WO2010005271A3 - 유기용제 분산성 전도성 고분자 및 이의 제조방법 - Google Patents

유기용제 분산성 전도성 고분자 및 이의 제조방법 Download PDF

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WO2010005271A3
WO2010005271A3 PCT/KR2009/003812 KR2009003812W WO2010005271A3 WO 2010005271 A3 WO2010005271 A3 WO 2010005271A3 KR 2009003812 W KR2009003812 W KR 2009003812W WO 2010005271 A3 WO2010005271 A3 WO 2010005271A3
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Prior art keywords
organic solvent
conductive polymer
manufacture
present
dispersible
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PCT/KR2009/003812
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English (en)
French (fr)
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WO2010005271A2 (ko
Inventor
서광석
김종은
김태영
이태희
김원중
Original Assignee
Suh Kwang Suck
Kim Jong Eun
Kim Tae Young
Lee Tae Hee
Kim Won Jung
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Application filed by Suh Kwang Suck, Kim Jong Eun, Kim Tae Young, Lee Tae Hee, Kim Won Jung filed Critical Suh Kwang Suck
Priority to CN2009801271671A priority Critical patent/CN102089348A/zh
Priority to US13/003,747 priority patent/US8691117B2/en
Priority to EP09794677A priority patent/EP2305730A2/en
Priority to JP2011517357A priority patent/JP2011527712A/ja
Publication of WO2010005271A2 publication Critical patent/WO2010005271A2/ko
Publication of WO2010005271A3 publication Critical patent/WO2010005271A3/ko

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/125Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one oxygen atom in the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/521Esters of phosphoric acids, e.g. of H3PO4
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124Intrinsically conductive polymers
    • H01B1/127Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/48Conductive polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/54Electrolytes
    • H01G11/56Solid electrolytes, e.g. gels; Additives therein
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3223Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/70Post-treatment
    • C08G2261/79Post-treatment doping
    • C08G2261/792Post-treatment doping with low-molecular weight dopants
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
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  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Conductive Materials (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

본 발명은 유기용매에 분산이 용이한 전도성 고분자 및 이의 제조방법에 관한 것으로서, 보다 상세하게는 단량체를 중합시킴에 있어 유기용매 가용성인 포스페이트계 화합물을 도판트 음이온으로 사용하여 화학 중합시킴으로써 유기 용매에 분산되는 전도성 고분자를 제조하는 방법에 관한 것이다. 본 발명은 간단한 공정으로 다양한 유기용매에 분산되는 전도성 고분자를 얻을 수 있기 때문에, 기존의 수계 분산된 전도성 고분자로는 응용이 제한되었던 여러 응용소재 분야에 적용이 가능하다.
PCT/KR2009/003812 2008-07-11 2009-07-11 유기용제 분산성 전도성 고분자 및 이의 제조방법 WO2010005271A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2009801271671A CN102089348A (zh) 2008-07-11 2009-07-11 对有机溶剂具有分散性的导电性聚合物及其制备方法
US13/003,747 US8691117B2 (en) 2008-07-11 2009-07-11 Organic solvent dispersible conductive polymer and method for manufacture thereof
EP09794677A EP2305730A2 (en) 2008-07-11 2009-07-11 Organic solvent-dispersible conductive polymer and method for manufacture thereof
JP2011517357A JP2011527712A (ja) 2008-07-11 2009-07-11 有機溶剤分散性導電性高分子およびその製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2008-0067836 2008-07-11
KR1020080067836A KR100949399B1 (ko) 2008-07-11 2008-07-11 유기용제 분산성 전도성 고분자 및 이의 제조방법

Publications (2)

Publication Number Publication Date
WO2010005271A2 WO2010005271A2 (ko) 2010-01-14
WO2010005271A3 true WO2010005271A3 (ko) 2010-04-29

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PCT/KR2009/003812 WO2010005271A2 (ko) 2008-07-11 2009-07-11 유기용제 분산성 전도성 고분자 및 이의 제조방법

Country Status (7)

Country Link
US (1) US8691117B2 (ko)
EP (1) EP2305730A2 (ko)
JP (1) JP2011527712A (ko)
KR (1) KR100949399B1 (ko)
CN (1) CN102089348A (ko)
TW (1) TW201008979A (ko)
WO (1) WO2010005271A2 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5728232B2 (ja) * 2008-01-17 2015-06-03 ソンジュ イ 可溶性伝導性高分子およびその製造方法
JP5642455B2 (ja) * 2010-08-30 2014-12-17 三洋電機株式会社 導電性高分子膜の形成方法ならびに導電性高分子の形成方法
CN102956373B (zh) * 2011-08-18 2016-01-13 海洋王照明科技股份有限公司 电解液及其配制方法
US10208160B2 (en) 2014-02-27 2019-02-19 Tayca Corporation Oxidant dopant agent for conductive polymer production, and a solution thereof, and a conductive polymer prepared by using either of them, as well as an electrolyte capacitor using the conductive polymer as an electrolyte
KR101735915B1 (ko) 2014-05-27 2017-05-15 주식회사 엘지화학 전도성 고분자 잉크 조성물
WO2015182954A1 (ko) * 2014-05-27 2015-12-03 주식회사 엘지화학 전도성 고분자 잉크 조성물
CN106519250A (zh) * 2016-09-29 2017-03-22 辽宁石油化工大学 含氮小分子有机配体调节荧光发射性质的一维链状铜配位聚合物的制备方法

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US7034104B2 (en) * 2002-12-06 2006-04-25 Myongji University Processes for preparing conductive macromolecular polythiophenes
KR20040073183A (ko) * 2003-02-13 2004-08-19 주식회사 금강고려화학 수용성 전도성 고분자 복합체, 이의 제조방법 및 이를포함하는 대전방지용 도료 조성물
WO2007013787A1 (en) * 2005-07-29 2007-02-01 Kwang Suck Suh Conducting polymer synthesized with partially substituted polymers as a dopant
KR100779255B1 (ko) * 2005-12-30 2007-11-28 재단법인서울대학교산학협력재단 분산 중합을 이용한 전도성 폴리피롤 나노입자의 대량 제조방법

Also Published As

Publication number Publication date
JP2011527712A (ja) 2011-11-04
CN102089348A (zh) 2011-06-08
KR20100007269A (ko) 2010-01-22
TW201008979A (en) 2010-03-01
KR100949399B1 (ko) 2010-03-24
US20110175034A1 (en) 2011-07-21
WO2010005271A2 (ko) 2010-01-14
EP2305730A2 (en) 2011-04-06
US8691117B2 (en) 2014-04-08

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