WO2011057911A3 - Rohrbündelreaktor zur herstellung von maleinsäureanhydrid - Google Patents

Rohrbündelreaktor zur herstellung von maleinsäureanhydrid Download PDF

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Publication number
WO2011057911A3
WO2011057911A3 PCT/EP2010/066597 EP2010066597W WO2011057911A3 WO 2011057911 A3 WO2011057911 A3 WO 2011057911A3 EP 2010066597 W EP2010066597 W EP 2010066597W WO 2011057911 A3 WO2011057911 A3 WO 2011057911A3
Authority
WO
WIPO (PCT)
Prior art keywords
reaction
heat
maleic acid
acid anhydride
reactor
Prior art date
Application number
PCT/EP2010/066597
Other languages
English (en)
French (fr)
Other versions
WO2011057911A2 (de
Inventor
Gerhard Olbert
Hans-Jürgen BASSLER
Michael Steiniger
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Priority to EP10771481A priority Critical patent/EP2498904A2/de
Priority to RU2012123724/04A priority patent/RU2566749C2/ru
Priority to CN2010800506121A priority patent/CN102639224A/zh
Publication of WO2011057911A2 publication Critical patent/WO2011057911A2/de
Publication of WO2011057911A3 publication Critical patent/WO2011057911A3/de

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0277—Metal based
    • B01J2219/0286—Steel

Abstract

Vorgeschlagen wird eine Anlage zur Herstellung von Maleinsäureanhydrid durch heterogenkatalysierte Gasphasenoxidation eines Einsatzstromes, enthaltend Kohlenwasserstoffe mit mindestens (4) Kohlenstoffatomen pro Moleküll, umfassend einen Reaktor mit einem Bündel von Reaktionsrohren, in die ein Feststoffkatalysator eingebracht ist, an dem die exotherme Umsetzung des Einsatzstromes mit einem Sauerstoff enthaltenden Gasstrom stattfindet, sowie eine oder mehrere Pumpen und eine oder mehrere ausserhalb des Reaktors liegende Wärmetauscher, über die ein Wärmeträger, gebildet aus einer Salzschmelze, geleitet wird, die den Reaktorzwischenraum zwischen den Reaktionsrohren durchströmt und die Reaktionswärme aufnimmt, wobei die Temperatur der Salzschmelze im Bereich zwischen 350 und 480 °C liegt, die dadurch gekennzeichnet ist, dass die Reaktionsrohre aus einem legierten warmfesten Stahl gefertigt sind, der entweder mindestens 0,5 Gew.-% Chrom oder mindestens 0,25 Gew.-% Molybdän oder mindestens 0,5 Gew.-% Chrom und mindestens 0,25 Gew.-% Molybdänenthält.
PCT/EP2010/066597 2009-11-10 2010-11-02 Rohrbündelreaktor zur herstellung von maleinsäureanhydrid WO2011057911A2 (de)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP10771481A EP2498904A2 (de) 2009-11-10 2010-11-02 Rohrbündelreaktor zur herstellung von maleinsäureanhydrid
RU2012123724/04A RU2566749C2 (ru) 2009-11-10 2010-11-02 Кожухотрубный реактор для получения ангидрида малеиновой кислоты
CN2010800506121A CN102639224A (zh) 2009-11-10 2010-11-02 用于生产马来酸酐的管壳式反应器

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09175466.3 2009-11-10
EP09175466 2009-11-10

Publications (2)

Publication Number Publication Date
WO2011057911A2 WO2011057911A2 (de) 2011-05-19
WO2011057911A3 true WO2011057911A3 (de) 2011-07-14

Family

ID=43859643

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/066597 WO2011057911A2 (de) 2009-11-10 2010-11-02 Rohrbündelreaktor zur herstellung von maleinsäureanhydrid

Country Status (6)

Country Link
US (1) US9522374B2 (de)
EP (1) EP2498904A2 (de)
CN (1) CN102639224A (de)
RU (1) RU2566749C2 (de)
TW (1) TW201132410A (de)
WO (1) WO2011057911A2 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2566749C2 (ru) 2009-11-10 2015-10-27 Басф Се Кожухотрубный реактор для получения ангидрида малеиновой кислоты
CN109012509A (zh) * 2018-09-29 2018-12-18 宁波浙铁江宁化工有限公司 顺酐制备反应器中的熔盐循环结构
WO2020121171A1 (en) 2018-12-12 2020-06-18 Sabic Global Technologies B.V. Dimerization of cyclopentadiene using shell & tube heat exchanger

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5095125A (en) * 1989-01-17 1992-03-10 Amoco Corporation Maleic anhydride production
DE10011309A1 (de) * 2000-03-10 2001-09-13 Basf Ag Verfahren zur Herstellung von Maleinsäreanhydrid
US20060004226A1 (en) * 2004-07-01 2006-01-05 Basf Aktiengesellschaft Preparation of acrolein or acrylic acid or a mixture thereof from propane
WO2008000740A1 (de) * 2006-06-27 2008-01-03 Basf Se Reaktor aus aufplattiertem rostfreiem stahl für die kontinuierliche heterogene katalysierte partielle dehydrierung wenigstens eines zu dehydrierenden kohlenwasserstoffs und verfahren
DE102007025869A1 (de) * 2007-06-01 2008-07-03 Basf Se Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett
DE102007035046A1 (de) * 2007-07-19 2009-01-22 Ceramic Oxides International B.V. Kontinuierlich betriebenes Rohrreaktorsystem

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PL103416B1 (pl) * 1976-04-30 1979-06-30 Sposob wytwarzania bezwodnikow kwasowych na drodze czesciowego utleniania weglowodorow aromatycznych
US4317778A (en) 1980-12-29 1982-03-02 Standard Oil Company (Sohio) Preparation of maleic anhydride using fluidized catalysts
US4933312A (en) 1989-01-17 1990-06-12 Amoco Corporation Maleic anhydride catalysts and process for their manufacture
US5137860A (en) 1991-06-27 1992-08-11 Monsanto Company Process for the transformation of vanadium/phosphorus mixed oxide catalyst precursors into active catalysts for the production of maleic anhydride
US5275996A (en) 1992-05-22 1994-01-04 Monsanto Company Phosphorous/vanadium oxide catalyst and process of preparation thereof
US5641722A (en) 1994-09-15 1997-06-24 Huntsman Petrochemical Corporation High performance VPO catalyst and process of preparation thereof
JP4149155B2 (ja) * 2001-09-28 2008-09-10 富士フイルム株式会社 撮影支援システム及び撮影支援サーバ
DE10334582A1 (de) * 2003-07-28 2005-02-24 Basf Ag Verfahren zur Herstellung von Maleinsäureanhydrid
US7439389B2 (en) * 2005-03-01 2008-10-21 Basf Aktiengesellschaft Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation
DE102006005208A1 (de) * 2006-02-02 2007-08-16 Hitachi Power Europe Gmbh Hängender Dampferzeuger
DE102006034811A1 (de) * 2006-07-27 2008-01-31 Man Dwe Gmbh Verfahren zur Temperaturänderung eines Rohrbündelreaktors
DE102008040896A1 (de) * 2008-07-31 2010-02-04 Evonik Degussa Gmbh Verwendung von keramischen oder keramikhaltigen Schneid- oder Stanzwerkzeugen als Schneiden oder Stanzen für keramikhaltige Verbundstoffe
RU2566749C2 (ru) 2009-11-10 2015-10-27 Басф Се Кожухотрубный реактор для получения ангидрида малеиновой кислоты

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5095125A (en) * 1989-01-17 1992-03-10 Amoco Corporation Maleic anhydride production
DE10011309A1 (de) * 2000-03-10 2001-09-13 Basf Ag Verfahren zur Herstellung von Maleinsäreanhydrid
US20060004226A1 (en) * 2004-07-01 2006-01-05 Basf Aktiengesellschaft Preparation of acrolein or acrylic acid or a mixture thereof from propane
WO2008000740A1 (de) * 2006-06-27 2008-01-03 Basf Se Reaktor aus aufplattiertem rostfreiem stahl für die kontinuierliche heterogene katalysierte partielle dehydrierung wenigstens eines zu dehydrierenden kohlenwasserstoffs und verfahren
DE102007025869A1 (de) * 2007-06-01 2008-07-03 Basf Se Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett
DE102007035046A1 (de) * 2007-07-19 2009-01-22 Ceramic Oxides International B.V. Kontinuierlich betriebenes Rohrreaktorsystem

Non-Patent Citations (4)

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Title
QUICK METALL: "Wekstoffdatenblatt 1.4541", XP002636715, Retrieved from the Internet <URL:http://www.quickmet.de/Werkstoffdatenblatt-1.4541.aspx> [retrieved on 20110512] *
QUICK METALL: "Wekstoffdatenblatt 1.4571", XP002636716, Retrieved from the Internet <URL:http://www.quickmet.de/Werkstoffdatenblatt-1.4571.aspx> [retrieved on 20110512] *
SALZGITTER FLACHSTAHL: "Heat-resistant pressure-vessel steels (Technical Datasheet)", XP002636714, Retrieved from the Internet <URL:http://www.salzgitter-flachstahl.de/en/Produkte/warmgewalzte_produkte/stahlsorten/Warmfeste_Druckbehaelterstaehle/druck?> [retrieved on 20110512] *
See also references of EP2498904A2 *

Also Published As

Publication number Publication date
US9522374B2 (en) 2016-12-20
RU2012123724A (ru) 2013-12-20
EP2498904A2 (de) 2012-09-19
WO2011057911A2 (de) 2011-05-19
CN102639224A (zh) 2012-08-15
US20110110830A1 (en) 2011-05-12
TW201132410A (en) 2011-10-01
RU2566749C2 (ru) 2015-10-27

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