WO2009078431A1 - 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体 - Google Patents

重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体 Download PDF

Info

Publication number
WO2009078431A1
WO2009078431A1 PCT/JP2008/072963 JP2008072963W WO2009078431A1 WO 2009078431 A1 WO2009078431 A1 WO 2009078431A1 JP 2008072963 W JP2008072963 W JP 2008072963W WO 2009078431 A1 WO2009078431 A1 WO 2009078431A1
Authority
WO
WIPO (PCT)
Prior art keywords
liquid crystal
polymerizable liquid
crystalline polymer
polymerizable
represent
Prior art date
Application number
PCT/JP2008/072963
Other languages
English (en)
French (fr)
Inventor
Kei Sakamoto
Naoto Kogoshi
Original Assignee
Zeon Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zeon Corporation filed Critical Zeon Corporation
Priority to JP2009546279A priority Critical patent/JP5407870B2/ja
Publication of WO2009078431A1 publication Critical patent/WO2009078431A1/ja

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/24—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing nitrogen-to-nitrogen bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/72—Hydrazones
    • C07C251/88—Hydrazones having also the other nitrogen atom doubly-bound to a carbon atom, e.g. azines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
    • C09K2019/0448—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3016—Polarising elements involving passive liquid crystal elements

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Liquid Crystal Substances (AREA)

Abstract

本発明は、下記式（Ｉ）で示される重合性液晶化合物、該重合性液晶化合物及び重合可能なキラル化合物を含有する重合性液晶組成物、前記重合性液晶化合物又は前記重合性液晶組成物を重合して得られる液晶性高分子、該液晶性高分子を構成材料とする光学異方体である。本発明によれば、より液晶相を示す温度範囲が広く、化学的に安定であり、安価に製造でき、かつ、選択反射波長帯域△λが広い（△ｎが大きい）重合性液晶化合物、この化合物を含有する重合性液晶組成物、これらを重合して得られる液晶性高分子、及びこの液晶性高分子を構成材料とする光学異方体が提供される。式（Ｉ）中、ＭはＣ１～３０の２価の有機基等を、Ｙ１～Ｙ8は－Ｏ－Ｃ（＝Ｏ）－、－Ｃ（＝Ｏ）－Ｏ－等を、Ｇ１及びＧ２はＣ１～２０の２価の脂肪族基等を、Ｚ１及びＺ２はＣ２～１０のアルケニル基等を、Ａ１及びＡ２はＣ１～３０の２価の有機基Ａを、Ｘ１～Ｘ16は水素原子等を表す。ａ、ｂ、ｃ及びｄは０又は１である。
PCT/JP2008/072963 2007-12-19 2008-12-17 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体 WO2009078431A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009546279A JP5407870B2 (ja) 2007-12-19 2008-12-17 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007328035 2007-12-19
JP2007-328035 2007-12-19

Publications (1)

Publication Number Publication Date
WO2009078431A1 true WO2009078431A1 (ja) 2009-06-25

Family

ID=40795545

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/072963 WO2009078431A1 (ja) 2007-12-19 2008-12-17 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体

Country Status (3)

Country Link
JP (1) JP5407870B2 (ja)
TW (1) TW200946649A (ja)
WO (1) WO2009078431A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010038591A1 (ja) * 2008-10-01 2010-04-08 日本ゼオン株式会社 重合性キラル化合物、重合性液晶組成物、液晶性高分子及び光学異方体
WO2011122298A1 (ja) * 2010-03-31 2011-10-06 日本ゼオン株式会社 重合性キラル化合物、重合性液晶組成物、液晶性高分子及び光学異方体
WO2012169424A1 (ja) * 2011-06-10 2012-12-13 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
EP2727904A1 (en) * 2011-06-24 2014-05-07 Zeon Corporation Polymerizable compounds, polymerizable composition, polymer, and optically anisotropic body
JP2017032987A (ja) * 2011-04-27 2017-02-09 日本ゼオン株式会社 光学フィルム、ヒドラジン化合物、その使用方法及び光学異方体の製造方法
JP2018025752A (ja) * 2016-08-03 2018-02-15 Dic株式会社 光学異方体
JP2023014150A (ja) * 2015-04-14 2023-01-26 Jsr株式会社 液晶配向剤

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0940585A (ja) * 1995-07-28 1997-02-10 Rolic Ag 光架橋性液晶１，４−フェニレン誘導体
EP0825176A1 (en) * 1996-08-22 1998-02-25 Dainippon Ink And Chemicals, Inc. Azine derivative, process for the preparation thereof, nematic liquid crystal composition and liquid crystal display system comprising same
JP2004182702A (ja) * 2002-12-06 2004-07-02 Nitto Denko Corp 重合性テルフェニル液晶化合物、液晶性組成物、コレステリック液晶組成物、光学フィルム、及び画像表示装置
JP2005213226A (ja) * 2004-01-30 2005-08-11 Dainippon Ink & Chem Inc 化合物、該化合物を含有する液晶組成物及び該液晶組成物を用いた液晶表示素子
WO2007142206A1 (ja) * 2006-06-05 2007-12-13 Zeon Corporation コレステリック液晶組成物及び円偏光分離シート、並びにその用途
WO2008102838A1 (ja) * 2007-02-23 2008-08-28 Zeon Corporation 液晶性化合物、液晶性組成物、光学フィルムおよび光学積層体
WO2008133290A1 (ja) * 2007-04-24 2008-11-06 Zeon Corporation 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0940585A (ja) * 1995-07-28 1997-02-10 Rolic Ag 光架橋性液晶１，４−フェニレン誘導体
EP0825176A1 (en) * 1996-08-22 1998-02-25 Dainippon Ink And Chemicals, Inc. Azine derivative, process for the preparation thereof, nematic liquid crystal composition and liquid crystal display system comprising same
JP2004182702A (ja) * 2002-12-06 2004-07-02 Nitto Denko Corp 重合性テルフェニル液晶化合物、液晶性組成物、コレステリック液晶組成物、光学フィルム、及び画像表示装置
JP2005213226A (ja) * 2004-01-30 2005-08-11 Dainippon Ink & Chem Inc 化合物、該化合物を含有する液晶組成物及び該液晶組成物を用いた液晶表示素子
WO2007142206A1 (ja) * 2006-06-05 2007-12-13 Zeon Corporation コレステリック液晶組成物及び円偏光分離シート、並びにその用途
WO2008102838A1 (ja) * 2007-02-23 2008-08-28 Zeon Corporation 液晶性化合物、液晶性組成物、光学フィルムおよび光学積層体
WO2008133290A1 (ja) * 2007-04-24 2008-11-06 Zeon Corporation 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
GEROLD S. ET AL.: "Cholesteric Networks Based on Lyotropic Mixtures", CHEMPHYSCHEM, vol. 4, no. 5, 2003, pages 505 - 508 *
MAKOTO NEGISHI ET AL.: "STN-LCD-yo Azine-kei Ekisho no Kaihatsu", DIC TECHNICAL REVIEW, no. 5, 1999, pages 17 - 20 *

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8603357B2 (en) 2008-10-01 2013-12-10 Zeon Corporation Polymerizable chiral compound, polymerizable liquid crystal composition, liquid crystal polymer and optically anisotropic body
WO2010038591A1 (ja) * 2008-10-01 2010-04-08 日本ゼオン株式会社 重合性キラル化合物、重合性液晶組成物、液晶性高分子及び光学異方体
JP5522047B2 (ja) * 2008-10-01 2014-06-18 日本ゼオン株式会社 重合性キラル化合物、重合性液晶組成物、液晶性高分子及び光学異方体
US8883271B2 (en) 2010-03-31 2014-11-11 Zeon Corporation Polymerizable chiral compound, polymerizable liquid crystal compound, liquid crystal polymer and optically anisotropic body
JP5737283B2 (ja) * 2010-03-31 2015-06-17 日本ゼオン株式会社 重合性キラル化合物、重合性液晶組成物、液晶性高分子及び光学異方体
CN102791749B (zh) * 2010-03-31 2016-03-16 日本瑞翁株式会社 聚合性手性化合物、聚合性液晶组合物、液晶性高分子及光学各向导性体
CN102791749A (zh) * 2010-03-31 2012-11-21 日本瑞翁株式会社 聚合性手性化合物、聚合性液晶组合物、液晶性高分子及光学各向导性体
WO2011122298A1 (ja) * 2010-03-31 2011-10-06 日本ゼオン株式会社 重合性キラル化合物、重合性液晶組成物、液晶性高分子及び光学異方体
JP2017032987A (ja) * 2011-04-27 2017-02-09 日本ゼオン株式会社 光学フィルム、ヒドラジン化合物、その使用方法及び光学異方体の製造方法
CN103582626B (zh) * 2011-06-10 2016-01-13 日本瑞翁株式会社 聚合性化合物、聚合性组合物、高分子以及光学各向异性体
US9029490B2 (en) 2011-06-10 2015-05-12 Zeon Corporation Polymerizable compound, polymerizable composition, polymer, and optically anisotropic body
JPWO2012169424A1 (ja) * 2011-06-10 2015-02-23 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
WO2012169424A1 (ja) * 2011-06-10 2012-12-13 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
CN103582626A (zh) * 2011-06-10 2014-02-12 日本瑞翁株式会社 聚合性化合物、聚合性组合物、高分子以及光学各向异性体
EP2727904A4 (en) * 2011-06-24 2015-04-01 Zeon Corp POLYMERIZABLE COMPOUNDS, POLYMERIZABLE COMPOSITION, POLYMER AND OPTICALLY ANISOTROPIC BODY
EP2727904A1 (en) * 2011-06-24 2014-05-07 Zeon Corporation Polymerizable compounds, polymerizable composition, polymer, and optically anisotropic body
JP2023014150A (ja) * 2015-04-14 2023-01-26 Jsr株式会社 液晶配向剤
JP7318787B2 (ja) 2015-04-14 2023-08-01 Jsr株式会社 液晶配向剤
JP2018025752A (ja) * 2016-08-03 2018-02-15 Dic株式会社 光学異方体

Also Published As

Publication number Publication date
JP5407870B2 (ja) 2014-02-05
TW200946649A (en) 2009-11-16
JPWO2009078431A1 (ja) 2011-04-28

Similar Documents

Publication Publication Date Title
WO2008133290A1 (ja) 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体
WO2009078431A1 (ja) 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体
WO2008102838A1 (ja) 液晶性化合物、液晶性組成物、光学フィルムおよび光学積層体
WO2008126421A1 (ja) 光学異方性膜及び液晶表示装置
WO2008090780A1 (ja) 液晶性化合物、液晶組成物および液晶表示素子
WO2008123235A1 (ja) 高分子安定化液晶組成物、液晶表示素子、液晶表示素子の製造方法
WO2008114821A1 (ja) 液晶組成物および液晶表示素子
ATE410497T1 (de) Mesogene verbindungen, flüssigkristallines medium und flüssigkristallanzeigevorrichtung
TW200704758A (en) Polymerizable liquid crystal compounds and polymerizable liquid crystal compositions containing the same, and polymers obtainable therefrom
WO2008128934A3 (en) Fluorinated dyes and their use in electrophoretic display devices
TW200720409A (en) High clarity cholesteric liquid crystal films
WO2009075343A1 (ja) 光学異方性膜、偏光板、液晶表示装置、ならびに高分子フィルム用レターデーション制御剤
TW200708600A (en) High birefringent liquid crystal compound and composition thereof
Wohlfarth Refractive index of the mixture (1) methanol;(2) tetrahydrofuran: Data extract from Landolt-Börnstein III/47: Optical Constants
Wohlfarth Refractive index of the mixture (1) methanol;(2) cyclohexanone: Data extract from Landolt-Börnstein III/47: Optical Constants
Wohlfarth Refractive index of the mixture (1) methoxybenzene;(2) 2-phenylethanol: Data extract from Landolt-Börnstein III/47: Optical Constants
Wohlfarth Refractive index of the mixture (1) ethyl acetate;(2) benzene: Data extract from Landolt-Börnstein III/47: Optical Constants
Wohlfarth Refractive index of the mixture (1) pentan-1-ol;(2) cyclohexanone: Data extract from Landolt-Börnstein III/47: Optical Constants
Wohlfarth Refractive index of the mixture (1) methanol;(2) 1-methylpiperazine: Data extract from Landolt-Börnstein III/47: Optical Constants
Wohlfarth Refractive index of the mixture (1) methanol;(2) diethyl carbonate: Data extract from Landolt-Börnstein III/47: Optical Constants
Wohlfarth Refractive index of the mixture (1) 1, 1, 1-trichloroethane;(2) methyl acetate: Data extract from Landolt-Börnstein III/47: Optical Constants
Wohlfarth Refractive index of the mixture (1) ethyl acetate;(2) toluene: Data extract from Landolt-Börnstein III/47: Optical Constants
Wohlfarth Refractive index of the mixture (1) 1, 1, 2, 2-tetrachloroethane;(2) methyl acetate: Data extract from Landolt-Börnstein III/47: Optical Constants
Wohlfarth Refractive index of the mixture (1) methanol;(2) ethyl propanoate: Data extract from Landolt-Börnstein III/47: Optical Constants
Wohlfarth Refractive index of the mixture (1) methanol;(2) 3-methylbutan-1-ol: Data extract from Landolt-Börnstein III/47: Optical Constants

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08862074

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 2009546279

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 08862074

Country of ref document: EP

Kind code of ref document: A1