WO2011058999A1 - フィルム状接着剤の製造方法、接着シート並びに半導体装置及びその製造方法 - Google Patents
フィルム状接着剤の製造方法、接着シート並びに半導体装置及びその製造方法 Download PDFInfo
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- WO2011058999A1 WO2011058999A1 PCT/JP2010/070019 JP2010070019W WO2011058999A1 WO 2011058999 A1 WO2011058999 A1 WO 2011058999A1 JP 2010070019 W JP2010070019 W JP 2010070019W WO 2011058999 A1 WO2011058999 A1 WO 2011058999A1
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- H01L2924/095—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00 with a principal constituent of the material being a combination of two or more materials provided in the groups H01L2924/013 - H01L2924/0715
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- H01L2924/15738—Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof the principal constituent melting at a temperature of greater than or equal to 950 C and less than 1550 C
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2809—Web or sheet containing structurally defined element or component and having an adhesive outermost layer including irradiated or wave energy treated component
Definitions
- the present invention relates to a method for producing a film adhesive, an adhesive sheet, a semiconductor device, and a method for producing the same.
- a stack package type semiconductor device in which a plurality of semiconductor elements are stacked in multiple stages is used for applications such as memory.
- a film adhesive such as a die attach film for a semiconductor is applied to bond semiconductor elements to each other or to a semiconductor element mounting support member (see, for example, Patent Document 1). ).
- the die attach film for semiconductor is required to have excellent fluidity during heat so that the wire and the substrate can be sufficiently embedded. Then, the die attach film for semiconductors which aimed at the improvement of fluidity at the time of heat is proposed (for example, refer to patent documents 2).
- the film adhesive as described above is prepared by preparing a coating solution in which an adhesive composition is dissolved or dispersed in a solvent, applying the solution on a substrate, and volatilizing the solvent by heating and drying.
- a coating solution in which an adhesive composition is dissolved or dispersed in a solvent
- the film-like adhesive of Patent Document 2 contains a large amount of thermosetting components in order to impart hot fluidity
- a partial crosslinking reaction proceeds during heat drying, and the hot fluidity is impaired. There was a problem such as.
- the film-like sealing sheet of Patent Document 3 is produced by pressing a composition containing a thermosetting resin and a filler.
- the sealing sheet obtained by such a method has a problem of warping after thermosetting when a semiconductor package or a wafer becomes large. In order to suppress this, when a large amount of inorganic filler such as silica is blended, it becomes difficult to coat all at once, and the flexibility of the film is impaired, making it difficult to wind and making it possible to lengthen the roll. The problem of disappearing, the problem that the handleability of the sheet is lowered and cracks are likely to occur during use, and the problem of the loss of fluidity during heating of the sealing sheet occur.
- This invention is made
- the present invention comprises (A) a radiation polymerizable compound, (B) a photoinitiator, and (C) a thermosetting resin on a substrate, and the content of the solvent is 5% by mass.
- An adhesive composition layer is formed by applying an adhesive composition that is liquid at 25 ° C. below, and the adhesive composition layer is irradiated with light to form a film adhesive.
- a method for producing a film adhesive is provided.
- the solvent means a radiation polymerizable group such as an ethylenically unsaturated group, an oxime ester group, a photoreactive group such as ⁇ -aminoacetophenone, phosphine oxide, an epoxy group, a phenolic hydroxyl group, a carboxyl group, an amino group, It means an organic compound that does not have a thermally reactive group such as an acid anhydride, isocyanate, peroxide, diazo group, imidazole, or alkoxysilane, has a molecular weight of 500 or less, and is liquid at room temperature (25 ° C.).
- Examples of such a solvent include dimethylformamide, toluene, benzene, xylene, methyl ethyl ketone, tetrahydrofuran, ethyl cellosolve, ethyl cellosolve acetate, dioxane, cyclohexanone, ethyl acetate, ⁇ -butyrolactone and N-methyl-pyrrolidinone.
- a film adhesive having excellent heat fluidity can be produced in a desired thickness in a shorter time than before. And since the film adhesive obtained is excellent in the fluidity at the time of heat
- the use of the specific liquid adhesive composition does not require heating for solvent drying after coating, so that heat energy and volatile organic compounds are used.
- VOC volatile organic compounds
- the component (A) is preferably liquid at 25 ° C.
- the viscosity can be reduced even in a composition containing no solvent, and the adhesiveness after curing can be further improved by blending a solid or high viscosity thermosetting resin while enabling film formation. .
- the component (A) preferably contains a monofunctional (meth) acrylate that is liquid at 25 ° C.
- monofunctional means having one carbon-carbon double bond in the molecule, and may have other functional groups.
- the monofunctional (meth) acrylate has an imide skeleton or a hydroxyl group.
- the component (B) preferably contains a photoinitiator having a molecular extinction coefficient of 100 ml / g ⁇ cm or more for light having a wavelength of 365 nm.
- the molecular extinction coefficient was determined by preparing a 0.001 mass% acetonitrile solution of the sample, placing the solution in a quartz cell, and measuring the spectrophotometer (Hitachi High-Technologies Corp., “U-” at room temperature (25 ° C.) under air. 3310 "(trade name)) to determine the absorbance.
- the photoinitiator having a molecular extinction coefficient with respect to light having a wavelength of 365 nm of 100 ml / g ⁇ cm or more is a compound having an oxime ester skeleton or a morpholine skeleton in the molecule.
- the tack force can be reduced in a short time without heating even by light irradiation under air.
- the adhesive composition may further contain (D) a curing agent.
- the adhesive composition may further contain (E) a thermal radical generator.
- E a thermal radical generator.
- the component (A) remaining unreacted after the light irradiation can be polymerized during thermosetting, so that the resulting film-like adhesive is foamed at the time of thermosetting or the subsequent heat history. Foaming and peeling can be further suppressed.
- the present invention also provides an adhesive sheet having a structure in which a dicing sheet and a film adhesive obtained by the method of the present invention are laminated.
- the adhesive sheet of the present invention can have the advantage that the film-like adhesive not only has excellent fluidity when heated, but is easy to manufacture. That is, according to the method for producing a film-like adhesive of the present invention, a dicing sheet made of a heat-sensitive material, for example, a flexible substrate such as polyolefin, polyvinyl chloride, or ethylene vinyl acetate (EVA) is used as the base material. It can be. In this case, an adhesive sheet having both a dicing function and a die bonding function can be easily manufactured in a short time.
- a dicing sheet made of a heat-sensitive material, for example, a flexible substrate such as polyolefin, polyvinyl chloride, or ethylene vinyl acetate (EVA) is used as the base material. It can be.
- EVA ethylene vinyl acetate
- the dicing sheet has a base film and a radiation curable pressure-sensitive adhesive layer provided on the base film, and the film adhesive is a radiation curable adhesive. It can have a structure laminated with an agent layer. Such an adhesive sheet can easily peel off the adhesive layer from the base film by an exposure process when picking up a diced semiconductor.
- the dicing sheet may be composed only of a base film. In this case, the manufacturing cost can be further reduced.
- the present invention also provides a semiconductor device having a structure in which semiconductor elements and / or a semiconductor element and a semiconductor element mounting support member are bonded by a film adhesive obtained by the method of the present invention.
- the semiconductor device of the present invention can be excellent in reliability by being bonded by the film adhesive according to the present invention having excellent fluidity during heat.
- the present invention also includes a step of attaching the film-like adhesive layer of the adhesive sheet of the present invention on one surface of a semiconductor wafer, and cutting the semiconductor wafer together with the film-like adhesive layer to obtain a semiconductor element with an adhesive layer. And a step of bonding a semiconductor element with an adhesive layer and another semiconductor element or a semiconductor element mounting support member by pressure-bonding the adhesive layer of the semiconductor element with an adhesive layer between the semiconductor element and the semiconductor element mounting support member.
- a method for manufacturing a semiconductor device is provided.
- the adhesive sheet of the present invention has both a dicing function and a die bonding function, and the film adhesive has excellent heat fluidity, the semiconductor device has excellent reliability. Can be obtained with high production efficiency.
- a manufacturing method of a film adhesive, an adhesive sheet, a semiconductor device, and a manufacturing method thereof capable of manufacturing a film adhesive having excellent heat fluidity at a desired thickness in a shorter time than before. Can be provided.
- the method for producing a film-like adhesive of the present invention comprises (A) a radiation polymerizable compound, (B) a photoinitiator, and (C) a thermosetting resin on a substrate, and the solvent content is 5 mass. %, And an adhesive composition layer that is liquid at 25 ° C. is formed to form an adhesive composition layer, and the adhesive composition layer is irradiated with light to form a film adhesive. To do.
- FIG. 3 is a schematic view showing an embodiment of the adhesive sheet according to the present invention.
- the adhesive sheet 50 shown in FIG. 3 has a structure in which a film adhesive 5 formed by the method for producing a film adhesive of the present invention is laminated on a substrate 6.
- thermosetting resin and other compounding components are added, followed by stirring and defoaming.
- the component (A) is preferably liquid at room temperature (25 ° C.).
- the solubility with respect to (A) component of (B) photoinitiator, (C) thermosetting resin, and another compounding component is scarce, it is preferable to stir, heating at 100 degrees C or less. This method can reduce the residual solid content. It is preferable to stir the adhesive composition in a light shielding or yellow room.
- thermosetting agents such as an imidazole and a thermal radical initiator
- solubility with respect to the other component of hardening accelerators, such as imidazole is scarce, it can disperse
- the obtained adhesive composition is preferably shielded from light, stored at 0 ° C. or lower, and more preferably at ⁇ 20 ° C. or lower.
- oxygen or air may be bubbled or enclosed in order to improve storage stability.
- the substrate examples include polyester film, polypropylene film, polyethylene terephthalate film, polyimide film, polyetherimide film, polyether naphthalate film, and methylpentene film. Two or more kinds of these base films may be combined to form a multilayer film, or the surface may be treated with a release agent such as silicone or silica.
- the method for applying the adhesive composition on the substrate is not particularly limited, and spray coating, curtain coating, bar coating, knife coating, and the like can be used. Moreover, it can also heat to 100 degrees C or less at the point which reduces the viscosity of an adhesive composition.
- the thickness of the coating film can be appropriately set according to the use of the film adhesive. According to the present invention, unlike the production by solvent volatilization, the film thickness can be increased. In the case of the use of a sealing film or a stress relaxation film, the thickness of the coating film is preferably set so that the thickness of the film adhesive is 50 to 200 ⁇ m. The film thickness of the film adhesive can be measured using a surface roughness measuring device (manufactured by Kosaka Laboratory).
- a radiation polymerizable compound is reacted to form a film adhesive by irradiating the adhesive composition layer with light.
- the reaction here include an addition reaction, a polymerization reaction, a rearrangement reaction, a cyclization reaction, a dimerization reaction, and the like, and a crosslinking reaction and a polymerization reaction are preferable in that a film can be formed with low energy.
- a polymerization reaction is further preferable in that tack reduction can be achieved with a low exposure amount.
- Examples of the light irradiation to the applied adhesive composition include irradiation with ionizing radiation and non-ionizing radiation. Specifically, excimer laser light such as ArF and KrF, electron beam extreme ultraviolet light, vacuum ultraviolet light, and the like. And ultraviolet irradiation such as X-ray, ion beam, i-line and g-line. In the case of ultraviolet irradiation, light irradiation can be performed under air, nitrogen or vacuum.
- light irradiation is preferably performed immediately after application of the adhesive. Moreover, light irradiation can be performed in the air, under nitrogen, under vacuum, or after laminating another substrate (cover film). Further, the cover film can be laminated after the light irradiation in the air, and further the light irradiation can be performed. By performing light irradiation again, tack after exposure can be further reduced.
- Heating can also be performed after light irradiation. Thereby, reaction by light irradiation progresses more and there exists a tendency for tack to be reduced. Heating can be performed on a hot plate or in a furnace. From the viewpoint of fluidity and adhesiveness reduction due to the progress of the curing reaction, the heating temperature is preferably 120 ° C. or less, more preferably 100 ° C. or less, and most preferably 80 ° C. or less.
- the adhesive composition is a solvent-free type having a solvent content of 5% by mass or less, but the solvent content is preferably 1% by mass or less.
- Examples of the component (A) used in the present invention include compounds having an ethylenically unsaturated group.
- the ethylenically unsaturated group include vinyl group, allyl group, propargyl group, butenyl group, ethynyl group, phenylethynyl group, maleimide group, nadiimide group, (meth) acryl group and the like.
- a (meth) acryl group is preferred from the viewpoint of reactivity.
- the component (A) is preferably liquid at room temperature (25 ° C.) in order to apply the adhesive composition without using a solvent.
- the viscosity at room temperature is preferably 30000 mPa ⁇ s or less, more preferably 20000 mPa ⁇ s or less, and most preferably 10000 mPa ⁇ s or less. When the viscosity exceeds 30000 mPa ⁇ s, the viscosity of the adhesive composition increases, making it difficult to produce a varnish, and it tends to be difficult to make a thin film or discharge.
- the viscosity at room temperature in this specification is a value measured with an E-type viscose clock at 25 ° C.
- the component (A) preferably contains (A1) monofunctional (meth) acrylate (hereinafter also referred to as A1 compound).
- the monofunctional here means having one carbon-carbon double bond in the molecule, and may have other functional groups.
- the monofunctional (meth) acrylate preferably has a 5% weight loss temperature of 100 ° C. or higher, more preferably 120 ° C. or higher, still more preferably 150 ° C. or higher, and 180 ° C. or higher. Is most preferred.
- a material design mainly composed of an organic compound is preferable.
- The% weight loss temperature is preferably 500 ° C. or less.
- the 5% mass reduction temperature of the monofunctional (meth) acrylate was measured using a differential thermothermal gravimetric simultaneous measurement apparatus (manufactured by SII NanoTechnology: TG / DTA6300) with a temperature rising rate of 10 ° C./min and a nitrogen flow (400 ml / min) is the 5% weight loss temperature as measured under.
- a compound having two or more carbon-carbon double bonds in the molecule is used in an amount of 0.1 to 50% by mass based on (A1) monofunctional (meth) acrylate. It can also be used together.
- Monofunctional (meth) acrylates include, for example, phenolic hydroxyl groups such as glycidyl group-containing (meth) acrylate, 4-hydroxyphenyl methacrylate, and 3,5-dimethyl-4-hydroxybenzylacrylamide in that the cured product can be toughened.
- Carboxy group-containing (meth) acrylates such as (meth) acrylate, 2-methacryloyloxyethylphthalic acid, 2-methacryloyloxypropylhexahydrophthalic acid, 2-methacryloyloxymethylhexahydrophthalic acid are preferable, and heat resistance is improved.
- R 1 represents a hydrogen atom or a methyl group
- R 3 represents a monovalent organic group
- R 2 and R 4 represent a divalent organic group, respectively.
- R 3 preferably has an aromatic group from the viewpoint of heat resistance.
- R 4 preferably has an aromatic group from the viewpoint of heat resistance.
- R 1 represents a hydrogen atom or a methyl group
- R 5 represents a divalent organic group
- R 6 , R 7 , R 8 , R 9 are Each represents a monovalent hydrocarbon group having 1 to 30 carbon atoms
- R 6 and R 7 may be bonded to each other to form a ring
- R 8 and R 9 may be bonded to each other to form a ring. May be.
- examples thereof include a benzene ring structure and an alicyclic structure.
- the benzene ring structure and the alicyclic structure may have a thermosetting group such as a carboxyl group, a phenolic hydroxyl group, and an epoxy group, or may have an organic group such as an alkyl group.
- the compounds represented by the general formulas (A-3) and (A-4) include, for example, an N-hydroxyalkylimide compound obtained by reacting a monofunctional acid anhydride and ethanolamine, an acrylate ester or an acrylic ester. It can be synthesized by reacting with an acid ester by a known method.
- Examples of the compounds represented by the general formulas (A-3) and (A-4) include storage stability, low tack after film formation, adhesion after film formation, heat resistance after thermosetting, adhesiveness, From the viewpoint of reliability, compounds represented by the following general formulas (A-5) to (A-9) can be preferably used, and from the viewpoint of low viscosity, the following general formulas (A-5), (A The compounds represented by -7) to (A-9) can be used more preferably.
- R 1 represents a hydrogen atom or a methyl group.
- a monofunctional (meth) acrylate from the viewpoint of adhesion to an adherend after film formation, adhesion after curing, and heat resistance, urethane group, isocyanur group, imide group, phenolic hydroxyl group, hydroxyl group It is preferable to have either, and it is especially preferable that it is a monofunctional (meth) acrylate having an imide group or a hydroxyl group in the molecule.
- a monofunctional (meth) acrylate having an epoxy group can also be preferably used.
- Monofunctional (meth) acrylates with epoxy groups have a 5% weight loss temperature during film formation from the viewpoints of storage stability, adhesion, assembly heating and low outgassing of the package after assembly, heat resistance and moisture resistance. It is preferably 150 ° C. or higher in that it can suppress volatilization or segregation on the surface due to heat drying, and it is further 180 ° C. or higher in that it can suppress voids and peeling due to outgassing during thermosetting and decrease in adhesion.
- the temperature is more preferably 200 ° C. or higher, and most preferably 260 ° C.
- Such a monofunctional (meth) acrylate having an epoxy group can satisfy the above heat resistance by using a polyfunctional epoxy resin having a 5% weight loss temperature of 150 ° C. or more as a raw material.
- Examples of the monofunctional (meth) acrylate having an epoxy group include, for example, glycidyl methacrylate, glycidyl acrylate, 4-hydroxybutyl acrylate glycidyl ether, 4-hydroxybutyl methacrylate glycidyl ether, a functional group that reacts with an epoxy group, and an ethylenic group. Examples thereof include compounds obtained by reacting a compound having a saturated group with a polyfunctional epoxy resin.
- An isocyanate group, a carboxyl group, a phenolic hydroxyl group, a hydroxyl group, an acid anhydride, an amino group, a thiol group, an amide group etc. are mentioned. These compounds can be used individually by 1 type or in combination of 2 or more types. More specifically, for example, in the presence of triphenylphosphine or tetrabutylammonium bromide, a polyfunctional epoxy resin having at least two or more epoxy groups in one molecule and 0.1 to 0 to 1 equivalent of epoxy groups. Obtained by reacting with 9 equivalents of (meth) acrylic acid.
- the monofunctional (meth) acrylate having an epoxy group has a high purity in which impurity ions such as alkali metal ions, alkaline earth metal ions, halogen ions, particularly chlorine ions and hydrolyzable chlorine are reduced to 1000 ppm or less. It is preferable to use a product from the viewpoint of preventing electromigration and preventing corrosion of a metal conductor circuit.
- the impurity ion concentration can be satisfied by using a polyfunctional epoxy resin with reduced alkali metal ions, alkaline earth metal ions, halogen ions, and the like as a raw material.
- the total chlorine content can be measured according to JIS K7243-3.
- the monofunctional (meth) acrylate component having an epoxy group that satisfies the above heat resistance and purity is not particularly limited, but bisphenol A type (or AD type, S type, F type) glycidyl ether, water-added bisphenol A type Glycidyl ether, ethylene oxide adduct bisphenol A and / or F type glycidyl ether, propylene oxide adduct bisphenol A and / or F type glycidyl ether, phenol novolac resin glycidyl ether, cresol novolac resin glycidyl ether, bisphenol A novolak Glycidyl ether of resin, glycidyl ether of naphthalene resin, trifunctional (or tetrafunctional) glycidyl ether, glycidyl ether of dicyclopentadiene phenol resin, glycidyl of dimer acid Glycol ester, 3 glycidylamine functional type (or
- the number of epoxy groups is preferably 3 or less in order to improve thermocompression bonding, low stress properties, and adhesion.
- a compound is not particularly limited, but is a compound represented by the following general formula (A-10), (A-11), (A-12), (A-13) or (A-14) Is preferably used.
- R 12 and R 16 represent a hydrogen atom or a methyl group
- R 10 , R 11 , R 13 and R 14 represent a divalent organic group.
- R 15 is an organic group having an epoxy group
- R 17 and R 18 are each an organic group having an ethylenically unsaturated group, and the rest are organic groups having an epoxy group.
- f in (A-13) represents an integer of 0 to 3.
- the content of the monofunctional (meth) acrylate is preferably 20 to 100% by mass, more preferably 40 to 100% by mass, and 50 to 100% by mass with respect to the total amount of component (A). Most preferably it is.
- the A1 compound preferably has a viscosity at 25 ° C. of 5000 mPa ⁇ s or less from the viewpoint of solubility of other components such as the component (B) and the component (C). More preferably, it is 3000 mPa ⁇ s or less, and even more preferably 2000 mPa ⁇ s or less. Further, from the viewpoint of improving adhesion by adding a large amount of a solid or high viscosity thermosetting resin, it is 1000 mPa ⁇ s or less. Most preferably it is.
- the viscosity here is a value for the A1 compound and is a viscosity value measured at 25 ° C. using an EHD type rotational viscometer manufactured by Tokyo Keiki Seisakusho.
- the viscosity of the A1 compound exceeds 5000 mPa ⁇ s, the viscosity of the adhesive composition increases, and it tends to be difficult to make a thin film or to be applied.
- the viscosity of the A1 compound at 25 ° C. is preferably 10 mPa ⁇ s or more.
- the viscosity of the A1 compound is preferably 1000 mPa ⁇ s or less from the viewpoint of improving dischargeability when the adhesive composition is discharged from a nozzle or the like and reducing the film thickness, and 5 mPa ⁇ s from the viewpoint of reducing outgas. The above is preferable.
- the A1 compound preferably has a 5% weight loss temperature of 100 ° C. or higher, more preferably 120 ° C. or higher, even more preferably 150 ° C. or higher, and 180 ° C. or higher.
- the 5% mass reduction temperature means that the A1 compound was heated at a rate of temperature increase of 10 ° C./min, a nitrogen flow (400 ml / 400 ml) using a differential thermothermal gravimetric simultaneous measurement apparatus (manufactured by SII Nanotechnology: TG / DTA6300) min) is the 5% weight loss temperature as measured under.
- the temperature is preferably 500 ° C. or lower.
- the A1 compound is preferably one in which the Tg of the polymer obtained by polymerizing the A1 compound is 100 ° C. or less from the viewpoint of low-temperature thermocompression bonding after film formation and fluidity during heat. From the viewpoint of pickup properties, those having a Tg of 20 ° C. or higher are preferred.
- the Tg of the polymer of the A1 compound is a composition obtained by dissolving I-379EG (manufactured by Ciba Japan), which is a photoinitiator, in the A1 component at a ratio of 3% by mass with respect to the A1 component, and PET (polyethylene terephthalate).
- the film was applied to a film thickness of 30 ⁇ m, and this coating film was exposed at 1000 mJ / cm 2 using a high-precision parallel exposure machine (Oak Seisakusho, trade name: EXM-1172-B- ⁇ ).
- the laminate obtained by laminating the obtained film to a film thickness of 150 ⁇ m was measured using a viscoelasticity measuring device (manufactured by Rheometrics Scientific F.E., trade name: ARES).
- the measurement plate is a parallel plate having a diameter of 8 mm, and the measurement conditions are a heating rate of 5 ° C./min, a measurement temperature of ⁇ 50 ° C. to 200 ° C., and a frequency of 1 Hz.
- the adhesive composition according to the present invention may contain a bifunctional or higher (meth) acrylate in addition to the A1 compound as the radiation polymerizable compound (A).
- the term “bifunctional or higher” as used herein means having two or more carbon-carbon double bonds in the molecule.
- Such acrylate is not particularly limited, but diethylene glycol diacrylate, triethylene glycol diacrylate, tetraethylene glycol diacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, trimethylolpropane diacrylate.
- R 19 and R 20 each independently represent a hydrogen atom or a methyl group, and g and h each independently represent an integer of 1 to 20.
- R 15 in the above formula (A-12) is an organic group having an ethylenically unsaturated group
- two or more of R 17 in the above formula (A-13) have an ethylenically unsaturated group.
- the above-mentioned radiation polymerizable compounds can be used singly or in combination of two or more.
- the radiation polymerizable compound having a glycol skeleton represented by the general formula (A-15) is preferable in that it can sufficiently impart solvent resistance after curing, and urethane acrylate and methacrylate, isocyanuric acid di / triacrylate.
- methacrylate are preferable in that they can sufficiently impart high adhesiveness after curing.
- the adhesive composition according to the present invention preferably contains a trifunctional or higher functional acrylate compound.
- the adhesiveness after curing can be further improved and outgassing during heating can be suppressed.
- the adhesive composition according to the present invention preferably contains isocyanuric acid ethylene oxide-modified di- and triacrylate in that heat resistance after curing can be sufficiently imparted.
- the adhesive composition according to the present invention may contain a monofunctional maleimide compound represented by the following structural formula for the purpose of reducing tack after exposure and improving adhesiveness.
- the radiation-polymerizable compound having a high functional group equivalent preferably has a polymerization functional group equivalent of 200 eq / g or more, more preferably 300 eq / g or more, and most preferably 400 eq / g or more.
- a radiation polymerizable compound having an ether skeleton, a urethane group and / or an isocyanuric group having a polymerization functional group equivalent of 200 eq / g or more it becomes possible to improve the adhesiveness of the adhesive composition.
- a radiation polymerizable compound having a polymerization functional group equivalent of 200 eq / g or more and a radiation polymerizable compound having a polymerization functional group equivalent of 200 eq / g or less may be used in combination.
- Component (A) preferably has a 5% weight loss temperature of 120 ° C. or higher, more preferably 150 ° C. or higher, and even more preferably 180 ° C. or higher.
- the 5% mass reduction temperature is the value of the entire component (A) contained in the adhesive composition, and the component (A) is subjected to a differential thermothermal gravimetric simultaneous measurement apparatus (manufactured by SII Nanotechnology: TG / DTA6300) is a 5% weight loss temperature when measured at a heating rate of 10 ° C./min and under a nitrogen flow (400 ml / min).
- the content of the component (A) is preferably 10 to 95% by mass, more preferably 20 to 90% by mass, and most preferably 40 to 90% by mass with respect to the total amount of the adhesive composition. preferable.
- the content of the component (A) is less than 10% by mass, the surface tack force after exposure tends to increase, and when it exceeds 95% by mass, the adhesive strength after thermosetting tends to decrease. .
- the adhesive composition according to the present invention has a high molecular weight when irradiated with light from the viewpoint of sufficiently excellent high-temperature adhesiveness, film handling properties such as bleeding during roll processing, and tackiness during lamination. It is preferable that the polymer of the above component (A) which is 50,000 to 1,000,000 is included.
- a polymer of the above component (A) having a molecular weight of 1,000 to 500,000 when irradiated with light is included.
- the molecular weight refers to a composition obtained by dissolving I-379EG (manufactured by Ciba Japan), which is a photoinitiator, in A component at a ratio of 3% by mass with respect to A component on polyethylene terephthalate (PET).
- a PET film that has been applied to a film thickness of 30 ⁇ m and a release film is laminated to the obtained coating film, and a high-precision parallel exposure machine (“EXM-1172-B- ⁇ ” (trade name) manufactured by Oak Manufacturing Co., Ltd.)
- EXM-1172-B- ⁇ trade name
- C-R4A Shimadzu high performance liquid chromatography
- the adhesive composition according to the present invention comprises a component (A) that becomes a polymer having a weight average molecular weight of 100,000 to 1,000,000 (“high molecular weight polymer”) when irradiated with light, and a weight average molecular weight of 1,000 to 50,000. It is more preferable to include a component (A) that becomes a polymer (“low molecular weight polymer”).
- the film adhesive that is formed contains both the above-mentioned “high molecular weight polymer” and “low molecular weight polymer”, so that high-temperature adhesiveness, film handling properties such as bleeding during roll processing, and adhesiveness during lamination And high fluidity when heated.
- the weight average molecular weight of the polymer of component (A) is the exposure conditions (oxygen concentration, temperature, strength), the amount of photoinitiator, the addition of thiol, phenolic hydroxyl group, amine or phenolic polymerization inhibitor, the type of acrylate and the heat. It can adjust with the compounding quantity of curable resin, and the viscosity of an adhesive composition.
- (B) As a photoinitiator, from the point of sensitivity improvement, those having a molecular extinction coefficient with respect to light having a wavelength of 365 nm of 100 ml / g ⁇ cm or more (B1 compound) are preferable, and those having a molecular absorption coefficient of 200 ml / g ⁇ cm or more. More preferred.
- the time required for forming a film is preferably within 60 s, and more preferably within 30 s in that a film adhesive can be more efficiently produced.
- a 0.001% by mass acetonitrile solution of the sample is prepared, and the absorbance of this solution is measured using a spectrophotometer (manufactured by Hitachi High-Technologies Corporation, “U-3310” (trade name)). Is required.
- the B1 compound is preferably an intramolecular cleavage type photoinitiator from the viewpoint of film formation efficiency.
- 2,2-dimethoxy-1,2-diphenylethane-1-one 2-hydroxy-1 - ⁇ 4- [4- (2-hydroxy-2-methyl-propionyl) -benzyl] -phenyl ⁇ -2-methyl-propan-1-one, 2-dimethylamino-2- (4-methyl-benzyl)- 1- (4-Morpholin-4-yl-phenyl) -butan-1-one, 2-benzyl-2-dimethylamino-1- (4-morpholinophenyl) -butanone-1, 2-methyl-1- (4 -(Methylthio) phenyl) -2-morpholinopropanone-1, 1- [4- (phenylthio)-, 2- (o-benzoyloxime)], ethanone, 1- [9-ethyl-6- (2 Methylbenzoyl) -9H-
- Examples include lysine derivatives, bisacylphosphine oxides such as bis (2,4,6, -trimethylbenzoyl) -phenylphosphine oxide, and compounds having maleimide. These can be used alone or in combination of two or more.
- 2,2-dimethoxy-1,2-diphenylethane-1-one, 2-benzyl-2-dimethylamino- and the like from the viewpoint of solubility in an adhesive composition containing no solvent.
- the B1 compound is preferably a compound having an oxime ester skeleton or a morpholine skeleton in the molecule in that film formation can be efficiently performed by exposure even in an air atmosphere (in the presence of oxygen).
- a compound is not particularly limited, but is a compound having an oxime ester group represented by the following general formula (B-1) and / or the following general formula (B-2), (B-3) or (B- A compound having a morpholine ring represented by 4) is preferred.
- the solubility in other components the efficiency of film formation (effect by exposure amount and atmosphere), low sublimation, storage stability, adhesion after film formation, and adhesion after curing are highly satisfactory.
- Most preferably used is dimethylamino-2- (4-methyl-benzyl) -1- (4-morpholin-4-yl-phenyl) -butan-1-one.
- R 51 and R 52 each independently represent a hydrogen atom, an alkyl group having 1 to 7 carbon atoms, or an organic group containing an aromatic hydrocarbon group
- R 53 represents an alkyl group having 1 to 7 carbon atoms.
- R 54 and R 55 each represents a monovalent organic group
- R 56 and R 57 represent an organic group containing an aromatic hydrocarbon group. Show.
- the aromatic hydrocarbon group is not particularly limited, and examples thereof include a phenyl group and a naphthyl group, a benzoin derivative, a carbazole derivative, a thioxanthone derivative, and a benzophenone derivative. Moreover, the aromatic hydrocarbon group may have a substituent.
- the B1 compound is a compound having an oxime ester group and / or a morpholine ring, a molecular extinction coefficient with respect to light having a wavelength of 365 nm of 1000 ml / g ⁇ cm or more, and a 5% mass reduction temperature of 150 ° C. These compounds.
- B1 compounds include compounds represented by the following structural formulas (B-5) to (B-9).
- the component (B) may contain a photoinitiator that exhibits a function of promoting polymerization and / or reaction of the epoxy resin by irradiation with radiation.
- a photoinitiator include a photobase generator that generates a base by irradiation, a photoacid generator that generates an acid by irradiation, and the photobase generator is particularly preferable.
- the high-temperature adhesiveness and moisture resistance of the adhesive composition to the adherend can be further improved.
- the base generated from the photobase generator acts as a curing catalyst for the epoxy resin efficiently, so that the crosslinking density can be further increased, and the generated curing catalyst corrodes the substrate and the like. This is thought to be because there are few.
- the crosslink density can be improved, and the outgas during standing at high temperature can be further reduced. Furthermore, the curing process temperature can be lowered and shortened.
- the photobase generator may be a compound that generates a base when irradiated with radiation.
- a strongly basic compound is preferable in terms of reactivity and curing speed.
- Examples of the base generated upon irradiation include imidazole derivatives such as imidazole, 2,4-dimethylimidazole and 1-methylimidazole, piperazine derivatives such as piperazine and 2,5-dimethylpiperazine, piperidine and 1,2-dimethylpiperidine.
- Piperidine derivatives such as, proline derivatives, trialkylamine derivatives such as trimethylamine, triethylamine and triethanolamine, pyridine derivatives substituted with an amino group or alkylamino group at the 4-position such as 4-methylaminopyridine and 4-dimethylaminopyridine, Pyrrolidine derivatives such as pyrrolidine, n-methylpyrrolidine, dihydropyridine derivatives, triethylenediamine, alicyclic amine derivatives such as 1,8-diazabiscyclo (5,4,0) undecene-1 (DBU), Rumechiruamin, benzyldimethylamine, and the like benzylamine derivatives such as benzyl diethylamine.
- DBU 1,8-diazabiscyclo (5,4,0) undecene-1
- photobase generators that generate a base upon irradiation are 2,4-dimethoxy-1,2-diphenylethane-1-one, 1,2-octanedione, 1- [4- (phenylthio)-, 2- Oxime derivatives such as (O-benzoyloxime)], ethanone, 1- [9-ethyl-6- (2-methylbenzoyl) -9H-carbazol-3-yl]-, 1- (O-acetyloxime) and light 2-Benzyl-2-dimethylamino-1- (4-morpholinophenyl) -butanone-1,2,2-dimethoxy-1,2-diphenylethane-1-one, 2-methyl, which is commercially available as a radical generator -1- (4- (methylthio) phenyl) -2-morpholinopropan-1-one, 2-benzyl-2-dimethylamino-1- (4-morpholinophenyl) -butyl
- the photobase generator a compound in which a base generating group is introduced into the main chain and / or side chain of the polymer may be used.
- the molecular weight in this case is preferably from 1,000 to 100,000, more preferably from 5,000 to 30,000, from the viewpoints of adhesiveness, fluidity and heat resistance as an adhesive.
- the above photobase generator does not show reactivity with the epoxy resin when not exposed to light, the storage stability at room temperature is very excellent.
- the content of the (B) photoinitiator is preferably 0.1 to 20 parts by mass with respect to 100 parts by mass of the component (A). More preferably, it is 5 to 10 parts by mass. If this content exceeds 20 parts by mass, the outgas will increase and the adhesiveness will tend to decrease, and the storage stability will tend to decrease. On the other hand, when the content is less than 0.1 parts by mass, film formation tends to be difficult.
- the ratio of the B1 compound in the (B) photoinitiator is preferably 20 to 100 parts by mass, and more preferably 50 to 100 parts by mass with respect to 100 parts by mass of the component (B).
- a sensitizer can be used in combination as necessary.
- this sensitizer include camphorquinone, benzyl, diacetyl, benzyldimethyl ketal, benzyl diethyl ketal, benzyl di (2-methoxyethyl) ketal, 4,4′-dimethylbenzyl-dimethyl ketal, anthraquinone, 1-chloroanthraquinone.
- the (C) thermosetting resin is not particularly limited as long as it is a component composed of a reactive compound that undergoes a crosslinking reaction by heat.
- epoxy resins, maleimide resins, and allyl nadiimide resins are preferable because they can be mentioned.
- epoxy resin those containing at least two epoxy groups in the molecule are preferable, and phenol glycidyl ether type epoxy resins are more preferable from the viewpoints of thermocompression bonding, curability, and cured product characteristics.
- examples of such resins include bisphenol A type (or AD type, S type, and F type) glycidyl ether, water-added bisphenol A type glycidyl ether, ethylene oxide adduct bisphenol A type glycidyl ether, and propylene oxide adduct.
- the epoxy resin it is possible to use a high-purity product in which impurity ions such as alkali metal ions, alkaline earth metal ions, halogen ions, particularly chlorine ions and hydrolyzable chlorine are reduced to 300 ppm or less. From the viewpoint of prevention and corrosion prevention of metal conductor circuits.
- impurity ions such as alkali metal ions, alkaline earth metal ions, halogen ions, particularly chlorine ions and hydrolyzable chlorine are reduced to 300 ppm or less.
- maleimide resins examples include bismaleimide resins represented by the following general formula (I) and novolac maleimide resins represented by the following general formula (II).
- R 5 represents a divalent organic group containing an aromatic ring and / or a linear, branched or cyclic aliphatic hydrocarbon.
- n represents an integer of 0 to 20.
- a bismaleimide resin represented by the following structural formula (III) and / or a novolac maleimide resin represented by the above general formula (II) in that heat resistance and high-temperature adhesive force after curing of the adhesive film can be imparted.
- an allylated bisphenol A, a cyanate ester compound or the like can be used in combination, or a catalyst such as a peroxide can be added.
- a catalyst such as a peroxide
- allyl nadiimide resin a compound containing two or more allyl naimide groups in the molecule can be used, and examples thereof include a bisallyl nadiimide resin represented by the following general formula (IV).
- R 1 represents a divalent organic group containing an aromatic ring and / or a linear, branched or cyclic aliphatic hydrocarbon.
- liquid hexamethylene type bisallyl nadiimide represented by the following structural formula (V) and low melting point (melting point: 40 ° C.) solid xylylene type bisallyl nadiimide represented by the following structural formula (VI) which is preferable in terms of providing good hot fluidity.
- Solid xylylene-type bisallylnadiimide can suppress the increase in adhesiveness after B-stage in addition to good fluidity during heat treatment, handling property, and easy release from dicing tape during pick-up. It is more preferable in terms of suppressing re-fusion of the cut surface after dicing.
- the above bisallylnadiimide can be used alone or in combination of two or more.
- the allyl nadiimide resin described above requires a curing temperature of 250 ° C. or higher when singly cured in the absence of a catalyst, which is a major obstacle to practical use. Only metal corrosive catalysts, which are a serious drawback in electronic materials such as onium salts and onium salts, can be used, and final curing requires a temperature of around 250 ° C. Can be cured at a low temperature of 200 ° C. or less by using any one of acrylate compound, methacrylate compound, and maleimide resin (reference: A. Renner, A. Kramer, “Allylindic-Imides: A New Class”). of Heat-Resistant Thermosets ", J. Polym. Sc ., Part A Polym.Chem., 27,1301 (1989)).
- thermosetting resin can be used regardless of liquid or solid at room temperature. In the case of a liquid thermosetting resin, the viscosity can be further reduced, and in the case of a solid thermosetting resin, tack after light irradiation can be further reduced. Moreover, you may use together a liquid thermosetting resin and a solid thermosetting resin.
- the viscosity is preferably 10,000 mPa ⁇ s or less, more preferably 5000 mPa ⁇ s or less, still more preferably 3000 mPa ⁇ s or less, and even more preferably 2000 mPa ⁇ s or less. Most preferably. When the viscosity exceeds 10,000 mPa ⁇ s, the viscosity of the adhesive composition increases and it tends to be difficult to form a thin film.
- Such a liquid thermosetting resin is not particularly limited, but is preferably an epoxy resin from the viewpoint of adhesiveness and heat resistance, and particularly a trifunctional (or tetrafunctional) glycidylamine or bisphenol A type (or AD type, S type, and F type glycidyl ethers are preferably used.
- a solid thermosetting resin when using a solid thermosetting resin, for example, it can be used by being dissolved in the component (A).
- a solid thermosetting resin From a viewpoint of thermocompression bonding property and viscosity, it is preferable that molecular weight is 2000 or less, Preferably it is 1000 or less, and a softening point is 100 degrees C or less, Preferably it is 80 degrees C The following is preferable.
- a trifunctional or higher functional epoxy resin is preferable from the viewpoint of adhesiveness and heat resistance.
- an epoxy resin for example, an epoxy resin having the following structure is preferably used.
- n an integer of 0 to 10.
- the (C) thermosetting resin preferably has a 5% weight loss temperature of 150 ° C. or higher, more preferably 180 ° C. or higher, and even more preferably 200 ° C. or higher.
- the 5% mass reduction temperature of the thermosetting resin means that the thermosetting resin is heated at a rate of 10 ° C./temperature using a differential thermothermal gravimetric simultaneous measurement apparatus (manufactured by SII Nanotechnology: TG / DTA6300).
- Min 5% weight loss temperature when measured under a nitrogen flow (400 ml / min).
- thermosetting resin having such heat resistance an epoxy resin having an aromatic group in the molecule is exemplified, and in particular from the viewpoint of adhesion and heat resistance, trifunctional (or tetrafunctional) glycidylamine, Bisphenol A type (or AD type, S type, F type) glycidyl ether is preferably used.
- the content of the thermosetting resin is preferably 1 to 100 parts by mass and more preferably 2 to 50 parts by mass with respect to 100 parts by mass of the component (A). When this content exceeds 100 parts by mass, the tack after exposure tends to increase. On the other hand, when the content is less than 2 parts by mass, there is a tendency that sufficient high-temperature adhesiveness cannot be obtained.
- the adhesive composition according to the present invention preferably further contains a curing accelerator.
- the curing accelerator is not particularly limited as long as it is a compound that accelerates curing / polymerization of the epoxy resin by heating.
- imidazoles are preferably used from the viewpoint of solubility and dispersibility when no solvent is contained.
- the content of the curing accelerator is preferably 0.01 to 50 parts by mass with respect to 100 parts by mass of the epoxy resin.
- imidazoles are particularly preferable from the viewpoints of adhesiveness, heat resistance, and storage stability.
- the reaction start temperature is preferably 50 ° C. or higher, and more preferably 80 ° C. or higher.
- the reaction start temperature is 50 ° C. or lower, the storage stability is lowered, so that the viscosity of the resin composition is increased and the control of the film thickness becomes difficult.
- imidazoles it is preferable to use imidazole that is soluble in an epoxy resin. By using such imidazole, a coating film with less unevenness can be obtained.
- Such imidazoles are not particularly limited, but 2-undecylimidazole, 2-heptadecylimidazole, 1,2-dimethylimidazole, 2-ethyl-4-methylimidazole, 1-benzyl-2-methylimidazole 1-benzyl-2-phenylimidazole, 1-cyanoethyl-2-methylimidazole, 1-cyanoethyl-2-ethyl-4-methylimidazole, 1-cyanoethyl-2-phenylimidazole and the like.
- imidazoles compounds pulverized to an average particle size of preferably 10 ⁇ m or less, more preferably 8 ⁇ m or less, and most preferably 5 ⁇ m or less can be used.
- a change in viscosity of the adhesive composition can be suppressed, and precipitation of imidazoles can be suppressed.
- surface irregularities can be reduced, and thereby a uniform film can be obtained.
- outgas can be reduced.
- the adhesive composition according to the present invention may further contain (D) a curing agent.
- a phenol type compound is mentioned, for example.
- the phenolic compound a phenolic compound having at least two phenolic hydroxyl groups in the molecule is more preferable. Examples of such compounds include phenol novolak, cresol novolak, t-butylphenol novolak, dicyclopentadiene cresol novolak, dicyclopentadienephenol novolak, xylylene-modified phenol novolak, naphthol compound, trisphenol compound, tetrakisphenol novolak, bisphenol.
- a novolak, poly-p-vinylphenol, phenol aralkyl resin, allyl-modified phenol novolak and the like are preferable, and those having a liquid state at room temperature are more preferable. Thereby, the outgas at the time of heating which causes the contamination of the semiconductor element or the device at the time of assembling the semiconductor device can be suppressed.
- the phenolic compound is preferably liquid, and the allyl-modified phenol novolak is preferably used because it is liquid and highly heat resistant.
- the content of the phenolic compound is preferably 50 to 120 parts by mass, more preferably 70 to 100 parts by mass with respect to 100 parts by mass of the thermosetting resin.
- the adhesive composition according to the present invention may further contain (E) a thermal radical generator.
- the thermal radical generator is preferably an organic peroxide.
- the organic peroxide preferably has a 1 minute half-life temperature of 80 ° C. or higher, more preferably 100 ° C. or higher, and most preferably 120 ° C. or higher.
- the organic peroxide is selected in consideration of the preparation conditions of the adhesive composition, the film forming temperature, the curing (bonding) conditions, other process conditions, storage stability, and the like.
- the peroxide that can be used is not particularly limited.
- the unreacted radiation-polymerizable compound remaining after exposure can be reacted, and low outgassing and high adhesion can be achieved.
- the content of the (E) thermal radical generator is preferably 0.01 to 20% by mass, more preferably 0.1 to 10% by mass, and more preferably 0.5 to 5%, based on the total amount of the (A) radiation polymerizable compound. Mass% is most preferred.
- the content of the thermal radical generator is less than 0.01% by mass, the curability is lowered and the effect of addition is reduced, and when it exceeds 5% by mass, the outgas amount is increased and the storage stability is decreased.
- the adhesive composition according to the present invention may further contain (F) a thermoplastic resin from the viewpoint of improving low stress, adhesion to an adherend, and thermocompression bonding.
- Tg of component (F) is preferably 150 ° C. or lower, more preferably 120 ° C. or lower, even more preferably 100 ° C. or lower, and most preferably 80 ° C. or lower.
- this Tg exceeds 150 ° C., the viscosity of the adhesive composition tends to increase. Further, a high temperature of 150 ° C. or higher is required for thermocompression bonding to the adherend, and the semiconductor wafer tends to be warped.
- Tg of component (F) means the main dispersion peak temperature when component (F) is formed into a film.
- the film thickness is 100 ⁇ m
- the heating rate is 5 ° C./min
- the frequency is 1 Hz
- the measurement temperature Measure at ⁇ 150 to 300 ° C., and determine the tan ⁇ peak temperature near Tg as Tg.
- the weight average molecular weight of the component (F) is preferably controlled within the range of 5000 to 500,000. Furthermore, the weight average molecular weight of the component (F) is more preferably 10,000 to 300,000 from the viewpoint that the thermocompression bonding property and the high temperature adhesiveness can be highly compatible.
- the “weight average molecular weight” means a weight average molecular weight when measured in terms of polystyrene using high performance liquid chromatography “C-R4A” (trade name) manufactured by Shimadzu Corporation.
- component (F) examples include polyester resins, polyether resins, polyimide resins, polyamide resins, polyamideimide resins, polyetherimide resins, polyurethane resins, polyurethaneimide resins, polyurethaneamideimide resins, siloxane polyimide resins, and polyesterimide resins.
- polybenzoxazole resin phenoxy resin, polysulfone resin, polyethersulfone resin, polyphenylene sulfide resin, polyester resin, polyether resin, polycarbonate resin, poly Examples thereof include ether ketone resins, (meth) acrylic copolymers having a weight average molecular weight of 10,000 to 1,000,000, novolac resins, and phenol resins. These can be used individually by 1 type or in combination of 2 or more types.
- the main chain and / or side chain of these resins may be provided with a glycol group such as ethylene glycol or propylene glycol, a carboxyl group, and / or a hydroxyl group.
- the component (F) is preferably a resin having an imide group.
- the resin having an imide group include a polyimide resin, a polyamideimide resin, a polyetherimide resin, a polyurethaneimide resin, a polyurethaneamideimide resin, a siloxane polyimide resin, a polyesterimide resin, a copolymer thereof, and a monomer having an imide group. These polymers are mentioned.
- the component (F) is preferably a polyimide resin and / or a polyamideimide resin.
- the polyimide resin and / or polyamideimide resin can be obtained, for example, by subjecting tetracarboxylic dianhydride and diamine to a condensation reaction by a known method. That is, in the organic solvent, tetracarboxylic dianhydride and diamine are equimolar, or if necessary, the total amount of diamine is preferably 0.00 with respect to the total 1.0 mol of tetracarboxylic dianhydride.
- the composition ratio is adjusted in the range of 5 to 2.0 mol, more preferably 0.8 to 1.0 mol (the order of addition of each component is arbitrary), and the addition reaction is performed at a reaction temperature of 80 ° C. or lower, preferably 0 to 60 ° C. .
- the polyimide resin and / or the polyamideimide resin can be obtained by dehydrating and ring-closing the reaction product (polyamide acid).
- the dehydration ring closure can be performed by a thermal ring closure method in which heat treatment is performed, a chemical ring closure method using a dehydrating agent, or the like.
- Examples of the tetracarboxylic dianhydride used as a raw material for the polyimide resin and / or the polyamideimide resin include, for example, 3,3 ′, 4,4′-biphenyltetracarboxylic dianhydride in that the linear expansion coefficient can be reduced.
- Acid dianhydrides having a biphenyl skeleton such as dianhydrides, 1,2,5,6-naphthalenetetracarboxylic dianhydride, 1,4,5,8-naphthalenetetracarboxylic dianhydride, 2,3, Acid dianhydrides having a naphthyl skeleton such as 6,7-naphthalenetetracarboxylic dianhydride and 1,2,4,5-naphthalenetetracarboxylic dianhydride are preferably used.
- 3,4,3 ′, 4′-benzophenone tetracarboxylic dianhydride, 2,3,2 ′, 3′-benzophenone tetracarboxylic dianhydride, Acid dianhydrides having a benzophenone skeleton such as, 3,3 ′, 4′-benzophenone tetracarboxylic dianhydride are preferably used.
- 1,2,3,4-butanetetracarboxylic dianhydride decahydronaphthalene-1,4,5,8-tetracarboxylic dianhydride, 4,8-dimethyl-1, 2,3,5,6,7-hexahydronaphthalene-1,2,5,6-tetracarboxylic dianhydride, cyclopentane-1,2,3,4-tetracarboxylic dianhydride, 1,2 , 3,4-cyclobutanetetracarboxylic dianhydride, bis (exo-bicyclo [2,2,1] heptane-2,3-dicarboxylic dianhydride, bicyclo- [2,2,2] -oct-7 -Acid dianhydrides having an alicyclic skeleton such as ene-2,3,5,6-tetracarboxylic dianhydride and 2,2-bis (3,4-dicarboxyphenyl) hexafluoropropane dianhydride
- tetracarboxylic dianhydride represented by the following general formula (1) is preferably used.
- a represents an integer of 2 to 20.
- the tetracarboxylic dianhydride represented by the general formula (1) can be synthesized from, for example, trimellitic anhydride monochloride and the corresponding diol, specifically 1,2- (ethylene) bis ( Trimellitate anhydride), 1,3- (trimethylene) bis (trimellitic anhydride), 1,4- (tetramethylene) bis (trimellitate anhydride), 1,5- (pentamethylene) bis (trimellitate anhydride), 1 , 6- (Hexamethylene) bis (trimellitic anhydride), 1,7- (heptamethylene) bis (trimellitic anhydride), 1,8- (octamethylene) bis (trimellitic anhydride), 1,9- (nonamethylene) ) Bis (trimellitic anhydride), 1,10- (decamethylene) bis (trimellitate anhydrous), 1,12- (dodecamechi) Emissions) bis (trimellitate anhydride), 1,16 (hexamethylene decamethylene) bis (
- the tetracarboxylic dianhydride is represented by the following general formula (2) or (3) from the viewpoint of imparting good solubility in the component (A), transparency to 365 nm light, and thermocompression bonding. Tetracarboxylic dianhydride is preferred.
- tetracarboxylic dianhydrides can be used singly or in combination of two or more.
- a polyimide resin containing a carboxyl group and / or a phenolic hydroxyl group can be used in terms of further increasing the adhesive strength.
- the diamine used as a raw material for the carboxyl group and / or hydroxyl group-containing polyimide resin preferably contains an aromatic diamine represented by the following general formula (4), (5), (6) or (7).
- diamines used as raw materials for the polyimide resin and / or polyamideimide resin are not particularly limited, but the following diamines can be used to adjust the Tg and solubility of the polymer.
- diamines used as raw materials for the polyimide resin and / or polyamideimide resin.
- 3,3′-diaminodiphenyl sulfide, 3,4′-diaminodiphenyl sulfide, 4,4′-diaminodiphenyl sulfide, bis (4- (3- Aminoenoxy) phenyl) sulfide and bis (4- (4-aminoenoxy) phenyl) sulfide are preferably used.
- diamines that can lower Tg include 1,3-bis (aminomethyl) cyclohexane, aliphatic ether diamines represented by the following general formula (8), and siloxane diamines represented by the following general formula (9). Etc.
- R 1 , R 2 and R 3 each independently represents an alkylene group having 1 to 10 carbon atoms, and b represents an integer of 2 to 80.
- R 4 and R 9 each independently represent an alkylene group having 1 to 5 carbon atoms or a phenylene group which may have a substituent
- R 5 , R 6 , R 7 and R 8 Each independently represents an alkyl group having 1 to 5 carbon atoms, a phenyl group or a phenoxy group
- d represents an integer of 1 to 5.
- aliphatic ether diamines represented by the general formula (8) are preferable, and ethylene glycol and / or propylene glycol diamines are more preferable in terms of imparting compatibility with other components.
- aliphatic ether diamines include Jeffamine D-230, D-400, D-2000, D-4000, ED-600, ED-900, ED-2000, and EDR manufactured by Sun Techno Chemical Co., Ltd. 148, aliphatic diamines such as polyoxyalkylene diamines such as polyetheramine D-230, D-400, D-2000 and the like. These diamines are preferably 20 mol% or more of the total diamine, and are compatible with other components such as (A) radiation-polymerizable compounds and (C) thermosetting resins, and thermocompression bonding and high-temperature adhesion. It is more preferable that it is 50 mol% or more from the standpoint of achieving high compatibility with the properties.
- the diamine is preferably a siloxane diamine represented by the general formula (9) from the viewpoint of imparting adhesiveness and adhesiveness at room temperature.
- diamines are preferably 0.5 to 80 mol% of the total diamine, and more preferably 1 to 50 mol% in terms of achieving both high thermocompression bonding and high temperature adhesiveness. If the amount is less than 0.5 mol%, the effect of adding siloxane diamine is reduced. If the amount exceeds 80 mol%, the compatibility with other components and high-temperature adhesiveness tend to be reduced.
- the above-mentioned diamines can be used alone or in combination of two or more.
- the said polyimide resin and / or a polyamide-imide resin can be used individually by 1 type or in mixture (blend) of 2 or more types as needed.
- the Tg when determining the composition of the polyimide resin and / or the polyamideimide resin, it is preferable to design the Tg to be 150 ° C. or less. It is particularly preferable to use an aliphatic ether diamine represented by the general formula (8).
- a monofunctional acid anhydride and / or a monofunctional amine such as a compound represented by the following general formula (10), (11) or (12) is condensed into a reaction solution. It is possible to introduce a functional group other than an acid anhydride or a diamine at the polymer terminal. Thereby, the molecular weight of the polymer can be lowered, the viscosity of the adhesive resin composition can be lowered, and the thermocompression bonding property can be improved.
- the thermoplastic resin may have a functional group having a function of promoting the curing of an epoxy resin such as imidazole in its main chain and / or side chain.
- the imidazole-containing polyimide can be obtained, for example, by using a diamine group-containing diamine as shown in the following structural formula as a diamine component shown above.
- a polymer having such an imidazole in the side chain is preferable because compatibility and storage stability can be improved.
- the polyimide resin and / or polyamide-imide resin can be uniformly B-staged, and the transmittance with respect to 365 nm when molded to 30 ⁇ m is preferably 10% or more, and can be B-staged with a lower exposure amount. And more preferably 20% or more.
- a polyimide resin and / or polyamideimide resin includes, for example, an acid anhydride represented by the general formula (2), an aliphatic ether diamine represented by the general formula (8), and / or the general formula. It can be synthesized by reacting with the siloxane diamine represented by (9).
- thermoplastic resin (F) it is preferable to use a liquid thermoplastic resin that is liquid at room temperature (25 ° C.) from the viewpoint of suppressing an increase in viscosity and further reducing undissolved residue in the adhesive composition. .
- a thermoplastic resin can be reacted by heating without using a solvent, and in an adhesive composition that does not apply the solvent as in the present invention, the solvent removal process is reduced, the residual solvent is reduced, and the reprecipitation process is performed. This is useful in terms of reduction.
- the liquid thermoplastic resin can be easily taken out from the reaction furnace.
- liquid thermoplastic resin examples include rubber-like polymers such as polybutadiene, acrylonitrile / butadiene oligomer, polyisoprene, and polybutene, polyolefins, acrylic polymers, silicone polymers, polyurethanes, polyimides, and polyamideimides. Of these, polyimide resins and / or polyamideimide resins are preferably used.
- the liquid polyimide resin and / or polyamideimide resin can be obtained, for example, by reacting the above acid anhydride with an aliphatic ether diamine or siloxane diamine.
- Examples of the synthesis method include a method in which an acid anhydride is dispersed in an aliphatic ether diamine or siloxane diamine without adding a solvent and heated.
- the content of the thermoplastic resin (F) is preferably 0.1 to 50% by mass with respect to the component (A), and 0.5 to 20% by mass from the viewpoints of film formability, film thickness uniformity, and suppression of viscosity increase. % Is more preferable. If the content of the thermoplastic resin is less than 0.1% by mass, the effect of addition tends to be lost, and if it exceeds 50% by mass, the film thickness uniformity decreases due to undissolved or the like. It tends to rise and make thinning difficult.
- Polymerization inhibitors such as quinones, polyhydric phenols, phenols, phosphites, sulfurs, etc. in order to impart storage stability, process adaptability or antioxidant properties to the adhesive composition according to the present invention Or you may add antioxidant in the range which does not impair sclerosis
- the adhesive composition according to the present invention may appropriately contain a filler.
- the filler include metal fillers such as silver powder, gold powder, copper powder, and nickel powder, alumina, aluminum hydroxide, magnesium hydroxide, calcium carbonate, magnesium carbonate, calcium silicate, magnesium silicate, calcium oxide, magnesium oxide, Inorganic fillers such as aluminum oxide, aluminum nitride, crystalline silica, amorphous silica, boron nitride, titania, glass, iron oxide, and ceramics, and organic fillers such as carbon and rubber fillers are included. Regardless, it can be used without any particular restrictions.
- the filler can be used properly according to the desired function.
- the metal filler is added for the purpose of imparting conductivity, thermal conductivity, thixotropy, etc. to the adhesive composition
- the nonmetallic inorganic filler is thermally conductive, low thermal expansion, low hygroscopicity to the adhesive layer.
- the organic filler is added for the purpose of imparting toughness to the adhesive layer.
- metal fillers, inorganic fillers or organic fillers can be used singly or in combination of two or more.
- metal fillers, inorganic fillers, or insulating fillers are preferable in terms of being able to impart conductivity, thermal conductivity, low moisture absorption characteristics, insulating properties, and the like required for adhesive materials for semiconductor devices, and inorganic fillers or insulating fillers.
- a silica filler is more preferable in that the dispersibility with respect to the adhesive composition is good and a high adhesive force during heating can be imparted.
- the filler preferably has an average particle size of 10 ⁇ m or less and a maximum particle size of 30 ⁇ m or less, more preferably an average particle size of 5 ⁇ m or less and a maximum particle size of 20 ⁇ m or less. If the average particle size exceeds 10 ⁇ m or the maximum particle size exceeds 30 ⁇ m, the effect of improving fracture toughness tends to be insufficient. Further, the lower limits of the average particle size and the maximum particle size are not particularly limited, but both are preferably 0.001 ⁇ m or more.
- the content of the filler is determined according to the properties or functions to be imparted, but is preferably 50% by mass or less, more preferably 1 to 40% by mass with respect to the total amount of the adhesive composition containing the filler. More preferred is 30% by mass.
- the amount of filler By increasing the amount of filler, low alpha, low moisture absorption, and high elastic modulus can be achieved, and dicing performance (cutability with a dicer blade), wire bonding performance (ultrasonic efficiency), and adhesive strength during heating are effectively improved. Can be made.
- the amount of filler is increased more than necessary, the viscosity tends to increase or the thermocompression bonding property tends to be impaired. Therefore, the filler content is preferably within the above range.
- the optimum filler content can be determined to balance the required properties. Mixing and kneading in the case of using a filler can be carried out by appropriately combining dispersers such as ordinary stirrers, raking machines, three rolls, and ball mills.
- various coupling agents can be added in order to improve interfacial bonding between different materials.
- the coupling agent include silane-based, titanium-based, and aluminum-based.
- a silane-based coupling agent is preferable because of its high effect, and a thermosetting group such as an epoxy group, methacrylate, and / or acrylate.
- a compound having a radiation polymerizable group such as is more preferred.
- the boiling point and / or decomposition temperature of the silane coupling agent is preferably 150 ° C. or higher, more preferably 180 ° C. or higher, and even more preferably 200 ° C. or higher.
- a silane coupling agent having a boiling point of 200 ° C. or higher and / or a decomposition temperature and having a thermosetting group such as an epoxy group and a radiation polymerizable group such as methacrylate and / or acrylate is most preferably used.
- the amount of the coupling agent used is preferably 0.01 to 20 parts by mass with respect to 100 parts by mass of the adhesive composition from the viewpoint of its effect, heat resistance and cost.
- an ion scavenger may be further added in order to adsorb ionic impurities and improve the insulation reliability during moisture absorption.
- an ion scavenger is not particularly limited, for example, a compound known as a copper damage inhibitor for preventing copper from being ionized and dissolved, such as a triazine thiol compound and a phenol-based reducing agent, a powder form Inorganic compounds such as bismuth-based, antimony-based, magnesium-based, aluminum-based, zirconium-based, calcium-based, titanium-based, zuz-based, and mixed systems thereof.
- IXE-300 antimony type
- IXE-500 bismuth type
- IXE-600 antimony and bismuth mixed type
- IXE-700. Matture of magnesium and aluminum
- IXE-800 zirconium
- IXE-1100 calcium and the like.
- the amount of the ion scavenger used is preferably 0.01 to 10 parts by mass with respect to 100 parts by mass of the adhesive composition from the viewpoint of the effect of addition, heat resistance, cost and the like.
- the adhesive composition according to the present invention preferably contains a compound having an imide group.
- the compound having an imide group is, for example, a low molecular compound such as a monofunctional (meth) acrylate having an imide group mentioned as the A1 compound, or a resin having an imide group such as a polyimide resin mentioned as the component (F). It can be included.
- the adhesive composition according to the present invention preferably has a viscosity at 25 ° C. of 10 to 30000 mPa ⁇ s, more preferably 30 to 20000 mPa ⁇ s, and even more preferably 50 to 10000 mPa ⁇ s. Preferably, it is 100 to 5000 mPa ⁇ s.
- the viscosity is less than 10 mPa ⁇ s, there is a tendency that the storage stability and heat resistance of the adhesive composition are lowered, and pinholes are likely to occur when the adhesive composition is applied.
- the viscosity exceeds 30000 mPa ⁇ s, there is a tendency that it is difficult to make a thin film at the time of coating, and it is difficult to discharge from the nozzle.
- the 5% weight reduction temperature of the adhesive composition formed into a film by light irradiation is preferably 150 ° C or higher, more preferably 180 ° C or higher, and 200 ° C or higher. Most preferably.
- the 5% weight loss temperature is lower than 150 ° C., peeling tends to occur due to outgas at the time of curing.
- a material design mainly composed of an organic compound is preferable, so the 5% weight loss temperature is 500 ° C. The following is preferable.
- the amount of the solvent contained in the adhesive composition is preferably 5% by mass or less, more preferably 3% by mass or less, and more preferably 1% by mass. Most preferably:
- the 5% weight loss temperature is a value measured as follows.
- the adhesive composition is applied onto a silicon wafer by spin coating (2000 rpm / 10 s, 4000 rpm / 20 s), and the obtained coating film is laminated with a hand roller at room temperature to obtain a high-precision coating. Exposure is performed at 1000 mJ / cm 2 using a parallel exposure machine (Oak Seisakusho, “EXM-1172-B- ⁇ ” (trade name)).
- the B-staged adhesive was measured using a differential thermothermal gravimetric simultaneous measurement apparatus (trade name “TG / DTA6300” manufactured by SII Nano Technology) with a temperature rising rate of 10 ° C./min, nitrogen flow (400 ml / Measure the 5% weight loss temperature under min).
- TG / DTA6300 manufactured by SII Nano Technology
- the surface tack force at 30 ° C. of the film formed by light irradiation is 200 gf / cm 2 or less, and the surface tack force at 120 ° C. is 200 gf / cm 2 or more. Is preferred.
- the surface tack force at 30 ° C. is preferably 0.1 gf / cm 2 or more.
- the surface tack force at 30 ° C. exceeds 200 gf / cm 2 , the adhesiveness of the resulting adhesive layer at room temperature tends to be high, and the handleability tends to be poor.
- water tends to enter the interface between the adhesive and the adherend during dicing and chip jumping occurs, and the peelability from the dicing sheet after dicing decreases and pickup properties tend to occur. This is not preferable.
- the amount of solvent in the adhesive composition is preferably 5% or less, more preferably 3% or less, and 1% or less. Is most preferred.
- the surface tack force is a value measured as follows.
- the adhesive composition was applied on a PET (polyethylene terephthalate) film so as to have a film thickness of 30 ⁇ m, and the obtained coating film was laminated with a release-treated PET film. Exposure is performed at 1000 mJ / cm 2 by “EXM-1172-B- ⁇ ” (trade name). Thereafter, the surface tack strength at 30 ° C. and 120 ° C. was measured using a probe tacking tester manufactured by Reska Co., Ltd., probe diameter: 5.1 mm, peeling speed: 10 mm / s, contact load: 100 gf / cm 2 , contact Measure the tack force at 30 ° C. and 120 ° C. with time: 1 s.
- the adhesive composition according to the present invention preferably has a minimum melt viscosity of 5000 Pa ⁇ s or less at 20 ° C. to 300 ° C. of a film formed by light irradiation.
- the minimum melt viscosity is that the adhesive composition is applied on a PET (polyethylene terephthalate) film so as to have a film thickness of 30 ⁇ m, and after laminating the substrate in air or after light exposure of 1000 mJ / cm 2 .
- the minimum value of the melt viscosity at 20 ° C. to 300 ° C. when the sample is measured using a viscoelasticity measuring device ARES (manufactured by Rheometrics Scientific F.E.) is shown.
- the measurement plate is a parallel plate having a diameter of 8 mm, the measurement conditions are a temperature increase of 5 ° C./min, the measurement temperature is 20 ° C. to 300 ° C., and the frequency is 1 Hz.
- the adhesive composition according to the present invention preferably has a storage elastic modulus at 100 ° C. of a film formed by light irradiation of 0.1 MPa or less.
- the storage elastic modulus at 100 ° C. exceeds 0.1 MPa, the low temperature sticking property and the thermocompression bonding property are impaired, voids are generated at the time of sticking or thermocompression bonding, and the thermocompression bonding temperature tends to increase. It is not preferable.
- the storage elastic modulus here means that the adhesive composition is applied on a PET (polyethylene terephthalate) film so as to have a film thickness of 30 ⁇ m, and after laminating the substrate in air or after light exposure of 1000 mJ / cm 2 .
- the sample was laminated by roll pressurization (temperature 60 ° C., linear pressure 4 kgf / cm, feed rate 0.5 m / min) so that the thickness was 150 ⁇ m, and the obtained laminate was cut into strips of 5 mm width.
- Storage 100 ° C. when measured at a temperature rising rate of 5 ° C./min, a frequency of 1 Hz, and a measurement temperature of 0 to 300 ° C. using a rheometrics viscoelasticity analyzer “RSA-2” (trade name) Indicates the elastic modulus.
- the adhesive composition according to the present invention is preferably formed into a film by light irradiation and further has a 5% weight loss temperature of 260 ° C. or higher after heat curing. If the 5% weight loss temperature is less than 260 ° C., peeling tends to occur due to a thermal history such as a reflow process.
- the amount of outgas at the time of heat curing is preferably 10% or less, more preferably 7% or less, and most preferably 5% or less. When the amount of outgas exceeds 10%, voids and separation tend to occur during heat curing.
- the outgas amount here is a value measured as follows.
- the adhesive composition was applied onto a PET (polyethylene terephthalate) film so as to have a film thickness of 30 ⁇ m, and the obtained coating film was laminated with a hand roller at room temperature to obtain a highly accurate parallel film.
- Exposure is carried out at 1000 mJ / cm 2 using an exposure machine (“EXM-1172-B- ⁇ ” (trade name) manufactured by Oak Seisakusho). Then, using a differential thermothermal gravimetric simultaneous measurement apparatus (trade name “TG / DTA6300”, manufactured by SII Nano Technology Co., Ltd.), the film-formed adhesive was heated at a rate of temperature increase of 50 under a nitrogen flow (400 ml / min).
- the film adhesive formed from the adhesive composition according to the present invention preferably has a shear adhesive strength at 260 ° C. of 0.2 MPa or more, and 0.5 MPa or more at the stage where the semiconductor element is bonded. It is more preferable. Peeling tends to occur due to thermal history such as a reflow process in which the shear bond strength is less than 0.2 MPa.
- the shear adhesive strength here refers to a silicon wafer prepared by attaching a film adhesive by roll pressurization (temperature 60 ° C., linear pressure 4 kgf / cm, feed rate 0.5 m / min). A silicon wafer is cut out. The cut silicon chip with adhesive is placed on a silicon chip that has been cut into 5 ⁇ 5 mm squares, and pressed with pressure of 200 gf for 2 seconds at 120 ° C. Thereafter, it is heated in an oven at 140 ° C. for 1 hour and then at 180 ° C. for 3 hours to obtain an adhesive sample. The obtained sample was measured for shear adhesive strength at 260 ° C. using a shear adhesive strength tester “Dage-4000” (trade name) (measurement conditions, speed: 50 ⁇ m / sec, height: 50 ⁇ m). Is the value of the shear bond strength.
- Examples of the adhesive sheet of the present invention include those having a structure in which a dicing sheet and a film adhesive according to the present invention are laminated (for example, FIG. 3). Such an adhesive sheet can be easily obtained by using a dicing sheet as a substrate in the method for producing a film adhesive of the present invention. In the present embodiment, it is preferable that the film adhesive is preliminarily formed (pre-cut) into a shape close to the wafer.
- an adhesive sheet more specifically, an adhesive sheet in which a base film, an adhesive layer and a film adhesive according to the present invention are formed in this order, or a base film and the film adhesive according to the present invention.
- the adhesive sheet formed from is mentioned.
- this adhesive sheet is an integral type comprising at least a film adhesive and a dicing sheet, or a base film capable of securing elongation (commonly referred to as expanding) when a tensile tension is applied.
- This is an adhesive sheet. That is, it is an adhesive sheet having characteristics required for both a dicing sheet and a die bonding film.
- a pressure-sensitive adhesive layer that functions as a dicing sheet is provided on the base film, and the film adhesive according to the present invention that functions as a die bonding film is further laminated on the pressure-sensitive adhesive layer, or
- a function as a dicing sheet at the time of dicing and a function as a die bonding film at the time of die bonding can be exhibited. Therefore, an integrated adhesive sheet can be used by picking up a semiconductor element with an adhesive after laminating and dicing the film adhesive of the integrated adhesive sheet on the back surface of the semiconductor wafer while heating the film adhesive on the back surface of the semiconductor wafer. it can.
- the pressure-sensitive adhesive layer may be either a pressure-sensitive type or a radiation-curing type, but the radiation-curing type has a high adhesive force during dicing, and is irradiated with ultraviolet rays (UV) before picking up. It is preferable in terms of low adhesive strength and easy control of adhesive strength.
- the radiation-curing pressure-sensitive adhesive layer should have sufficient adhesive strength so that the semiconductor element does not scatter during dicing, and has a low adhesive strength that does not damage the semiconductor element in the subsequent pick-up process of the semiconductor element. Conventionally known ones can be used without particular limitation.
- the base film is not particularly limited as long as it can secure elongation (commonly referred to as expanded) when a tensile tension is applied, but a film made of polyolefin is preferably used.
- the film-like adhesive and the adhesive sheet according to the present invention include semiconductor elements such as IC and LSI, lead frames such as 42 alloy lead frames and copper lead frames, plastic films such as polyimide resins and epoxy resins, and substrates such as glass nonwoven fabrics. It can be used as an adhesive material for die bonding for adhering to an adherend such as a semiconductor mounting support member such as ceramics such as alumina. Among them, it is suitably used as an adhesive material for die bonding for bonding an organic substrate having an uneven surface on a surface such as an organic substrate having an organic resist layer on the surface and an organic substrate having wiring on the surface, and a semiconductor element.
- a Stacked-PKG having a structure in which a plurality of semiconductor elements are stacked, it is also suitably used as an adhesive material for protecting, filling and bonding the semiconductor elements.
- Step 1 A peelable adhesive tape (back grind tape) 4 is laminated on the circuit surface S1 of the semiconductor chip (semiconductor element) 2 formed in the semiconductor wafer 1 (see FIG. 1).
- Step 2 The semiconductor wafer 1 is polished from the surface (back surface) S2 opposite to the circuit surface S1 to thin the semiconductor wafer 1 (see FIG. 2).
- Step 3 The adhesive sheet 50 of the present invention is prepared (see FIG. 3), and the adhesive layer 5 (film adhesive) of the adhesive sheet 50 of the present invention is formed on the surface S2 of the semiconductor wafer 1 opposite to the circuit surface S1. ) (See FIG. 4).
- Step 4 The peelable adhesive tape 4 is peeled off (see FIG. 5).
- Step 5 The semiconductor wafer 1 is cut into a plurality of semiconductor chips (semiconductor elements) 2 by dicing (see FIG. 6).
- Step 6 The semiconductor chip 2 is picked up and pressure-bonded (mounted) to the semiconductor device support member (semiconductor element mounting support member) 7 or the semiconductor chip (see FIGS. 7, 8, and 9).
- Step 7 The mounted semiconductor chip is connected to an external connection terminal on the support member 7 through the wire 16 (see FIG. 10).
- Step 8 The stacked body including the plurality of semiconductor chips 2 is sealed with the sealing material 17 to obtain the semiconductor device 100 (see FIG. 11).
- Step 1 (Step 1) to (Step 8) will be described in detail.
- a peelable adhesive tape 4 is laminated on the circuit surface S1 side of the semiconductor wafer 1 on which a circuit is formed. Lamination of the adhesive tape 4 can be performed by a method of laminating a film previously formed into a film shape.
- Process 2 The surface S2 opposite to the adhesive tape 4 of the semiconductor wafer 1 is polished to thin the semiconductor wafer 1 to a predetermined thickness. Polishing is performed using a grinding apparatus 8 in a state where the semiconductor wafer 1 is fixed to a polishing jig by an adhesive tape 4.
- the adhesive sheet 50 can be produced by using a dicing sheet as a base material in the above-described method for producing a film adhesive of the present invention.
- Examples of a method for attaching the adhesive layer 5 of the adhesive sheet 50 to the back surface of the semiconductor wafer 1 include roll lamination.
- the adhesive tape 4 attached to the circuit surface of the semiconductor wafer 1 is peeled off.
- an adhesive tape whose adhesiveness is reduced by irradiation with actinic rays typically ultraviolet rays
- it can be peeled off.
- the semiconductor wafer 1 is cut along with the adhesive layer 5 along the dicing line D.
- the semiconductor wafer 1 is cut into a plurality of semiconductor chips 2 each provided with an adhesive layer 5 on the back surface. Dicing is performed using a dicing blade 11 in a state where the whole is fixed to a frame (wafer ring) 10 with an adhesive tape (dicing tape) 6.
- Step 6 After dicing, the cut semiconductor chip 2 is picked up together with the adhesive layer 5 by the die bonding apparatus 12, that is, the semiconductor element with the adhesive layer is picked up, and a support member for semiconductor device (support member for mounting semiconductor elements) 7 Alternatively, it is pressure-bonded (mounted) to another semiconductor chip 2.
- the pressure bonding is preferably performed while heating.
- the heating temperature is usually 20 to 250 ° C.
- the load is usually 0.01 to 20 kgf
- the heating time is usually 0.1 to 300 seconds.
- the shear bond strength at 260 ° C. between the semiconductor chip and the supporting member or other semiconductor chip is preferably 0.2 MPa or more, more preferably 0.5 MPa or more in terms of suppressing peeling due to thermal history, Most preferred is 1.0 MPa or more from the viewpoint of moisture absorption reflow resistance.
- the shear adhesive strength is preferably 50 MPa or less. The shear bond strength can be measured in the same manner as described above.
- each semiconductor chip 2 is connected to an external connection terminal on the support member 7 through a wire 16 connected to the bonding pad.
- the semiconductor device 100 is obtained by sealing the stacked body including the semiconductor chip 2 with the sealing material 17.
- the film adhesive of the present invention may be used. Specifically, it can be sealed by laminating the film adhesive of the present invention on a laminate and heat-curing. Further, dicing can be performed after collective sealing to separate the package.
- a semiconductor device having a structure in which semiconductor elements and / or a semiconductor element and a semiconductor element mounting support member are bonded to each other is manufactured by the film adhesive according to the present invention. It can.
- the configuration and the manufacturing method of the semiconductor device are not limited to the above embodiment, and can be appropriately changed without departing from the gist of the present invention.
- the order of steps 1 to 7 can be changed as necessary.
- the film adhesive according to the present invention can be attached to the back surface of a semiconductor wafer diced in advance.
- thermoplastic resin Preparation of thermoplastic resin>.
- P-1 In a four-necked flask, weigh 80 g of dimethylformamide and 20 g of N-acryloyloxyethylhexahydrophthalimide, stir them, add 0.6 g of 2,2′-azobisisobutyronitrile and dissolve. I let you. Then, after hold
- thermoplastic resins (P-1) and (P-2) obtained above each component was blended in the composition ratios (unit: parts by mass) shown in Tables 1 to 3 below. 13 adhesive compositions and Comparative Example 1-2 adhesive compositions (adhesive layer forming varnish) were obtained.
- M-140 N-acryloyloxyethyl hexahydrophthalimide (5% weight loss temperature: 200 ° C., viscosity at 25 ° C .: 450 mPa ⁇ s) manufactured by Toa Gosei Co., Ltd.
- A-BPE4 Shin-Nakamura Chemical Co., Ltd., ethoxylated bisphenol A acrylate (5% weight loss temperature: 330 ° C., viscosity at 25 ° C .: 950 mPa ⁇ s).
- I-651 2,2-dimethoxy-1,2-diphenylethane-1-one (5% weight loss temperature: 170 ° C., i-line extinction coefficient: 400 ml / g ⁇ cm), manufactured by Ciba Japan.
- I-379EG 2-dimethylamino-2- (4-methyl-benzyl) -1- (4-morpholin-4-yl-phenyl) -butan-1-one (5% weight loss temperature, manufactured by Ciba Japan) : 260 ° C., molecular extinction coefficient at 365 nm: 8000 ml / g ⁇ cm).
- I-907 2-methyl-1- (4- (methylthio) phenyl) -2-morpholinopropan-1-one (5% weight loss temperature: 220 ° C., molecular extinction coefficient at 365 nm, manufactured by Ciba Japan : 450 ml / g ⁇ cm).
- I-OXE02 Etanone, 1- [9-ethyl-6- (2-methylbenzoyl) -9H-carbazol-3-yl]-, 1- (o-acetyloxime), manufactured by Ciba Japan, (5% Weight reduction temperature: 370 ° C., molecular extinction coefficient at 365 nm: 7700 ml / g ⁇ cm).
- YDF-8170C manufactured by Tohto Kasei Co., Ltd., bisphenol F type bisglycidyl ether (5% weight loss temperature: 270 ° C., viscosity at 25 ° C .: 1300 mPa ⁇ s).
- 1032H60 manufactured by Japan Epoxy Resin Co., Ltd., tris (hydroxyphenyl) methane type solid epoxy resin (5% weight loss temperature: 350 ° C., solid, melting point 60 ° C.).
- MEH-8000H manufactured by Meiwa Kasei Co., Ltd., modified liquid phenol novolak resin (5% weight loss temperature: 220 ° C., viscosity: 2500 mPa ⁇ s).
- 2PHZ-PW 2-phenyl-4,5-dihydroxymethylimidazole (average particle diameter: about 3 ⁇ m) manufactured by Shikoku Chemicals.
- 1B2PZ 1-benzyl-2-phenylimidazole manufactured by Shikoku Kasei Co., Ltd.
- Park Mill D Dicumyl peroxide (manufactured by NOF Corporation, 1 minute half-life temperature: 175 ° C.)
- NMP N-methyl-2-pyrrolidone manufactured by Kanto Chemical Co., Inc.
- the above 5% weight loss temperature is measured using a differential thermothermal gravimetric simultaneous measurement apparatus (product name “TG / DTA6300” manufactured by SII Nano Technology) with a heating rate of 10 ° C./min, nitrogen flow ( 400 ml / min).
- the above viscosity is a value measured at 25 ° C. under the conditions of a sample volume of 0.4 mL and a 3 ° cone using an EHD type rotational viscometer manufactured by Tokyo Keiki Seisakusho.
- the molecular extinction coefficient was determined by preparing a 0.001 mass% acetonitrile solution of the sample, placing the solution in a quartz cell, and measuring the spectrophotometer (Hitachi High-Technologies Corp., “U-” at room temperature (25 ° C.) under air. 3310 "(trade name)) and the absorbance was measured.
- the viscosity of the adhesive composition was evaluated on the minimum required light amount for film formation, the minimum required time for film formation, melt viscosity, thermocompression bonding, 5% weight loss temperature after light irradiation, and 260 ° C. adhesive strength.
- the adhesive composition was applied onto a polyethylene terephthalate (PET) film so as to have a predetermined film thickness using an applicator.
- the obtained coating film was laminated with a release roller using a hand roller, and then a high-precision parallel exposure machine (manufactured by Oak Manufacturing Co., Ltd., “EXM-1172-B- ⁇ ” (trade name), strength: 10 mW / was subjected to exposure in 1000mJ / cm 2 by cm 2).
- the obtained adhesive layer having a predetermined film thickness was peeled off from the polyethylene terephthalate (PET) film, and A was able to obtain a film-like structure alone, and C was evaluated as not being able to be obtained.
- ⁇ Film thickness> The thickness of the adhesive layer was measured using a surface roughness measuring device (manufactured by Kosaka Laboratory).
- the adhesive composition was applied onto a polyethylene terephthalate (PET) film so as to have a predetermined film thickness using an applicator.
- PET polyethylene terephthalate
- the obtained coating film was laminated with a release roller using a hand roller, and then a high-precision parallel exposure machine (manufactured by Oak Seisakusho, “EXM-1172-B- ⁇ ” (trade name), strength: 10 mW / Cm 2 ) and exposure was performed at 1000 mJ / cm 2 . Thereafter, the surface tack strength at 30 ° C.
- the adhesive composition was applied onto a polyethylene terephthalate (PET) film so as to have a predetermined film thickness using an applicator.
- PET polyethylene terephthalate
- the obtained coating film was exposed at 1000 mJ / cm 2 with a high-precision parallel exposure machine (manufactured by Oak Seisakusho, “EXM-1172-B- ⁇ ” (trade name), strength: 10 mW / cm 2 ) under air at room temperature. Was done. Thereafter, the surface tack strength at 30 ° C.
- the adhesive composition was applied on a polyethylene terephthalate (PET) film using an applicator so as to have a film thickness of 30 ⁇ m.
- PET polyethylene terephthalate
- the obtained coating film was laminated at room temperature air, and in Example 3 after laminating a release-treated PET film, a high-precision parallel exposure machine (oak) was laminated at room temperature air.
- 100, 200, 500, and 1000 mJ / cm 2 were respectively exposed using “EXM-1172-B- ⁇ ” (trade name), strength: 10 mW / cm 2 , manufactured by Seisakusho.
- the exposure amount at which the surface tack force at 30 ° C. measured by the above method was 200 gf / cm 2 or less was defined as the minimum required light amount (mJ / cm 2 ).
- the required time at that time was defined as the minimum required time for film formation (s).
- melt viscosity here is a value measured as follows.
- the adhesive composition was applied on a PET film so as to have a film thickness of 50 ⁇ m.
- the obtained coating film was laminated at room temperature air, and in Example 3 after laminating a release-treated PET film, a high-precision parallel exposure machine (oak) was laminated at room temperature air. Exposure was carried out at 1000 mJ / cm 2 using “EXM-1172-B- ⁇ ” (trade name) manufactured by Seisakusho.
- the obtained adhesive sheet is placed on a Teflon sheet, the adhesive layer is set to the Teflon sheet side, and the thickness is about 200 ⁇ m by pressing with a roll (temperature 60 ° C., linear pressure 4 kgf / cm, feed rate 0.5 m / min). It was laminated so as to be.
- the obtained sample was measured using a viscoelasticity measuring apparatus (Rheometrics Scientific F.E., trade name: ARES).
- the measurement plate was a parallel plate having a diameter of 25 mm, and the measurement conditions were set to a temperature increase of 10 ° C./min and a frequency of 1 Hz.
- the lowest melt viscosity at 20 ° C. to 200 ° C. was taken as the melt viscosity.
- ⁇ Low temperature adhesiveness> A silicon wafer (6 inch diameter, 400 ⁇ m thickness) is placed on a support base, and an adhesive layer produced by the same method as the above ⁇ film formation by light irradiation> is placed on the silicon wafer.
- An adhesive layer produced by the same method as the above ⁇ film formation by light irradiation> is placed on the silicon wafer.
- a polyimide film having a thickness of 80 ⁇ m, a width of 10 mm, and a length of 40 mm (“Upilex” (trade name) manufactured by Ube Industries, Ltd.) Laminating was performed under roll pressure under the same conditions.
- the sample of the laminated body which consists of a silicon wafer, an adhesive bond layer, and a polyimide film, and these are laminated
- the obtained sample was subjected to a 90 ° peel test at room temperature using a rheometer (manufactured by Toyo Seisakusho Co., Ltd., “Strograph ES” (trade name)) to peel the adhesive layer and the polyimide film. The strength was measured. Based on the measurement results, stickability was evaluated with a sample having a peel strength of 2 N / cm or more as A and a sample having a peel strength of less than 2 N / cm as C.
- a silicon wafer (6 inch diameter, 400 ⁇ m thickness) is placed on a support base, and an adhesive layer produced by the same method as the above ⁇ film formation by light irradiation> is placed on the silicon wafer.
- An adhesive layer produced by the same method as the above ⁇ film formation by light irradiation> is placed on the silicon wafer.
- was laminated by roll pressurization (temperature 80 ° C., linear pressure 4 kgf / cm, feed rate 0.5 m / min) so as to be in contact with the back surface (surface opposite to the support).
- PET film base material
- a silicon wafer was cut into a 3 ⁇ 3 mm square.
- the cut silicon chip with adhesive was placed on a silicon chip that had been cut into 5 ⁇ 5 mm square in advance, and thermocompression bonded at 120 ° C.
- thermocompression resistance was evaluated with A being less than 1 MPa and C being C.
- the adhesive composition was applied onto a polyethylene terephthalate (PET) film so as to have a predetermined film thickness using an applicator.
- PET polyethylene terephthalate
- the obtained coating film was laminated with a release-treated PET film, and then 1000 mJ using a high-precision parallel exposure machine (manufactured by Oak Seisakusho, “EXM-1172-B- ⁇ ” (trade name), strength: 10 mW / cm 2 ). The exposure was performed at / cm 2 .
- the film-like adhesive thus obtained was subjected to a simultaneous differential thermothermogravimetric measuring device (trade name “TG / DTA6300” manufactured by SII Nano Technology Co., Ltd.) and a nitrogen flow rate (400 ml). The 5% weight loss temperature was measured under
- a silicon wafer (6 inch diameter, 400 ⁇ m thickness) is placed on a support base, and an adhesive layer produced by the same method as the above ⁇ film formation by light irradiation> is placed on the silicon wafer.
- An adhesive layer produced by the same method as the above ⁇ film formation by light irradiation> is placed on the silicon wafer.
- was laminated by roll pressurization temperature 80 ° C., linear pressure 4 kgf / cm, feed rate 0.5 m / min
- a silicon wafer was cut into a 3 ⁇ 3 mm square.
- the cut silicon chip with adhesive was placed on a silicon chip that had been cut into 5 ⁇ 5 mm square in advance, and thermocompression bonded at 120 ° C.
- the obtained sample was measured for adhesive strength at 260 ° C. using a shear adhesive strength tester “Dage-4000” (trade name) (measurement conditions, speed: 50 ⁇ m / sec, height: 50 ⁇ m). This was made into the value of 260 degreeC adhesive strength.
- SYMBOLS 1 ... Semiconductor wafer, 2 ... Semiconductor chip, 4 ... Adhesive tape (back grind tape), 5 ... Adhesive layer (film adhesive), 6 ... Dicing tape, 7 ... Support member, 8 ... Grinding device, 9 ... Exposure Device: 10 ... Wafer ring, 11 ... Dicing blade, 12 ... Die bonding device, 14, 15 ... Hot plate, 16 ... Wire, 17 ... Sealing material, 18 ... Connection terminal, 50 ... Adhesive sheet, 100 ... Semiconductor device, S1 ... the circuit surface of the semiconductor wafer, S2 ... the back surface of the semiconductor wafer.
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Abstract
Description
工程1:半導体ウェハ1内に形成された半導体チップ(半導体素子)2の回路面S1上にはく離可能な粘着テープ(バックグラインドテープ)4を積層する(図1を参照)。
工程2:半導体ウェハ1を回路面S1とは反対側の面(裏面)S2から研磨して半導体ウェハ1を薄くする(図2を参照)。
工程3:本発明の接着シート50を用意し(図3を参照)、半導体ウェハ1の回路面S1とは反対側の面S2に本発明の接着シート50の接着剤層5(フィルム状接着剤)を貼り付ける(図4を参照)。
工程4:はく離可能な粘着テープ4をはく離する(図5を参照)。
工程5:半導体ウェハ1をダイシングにより複数の半導体チップ(半導体素子)2に切り分ける(図6を参照)。
工程6:半導体チップ2をピックアップして半導体装置用の支持部材(半導体素子搭載用支持部材)7または半導体チップに圧着(マウント)する(図7、8、9を参照)。
工程7:マウントされた半導体チップを、ワイヤ16を介して支持部材7上の外部接続端子と接続する(図10を参照)。
工程8:複数の半導体チップ2を含む積層体を封止材17によって封止して、半導体装置100を得る(図11を参照)。
表面に回路を形成した半導体ウェハ1の回路面S1側にはく離可能な粘着テープ4を積層する。粘着テープ4の積層は、予めフィルム状に成形されたフィルムをラミネートする方法により行なうことができる。
半導体ウェハ1の粘着テープ4とは反対側の面S2を研磨して、半導体ウェハ1を所定の厚さまで薄くする。研磨は、粘着テープ4によって半導体ウェハ1を研磨用の治具に固定した状態で、グラインド装置8を用いて行う。
接着シート50は、上述した本発明のフィルム状接着剤の製造方法において基材としてダイシングシートを用いることにより作製することができる。
続いて、半導体ウェハ1の回路面に貼り付けられた粘着テープ4をはく離する。例えば、活性光線(典型的には紫外線)を照射することによって粘着性が低下する粘着テープを使用し、粘着テープ4側から露光した後、これをはく離することができる。
ダイシングラインDに沿って半導体ウェハ1を接着剤層5とともに切断する。このダイシングにより、半導体ウェハ1が、それぞれの裏面に接着剤層5が設けられた複数の半導体チップ2に切り分けられる。ダイシングは、粘着テープ(ダイシングテープ)6によって全体をフレーム(ウェハリング)10に固定した状態でダイシングブレード11を用いて行われる。
ダイシングの後、切り分けられた半導体チップ2を、ダイボンド装置12によって接着剤層5とともにピックアップし、すなわち接着剤層付き半導体素子をピックアップし、半導体装置用の支持部材(半導体素子搭載用支持部材)7または他の半導体チップ2に圧着(マウント)する。圧着は加熱しながら行なうことが好ましい。加熱温度は、通常、20~250℃、荷重は、通常、0.01~20kgf、加熱時間は、通常、0.1~300秒間である。
工程6の後、それぞれの半導体チップ2はそのボンディングパッドに接続されたワイヤ16を介して支持部材7上の外部接続端子と接続される。
半導体チップ2を含む積層体を封止材17によって封止することにより、半導体装置100が得られる。このときの封止材として、本発明のフィルム状接着剤を用いてもよい。具体的には、積層体に本発明のフィルム状接着剤をラミネートし、加熱硬化することによって、封止することができる。また、一括封止後にダイシングを行ない、パッケージを個片化することもできる。
(P-1)
四つ口フラスコに、ジメチルホルムアミドを80g、及びN-アクリロイルオキシエチルヘキサヒドロフタルイミドを20g秤取り、これらをかく拌した後、2,2’-アゾビスイソブチロニトリル0.6gを加えて溶解させた。その後、60℃で3時間保持した後、1時間90℃に保ち、自然冷却して、アクリル重合体の溶液を得た。続いて、メタノール/THF系で3回再沈殿を行い、アクリル重合体の白色固体(P-1)を得た。このアクリル重合体(P-1)のGPC測定を行ったところ、ポリスチレン換算で重量平均分子量(Mw)=40000であった。また、(P-1)のTgは70℃であった。
撹拌機、温度計及び窒素置換装置(窒素流入管)を備えた300mLフラスコ内に、ジアミンである5,5’-メチレンビス(アントラニル酸)(分子量286.3)(以下「MBAA」と略す。)5.72g(0.02mol)、ポリオキシプロピレンジアミン(商品名「D-400」(分子量:452.4)、BASF製)13.57g(0.03mol)、及び1,1,3,3-テトラメチル-1,3-ビス(3-アミノプロピル)ジシロキサン(商品名「BY16-871EG」、東レ・ダウコーニング(株)製)2.48g(0.01mol)、溶媒であるNMP(N-メチル-2-ピロリドン)115gを仕込み、撹拌してジアミンを溶媒に溶解させた。
上記で得られた熱可塑性樹脂(P-1)及び(P-2)を用いて、下記表1~3に示す組成比(単位:質量部)にて各成分を配合し、実施例1~13の接着剤組成物及び比較例1~2の接着剤組成物(接着剤層形成用ワニス)を得た。
M-140:東亜合成社製、N-アクリロイルオキシエチルヘキサヒドロフタルイミド(5%重量減少温度:200℃、25℃での粘度:450mPa・s)。
702A:新中村化学工業社製、2-ヒドロキシ-3-フェノキシプロピルアクリレート(5%重量減少温度:175℃、25℃での粘度:160mPa・s)
A-BPE4:新中村化学工業社製、エトキシ化ビスフェノールA型アクリレート(5%重量減少温度:330℃、25℃での粘度:950mPa・s)。
I-651:チバ・ジャパン社製、2,2-ジメトキシ-1,2-ジフェニルエタン-1-オン(5%重量減少温度:170℃、i線吸光係数:400ml/g・cm)。
I-379EG:チバ・ジャパン社製、2-ジメチルアミノ-2-(4-メチルーベンジル)-1-(4-モルフォリン-4-イルーフェニル)-ブタン-1-オン(5%重量減少温度:260℃、365nmでの分子吸光係数:8000ml/g・cm)。
I-907:チバ・ジャパン社製、2-メチル-1-(4-(メチルチオ)フェニル)-2-モルフォリノプロパン-1―オン(5%重量減少温度:220℃、365nmでの分子吸光係数:450ml/g・cm)。
I-OXE02:チバ・ジャパン社製、エタノン,1-[9-エチル-6-(2-メチルベンゾイル)-9H-カルバゾール-3-イル]-,1-(o-アセチルオキシム)、(5%重量減少温度:370℃、365nmでの分子吸光係数:7700ml/g・cm)。
YDF-8170C:東都化成社製、ビスフェノールF型ビスグリシジルエーテル(5%重量減少温度:270℃、25℃での粘度:1300mPa・s)。
1032H60:ジャパンエポキシレジン社製、トリス(ヒドロキシフェニル)メタン型固形エポキシ樹脂(5%重量減少温度:350℃、固形、融点60℃)。
MEH-8000H:明和化成社製、変性液状フェノールノボラック樹脂(5%重量減少温度:220℃、粘度:2500mPa・s)。
2PHZ-PW:四国化成社製、2-フェニル-4,5-ジヒドロキシメチルイミダゾール(平均粒子径:約3μm)。
1B2PZ:四国化成社製、1-ベンジル-2-フェニルイミダゾール。
パークミルD:日油社製、ジクミルパーオキサイド(1分間半減期温度:175℃)。
NMP:関東化学社製、N-メチル-2-ピロリドン。
東京計器製造所製のEHD型回転粘度計を用い、25℃における粘度を測定した。
接着剤組成物をポリエチレンテレフタレート(PET)フィルム上に、アプリケーターを用いて所定の膜厚となるように塗布した。得られた塗膜に離型処理したPETフィルムをハンドローラーを用いてラミネートした後、高精度平行露光機(オーク製作所製、「EXM-1172-B-∞」(商品名)、強度:10mW/cm2)により1000mJ/cm2で露光を行なった。得られた所定の膜厚の接着剤層をポリエチレンテレフタレート(PET)フィルムからはく離させ、単体で膜状の構造を得ることができたものをA、できなかったものをCと評価した。
表面粗さ測定器(小坂研究所製)を用いて接着剤層の厚みを測定した。
接着剤組成物をポリエチレンテレフタレート(PET)フィルム上に、アプリケーターを用いて所定の膜厚となるように塗布した。得られた塗膜に、離型処理したPETフィルムをハンドローラーを用いてラミネートした後、高精度平行露光機(オーク製作所製、「EXM-1172-B-∞」(商品名)、強度:10mW/cm2)により1000mJ/cm2で露光を行なった。その後、30℃での表面のタック強度をレスカ社製のプローブタッキング試験機を用いて、プローブ直径:5.1mm、引き剥がし速度:10mm/s、接触荷重:100gf/cm2、接触時間:1sにより、30℃におけるタック力を5回測定し、その平均値を算出した。
接着剤組成物をポリエチレンテレフタレート(PET)フィルム上に、アプリケーターを用いて所定の膜厚となるように塗布した。得られた塗膜に、室温空気下で、高精度平行露光機(オーク製作所製、「EXM-1172-B-∞」(商品名)、強度:10mW/cm2)により1000mJ/cm2で露光を行なった。その後、30℃での表面のタック強度をレスカ社製のプローブタッキング試験機を用いて、プローブ直径:5.1mm、引き剥がし速度:10mm/s、接触荷重:100gf/cm2、接触時間:1sにより、30℃におけるタック力を5回測定し、その平均値を算出した。
接着剤組成物をポリエチレンテレフタレート(PET)フィルム上に、アプリケーターを用いて膜厚30μmとなるように塗布した。得られた塗膜に、実施例1~2及び4~14は室温空気下で、また実施例3は離型処理したPETフィルムをラミネートした後、室温空気下で、高精度平行露光機(オーク製作所製、「EXM-1172-B-∞」(商品名)、強度:10mW/cm2)によりそれぞれ100、200、500、1000mJ/cm2の露光を行った。これら所定量の露光を行なった後、上記方法で測定した30℃での表面タック力が200gf/cm2以下となる露光量をフィルム化最低所要光量(mJ/cm2)とした。また、そのときの所要時間をフィルム化最短所要時間(s)とした。
ここでの溶融粘度は以下のように測定した値である。接着剤組成物をPETフィルム上に膜厚50μmとなるように塗布した。得られた塗膜に、実施例1~2及び4~14は室温空気下で、また実施例3は離型処理したPETフィルムをラミネートした後、室温空気下で、高精度平行露光機(オーク製作所製、「EXM-1172-B-∞」(商品名))により1000mJ/cm2で露光を行った。得られた接着シートをテフロンシート上に、接着剤層をテフロンシート側にしてロール(温度60℃、線圧4kgf/cm、送り速度0.5m/分)で加圧することによって厚みが約200μmとなるように積層した。得られたサンプルを粘弾性測定装置(レオメトリックス・サイエンティフィック・エフ・イー株式会社製、商品名:ARES)を用いて測定した。測定プレートは直径25mmの平行プレート、測定条件は昇温10℃/min、周波数1Hzに設定した。20℃~200℃での溶融粘度の最低値を溶融粘度とした。
支持台上にシリコンウェハ(6インチ径、厚さ400μm)を載せ、その上に、上記の<光照射によるフィルム形成性>と同様の手法で作製した接着剤層を、接着剤層がシリコンウェハの裏面(支持台と反対側の面)と接するように、ロール加圧(温度80℃、線圧4kgf/cm、送り速度0.5m/分)により積層した。基材(PETフィルム)を剥離除去した後、露出した接着剤層上に、厚み80μm、幅10mm、長さ40mmのポリイミドフィルム(宇部興産社製、「ユーピレックス」(商品名))を、上記と同様の条件でロール加圧して積層した。このようにして、シリコンウェハ、接着剤層及びポリイミドフィルムからなり、これらがこの順に積層する積層体のサンプルを得た。
支持台上にシリコンウェハ(6インチ径、厚さ400μm)を載せ、その上に、上記の<光照射によるフィルム形成性>と同様の手法で作製した接着剤層を、接着剤層がシリコンウェハの裏面(支持台と反対側の面)と接するように、ロール加圧(温度80℃、線圧4kgf/cm、送り速度0.5m/分)により積層した。基材(PETフィルム)を剥離除去した後、3×3mm角にシリコンウェハを切り出した。切り出した接着剤付きシリコンチップを予め5×5mm角に切り出したシリコンチップ上に載せ、200gfで加圧しながら、120℃で2秒間加熱圧着した。得られたサンプルをせん断接着力試験機「Dage-4000」(商品名)(測定条件、速度:50μm/sec、高さ:50μm)を用いて室温での接着力を測定し、1MPa以上であったものをA、1MPa未満であったものをCとして、熱圧着性の評価を行った。
接着剤組成物をポリエチレンテレフタレート(PET)フィルム上に、アプリケーターを用いて所定の膜厚となるように塗布した。得られた塗膜に離型処理したPETフィルムをラミネートした後、高精度平行露光機(オーク製作所製、「EXM-1172-B-∞」(商品名)、強度:10mW/cm2)により1000mJ/cm2で露光を行なった。その後、得られたフィルム状接着剤を示差熱熱重量同時測定装置(エスアイアイ・ナノテクノロジー社製、商品名「TG/DTA6300」)を用いて、昇温速度10℃/min、窒素フロー(400ml/分)下で5%重量減少温度を測定した。
支持台上にシリコンウェハ(6インチ径、厚さ400μm)を載せ、その上に、上記の<光照射によるフィルム形成性>と同様の手法で作製した接着剤層を、接着剤層がシリコンウェハの裏面(支持台と反対側の面)と接するように、ロール加圧(温度80℃、線圧4kgf/cm、送り速度0.5m/分)により積層した。基材(PETフィルム)を剥離除去した後、3×3mm角にシリコンウェハを切り出した。切り出した接着剤付きシリコンチップを予め5×5mm角に切り出したシリコンチップ上に載せ、200gfで加圧しながら、120℃で2秒間加熱圧着した。得られたサンプルをせん断接着力試験機「Dage-4000」(商品名)(測定条件、速度:50μm/sec、高さ:50μm)を用いて260℃での接着力を測定した。これを260℃接着強度の値とした。
Claims (13)
- 基材上に、(A)放射線重合性化合物、(B)光開始剤、及び(C)熱硬化性樹脂を含み、溶剤の含有量が5質量%以下であり且つ25℃で液状である接着剤組成物を塗布して接着剤組成物層を形成し、当該接着剤組成物層に光照射してフィルム状接着剤を形成することを特徴とするフィルム状接着剤の製造方法。
- 前記(A)成分が25℃で液状であることを特徴とする請求項1に記載のフィルム状接着剤の製造方法。
- 前記(A)成分が、25℃で液状の単官能(メタ)アクリレートを含むことを特徴とする請求項1又は2に記載のフィルム状接着剤の製造方法。
- 前記単官能(メタ)アクリレートがイミド骨格又は水酸基を有するものであることを特徴とする請求項3に記載のフィルム状接着剤の製造方法。
- 前記(B)成分が、波長365nmの光に対する分子吸光係数が100ml/g・cm以上の光開始剤を含むことを特徴とする請求項1~4のいずれか一項に記載のフィルム状接着剤の製造方法。
- 波長365nmの光に対する分子吸光係数が100ml/g・cm以上の前記光開始剤が、分子内にオキシムエステル骨格又はモルホリン骨格を有する化合物であることを特徴とする請求項5に記載のフィルム状接着剤の製造方法。
- 前記接着剤組成物が(D)硬化剤を更に含有することを特徴とする請求項1~6のいずれか一項に記載のフィルム状接着剤の製造方法。
- 前記接着剤組成物が(E)熱ラジカル発生剤を更に含有することを特徴とする請求項1~7のいずれか一項に記載のフィルム状接着剤の製造方法。
- ダイシングシートと、請求項1~8のいずれか一項に記載の方法により得られたフィルム状接着剤と、が積層した構造を有することを特徴とする接着シート。
- 前記ダイシングシートが、基材フィルムと、該基材フィルム上に設けられた放射線硬化型粘着剤層と、を有するものであり、
前記フィルム状接着剤が、前記放射線硬化型粘着剤層と積層した構造を有することを特徴とする請求項9に記載の接着シート。 - 前記ダイシングシートが、基材フィルムのみからなるものであることを特徴とする請求項9に記載の接着シート。
- 半導体素子同士及び/又は半導体素子と半導体素子搭載用支持部材とが請求項1~8のいずれか一項に記載の方法により得られたフィルム状接着剤により接着された構造を有する、半導体装置。
- 半導体ウェハの一方面上に、請求項9~11のいずれか一項に記載の接着シートの前記フィルム状接着剤層を貼り付ける工程と、
前記フィルム状接着剤層とともに前記半導体ウェハを切断して接着剤層付き半導体素子を得る工程と、
前記接着剤層付き半導体素子と、他の半導体素子又は半導体素子搭載用支持部材とを、前記接着剤層付き半導体素子の接着剤層を挟んで圧着することにより接着する工程と、
を備える、半導体装置の製造方法。
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013001847A (ja) * | 2011-06-17 | 2013-01-07 | Hitachi Chemical Co Ltd | 半導体用積層シート、接着剤層付き半導体チップの製造方法及び半導体装置の製造方法 |
JP2013160899A (ja) * | 2012-02-03 | 2013-08-19 | Hitachi Chemical Co Ltd | 感光性樹脂組成物、フィルム状接着剤、接着シート、接着剤パターン、接着剤層付半導体ウェハ、及び半導体装置 |
JP2013231097A (ja) * | 2012-04-27 | 2013-11-14 | Hitachi Chemical Co Ltd | 回路接続材料、フィルム状回路接続材料、回路接続シート、回路接続体及び回路部材の接続方法 |
JP2013245272A (ja) * | 2012-05-25 | 2013-12-09 | Nof Corp | コロイド結晶用組成物、及び、これより得られるコロイド結晶硬化膜とその製造方法 |
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Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102842512A (zh) * | 2011-06-22 | 2012-12-26 | 日东电工株式会社 | 半导体装置的制造方法 |
KR101355856B1 (ko) * | 2011-12-26 | 2014-01-27 | 제일모직주식회사 | 이방 전도성 접착 필름용 조성물 및 이를 이용한 이방 전도성 접착 필름 |
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KR102313687B1 (ko) | 2017-10-02 | 2021-10-18 | 린텍 가부시키가이샤 | 소성 재료 조성물, 필름상 소성 재료의 제조방법, 및 지지 시트를 가지는 필름상 소성 재료의 제조방법 |
JP6839114B2 (ja) * | 2018-02-05 | 2021-03-03 | 信越化学工業株式会社 | 半導体封止用熱硬化性エポキシ樹脂シート、半導体装置、及びその製造方法 |
US11049805B2 (en) | 2018-06-29 | 2021-06-29 | Taiwan Semiconductor Manufacturing Company, Ltd. | Semiconductor package and method |
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WO2020137934A1 (ja) * | 2018-12-28 | 2020-07-02 | リンテック株式会社 | フィルム状接着剤、積層シート、複合シート、及び積層体の製造方法 |
KR102583389B1 (ko) * | 2020-05-19 | 2023-09-26 | 삼성에스디아이 주식회사 | 반도체 소자 밀봉 필름용 에폭시 수지 조성물, 반도체 소자 밀봉용 필름 및 이를 이용하여 밀봉된 반도체 장치 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007004569A1 (ja) * | 2005-07-05 | 2007-01-11 | Hitachi Chemical Company, Ltd. | 感光性接着剤組成物、並びにこれを用いて得られる接着フィルム、接着シート、接着剤層付半導体ウェハ、半導体装置及び電子部品 |
JP2009239190A (ja) * | 2008-03-28 | 2009-10-15 | Sekisui Chem Co Ltd | ダイシング・ダイボンディングテープ |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101119783B1 (ko) * | 2002-12-28 | 2012-03-23 | 제이에스알 가부시끼가이샤 | 감방사선성 수지 조성물 |
JP2007308694A (ja) * | 2006-04-18 | 2007-11-29 | Hitachi Chem Co Ltd | 半導体用接着部材、半導体装置及び半導体装置の製造方法 |
JP5524465B2 (ja) * | 2007-10-24 | 2014-06-18 | 日立化成株式会社 | 接着シート及びこれを用いた半導体装置およびその製造方法 |
US8258017B2 (en) * | 2007-12-04 | 2012-09-04 | Hitachi Chemical Company, Ltd. | Photosensitive adhesive |
US20110121435A1 (en) * | 2008-01-16 | 2011-05-26 | Kazuyuki Mitsukura | Photosensitive adhesive composition, filmy adhesive, adhesive sheet, adhesive pattern, semiconductor wafer with adhesive layer, semiconductor device, and process for producing semiconductor device |
-
2010
- 2010-11-10 JP JP2011540524A patent/JP5505421B2/ja active Active
- 2010-11-10 US US13/509,370 patent/US20120248634A1/en not_active Abandoned
- 2010-11-10 CN CN2010800503759A patent/CN102687256A/zh active Pending
- 2010-11-10 WO PCT/JP2010/070019 patent/WO2011058999A1/ja active Application Filing
- 2010-11-11 TW TW099138868A patent/TW201129667A/zh unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007004569A1 (ja) * | 2005-07-05 | 2007-01-11 | Hitachi Chemical Company, Ltd. | 感光性接着剤組成物、並びにこれを用いて得られる接着フィルム、接着シート、接着剤層付半導体ウェハ、半導体装置及び電子部品 |
JP2009239190A (ja) * | 2008-03-28 | 2009-10-15 | Sekisui Chem Co Ltd | ダイシング・ダイボンディングテープ |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013001847A (ja) * | 2011-06-17 | 2013-01-07 | Hitachi Chemical Co Ltd | 半導体用積層シート、接着剤層付き半導体チップの製造方法及び半導体装置の製造方法 |
JP2013160899A (ja) * | 2012-02-03 | 2013-08-19 | Hitachi Chemical Co Ltd | 感光性樹脂組成物、フィルム状接着剤、接着シート、接着剤パターン、接着剤層付半導体ウェハ、及び半導体装置 |
JP2013231097A (ja) * | 2012-04-27 | 2013-11-14 | Hitachi Chemical Co Ltd | 回路接続材料、フィルム状回路接続材料、回路接続シート、回路接続体及び回路部材の接続方法 |
JP2013245272A (ja) * | 2012-05-25 | 2013-12-09 | Nof Corp | コロイド結晶用組成物、及び、これより得られるコロイド結晶硬化膜とその製造方法 |
US10428253B2 (en) | 2013-07-16 | 2019-10-01 | Hitachi Chemical Company, Ltd | Photosensitive resin composition, film adhesive, adhesive sheet, adhesive pattern, semiconductor wafer with adhesive layer, and semiconductor device |
JP2019189875A (ja) * | 2013-11-19 | 2019-10-31 | 日東電工株式会社 | 樹脂シート |
JP7082592B2 (ja) | 2013-11-19 | 2022-06-08 | 日東電工株式会社 | 樹脂シート |
JP2021101027A (ja) * | 2014-08-27 | 2021-07-08 | 積水化学工業株式会社 | 樹脂組成物 |
JP7130082B2 (ja) | 2014-08-27 | 2022-09-02 | 積水化学工業株式会社 | 樹脂組成物 |
WO2019044798A1 (ja) * | 2017-08-28 | 2019-03-07 | 日立化成株式会社 | パワー半導体装置を製造する方法、熱プレス用シート及び熱プレス用熱硬化性樹脂組成物 |
JPWO2019044798A1 (ja) * | 2017-08-28 | 2020-09-24 | 日立化成株式会社 | パワー半導体装置を製造する方法、熱プレス用シート及び熱プレス用熱硬化性樹脂組成物 |
JP7176523B2 (ja) | 2017-08-28 | 2022-11-22 | 昭和電工マテリアルズ株式会社 | パワー半導体装置を製造する方法、熱プレス用シート及び熱プレス用熱硬化性樹脂組成物 |
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