WO2009060022A1 - Verfahren zur herstellung von schwefelsäure - Google Patents
Verfahren zur herstellung von schwefelsäure Download PDFInfo
- Publication number
- WO2009060022A1 WO2009060022A1 PCT/EP2008/065044 EP2008065044W WO2009060022A1 WO 2009060022 A1 WO2009060022 A1 WO 2009060022A1 EP 2008065044 W EP2008065044 W EP 2008065044W WO 2009060022 A1 WO2009060022 A1 WO 2009060022A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sulfur
- sulfuric acid
- sulfur dioxide
- combustion
- air
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
- C01B17/54—Preparation of sulfur dioxide by burning elemental sulfur
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
- C01B17/58—Recovery of sulfur dioxide from acid tar or the like or from any waste sulfuric acid
Definitions
- the invention relates to a process for the preparation of sulfuric acid by the contact method.
- Sulfuric acid is one of the basic products of the chemical industry. Sulfuric acid is made from sulfur dioxide, which is oxidized to sulfur trioxide. This is reacted with water in concentrated sulfuric acid to sulfuric acid.
- the sulfur dioxide is produced largely by burning elemental sulfur, but also from waste sulfuric acids by their cleavage.
- Liquid sulfur of 140 - 150 0 C is sprayed by means of nozzles in finely divided droplet form in combustion chambers.
- the concentration of sulfur dioxide in the exiting gas mixture is usually adjusted with air to 9-1 1, 5% by volume;
- the content of oxygen present in the gas mixture is sufficient for the subsequent production of sulfur trioxide.
- the hot gases are then cooled to about 450 0 C via a waste heat boiler, in which water vapor is generated. A cleaning operation is not necessary (see KH Büchel et al .: Industrial Inorganic Chemistry, 3rd edition, Verlag Chemie, Weinheim 1999, p 1 10 - 122).
- sulfur dioxide can also be obtained from waste sulfuric acids by splitting them.
- Contaminated sulfuric acids are found in many processes, especially in organic chemistry, petrochemistry and the metal industry.
- the surest way to avoid waste problems and possible environmental impacts is the thermal cracking to form sulfur dioxide, according to the following reaction equation:
- Sulfuric acid is widely used as one of the key products of the chemical industry.
- An important field of application is the concentration of so-called azeotropic nitric acid, ie nitric acid with a concentration in the range of the azeotropic composition, from about 68% nitric acid, to concentrated nitric acid, with a nitric acid content of up to 100%.
- Concentrated nitric acid is needed, for example, for the production of dinitrotoluene.
- the object is achieved by a process for the production of sulfuric acid, whereby sulfur dioxide-containing process gases are obtained by combustion of liquid sulfur with process air supplied from outside or by splitting waste sulfuric acids, and the sulfur dioxide from the sulfur dioxide-containing process gases is oxidized to sulfur trioxide and into sulfuric acid is transferred by the contact method, which is characterized in that the process air, which is supplied from the outside for the combustion of sulfur, or the sulfur dioxide-containing process gases, which are obtained by splitting of waste sulfuric acid, are reduced in their water vapor content by being cooled.
- the process air is passed from the outside to the combustion of liquid sulfur via a compressor. It is advantageous to use the process air
- the process is more favorable in terms of energy, because the compressor compresses cooler air and thus requires less energy for thermodynamic reasons.
- the process air for the combustion of liquid sulfur or the sulfur dioxide-containing process gases obtained by splitting waste sulfuric acids are cooled in a preferred embodiment of the invention by direct contact with a cooling medium.
- cooling medium is advantageously used water having a temperature in the range of 1 to 10 0 C or sulfuric acid having a temperature in the range of -5 to +10 0 C or brine.
- the process air for the combustion of liquid sulfur or the sulfur dioxide-containing process gases, which are obtained by cleavage of waste sulfuric acids can be cooled in a further preferred embodiment by indirect cooling with a cooling medium.
- the indirect cooling can be done advantageously with a commercial air conditioning.
- the expert will decide on the basis of economic aspects in an individual case, taking into account in particular the water vapor loading of the air at the site of the Process and the desired degree of concentration of the sulfuric acid to be produced.
- the externally supplied process air for the combustion of sulfur or the sulfur dioxide-containing process gases can be cooled to a temperature below 5 ° C.
- the water vapor content of the process air for the combustion of liquid sulfur or the sulfur dioxide-containing process gases, which are formed by cleavage of waste sulfuric acids, can preferably be reduced to less than 1% by volume.
- the inventive method has the advantage that it reduces the entry of water into processes for the production of sulfuric acid in a technically easy to implement way.
- Figure 1 shows a flow diagram of a sulfuric acid plant according to the invention by the double contact method
- FIG. 2 is a flow diagram of a Spaltschwefelklare plant according to the invention.
- air, stream 1 is fed, according to the invention, via a heat exchanger WT, to a combustion plant VS1 for liquid sulfur, stream 2.
- Much of the energy released during combustion is used to produce steam while the combustion gas is being cooled down by transferring feed water, stream 3, into steam, stream 4.
- the reaction mixture from the sulfur combustion VS1 is fed to a first process stage, VS2, the so-called double-contact process, which has an efficiency of about 95%.
- VS3 sulfuric acid and oleum, stream 6, are prepared.
- sulfur trioxide is dissolved in concentrated sulfuric acid with the uniform addition of water, stream 5.
- the concentration of oleum is kept constant by the continuous addition of sulfuric acid.
- Process stage VS4 is the second stage of the catalytic oxidation of sulfur dioxide with atmospheric oxygen to sulfur trioxide by the double contact process.
- the removal of sulfur trioxide from the chemical equilibrium carried out in process stage VS3 favors the conversion of the remaining about 5% sulfur dioxide in process stage VS4.
- the total sales in process steps VS2 and VS4, ie the first and second stages of the double-contact process, is more than 99.7%.
- sulfuric acid is produced by absorption of the sulfur trioxide formed in process stage VS4 in the final absorber, VS5.
- the exhaust gas leaving the final absorber VS5, stream 7, consists essentially of nitrogen and the remaining oxygen.
- the dashed lines between VS3 and VS5 indicate the acid exchange between the intermediate and final absorption stages.
- FIG. 2 shows the flow diagram of a Spaltschwefelklare plant according to the invention.
- the cracking and vapor extraction A are supplied with feed water, stream 8, back acid, stream 9, heavy oil, stream 10, sulfur, stream 11, atomizing air, stream 12 and air, stream 13.
- stream 14 From the cleavage and steam extraction steam, stream 14, deducted and sulfur dioxide-containing process gas 15, which is derived via a gas cleaning and cooling B, from which wastewater 16, according to the invention via a not shown SO 2 -Trockner and heat exchanger in a contact part C and further to the absorption D passed. From this exhaust air 17 and sulfuric acid, stream 18, deducted.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08847708A EP2219994A1 (de) | 2007-11-07 | 2008-11-06 | Verfahren zur herstellung von schwefelsäure |
CN200880115255A CN101855167A (zh) | 2007-11-07 | 2008-11-06 | 制备硫酸的方法 |
JP2010532585A JP2011502929A (ja) | 2007-11-07 | 2008-11-06 | 硫酸の製造方法 |
US12/741,089 US20100254889A1 (en) | 2007-11-07 | 2008-11-06 | Method for producing sulfuric acid |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07120139.6 | 2007-11-07 | ||
EP07120139 | 2007-11-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009060022A1 true WO2009060022A1 (de) | 2009-05-14 |
Family
ID=40260589
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2008/065044 WO2009060022A1 (de) | 2007-11-07 | 2008-11-06 | Verfahren zur herstellung von schwefelsäure |
Country Status (6)
Country | Link |
---|---|
US (1) | US20100254889A1 (de) |
EP (1) | EP2219994A1 (de) |
JP (1) | JP2011502929A (de) |
KR (1) | KR20100103489A (de) |
CN (1) | CN101855167A (de) |
WO (1) | WO2009060022A1 (de) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017001463A1 (en) * | 2015-07-02 | 2017-01-05 | Haldor Topsøe A/S | Process for production of sulfuric acid |
WO2017037256A1 (de) * | 2015-09-04 | 2017-03-09 | Thyssenkrupp Industrial Solutions Ag | Verfahren und vorrichtung zur herstellung von schwefelsäure |
CN109052335A (zh) * | 2018-07-24 | 2018-12-21 | 上海三夫工程技术有限公司 | 一种硫磺气体还原废硫酸制液体二氧化硫和硫酸的方法 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8815202B2 (en) * | 2012-08-27 | 2014-08-26 | E I Du Pont De Nemours And Company | Process for producing sulfuric acid with low levels of nitrogen oxides |
TWI552950B (zh) * | 2013-11-20 | 2016-10-11 | 綠美企業股份有限公司 | 製造硫酸的方法、設備及系統 |
CN105480953A (zh) * | 2014-10-09 | 2016-04-13 | 中国石油化工股份有限公司 | 一种使用硫磺作为燃料的烷基化废酸裂解工艺 |
CN109573957A (zh) * | 2018-12-28 | 2019-04-05 | 华陆工程科技有限责任公司 | 一种硫磺同时制取不同浓度的二氧化硫和硫酸的联产方法 |
WO2021089217A1 (en) * | 2019-11-04 | 2021-05-14 | Outotec (Finland) Oy | Process and plant for producing sulphuric acid |
CN111994879A (zh) * | 2020-08-27 | 2020-11-27 | 福建天甫电子材料有限公司 | 一种电子级硫酸的制备工艺 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2028733A (en) * | 1933-06-06 | 1936-01-21 | American Cyanamid Co | Production of sulphuric acid by the contact process |
DE2703474A1 (de) * | 1977-01-28 | 1978-08-03 | Ernst Jenniges | Verfahren zur gastrocknung und so tief 3 -absorption bei der herstellung von schwefelsaeure |
US5308587A (en) * | 1991-11-11 | 1994-05-03 | Cameron Gordon M | Cooled sulphur furnace bypass system |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2519928C3 (de) * | 1975-05-05 | 1981-04-02 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Herstellung von Schwefelsäure |
DE2725432C3 (de) * | 1977-06-04 | 1980-02-21 | Davy International Ag, 6000 Frankfurt | Verfahren zur Herstellung von konzentrierter Schwefelsäure |
US4213958A (en) * | 1977-11-14 | 1980-07-22 | Canadian Industries Limited | Production of sulphur trioxide, sulphuric acid and oleum |
CA1198261A (en) * | 1983-04-29 | 1985-12-24 | Gordon M. Cameron | Liquid sulphur dioxide manufacture |
AR039994A1 (es) * | 2002-11-06 | 2005-03-09 | Quimetal Ind S A | Metodo de produccion automatizada de so2 puro a partir de azufre y oxigeno |
JP3696224B2 (ja) * | 2003-03-19 | 2005-09-14 | 株式会社グリーンセイジュ | 乾燥システム |
EP1774230A2 (de) * | 2004-06-08 | 2007-04-18 | Nanopore, Inc. | Sorptionskühlsysteme, ihre verwendung in kraftfahrzeugkühlanwendungen und diese betreffende verfahren |
-
2008
- 2008-11-06 KR KR1020107012063A patent/KR20100103489A/ko not_active Application Discontinuation
- 2008-11-06 EP EP08847708A patent/EP2219994A1/de not_active Withdrawn
- 2008-11-06 US US12/741,089 patent/US20100254889A1/en not_active Abandoned
- 2008-11-06 CN CN200880115255A patent/CN101855167A/zh active Pending
- 2008-11-06 WO PCT/EP2008/065044 patent/WO2009060022A1/de active Application Filing
- 2008-11-06 JP JP2010532585A patent/JP2011502929A/ja not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2028733A (en) * | 1933-06-06 | 1936-01-21 | American Cyanamid Co | Production of sulphuric acid by the contact process |
DE2703474A1 (de) * | 1977-01-28 | 1978-08-03 | Ernst Jenniges | Verfahren zur gastrocknung und so tief 3 -absorption bei der herstellung von schwefelsaeure |
US5308587A (en) * | 1991-11-11 | 1994-05-03 | Cameron Gordon M | Cooled sulphur furnace bypass system |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017001463A1 (en) * | 2015-07-02 | 2017-01-05 | Haldor Topsøe A/S | Process for production of sulfuric acid |
KR20180023889A (ko) * | 2015-07-02 | 2018-03-07 | 할도르 토프쉐 에이/에스 | 황산의 제조 방법 |
EA034697B1 (ru) * | 2015-07-02 | 2020-03-10 | Хальдор Топсёэ А/С | Способ производства серной кислоты |
US10829376B2 (en) | 2015-07-02 | 2020-11-10 | Haldor Topsøe A/S | Process for production of sulfuric acid |
AU2016287352B2 (en) * | 2015-07-02 | 2021-01-07 | Haldor Topsøe A/S | Process for production of sulfuric acid |
KR102615985B1 (ko) | 2015-07-02 | 2023-12-20 | 토프쉐 에이/에스 | 황산의 제조 방법 |
WO2017037256A1 (de) * | 2015-09-04 | 2017-03-09 | Thyssenkrupp Industrial Solutions Ag | Verfahren und vorrichtung zur herstellung von schwefelsäure |
US10435299B2 (en) | 2015-09-04 | 2019-10-08 | Thyssenkrupp Industrial Solutions Ag | Method and device for producing sulfuric acid |
CN109052335A (zh) * | 2018-07-24 | 2018-12-21 | 上海三夫工程技术有限公司 | 一种硫磺气体还原废硫酸制液体二氧化硫和硫酸的方法 |
CN109052335B (zh) * | 2018-07-24 | 2023-08-22 | 上海三夫工程技术有限公司 | 一种硫磺气体还原废硫酸制液体二氧化硫和硫酸的方法 |
Also Published As
Publication number | Publication date |
---|---|
JP2011502929A (ja) | 2011-01-27 |
KR20100103489A (ko) | 2010-09-27 |
EP2219994A1 (de) | 2010-08-25 |
CN101855167A (zh) | 2010-10-06 |
US20100254889A1 (en) | 2010-10-07 |
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