WO2013006877A1 - Vorrichtung und verfahren zum vergasen von biomasse - Google Patents
Vorrichtung und verfahren zum vergasen von biomasse Download PDFInfo
- Publication number
- WO2013006877A1 WO2013006877A1 PCT/AT2012/050074 AT2012050074W WO2013006877A1 WO 2013006877 A1 WO2013006877 A1 WO 2013006877A1 AT 2012050074 W AT2012050074 W AT 2012050074W WO 2013006877 A1 WO2013006877 A1 WO 2013006877A1
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- WO
- WIPO (PCT)
- Prior art keywords
- biomass
- reactor
- product gas
- hopper
- oxidation air
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C10J3/22—Arrangements or dispositions of valves or flues
- C10J3/24—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed
- C10J3/26—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed downwardly
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/02—Loose filtering material, e.g. loose fibres
- B01D39/04—Organic material, e.g. cellulose, cotton
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
- B01D39/1623—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
- B01D39/163—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin sintered or bonded
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C10J3/30—Fuel charging devices
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C10J3/32—Devices for distributing fuel evenly over the bed or for stirring up the fuel bed
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C10J3/34—Grates; Mechanical ash-removing devices
- C10J3/40—Movable grates
- C10J3/42—Rotary grates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/024—Dust removal by filtration
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/026—Dust removal by centrifugal forces
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/20—Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
- F23G5/0276—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using direct heating
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
- F23G5/14—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/24—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber
- F23G5/26—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber having rotating bottom
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/24—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber
- F23G5/28—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber having raking arms
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/44—Details; Accessories
- F23G5/46—Recuperation of heat
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/50—Control or safety arrangements
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/10—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of field or garden waste or biomasses
- F23G7/105—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of field or garden waste or biomasses of wood waste
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/0407—Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/12—Special parameters characterising the filtering material
- B01D2239/1233—Fibre diameter
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/12—Special parameters characterising the filtering material
- B01D2239/1241—Particle diameter
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1869—Heat exchange between at least two process streams with one stream being air, oxygen or ozone
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2206/00—Waste heat recuperation
- F23G2206/10—Waste heat recuperation reintroducing the heat in the same process, e.g. for predrying
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2206/00—Waste heat recuperation
- F23G2206/20—Waste heat recuperation using the heat in association with another installation
- F23G2206/203—Waste heat recuperation using the heat in association with another installation with a power/heat generating installation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2207/00—Control
- F23G2207/10—Arrangement of sensing devices
- F23G2207/102—Arrangement of sensing devices for pressure
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/12—Heat utilisation in combustion or incineration of waste
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the invention relates to a reactor for gasifying biomass, in particular wood, having a filling shaft and an ash bed arranged below the filling shaft.
- the invention relates to a fine filter for cleaning a product gas generated from biomass.
- the invention relates to a use of such a fine filter.
- the invention relates to a process for the gasification of biomass in a reactor, in particular in a reactor of the type mentioned, to a product gas.
- Biomass gasifiers are known as such from the prior art.
- a device is known, gasified with the biomass such as wood, straw or biological waste in a reactor and a resulting gas is then passed into a gas-powered engine, where this gas
- Combustion is converted into mechanical energy.
- the motor is connected to a generator, which converts the mechanical energy into electrical energy.
- the object of the invention is to overcome or reduce the disadvantages of the prior art by providing a reactor with which a more efficient method is possible. In addition, a fine filter is to be specified, which further increases the efficiency of such a method.
- the aim is further to specify a use of such a fine filter.
- the first object is inventively achieved in that in a reactor of the type mentioned a device is provided, with the biomass adhering to the hopper is solvable and / or a heat exchanger is provided, with a produced from the biomass product gas heat tracked in the hopper
- the heat exchanger with which the heat of the product gas can be transferred to the biomass in the hopper and the oxidation air in particular also has the advantage that an energy required for pyrolysis and preheating the oxidation air can be taken from the product gas, so less Energy must be taken from the biomass and a temperature of the
- Product gases can be reduced. If the product gas in one
- the multiple jacket is formed such that it has a plurality of approximately cylindrical, approximately concentric coats, between a first jacket, which forms the hopper, and a second jacket, which encloses the first jacket, product gas in a preferred vertical installation due to thermal buoyancy can flow from bottom to top and around this second jacket, a third jacket is arranged such that the area between the second jacket and the third jacket of the oxidizing air can be flowed through. In this way, heat transfer from the product gas via the first jacket or biomass in the feed chute and over the second mantle to oxidation air can take place and the temperature of the product can be increased
- the first jacket which on the one hand borders the biomass and, on the other hand, the product gas, preferably consists of temperature- and acid-resistant material, for example an austenitic chromium-nickel-molybdenum steel.
- the second jacket adjacent to the oxidizing air as well as to the product gas is preferably made only in a lower region of heat-resistant steel and in an upper region of a normal boiler plate in order to minimize manufacturing costs. It is advantageous if an insulating layer of a heat-insulating material is applied to the third jacket, which is preferably also made of steel, in order to prevent heat from the oxidizing air from being emitted to an environment.
- the hopper can be added by means of the vibrator vibrated.
- the vibrator may consist of a motor and an imbalance or other electromagnetic associated with the motor or mechanical devices, oscillations of the vibrating device are preferably transferable by means of molding tubes to the hopper. These forming tubes can form a direct connection between the vibrator and the hopper; but it can also be provided that the vibrator is connected indirectly via flexible connecting elements with the hopper.
- the connection between vibrator and hopper is preferably designed such that temperature-induced mechanical stresses throughout the reactor are minimized and a tightness of the hopper is permanently guaranteed.
- the vibrator is activated at regular intervals between 10 and 30 minutes, preferably between 15 and 25 minutes, more preferably about 20 minutes for a few seconds, preferably for about 5 seconds.
- the wedge slide preferably comprises a slide plate, which is guided linearly movable in a groove of a frame rigidly connected to the feed chute.
- the wedge slide and the frame are preferably components of a lock over which the biomass the
- connection of the slide plate with the frame is preferably carried out particularly wear with one or more ball bearings. Other types of storage are possible. Due to an acidic atmosphere in the
- Hopper is the entire wedge slide or parts thereof in an acid-resistant material, preferably an acid-resistant steel executed. It is advantageous that a sealed feed device is provided, with which the biomass can be fed to the feed chute in the absence of oxygen. This is particularly important, therefore, in order to prevent unwanted gases, in particular oxygen, from entering the feed chute in order to be able to trigger chemical reactions in the feed chute in a targeted manner, that of a controlled or controlled one
- Air ratio are dependent.
- the feed chute is tapered in a lower region, in particular with a ratio of one
- Chute cross section measured in a cylindrical upper portion of the hopper and the fire zone cross section in a fire zone. Since the biomass changes its volume as it moves through the lower part of the pyrolysis that takes place in this lower region, it is advantageous if the hopper is adapted to a volume change of the biomass, to ensure a uniform flow velocity of the biomass and optimal conditions for the running chemical To enable processes.
- a cone angle between a cone axis and a lateral surface of the conical lower region is between 20 ° and 60 °, more preferably between 30 ° and 50 °, in particular about 40 °.
- the fire zone adjoining this conical region is preferably cylindrical
- a lower region between the fire zone and a constriction, which further adjoins the fire zone is preferably likewise conical, in order to constructively take into account the volume change of the biomass even in this lowermost region.
- a cone angle of this lowermost region is preferably between 20 ° and 60 °, more preferably between 30 ° and 50 °, in particular about 40 °. This cone angle can also correspond to the cone angle of the lower region.
- an oxidation air supply is connected via an intermediate region and an oxidation air ring with oxidation air nozzles, which open into a fire zone.
- the oxidation air can be preheated both in the intermediate region, which is preferably thermally connected to a product gas region, and in the oxidation air ring, which is preferably thermally connected to the fire zone. This preheating the oxidation air is made particularly favorable. Another advantage can also be seen in the fact that the oxidation air can occur evenly over a circumference of the fire zone in this and thus can be evenly distributed in the fire zone.
- an air outlet velocity at the oxidation air nozzles can be particularly favorably influenced, which has a high influence on a chemical reaction in the fire zone.
- a higher air outlet velocity results in a higher temperature in the fire zone, but a spatial extension of a glow zone is less.
- According to a composition and a calorific value of the biomass can be an optimal Change air inlet cross section. It has proven particularly useful that a sum of all cross sections of the oxidation air nozzles corresponds to between 1% and 10%, preferably between 2% and 8%, in particular approximately 4%, of a constriction cross section.
- the constriction cross section is that cross section of the hopper at which the biomass can escape from the hopper to the ash bed.
- the oxidation air nozzles are distributed so uniformly over a circumference of the fire zone, that between two oxidation air nozzles at the periphery of the fire zone, a distance of between 2 and 30 cm, preferably between 5 and 20 cm, in particular about 10 to 12 cm ,
- a distance of between 2 and 30 cm preferably between 5 and 20 cm, in particular about 10 to 12 cm
- Oxidation air nozzles preferably arranged in a plane a multi-level arrangement is also possible. Depending on the extent of the fire zone, this results in a particularly favorable number for the chemical reaction in the fire zone
- Oxidation air nozzles and a favorable air velocity Oxidation air nozzles and a favorable air velocity.
- a rotary grate is provided with at least one stirring pin on the ash bed, are solvable with the packaging of biomass.
- the rotary grate thereby enables a uniform burning of the biomass and additionally serves one
- Ash discharge into an underlying ash cone is preferably carried out by means of a linear motor via a drive linkage.
- the drive linkage is preferably gas-tightly sealed by means of a stuffing box, which has a temperature-resistant graphite sealing cord for producing a tightness.
- the at least one stirring pin enables a loosening of the grate-gripping biomass in a particularly favorable manner.
- sensors are provided with which a pressure before and after the ash bed can be measured in order to use data obtained during a measurement for a control and / or regulation of the stirring pins.
- attachments of biomass to the rotating grate are particularly easily recognizable, since packaging leads to an increased difference between a pressure before and a pressure after the rotary grate.
- the stirring pins can be activated exactly when more
- Apparatus for producing a product gas from biomass comprising
- Fuel storage for the biomass a reactor for gasifying the biomass, at least one conveying means for conveying the biomass from the fuel storage in the reactor and at least one filter system for cleaning generated from the biomass
- Product gas, the reactor is designed according to the invention.
- This biomass can fully automatically transported from a fuel storage in the reactor and the product gas are then cleaned in a filter system.
- the system efficiency of the entire device is better than in the case of devices of the prior art.
- At least one cyclone filter is arranged downstream of the reactor.
- the product gas is freed of dust and fly ash, so that the product gas has a higher quality for further use.
- three parallel cyclone filters are provided, whereby only one cyclone filter or more than three cyclone filters are equally possible.
- Several cyclone filters can be arranged parallel or serially through by gas, wherein a
- Zyklonfilteraschemic matterer is arranged such that an ash that can be deposited in the at least one cyclone filter, preferably automatically in the
- Cyclone filter ash container is passed.
- Zyklonfilterasche meansers below the cyclone filter this is particularly easy.
- the operation of the cyclone filter is well known and is based on a centrifugal force, with the dust and
- At least one fine filter is connected downstream of the reactor, which contains biomass as a filter medium.
- This fine filter can the cyclone filter
- Product gas is conductive, and the internal combustion engine is coupled to a generator for generating electrical energy.
- a generator for generating electrical energy.
- another internal combustion engine for example a gas turbine, may also be provided. This allows the device biomass fully automatically convert into electrical energy.
- a waste heat heat exchanger is provided, with which a heat of an exhaust gas of the internal combustion engine to the biomass for preheating the same is transferable.
- a system efficiency of the entire system is further increased, since the heat of the exhaust gas of the internal combustion engine can be reused.
- the second object is achieved in that contains a fine filter of the type mentioned as a filter medium biomass.
- This biomass may preferably contain wood chips according to ⁇ NORM M7133 G50 or G30 as well as sawdust.
- Advantage of this design is that the filter medium transported after a long period of use in the fuel storage and can be processed in the reactor such as biomass, so this filter medium is easily recyclable.
- This filter medium is preferably flowed through in the fine filter from bottom to top of the product gas, with impurities present in the product gas, in particular tar, settling on the biomass.
- the biomass can be stored on one or more levels. It can also be provided a sensor that measures a pressure drop across the filter and so the optimal time to transfer the polluted biomass in the
- the filter medium is on several levels in the filter on porous perforated plates, preferably perforated plates, and is serially from the product gas from bottom to top flowed through. It has a bottom layer about 20% wood chips and about 80% sawdust and a top layer about 70% wood chips and about 30% sawdust. In intermediate layers, a proportion of wood chips is above the lowest layer and rises to the top layer. It is preferred that wood chips and sawdust are made of spruce wood.
- the third object is achieved by using a filter according to the invention for purifying a product gas produced from biomass, in particular for depositing tar. This makes it possible to achieve a particularly cost-effective and environmentally friendly type of product gas purification.
- the fourth object is achieved in that dissolved in a method of the type mentioned at the hopper biomass and / or released from the product gas heat to biomass and an oxidation air.
- a shaking device at certain intervals, preferably at intervals of 10 to 30 minutes, in particular 15 to 25 minutes, preferably about 20 minutes, for the duration of less than 5 minutes, preferably less than 1 minute, particularly preferably for about 5 seconds, to release biomass attached to the hopper.
- a flow velocity of the biomass in a lower region of the feed chute is kept approximately constant over a conical design of the feed chute in this region. Since the biomass in the lower region changes its volume due to chemical reactions, a conical design of the hopper, which leads to a uniform flow rate, has a particularly favorable effect
- Conditions of these chemical reactions such as pressure or temperature off. It is advantageous that in a lowermost region of the filling shaft, in particular in the region of a constriction, in more than 50%, in particular more than 70%, preferably more than 90% of the biomass, a temperature between 1000 ° C and 1600 ° C, in particular 1200 ° C and 1500 ° C, preferably 1220 ° C and 1470 ° C, is located. This ensures cracking of long-chain hydrocarbons (tars) and thus avoids or at least reduces the accumulation of long-chain hydrocarbons in pipelines and in any downstream internal combustion engine. It has been proven that a pressure drop over an ash bed continuously measured and when a predetermined limit is exceeded, a stirring device in
- Ash bed is activated. This allows the identification and detachment of biomass on the ash bed or on a rotating grate, so that the functionality of the
- Oxidation air ring to air nozzles flows into a fire zone, where oxidation of
- Biomass is caused. This ensures that the oxidation air is sufficiently preheated, so that higher product gas temperatures are reached after the oxidation zone. Through the oxidation air ring and the oxidation air nozzles, the air can be distributed evenly into the fire zone, so that even temperatures are reached.
- FIG. 1 shows a schematic representation of a reactor according to the invention for gasification of biomass
- Fig. 2 is a schematic representation of a device for generating a
- Fig. 3 is an illustration of a fine filter with biomass as a filter medium.
- Fig. 1 shows a schematic representation of a reactor 1 for gasifying
- Biomass, especially wood Via a lock 6, the biomass can be introduced with a head-side wedge gate in the reactor 1 and a hopper 7, which is sealed gas-tight by means of a temperature-resistant Graphitdichtschnur to accurately control an oxygen content in the reactor 1 can.
- the wedge gate valve is equipped with position sensors so that a current position of a slide plate can be detected at any time for automatic operation.
- a drive of the slide plate by means of an electric motor.
- Attached to the side of the reactor 1 is a vibrating device 8 with which biomass adhering to the filling shaft 7 can be released. A shaking movement is for this purpose of the vibrator 8 via one or more molding tubes 9 to the hopper 7 transferable.
- a transmission of the vibrating motion with other structural components instead of a forming tube 9 is possible, for example mechanically softer or stiffer components in order to achieve an optimal croqutteltex.
- the vibrator 8 is regularly activated every 20 minutes for about 5 seconds to dissolve adhering biomass from the hopper 7.
- the choice of longer intervals between the shaking intervals as well as longer shaking intervals are just as possible as the choice of shorter times for these intervals.
- the regulation of the vibrator 8 is possible via a sensor which detects a volume or mass of an adherent biomass and tuned to the vibrator 8 activated.
- the first jacket 23 is partially conical, with an angle between a conical axis and a conical surface being approximately 40 °, whereby the conical formation is interrupted by a cylindrically formed fire zone 13 and ends a constriction 17, at which the biomass can emerge from the hopper 7 to an ash bed during operation
- a constriction ratio of a Feuerzonenqueriteses to a Gression rrough is about 1: 1, 9, the constriction ratio formed with the cross section of the hopper 7 in the cylindrical upper portion 10
- This necking ratio and angle depend on a composition of the biomass and may be smaller or larger depending on the application, for example, the necking ratio is about 1: 1, 8 for a softwood as a major component of the biomass and about 1: 2 for hardwood as one m main component of biomass.
- an oxidation air ring 15 is arranged around the hopper 7, which is connected via a compensator, which can compensate for thermal expansion, with the intermediate region. From the oxidation air ring 15 protrude Oxidation air nozzles 16 in a plane in the fire zone 13. In the exemplary embodiment, the number of oxidation air nozzles 16 is selected such that over a circumference of the
- Fire zone 13 between the centers of the oxidation air nozzles 16 remains a distance of about 10 to 12 cm in the circumferential direction.
- Oxidation air nozzles 16 is chosen such that the sum of all cross sections corresponds to about 4% of a constriction cross section. However, the function is also at other cross-sectional ratios, for example 1% to 20%, or distances between the oxidation air nozzles 16, for example 1 to 30 cm, at least
- constriction cross section is that smallest cross section of the hopper 7, through which the biomass exits from the hopper 7 to the ash bed.
- the ash bed on which the biomass falls after passing through the reactor 1.
- the ash bed in this case comprises a rotary grate 18, which is connected via a drive linkage with a motor, preferably a linear motor 20, and can be driven by this.
- a gas-tight implementation of the drive linkage from the rotary grate 18 to the outside of the reactor 1 lying engine is achieved via a stuffing box, which with a temperature-resistant
- Graphite sealing cord is sealed.
- Stirring pins 19 are arranged on the rotating grate 18, with which biomass adhering to the rotating grate 18 can be detached.
- Adhering biomass obstructs an ash discharge in a arranged under the rotary grate 18 ash cone 21 and due to an increased pressure loss on the rotary grate 18 unimpeded outflow of the product gas.
- the optimum time is determined at which the stirring pins 19 are activated and biomass is released from the rotary grate 18. As a result, a function of the reactor 1 is constantly monitored.
- a product gas flows from the constriction 17 upwardly out of the reactor 1.
- an oxidation air flows from an oxidation air supply 43 to an oxidation air ring 15.
- biomass which is introduced by the wedge slide in the hopper 7 and this passes from top to bottom.
- the product gas gives heat via the first jacket 23 to the biomass located in the filling shaft 7 and via the second jacket 24 to the From oxidation air.
- Biomass adhering to the filling shaft 7 is achieved by activating the vibrating device 8 for 5 seconds after every 20 minutes.
- the biomass is dried in the upper region 10 of the hopper 7 by a heat of the product gas and preheated.
- the middle range 1 1 begins the pyrolysis, in the course of a thermal decomposition, inter alia, organic acids such as acetic acid,
- Methyl alcohol and tar arise. Further decomposes in this central region 1 1 at a temperature of 200 ° C to 300 ° C hemicellulose, which is possibly contained in the biomass. Upon further heating, between 325 ° C and 375 ° C contained in the biomass cellulose is split and it produces carbon dioxide, methane and organic acids, especially acetic acid. As the temperature rises above 375 ° C, lignin breaks down into smaller chemical compounds. Next fall
- a lower region 12 of the hopper 7 the oxidation of the biomass begins.
- Oxidation air nozzles 16 the oxidation air supplied and burn it
- a temperature is about 650 ° C to 850 ° C, with carbon dioxide, water and methane.
- a temperature range can be particularly favorable control over the amount of the supplied oxidizing air and a speed at which the oxidation air penetrates.
- the formation of combustible gas is made possible inter alia by a gasification of carbon.
- the resulting in the oxidation intermediates such as carbon dioxide and water are reduced in hot spots, with carbon monoxide, hydrogen and higher
- Constriction 17 ideal temperatures between 1220 ° C and 1470 ° C reached, which are close to the ash melting point of the biomass. A limited function is also possible in a temperature range of 1000 ° C to 1600 ° C.
- Forming the filling shaft 7 in the lowermost region 14 can be in particular in the region of the Einschürung 17 over a large part of the volume of the biomass one achieve consistent temperature, with the cracking of long-chain
- the stirring pins 19 are actuated to the exact extent necessary to dissolve adherent biomass.
- a pressure difference is measured before and after the rotary grate 18 and these values are used for a control of the stirring pins 19.
- Fig. 2 shows a device 2 in which the reactor 1 is embedded in order to produce a product gas from biomass.
- the biomass can be transported from a fuel storage 3 by means of a conveyor 4 via a biomass dryer 5 in the reactor 1.
- a gas outlet of the reactor 1 is connected to cyclone filters 27, where the product gas can be freed of dust and fly ash.
- three parallel cyclone filters 27 are provided, which can be flowed through uniformly and in parallel by gas.
- the product gas at a very high speed in a circular path feasible, so that due to a centrifugal force dust and ash are pressed radially outward, from where this down into a
- Cyclone filter ash container 28 can be discharged.
- a fine filter 29 Downstream of the cyclone filter 27 is a fine filter 29, in which the product gas is cleaned by means of wood chips and sawdust.
- a particular advantage of the wood chips as a filter material in this fine filter 29 is that the wood chips, after they are saturated with impurities, fed to the fuel storage room and thus can be recycled directly. In this way, no filter waste.
- the fine filter 29 is formed such that it is flowed through during operation of the product gas from bottom to top, with dirt and tar on the wood chips can start.
- a gas outlet of the fine filter 29 is connected to a four-cylinder gasoline engine or generally an internal combustion engine 30, which drives a generator 31 and thus can convert the energy of the gas into electrical energy.
- a gas turbine or other machinery is possible, which can convert a chemical energy of a product gas into mechanical energy and subsequently into electrical energy.
- Downstream of the gas engine is a waste heat heat exchanger 32, which makes use of waste heat of the gas engine for preheating the biomass and for any heating purposes. It can be seen in Fig. 2, a biomass preheating line 33, of which at least a portion of the residual heat of
- Product gas for the preheating of biomass in biomass dryer 5 is usable.
- a heat storage 34 for temporary storage of waste heat is also provided.
- the method for purifying biomass-derived product gas and further processing into electrical energy works with the device 2 such that the biomass is supplied from the fuel storage 3 by means of the conveyor 4 via the lock 6 to the hopper 7. Subsequently, the biomass is gasified as described above in the reactor 1 to product gas. After exiting the reactor 1 is the
- Fig. 3 shows a representation of the fine filter 29, is used in the biomass as a filter material.
- the product gas may enter the fine filter 29 via a product gas inlet 35 at a lower end.
- the filter medium is distributed over four layers 38, 39, 40, 41 on perforated plates 37, through which the product gas can flow.
- the perforated plates 37 are preferably formed from sheets with a plurality of holes, but it can also be another type of porous bottom can be selected, which is preferably formed temperature resistant.
- the product gas flows through the fine filter 29 during operation from bottom to top and flows serially through the individual levels until it leaves the fine filter 29 cleaned at the product gas outlet 36.
- the product gas flows through the fine filter 29 during operation from bottom to top and flows serially through the individual levels until it leaves the fine filter 29 cleaned at the product gas outlet 36.
- the filter medium of the layer 38 consists of 20% wood chips and 80% sawdust, the filter medium of the layer 39 to 30% from wood chips and 70% from sawdust, the filter medium layer 40 to 50% from wood chips and 50% from sawdust and the filter medium of the layer 41 to 70% of wood chips and 30% of sawdust.
- Wood chips and sawdust are preferably made of spruce wood, but it is also conceivable to use other types of biomass, with a filter performance depends on the biomass used.
- a particular advantage of the use of biomass as a filter medium is that the biomass after contamination in the fine filter 29 fed to the fuel storage 3 and thus can be recycled in the simplest way. An optimal time to exchange the
- Filter media due to contamination can be determined by a pressure difference measurement, with a pressure drop across the fine filter 29 is measured.
- a pressure difference measurement with a pressure drop across the fine filter 29 is measured.
- a purely time-dependent exchange of the filter media is possible. If the filter media are replaced time-dependent, replacement after approx. 100 operating hours is recommended.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Wood Science & Technology (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Processing Of Solid Wastes (AREA)
- Industrial Gases (AREA)
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- Chimneys And Flues (AREA)
- Filtering Materials (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/232,468 US20140290593A1 (en) | 2011-07-14 | 2012-05-24 | Device and method for gasifying biomass |
AU2012283719A AU2012283719A1 (en) | 2011-07-14 | 2012-05-24 | Device and method for gasifying biomass |
CN201280045157.5A CN103797095A (zh) | 2011-07-14 | 2012-05-24 | 用于气化生物质的装置及方法 |
RU2014105490/05A RU2014105490A (ru) | 2011-07-14 | 2012-05-24 | Реактор и способ газификации биомассы, устройство получения газа из биомассы, фильтр тонкой очистки полученного из биомассы газа и способ очистки названного газа |
EP12730142.2A EP2732011A1 (de) | 2011-07-14 | 2012-05-24 | Vorrichtung und verfahren zum vergasen von biomasse |
CA2841898A CA2841898A1 (en) | 2011-07-14 | 2012-05-24 | Device and method for gasifying biomass |
BR112014000781A BR112014000781A2 (pt) | 2011-07-14 | 2012-05-24 | dispositivo e método para gaseificação de biomassa |
JP2014519339A JP2014527095A (ja) | 2011-07-14 | 2012-05-24 | バイオマスを気化させるデバイスおよび方法 |
IN256MUN2014 IN2014MN00256A (de) | 2011-07-14 | 2014-02-07 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ATA1033/2011A AT511684B1 (de) | 2011-07-14 | 2011-07-14 | Vorrichtung und verfahren zum vergasen von biomasse |
ATA1033/2011 | 2011-07-14 |
Publications (1)
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WO2013006877A1 true WO2013006877A1 (de) | 2013-01-17 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/AT2012/050074 WO2013006877A1 (de) | 2011-07-14 | 2012-05-24 | Vorrichtung und verfahren zum vergasen von biomasse |
Country Status (12)
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US (1) | US20140290593A1 (de) |
EP (1) | EP2732011A1 (de) |
JP (1) | JP2014527095A (de) |
CN (1) | CN103797095A (de) |
AT (1) | AT511684B1 (de) |
AU (1) | AU2012283719A1 (de) |
BR (1) | BR112014000781A2 (de) |
CA (1) | CA2841898A1 (de) |
EC (1) | ECSP14013210A (de) |
IN (1) | IN2014MN00256A (de) |
RU (1) | RU2014105490A (de) |
WO (1) | WO2013006877A1 (de) |
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FR3043090A1 (fr) * | 2015-11-04 | 2017-05-05 | Haffner Energy | Dispositif de pyrolyse avec secousses |
CN110097989A (zh) * | 2018-01-31 | 2019-08-06 | 中国辐射防护研究院 | 一种用于球床高温气冷堆的去石墨粉尘污染方法 |
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CA2923215A1 (en) * | 2013-09-05 | 2015-03-12 | Ag Energy Solutions, Inc. | Apparatuses, systems, mobile gasification systems, and methods for gasifying residual biomass |
ITMO20150098A1 (it) * | 2015-05-05 | 2016-11-05 | Syn Gas Gruppo S R L | Reattore per impianti di gassificazione |
CN105674283B (zh) * | 2016-03-21 | 2018-09-07 | 安徽未名生物环保有限公司 | 一种热解气化炉内循环控制*** |
CN105805761B (zh) * | 2016-03-21 | 2018-07-20 | 安徽未名生物环保有限公司 | 一种垃圾燃烧热能利用装置 |
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US11370983B2 (en) | 2019-02-04 | 2022-06-28 | Eastman Chemical Company | Gasification of plastics and solid fossil fuels |
US11447576B2 (en) | 2019-02-04 | 2022-09-20 | Eastman Chemical Company | Cellulose ester compositions derived from recycled plastic content syngas |
US11939406B2 (en) | 2019-03-29 | 2024-03-26 | Eastman Chemical Company | Polymers, articles, and chemicals made from densified textile derived syngas |
CN114728223A (zh) * | 2019-11-11 | 2022-07-08 | 塔卡查有限公司 | 用于控制生物质转化***的***和方法 |
JP7501042B2 (ja) * | 2020-03-30 | 2024-06-18 | 三機工業株式会社 | フィルタ装置及びバイオマス発電システム |
CN114321956B (zh) * | 2021-12-20 | 2022-10-28 | 徐州长盛电力设备有限公司 | 一种具有废气分离处理功能的环保型电杆生产用工业锅炉 |
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CN116084872B (zh) * | 2023-04-11 | 2023-06-27 | 任丘市华北石油铖达节能设备有限公司 | 一种原油运移助推装置 |
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-
2011
- 2011-07-14 AT ATA1033/2011A patent/AT511684B1/de not_active IP Right Cessation
-
2012
- 2012-05-24 BR BR112014000781A patent/BR112014000781A2/pt not_active IP Right Cessation
- 2012-05-24 CN CN201280045157.5A patent/CN103797095A/zh active Pending
- 2012-05-24 US US14/232,468 patent/US20140290593A1/en not_active Abandoned
- 2012-05-24 RU RU2014105490/05A patent/RU2014105490A/ru not_active Application Discontinuation
- 2012-05-24 EP EP12730142.2A patent/EP2732011A1/de not_active Ceased
- 2012-05-24 JP JP2014519339A patent/JP2014527095A/ja active Pending
- 2012-05-24 CA CA2841898A patent/CA2841898A1/en not_active Abandoned
- 2012-05-24 AU AU2012283719A patent/AU2012283719A1/en not_active Abandoned
- 2012-05-24 WO PCT/AT2012/050074 patent/WO2013006877A1/de active Application Filing
-
2014
- 2014-02-07 IN IN256MUN2014 patent/IN2014MN00256A/en unknown
- 2014-02-14 EC ECSP14013210 patent/ECSP14013210A/es unknown
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103822214A (zh) * | 2014-03-13 | 2014-05-28 | 四川耀农机电科技有限公司 | 环保型生活垃圾焚烧炉 |
CN103822214B (zh) * | 2014-03-13 | 2015-12-23 | 四川耀农机电科技有限公司 | 环保型生活垃圾焚烧炉 |
FR3043090A1 (fr) * | 2015-11-04 | 2017-05-05 | Haffner Energy | Dispositif de pyrolyse avec secousses |
WO2017077245A1 (fr) | 2015-11-04 | 2017-05-11 | Haffner Energy | Dispositif de pyrolyse avec secousses |
CN110097989A (zh) * | 2018-01-31 | 2019-08-06 | 中国辐射防护研究院 | 一种用于球床高温气冷堆的去石墨粉尘污染方法 |
CN110097989B (zh) * | 2018-01-31 | 2022-11-18 | 中国辐射防护研究院 | 一种用于球床高温气冷堆的去石墨粉尘污染方法 |
Also Published As
Publication number | Publication date |
---|---|
AU2012283719A1 (en) | 2014-02-13 |
IN2014MN00256A (de) | 2015-09-25 |
EP2732011A1 (de) | 2014-05-21 |
AT511684B1 (de) | 2013-12-15 |
AT511684A1 (de) | 2013-01-15 |
US20140290593A1 (en) | 2014-10-02 |
ECSP14013210A (es) | 2014-03-31 |
CN103797095A (zh) | 2014-05-14 |
RU2014105490A (ru) | 2015-08-20 |
JP2014527095A (ja) | 2014-10-09 |
CA2841898A1 (en) | 2013-01-17 |
BR112014000781A2 (pt) | 2017-03-01 |
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