WO2009057567A1 - 発光素子材料および発光素子 - Google Patents
発光素子材料および発光素子 Download PDFInfo
- Publication number
- WO2009057567A1 WO2009057567A1 PCT/JP2008/069485 JP2008069485W WO2009057567A1 WO 2009057567 A1 WO2009057567 A1 WO 2009057567A1 JP 2008069485 W JP2008069485 W JP 2008069485W WO 2009057567 A1 WO2009057567 A1 WO 2009057567A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- luminescent
- aryl
- group
- halogeno
- cycloalkenyl
- Prior art date
Links
- 239000000463 material Substances 0.000 title abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 2
- -1 pyrromethene compound Chemical class 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 125000005013 aryl ether group Chemical group 0.000 abstract 1
- 150000004832 aryl thioethers Chemical group 0.000 abstract 1
- 125000000392 cycloalkenyl group Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000001072 heteroaryl group Chemical group 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/44—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having three double bonds between ring members or between ring members and non-ring members
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
- C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
- C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
- C07D235/18—Benzimidazoles; Hydrogenated benzimidazoles with aryl radicals directly attached in position 2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
- C07D307/79—Benzo [b] furans; Hydrogenated benzo [b] furans with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
- C07D307/80—Radicals substituted by oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/022—Boron compounds without C-boron linkages
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/14—Carrier transporting layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
- H10K85/321—Metal complexes comprising a group IIIA element, e.g. Tris (8-hydroxyquinoline) gallium [Gaq3]
- H10K85/322—Metal complexes comprising a group IIIA element, e.g. Tris (8-hydroxyquinoline) gallium [Gaq3] comprising boron
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/615—Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
- H10K85/622—Polycyclic condensed aromatic hydrocarbons, e.g. anthracene containing four rings, e.g. pyrene
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/631—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
- H10K85/633—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine comprising polycyclic condensed aromatic hydrocarbons as substituents on the nitrogen atom
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/649—Aromatic compounds comprising a hetero atom
- H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
- H10K85/6572—Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/649—Aromatic compounds comprising a hetero atom
- H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
- H10K85/6574—Polycyclic condensed heteroaromatic hydrocarbons comprising only oxygen in the heteroaromatic polycondensed ring system, e.g. cumarine dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1018—Heterocyclic compounds
- C09K2211/1025—Heterocyclic compounds characterised by ligands
- C09K2211/1096—Heterocyclic compounds characterised by ligands containing other heteroatoms
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/917—Electroluminescent
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Inorganic Chemistry (AREA)
- Optics & Photonics (AREA)
- Electroluminescent Light Sources (AREA)
- Pyrrole Compounds (AREA)
Abstract
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020107012068A KR101142621B1 (ko) | 2007-11-02 | 2008-10-28 | 발광 소자 재료 및 발광 소자 |
US12/740,821 US8962155B2 (en) | 2007-11-02 | 2008-10-28 | Light emitting device based on a pyrromethene compound |
EP08844375.9A EP2208772B1 (en) | 2007-11-02 | 2008-10-28 | Luminescent-element material and luminescent element |
JP2008555548A JP4941471B2 (ja) | 2007-11-02 | 2008-10-28 | 発光素子材料および発光素子 |
CN200880113148.9A CN101835873B (zh) | 2007-11-02 | 2008-10-28 | 发光元件材料及发光元件 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007285862 | 2007-11-02 | ||
JP2007-285862 | 2007-11-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009057567A1 true WO2009057567A1 (ja) | 2009-05-07 |
Family
ID=40590958
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2008/069485 WO2009057567A1 (ja) | 2007-11-02 | 2008-10-28 | 発光素子材料および発光素子 |
Country Status (7)
Country | Link |
---|---|
US (1) | US8962155B2 (ja) |
EP (1) | EP2208772B1 (ja) |
JP (1) | JP4941471B2 (ja) |
KR (1) | KR101142621B1 (ja) |
CN (1) | CN101835873B (ja) |
TW (1) | TWI464231B (ja) |
WO (1) | WO2009057567A1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2009116456A1 (ja) * | 2008-03-19 | 2011-07-21 | 東レ株式会社 | 発光素子材料及び発光素子 |
JP2011241160A (ja) * | 2010-05-17 | 2011-12-01 | Yamamoto Chem Inc | 色変換材料、該材料を含む組成物、該組成物を使用した色変換光学部品および該色変換光学部品を使用した発光素子 |
WO2017002707A1 (ja) * | 2015-06-29 | 2017-01-05 | 東レ株式会社 | 色変換組成物、色変換フィルム並びにそれを含む発光装置、液晶表示装置および照明装置 |
WO2019013063A1 (ja) * | 2017-07-10 | 2019-01-17 | 東レ株式会社 | 発光素子、それを含むディスプレイ、照明装置およびセンサ |
JPWO2019146332A1 (ja) * | 2018-01-26 | 2020-02-06 | 東レ株式会社 | ピロメテンホウ素錯体、色変換組成物、色変換フィルム、光源ユニット、ディスプレイ、照明装置および発光素子 |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20110089412A1 (en) * | 2008-06-16 | 2011-04-21 | Shigeo Fujimori | Patterning method, production method of device using the patterning method, and device |
KR101686077B1 (ko) * | 2013-08-07 | 2016-12-13 | 제일모직 주식회사 | 유기 광전자 소자용 화합물, 이를 포함하는 유기 광전자 소자 및 상기 유기 광전자 소자를 포함하는 표시장치 |
TWI473780B (zh) | 2014-04-09 | 2015-02-21 | Nat Univ Chung Hsing | 光敏染料化合物以及染料敏化太陽能電池 |
TWI617659B (zh) * | 2015-01-31 | 2018-03-11 | Lg 化學股份有限公司 | 色彩轉換膜、其製造方法、背光單元和顯示設備 |
SG11201709751SA (en) * | 2015-05-26 | 2017-12-28 | Toray Industries | Pyrromethene-boron complex, color-changing composition, color-changing film, light source unit including same, display, and lighting |
KR102148289B1 (ko) * | 2018-07-04 | 2020-08-26 | 에스에프씨주식회사 | 고효율의 유기 발광 소자 |
JP7239253B2 (ja) | 2018-10-15 | 2023-03-14 | エルジー・ケム・リミテッド | 化合物、それを含む色変換組成物および色変換フィルム、それを含むバックライトユニット、それを含むディスプレイデバイス、並びに色変換フィルムの製造方法 |
WO2021149510A1 (ja) * | 2020-01-24 | 2021-07-29 | 東レ株式会社 | ピロメテンホウ素錯体、それを含有する発光素子、表示装置および照明装置 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000208265A (ja) | 1998-11-09 | 2000-07-28 | Toray Ind Inc | 発光素子 |
JP2003012676A (ja) | 2001-04-25 | 2003-01-15 | Toray Ind Inc | ピロメテン金属錯体、それを用いた発光素子材料ならびに発光素子 |
JP2003151773A (ja) * | 2001-11-13 | 2003-05-23 | Toray Ind Inc | 発光素子 |
JP2004107263A (ja) * | 2002-09-19 | 2004-04-08 | Canon Inc | フェナントロリン化合物及びそれを用いた有機発光素子 |
JP2004200162A (ja) * | 2002-12-05 | 2004-07-15 | Toray Ind Inc | 発光素子 |
JP2005053900A (ja) | 2003-07-23 | 2005-03-03 | Toray Ind Inc | ピロメテン化合物、それを用いた発光素子材料ならびに発光素子 |
JP2006245172A (ja) * | 2005-03-02 | 2006-09-14 | Toray Ind Inc | 発光素子 |
JP2007510294A (ja) * | 2003-10-24 | 2007-04-19 | イーストマン コダック カンパニー | 非対称ホストを有するoled素子 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4024009B2 (ja) * | 2000-04-21 | 2007-12-19 | Tdk株式会社 | 有機el素子 |
TW565604B (en) * | 2001-04-25 | 2003-12-11 | Toray Industries | Pyrromethene metal complex, material of luminescent element using it and luminescent element |
US8278819B2 (en) * | 2007-03-09 | 2012-10-02 | Idemitsu Kosan Co., Ltd. | Organic electroluminescence device and display |
CN101205416A (zh) | 2007-12-06 | 2008-06-25 | 山东师范大学 | 吡咯二甲川类荧光染料及其合成方法和用途 |
-
2008
- 2008-10-28 CN CN200880113148.9A patent/CN101835873B/zh active Active
- 2008-10-28 KR KR1020107012068A patent/KR101142621B1/ko active IP Right Grant
- 2008-10-28 JP JP2008555548A patent/JP4941471B2/ja active Active
- 2008-10-28 WO PCT/JP2008/069485 patent/WO2009057567A1/ja active Application Filing
- 2008-10-28 EP EP08844375.9A patent/EP2208772B1/en active Active
- 2008-10-28 US US12/740,821 patent/US8962155B2/en active Active
- 2008-10-30 TW TW097141743A patent/TWI464231B/zh active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000208265A (ja) | 1998-11-09 | 2000-07-28 | Toray Ind Inc | 発光素子 |
JP2003012676A (ja) | 2001-04-25 | 2003-01-15 | Toray Ind Inc | ピロメテン金属錯体、それを用いた発光素子材料ならびに発光素子 |
JP2003151773A (ja) * | 2001-11-13 | 2003-05-23 | Toray Ind Inc | 発光素子 |
JP2004107263A (ja) * | 2002-09-19 | 2004-04-08 | Canon Inc | フェナントロリン化合物及びそれを用いた有機発光素子 |
JP2004200162A (ja) * | 2002-12-05 | 2004-07-15 | Toray Ind Inc | 発光素子 |
JP2005053900A (ja) | 2003-07-23 | 2005-03-03 | Toray Ind Inc | ピロメテン化合物、それを用いた発光素子材料ならびに発光素子 |
JP2007510294A (ja) * | 2003-10-24 | 2007-04-19 | イーストマン コダック カンパニー | 非対称ホストを有するoled素子 |
JP2006245172A (ja) * | 2005-03-02 | 2006-09-14 | Toray Ind Inc | 発光素子 |
Non-Patent Citations (2)
Title |
---|
APPLIED PHYSICS LETTERS, USA, vol. 51, no. 12, 1987, pages 913 - 915 |
See also references of EP2208772A4 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2009116456A1 (ja) * | 2008-03-19 | 2011-07-21 | 東レ株式会社 | 発光素子材料及び発光素子 |
JP2011241160A (ja) * | 2010-05-17 | 2011-12-01 | Yamamoto Chem Inc | 色変換材料、該材料を含む組成物、該組成物を使用した色変換光学部品および該色変換光学部品を使用した発光素子 |
WO2017002707A1 (ja) * | 2015-06-29 | 2017-01-05 | 東レ株式会社 | 色変換組成物、色変換フィルム並びにそれを含む発光装置、液晶表示装置および照明装置 |
KR20180022705A (ko) * | 2015-06-29 | 2018-03-06 | 도레이 카부시키가이샤 | 색변환 조성물, 색변환 필름, 그리고 그것을 포함하는 발광 장치, 액정 표시 장치 및 조명 장치 |
JPWO2017002707A1 (ja) * | 2015-06-29 | 2018-07-05 | 東レ株式会社 | 色変換組成物、色変換フィルム並びにそれを含む発光装置、液晶表示装置および照明装置 |
US10703970B2 (en) | 2015-06-29 | 2020-07-07 | Toray Industries, Inc. | Color conversion composition, color conversion film and light emitting device including the same, liquid crystal display device, and illumination device |
KR102386152B1 (ko) * | 2015-06-29 | 2022-04-13 | 도레이 카부시키가이샤 | 색변환 조성물, 색변환 필름, 그리고 그것을 포함하는 발광 장치, 액정 표시 장치 및 조명 장치 |
WO2019013063A1 (ja) * | 2017-07-10 | 2019-01-17 | 東レ株式会社 | 発光素子、それを含むディスプレイ、照明装置およびセンサ |
JPWO2019013063A1 (ja) * | 2017-07-10 | 2020-05-07 | 東レ株式会社 | 発光素子、それを含むディスプレイ、照明装置およびセンサ |
JP7120015B2 (ja) | 2017-07-10 | 2022-08-17 | 東レ株式会社 | 発光素子 |
JPWO2019146332A1 (ja) * | 2018-01-26 | 2020-02-06 | 東レ株式会社 | ピロメテンホウ素錯体、色変換組成物、色変換フィルム、光源ユニット、ディスプレイ、照明装置および発光素子 |
Also Published As
Publication number | Publication date |
---|---|
US8962155B2 (en) | 2015-02-24 |
TWI464231B (zh) | 2014-12-11 |
EP2208772B1 (en) | 2016-01-06 |
JPWO2009057567A1 (ja) | 2011-03-10 |
CN101835873A (zh) | 2010-09-15 |
TW200927877A (en) | 2009-07-01 |
EP2208772A4 (en) | 2011-08-17 |
KR101142621B1 (ko) | 2012-05-03 |
US20100264406A1 (en) | 2010-10-21 |
CN101835873B (zh) | 2015-04-08 |
EP2208772A1 (en) | 2010-07-21 |
KR20100092472A (ko) | 2010-08-20 |
JP4941471B2 (ja) | 2012-05-30 |
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