WO2012173313A1 - Verre décoratif utilisant du papier coréen et son procédé de fabrication - Google Patents

Verre décoratif utilisant du papier coréen et son procédé de fabrication Download PDF

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Publication number
WO2012173313A1
WO2012173313A1 PCT/KR2011/008848 KR2011008848W WO2012173313A1 WO 2012173313 A1 WO2012173313 A1 WO 2012173313A1 KR 2011008848 W KR2011008848 W KR 2011008848W WO 2012173313 A1 WO2012173313 A1 WO 2012173313A1
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Prior art keywords
layer
eva resin
hanji
glass
heating
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PCT/KR2011/008848
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English (en)
Korean (ko)
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김종섭
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(주)로움
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Publication of WO2012173313A1 publication Critical patent/WO2012173313A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B32B17/10256—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques
    • B32B17/10266—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons created by printing techniques on glass pane
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10018—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10788—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00—Layered products comprising a layer of paper or cardboard
    • B32B29/06—Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00—Inking and printing with a printer's forme
    • B41M1/26—Printing on other surfaces than ordinary paper
    • B41M1/34—Printing on other surfaces than ordinary paper on glass or ceramic surfaces
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001—General methods for coating; Devices therefor
    • C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2315/00—Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
    • B32B2315/08—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2317/00—Animal or vegetable based
    • B32B2317/12—Paper, e.g. cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2331/00—Polyvinylesters
    • B32B2331/04—Polymers of vinyl acetate, e.g. PVA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/14—Printing or colouring
    • B32B38/145—Printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/16—Drying; Softening; Cleaning
    • B32B38/162—Cleaning
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00—Inking and printing with a printer's forme
    • B41M1/12—Stencil printing; Silk-screen printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0054—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or film forming compositions cured by thermal means, e.g. infrared radiation, heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/72—Decorative coatings

Definitions

  • the present invention relates to a decorative glass using Hanji and a method of manufacturing the same, and more particularly, it is made in the traditional manner through a pattern layer and a Hanji layer and a back sheet that are sequentially printed and attached to the back of the glass plate and the ancient texture of Hanji and Using the hanji, the unique characteristics and colors of each layer can be well expressed according to the viewing angle, and the shell of the hanji can be visually expressed through the phosphorescence phenomenon.
  • the present invention relates to a decorative glass and a method of manufacturing the same.
  • decorative glass is attached to prevent damages such as scratches on the surface of the furniture, buildings, and home appliances that are widely used in homes and businesses.
  • Such decorative glass is usually formed through heat treatment to etch the surface of the glass plate or to form multiple printed layers to express various colors and patterns.
  • the decorative glass having a printing layer of the conventional decorative glass is disclosed in Korean Patent Laid-Open Publication No. 10-2009-0105254 (Application No. 10-2008-0030585) "Decorative glass for refrigerators and a method of manufacturing the same" Patent Publication No. 10-2009-0021022 "Decorative glass and its manufacturing method" has been proposed, they form a printing layer providing a pattern in a single layer or a multilayer on one surface of the glass plate and a protective film layer on the upper surface of the printing layer It is made by attaching. They have the disadvantage of producing the same color and pattern shape, and to solve this problem, each printing part is needed to express various colors and pattern shapes, so it is expensive. there was.
  • Korean Patent Application Publication No. 10-1999-0031895 (Application No. 10-1997-0052777) proposed a method of forming a natural veneer ornament on glass, and a natural veneer ornament on the glass.
  • the method of forming the pattern is to decorate the pattern, shape in a variety of forms in general glass, color glass and etching glass, natural pattern decoration carved in a variety of forms of natural veneer to which the reinforcement paper is bonded to various glass (8) After bonding with the adhesive (4) of the urethane layer is provided on the surface.
  • the decorative glass manufactured by forming the natural veneer decoration on the glass can provide comfort through the natural beauty of the natural veneer, but the natural veneer is cut into various shapes to fit the prepared pattern, and the pieces are bonded to the tape. It is difficult to express the luxury because it is very difficult to fix the pattern wood and the sense of aesthetics is different depending on the shape of the pattern.
  • the decorative glass attached to the conventional hanji had a disadvantage that the good state is not maintained for a long time because the hanji is discolored or discolored during use.
  • an object of the present invention comprises a pattern layer and a Hanji layer and a back sheet that is sequentially printed and attached to one side of the glass plate is included in the fiber tissue of Hanji While expressing the unique aesthetics of the shell as it is, the pattern and color of the printed layer and backsheet can be expressed well according to the viewing angle, and after the light-off, especially the shell of the Korean paper expresses visual unsafeness through the phosphorescence phenomenon.
  • the present invention provides a decorative glass using a Korean paper and a method for manufacturing the same.
  • Method for producing a decorative glass using a hanji of the present invention for achieving the above object is a preparatory step of washing the cut glass plate and heat-dried to load the loading box; Supplying the glass plates loaded into the loading box one by one to the ascending cylinder and the adsorption cylinder; Forming a printed layer by printing a pattern on the one surface of the glass plate through silk printing and heating and drying it; Forming an EVA resin layer by coating an EVA resin on the glass plate and the back surface of the printing layer; Attaching the hanji while pressing the roller to bond the EVA resin layer and curing through heating and cooling with a press to form a first adhesive layer; A fluorine layer forming step of applying a fluorine resin, which is a transparent adhesive, to the back surface of the hanji, and heating and cooling to ban the fluorine resin; Forming an EVA resin layer by coating an EVA resin on the back surface of the fluorine layer; And attaching the backsheet while pressing the roller to bond the PET film backsheet printed with colors and patterns
  • Decorative glass using the hanji of the present invention for achieving the above object is a glass plate for use as a surface body, a printed layer printed by silk printing on the glass plate, and the fluorine resin coated on the back of the glass plate and the printing layer EVA resin is applied to the semi-cured fluororesin layer, and a thin Hanji is attached to the EVA resin layer to form a transparent first adhesive layer and Hanji formed by heating, pressurization and cooling, and a fluorine resin applied to the back side of the Hanji.
  • a transparent second adhesive layer which is cured by applying a semi-hardened and coated EVA resin to the semi-cured fluororesin layer, and the PET film backsheet printed with colors and patterns through heating, pressurization and cooling to the EVA resin layer. It may be characterized by technical configuration.
  • the shell of the hanji is made by applying and drying the luminous material to express visual unsafeness through the phosphorescence phenomenon It can be characterized by the configuration.
  • the present invention prints while expressing the unique aesthetics of the shell contained in the fiber tissue of Hanji by bonding the pattern layer, the Hanji layer, and the backsheet, which are sequentially printed and attached to one surface of the glass plate, with the transparent first adhesive layer and the second adhesive layer.
  • the pattern and color of the layer and the backsheet can be well expressed according to the viewing angle, and after extinguishing, the shell of the Korean paper can express visual stupidity through phosphorescence phenomenon, and the first adhesive layer and the second It is useful to increase the durability by protecting the adhesive layer and the back sheet, and to maintain the texture of Hanji for a long time.
  • FIG. 1 is a block diagram showing a process diagram of a decorative glass manufacturing method using Hanji according to the present invention.
  • Figure 2 is a schematic cross-sectional view of the decorative glass using Hanji according to the present invention.
  • Figure 3 is a photograph showing various shapes and colors of decorative glass using Hanji according to the invention.
  • Figure 4 is a photograph showing a comparison of the state of the phosphorescence of the decorative glass using Hanji according to the invention.
  • glass plate 2 printing layer
  • first adhesive layer 6 second adhesive layer
  • Decorative glass using the hanji of the present invention and a method for manufacturing the same as shown in Figs. 1 and 2 to form a printing layer (2) on the glass plate 1, the glass sheet 1 and the printing layer (2) ) And the back sheet 4 are bonded to each other by the first and second adhesive layers 5 and 6 to produce the decorative glass 100.
  • the glass plate (1) is used to strengthen by heat treatment after cutting according to the size used for durability, or Hanji ((3) and back sheet (4) and the first, second adhesive layers (5, 6) serves as a bonding film Therefore, even if the glass is broken, the fragmented glass is attached and safe. Therefore, the glass can be manufactured in a large area using normal glass as it is, and then it can be used by cutting by the required size.
  • the glass plate 1 is cut and washed and dried for about 10 to 20 minutes at 181 ⁇ 200 °C temperature It has a preparation step for loading.
  • the state prepared for loading the plate glass (1) has a step of automatically supplying the glass plate (1) one by one to the rising cylinder and the push cylinder.
  • the lift cylinder and the push cylinder are operated by pneumatic or hydraulic pressure and the glass plate 1 is transferred to the next process one by one while operating through a conventional control device.
  • the printing layer 2 is formed by printing and heating and drying a pattern as ink having a predetermined color on a surface of the glass plate 1 transferred from the glass plate 1 supplying step using a silk printing apparatus.
  • the ink is one-component or two-component, and has excellent weather resistance, such as strong adhesion to the glass material, solvent resistance, wear resistance, etc., the film thickness is 10 ⁇ 5 ⁇ m at a humidity of 40 ⁇ 70% or less at room temperature, 24 hours at room temperature Although curing time is required, it is completed by drying for 1 ⁇ 5 minutes under glass surface temperature of 160 ⁇ 190 °C so that it can be dried in a short time without bubble generation by using infrared ray and halogen lamp with deep heat transfer wavelength.
  • EVA ethylene vinyl acetate resin
  • the EVA resin can provide transparency, bonding properties and durability, and the convenience that can be bonded by directly applying 130 ⁇ 150 °C heat while contacting the Hanji (3) to be described later even after curing.
  • the paper sheet 1 and the printing layer 2 is pressurized with a roller so that the Hanji 3 is bonded to the EVA resin layer 51 coated on the back surface, heated with a heating press at 130 to 150 ° C., and circulated with cooling water.
  • the EVA resin layer 51 changes to the first adhesive layer 5 and has a step of firmly attaching the paper 3.
  • the EVA resin serves to increase the durability to prevent the peeling of the Hanji (3) and to prevent the peeling also by bonding with the fluorine resin described later.
  • the Hanji (3) has a 50 to 80% transmittance to the plate glass (1) while the natural texture is transmitted through the printing layer (2) so that the color and pattern of the back sheet 4 to be described later passes 40 to 70% transmittance
  • the thickness of the Korean paper 3 is formed to 15-25 ⁇ 5 ⁇ m / m2.
  • the semi-cured fluorine layer forming step is 15 ⁇ 5 ⁇ m thickness of the transparent adhesive fluorine resin by contacting the back surface of the paper (3) supplied in contact with the roller surface using a roller coating device widely used Then, the fluorine resin applied to the Hanji (3) at a predetermined speed while passing through the chamber maintained at 70 ⁇ 80 °C or 180 ⁇ 200 °C and again 70 ⁇ 80 °C through the temperature increase and cooling step by step Semi-curing the fluorine resin to form the semi-cured fluorine layer 61.
  • the fluorine resin coating GK-570 developed by Daikin Co., Ltd.
  • the fluorine resin can increase the endothermic efficiency by preventing the emission of irradiated light, which is an inherent property of fluorine, and Moisture permeability, UV protection, transparency and durability can be obtained because it blocks the humidity, while maintaining the unique characteristics of Hanji serves to concentrate the energy to the luminous material described below.
  • EVA ethylene vinyl acetate resin
  • the EVA resin serves to provide transparency, bonding properties and durability, and convenience of bonding by directly applying 130 to 150 ° C heat while keeping the back sheet 4 to be described later even after curing.
  • the back sheet 4 made of a PET (polyethylene terephthalate) film on which the EVA resin layer 62 coated on the fluorine layer 61 is printed with colors and patterns is pressurized with a roller and heated with a heating press.
  • the EVA resin layer 61 changes the second adhesive layer 6 to form the decorative sheet through the step of firmly attaching the back sheet 4 Complete with (100).
  • the decorative glass 100 has a characteristic of the print layer 2 and the Chinese characters 1 and the back sheet 4 of the color, pattern, and natural texture of the Hanji through each other. It is.
  • the step of applying a luminous material to the hanji (3) by precipitation or spray method comprises a step of drying.
  • the coated hanji (3) of the luminous material is most applied to the shell (aka: Doc) of the hanji (3) in particular can improve the appearance of visual unsafeness through the phosphorescence of the shell portion at night .
  • the present invention is to provide a decorative glass using a high quality paper through the process of sequentially moving each of the manufacturing steps.
  • Decorative glass 100 using Hanji made in the manufacturing step as described above is a glass plate (1) to be used as a surface body as shown in Figure 2, and the printing layer (2) printed through silk printing on the glass plate (2) and A transparent first adhesive layer formed by heating, pressing and cooling by applying an EVA resin to the back surface of the glass plate 1 and the printing layer 2 and attaching a thin Korean paper 3 to the EVA resin layer 51 ( 5) and the Hanji 3 and the fluorine resin applied to the back surface of the Hanji 3 are semi-hardened and EVA resin is applied to the semi-cured fluororesin layer 61 and heated to the EVA resin layer 62, It consists of a transparent second adhesive layer 6 which is cured while bonding the back sheet 4, which is a PET film material printed with colors and patterns through pressing and cooling.
  • the thickness of the printed layer 2 is 10 ⁇ 5 ⁇ m and the thickness of the first adhesive layer 5 and the second adhesive layer 6 made of the EVA resin is 10 ⁇ 20 ⁇ 5 ⁇ m the Korean paper 3 50 to 80% of the permeability, and the thickness of the Korean paper 3 to 15 to 25g / m2 is made so that the color and pattern of the back sheet 4 can be transmitted 40 to 70%.
  • the natural texture and softness of the Hanji (3) may be more pronounced or the pattern may appear more sharply depending on the viewing angle.
  • the texture expression of 3) is clear and can be maintained for a long time.
  • the luminous material is coated on the Hanji (1) and the uncoated portion, as shown in the light condensation of the light improves the phosphorescence phenomenon in the shell portion of the luminous material is applied The more pronounced, the better the expression of visual wrongity.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

Selon la présente invention, sont proposés un verre décoratif utilisant du papier coréen et un procédé de fabrication du verre décoratif. Le verre décoratif exprime la texture antique et la nature délicate du papier coréen fabriqué à l'aide d'une méthode traditionnelle, et exprime de façon appropriée diverses couleurs d'une couche imprimée et d'un dos. La surface externe du papier coréen est phosphorescente de façon à exprimer une élégance visuelle. Le papier coréen est durable et résistant aux rayonnements ultraviolets, permettant ainsi d'étendre la durée de vie de service du verre décoratif. Le procédé de fabrication du verre décoratif comprend : une étape de préparation suivant laquelle on lave, on chauffe et on séche des plaques de verre découpées puis on les empile dans une boîte de stockage ; une étape consistant à introduire les plaques de verre découpées empilées dans la boîte de stockage une par une à l'aide d'un cylindre de levage et d'un cylindre d'aspiration ; une étape consistant à former une couche imprimée par impression d'un motif sur une surface de la plaque de verre découpée par sérigraphie, puis chauffage/séchage de la plaque de verre découpée ; une étape consistant à former une couche de résine d'éthylène-acétate de vinyle (EVA) par application d'une résine d'EVA sur la plaque de verre découpée et une surface arrière de la couche imprimée ; une étape consistant à attacher le papier coréen à la couche de résine d'EVA par pressage de la couche de résine d'EVA sur le papier coréen avec un rouleau et durcissement de la couche de résine d'EVA par chauffage et refroidissement à l'aide d'une presse de façon à former une première couche d'adhérence ; une étape consistant à former une couche de fluorure par application d'une résine de fluorure comme adhésif transparent sur la surface arrière du papier coréen et chauffage et refroidissement de la résine de fluorure jusqu'à un état semi-durci ; une étape consistant à former une couche de résine d'EVA par application de la résine d'EVA sur la surface arrière de la couche de fluorure ; et une étape consistant à fixer une feuille de support de film de PET coloré et imprimé par des motifs à la couche de résine d'EVA appliquée sur la couche de fluorure par pressage de la couche de résine d'EVA par un rouleau et durcissement de la couche de résine d'EVA par chauffage et refroidissement à l'aide d'une presse de façon à former une seconde couche d'adhérence.
PCT/KR2011/008848 2011-06-14 2011-11-18 Verre décoratif utilisant du papier coréen et son procédé de fabrication WO2012173313A1 (fr)

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KR10-2011-0057233 2011-06-14
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CN110357448A (zh) * 2019-07-23 2019-10-22 嘉善银升玻璃有限公司 玻璃表面高温拉丝纹理工艺
DE102020102802A1 (de) 2020-02-04 2021-08-05 Bellicon Ag Trampolin
DE102020102803A1 (de) 2020-02-04 2021-08-05 Bellicon Ag Trampolin

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KR101381946B1 (ko) * 2013-11-18 2014-04-07 정병수 한지 무늬를 가지는 시트 및 이를 구비한 페어 유리

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JPS5795855A (en) * 1980-12-09 1982-06-14 Yukiaki Tada Industrial art objects of glass made by forming pattern with paper or cloth and synthetic resin on glass surface
KR20020003155A (ko) * 2001-11-10 2002-01-10 옥문수 코팅용액의 제조방법
KR20060002543A (ko) * 2004-07-02 2006-01-09 박충기 한지를 이용한 가구의 문양표현방법 및 그 방법에 의한 가구
KR20070021682A (ko) * 2005-08-19 2007-02-23 차봉수 건축자재용 착색유리 및 그 제조방법
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JPS5795855A (en) * 1980-12-09 1982-06-14 Yukiaki Tada Industrial art objects of glass made by forming pattern with paper or cloth and synthetic resin on glass surface
KR20020003155A (ko) * 2001-11-10 2002-01-10 옥문수 코팅용액의 제조방법
KR20060002543A (ko) * 2004-07-02 2006-01-09 박충기 한지를 이용한 가구의 문양표현방법 및 그 방법에 의한 가구
KR20070021682A (ko) * 2005-08-19 2007-02-23 차봉수 건축자재용 착색유리 및 그 제조방법
KR200451359Y1 (ko) * 2010-05-12 2010-12-10 박충배 한지 무늬를 갖는 유리

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110357448A (zh) * 2019-07-23 2019-10-22 嘉善银升玻璃有限公司 玻璃表面高温拉丝纹理工艺
DE102020102802A1 (de) 2020-02-04 2021-08-05 Bellicon Ag Trampolin
DE102020102803A1 (de) 2020-02-04 2021-08-05 Bellicon Ag Trampolin

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