WO2009048041A1 - ガソリン基材の製造方法及びガソリン - Google Patents

ガソリン基材の製造方法及びガソリン Download PDF

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Publication number
WO2009048041A1
WO2009048041A1 PCT/JP2008/068162 JP2008068162W WO2009048041A1 WO 2009048041 A1 WO2009048041 A1 WO 2009048041A1 JP 2008068162 W JP2008068162 W JP 2008068162W WO 2009048041 A1 WO2009048041 A1 WO 2009048041A1
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WO
WIPO (PCT)
Prior art keywords
product oil
mass ppm
content
gasoline
compounds
Prior art date
Application number
PCT/JP2008/068162
Other languages
English (en)
French (fr)
Inventor
Shigeto Hatanaka
Koji Shimada
Hideshi Iki
Original Assignee
Nippon Oil Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Oil Corporation filed Critical Nippon Oil Corporation
Priority to CN2008801111979A priority Critical patent/CN101821362B/zh
Priority to US12/681,787 priority patent/US8303805B2/en
Priority to KR1020107008422A priority patent/KR101514954B1/ko
Priority to EP08837277.6A priority patent/EP2202286B1/en
Publication of WO2009048041A1 publication Critical patent/WO2009048041A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of catalytic cracking in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

　本発明の製造方法は、接触分解ガソリンを、該接触分解ガソリン中に含有されるオレフィンの水素化率が２５モル％以下、生成油の質量を基準とする全硫黄分の含有量が２０質量ｐｐｍ以下、チオフェン類及びベンゾチオフェン類に由来する硫黄分の含有量が５質量ｐｐｍ以下、かつ、チアシクロペンタン類に由来する硫黄分が０．１質量ｐｐｍ以下となるように水素化脱硫する第１の工程と、第１の工程の生成油を、第１の工程におけるオレフィンの水素化率と本工程におけるオレフィンの水素化率との合計が３０モル％以下、生成油の質量を基準とする全硫黄分の含有量が１０質量ｐｐｍ以下、かつ、チオール類に由来する硫黄分の含有量が５質量ｐｐｍ以下となるようにさらに水素化脱硫する第２の工程と、を備える。
PCT/JP2008/068162 2007-10-12 2008-10-06 ガソリン基材の製造方法及びガソリン WO2009048041A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2008801111979A CN101821362B (zh) 2007-10-12 2008-10-06 汽油基材的制造方法及汽油
US12/681,787 US8303805B2 (en) 2007-10-12 2008-10-06 Process for producing gasoline base and gasoline
KR1020107008422A KR101514954B1 (ko) 2007-10-12 2008-10-06 가솔린 기재의 제조방법 및 가솔린
EP08837277.6A EP2202286B1 (en) 2007-10-12 2008-10-06 Process for producing gasoline base and gasoline

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-267031 2007-10-12
JP2007267031A JP5123635B2 (ja) 2007-10-12 2007-10-12 ガソリン基材の製造方法及びガソリン

Publications (1)

Publication Number Publication Date
WO2009048041A1 true WO2009048041A1 (ja) 2009-04-16

Family

ID=40549185

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/068162 WO2009048041A1 (ja) 2007-10-12 2008-10-06 ガソリン基材の製造方法及びガソリン

Country Status (6)

Country Link
US (1) US8303805B2 (ja)
EP (1) EP2202286B1 (ja)
JP (1) JP5123635B2 (ja)
KR (1) KR101514954B1 (ja)
CN (1) CN101821362B (ja)
WO (1) WO2009048041A1 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108654702A (zh) * 2018-03-29 2018-10-16 南京大学连云港高新技术研究院 一种劣质重油裂解脱硫减粘的催化剂、制备方法及其应用

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102604673B (zh) * 2011-01-20 2014-12-03 中国石油化工股份有限公司 一种生产低硫汽油的方法
CN102839021A (zh) * 2011-06-22 2012-12-26 北京金伟晖工程技术有限公司 一种低成本制造低硫高辛烷值汽油的装置及其方法
FR3122105B1 (fr) 2021-04-21 2023-11-24 Ifp Energies Now Catalyseur contenant du phosphore et du sodium et son utilisation dans un procede d’hydrodesulfuration

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US4149965A (en) 1978-06-27 1979-04-17 Exxon Research & Engineering Co. Method for starting-up a naphtha hydrorefining process
US4990242A (en) 1989-06-14 1991-02-05 Exxon Research And Engineering Company Enhanced sulfur removal from fuels
US5352354A (en) 1991-08-15 1994-10-04 Mobil Oil Corporation Gasoline upgrading process
JPH0940972A (ja) * 1995-07-26 1997-02-10 Mitsubishi Oil Co Ltd 接触分解ガソリンの脱硫方法
JP2000505358A (ja) 1996-02-02 2000-05-09 エクソン リサーチ アンド エンジニアリング カンパニー 選択的水素化脱硫触媒及び方法
JP2000239668A (ja) 1999-02-24 2000-09-05 Inst Fr Petrole 低硫黄含有量のガソリン製造方法
JP2003528942A (ja) * 1999-11-24 2003-09-30 エクソンモービル リサーチ アンド エンジニアリング カンパニー メルカプタンの形成が低減された二段高度ナフサ脱硫
JP2003327970A (ja) * 2002-03-29 2003-11-19 Inst Fr Petrole 硫黄およびメルカプタンの含量の低い炭化水素を製造する方法
JP2006508196A (ja) * 2002-05-21 2006-03-09 エクソンモービル リサーチ アンド エンジニアリング カンパニー 積層床反応器による分解ナフサ・ストリームの多段水素化脱硫

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FR2476118B1 (fr) * 1980-02-19 1987-03-20 Inst Francais Du Petrole Procede de desulfuration d'un effluent de craquage catalytique ou de craquage a la vapeur
US5360532A (en) * 1991-08-15 1994-11-01 Mobil Oil Corporation Gasoline upgrading process
FR2807061B1 (fr) * 2000-03-29 2002-05-31 Inst Francais Du Petrole Procede de desulfuration d'essence comprenant une desulfuration des fractions lourde et intermediaire issues d'un fractionnement en au moins trois coupes
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US6610197B2 (en) * 2000-11-02 2003-08-26 Exxonmobil Research And Engineering Company Low-sulfur fuel and process of making
US20020175108A1 (en) * 2001-03-12 2002-11-28 Institut Francais Du Petrole Process for the production of a desulfurized gasoline from a gasoline fraction that contains conversion gasoline
JP4486329B2 (ja) * 2003-07-14 2010-06-23 財団法人石油産業活性化センター ガソリン留分の水素化脱硫触媒および水素化脱硫方法
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4149965A (en) 1978-06-27 1979-04-17 Exxon Research & Engineering Co. Method for starting-up a naphtha hydrorefining process
US4990242A (en) 1989-06-14 1991-02-05 Exxon Research And Engineering Company Enhanced sulfur removal from fuels
US5352354A (en) 1991-08-15 1994-10-04 Mobil Oil Corporation Gasoline upgrading process
JPH0940972A (ja) * 1995-07-26 1997-02-10 Mitsubishi Oil Co Ltd 接触分解ガソリンの脱硫方法
JP2000505358A (ja) 1996-02-02 2000-05-09 エクソン リサーチ アンド エンジニアリング カンパニー 選択的水素化脱硫触媒及び方法
JP2000239668A (ja) 1999-02-24 2000-09-05 Inst Fr Petrole 低硫黄含有量のガソリン製造方法
JP2003528942A (ja) * 1999-11-24 2003-09-30 エクソンモービル リサーチ アンド エンジニアリング カンパニー メルカプタンの形成が低減された二段高度ナフサ脱硫
JP2003327970A (ja) * 2002-03-29 2003-11-19 Inst Fr Petrole 硫黄およびメルカプタンの含量の低い炭化水素を製造する方法
JP2006508196A (ja) * 2002-05-21 2006-03-09 エクソンモービル リサーチ アンド エンジニアリング カンパニー 積層床反応器による分解ナフサ・ストリームの多段水素化脱硫

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See also references of EP2202286A4 *
TOYOTA TECHNICAL REVIEW, vol. 50, no. 2, December 2000 (2000-12-01), pages 28 - 33

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108654702A (zh) * 2018-03-29 2018-10-16 南京大学连云港高新技术研究院 一种劣质重油裂解脱硫减粘的催化剂、制备方法及其应用

Also Published As

Publication number Publication date
EP2202286A4 (en) 2012-12-05
CN101821362B (zh) 2013-04-24
JP2009096830A (ja) 2009-05-07
KR20100072262A (ko) 2010-06-30
EP2202286B1 (en) 2017-07-19
KR101514954B1 (ko) 2015-04-24
EP2202286A1 (en) 2010-06-30
JP5123635B2 (ja) 2013-01-23
US8303805B2 (en) 2012-11-06
US20100219102A1 (en) 2010-09-02
CN101821362A (zh) 2010-09-01

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