housing; And상기 하우징의 하부에 수직으로 배치되어 상기 하우징의 하부 공간을 제1 및 제2 챔버로 양분하는 분리벽을 포함하는 액체 분배장치. And a dividing wall disposed vertically under the housing to divide the lower space of the housing into the first and second chambers.
- 제1항에 있어서, The method of claim 1,상기 콜렉터 트레이는,The collector tray,본체 플레이트와, With body plate,상기 본체 플레이트 상에서 상기 본체 플레이트 상부와 하부간의 기체 이동이 용이하도록 관통 형성되는 복수개의 라이저(riser)와,A plurality of risers formed through the body plate to facilitate gas movement between the upper and lower parts of the body plate;상기 라이저의 상부에 상기 다공판을 향하여 경사지게 배치되고 상기 상부 그리드를 통해 유입된 액체가 상기 라이저로 유입되는 것을 방지하는 햇(hat)을 포함하는 액체 분배장치.And a hat disposed at an upper portion of the riser toward the perforated plate and preventing a liquid introduced through the upper grid from entering the riser.
- 제2항에 있어서, The method of claim 2,'└┘'의 단면 형태로 형성되고 상기 본체 플레이트와 상기 다공판을 연결하는 섬프(sump)를 더 포함하는 액체 분배장치.It is formed in the cross-sectional shape of └┘ and further comprises a sump (sump) connecting the body plate and the porous plate.
- 제1항에 있어서, The method of claim 1,상기 분배함은,The distribution box,직육면체 형태이고, 상부는 개방 형성되는 박스 본체와, A box body having a rectangular parallelepiped shape, and having an upper portion formed therein;상기 박스 본체의 내측에 배치되어 상기 박스 본체의 내측을 제1 및 제2 단위 챔버로 분리하는 제1 단위 격벽과,A first unit partition wall disposed inside the box body and separating the inside of the box body into first and second unit chambers;상기 제1 단위 격벽과 상기 박스 본체의 내벽을 연결하여 단위 분리 공간을 형성하는 제2 단위 격벽을 포함하는 액체 분배장치. And a second unit partition wall connecting the first unit partition wall and the inner wall of the box body to form a unit separation space.
- 제4항에 있어서, The method of claim 4, wherein상기 제1 단위 격벽의 높이는 상기 박스 본체의 높이보다 낮고, 상기 제2 단위 격벽의 높이는 상기 제1 단위 격벽의 높이보다 낮게 형성되는 액체 분배장치. The height of the first unit partition wall is lower than the height of the box body, the height of the second unit partition wall is formed lower than the height of the first unit partition wall.
- 제5항에 있어서, The method of claim 5,상기 제1 및 제2 단위 격벽은 상기 박스 본체의 내측 양단에 대칭되는 형태로 배치되는 액체 분배장치. The first and second unit partitions are disposed in a symmetrical form on both inner ends of the box body.
- 제4항에 있어서, The method of claim 4, wherein상기 유출관은 상기 단위 분리 공간 상의 액체를 외부로 유출하도록 연결되는 액체 분배장치. The outlet pipe is connected to the liquid outflow device on the unit separation space to the outside.
- 제7항에 있어서, The method of claim 7, wherein상기 유출관은 상기 유출된 액체가 상기 액체 분배부로 유입되도록 상기 유입관에 연결되어 액체 분배장치. The outlet pipe is connected to the inlet pipe so that the outflow of the liquid flows into the liquid distribution unit is a liquid distribution device.
- 제1항에 있어서, The method of claim 1,상기 액체 분배부는 육면체 형태로서 상하로 개방 형성되어 상기 제1 및 제2 챔버에 서로 대칭되는 형태로 배치되는 제1 단위 분배 유닛과, The liquid dispensing unit is a hexahedral shape of the first unit dispensing unit which is open up and down and arranged in a symmetrical form in the first and second chambers,상기 제1 단위 분배 유닛의 양측으로 대칭되는 형태로서 복수개가 배치되고 상시 제1 단위 분배 유닛과 액체 이동이 가능하게 연결되는 제2 단위 분배 유닛을 포함하는 액체 분배장치.And a second unit dispensing unit disposed in a symmetrical form on both sides of the first unit dispensing unit, the second unit dispensing unit being movably connected to the first unit dispensing unit at all times.
- 제4항 또는 제9항에 있어서, The method according to claim 4 or 9,상기 연결관은 상기 제1 단위 분배 유닛과 상기 1 및 제2 단위 챔버의 하부를 연결하는 액체 분배장치.The connecting pipe connects the first unit dispensing unit and a lower portion of the first and second unit chambers.
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU2014142788/05A RU2601325C2 (en) | 2012-03-23 | 2012-08-01 | Liquid distribution device |
MX2014011448A MX2014011448A (en) | 2012-03-23 | 2012-08-01 | Liquid dispensing device. |
JP2015503088A JP6207031B2 (en) | 2012-03-23 | 2012-08-01 | Liquid dispensing device |
CA2868352A CA2868352C (en) | 2012-03-23 | 2012-08-01 | Liquid dispensing device |
US14/387,251 US9950272B2 (en) | 2012-03-23 | 2012-08-01 | Liquid dispensing device |
CN201280071737.1A CN104203361B (en) | 2012-03-23 | 2012-08-01 | Liquid dispensing apparatus |
EP12871946.5A EP2829308B1 (en) | 2012-03-23 | 2012-08-01 | Liquid dispensing device |
AU2012374201A AU2012374201B2 (en) | 2012-03-23 | 2012-08-01 | Liquid dispensing device |
SG11201405959VA SG11201405959VA (en) | 2012-03-23 | 2012-08-01 | Liquid dispensing device |
IN8565DEN2014 IN2014DN08565A (en) | 2012-03-23 | 2012-08-01 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2012-0030223 | 2012-03-23 | ||
KR20120030223A KR101351637B1 (en) | 2012-03-23 | 2012-03-23 | Liquid Splitter |
Publications (1)
Publication Number | Publication Date |
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WO2013141448A1 true WO2013141448A1 (en) | 2013-09-26 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/KR2012/006138 WO2013141448A1 (en) | 2012-03-23 | 2012-08-01 | Liquid dispensing device |
Country Status (13)
Country | Link |
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US (1) | US9950272B2 (en) |
EP (1) | EP2829308B1 (en) |
JP (1) | JP6207031B2 (en) |
KR (1) | KR101351637B1 (en) |
CN (1) | CN104203361B (en) |
AU (1) | AU2012374201B2 (en) |
CA (1) | CA2868352C (en) |
IN (1) | IN2014DN08565A (en) |
MX (1) | MX2014011448A (en) |
MY (1) | MY171252A (en) |
RU (1) | RU2601325C2 (en) |
SG (1) | SG11201405959VA (en) |
WO (1) | WO2013141448A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104118917A (en) * | 2014-07-08 | 2014-10-29 | 李庆权 | Distilled water pot |
US9950272B2 (en) | 2012-03-23 | 2018-04-24 | Amtpacific Co., Ltd. | Liquid dispensing device |
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- 2012-08-01 CN CN201280071737.1A patent/CN104203361B/en active Active
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Also Published As
Publication number | Publication date |
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CN104203361B (en) | 2016-03-16 |
MY171252A (en) | 2019-10-05 |
SG11201405959VA (en) | 2014-11-27 |
JP6207031B2 (en) | 2017-10-04 |
AU2012374201A1 (en) | 2014-11-06 |
EP2829308B1 (en) | 2017-12-06 |
IN2014DN08565A (en) | 2015-05-22 |
RU2014142788A (en) | 2016-05-20 |
US9950272B2 (en) | 2018-04-24 |
KR20130107987A (en) | 2013-10-02 |
KR101351637B1 (en) | 2014-01-16 |
EP2829308A4 (en) | 2016-01-13 |
EP2829308A1 (en) | 2015-01-28 |
MX2014011448A (en) | 2015-03-03 |
RU2601325C2 (en) | 2016-11-10 |
US20150122630A1 (en) | 2015-05-07 |
AU2012374201B2 (en) | 2015-09-03 |
CN104203361A (en) | 2014-12-10 |
CA2868352A1 (en) | 2013-09-26 |
JP2015514571A (en) | 2015-05-21 |
CA2868352C (en) | 2016-11-29 |
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