WO2013113541A1 - A composition and method for treating substrates - Google Patents

A composition and method for treating substrates Download PDF

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Publication number
WO2013113541A1
WO2013113541A1 PCT/EP2013/050546 EP2013050546W WO2013113541A1 WO 2013113541 A1 WO2013113541 A1 WO 2013113541A1 EP 2013050546 W EP2013050546 W EP 2013050546W WO 2013113541 A1 WO2013113541 A1 WO 2013113541A1
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WO
WIPO (PCT)
Prior art keywords
composition
weight
fatty acid
composition according
perfume
Prior art date
Application number
PCT/EP2013/050546
Other languages
French (fr)
Inventor
Amit Kumar GHOSH
Aravindakshan Perincheery
Abhishek Rastogi
Arpita Sarkar
Kingshuk Dutta
Original Assignee
Unilever N.V.
Unilever Plc
Hindustan Unilever Limited
Conopco, Inc., D/B/A Unilever
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=47557162&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2013113541(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Unilever N.V., Unilever Plc, Hindustan Unilever Limited, Conopco, Inc., D/B/A Unilever filed Critical Unilever N.V.
Priority to ES13700225.9T priority Critical patent/ES2584384T3/en
Priority to CN201380007463.4A priority patent/CN104080900B/en
Priority to IN1460MUN2014 priority patent/IN2014MN01460A/en
Priority to BR112014017891A priority patent/BR112014017891A8/en
Priority to EP13700225.9A priority patent/EP2809757B1/en
Publication of WO2013113541A1 publication Critical patent/WO2013113541A1/en
Priority to ZA2014/04680A priority patent/ZA201404680B/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06—Inorganic compounds
    • C11D9/08—Water-soluble compounds
    • C11D9/10—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/225—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/26—Organic compounds, e.g. vitamins containing oxygen
    • C11D9/262—Organic compounds, e.g. vitamins containing oxygen containing carbohydrates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/17—Halides of elements of Groups 3 or 13 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/57—Sulfates or thiosulfates of elements of Groups 3 or 13 of the Periodic Table, e.g. alums
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/02—Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01—Stain or soil resistance

Definitions

  • the present invention relates to a composition and a method for treating substrates, such as fabrics; particularly to make the substrate stain repellent and easier to clean upon the subsequent wash.
  • Fabrics are generally cleaned with detergents.
  • Standard detergent compositions include surfactants and builders. Surfactants clean the fabrics.
  • Some detergent compositions also contain soda ash to enhance the cleaning action.
  • Many detergent compositions also include specialty polymers that help release stains. Such polymers are called soil release polymers (SRP).
  • SRP soil release polymers
  • Some detergent compositions also include additives that reduce re-deposition of dirt which is released in the wash liquor. Such additives are called anti-redeposition agents (ARD).
  • Fabrics tend to get stained during use. Stains are generally, either oily, or aqueous. Common sources of aqueous stains include tea, coffee, beverages and inks. Common sources of oily stains include pickles, sauces and ketchups, motor oil, and grease. People do prefer to wear clothes with lesser stains. This is particularly applicable to white fabrics, such as white shirts. People also prefer that kitchen, bathroom surfaces and windows surfaces are free of stains.
  • One of the ways to prevent fabrics and hard surfaces from getting stained is to treat them with compositions that form a film on the surface of the fabric or hard surface.
  • This film prevents, or at least reduces, the adhesion of stains.
  • the film also allows for facile removal of stains during washing, and it may be said to form a sacrificial layer, such as disclosed in our application WO2009/077255.
  • Another way to provide easier cleaning upon the next wash is to reduce the ability of the fabric to get soiled or stained.
  • salts of metals are generally present in such compositions. Surfaces get stained when stains spreads on it. In such cases, the stain wets the surface.
  • the contact angle between the stain and the surface is very low, generally less than 10(°).
  • a surface treatment composition forms a film, the film increases the contact angle. In other words, this film doesn't allow the stain to wet the surface.
  • water contact angle in the range of 90(°) to 170(°) is considered to be good for repelling aqueous stains.
  • oil contact angles greater than 60 are considered to be good for repelling oily stains.
  • Such treated surfaces may be termed as super-hydrophobic or super- oleophobic. Compositions to provide such stain repellence to fabrics are disclosed in WO2010/069731.
  • the contact angle is the angle at which a liquid/vapour (or two immiscible liquids) interface meets a solid surface.
  • the contact angle is specific for any given system and is determined by the interactions across the two interfaces. Most often, the concept is illustrated with a liquid droplet resting on a flat horizontal solid surface. The shape of the droplet is determined by Young-Laplace equation.
  • One of the ways to measure contact angle is to use a contact angle goniometer on a sessile drop of the liquid. This method is used to estimate wetting properties of a localized region on a solid surface. The angle between the baseline of the drop and the tangent at the drop boundary is the contact angle.
  • WO2011/134756 discloses stain repellent liquid compositions and a method for their use.
  • the compositions help make substrates, particularly fabrics, repellent to hydrophilic stains.
  • the compositions include 25 to 50 wt% soap, 10 to 30 wt% a complex of zinc and triethanolamine, 30 to 65 wt% trivalent metal ion and/or tetravalent metal ion, and a solvent having a lower alcohol and water in a ratio of 99: 1 to 85: 15.
  • compositions are dosed in the final rinse of the machine washing cycle, together with or instead of a fabric conditioner.
  • fabric conditioners comprising metal salt electrolytes and soap have been disclosed, however, they have not been found to provide any stain repellence or improved cleaning benefits on the subsequent wash.
  • Similar compositions are disclosed in US 4,417,995, disclosing fabric softener composition comprising
  • Aluminium Chlorhydrate a.k.a. Poly Aluminium Chloride
  • Pristerene a tallow fatty acid
  • GB 552447 discloses a permanent coating for water- proofing and rot-proofing materials.
  • GB662945 discloses a fabric treatment composition that serves as an ironing aid and imparts to the fabric a permanent, protective, stain- resistant, water- repellent and starchy finish.
  • GB662945 discloses polymer concentrations of less than 0.3%. When it comes to fabrics, however, consumers prefer removable coatings than permanent ones. Therefore, it still remains to be desired to have compositions that impart improved stain repellency and next time cleaning benefit through a fabric conditioner.
  • WO01/07551 discloses the use of polyvinyl alcohols (soil release polymers) as detergent additives in main wash detergent compositions.
  • composition disclosed in this document does not provide a next time cleaning benefit through a fabric conditioner.
  • US 4136038 relates to fabric conditioning compositions comprising a soil release polymer.
  • the composition disclosed in this document does not provide a next time cleaning benefit. Therefore, a next time cleaning benefit through a fabric conditioner is still desired.
  • the present invention provides a composition for treating a substrate, said composition comprising 2 - 25% by weight of a C8-C24 fatty acid, 2.5-40% by weight of a water soluble salt of Aluminium, 0.01 -2.0% by weight of an alkalinity source; 0.3 - 10% by weight of a non-ionic polymer having an HLB value of 12 to 20, perfume and water; and wherein the pH of the composition is between 1 and 6 and wherein 5 to 50% by weight of the total fatty acid is neutralised by the alkalinity source.
  • the present invention provides a method for treating a substrate comprising the steps of preparing a 0.05 - 1 % by weight solution of the composition according to the invention in water, rinsing a fabric article in the solution, and drying the fabric article.
  • the present invention provides a method for preparing the composition of the invention comprising the steps in sequence of partially neutralising fatty acid with the alkali source at a temperature above the melting point of the fatty acid, mixing the polymer into the partially neutralized fatty acid mixture, adding the aluminium salt to the mixture, homogenize the mixture, and leave the composition to cool down to room temperature; and optionally add a perfume.
  • the present invention provides a bottled rinse conditioner agent comprising the composition according to the invention in a 250 ml. to 5 L bottle.
  • the improved cleaning upon the subsequent wash benefit is also referred to as next time cleaning benefit
  • the composition as applied to the fabric is also referred to as sacrificial layer.
  • stain repellence The benefit of reduced uptake of stains or soil onto or into a fabric is also referred to as stain repellence, regardless of whether it relates to a specific stain or soils in general.
  • the present invention provides a composition for treating a substrate, comprising a C 8 - C 2 4 fatty acid, a water soluble salt of Aluminium, an alkalinity source; a non-ionic polymer.
  • the composition preferably comprises further optional ingredients.
  • the balance of the composition is made up to 100% by weight with water.
  • the pH of the composition is between 1 and 6.
  • the composition comprises a fatty acid comprising a carbon chain length of from 8 to 24 carbon atoms, herein after referred to as C 8 -C 2 4 fatty acid.
  • the composition preferably comprises a fatty acid having a carbon chain length of at least 10 carbon atoms, but preferably not more than 20, more preferably not more than 18, still more preferably not more than 16 carbon atoms or even not more than 14 carbon atoms. Combinations of different fatty acids are preferred from a cost perspective, as the commercially available fatty acids typically comprise of a mixture of different fatty acids with similar chain lengths.
  • the fatty acid may or may not have one or more carbon-carbon double bonds or triple bonds.
  • the iodine value which is indicative of degree of unsaturation, is preferably less than 20, more preferably less than 10, and most preferably less than 5.
  • Saturated fatty acid having no carbon-carbon double bond or triple bond is particularly preferred.
  • the fatty acids are water-insoluble.
  • Non-limiting examples of water-insoluble fatty acids that may be used according to the present invention include lauric acid, caprylic acid, myristic acid, stearic acid, oleic acid, and palmitic acid.
  • composition comprises 2 - 25% by weight of the fatty acid, preferably at least 5%, or even at least 10% by weight, but typically less than 22% by weight of the
  • the composition comprises an alkalinity source.
  • the purpose of the alkalinity source is to partially neutralise the fatty acid.
  • Preferably 5-50% by weight of the total fatty acid is neutralised by the alkalinity source, more preferably at least 10%, more preferably at least 12%, or even at least 15% by weight, but typically not more than 40%, more preferably not more than 30% by weight of the total fatty acid is neutralised.
  • the alkalinity source is preferably a hydroxide salt, more preferably an alkali metal hydroxide, wherein sodium and potassium hydroxides are the most common. Sodium hydroxide is the most preferred alkalinity source.
  • the composition comprises 0.05-0.5 mol of a hydroxide salt per mol of the fatty acid.
  • the composition comprises 0.01 -2.0% by weight of an alkalinity source, preferably at least 0.02%, more preferably at least 0.05%, still more preferably at least 0.1 % by weight, but typically not more than 1.5%, more preferably not more than 1.2% by weight of the composition.
  • the aluminium salt according is preferably a water soluble salt of aluminium, including aluminium nitrate, aluminium sulphate, and aluminium chloride.
  • the aluminium compounds of the invention include poly salts of aluminium, including polyaluminium chloride and polyaluminium sulphate. Polyaluminium chloride is the most preferred.
  • Poly aluminium chloride (PAC) may be defined as a non-stoichiometric oligomer of aluminium hydroxychloride having general formula [Al n CI(3n-m ) (OH) m ] where the value of m is preferably in the range of 5 to 24 and n preferably in the range of 2 to 12.
  • Water-insoluble aluminium compounds like clays, alumina and aluminium hydroxide are excluded from the scope of the present invention.
  • the composition comprises 2.5-40% by weight of the water soluble salt of aluminium, preferably at least 5%, more preferably at least 10% by weight, but typically not more than 30%, more preferably not more than 25% by weight of the composition.
  • the aluminium salt and the fatty acid form an aluminium soap that deposits onto the fabric fibres, thereby providing hydrophobicity.
  • composition comprises a further poly-valent metal ion.
  • poly-valent metal salt is ideally water soluble.
  • the metal salts provide further ionic strength to the medium that helps in deposition of the actives on the surface. Therefore polyvalent metals are more preferred than monovalent metal salts. Polyvalent metals are also more hydrolysable than monovalent metal salts and thereby tend to help deposition of the actives further through weak agglomeration and flocculation of actives on the surface.
  • Preferred polyvalent metal ions are selected from alkaline earth metal ions, titanium and zinc ions. More preferably, the metal salts including calcium, zinc, magnesium, barium, titanium, more preferably is chosen from calcium, zinc, magnesium or iron. These metal salts can be used in combination with PAC in the composition. Chromium is not preferred for household use as it is toxic. Corresponding anions of the metal salts may be chloride, nitrate, sulphate and acetate, or other water-soluble anions. Chloride, nitrate, sulphate and acetate are the most preferred.
  • the poly-valent metal salt is preferably present in the composition in a concentration of between 5 and 30% by weight, more preferably 5- 25% by weight, still more preferably 5-20% by weight, or even 5-15% by weight of the composition.
  • the combined amount of the water soluble aluminium salt and the polyvalent metal salt together is 7.5-40% by weight, preferably at least 10% by weight, but typically not more than 30%, more preferably not more than 25% by weight of the composition.
  • both Aluminium (Al) and the further polyvalent metal (M) are present in the composition, the best results are obtained when the molar ratio of Al to M is between 0.2 to 2.5 for good perfume delivery. The best hydrophobicity and stability results are obtained between 0.5 and 2.5. The best cleaning results are obtained at a molar ratio between 0.2 and 1 , preferably between 0.5 and 1.
  • the fatty acid to metal in ratio determines the deposition of perfume, fabric
  • the fatty acid to aluminium salt ratio (on weight basis) is preferably between 0.2 and 5 for good perfume deposition and delivery, preferably between 0.4 and 2 or even between 0.6 and 1.5 for improved hydrophobicity and stain repellence.
  • compositions typically phase separate at fatty acid to aluminium salt ratios above 1.5 (on weight basis).
  • 2-phase systems that need to be shaken before use are also acceptable to the consumer.
  • the fatty acid to aluminium salt ratio is preferably between 0.6 and 1.5, or even more preferably between 0.8 and 1.2 on weight basis.
  • the fatty acid to metal ion ratio (molar basis) is preferably between 0.2 and 2 for good perfume deposition and delivery, preferably between 0.5 and 1.2 for improved hydrophobicity and stain repellence.
  • compositions typically phase separate or solidify at fatty acid to metal ion ratios (on molar basis) above 1.2.
  • the fatty acid to metal ion ratio is preferably between 0.6 and 1.5, or even more preferably between 0.8 and 1.2 on molar basis.
  • composition according to the invention comprises a non-ionic polymer.
  • Non-ionic polymers typically comprise of hydrophilic and lipophilic parts. To define the hydrophilic to lipophilic balance, the HLB value of a polymer is widely used in the art.
  • the polymer is used to stabilise the composition and aid in the deposition of the composition onto the fabric.
  • compositions providing excellent perfume delivery to and extended perfume release from a fabric is obtained when the HLB value is in the range from 10 to 20.
  • HLB value is between 10 and 18, preferably between 12 and 18, or even between 15 and 17.
  • the HLB is preferably between 12 and 18.
  • the non-ionic polymer of the invention is preferably selected from homopolymers and copolymers of alkylene oxides, including ethylene oxide and propylene oxide and copolymers thereof and polyvinyl alcohols, having an HLB value in the range from 12 to 20.
  • Ethylene oxide/Propylene oxide block co-polymer and polyvinyl alcohols are the most preferred.
  • poly vinyl alcohol polymers when used have a degree of hydrolysiation of at least 75(%), preferably at least 80%, or even at least 85%, but preferably less than 95%. A degree of hydrolysation between 85-91 %, or even 87-89% is the most preferred.
  • the molecular mass of the PVA is preferably between 10,000 u and 200,000 u.
  • Ethylene oxide/Propylene oxide block co-polymers are especially preferred, and preferably have a molecular mass of between 2500 and 25000 u (wherein u is the SI atomic mass unit), and a PPG block of between 5 and 30%, more preferably 10-25%, or even between 15 and 20% by weight of the polymer.
  • the composition comprises 0.3 - 10% by weight of the non-ionic polymer, preferably at least 0.5%, more preferably at least 1 % or even at least 2% by weight, but typically less than 8% by weight of the composition. pH of the composition
  • composition in the rinse water of a machine wash cycle is acidic. At alkaline pH the composition does not or only partially deposit onto the fabric.
  • the pH of the composition is between 1 and 6. The best results are obtained when the pH of the composition is less than 5.
  • composition according to the invention comprises 0.1 -10% by weight of a perfume, preferably at least 0.2%, more preferably at least 0.5%, but typically not more than 5% by weight of the composition. Further optional ingredients for oily soil removal
  • composition further comprises a further polymer or non-ionic surfactant.
  • a further polymer or non-ionic surfactant for the best cleaning performance upon the subsequent wash, especially for improved cleaning of oily soils and stains it is preferred that the composition further comprises a further polymer or non-ionic surfactant.
  • a lower alkyl cellulose preferably methyl cellulose improves the removal of fatty soils upon the next wash. It is preferred that a 2% solution of the alkyl cellulose in water has a viscosity of between 2000 and 6000 mPa.s (at 20°, measured in a Brookfield viscometer)
  • the composition preferably comprises between 0.1 and 2.5% by weight of the composition of the alkyl cellulose.
  • the composition preferably comprises between 0.1 and 2.5% by weight of the soil release polymer.
  • Fatty acid esters may be produced by an alkali-catalyzed reaction between fats or fatty acids and methanol/ethanol.
  • Preferred examples include methyl laurate, ethyl octanoate, ethyl laurate, ethyl octanoate, methyl hexanoate, methyl myristate, methyl stearate.
  • Non-ionic surfactants are well-known in the art. They normally consist of a water- solubilising polyalkoxylene (preferably from 3 to10 ethoxy and/or propoxy groups) or a mono- or di-alkanolamide group in chemical combination with an organic hydrophobic group derived from, for example, fatty alcohols with from 9 to 15 carbon atoms
  • alkylphenols (preferably from 12 to 20 carbon atoms) in which the alkyl group contains from about 6 to about 12 carbon atoms, dialkylphenols in which each alkyl group contains from 6 to 12 carbon atoms, primary, secondary or tertiary aliphatic alcohols (or alkyl-capped derivatives thereof) monocarboxylic acids having from 10 to about 24 carbon atoms in the alkyl group and polyoxypropylenes.
  • Fatty acid mono- and dialkanolamides in which the alkyl group of the fatty acid radical contains from 10 to about 20 carbon atoms and the alkyloyl group having from 1 to 3 carbon atoms are also common.
  • polyalkoxylene containing surfactants usually consists of an average of from 2 to 20 groups of ethylene oxide, propylene oxide groups or mixtures thereof.
  • the latter class includes those described in European Patent
  • ethoxylated non-ionics which are condensation products of fatty alcohols with from 9 to 15 carbon atoms condensed with 3 to 12 moles of ethylene oxide (generally understood to be an average value).
  • condensation products of C9 to C15 alcohols with 3 or 7 moles of ethylene oxide, or mixtures thereof may be used as the sole non-ionic surfactant or in combination with those described in EP-A-0,225,654.
  • the fabric softening cationic co-surfactant is a quaternary ammonium salt surfactant, characterised in that the ammonium salt has the general formula: R1 R2R3R4N+ X-, wherein R1 to R4 are alkyl or aryl groups, and X- is an inorganic anion.
  • R1 R2R3R4N+ X- Preferably partially hardened triethanolmaine ester quaternary surfactants are used.
  • Specifically preferred quaternary ammonium cationic cosurfactants are Methyl bis[ethyl (tallowate)]- 2-hydroxyethyl ammonium methyl sulphate, Methyl bis[ethyl (palmate)]-2-hydroxyethyl ammonium methyl sulphate, etc.
  • Anionic Surfactants are Methyl bis[ethyl (tallowate)]- 2-hydroxyethyl ammonium methyl sulphate, Methy
  • the anionic surfactant is selected from linear alkylbenzenesulfonates, branched alkylbenzenesulfonates, alkylpoly(ethoxylates), alkyl sulfates, methyl ester sulfonates, and mixtures thereof.
  • anionic surfactants useful herein include any of the common anionic surfactants such as linear or modified, e. g. alkylbenzenesulfonate surfactants, alkylpoly(ethoxylate) surfactants, alkyl sulfates, methyl ester sulfonates, or mixtures thereof.
  • the ratio of Cationic to Anionic is between 5: 1 and 1 :1 , preferably between 3:1 and 1 : 1.
  • the composition typically comprises a perfume, typically between 0.1 and 10% of the total composition, preferably between 0.1 and 5%, or even between 0.3 and 3% of the composition.
  • composition may further comprise softening agents as commonly used in fabric softening compositions.
  • the invention provides a method for treating a substrate comprising the steps of preparing a 0.05 - 1 % by weight solution of the composition of the invention in water, rinsing a fabric article in the solution, and drying the fabric article.
  • the solution is preferably 0.1 - 0.5% by weight of the composition in water.
  • the solution as dosed to a commercially available front load washing machine is tically between 25 and 100 ml of the composition into 12-15 L of rinse water.
  • the dosage is typically 50-150 ml to 50-60 L of rinse water.
  • the invention provides a method for preparing the compositions according to the invention comprising the steps in sequence of partially neutralising fatty acid with the alkali source at a temperature above the melting point of the fatty acid, mixing the polymer into the partially neutralized fatty acid mixture, adding the aluminium salt to the mixture, homogenize the mixture, leave the composition to cool down to room temperature; and optionally add a perfume.
  • room temperature is meant a temperature between 20 and 25°C.
  • the fatty acid is preferably partially neutralized with alkali solution at a temperature of less than 100°C, more preferably at a temperature of less than 90°C, still more preferably at a temperature of less than 80°C, or even less than 75°C, while the temperature is typically above the melting point of the fatty acid, typically at least 45°C, more preferably at least 50°C, still more preferably at least 55°C, or even at least 60°C.
  • the product is typically packed in a bottle, preferably a plastic bottle at volumes of between 250 ml and 5 L, more preferably between 250 ml and 1.5 L.
  • a bottle preferably a plastic bottle at volumes of between 250 ml and 5 L, more preferably between 250 ml and 1.5 L.
  • Common supermarket size bottles are 250 ml, 500 ml, 750ml, 1 L and 1.5 L.
  • the bottles may optionally have a measuring cup attached, or a measuring scale indicator in the cap, to enable the consumer to dose the right amount into the rinse conditioner compartment of the washing machine.
  • Trigger spray dispenser bottles typically have a volume of between 250 ml and 1.5 L. Common volumes include 400 ml, 500 ml, 750 ml, and 1 L.
  • fatty acid was partially neutralized with alkali solution at 70 °C temperature.
  • polyvinyl alcohol was mixed into the partially neutralized fatty acid.
  • PAC was added to the above mixture.
  • the mixture was homogenized for 5 min and was allowed to cool down at room temperature (25 °C) and perfume was added to the cooled mixture and was mixed well. Further ingredients as used in some of the examples were added subsequently.
  • a droplet of water is dropped on a fabric kept horizontally from a height of ⁇ 2cm and the behaviour of the droplet is studies and ratings are given as tabulated below:
  • Carbon soot soiling To 1 L of de-ionized water 150mg of carbon soot (Cabot India) was added and sonicated in a sonication bath for 2 hrs. 0.2 ml of this carbon soot slurry was dropped onto the fabric which was placed at an inclined plane of 45°. The fabrics were allowed to dry over-night.
  • Red mud soiling To ⁇ It de-ionized water 5 g of red mud (sieved, ⁇ 150 microns) was added and sonicated in a sonication bath for 2 hrs. 0.2 ml of this slurry was dropped onto the fabric which was placed at an inclined plane of 45°. The fabrics were allowed to dry over- night.
  • Tea stain soiling Two tea bags were dipped in 150ml hot milk to make tea. 0.2 ml of this tea was dropped onto the fabric which was placed at an inclined plane of 45°. The fabrics were allowed to dry over-night.
  • Dirty motor oil (DMO) soiling 50 ml of dirty motor oil was mixed with 50 ml of fresh motor oil to obtain the stain. 0.2 ml of the stain was dropped onto the fabric which was placed at an inclined plane of 45°. The fabrics were allowed to dry over-night.
  • Cooking oil soiling 0.2 g of Macrolex (trademark) violet dye was added to 100 ml of sunflower oil and was mixed well. 0.2 ml of the stain was dropped onto the fabric which was placed at an inclined plane of 45°. The fabrics were allowed to dry over-night.
  • the soiled 10x10 cm swatches were stapled onto one of the ballast shirts (as described in the fabric treatment protocol).
  • Total wash load was 3.5kg comprising of the soiled swatches and the ballast shirts. Washing was done with 30 grams Surf Excel Matic Front Load (ex Hindustan Unilever Ltd, India) at 6°fH. Cotton, poly-cotton and polyester swatches, both treated and untreated, were used for each study.
  • a typical wash cycle comprised of wash and two rinses along with spin. After washing was completed, the swatches were removed and then dried in the drier. The extent of stain removal was compared against the control (untreated) fabrics on a one to a one basis for each stain type.
  • 50x50 cm polyester swatches were used for the perfume evaluation study. 5 swatches were treated with each of the test formulation, as described in the examples, in a manner already described. 40g of test formulation was used for treatment. As a control,
  • Comfort (Market sample-Batch no. B.876, Blue variant, India) was used. After 2 hours of treatment and drying, the perfume impact of the treated swatches was compared against the control (in this case Comfort treated) on a one to one basis for each set. A score "+” was given in cases where the perfume impact on the treated fabrics appeared greater than that on the control fabrics. Similarly, a score "-" was given in cases where the perfume impact on the treated fabrics appeared lesser than that on the control fabrics. In all the cases, the evaluation was done by trained persons. Materials
  • PPG/PEG co-polymer Pluronic F108 and F65 (ex BASF)
  • Soil release polymer REPEL-O-TEX SF2 (ex Rhodia)
  • Example 1 effect of fatty acid to poly aluminium chloride ratio
  • composition was prepared as indicated above.
  • Laurie acid was neutralised to ca 15%.
  • the polymer used was Poly vinyl alcohol (PVA) having a Mw of 85-124k u.
  • Sodium hydroxide (NaOH) was used to neutralise the fatty acid.
  • the following compositions were used (see table below). 1 % of perfume was used in the compositions below.
  • the balance is water.
  • Example 2 effect of fatty acid to poly aluminium chloride ratio
  • Example 1-4 were repeated with a commercially available mixture of fatty acids comprising 55% Why, 22% Myristic, 22% Palmitic and 1 % oleic acid (Prifac 5908, ex Croda),
  • the polymer used was Poly vinyl alcohol (PVA) having a Mw of 13-23k u.
  • Sodium hydroxide (NaOH) was used to neutralise the fatty acid.
  • the following compositions were used (see table below). 1 % of perfume was used in the compositions below.
  • the balance is water.
  • Example compositions Ex5-Ex8 The table above shows that the perfume delivery throughout Example compositions Ex5-Ex8 is good. The best stability and hydrophobicity results are obtained with example Ex6 and Ex7.
  • Example 2 The effect of the degree of neutralization is demonstrated.
  • the experiments were carried out as in Example 1.
  • the polymer used was Poly vinyl ohol (PVA) having a Mw of 85-124k u.
  • Sodium hydroxide (NaOH) was used to neutralise the fatty acid.
  • the following compositions were used (see table below). 1 % of perfume was used in the compositions below.
  • the balance is water.
  • compositions in this example contained 20% Why acid and 20% PAC; other ingredients are listed below. The balance is water.
  • compositions were used (see table below). 1 % of perfume was used in the compositions below.
  • HLB was calculated by Griffin's method.
  • HLB was calculated by Group Calculation method.
  • Example 1 was repeated with different degrees of hydrolysis of the poly vinyl alcohol (PVA) polymer.
  • the balance is water.
  • All composition below contained 20% Why acid, 20% PAC, 0.6% NaOH.
  • the concentration, type, HLB and degree of hydrolysis are given below.
  • compositions were used (see table below). 1 % of perfume was used in the compositions below.
  • compositions having an HLB below 18 give the best stability (i.e. no phase separation) of the composition.
  • Example 1 was repeated and the cleaning efficacy on the subsequent wash was demonstrated and compared with a control without treatment.
  • compositions were used (see table below). 1 % of perfume was used in the compositions below.
  • Example 7 Effect of further metal ion.
  • fatty acid was partially neutralized with alkali solution at 70 °C temperature.
  • polyvinyl alcohol was mixed into the partially neutralized fatty acid.
  • an aqueous solution comprising of a mixture of PAC (poly aluminium chloride) and CaCI2.2H20 was added to the above mixture.
  • the mixture was homogenized for 5 min and was allowed to cool down at room temperature (25 °C) and perfume was added to the cooled mixture and was mixed well. Further ingredients as used in some of the examples were added subsequently.
  • the polymer used was Poly vinyl alcohol (PVA) having a Mw of 85-124k u.
  • Sodium hydroxide (NaOH) was used to neutralise the fatty acid.
  • PAC was used as a source of Aluminium. PAC contains 15% Al (mole calculation were done on this basis)
  • compositions were used (see table below). 1 % of perfume was used in the compositions below.
  • the results show that perfume delivery is good for al formulations.
  • the results further show that a Al to Ca mole ratio greater than 2.3 leads to stable formulations but inferior oily (DMO) soil cleaning, a Al to Ca mole ratio between 0.5 to 2.3 leads to stable formulations with better oily (DMO) soil cleaning, and a Al to Ca mole ratio less than 0.5 leads to unstable formulations but better oily (DMO) soil cleaning.
  • Formulations are immediately stable, solidify upon keeping for overnight. Treatment was done immediately.
  • Example 8 Effect of Fatty acid to Total metal (Al + Ca) mole ratio:
  • composition was prepared as indicated above.
  • Laurie acid was neutralised to 20%.
  • the polymer used was Poly vinyl alcohol (PVA) having a Mw of 85-124k u.
  • Sodium hydroxide (NaOH) was used to neutralise the fatty acid.
  • PAC was used as a source of Al. PAC contains 15% Al (mole calculation were done on this basis)
  • compositions were used (see table below). 1 % of perfume was used in the compositions below.
  • the composition was prepared as indicated above.
  • the polymer used was Poly vinyl alcohol (PVA) having a Mw of 85-124k u.
  • Sodium hydroxide (NaOH) was used to neutralise the fatty acid.
  • PAC was used as a source of Al.
  • PAC contains 15% Al (mole calculation were done on this basis). 1 % of perfume was used in the compositions below.
  • Example 11 Optional oil removal ingredients
  • fatty acid was partially neutralized with alkali solution at 70 °C temperature.
  • polyvinyl alcohol was mixed into the partially neutralized fatty acid.
  • PAC was added to the above mixture.
  • the mixture was homogenized for 5 min and was allowed to cool down at room temperature (25 °C) and perfume was added to the cooled mixture and was mixed well. Further ingredients as used in some of the examples were added subsequently.
  • the formulation containing a combination of anionic and cationic surfactant for enhanced oily soil removal was prepared as follows: Partially neutralising fatty acid with the alkali source at a temperature above the melting point of the fatty acid, mixing the polymer into the partially neutralized fatty acid mixture, adding a solution of aluminium salt to the mixture, homogenize the mixture, followed by addition of the cationic surfactant and then the anionic surfactant, the composition was then let to cool down to room temperature; and optionally perfume was added.
  • room temperature is meant a temperature between 20 and 25°C.
  • LAS acid RHODACAL SSA/R
  • the table below shows the compositions as used. 1 % of perfume was used in the compositions below.
  • the composition was prepared as indicated above.
  • Being acid was partially neutralised to 15%.
  • the polymer used was Poly vinyl alcohol (PVA) having a Mw of 85-124k u.
  • Sodium hydroxide (NaOH) was used to neutralise the fatty acid.
  • Fatty acid to PAC ratio is fixed at 0.83.
  • the table below shows the compositions as used. 1 % of perfume was used in the compositions below.
  • compositions according to the invention show the best results for stability, hydrophobicity and perfume delivery.

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Abstract

The present invention relates to a composition and a method for treating substrates, such as fabrics; particularly to make the substrate stain repellent and easier to clean upon the subsequent wash. The invention has been developed primarily for use on fabrics, and will be described hereinafter with reference to these applications. It is an object of the present invention to provide stain repellence to a fabric. It is still another object of the invention to provide a composition that provides improved perfume delivery to the fabric. It has been found that improved perfume delivery is obtained in compositions comprising a fatty acid, a water soluble salt of Aluminium and a non-ionic polymer. Improved stain repellence is obtained when the HLB of the polymer is between 12 and 18.

Description

A COMPOSITION AND METHOD FOR TREATING SUBSTRATES Field of the invention
The present invention relates to a composition and a method for treating substrates, such as fabrics; particularly to make the substrate stain repellent and easier to clean upon the subsequent wash.
The invention has been developed primarily for use on fabrics, and will be described hereinafter with reference to these applications.
Background of the invention
Fabrics are generally cleaned with detergents. Standard detergent compositions include surfactants and builders. Surfactants clean the fabrics. Some detergent compositions also contain soda ash to enhance the cleaning action. Many detergent compositions also include specialty polymers that help release stains. Such polymers are called soil release polymers (SRP). Some detergent compositions also include additives that reduce re-deposition of dirt which is released in the wash liquor. Such additives are called anti-redeposition agents (ARD). Fabrics tend to get stained during use. Stains are generally, either oily, or aqueous. Common sources of aqueous stains include tea, coffee, beverages and inks. Common sources of oily stains include pickles, sauces and ketchups, motor oil, and grease. People do prefer to wear clothes with lesser stains. This is particularly applicable to white fabrics, such as white shirts. People also prefer that kitchen, bathroom surfaces and windows surfaces are free of stains.
One of the ways to prevent fabrics and hard surfaces from getting stained is to treat them with compositions that form a film on the surface of the fabric or hard surface. This film prevents, or at least reduces, the adhesion of stains. The film also allows for facile removal of stains during washing, and it may be said to form a sacrificial layer, such as disclosed in our application WO2009/077255. Another way to provide easier cleaning upon the next wash is to reduce the ability of the fabric to get soiled or stained. Typically salts of metals are generally present in such compositions. Surfaces get stained when stains spreads on it. In such cases, the stain wets the surface. When a stain wets a surface, the contact angle between the stain and the surface is very low, generally less than 10(°). When a surface treatment composition forms a film, the film increases the contact angle. In other words, this film doesn't allow the stain to wet the surface. Generally, water contact angle in the range of 90(°) to 170(°) is considered to be good for repelling aqueous stains. On the other hand, oil contact angles greater than 60 are considered to be good for repelling oily stains. Such treated surfaces may be termed as super-hydrophobic or super- oleophobic. Compositions to provide such stain repellence to fabrics are disclosed in WO2010/069731.
The contact angle is the angle at which a liquid/vapour (or two immiscible liquids) interface meets a solid surface. The contact angle is specific for any given system and is determined by the interactions across the two interfaces. Most often, the concept is illustrated with a liquid droplet resting on a flat horizontal solid surface. The shape of the droplet is determined by Young-Laplace equation. One of the ways to measure contact angle is to use a contact angle goniometer on a sessile drop of the liquid. This method is used to estimate wetting properties of a localized region on a solid surface. The angle between the baseline of the drop and the tangent at the drop boundary is the contact angle.
Fabric treatment compositions have been disclosed in co-pending unpublished Indian applications WO2011/134755 and WO2011/134756 (both by Unilever).
WO2011/134756 discloses stain repellent liquid compositions and a method for their use. The compositions help make substrates, particularly fabrics, repellent to hydrophilic stains. The compositions include 25 to 50 wt% soap, 10 to 30 wt% a complex of zinc and triethanolamine, 30 to 65 wt% trivalent metal ion and/or tetravalent metal ion, and a solvent having a lower alcohol and water in a ratio of 99: 1 to 85: 15.
Ideally such compositions are dosed in the final rinse of the machine washing cycle, together with or instead of a fabric conditioner. In US 4,555,349 fabric conditioners comprising metal salt electrolytes and soap have been disclosed, however, they have not been found to provide any stain repellence or improved cleaning benefits on the subsequent wash. Similar compositions are disclosed in US 4,417,995, disclosing fabric softener composition comprising
Aluminium Chlorhydrate (a.k.a. Poly Aluminium Chloride) and Pristerene (a tallow fatty acid), but said compositions do not provide improved cleaning on the subsequent wash or improved stain repellence. Furthermore, US 4,555,349 and US 4,417,995 do not provide improved perfume delivery to the fabric.
GB 552447 discloses a permanent coating for water- proofing and rot-proofing materials. Similarly, GB662945 discloses a fabric treatment composition that serves as an ironing aid and imparts to the fabric a permanent, protective, stain- resistant, water- repellent and starchy finish. Moreover, GB662945 discloses polymer concentrations of less than 0.3%. When it comes to fabrics, however, consumers prefer removable coatings than permanent ones. Therefore, it still remains to be desired to have compositions that impart improved stain repellency and next time cleaning benefit through a fabric conditioner. WO01/07551 discloses the use of polyvinyl alcohols (soil release polymers) as detergent additives in main wash detergent compositions. However, the composition disclosed in this document does not provide a next time cleaning benefit through a fabric conditioner. US 4136038 relates to fabric conditioning compositions comprising a soil release polymer. However, the composition disclosed in this document does not provide a next time cleaning benefit. Therefore, a next time cleaning benefit through a fabric conditioner is still desired.
It is an object of the present invention to provide stain repellence to a fabric.
It is a further object of the present invention to provide improved cleaning upon the subsequent wash. It is yet another object of the invention to provide a stable composition that does not phase separate.
It is still another object of the invention to provide a composition that provides improved perfume delivery to the fabric.
It is still another object of the invention to provide a composition that provides improved perfume release from the fabric. It is still another object of the invention to provide a composition that provides fabric softness.
Surprisingly, it has been found that improved perfume delivery is obtained in compositions comprising a fatty acid, a water soluble salt of Aluminium and a non-ionic polymer. Improved stain repellence is obtained when the HLB of the polymer is between 12 and 18.
Summary of the invention
Accordingly the present invention provides a composition for treating a substrate, said composition comprising 2 - 25% by weight of a C8-C24 fatty acid, 2.5-40% by weight of a water soluble salt of Aluminium, 0.01 -2.0% by weight of an alkalinity source; 0.3 - 10% by weight of a non-ionic polymer having an HLB value of 12 to 20, perfume and water; and wherein the pH of the composition is between 1 and 6 and wherein 5 to 50% by weight of the total fatty acid is neutralised by the alkalinity source.
In a second aspect the present invention provides a method for treating a substrate comprising the steps of preparing a 0.05 - 1 % by weight solution of the composition according to the invention in water, rinsing a fabric article in the solution, and drying the fabric article.
In a third aspect the present invention provides a method for preparing the composition of the invention comprising the steps in sequence of partially neutralising fatty acid with the alkali source at a temperature above the melting point of the fatty acid, mixing the polymer into the partially neutralized fatty acid mixture, adding the aluminium salt to the mixture, homogenize the mixture, and leave the composition to cool down to room temperature; and optionally add a perfume. In a fourth aspect the present invention provides a bottled rinse conditioner agent comprising the composition according to the invention in a 250 ml. to 5 L bottle.
For the avoidance of doubt, the improved cleaning upon the subsequent wash benefit, is also referred to as next time cleaning benefit, while the composition as applied to the fabric is also referred to as sacrificial layer. The benefit of reduced uptake of stains or soil onto or into a fabric is also referred to as stain repellence, regardless of whether it relates to a specific stain or soils in general.
These and other aspects, features and advantages will become apparent to those of ordinary skill in the art from a reading of the following detailed description and the appended claims. For the avoidance of doubt, any feature of one aspect of the present invention may be utilised in any other aspect of the invention. The word "comprising" is intended to mean "including" but not necessarily "consisting of" or "composed of." In other words, the listed steps or options need not be exhaustive. It is noted that the examples given in the description below are intended to clarify the invention and are not intended to limit the invention to those examples per se. Similarly, all percentages are weight/weight percentages unless otherwise indicated. Except in the operating and comparative examples, or where otherwise explicitly indicated, all numbers in this description indicating amounts of material or conditions of reaction, physical properties of materials and/or use are to be understood as modified by the word "about".
Numerical ranges expressed in the format "from x to y" are understood to include x and y. When for a specific feature multiple preferred ranges are described in the format "from x to y", it is understood that all ranges combining the different endpoints are also contemplated.
Detailed description of the invention
The present invention provides a composition for treating a substrate, comprising a C8- C24 fatty acid, a water soluble salt of Aluminium, an alkalinity source; a non-ionic polymer. The composition preferably comprises further optional ingredients. The balance of the composition is made up to 100% by weight with water. The pH of the composition is between 1 and 6. Fatty acid
The composition comprises a fatty acid comprising a carbon chain length of from 8 to 24 carbon atoms, herein after referred to as C8-C24 fatty acid. The composition preferably comprises a fatty acid having a carbon chain length of at least 10 carbon atoms, but preferably not more than 20, more preferably not more than 18, still more preferably not more than 16 carbon atoms or even not more than 14 carbon atoms. Combinations of different fatty acids are preferred from a cost perspective, as the commercially available fatty acids typically comprise of a mixture of different fatty acids with similar chain lengths. The fatty acid may or may not have one or more carbon-carbon double bonds or triple bonds. The iodine value, which is indicative of degree of unsaturation, is preferably less than 20, more preferably less than 10, and most preferably less than 5. Saturated fatty acid having no carbon-carbon double bond or triple bond is particularly preferred. The fatty acids are water-insoluble. Non-limiting examples of water-insoluble fatty acids that may be used according to the present invention include lauric acid, caprylic acid, myristic acid, stearic acid, oleic acid, and palmitic acid.
The composition comprises 2 - 25% by weight of the fatty acid, preferably at least 5%, or even at least 10% by weight, but typically less than 22% by weight of the
composition.
Alkalinity source
The composition comprises an alkalinity source. The purpose of the alkalinity source is to partially neutralise the fatty acid. Preferably 5-50% by weight of the total fatty acid is neutralised by the alkalinity source, more preferably at least 10%, more preferably at least 12%, or even at least 15% by weight, but typically not more than 40%, more preferably not more than 30% by weight of the total fatty acid is neutralised. The alkalinity source is preferably a hydroxide salt, more preferably an alkali metal hydroxide, wherein sodium and potassium hydroxides are the most common. Sodium hydroxide is the most preferred alkalinity source. To neutralise the fatty acid to an extent of 5-50% by weight of the total fatty acid, the composition comprises 0.05-0.5 mol of a hydroxide salt per mol of the fatty acid.
Thus, the composition comprises 0.01 -2.0% by weight of an alkalinity source, preferably at least 0.02%, more preferably at least 0.05%, still more preferably at least 0.1 % by weight, but typically not more than 1.5%, more preferably not more than 1.2% by weight of the composition.
Aluminium salt
The aluminium salt according is preferably a water soluble salt of aluminium, including aluminium nitrate, aluminium sulphate, and aluminium chloride. For the avoidance of doubt, the aluminium compounds of the invention include poly salts of aluminium, including polyaluminium chloride and polyaluminium sulphate. Polyaluminium chloride is the most preferred. Poly aluminium chloride (PAC) may be defined as a non-stoichiometric oligomer of aluminium hydroxychloride having general formula [AlnCI(3n-m)(OH)m] where the value of m is preferably in the range of 5 to 24 and n preferably in the range of 2 to 12.
Water-insoluble aluminium compounds like clays, alumina and aluminium hydroxide are excluded from the scope of the present invention.
The best results are obtained when a 1 % solution of the aluminium salt according to the invention in water of 20°C gives a pH of between 1 and 6, more preferably between 2 and 5.
The composition comprises 2.5-40% by weight of the water soluble salt of aluminium, preferably at least 5%, more preferably at least 10% by weight, but typically not more than 30%, more preferably not more than 25% by weight of the composition. Without wishing to be bound by a theory, it is thought that the aluminium salt and the fatty acid form an aluminium soap that deposits onto the fabric fibres, thereby providing hydrophobicity. Further poly-valent metal ion
Further improved results may be obtained when the composition comprises a further poly-valent metal ion. From the perspective of the cost of the composition several polyvalent metal ions are also less costly than Aluminium, and therefore more preferred. The poly-valent metal salt is ideally water soluble.
The metal salts provide further ionic strength to the medium that helps in deposition of the actives on the surface. Therefore polyvalent metals are more preferred than monovalent metal salts. Polyvalent metals are also more hydrolysable than monovalent metal salts and thereby tend to help deposition of the actives further through weak agglomeration and flocculation of actives on the surface.
Preferred polyvalent metal ions are selected from alkaline earth metal ions, titanium and zinc ions. More preferably, the metal salts including calcium, zinc, magnesium, barium, titanium, more preferably is chosen from calcium, zinc, magnesium or iron. These metal salts can be used in combination with PAC in the composition. Chromium is not preferred for household use as it is toxic. Corresponding anions of the metal salts may be chloride, nitrate, sulphate and acetate, or other water-soluble anions. Chloride, nitrate, sulphate and acetate are the most preferred. The poly-valent metal salt is preferably present in the composition in a concentration of between 5 and 30% by weight, more preferably 5- 25% by weight, still more preferably 5-20% by weight, or even 5-15% by weight of the composition.
When a poly-valent metal salt is present, the combined amount of the water soluble aluminium salt and the polyvalent metal salt together is 7.5-40% by weight, preferably at least 10% by weight, but typically not more than 30%, more preferably not more than 25% by weight of the composition. When both Aluminium (Al) and the further polyvalent metal (M) are present in the composition, the best results are obtained when the molar ratio of Al to M is between 0.2 to 2.5 for good perfume delivery. The best hydrophobicity and stability results are obtained between 0.5 and 2.5. The best cleaning results are obtained at a molar ratio between 0.2 and 1 , preferably between 0.5 and 1.
Fatty acid to Metal Ion ratio
The fatty acid to metal in ratio determines the deposition of perfume, fabric
hydrophobicity and cleaning efficacy.
Fatty acid to aluminium alone
The fatty acid to aluminium salt ratio (on weight basis) is preferably between 0.2 and 5 for good perfume deposition and delivery, preferably between 0.4 and 2 or even between 0.6 and 1.5 for improved hydrophobicity and stain repellence.
The compositions typically phase separate at fatty acid to aluminium salt ratios above 1.5 (on weight basis). However, 2-phase systems that need to be shaken before use are also acceptable to the consumer. For the best stain repellence properties, the fatty acid to aluminium salt ratio is preferably between 0.6 and 1.5, or even more preferably between 0.8 and 1.2 on weight basis.
Fatty acid to total metal ion ratio (aluminium + further polyvalent metal)
The fatty acid to metal ion ratio (molar basis) is preferably between 0.2 and 2 for good perfume deposition and delivery, preferably between 0.5 and 1.2 for improved hydrophobicity and stain repellence.
The compositions typically phase separate or solidify at fatty acid to metal ion ratios (on molar basis) above 1.2.
For the best stain repellence properties, the fatty acid to metal ion ratio is preferably between 0.6 and 1.5, or even more preferably between 0.8 and 1.2 on molar basis. Polymer
The composition according to the invention comprises a non-ionic polymer. Non-ionic polymers typically comprise of hydrophilic and lipophilic parts. To define the hydrophilic to lipophilic balance, the HLB value of a polymer is widely used in the art.
The polymer is used to stabilise the composition and aid in the deposition of the composition onto the fabric.
HLB values may be calculated, e.g. by Griffin's method (Griffin WC: "Calculation of HLB Values of Non-Ionic Surfactants," Journal of the Society of Cosmetic Chemists 5 (1954): 259), or Davies' group contribution method (Davies JT: "A quantitative kinetic theory of emulsion type, I. Physical chemistry of the emulsifying agent," Gas/Liquid and Liquid/Liquid Interface. Proceedings of the International Congress of Surface Activity (1957): 426-438); or the group calculation method (HLB= 7+∑(Hydrophilic group numbers)-∑(Lipophilic group numbers)).
For the purpose of the present invention, compositions providing excellent perfume delivery to and extended perfume release from a fabric is obtained when the HLB value is in the range from 10 to 20.
The best stain repellence properties are obtained when the HLB value is between 10 and 18, preferably between 12 and 18, or even between 15 and 17.
For the best stability of the compositions, and to obtain compositions that do not phase separate, the HLB is preferably between 12 and 18.
The non-ionic polymer of the invention is preferably selected from homopolymers and copolymers of alkylene oxides, including ethylene oxide and propylene oxide and copolymers thereof and polyvinyl alcohols, having an HLB value in the range from 12 to 20.
Ethylene oxide/Propylene oxide block co-polymer and polyvinyl alcohols are the most preferred. To get the best stability of the composition, it is preferred that poly vinyl alcohol polymers (PVA), when used have a degree of hydrolysiation of at least 75(%), preferably at least 80%, or even at least 85%, but preferably less than 95%. A degree of hydrolysation between 85-91 %, or even 87-89% is the most preferred. The molecular mass of the PVA is preferably between 10,000 u and 200,000 u.
Ethylene oxide/Propylene oxide block co-polymers (commercially available as Pluronic, ex BASF) are especially preferred, and preferably have a molecular mass of between 2500 and 25000 u (wherein u is the SI atomic mass unit), and a PPG block of between 5 and 30%, more preferably 10-25%, or even between 15 and 20% by weight of the polymer.
The composition comprises 0.3 - 10% by weight of the non-ionic polymer, preferably at least 0.5%, more preferably at least 1 % or even at least 2% by weight, but typically less than 8% by weight of the composition. pH of the composition
The best results upon use of the composition in the rinse water of a machine wash cycle is acidic. At alkaline pH the composition does not or only partially deposit onto the fabric.
Therefore it is preferred that the pH of the composition is between 1 and 6. The best results are obtained when the pH of the composition is less than 5. Perfume
The composition according to the invention comprises 0.1 -10% by weight of a perfume, preferably at least 0.2%, more preferably at least 0.5%, but typically not more than 5% by weight of the composition. Further optional ingredients for oily soil removal
For the best cleaning performance upon the subsequent wash, especially for improved cleaning of oily soils and stains it is preferred that the composition further comprises a further polymer or non-ionic surfactant. Cellulose polymers
It is found that the addition of a lower alkyl cellulose, preferably methyl cellulose improves the removal of fatty soils upon the next wash. It is preferred that a 2% solution of the alkyl cellulose in water has a viscosity of between 2000 and 6000 mPa.s (at 20°, measured in a Brookfield viscometer) The composition preferably comprises between 0.1 and 2.5% by weight of the composition of the alkyl cellulose.
Similar results are found with soil release polymers, such as the Repel-O-Tex range of Rhodia (trade mark) i.e. SF2, PF94, Crystal, notably Repel-O-Tex SF2. The composition preferably comprises between 0.1 and 2.5% by weight of the soil release polymer.
Similar results may be obtained with sodium carboxymethylcellulose having a molecular mass of 40-200ku, Polyacrylic acid having a molecular mass of 2k-100ku, and Polythylene oxide having a molecular mass of 10k-100ku.
The best results are obtained when both the repel-o-tex polymer and the alkyl cellulose are included in the composition. Fatty acid alkyl esters
Fatty acid esters may be produced by an alkali-catalyzed reaction between fats or fatty acids and methanol/ethanol. Preferred examples include methyl laurate, ethyl octanoate, ethyl laurate, ethyl octanoate, methyl hexanoate, methyl myristate, methyl stearate.
Non-ionic Surfactants
Non-ionic surfactants are well-known in the art. They normally consist of a water- solubilising polyalkoxylene (preferably from 3 to10 ethoxy and/or propoxy groups) or a mono- or di-alkanolamide group in chemical combination with an organic hydrophobic group derived from, for example, fatty alcohols with from 9 to 15 carbon atoms
(optionally branched, e.g. methyl branched), alkylphenols (preferably from 12 to 20 carbon atoms) in which the alkyl group contains from about 6 to about 12 carbon atoms, dialkylphenols in which each alkyl group contains from 6 to 12 carbon atoms, primary, secondary or tertiary aliphatic alcohols (or alkyl-capped derivatives thereof) monocarboxylic acids having from 10 to about 24 carbon atoms in the alkyl group and polyoxypropylenes. Fatty acid mono- and dialkanolamides in which the alkyl group of the fatty acid radical contains from 10 to about 20 carbon atoms and the alkyloyl group having from 1 to 3 carbon atoms are also common. In any of the mono- and dialkanolamide derivatives, optionally, there may be a polyoxyalkylene moiety joining the latter groups and the hydrophobic part of the molecule.
In all polyalkoxylene containing surfactants, the polyalkoxylene moiety usually consists of an average of from 2 to 20 groups of ethylene oxide, propylene oxide groups or mixtures thereof. The latter class includes those described in European Patent
Specification EP-A-0,225,654, especially for use as all or part of the liquid phase, incorporated herein by reference.
Especially preferred are those ethoxylated non-ionics which are condensation products of fatty alcohols with from 9 to 15 carbon atoms condensed with 3 to 12 moles of ethylene oxide (generally understood to be an average value). Examples of those are the condensation products of C9 to C15 alcohols with 3 or 7 moles of ethylene oxide, or mixtures thereof. These may be used as the sole non-ionic surfactant or in combination with those described in EP-A-0,225,654.
Fabric Softening Cationic Co-surfactant
The fabric softening cationic co-surfactant is a quaternary ammonium salt surfactant, characterised in that the ammonium salt has the general formula: R1 R2R3R4N+ X-, wherein R1 to R4 are alkyl or aryl groups, and X- is an inorganic anion. Preferably partially hardened triethanolmaine ester quaternary surfactants are used. Specifically preferred quaternary ammonium cationic cosurfactants are Methyl bis[ethyl (tallowate)]- 2-hydroxyethyl ammonium methyl sulphate, Methyl bis[ethyl (palmate)]-2-hydroxyethyl ammonium methyl sulphate, etc. Anionic Surfactants
The anionic surfactant is selected from linear alkylbenzenesulfonates, branched alkylbenzenesulfonates, alkylpoly(ethoxylates), alkyl sulfates, methyl ester sulfonates, and mixtures thereof. Examples of anionic surfactants useful herein include any of the common anionic surfactants such as linear or modified, e. g. alkylbenzenesulfonate surfactants, alkylpoly(ethoxylate) surfactants, alkyl sulfates, methyl ester sulfonates, or mixtures thereof.
Ideally, when both an cationic surfactant and an anionic surfactant are present the ratio of Cationic to Anionic is between 5: 1 and 1 :1 , preferably between 3:1 and 1 : 1.
Further optional ingredients
The composition typically comprises a perfume, typically between 0.1 and 10% of the total composition, preferably between 0.1 and 5%, or even between 0.3 and 3% of the composition.
The composition may further comprise softening agents as commonly used in fabric softening compositions. Process for treating a fabric
In another aspect the invention provides a method for treating a substrate comprising the steps of preparing a 0.05 - 1 % by weight solution of the composition of the invention in water, rinsing a fabric article in the solution, and drying the fabric article. The solution is preferably 0.1 - 0.5% by weight of the composition in water.
The solution as dosed to a commercially available front load washing machine is tically between 25 and 100 ml of the composition into 12-15 L of rinse water. For top load washing machines the dosage is typically 50-150 ml to 50-60 L of rinse water.
Process for preparing the composition
In another aspect the invention provides a method for preparing the compositions according to the invention comprising the steps in sequence of partially neutralising fatty acid with the alkali source at a temperature above the melting point of the fatty acid, mixing the polymer into the partially neutralized fatty acid mixture, adding the aluminium salt to the mixture, homogenize the mixture, leave the composition to cool down to room temperature; and optionally add a perfume.
By room temperature is meant a temperature between 20 and 25°C.
The fatty acid is preferably partially neutralized with alkali solution at a temperature of less than 100°C, more preferably at a temperature of less than 90°C, still more preferably at a temperature of less than 80°C, or even less than 75°C, while the temperature is typically above the melting point of the fatty acid, typically at least 45°C, more preferably at least 50°C, still more preferably at least 55°C, or even at least 60°C.
Further ingredients according to the invention may be added subsequently.
Product Format
The product is typically packed in a bottle, preferably a plastic bottle at volumes of between 250 ml and 5 L, more preferably between 250 ml and 1.5 L. Common supermarket size bottles are 250 ml, 500 ml, 750ml, 1 L and 1.5 L. The bottles may optionally have a measuring cup attached, or a measuring scale indicator in the cap, to enable the consumer to dose the right amount into the rinse conditioner compartment of the washing machine.
Also considered in the context of the present invention is a product format in the form of a bottle with a trigger spray dispenser comprising the composition according to the invention. Trigger spray dispenser bottles typically have a volume of between 250 ml and 1.5 L. Common volumes include 400 ml, 500 ml, 750 ml, and 1 L.
Larger containers for industrial scale use are also included the scope of this invention.
Examples
The invention is now illustrated by means of the following non-limiting examples. Preparing the compositions
First, fatty acid was partially neutralized with alkali solution at 70 °C temperature. Then, polyvinyl alcohol was mixed into the partially neutralized fatty acid. After that, PAC was added to the above mixture. After the complete addition of PAC, the mixture was homogenized for 5 min and was allowed to cool down at room temperature (25 °C) and perfume was added to the cooled mixture and was mixed well. Further ingredients as used in some of the examples were added subsequently.
Fabric treatment protocol
All the treatment processes in the examples were carried out in a 5 kg front loader washing machine (IFB make, 5 kg) with 6°fH water. 10 of each cotton, poly-cotton and polyester 10x10 cm swatches were used for treatment. 3.5 kg of fabrics which comprised of a mix of cotton, poly-cotton (60:40) and polyester shirts were used as ballast material. The fabric swatches were stapled into one of the ballast shirts. 30 grams of Surf Excel Matic - Front Load (ex Hindustan Unilever Ltd, India) was used for the main-wash and it was dispensed through the detergent compartment of the machine. In a typical process, 40g of the test formulation as described in the examples, was used for fabric surface treatment and was dispensed through the fabric conditioner compartment of the machine during the third (=final) rinse. After the completion of the full cycle (comprising of wash and 3 rinses with spin), the swatches were removed and then dried in a drier and ironed.
Evaluation of fabric hydrophobicity
A droplet of water is dropped on a fabric kept horizontally from a height of ~2cm and the behaviour of the droplet is studies and ratings are given as tabulated below:
Hydrophobicity Ratings
Time taken by droplet to wick in fabric Hydrophobicity Rating
Fabric not wetted till 10s after contacting Superhydrophobic (SH)
Fabric not wetted till 5s after contacting or Fabric Hydrophobic (H)
is wetted between 5-10s after contacting
Fabric wetted in less than 5s after contacting Wicking (w) Staining Protocol
Carbon soot soiling: To 1 L of de-ionized water 150mg of carbon soot (Cabot India) was added and sonicated in a sonication bath for 2 hrs. 0.2 ml of this carbon soot slurry was dropped onto the fabric which was placed at an inclined plane of 45°. The fabrics were allowed to dry over-night.
Red mud soiling: To Ί It de-ionized water 5 g of red mud (sieved, < 150 microns) was added and sonicated in a sonication bath for 2 hrs. 0.2 ml of this slurry was dropped onto the fabric which was placed at an inclined plane of 45°. The fabrics were allowed to dry over- night.
Tea stain soiling: Two tea bags were dipped in 150ml hot milk to make tea. 0.2 ml of this tea was dropped onto the fabric which was placed at an inclined plane of 45°. The fabrics were allowed to dry over-night.
Dirty motor oil (DMO) soiling: 50 ml of dirty motor oil was mixed with 50 ml of fresh motor oil to obtain the stain. 0.2 ml of the stain was dropped onto the fabric which was placed at an inclined plane of 45°. The fabrics were allowed to dry over-night. Cooking oil soiling: 0.2 g of Macrolex (trademark) violet dye was added to 100 ml of sunflower oil and was mixed well. 0.2 ml of the stain was dropped onto the fabric which was placed at an inclined plane of 45°. The fabrics were allowed to dry over-night.
Washing Protocol
The soiled 10x10 cm swatches were stapled onto one of the ballast shirts (as described in the fabric treatment protocol). Total wash load was 3.5kg comprising of the soiled swatches and the ballast shirts. Washing was done with 30 grams Surf Excel Matic Front Load (ex Hindustan Unilever Ltd, India) at 6°fH. Cotton, poly-cotton and polyester swatches, both treated and untreated, were used for each study. A typical wash cycle comprised of wash and two rinses along with spin. After washing was completed, the swatches were removed and then dried in the drier. The extent of stain removal was compared against the control (untreated) fabrics on a one to a one basis for each stain type. A score "+" was given in cases where the stains on the treated fabrics appeared lighter than that on the untreated fabrics. Similarly, a score "-" was given in cases where the stains on the treated fabrics appeared darker than that on the untreated fabrics. In all the cases, the evaluation was done by a trained person.
Evaluation of Perfume Performance
50x50 cm polyester swatches were used for the perfume evaluation study. 5 swatches were treated with each of the test formulation, as described in the examples, in a manner already described. 40g of test formulation was used for treatment. As a control,
®
40g Comfort (Market sample-Batch no. B.876, Blue variant, India) was used. After 2 hours of treatment and drying, the perfume impact of the treated swatches was compared against the control (in this case Comfort treated) on a one to one basis for each set. A score "+" was given in cases where the perfume impact on the treated fabrics appeared greater than that on the control fabrics. Similarly, a score "-" was given in cases where the perfume impact on the treated fabrics appeared lesser than that on the control fabrics. In all the cases, the evaluation was done by trained persons. Materials
Prifac 5908, (ex Croda Chemicals - 55% Laurie, 22% Myristic, 22% Palmitic,1 % oleic) Commercially available Laurie acid
Poly aluminium chloride: Grade _ AC/100S (ex Grasim, India).
Polyvinyl alcohol (ex Sigma Aldrich, wt average MW - 13-250K, 87-89% hydrolyzed). Methyl cellulose (ex Sigma-Aldrich, 4000 cp, 2% H20 @ 20 °C))
PPG/PEG co-polymer: Pluronic F108 and F65 (ex BASF)
Soil release polymer: REPEL-O-TEX SF2 (ex Rhodia)
Example 1 : effect of fatty acid to poly aluminium chloride ratio
The composition was prepared as indicated above. Laurie acid was neutralised to ca 15%. The polymer used was Poly vinyl alcohol (PVA) having a Mw of 85-124k u.
Sodium hydroxide (NaOH) was used to neutralise the fatty acid. The following compositions were used (see table below). 1 % of perfume was used in the compositions below.
Figure imgf000020_0001
The balance is water.
The results for stability, hydrophobicity and perfume delivery are given in the table below
Figure imgf000020_0002
The table above shows that the perfume delivery throughout Example compositions Ex1-Ex4 is good. The best stability and hydrophobicity results are obtained with example Ex2 and 3.
Example 2: effect of fatty acid to poly aluminium chloride ratio
Example 1-4 were repeated with a commercially available mixture of fatty acids comprising 55% Laurie, 22% Myristic, 22% Palmitic and 1 % oleic acid (Prifac 5908, ex Croda), The polymer used was Poly vinyl alcohol (PVA) having a Mw of 13-23k u. Sodium hydroxide (NaOH) was used to neutralise the fatty acid. The following compositions were used (see table below). 1 % of perfume was used in the compositions below.
Figure imgf000021_0001
The balance is water.
The results for stability, hydrophobicity and perfume delivery are given in the table below
Figure imgf000021_0002
The table above shows that the perfume delivery throughout Example compositions Ex5-Ex8 is good. The best stability and hydrophobicity results are obtained with example Ex6 and Ex7.
Example 3: Effect of the degree of neutralisation of the fatty acid
In this example the effect of the degree of neutralization is demonstrated. The experiments were carried out as in Example 1. The polymer used was Poly vinyl ohol (PVA) having a Mw of 85-124k u. Sodium hydroxide (NaOH) was used to neutralise the fatty acid. The following compositions were used (see table below). 1 % of perfume was used in the compositions below.
Figure imgf000022_0001
The balance is water.
The results for stability, hydrophobicity and perfume delivery are given in the table below
Example Stability Perfume Hydrophobicity
delivery score Cotton Poly/cotton Polyester
Ex9 Phase + W W W
separated
Ex10 Phase + W W W
separated
Ex11 Yes + SH SH SH
Ex12 Yes + SH SH SH
Ex13 Phase + W W W
separated
Ex14 Phase + W W W
separated The table above shows that perfume delivery throughout the Ex9-Ex14 is good. The best stability and hydrophobicity results are obtained with example compositions Ex1 1 and Ex12.
Example 4: Effect of the HLB value of the polymer
In this example the effect of the HLB value of the polymer is demonstrated. The experiments we carried out as in Example 1.
All compositions in this example contained 20% Laurie acid and 20% PAC; other ingredients are listed below. The balance is water.
The following compositions were used (see table below). 1 % of perfume was used in the compositions below.
Figure imgf000023_0001
1) HLB was calculated by Griffin's method.
2) HLB was calculated by Group Calculation method.
The results for stability, and hydrophobicity are given in the table below Example Stability Hydrophobicity
Cotton Poly/cotton Polyester
Ex15 Yes SH SH SH
Ex16 Yes SH SH SH
Ex17 Phase SH SH SH
separated
CompA Phase W W W
separated
CompB Phase W W W
separated
CompC Phase W W W
separated
CompD Phase W W W
separated
The table above shows that the best hydrophobicity results are obtained with Ex15, Ex16 and Ex17. Ex 17 showed some phase separation, but is considered to be quite suitable for shake-before-use compositions.
Example 5: effect of degree polymer hydrolysis
Example 1 was repeated with different degrees of hydrolysis of the poly vinyl alcohol (PVA) polymer. The balance is water. All composition below contained 20% Laurie acid, 20% PAC, 0.6% NaOH. The concentration, type, HLB and degree of hydrolysis are given below.
The following compositions were used (see table below). 1 % of perfume was used in the compositions below.
Example Mol. wt. Degree of HLB PVA (%) Stability
(Mw) Hydrolysis (%) (1 )
Ex18 89k-98k 99 19.61 5 No
Ex19 146k- 186k 99 19.61 5 No
Ex20 85k-124k 99 19.61 5 No Ex21 31 k-50k 98-99 19.23 5 No
Ex22 85k-124k 96 18.49 5 No
Ex23 85k-124k 87-89 16.1 1 3 Yes
Ex24 13k-23k 87-89 15.48 3 Yes
The table above shows that compositions having an HLB below 18 give the best stability (i.e. no phase separation) of the composition.
Example 6: Effect of the addition of additional polymers
Example 1 was repeated and the cleaning efficacy on the subsequent wash was demonstrated and compared with a control without treatment.
Additionally some examples with optional further polymers were carried out and the effect of oily soil cleaning was demonstrated
The following compositions were used (see table below). 1 % of perfume was used in the compositions below.
Figure imgf000025_0001
The results for cleaning upon the subsequent wash are given in the table below Formulation Stain Type Cotton Polycotton Polyester
Carbon soot + + +
Tea stain + + +
Ex25 Red mud + + +
Dirty motor oil - - =
Cooking oil - - -
Carbon soot + + +
Tea stain + + +
EX26 Red mud + + +
Dirty motor oil - - =
Cooking oil - - =
Carbon soot + + +
Tea stain + + +
Ex27 Red mud + + +
Dirty motor oil = + +
Cooking oil = = =
Carbon soot + + +
Tea stain + + +
Ex28 Red mud + + +
Dirty motor oil + + +
Cooking oil = + +
The table above shows that the fabrics that are treated with compositions according to the invention all perform better than untreated upon the subsequent wash for carbon soot, tea and mud stains, while the compositions with the optional polymers, also perform better on the removal of oily soils (dirty motor oil and cooking oil).
Example 7: Effect of further metal ion.
The following materials were used in the examples below:
Prifac 5908, (ex Croda Chemicals - 55% Laurie, 22% Myristic, 22% Palmitic, 1 % oleic) Commercially available Laurie acid
Poly aluminium chloride: Grade _ AC/100S (ex Grasim, India).
CaCI2.2H20- CAS: 10035-04-8 Merck India
MgCI2.6H20- CAS: 7791-18-6 Merck India
ZnCI2- CAS: 7646-85-7 Merck India
NaOH- CAS: 1310-73-2 Merck India Polyvinyl alcohol Sigma Aldrich, wt average Mw of 85-124k u, 87-89% hydrolyzed)
First, fatty acid was partially neutralized with alkali solution at 70 °C temperature. Then, polyvinyl alcohol was mixed into the partially neutralized fatty acid. After that, an aqueous solution comprising of a mixture of PAC (poly aluminium chloride) and CaCI2.2H20 was added to the above mixture. After the complete addition of the solution containing Al and Ca, the mixture was homogenized for 5 min and was allowed to cool down at room temperature (25 °C) and perfume was added to the cooled mixture and was mixed well. Further ingredients as used in some of the examples were added subsequently.
Laurie acid was neutralised to 20%. The polymer used was Poly vinyl alcohol (PVA) having a Mw of 85-124k u. Sodium hydroxide (NaOH) was used to neutralise the fatty acid. PAC was used as a source of Aluminium. PAC contains 15% Al (mole calculation were done on this basis)
The following compositions were used (see table below). 1 % of perfume was used in the compositions below.
Figure imgf000027_0001
The results for stability, hydrophobicity and perfume delivery are given in the table below: Ex Stability Perfume Hydrophobicity DMO cleaning
delivery Cotton Poly- PolyCotton Poly- Polyscore cotton ester cotton ester
Ex 29 Yes + SH SH SH - - -
Ex 30 Yes + SH SH SH = - =
Ex 31 Yes + SH SH SH + = +
Ex 32 Yes + SH SH SH + + +
Ex 33 Solidified + W W W + + +
The results show that perfume delivery is good for al formulations. The results further show that a Al to Ca mole ratio greater than 2.3 leads to stable formulations but inferior oily (DMO) soil cleaning, a Al to Ca mole ratio between 0.5 to 2.3 leads to stable formulations with better oily (DMO) soil cleaning, and a Al to Ca mole ratio less than 0.5 leads to unstable formulations but better oily (DMO) soil cleaning.
Formulations are immediately stable, solidify upon keeping for overnight. Treatment was done immediately.
Example 8: Effect of Fatty acid to Total metal (Al + Ca) mole ratio:
The composition was prepared as indicated above. Laurie acid was neutralised to 20%. The polymer used was Poly vinyl alcohol (PVA) having a Mw of 85-124k u. Sodium hydroxide (NaOH) was used to neutralise the fatty acid. PAC was used as a source of Al. PAC contains 15% Al (mole calculation were done on this basis)
The following compositions were used (see table below). 1 % of perfume was used in the compositions below.
Example Laurie Acid PAC CaCI2.2H20
(%w) (moles) (%w) (moles of Al) (%w) (moles of Ca)
Ex 34 20 0.1 7.2 0.04 4.8 0.033
Ex 35 20 0.1 8.4 0.047 5.6 0.038
Ex 36 20 0.1 12 0.067 8 0.054 Ex 37 20 0.1 15 0.083 10 0.068
Ex 38 20 0.1 24 0.133 16 0.109 continued
Figure imgf000029_0001
The results for stability, hydrophobicity and perfume delivery are given in the table below:
Figure imgf000029_0002
The results show that the perfume delivery is good for all examples. The results further show that a fatty acid to (Al + Ca) mole ratio greater than 1.2 leads to unstable formulations, parity/better DMO cleaning, a fatty acid to (Al + Ca) mole ratio between 0.5-1.2 to leads to stable formulations with better oily (DMO) soil cleaning, and a fatty acid to (Al + Ca) mole ratio lesser than 0.5 leads to stable formulations, wetting in all cases and inferior oily (DMO) soil cleaning. Example 9: Effect of the degree of neutralisation of the fatty acid
The composition was prepared as indicated above. The polymer used was Poly vinyl alcohol (PVA) having a Mw of 85-124k u. Sodium hydroxide (NaOH) was used to neutralise the fatty acid. PAC was used as a source of Al. PAC contains 15% Al (mole calculation were done on this basis). 1 % of perfume was used in the compositions below.
Figure imgf000030_0001
The results for stability, hydrophobicity and perfume delivery are given in the table below:
Figure imgf000030_0002
The results show that the perfume delivery is good for all examples. The results further show that for Fatty acid neutralization below 10% and above 40% the formulation is unstable, while the formulation is stable between 15-40%. Example 10: With PAC and other metal ions
CaCI2. 2H20 (MW 147); MgCI2 .6H20 (MW 203) and Anhydrous ZnCI2 (MW 136) were used. PAC was used as a source of Al. PAC contains 15% Al (mole calculation were done on this basis) The following compositions were used (see table below). 1 % of perfume was used in the compositions below.
Figure imgf000031_0001
continued
Figure imgf000031_0002
The results for stability, hydrophobicity and perfume delivery are given in the table below:
Ex StabiPerfume Hydrophobicity DMO cleaning lity delivery Cotton Poly- PolyCotton Poly- Polyscore cotton ester cotton ester
Ex 43 Yes + SH SH SH + +
Ex 44 Yes + SH SH SH + +
Ex 45 Yes + SH SH SH + + + The results show that different metal salts provide the same effect.
Example 11 : Optional oil removal ingredients
The following further ingredients were use in the same experimental setup as above.
Figure imgf000032_0001
First, fatty acid was partially neutralized with alkali solution at 70 °C temperature. Then, polyvinyl alcohol was mixed into the partially neutralized fatty acid. After that, PAC was added to the above mixture. After the complete addition of PAC, the mixture was homogenized for 5 min and was allowed to cool down at room temperature (25 °C) and perfume was added to the cooled mixture and was mixed well. Further ingredients as used in some of the examples were added subsequently. The formulation containing a combination of anionic and cationic surfactant for enhanced oily soil removal was prepared as follows: Partially neutralising fatty acid with the alkali source at a temperature above the melting point of the fatty acid, mixing the polymer into the partially neutralized fatty acid mixture, adding a solution of aluminium salt to the mixture, homogenize the mixture, followed by addition of the cationic surfactant and then the anionic surfactant, the composition was then let to cool down to room temperature; and optionally perfume was added. By room temperature is meant a temperature between 20 and 25°C. Where used, LAS acid (RHODACAL SSA/R) was neutralized with 40% NaOH solution and the final pH of the mixture was set to 10. This mixture was used in all the experiments. The table below shows the compositions as used. 1 % of perfume was used in the compositions below.
Figure imgf000033_0001
The results are given below
Ex Stability Perfume delivery Hydrophobicity
score Cotton Poly/cotton Polyester
Ex 46 Yes + SH SH SH
Ex 47 Yes + SH SH SH
Ex 48 Yes + SH SH SH
Ex 49 Yes + SH SH SH
Ex 50 Phase + W W W separated
Ex 51 Yes + W SH SH
Ex 52 Yes + SH SH SH The table below shows that the fabrics that are treated with compositions according to the invention all perform better than untreated upon the subsequent was for carbon soot, tea and mud stains, while the compositions with the optional polymers, also perform better on the removal of oily soils.
Formulation Stain Type Cotton Polycotton Polyester
Carbon soot + + +
Tea stain + + +
EX46 Red mud + + +
Dirty motor oil - - =
Cooking oil - - -
Carbon soot + + +
Tea stain + + +
Ex47 Red mud + + +
Dirty motor oil + = +
Cooking oil = = +
Carbon soot + + +
Tea stain + + +
Ex48 Red mud + + +
Dirty motor oil = = =
Cooking oil = = +
Carbon soot + + +
Tea stain + + +
EX49 Red mud + + +
Dirty motor oil + = =
Cooking oil + + +
Carbon soot = - =
Tea stain - - =
Ex50 Red mud = = +
Dirty motor oil = = +
Cooking oil = = =
Carbon soot = = =
Tea stain + = =
Ex51 Red mud = - =
Dirty motor oil = - -
Cooking oil - - -
Carbon soot + + +
Tea stain + + +
Ex52 Red mud + + +
Dirty motor oil = = +
Cooking oil = = + Example 12: Effect of concentration of PVA
The composition was prepared as indicated above. Laurie acid was partially neutralised to 15%. The polymer used was Poly vinyl alcohol (PVA) having a Mw of 85-124k u. Sodium hydroxide (NaOH) was used to neutralise the fatty acid. Fatty acid to PAC ratio is fixed at 0.83.
The table below shows the compositions as used. 1 % of perfume was used in the compositions below.
Example Fatty Acid PAC NaOH FA: PAC PVA
(%w) (%w) (%w) ratio (%w)
Ex 53 10 12 0.2 0.83 0.1
Ex 54 10 12 0.2 0.83 0.2
Ex 55 10 12 0.2 0.83 0.5
Ex 56 10 12 0.2 0.83 3
Ex 57 10 12 0.2 0.83 12
The results for stability, hydrophobicity and perfume delivery are given in the table below:
Example Stability Hydrophobicity
Perfume
delivery score
Cotton Poly/cotton Polyester
Ex 53 Phase
+ SH SH SH separated
Ex 54 Phase
+ SH SH SH separated
Ex 55 Yes + SH SH SH
Ex 56 Yes + SH SH SH
Ex 57 Yes = W W W The results show that perfume delivery is good for all examples. The results further show that a PVA concentration of less than .3 % leads to unstable, phase separated compositions. Compositions according to the invention (Ex55 and Ex 56) show the best results for stability, hydrophobicity and perfume delivery.

Claims

Claims
1 A composition for treating a substrate, said composition comprising:
a 2 - 25% by weight of a C8-C24 fatty acid,
b 2.5-40% by weight of a water soluble salt of Aluminium,
c 0.01-2.0% by weight of an alkalinity source;
d 0.3 - 10% by weight of a non-ionic polymer having an HLB value of 10 to 20,
e Water, and
f Perfume; and
wherein the pH of the composition is between 1 and 6 and wherein 5 to 50% by weight of the total fatty acid is neutralised by the alkalinity source.
2 A composition according to claim 1 further comprising 5-30% of a salt of a further poly-valent metal ion, wherein the total amount of aluminium salt and polyvalent metal salt is between 7.5 and 40% by weight.
3 A composition according to claim 2, where in the ratio of Aluminium ion to polyvalent metal ion is in the range of 2.5: 1 and 1 :2.
4 A composition according to any one of claims 2 or 3, wherein the poly-valent metal ion is select from calcium, zinc, magnesium, barium and titanium
5 A composition according to any one of the preceding claims, further comprising 0.1 - 10% by weight of a perfume.
6 A composition according to any one of the preceding claims, further comprising 0.1 - 2.5% by weight of methyl cellulose.
7 A composition according to any one of the preceding claims, further comprising 0.1 - 2.5% by weight of a soil release polymer.
8 A composition according to any one of the preceding claims, wherein the non- ionic polymer has an HLB value of 12 to 18. A method for treating a substrate comprising the steps of:
a Preparing a 0.05 - 1 % by weight solution of the composition according to anyone of claims 1 to 8 in water,
b Rinsing a fabric article in the solution, and
c drying the fabric article. A method for preparing the composition according to anyone of claims 1 to 8, comprising the steps in sequence of:
a Partially neutralising fatty acid with the alkali source at a temperature above the melting point of the fatty acid,
b Mixing the polymer into the partially neutralized fatty acid mixture, c Adding the aluminium salt to the mixture,
d Homogenize the mixture,
e Leave the composition to cool down to room temperature; and
f Add the perfume. A bottled rinse conditioner agent comprising the composition according to anyone of claims 1 to 8 in a 250 ml to 5 L bottle. A trigger spray bottled rinse conditioner agent comprising the composition according to anyone of claims 1 to 8 in a 250 ml to 1.5 L bottle.
PCT/EP2013/050546 2012-01-31 2013-01-14 A composition and method for treating substrates WO2013113541A1 (en)

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