WO2010148970A1 - Polished glaze tiles transmutated in furnace and production method thereof - Google Patents

Polished glaze tiles transmutated in furnace and production method thereof Download PDF

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Publication number
WO2010148970A1
WO2010148970A1 PCT/CN2010/073897 CN2010073897W WO2010148970A1 WO 2010148970 A1 WO2010148970 A1 WO 2010148970A1 CN 2010073897 W CN2010073897 W CN 2010073897W WO 2010148970 A1 WO2010148970 A1 WO 2010148970A1
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WO
WIPO (PCT)
Prior art keywords
requirement
glaze
furnace
layer
transmutated
Prior art date
Application number
PCT/CN2010/073897
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French (fr)
Chinese (zh)
Inventor
陈满坚
黑格比•唐纳德•温
Original Assignee
Chen Manjian
Higby Donald Wayne
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Publication date
Priority claimed from CNA200910040456XA external-priority patent/CN101591962A/en
Application filed by Chen Manjian, Higby Donald Wayne filed Critical Chen Manjian
Publication of WO2010148970A1 publication Critical patent/WO2010148970A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/32—Burning methods
    • C04B33/34—Burning methods combined with glazing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567—Treatment time

Definitions

  • the matching of ceramic products is very good with ceramics, the ground can be used for homes or large, or for small ones or for. Different fits require different styles.
  • the method of the embossed birth method utilizes the melting of the high temperature melt and the formation of a relief part in the embossed portion that has an approximate combination of the embossed portion has a special natural rest.
  • the method of making stone ceramics for wrapping wood is the method of making stone ceramics that are wrapped in wood .
  • the method of making color , or the like is to the surface of the glass .
  • a package having a certain thickness is formed on the surface, and the package is applied to the ceramic according to a pre-prepared scheme, and then the water is applied to the ceramic to be fixed on the ceramic, fired, and the like to form a natural stone effect.
  • This book is to provide a partial blank of wood and a color with a natural blend of fine colors and methods.
  • the purpose of the above-mentioned wood scheme is to include the following steps.
  • It can be printed or other methods. It can be printed, or otherwise.
  • step A will be good in the formation of the concave part of the surface.
  • the step of forming a depression is good.
  • the first surface is printed on the surface.
  • the method can be applied to the second step in the recessed part of the second step.
  • the magical approach to the method is to include gold on the surface.
  • the temperature at which the heat was burned was 750 105 C and the same as 60 90 .
  • Transparent or opaque 80 200 was 750 105 C and the same as 60 90 .
  • the surface produced by this method is at a high temperature
  • the shape and color of the formation depends not only on the printed surface
  • 2 is a finished product of 1 .
  • Each is a semi-finished/finished product of each step.
  • each is the semi-finished/finished product of each step.
  • 10 is the finished product of 6 .
  • 11 is the finished product of 7 .
  • 80 200 s consists of glass
  • a 40 60 thickness is controlled at 0.3 5.
  • the firing temperature is 850 105 C and the same as 60 90 .
  • the formation of the firing is fixed on the surface.
  • the firing temperature is 950 105 C and the same as 60 90 .
  • the high temperature of the sheep is melted. This is the "ceramic sheep" of each of the Nannan sheep, the Nanjing chemical sheep, and the material sheep and copper. Because of the god and the different thickness of the printed There are also differences that form a color that creates a natural blending effect of the same color.
  • the reverse semi-finished surface is her. Because of the difference, the opposite is different, so the color is different. She also agrees with the color of the surface. The requirements of her still can control the color of the surface of the finished product.
  • the finished product is finally obtained.
  • the surface of the finished product is smooth and the color is naturally high.
  • the surface effect shown in Fig. 12a is red. 2 of the finished product 1 of the top 2 of the top 3 2
  • the recipe can be the same as or different from 1.
  • the Chinese sheep are expressed as follows
  • the firing temperature is 950 105 C and the same as 60 90 .
  • the formation of the firing is fixed on the surface 2 .
  • 3 Good A is printed on the upper surface, and the second part is burnt to form a reverse formed 3 as shown by 4c
  • the firing temperature is 950 105 C and the same as 60 90 .
  • the good step is to print the concave surface formed by the other step.
  • the third formation 4 is as shown in 4, and the depth of the depression is determined by the thickness.
  • the firing temperature is 750 950C and the same as 60 90. This firing temperature is slightly lower than the temperature of the previous firing.
  • the surface of the semi-finished product is fired.
  • the requirement is to control the depth and control the effect of the color of the finished surface.
  • the formula can be the same or different from 1 or.
  • the composition of its chemical sheep is as follows: 0.1687 0.2001
  • the firing temperature is 950 105 C and the same as 60 90 .
  • the formation of the firing is fixed on the surface 2 .
  • the firing temperature is 950 105 C and the same as 60 90 .
  • gold such as gold
  • the surface of the semi-finished product includes a recessed portion as shown in 6.
  • the gold portion of the concave portion of the red surface of the surface 12 is obtained as shown in Fig. 6e. 15 4
  • the formula can be the same or different from 1, 2 or 2.
  • the composition of its sheep is as follows 0.1687 0.2001
  • the firing temperature is 950 105 C and the same as 60 90 .
  • the formation of the firing is fixed on the surface 2 .
  • 3 Good A is printed on the upper surface, and the second part is burned to form a reverse formed 3 as shown in 8c.
  • the firing temperature is 950 105 C and the same as 60 90 .
  • 4 Good A is printed on the concave surface formed by the step and the third is burned to form 4 as shown in 8
  • the depth of the depression is determined by the thickness
  • the firing temperature is 750 950C and the same as 60 90. This firing temperature is slightly lower than the temperature of the previous firing.
  • the surface of the semi-finished product includes a concave portion as shown in Fig. 8e.
  • the surface is the surface part of the semi-finished product and above.
  • the depth of the palm grip is to expose the surface and control the color.
  • the required part is maintained as shown in Fig. 8.
  • the surface effect of the 12e is shown in the red concave part of the gold on the gold above the sleeve. 5
  • the formula can be the same or different from the previous example.
  • the firing temperature is 950 105 C and the firing is the same as 60 90 .
  • the fixation formed by firing forms a surface 2 .
  • 3 Good A is printed on the upper surface and is in the recessed part, then the second is fired to form the reverse formed 3
  • the firing temperature is 950 105 C and the same as 60 90 .
  • the surface is the surface part of the semi-finished product. She obtains the color of the 5 in the recessed part due to or not the 1 is not. 6
  • the formula can be the same or different from the previous example.
  • the firing temperature is 950 105 C and the same as 60 90 .
  • the formation of the firing is fixed on the surface 2 .
  • the firing temperature is 950 105 C and the same as 60 90 .
  • the formula can be the same or different from the previous example.
  • the firing temperature is 950 105 C and the same as 60 90 .
  • the formation of the firing is fixed on the surface 2 .
  • the firing temperature is 950 105 C and the same as 60 90 .
  • the same or different can be used in the recess.
  • the firing temperature is 750 950C and the same as 60 90.
  • the temperature of this firing is slightly lower than the temperature of the previous firing.

Abstract

A production method for a polished glaze tile transmutated in the furnace comprises the following steps: (A) covering a green brick (1) with frit powder and sintering them to form a frit layer (2); (B) glazing the sintered frit layer (2) and sintering them, and during the sintering process the frit layer (2) is reacted with the glaze layer to be transmutated in the furnace so as to obtain unartificial and gradually changing patterns. The polished glaze tile produced by the method is provided, wherein the surface of the frit layer (2) is reacted with glaze material of the decorative glaze layer at a high temperature in a furnace to form a glaze layer (3) transmutated in the furnace. The shape and color of patterns not only depend on the glaze material printed but also are influenced by the consequence of the reaction between the frit layer (2) and the glaze material. The finished ceramic tile has excellent decorative effect. It is fuzzy in boarders of different color blocks, and unartificial in transition. And it has mature, elegant and gorgeous aesthetic feeling.

Description

及其 方法 木領域  And its method
本 涉及 陶瓷制品 尤其涉及 木領域。 背景 木  This relates to ceramics, especially in the wood sector. Background
陶瓷制品的 切合非常 以陶瓷 就可 于 、 地面 可用于家 居或亦 大 的 也可以用于小 的裝 或者是 。 不同的 切合 需要不同凡格的 。  The matching of ceramic products is very good with ceramics, the ground can be used for homes or large, or for small ones or for. Different fits require different styles.
公升 C 97043A 你 夜光印刷 及其印花夜光 的制作方法"的 中 吉利 公升 夜光印刷 及其印花夜光 的制作方法 其  Lisheng C 97043A "How to Produce Luminous Printing and Printing Luminous Lights", the production method of Zhongli Lisheng Luminous Printing and Printing Night Light
、 和夜光 燒成 得的 亮度高 余 同 可在 她 彩色 。  And the brightness of the night light is high, and the same color can be colored in her.
公升 C 281778A 你 浮雕 的生 方法"的中 吉利 公升 浮雕 的生 方法 方法利用 在高溫熔融 的熔解和 在 浮雕部分形成含有近似于 的 組合 未的 浮雕部分具有 特 的自然 休 。  Lit C 281778A The method of the embossed birth method "The method of the Chinese Geely liter relief method utilizes the melting of the high temperature melt and the formation of a relief part in the embossed portion that has an approximate combination of the embossed portion has a special natural rest.
公升 C 00387545C 你 于 包裹 木的 石材 陶瓷 的制造方法"的中 吉利公升 于 包裹 木的 石材 陶瓷 的制 造方法 是將顏色 、 或 等方式 至玻璃 表面 然  升 C C 00387545C " The method of making stone ceramics for wrapping wood " is the method of making stone ceramics that are wrapped in wood . The method of making color , or the like is to the surface of the glass .
在 表面形成一定具有厚度的包裹 而 將包裹 的 按照預先 好的方案 至陶瓷 上 再 施加 性水 使 顆粒 接固定在陶瓷 上 再 、 燒成、 等 形成具有天然石材外 效果的 。 A package having a certain thickness is formed on the surface, and the package is applied to the ceramic according to a pre-prepared scheme, and then the water is applied to the ceramic to be fixed on the ceramic, fired, and the like to form a natural stone effect.
再 公升 C 1644559 你 金 陶瓷制品及其制作工 "的 中 吉利公升 金 的制作工 其特 是 先將 的印花 的阿板印制在 上 再在 上印刷透明 然 燒成 而 她 。 所制得的 、 同界限分明、 休 。 在制作 中 和 料不友生化羊反 。 能使 史官有 休 但 本身 不 的組成部分 只是 到把 印制 的 固定在 上的作用。 及色彩 必須 透明的 。 上 可成功地制作出色 好、 休 、 各 突 出的陶瓷制品 滿足 方面的 需求。 但 的需求是多 化的 因而生 者需要不 及 新才能滿足、甚至 造出多 多 的 需求。 及 內容 The liters of C 1644559, your gold ceramics and its makers, the production of the Chinese Geely liters, is printed on the printed board and then printed on the top and printed on it. The same line of distinction, Hugh. In the production and materials are not friends with biochemical sheep. Can make the history officer have a break but not the part of itself is only to fix the role of printing. And the color must be transparent. Produce outstanding, rest, and outstanding ceramic products to meet the needs. However, the demand is multi-dimensional, so the living needs less than new to meet, and even create a lot of demand. And content
本 的目的在于 有 木的部分空白 提供 及色彩具有自然混合 顏色 細膩、 的 及其 方法。  The purpose of this book is to provide a partial blank of wood and a color with a natural blend of fine colors and methods.
到上 明目的 本 以下 木方案 的生 方法 其 特 在于依 包括以下步驟 The purpose of the above-mentioned wood scheme is to include the following steps.
A 在 上 形成  A is formed on
在所 燒成的 上 反 以 得 自然 。  It is natural to be burned.
其中 可以 印制或其它方法 于 上。 可 印制、 或其它方 法 于 上。  It can be printed or other methods. It can be printed, or otherwise.
以后 半成品 一步 她 。  After the semi-finished products step by step her.
休 未 步驟 A 是 好的阿 將 好的 在 面上形成 中的凹陷部分 然 第一 形成帶有凹陷的 步驟 是 好的阿 在所 的表面印刷第一 第二 。  Hugh no step A is good A will be good in the formation of the concave part of the surface. First, the step of forming a depression is good. The first surface is printed on the surface.
作力 神可 方案 上 方法 一步包括在第二 在所 中的凹陷部 分 另一 第三 。  The method can be applied to the second step in the recessed part of the second step.
作力 神可 方案 上 方法 一步包括在 的 表面 上金 。 作力 神可 方案 上 方法 包括在所 中的凹陷部分 第二  The magical approach to the method is to include gold on the surface. Working on the scheme, including the concave part in the second
在其上 透明 第三 。 On it is transparent third.
作力 神可 方案 上 方法 包括在所 中的凹陷部分  Work on the scheme, including the concave part in
之上 第二 第三 第二 反 。  Above the second third and second opposition.
。  .
休 未 中燒成的溫度 750 105 C 燒成 同 60 90 。 用 的 透明或不透明 80 200 。  The temperature at which the heat was burned was 750 105 C and the same as 60 90 . Transparent or opaque 80 200 .
本 提供 由上 方法所生 的 。  This is provided by the above method.
本 的方法制作出的 表面在 的高溫下 的  The surface produced by this method is at a high temperature
的形狀及色彩的形成不但取決于印制上去的 表面  The shape and color of the formation depends not only on the printed surface
的 而 。 反 的影 不同 之同的 模糊 自然 具有成熟、高 、 的 。 依 此方法所制作的陶瓷 效果好 可 則的 也可以 大型地 面/ 而 投出具有強烈 效果的士 。 本 具有 的 前景和良好 的 和 合效益。 1是 1的工 。And. The opposite of the opposite is naturally mature, high, of. The ceramics produced according to this method have a good effect, and can also cast a strong effect on a large ground. This has the prospect and good synergy. 1 is the work of 1.
2是 1的成品拮 。 2 is a finished product of 1 .
3是 2的工 。 3 is the work of 2.
4各 是 各步驟的半成品/成品拮 。 4 Each is a semi-finished/finished product of each step.
5是 3的工 。 5 is the work of 3.
6各 是 各步驟的半成品/成品拮 。 6 each is the semi-finished/finished product of each step.
7是 的工 。 7 is the work.
8各 是 各步驟的半成品/成品拮 。 8 are each semi-finished/finished product of each step.
9是 5的成品拮 。 9 is the finished product of 5.
10是 6的成品拮 。 10 is the finished product of 6 .
11是 7的成品拮 。 11 is the finished product of 7 .
12是各 中 的表面效果 。 休 方式 1所示 本 依 按照以下工 步驟 12 is the surface effect in each. According to the following steps:
1 表面她 1 her face
2 好的阿 將 好的 印制在 面上形成 然 第一 燒成  2 Good A will be printed on the surface, the first is burned
可 透明的 也可以 不透明的 其色彩 的需要而 。 的 80 200 士 成份由 玻璃 本 中 其  It can be transparent or opaque for its color needs. 80 200 s consists of glass
表示如下 0.1687 0.2001 Expressed as follows 0.1687 0.2001
0.1283 0.1521 a  0.1283 0.1521 a
0.2827 0.2519 CaO 0.6216 0.4162 A l 7.2464 5.0923  0.2827 0.2519 CaO 0.6216 0.4162 A l 7.2464 5.0923
0.0396 0.0354 gO 0.0103 0.0151 Fe l 1.6968 1.3456 0.0396 0.0354 gO 0.0103 0.0151 Fe l 1.6968 1.3456
Figure imgf000006_0001
Figure imgf000006_0001
0.1299 0.1079 aO 0.1299 0.1079 aO
Figure imgf000006_0002
Figure imgf000006_0002
阿的 40 60 厚度控制在0．3 5. mn  A 40 60 thickness is controlled at 0.3 5. mn
。  .
燒成的溫度 850 105 C 燒成 同 60 90 。 燒成 形成的 固定在 表面形成 。 The firing temperature is 850 105 C and the same as 60 90 . The formation of the firing is fixed on the surface.
3 好的阿 在上 表面印刷 好的 要求 的燒成 在 的熔融 內 然 第二 燒成  It is the second firing in the melting of the melting
。  .
燒成的溫度 950 105 C 燒成 同 60 90 。 在 內 在高溫下合熔 化 高溫化羊反 此 "。 于 反 生的各 可 南工羊 、 南京化工羊 、 材料 羊 合銅的 《陶瓷 羊》。 由于 的神 及不同 印制厚度的 故 的反 的 也存在差別 而形成顏色 的 使不同顏色之同形成一 自然的混合效果。 The firing temperature is 950 105 C and the same as 60 90 . In the inner high temperature, the high temperature of the sheep is melted. This is the "ceramic sheep" of each of the Nannan sheep, the Nanjing chemical sheep, and the material sheep and copper. Because of the god and the different thickness of the printed There are also differences that form a color that creates a natural blending effect of the same color.
4 表面  4 surface
上 步驟中 反 的半成品表面 她 。 由于 的 反 她 不同 反 的 也不同 因此顏色的 也不同。 她理的 也合 表面的顏色 。 的要求 尚的 她 深度就能控 制成品表面的顏色 。  In the upper step, the reverse semi-finished surface is her. Because of the difference, the opposite is different, so the color is different. She also agrees with the color of the surface. The requirements of her still can control the color of the surface of the finished product.
一步 最終得到成品。 成品 表面平滑、 顏色 自然 具有高 、 的凡 格。 的表面效果 12a所示 表面的 紅色 的 。 成品 的 2所示 1 于 上的 2 最上面的 的 3 2 In one step, the finished product is finally obtained. The surface of the finished product is smooth and the color is naturally high. The surface effect shown in Fig. 12a is red. 2 of the finished product 1 of the top 2 of the top 3 2
3所示的工 Work shown in 3
1 4a中的 1 表面她 1 4a in the face of her
2 好的阿 將 好的 印制在 面上形成 在 中 的凹陷部分則 然 第一 燒成 形成帶有凹陷22及 21的 2 如 4b 所示 2 A good A will be printed on the surface in the middle The recessed portion is then first fired to form 2 with recesses 22 and 21 as shown by 4b
的配方可以和 1相同也可以不同。 本 中 其化羊 表示如下  The recipe can be the same as or different from 1. The Chinese sheep are expressed as follows
A l 7.2463 5.0923 O A l 7.2463 5.0923 O
Fe2 3 1．6968 1.3456
Figure imgf000007_0001
Fe2 3 1.6968 1.3456
Figure imgf000007_0001
。  .
燒成的溫度 950 105 C 燒成 同 60 90 。 燒成 形成的 固定在 表面形成 2。 The firing temperature is 950 105 C and the same as 60 90 . The formation of the firing is fixed on the surface 2 .
3 好的阿 在上 表面印刷 好的 于凹陷的部位則 然 第二 燒成 形成 反 形成的 3 如 4c所示  3 Good A is printed on the upper surface, and the second part is burnt to form a reverse formed 3 as shown by 4c
。  .
燒成的溫度 950 105 C 燒成 同 60 90 。 The firing temperature is 950 105 C and the same as 60 90 .
4 好的阿 在上 步驟 形成的凹陷表面印刷另一 然 第三 形成 4 如 4 所示 凹陷的深度 由 的厚度決定  4 The good step is to print the concave surface formed by the other step. The third formation 4 is as shown in 4, and the depth of the depression is determined by the thickness.
。  .
燒成的溫度 750 950C 燒成 同 60 90 。 此 燒成的溫度比前 燒成的溫度 稍低。  The firing temperature is 750 950C and the same as 60 90. This firing temperature is slightly lower than the temperature of the previous firing.
的需要 可以 再 的 印刷及再 的燒成 以 得預期的裝 效果。 5 表面  The need can be printed and re-fired to achieve the desired effect. 5 surface
燒成 的半成品表面 她 。 的要求 控制 的深度 而控制成 品表面的顏色 以 到 的效果。  The surface of the semi-finished product is fired. The requirement is to control the depth and control the effect of the color of the finished surface.
得到如 4d所示 的 。 的表面效果 12b 2c所示 表面的 紅色  Obtained as shown in 4d. Surface effect 12b 2c surface red
的 凹陷部分的 或我中的白色部分力裝 。 3 The concave part or the white part of me is loaded. 3
5所示的工 Work shown in 5
1 6a中的 1 表面她 1 of 6a in her face
2 好的阿 將 好的 印制在 面上形成 在 中 的凹陷部分則 然 第一 燒成 形成帶有凹陷22及 21的 2 如 6b 所示 2 A good ah is printed on the concave portion formed on the surface, but the first firing forms 2 with the recesses 22 and 21, such as 6b. Shown
的配方可以和 1或 相同或不同。 本 中 其化羊組成 表示如下 0.1687 0.2001  The formula can be the same or different from 1 or. The composition of its chemical sheep is as follows: 0.1687 0.2001
0.1283 0.1521 a  0.1283 0.1521 a
0.2827 0.2519 CaO 0.6216 0.4162 A l 7.2463 5.0923 O  0.2827 0.2519 CaO 0.6216 0.4162 A l 7.2463 5.0923 O
0.0396 0.0354 gO 0.0103 0.0151 Fe l 1.6968 1.3456 BCb3
Figure imgf000008_0001
0.0396 0.0354 gO 0.0103 0.0151 Fe l 1.6968 1.3456 BCb3
Figure imgf000008_0001
0.1299 0.1079 aO 0.1299 0.1079 aO
Figure imgf000008_0002
Figure imgf000008_0002
。  .
燒成的溫度 950 105 C 燒成 同 60 90 。 燒成 形成的 固定在 表面形成 2。  The firing temperature is 950 105 C and the same as 60 90 . The formation of the firing is fixed on the surface 2 .
5 3 好的阿 在上 表面印刷 好的 于凹陷的部位則 然 第二 燒成 形成 反 形成的 3 如 6c所示  5 3 Good A. The upper surface is printed on the concave part, but the second is fired to form the reverse formed 3 as shown in 6c.
。  .
燒成的溫度 950 105 C 燒成 同 60 90 。 The firing temperature is 950 105 C and the same as 60 90 .
4 多 萬于破法在半成品的表面 上金 5 如 金、 等 使金  More than 4 million in the surface of the semi-finished product, gold, such as gold, etc.
半成品的 表面 包括凹陷部份 如 6 所示。 The surface of the semi-finished product includes a recessed portion as shown in 6.
0 5 表面 即 半成品表面部分的 及其上面 她 深度的掌 握是要將表面 露出 、 控制好顏色的 以 到 的要求 凹 陷部分則保持 的效果。  0 5 Surface is the surface part of the semi-finished product and above. The depth of the palm is the effect of the concave part to expose the surface and control the color.
得到如 6e所示 的 的效果 12 表面的 紅色 的 凹陷部分的金色部分力金 。 15 4 The gold portion of the concave portion of the red surface of the surface 12 is obtained as shown in Fig. 6e. 15 4
7所示的工 Work shown in 7
1 8a中的 1 表面她 1 of 8a in her face
2 好的阿 將 好的 印制在 面上形成 在 中 的凹陷部分則 然 第一 燒成 形成帶有凹陷22及 21的 2 如 8b 20 所示  2 A good ah is printed on the surface of the concave portion formed in the surface, then the first firing forms a depression with 22 and 21 as shown in 8b 20
的配方可以和 1、 2或 相同或不同。本 中 其化羊組成 表示如 下 0.1687 0.2001 The formula can be the same or different from 1, 2 or 2. The composition of its sheep is as follows 0.1687 0.2001
0.1283 0.1521 a  0.1283 0.1521 a
0.2827 0.2519 CaO 0.6216 0.4162 A 7.2463 5.0923  0.2827 0.2519 CaO 0.6216 0.4162 A 7.2463 5.0923
0.0396 0.0354 gO 0.0103 0.0151 Fe l 1.6968 1.3456 BCb3
Figure imgf000009_0001
0.0396 0.0354 gO 0.0103 0.0151 Fe l 1.6968 1.3456 BCb3
Figure imgf000009_0001
0.1299 0.1079 aO 0.1299 0.1079 aO
Figure imgf000009_0002
Figure imgf000009_0002
。  .
燒成的溫度 950 105 C 燒成 同 60 90 。 燒成 形成的 固定在 表面形成 2。 The firing temperature is 950 105 C and the same as 60 90 . The formation of the firing is fixed on the surface 2 .
3 好的阿 在上 表面印刷 好的 于凹陷的部位則 然 第二 燒成 形成 反 形成的 3 如 8c所示  3 Good A is printed on the upper surface, and the second part is burned to form a reverse formed 3 as shown in 8c.
。  .
燒成的溫度 950 105 C 燒成 同 60 90 。 The firing temperature is 950 105 C and the same as 60 90 .
4 好的阿 在上 步驟 形成的凹陷表面印刷另一 然 第三 燒 成 形成 4 如 8 所示 凹陷的深度 由 的厚度決定  4 Good A is printed on the concave surface formed by the step and the third is burned to form 4 as shown in 8 The depth of the depression is determined by the thickness
。  .
燒成的溫度 750 950C 燒成 同 60 90 。 此 燒成的溫度比前 燒成的溫度 稍低。 The firing temperature is 750 950C and the same as 60 90. This firing temperature is slightly lower than the temperature of the previous firing.
5 多 萬于破法在半成品的表面 上金 如 金、 等 使金 5 半成品的 表面 包括凹陷部份 如 8e所示。 More than 5 million in the surface of the semi-finished product, such as gold, gold, etc., so that the surface of the gold 5 semi-finished product includes a concave portion as shown in Fig. 8e.
6 表面 即 半成品表面部分的 及其上面 她 深度的掌 握是要將表面 露出 、 控制好顏色的 以 到 的要求 部分則保持 的效果 得到如 8 所示 的 。 的表面效果 12e所示 表面的 紅色 的 凹陷部分的金色 于 袖之上的金 。 5  6 The surface is the surface part of the semi-finished product and above. The depth of the palm grip is to expose the surface and control the color. The required part is maintained as shown in Fig. 8. The surface effect of the 12e is shown in the red concave part of the gold on the gold above the sleeve. 5
以下步驟 Following steps
1 9中的 1 表面她 1 of 9 in her face
2 好的阿 將 好的 印制在 面上形成 在 中 的凹陷部分則 然 第一 燒成 形成帶有凹陷22及 21的 2  2 A good ah is printed on the surface of the concave portion formed in the surface, then the first firing forms a depression with 22 and 21 2
。  .
的配方可以和前例相同或不同。 燒成的溫度 950 105 C 燒成 同 60 90 。 燒成 形成的 固定在 表面形成 2。 3 好的阿 在上 表面印刷 好的 于凹陷的部位則 然 第二 燒成 形成 反 形成的 3 The formula can be the same or different from the previous example. The firing temperature is 950 105 C and the firing is the same as 60 90 . The fixation formed by firing forms a surface 2 . 3 Good A is printed on the upper surface and is in the recessed part, then the second is fired to form the reverse formed 3
。  .
燒成的溫度 950 105 C 燒成 同 60 90 。 The firing temperature is 950 105 C and the same as 60 90 .
4 表面 即 半成品表面部分的 她 得到如 9所示的 其 5 中在凹陷部分 由于 或 因此 未的是 1 未所具有的顏 色。 6  4 The surface is the surface part of the semi-finished product. She obtains the color of the 5 in the recessed part due to or not the 1 is not. 6
以下步驟 Following steps
1 10中的 1 表面她 1 of 10 in the face of her
0 2 好的阿 將 好的 印制在 面上形成 在 中 的凹陷部分則 然 第一 燒成 形成帶有凹陷22及 21的 2  0 2 Good A will be printed on the surface of the concave portion formed in the surface, then the first firing will form a depression with 22 and 21 2
。  .
的配方可以和前例相同或不同。 燒成的溫度 950 105 C 燒成 同 60 90 。 燒成 形成的 固定在 表面形成 2。 The formula can be the same or different from the previous example. The firing temperature is 950 105 C and the same as 60 90 . The formation of the firing is fixed on the surface 2 .
3 好的阿 在上 表面印刷 好的 于凹陷的部位則 然 15 第二 燒成 形成 反 形成的 3  3 Good A. Printing on the upper surface is good in the concave part. 15 Second firing forms the reverse formed 3
。  .
燒成的溫度 950 105 C 燒成 同 60 90 。 The firing temperature is 950 105 C and the same as 60 90 .
4 好的阿 在上 步驟 形成的凹陷表面印刷另一 在  4 Good Ah, on the step, the concave surface formed by the printing another
4上 透明 6 然 第三 燒成 凹陷中的透明 不友 反 凹陷中 的色彩是 4所具有的色彩 因此 用的 透明  4 on the transparent 6 but the third in the depression, the transparency in the depression, the color in the depression is the color of 4, so the transparency used
。  .
20 燒成的溫度 750 950C 燒成 同 60 90 。 此 燒成的溫度比前 燒成的溫度 稍低。20 firing temperature 750 950C firing with 60 90. This firing temperature is slightly lower than the temperature of the previous firing.
5 需要 決定是否再在半成品的表面 上金 如 金、 等。 5 It is necessary to decide whether to re-golden gold, etc. on the surface of the semi-finished product.
6 表面 即 半成品表面部分的 及其上面 她 深度的掌 握是要將表面 露出 、 控制好顏色的 以 到 的要求 25 部分則保持 的效果 得到如 10所示的 。 7  6 Surface is the surface part of the semi-finished product and above. Her deep grip is the requirement to expose the surface and control the color. The effect of the 25 part is maintained as shown in Fig. 10. 7
以下步驟 Following steps
1 11中的 1 表面她 1 of 11 in her face
2 好的阿 將 好的 印制在 面上形成 在 中 的凹陷部分則 然 第一 燒成 形成帶有凹陷22及 21的 2 2 A good A will be printed on the surface in the middle The recessed portion is then first fired to form 2 with recesses 22 and 21
。  .
的配方可以和前例相同或不同。 燒成的溫度 950 105 C 燒成 同 60 90 。 燒成 形成的 固定在 表面形成 2。 The formula can be the same or different from the previous example. The firing temperature is 950 105 C and the same as 60 90 . The formation of the firing is fixed on the surface 2 .
3 好的阿 在上 表面印刷 好的 于凹陷的部位則 然 第二 燒成 形成 反 形成的 3  3 Good A. The upper surface is printed on the surface of the depression, but the second is fired to form the reverse.
。  .
燒成的溫度 950 105 C 燒成 同 60 90 。 The firing temperature is 950 105 C and the same as 60 90 .
4 好的阿 在上 步驟 形成的凹陷表面 7 在 7 之上 另一 然 第三 燒成 形成凹陷22內的 8。  4 Good A. The concave surface formed in the upper step 7 is above 7 and the third is fired to form 8 in the recess 22.
凹陷內 用的 可以 2 用的 相同或不同 可以  The same or different can be used in the recess.
或不透明 。  Or opaque.
。  .
燒成的溫度 750 950C 燒成 同 60 90 。此 燒成的溫度比前 燒成的溫度稍低。The firing temperature is 750 950C and the same as 60 90. The temperature of this firing is slightly lower than the temperature of the previous firing.
5 需要 決定是否再在半成品的表面 上金 如 金、 等。 5 It is necessary to decide whether to re-golden gold, etc. on the surface of the semi-finished product.
6 表面 即 半成品表面部分的 她 凹陷部分則保持 的 效果 得到如 11所示的 。  6 The surface, that is, the concave portion of the semi-finished surface portion, maintains the effect as shown in Fig. 11.
本 的保 不同 于上面的 休 方式 本領域 木人 上面 方式的 等同 化仍然 本 的保 。  This insurance is different from the above-mentioned rest mode. The equivalent of the above method in this field is still guaranteed.

Claims

要 求 1、 的生 方法 其特 在于依 包括以下步驟Requirements 1, the method of birth is characterized by the following steps
A 在 上 形成  A is formed on
在所 燒成的 上 反 以 得 自然 。 2、 要求 1 的生 方法 其特 在于 包括步驟 C 半成品  It is natural to be burned. 2, the requirements of the 1 method is characterized by the inclusion of step C semi-finished products
她 。  she was .
3、 要求1 的生 方法 其特 在于 步驟 A 是 好的阿 將 好的 在 面上形成 中的凹陷部分 然 第一 形成 帶有凹陷的 步驟 是 好的阿 在所 的表面印刷第一 3. The method of requirement 1 is that step A is a good part of the depression formed on the surface, but the first step of forming a depression is good.
第二 。 4、 要求3 的生 方法 其特 在于 包括在第二 在所 中的凹 陷部分 另一 第三 。  Second. 4. The method of claim 3 is characterized by being included in the second portion of the recessed portion and the third portion.
5、 要求 3 的生 方法其特 在于 方法 包括在 的 表面 上金 。 6、 要求 4 的生 方法其特 在于 方法 包括在 的 表面 上金 。 7、 要求3 的生 方法 其特 在于 包括在所 中的凹陷部分 第二 在其上 透明 第三 。5. The method of requirement 3 is characterized in that the method includes gold on the surface. 6. The method of requirement 4 is characterized in that the method includes gold on the surface. 7. The method of claim 3 is characterized in that it is included in the depressed portion of the second portion and is transparent on the third portion.
8、 要求3 的生 方法 其特 在于 包括在所 中的凹陷部分 8. The method of requirement 3 is characterized in that it is included in the depressed portion of
之上 第二 第三 第 二 反 。 9、 要求 任一 要求 的生 方法其特 在于 燒成的溫度 750 1050 。 Above the second third and second opposition. 9. The required method for any of the requirements is characterized by a firing temperature of 750 1050.
C 燒成 同 60 90 。 10、 要求 任一 要求 的生 方法 其特 在于 透明或不 透明 80 200 。 C is fired with 60 90 . 10. The required method of life is required to be transparent or opaque 80 200 .
11、 其特 在于 包括 、 成形于 上面的 及由 11. It is characterized by, formed on, and
反 形成的 。 Anti-formed.
1 、 要求11 的 其特 在于 包括由 而成的士休 及 休 同的凹陷。 1. The special feature of Requirement 11 consists of a depression consisting of a taxi and a rest.
13、 要求12 的 其特 在于 凹陷內具有 。 13. The requirement of Requirement 12 is that it has a recess.
14、 要求12 的 其特 在于 凹陷內具有金 。 14. The requirement of Requirement 12 is that there is gold in the depression.
15、 要求13 的 其特 在于 凹陷內的 之上 有金 。15. The requirement of Requirement 13 is that there is gold above the depression.
16、 要求12 的 其特 在于 所述凹陷內具有 且在 料之上 有一透明 。 16. The requirement of claim 12 is that there is a transparency in the recess and above the material.
17、 要求12 的 其特 在于 所述凹陷內具有一 及 由 17. The requirement of claim 12 is that the recess has one and
于 之上的 反 形成的 。  On the other side of the formation.
18、 要求 11 17任一 要求 的 其特 在于 的色彩 接合深度的 化而 。 18. Requirement 11 17 Any of the requirements for color joint depth.
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CN103274765A (en) * 2013-05-31 2013-09-04 景德镇陶瓷学院 Co-Zn-Cr-Al composite spinel type blue ceramic pigment and preparation method thereof
CN104591806A (en) * 2015-01-28 2015-05-06 广东宏陶陶瓷有限公司 Pure black glazed tile produced by using waste glaze slip and preparation method of pure black glazed tile
CN106866160A (en) * 2017-02-23 2017-06-20 佛山市东鹏陶瓷有限公司 A kind of natural-like stone polished bricks and its preparation technology
CN110066178A (en) * 2019-04-12 2019-07-30 佛山市乐陶工艺陶瓷有限公司 The manufacture craft of transmutation background ceramic board pictures
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